DE60238939D1 - Organometallische übergangsmetallverbindung, biscyclopentadienylligandsystem, katalysatorsystem und herstellung von polyolefinen - Google Patents
Organometallische übergangsmetallverbindung, biscyclopentadienylligandsystem, katalysatorsystem und herstellung von polyolefinenInfo
- Publication number
- DE60238939D1 DE60238939D1 DE60238939T DE60238939T DE60238939D1 DE 60238939 D1 DE60238939 D1 DE 60238939D1 DE 60238939 T DE60238939 T DE 60238939T DE 60238939 T DE60238939 T DE 60238939T DE 60238939 D1 DE60238939 D1 DE 60238939D1
- Authority
- DE
- Germany
- Prior art keywords
- polyolefines
- preparation
- transition metal
- metal compound
- organometallic transition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE60238939T DE60238939D1 (de) | 2001-11-30 | 2002-11-26 | Organometallische übergangsmetallverbindung, biscyclopentadienylligandsystem, katalysatorsystem und herstellung von polyolefinen |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10158656A DE10158656A1 (de) | 2001-11-30 | 2001-11-30 | Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
| DE60238939T DE60238939D1 (de) | 2001-11-30 | 2002-11-26 | Organometallische übergangsmetallverbindung, biscyclopentadienylligandsystem, katalysatorsystem und herstellung von polyolefinen |
| PCT/EP2002/013296 WO2003045551A1 (en) | 2001-11-30 | 2002-11-26 | Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and preparation of polyolefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE60238939D1 true DE60238939D1 (de) | 2011-02-24 |
Family
ID=7707431
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE10158656A Withdrawn DE10158656A1 (de) | 2001-11-30 | 2001-11-30 | Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
| DE60238939T Expired - Lifetime DE60238939D1 (de) | 2001-11-30 | 2002-11-26 | Organometallische übergangsmetallverbindung, biscyclopentadienylligandsystem, katalysatorsystem und herstellung von polyolefinen |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE10158656A Withdrawn DE10158656A1 (de) | 2001-11-30 | 2001-11-30 | Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7109278B2 (de) |
| EP (1) | EP1455938B1 (de) |
| JP (1) | JP4416507B2 (de) |
| AR (1) | AR037470A1 (de) |
| AT (1) | ATE494954T1 (de) |
| AU (1) | AU2002358541A1 (de) |
| DE (2) | DE10158656A1 (de) |
| WO (1) | WO2003045551A1 (de) |
Families Citing this family (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10200422A1 (de) * | 2002-01-08 | 2003-07-17 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von Dialkyl-ansa-Metallocenen |
| ATE445651T1 (de) * | 2002-09-06 | 2009-10-15 | Basell Polyolefine Gmbh | Verfahren zur copolymerisation von ethylen |
| US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
| US20060252637A1 (en) * | 2003-05-28 | 2006-11-09 | Basell Polyolefine Gmbh | Bisindenyl zirconium complexes for use in the polymerization of olefins |
| EP1664139A1 (de) * | 2003-09-11 | 2006-06-07 | Basell Polyolefine GmbH | Mehrschrittverfahren zur herstellung von heterophasigen propylencopolymeren |
| DE10358082A1 (de) | 2003-12-10 | 2005-07-14 | Basell Polyolefine Gmbh | Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen |
| EP1753792B1 (de) * | 2004-05-04 | 2009-10-14 | Basell Polyolefine GmbH | Verfahren zur herstellung von ataktischen 1-butenpolymeren |
| DE102004027332A1 (de) * | 2004-06-04 | 2005-12-22 | Basell Polyolefine Gmbh | Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
| DE102004056104A1 (de) * | 2004-11-19 | 2006-05-24 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von niedermolekularen Olefinpolymeren, Organoübergangsmetallverbindungen, Biscyclopentadienylligandsysteme und Katalysatorsysteme |
| WO2006065906A2 (en) * | 2004-12-16 | 2006-06-22 | Exxonmobil Chemical Patents Inc. | Halogen substituted metallocene compounds for olefin polymerization |
| ES2692449T3 (es) * | 2005-06-13 | 2018-12-03 | Basell Polyolefine Gmbh | Proceso para la copolimerización de propileno |
| WO2007028536A2 (en) * | 2005-09-06 | 2007-03-15 | Basell Polyolefine Gmbh | Process for preparing olefin polymers in the presence of catalyst systems having photochromic groups |
| DE102005052654A1 (de) * | 2005-11-04 | 2007-05-16 | Ticona Gmbh | Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren |
| US8034886B2 (en) | 2005-11-04 | 2011-10-11 | Ticona Gmbh | Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts |
| US7598329B2 (en) * | 2005-11-04 | 2009-10-06 | Ticona Gmbh | Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts |
| WO2007070041A1 (en) | 2005-12-14 | 2007-06-21 | Exxonmobil Chemical Patents Inc. | Halogen substituted metallocene compounds for olefin polymerization |
| US7667064B2 (en) * | 2005-12-14 | 2010-02-23 | Exxonmobil Chemical Patents Inc. | Halogen substituted metallocene compounds for olefin polymerization |
| US7538168B2 (en) | 2005-12-14 | 2009-05-26 | Exxonmobil Chemical Patents Inc. | Halogen substituted metallocene compounds for olefin polymerization |
| US7550544B2 (en) * | 2005-12-14 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Halogen substituted metallocene compounds for olefin polymerization |
| US7868197B2 (en) | 2005-12-14 | 2011-01-11 | Exxonmobil Chemical Patents Inc. | Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization |
| EP2010579A1 (de) * | 2006-04-21 | 2009-01-07 | Basell Polyolefine GmbH | Verfahren zur herstellung von ethylen-propylen-copolymeren |
| EP2010580B1 (de) * | 2006-04-21 | 2016-07-13 | Basell Polyolefine GmbH | Verfahren zur herstellung von ethylencopolymeren |
| US8242237B2 (en) | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
| EP2160419B1 (de) | 2007-06-04 | 2013-11-13 | ExxonMobil Chemical Patents Inc. | Homogene propylenpolymerisation unter superlösungsbedingungen |
| EP2235071A2 (de) | 2007-10-25 | 2010-10-06 | Novolen Technology Holdings, C.V. | Metallocenverbindungen, katalysatoren, die diese enthalten, verfahren zur herstellung eines olefinpolymers unter verwendung der katalysatoren und olefinhomo- und copolymere |
| KR20100101092A (ko) | 2007-10-25 | 2010-09-16 | 루머스 노보렌 테크놀로지 게엠베하 | 메탈로센 화합물, 이를 포함하는 촉매, 이 촉매를 사용한 올레핀 폴리머생산방법, 및 올레핀 호모- 및 코폴리머 |
| US7812104B2 (en) * | 2008-01-18 | 2010-10-12 | Exxonmobil Chemical Patents Inc. | Production of propylene-based polymers |
| US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
| US7544825B1 (en) * | 2008-06-12 | 2009-06-09 | Basell Polyolefine Gmbh | Preparation of siloxy-bridged metallocenes |
| US9567351B2 (en) * | 2011-07-08 | 2017-02-14 | Borealis Ag | Heterophasic copolymers |
| JP6176015B2 (ja) | 2012-11-01 | 2017-08-09 | 日本ポリプロ株式会社 | メタロセン錯体およびオレフィンの重合方法 |
| EP2935296B1 (de) | 2012-12-21 | 2017-11-15 | Borealis AG | Katalysator |
| ES2645256T3 (es) | 2012-12-21 | 2017-12-04 | Borealis Ag | Catalizadores |
| ES2674576T3 (es) * | 2012-12-21 | 2018-07-02 | Borealis Ag | Catalizador |
| JP5710035B2 (ja) | 2013-02-27 | 2015-04-30 | 日本ポリエチレン株式会社 | メタロセン化合物およびオレフィン重合体の製造方法 |
| JP5695687B2 (ja) | 2013-03-05 | 2015-04-08 | 日本ポリエチレン株式会社 | エチレン／α−オレフィン共重合体の製造方法 |
| WO2015009479A1 (en) | 2013-07-17 | 2015-01-22 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
| US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
| WO2015009470A1 (en) | 2013-07-17 | 2015-01-22 | Exxonmobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| EP3848401A1 (de) | 2013-07-17 | 2021-07-14 | ExxonMobil Chemical Patents Inc. | Isotaktische propylenpolymere |
| EP3022233B1 (de) | 2013-07-17 | 2019-05-01 | ExxonMobil Chemical Patents Inc. | Cyclopropyl-substituierte metallocenkatalysatoren |
| WO2015009472A1 (en) | 2013-07-17 | 2015-01-22 | Exxonmobil Chemcal Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| KR101743327B1 (ko) * | 2014-07-16 | 2017-06-02 | 주식회사 엘지화학 | 신규한 리간드 화합물 및 전이금속 화합물 |
| KR101785764B1 (ko) | 2014-07-16 | 2017-10-16 | 주식회사 엘지화학 | 신규한 리간드 화합물 및 전이금속 화합물의 제조방법 |
| WO2016196331A1 (en) | 2015-06-05 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Supported metallocene catalyst systems for polymerization |
| US10280235B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers |
| US10329360B2 (en) | 2015-06-05 | 2019-06-25 | Exxonmobil Chemical Patents Inc. | Catalyst system comprising supported alumoxane and unsupported alumoxane particles |
| US9809664B2 (en) | 2015-06-05 | 2017-11-07 | Exxonmobil Chemical Patents Inc. | Bimodal propylene polymers and sequential polymerization |
| CN107690441A (zh) | 2015-06-05 | 2018-02-13 | 埃克森美孚化学专利公司 | 聚合物在气相或淤浆相中的单反应器制备 |
| US10294316B2 (en) | 2015-06-05 | 2019-05-21 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
| EP3885373A1 (de) | 2015-06-05 | 2021-09-29 | ExxonMobil Chemical Patents Inc. | Herstellung von heterophasischen polymeren in gas- oder schlämmephase |
| US10280233B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst systems and methods of making and using the same |
| EP3464390A1 (de) | 2016-05-27 | 2019-04-10 | ExxonMobil Chemical Patents Inc. | Metallocenkatalysatorzusammensetzungen und und polymerisationsverfahren damit |
| JP7248405B2 (ja) * | 2018-09-27 | 2023-03-29 | 三井化学株式会社 | 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| KR102624685B1 (ko) * | 2019-01-28 | 2024-01-11 | 주식회사 엘지화학 | 전이 금속 화합물, 촉매 조성물 및 이를 이용한 폴리프로필렌의 제조 방법 |
| KR102524952B1 (ko) * | 2019-06-13 | 2023-04-24 | 주식회사 엘지화학 | 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법 |
| EP3925987A4 (de) * | 2019-06-13 | 2022-04-27 | Lg Chem, Ltd. | Hybrider geträgerter metallocenkatalysator und verfahren zur herstellung von polypropylen damit |
| US11472828B2 (en) | 2019-10-11 | 2022-10-18 | Exxonmobil Chemical Patents Inc. | Indacene based metallocene catalysts useful in the production of propylene polymers |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1991009882A1 (en) | 1990-01-02 | 1991-07-11 | Exxon Chemical Patents Inc. | Supported ionic metallocene catalysts for olefin polymerization |
| PL182074B1 (en) | 1994-06-24 | 2001-11-30 | Exxon Chemical Patents Inc | Catalytic systems for polymerisation processes, their production and application |
| CA2164461C (en) * | 1994-12-06 | 2000-08-08 | Tatsuya Tanizaki | Polypropylene composition and uses thereof |
| KR100405780B1 (ko) | 1996-04-22 | 2004-03-30 | 닛뽕폴리올레핀가부시키가이샤 | 폴리올레핀제조용촉매및폴리올레핀의제조방법 |
| CA2262493A1 (en) | 1997-03-07 | 1998-09-17 | Targor Gmbh | Method for producing olefin polymers with a higher melting point |
| DE19757563A1 (de) | 1997-03-07 | 1999-07-08 | Targor Gmbh | Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| DE19733017A1 (de) | 1997-07-31 | 1999-02-04 | Hoechst Ag | Chemische Verbindung |
| DE19813656A1 (de) | 1998-03-27 | 1999-09-30 | Aventis Res & Tech Gmbh & Co | Übergangsmetallverbindung |
| DE19813657A1 (de) | 1998-03-27 | 1999-09-30 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| JPH11349618A (ja) * | 1998-06-04 | 1999-12-21 | Mitsubishi Chemical Corp | α−オレフィン重合用触媒成分、触媒およびα−オレフィン重合体の製造方法 |
| JPH11349617A (ja) * | 1998-06-04 | 1999-12-21 | Mitsubishi Chemical Corp | α−オレフィン重合用触媒成分、触媒およびα−オレフィン重合体の製造方法 |
| DE19833170A1 (de) | 1998-07-23 | 2000-01-27 | Targor Gmbh | Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz |
| DE19903306A1 (de) * | 1999-01-28 | 2000-08-03 | Targor Gmbh | Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung |
| PL347324A1 (en) * | 1998-10-08 | 2002-03-25 | Dow Chemical Co | Bridged metal complexes |
| UA57864C2 (uk) | 1998-10-08 | 2003-07-15 | Бп Кемікалз Лімітед | Спосіб полімеризації олефінів з використанням місточкових металевих комплексів |
| RU2002120467A (ru) | 1999-12-21 | 2004-01-10 | Базель Полиолефин Гмбх (De) | Частично кристаллическая пропилен-полимерная композиция для получения биаксиально вытянутых полипропиленовых пленок |
| US7342078B2 (en) * | 1999-12-23 | 2008-03-11 | Basell Polyolefine Gmbh | Transition metal compound, ligand system, catalyst system and the use of the latter for polymerisation and copolymerisation of olefins |
| DE19962905A1 (de) * | 1999-12-23 | 2001-07-12 | Basell Polyolefine Gmbh | Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation und Copolymerisation von Olefinen |
| US6492465B1 (en) * | 2000-02-08 | 2002-12-10 | Exxonmobil Chemical Patents, Inc. | Propylene impact copolymers |
| ATE309259T1 (de) * | 2000-06-30 | 2005-11-15 | Exxonmobil Chem Patents Inc | Überbrückte bisindenylmetallocenverbindungen |
| DE60112307T8 (de) | 2000-06-30 | 2007-02-15 | Exxonmobil Chemical Patents Inc., Baytown | Metallocenverbindungen mit einem verbrückten 4-phenylindenyl-ligandsystem zur polymerisation von olefinen |
| WO2002018397A1 (de) | 2000-08-29 | 2002-03-07 | Basell Polypropylen Gmbh | VERFAHREN ZUR HERSTELLUNG VON AlKYLVERBRÜCKTEN LIGANDSYSTEMEN UND ÜBERGANGSMETALLVERBINDUNGEN |
| GB0111020D0 (en) * | 2001-05-04 | 2001-06-27 | Borealis Tech Oy | Process |
| DE10126265A1 (de) | 2001-05-29 | 2002-12-05 | Basell Polyolefine Gmbh | Verfahren zur Abreicherung von anorganischen Nebenprodukten und organometallischen Nebenprodukten bei der Herstellung von Metallocenen sowie der wirtschaftlichen Rückgewinnung der eingesetzten Edukte |
| EP1421090B1 (de) * | 2001-06-29 | 2014-03-26 | ExxonMobil Chemical Patents Inc. | Metallocene und diese enthaltende katalysatorzusammensetzungen |
-
2001
- 2001-11-30 DE DE10158656A patent/DE10158656A1/de not_active Withdrawn
-
2002
- 2002-11-26 EP EP02792805A patent/EP1455938B1/de not_active Expired - Lifetime
- 2002-11-26 US US10/496,142 patent/US7109278B2/en not_active Expired - Lifetime
- 2002-11-26 JP JP2003547045A patent/JP4416507B2/ja not_active Expired - Lifetime
- 2002-11-26 DE DE60238939T patent/DE60238939D1/de not_active Expired - Lifetime
- 2002-11-26 AT AT02792805T patent/ATE494954T1/de not_active IP Right Cessation
- 2002-11-26 WO PCT/EP2002/013296 patent/WO2003045551A1/en active Application Filing
- 2002-11-26 AU AU2002358541A patent/AU2002358541A1/en not_active Abandoned
- 2002-11-29 AR ARP020104606A patent/AR037470A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20040260107A1 (en) | 2004-12-23 |
| AU2002358541A1 (en) | 2003-06-10 |
| JP4416507B2 (ja) | 2010-02-17 |
| EP1455938B1 (de) | 2011-01-12 |
| ATE494954T1 (de) | 2011-01-15 |
| WO2003045551A1 (en) | 2003-06-05 |
| AR037470A1 (es) | 2004-11-10 |
| EP1455938A1 (de) | 2004-09-15 |
| DE10158656A1 (de) | 2003-06-26 |
| US7109278B2 (en) | 2006-09-19 |
| JP2005510546A (ja) | 2005-04-21 |
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