DE567775C - Fast drying paints - Google Patents
Fast drying paintsInfo
- Publication number
- DE567775C DE567775C DEV27649D DEV0027649D DE567775C DE 567775 C DE567775 C DE 567775C DE V27649 D DEV27649 D DE V27649D DE V0027649 D DEV0027649 D DE V0027649D DE 567775 C DE567775 C DE 567775C
- Authority
- DE
- Germany
- Prior art keywords
- oil
- drying
- paints
- oils
- fast drying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000001035 drying Methods 0.000 title claims description 16
- 239000003973 paint Substances 0.000 title claims description 12
- 239000003921 oil Substances 0.000 claims description 23
- 239000002966 varnish Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 4
- -1 aliphatic ketones Chemical class 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 2
- 239000010685 fatty oil Substances 0.000 claims 1
- 235000019198 oils Nutrition 0.000 description 17
- 239000002023 wood Substances 0.000 description 5
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 4
- 235000021388 linseed oil Nutrition 0.000 description 4
- 239000000944 linseed oil Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 2
- GWEHVDNNLFDJLR-UHFFFAOYSA-N 1,3-diphenylurea Chemical compound C=1C=CC=CC=1NC(=O)NC1=CC=CC=C1 GWEHVDNNLFDJLR-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 2
- 239000004312 hexamethylene tetramine Substances 0.000 description 2
- 241000016649 Copaifera officinalis Species 0.000 description 1
- 239000004859 Copal Substances 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- FCSHMCFRCYZTRQ-UHFFFAOYSA-N N,N'-diphenylthiourea Chemical compound C=1C=CC=CC=1NC(=S)NC1=CC=CC=C1 FCSHMCFRCYZTRQ-UHFFFAOYSA-N 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical class [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- XZBSGMLNFFDGNN-UHFFFAOYSA-N [Co][Ca][Pb] Chemical compound [Co][Ca][Pb] XZBSGMLNFFDGNN-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 229950011260 betanaphthol Drugs 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- JQLKSEQEILIJEG-UHFFFAOYSA-N n-(propan-2-ylideneamino)aniline Chemical compound CC(C)=NNC1=CC=CC=C1 JQLKSEQEILIJEG-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Description
Schnell trocknende Anstrichstoffe Es ist schon lange bekannt, daß verschiedene Superoxyde, z. B. Benzoylsuperoxyd, verharztes Terpentinöl usw., die Trocknung chemisch trocknender Anstrichstoffe in geringem Maße zu beschleunigen vermögen. Im Laufe der letzten Jahre ist nun außerdem eine Reihe von organischen Stoffen, wie Carbanilid, Thiocarbanilid, Hexamethylentetramin, Diphenylguanidin (M a r 1 i n in Drugs, O i 1 s und P a i n t s , Vol. XL I I, Philadelphia, April 1927, Heft Nr. i i, Seite 373), bekanntgeworden, die auf chemisch trocknende Anstrichstoffe, wie Öle, Standöle, geschwefelte Öle, Üllacke. Öl- und öllackfarben, ferner unter Verwendung trocknender, fetter Öle hergestellte Spachtel, Kitte, Künstlerfarben usw., in An-oder Abwesenheit von Metalltrockenstoffen (sogenannten Sikkativen ) eine wenn auch sehr geringe Trocknungsbeschleunigung ausüben, die bei einigen von ihnen (z. B. Hexamethylentetramin, Diphenylguanidin) durch die Gegenwart von Oxyden der Metalle der zweiten Gruppe des periodischen Systems wesentlich verstärkt wird.Fast drying paints It has long been known that various super oxides, e.g. B. Benzoylsuperoxid, resinous turpentine oil, etc., able to accelerate the drying of chemically drying paints to a small extent. In the course of the last few years a number of organic substances such as carbanilide, thiocarbanilide, hexamethylenetetramine, diphenylguanidine (M ar 1 in in Drugs, O i 1 s and P aints, Vol. XL II, Philadelphia, April 1927, issue No. ii, page 373), became known that on chemically drying paints, such as oils, stand oils, sulfurized oils, oil varnishes. Oil and oil varnish paints, as well as fillers, putties, artist paints, etc. made using drying, greasy oils, in the presence or absence of dry metal substances (so-called siccatives) exert a very slight drying acceleration, which in some of them (e.g. Hexamethylenetetramine, diphenylguanidine) is significantly increased by the presence of oxides of the metals of the second group of the periodic table.
Schließlich ist hier noch Betanaphthol zu nennen (Farbe und Lack iC)26, Seite 29, linke Spaltet, das aber nur spezifisch bei Holzöl und Holzölprodukten wirkt, während es bei Leinöl die Trocknung verzögert.Finally, betanaphthol should also be mentioned here (paint and varnish iC) 26, Page 29, left column, but only specifically for wood oil and wood oil products works, while with linseed oil it delays drying.
Es wurde nun gefunden, daß die Phenylhydrazone aliphatischer Ketone viel intensiver und universeller die Trocknung chemisch trocknender Anstrichstoffe zu beschleunigen vermögen. Nicht nur, daß sie in Abwesenheit von Metalloxyden, ja selbst von Metalltr ockenstoffen (Sikkativen ) wirksam sind, sie beschleunigen sowohl Leinöl und Leinölprodukte als auch Holzöl und Holzölprodukte. Beispiele i. Rohes Leinöl, in dünner Schicht auf einer Glasplatte aufgestrichen, ist in etwa 70 Stunden staubtrocken; durch Zusatz von i % Acetonphenylhydrazon trocknet es in etwa 3o Stunden. Bei rohem Holzöl kann durch denselben Zusatz die Staubtrocknung von etwa 70 Stunden auf etwa 6 Stunden herabgedrückt werden.It has now been found that the phenylhydrazones of aliphatic ketones are able to accelerate the drying of chemically drying paints much more intensively and universally. Not only that they are effective in the absence of metal oxides, even of metal desiccants (siccatives), they accelerate both linseed oil and linseed oil products as well as wood oil and wood oil products. Examples i. Raw linseed oil, spread in a thin layer on a glass plate, is dust-dry in about 70 hours; by adding 1% acetone phenylhydrazone it dries in about 30 hours. With raw wood oil, the same addition can reduce the dust drying time from around 70 hours to around 6 hours.
2. Eine schwarze Lackfarbe, bestehend aus 41 Gewichtsteilen Elfenbeinschwarz, i Gewichtsteil Ruß, 29 Gewichtsteilen Standöl, 2o Gewichtsteilen Copal-Harzester-Öllack, g Gewichtsteilen Lackbenzin, .1 Gewichtsteilen Kobalt-Blei-Calciumsikkativ, trocknet in etwa 27 Stunden. Durch Zusatz von o,8 % des Phenylhydrazons von Methyläthylketon kann man die Trocknung auf etwa 6i/-, Stunden herunterdrücken.2. A black paint, consisting of 41 parts by weight of ivory black, 1 part by weight of carbon black, 29 parts by weight of stand oil, 2o parts by weight of Copal resin ester oil varnish, g parts by weight of mineral spirits, .1 part by weight of cobalt-lead-calcium siccative, dries in about 27 hours. By adding 0.8% of the phenylhydrazone of methyl ethyl ketone the drying time can be reduced to about 6 1/2 hours.
An Stelle des lackartigen Bindemittels kann auch ein trocknendes Ö1., ein Ölfirnis, ein Standöl, ein geschwefeltes Öl in An- oder Abwesenheit von Metalltrockenstoffen verwandt werden. An Stelle des Elfenbeinschwarzes und Rußes können auch andere Farbkörper angewandt werden.Instead of the lacquer-like binder, a drying oil can also be used. an oil varnish, a stand oil, a sulphurized oil in the presence or absence of dry metal substances be used. Instead of the ivory black and soot, other color bodies can also be used can be applied.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEV27649D DE567775C (en) | 1931-12-20 | 1931-12-20 | Fast drying paints |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEV27649D DE567775C (en) | 1931-12-20 | 1931-12-20 | Fast drying paints |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE567775C true DE567775C (en) | 1933-01-09 |
Family
ID=7583555
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEV27649D Expired DE567775C (en) | 1931-12-20 | 1931-12-20 | Fast drying paints |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE567775C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE967027C (en) * | 1953-02-21 | 1957-09-26 | Albertuswerke G M B H | Process for improving the drying of drying fatty oils |
| DE1058665B (en) * | 1955-10-11 | 1959-06-04 | Gen Aniline & Film Corp | Drying accelerator for film formers containing drying or semi-drying oils |
-
1931
- 1931-12-20 DE DEV27649D patent/DE567775C/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE967027C (en) * | 1953-02-21 | 1957-09-26 | Albertuswerke G M B H | Process for improving the drying of drying fatty oils |
| DE1058665B (en) * | 1955-10-11 | 1959-06-04 | Gen Aniline & Film Corp | Drying accelerator for film formers containing drying or semi-drying oils |
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