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DE60112307T8 - Metallocenverbindungen mit einem verbrückten 4-phenylindenyl-ligandsystem zur polymerisation von olefinen - Google Patents

Metallocenverbindungen mit einem verbrückten 4-phenylindenyl-ligandsystem zur polymerisation von olefinen Download PDF

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Publication number
DE60112307T8
DE60112307T8 DE60112307T DE60112307T DE60112307T8 DE 60112307 T8 DE60112307 T8 DE 60112307T8 DE 60112307 T DE60112307 T DE 60112307T DE 60112307 T DE60112307 T DE 60112307T DE 60112307 T8 DE60112307 T8 DE 60112307T8
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Prior art keywords
group
groups
aryl
alkyl
halogen atom
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DE60112307T
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DE60112307D1 (de
DE60112307T2 (de
Inventor
J. Terry BURKHARDT
M. Udo STEHLING
R. James HART
T. William HAYGOOD
T. Robert LI
C. James VIZZINI
C. Matthew KUCHTA
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ExxonMobil Chemical Patents Inc
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ExxonMobil Chemical Patents Inc
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Priority claimed from US09/619,752 external-priority patent/US6399723B1/en
Priority claimed from US09/619,759 external-priority patent/US6376408B1/en
Priority claimed from US09/620,522 external-priority patent/US6380124B1/en
Priority claimed from US09/619,750 external-priority patent/US6380120B1/en
Priority claimed from US09/619,764 external-priority patent/US6376409B1/en
Priority claimed from US09/619,749 external-priority patent/US6376407B1/en
Priority claimed from US09/620,303 external-priority patent/US6414095B1/en
Priority claimed from US09/620,304 external-priority patent/US6376412B1/en
Priority claimed from US09/620,175 external-priority patent/US6376410B1/en
Priority claimed from US09/619,748 external-priority patent/US6376627B1/en
Priority claimed from US09/620,198 external-priority patent/US6380330B1/en
Priority claimed from US09/620,302 external-priority patent/US6376411B1/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of DE60112307D1 publication Critical patent/DE60112307D1/de
Application granted granted Critical
Publication of DE60112307T2 publication Critical patent/DE60112307T2/de
Publication of DE60112307T8 publication Critical patent/DE60112307T8/de
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE60112307T 2000-06-30 2001-05-21 Metallocenverbindungen mit einem verbrückten 4-phenylindenyl-ligandsystem zur polymerisation von olefinen Active DE60112307T8 (de)

Applications Claiming Priority (29)

Application Number Priority Date Filing Date Title
US619752 1984-06-12
US620304 1984-06-13
US619749 1990-11-29
US21545900P 2000-06-30 2000-06-30
US21559700P 2000-06-30 2000-06-30
US215459P 2000-06-30
US215597P 2000-06-30
US620303 2000-07-19
US09/619,749 US6376407B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US619759 2000-07-19
US09/620,303 US6414095B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US620175 2000-07-19
US09/620,304 US6376412B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US619748 2000-07-19
US620198 2000-07-19
US09/619,748 US6376627B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,198 US6380330B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US620302 2000-07-19
US09/619,759 US6376408B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,302 US6376411B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,752 US6399723B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,175 US6376410B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,764 US6376409B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US619764 2000-07-19
US09/619,750 US6380120B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,522 US6380124B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US619750 2000-07-19
US620522 2000-07-19
PCT/US2001/016573 WO2002002576A1 (en) 2000-06-30 2001-05-21 Bridged bis (indenyl) metallocene compounds

Publications (3)

Publication Number Publication Date
DE60112307D1 DE60112307D1 (de) 2005-09-01
DE60112307T2 DE60112307T2 (de) 2006-05-24
DE60112307T8 true DE60112307T8 (de) 2007-02-15

Family

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DE60112307T Active DE60112307T8 (de) 2000-06-30 2001-05-21 Metallocenverbindungen mit einem verbrückten 4-phenylindenyl-ligandsystem zur polymerisation von olefinen

Country Status (6)

Country Link
EP (2) EP1313746B1 (de)
JP (1) JP2004502699A (de)
CN (2) CN1332966C (de)
AT (1) ATE300550T1 (de)
DE (1) DE60112307T8 (de)
WO (1) WO2002002576A1 (de)

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