DE4320893C1 - Process for the surface coating of molded wood parts - Google Patents
Process for the surface coating of molded wood partsInfo
- Publication number
- DE4320893C1 DE4320893C1 DE19934320893 DE4320893A DE4320893C1 DE 4320893 C1 DE4320893 C1 DE 4320893C1 DE 19934320893 DE19934320893 DE 19934320893 DE 4320893 A DE4320893 A DE 4320893A DE 4320893 C1 DE4320893 C1 DE 4320893C1
- Authority
- DE
- Germany
- Prior art keywords
- cavity
- wall
- coated
- surface coating
- wood
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011248 coating agent Substances 0.000 title claims description 32
- 238000000576 coating method Methods 0.000 title claims description 32
- 238000000034 method Methods 0.000 title claims description 23
- 239000002023 wood Substances 0.000 title claims description 19
- 239000000463 material Substances 0.000 claims description 24
- 239000007788 liquid Substances 0.000 claims description 17
- 230000005855 radiation Effects 0.000 claims description 7
- 229920003002 synthetic resin Polymers 0.000 claims description 4
- 239000000057 synthetic resin Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000011344 liquid material Substances 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 230000005670 electromagnetic radiation Effects 0.000 claims description 2
- 238000004381 surface treatment Methods 0.000 claims description 2
- 238000000465 moulding Methods 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000011120 plywood Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 210000003734 kidney Anatomy 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/0025—Applying surface layers, e.g. coatings, decorative layers, printed layers, to articles during shaping, e.g. in-mould printing
- B29C37/0028—In-mould coating, e.g. by introducing the coating material into the mould after forming the article
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C9/00—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C9/00—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important
- B05C9/04—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying liquid or other fluent material to opposite sides of the work
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/06—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0888—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using transparant moulds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/22—Component parts, details or accessories; Auxiliary operations
- B29C39/42—Casting under special conditions, e.g. vacuum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0053—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/68—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
- B29C70/70—Completely encapsulating inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/68—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
- B29C70/78—Moulding material on one side only of the preformed part
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
- B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
- B05D3/065—After-treatment
- B05D3/066—After-treatment involving also the use of a gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
- B29C2035/0827—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using UV radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0053—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping
- B29C2045/0075—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping curing or polymerising by irradiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2711/00—Use of natural products or their composites, not provided for in groups B29K2601/00 - B29K2709/00, for preformed parts, e.g. for inserts
- B29K2711/14—Wood, e.g. woodboard or fibreboard
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Toxicology (AREA)
- Physics & Mathematics (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Thermal Sciences (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Description
Die Erfindung betrifft ein Verfahren zur Oberflächenbe schichtung von Holzformteilen.The invention relates to a method for surface coating layering of molded wood parts.
Derartige Holzformteile mit einer Holzoberfläche werden bei spielsweise zur Innenausstattung von Kraftfahrzeugen verwen det. Dabei wird die Oberfläche derartiger Holzformteile, die als massive Teile oder als Sperrholzformteile ausgebildet sein können, die aber auch eine furnierte Oberfläche haben können, mit einem durchsichtigen Lack oder einem anderen durchsichtigen Oberflächenbeschichtungsmaterial versehen, so daß einerseits eine gegebenenfalls glänzende und strapazier fähige Oberfläche entsteht, während andererseits durch diese üblicherweise als transparente Lackierung bezeichnete durch sichtige Oberflächenbeschichtung die Struktur des Holzes nicht nur sichtbar bleibt, sondern sogar noch hervorgehoben wird.Such molded wood parts with a wooden surface are used use for example for the interior of motor vehicles det. The surface of such molded wood parts, the designed as solid parts or as molded plywood can be, but also have a veneered surface can, with a clear varnish or another provided transparent surface coating material, so that on the one hand a possibly shiny and hard-wearing capable surface, while on the other hand through this usually referred to as transparent painting by visible surface coating the structure of the wood not only remains visible, but even emphasized becomes.
Bei herkömmlichen Herstellungsverfahren sind die verwendeten Oberflächenbeschichtungsmaterialien auf die zu beschichtenden Oberflächen aufgespritzt oder auflackiert worden. Damit die Oberflächen einschlußfrei und völlig gleichmäßig ausfallen, ist es dazu notwendig, erhöhte Vorsichtsmaßnahmen zu ergrei fen, teilweise müssen Lackschichten in mehreren Stufen nach einander aufgebracht werden. Derartige Verfahren sind teuer, außerdem läßt sich nicht vermeiden, daß dabei durch Ein schlüsse und andere Störungen Ausschußteile produziert werden.In conventional manufacturing processes, those are used Surface coating materials on those to be coated Surfaces have been sprayed on or painted on. So that Surfaces are free of inclusions and completely uniform, it is necessary to take increased precautionary measures In some cases, layers of paint have to be applied in several stages be applied to each other. Such processes are expensive moreover, it can not be avoided that by A conclusions and other malfunctions committee parts are produced.
Es ist Aufgabe der Erfindung, ein gattungsgemäßes Verfahren so auszuführen, daß die Oberflächenbeschichtung vom Vorgang her vereinfacht wird und daß gleichzeitig die Qualität der Oberflächenbeschichtung verbessert wird.The object of the invention is a generic method so that the surface coating of the process here is simplified and that at the same time the quality of Surface coating is improved.
Diese Aufgabe wird bei einem Verfahren der eingangs beschrie benen Art erfindungsgemäß dadurch gelöst, daß man das an der Oberfläche zu beschichtende Holzformteil in einen Hohlraum einlegt, dessen Innenwand von dem Holzformteil im Bereich der zu beschichtenden Oberfläche einen geringen Abstand aufweist und dadurch zwischen der Innenwand und der zu beschichtenden Oberfläche einen sich über die gesamte zu beschichtende Ober fläche erstreckenden Spaltraum mit im wesentlichen konstanter Dicke ausbildet, daß man den Hohlraum zumindest teilweise evakuiert, daß man während des Evakuierens oder danach ein flüssiges Oberflächenbeschichtungsmaterial in den Hohlraum einfüllt und daß man nach vollständiger Füllung des Spaltrau mes das flüssige Material im Innern des Hohlraumes aushärtet.This task is described in a method of the beginning benen type solved according to the invention in that the Wooden molded part to be coated in a cavity inserts, the inner wall of the wood molding in the area of has a small distance from the surface to be coated and thereby between the inner wall and the one to be coated Surface over the entire surface to be coated area-extending gap space with a substantially constant Thickness forms that the cavity is at least partially evacuated that one during evacuation or after liquid surface coating material in the cavity filled and that after the gap is completely filled with the liquid material hardens inside the cavity.
Im Gegensatz zu herkömmlichen Techniken der Oberflächenbe schichtung, bei denen das Material auf die freie Oberfläche aufgetragen wird, wird hier das Formteil in einem Hohlraum gleichsam eingebettet in das flüssige Beschichtungsmaterial, wobei das Beschichtungsmaterial den Spaltraum zwischen zu be schichtender Oberfläche und Innenwand des Hohlraumes voll ständig ausfüllt, so daß die Geometrie dieses Spaltraumes der Geometrie der aufgebrachten Oberflächenschicht entspricht. Durch das Evakuieren des Hohlraumes wird dafür Sorge getra gen, daß in die Oberflächenschicht keinerlei Gasblasen einge bettet werden, die Evakuierung führt außerdem dazu, daß das eingefüllte flüssige Material sich vollständig gleichmäßig in alle freibleibenden Bereiche des Spaltraumes ergießt und die sen vollständig homogen komplett ausfüllt. Dies wiederum ge währt eine homogene und unterbrechungsfreie Qualität der Oberflächenbeschichtung.In contrast to conventional techniques of surface treatment layering where the material is on the free surface is applied, the molded part is in a cavity as it were embedded in the liquid coating material, the coating material being the gap between layered surface and inner wall of the cavity fully constantly fills, so that the geometry of this gap the Geometry of the applied surface layer corresponds. This is ensured by evacuating the cavity conditions that no gas bubbles are inserted into the surface layer be bedded, the evacuation also leads to the fact that filled liquid material is completely even in all free areas of the gap pour and the completely filled completely homogeneously. This in turn ge maintains a homogeneous and uninterrupted quality of Surface coating.
Diese Füllung kann noch dadurch verbessert werden, daß man das flüssige Oberflächenbeschichtungsmaterial unter erhöhtem Druck in den Hohlraum einfüllt, also praktisch in den Spalt raum einpreßt.This filling can be improved by the fact that the liquid surface coating material under increased Filled pressure into the cavity, so practically in the gap presses in space.
Die Härtung des eingefüllten, flüssigen Oberflächenmaterials kann in verschiedener Weise erfolgen, es sind chemische oder physikalische Härtungsvorgänge möglich, beispielsweise durch Erwärmen. Besonders günstig ist es, wenn man das flüssige Oberflächenmaterial nach dem Füllen des Hohlraumes durch die strahlungsdurchlässig ausgebildeten Wände des Hohlraumes hin durch mit einer die Härtung des flüssigen Oberflächenma terials fördernden Strahlung beaufschlagt, insbesondere, wenn die Strahlung eine elektromagnetische Strahlung im Uv-Bereich ist. Es werden dann Formen mit Hohlraum verwendet, die für diese Strahlung durchlässig sind, beispielsweise Glasformen.The hardening of the filled, liquid surface material can be done in different ways, they are chemical or physical hardening processes possible, for example by Heat. It is particularly cheap if you have the liquid Surface material after filling the cavity through the radiation-permeable walls of the cavity through with a the hardening of the liquid surface measure terials promoting radiation, especially if the radiation is electromagnetic radiation in the uv range is. Then cavity molds are used which are suitable for this radiation is transparent, for example glass molds.
Als flüssiges Oberflächenbeschichtungsmaterial kann man vor zugsweise Kunstharze auf Polyurethan-, Polyester- oder Acryl basis verwenden.As a liquid surface coating material you can preferably synthetic resins on polyurethane, polyester or acrylic use base.
Das Verfahren läßt sich auch dadurch ganz besonders ökono misch durchführen, daß man das beschichtete Holzformteil nach dem Aushärten aus dem Hohlraum entnimmt und ohne ohne weitere Oberflächenbearbeitung läßt. Dies ist insbesondere dann mög lich, wenn die Innenwand des Hohlraumes vollständig glatt ist, man erhält dann eine hochglänzende Oberfläche der Ober flächenbeschichtung.This also makes the process particularly economical perform mix that the coated wood part after removed from the cavity after curing and without further Surface processing leaves. This is particularly possible Lich when the inner wall of the cavity is completely smooth is then you get a high-gloss surface of the upper surface coating.
Andererseits ist es auch möglich, daß man einen Hohlraum mit einer strukturierten Innenwand verwendet, so daß man eine Be schichtung mit einer entsprechenden Oberflächenstruktur er reicht, beispielsweise eine mattierte Oberfläche oder eine geriffelte Oberfläche.On the other hand, it is also possible to have a cavity with a structured inner wall is used, so that one Be layering with a corresponding surface structure enough, for example a matt surface or a corrugated surface.
Bei einer ersten Ausführungsform des beschriebenen Verfahrens kann vorgesehen sein, daß man das Holzformteil so in dem Hohlraum anordnet, daß allseitig zwischen der Oberfläche des Holzformteiles und der Innenwand des Hohlraumes ein Spaltraum ausgebildet wird. Man erhält damit eine allseitige und voll ständig gleichmäßige Beschichtung des eingelegten Holzform teils, sozusagen eine vollständige Ummantelung.In a first embodiment of the method described can be provided that the wooden molded part in the Arranges cavity on all sides between the surface of the Wood molding and the inner wall of the cavity a gap is trained. You get an all-round and full Constantly uniform coating of the inserted wood mold partly, a complete casing, so to speak.
Es ist aber bei einem anderen Ausführungsbeispiel auch mög lich, daß man das Holzformteil bereichsweise flächig unmit telbar an die Innenwand des Hohlraumes anlegt, so daß nur in den übrigen Oberflächenbereichen ein Spaltraum zwischen der zu beschichtenden Oberfläche und der Innenwand des Hohlraumes angeordnet ist. Dadurch läßt sich auch bereichsweise eine Be schichtung erzielen. In vielen Fällen reicht es bei Innenver kleidungsteilen von Kraftfahrzeugen beispielsweise aus, wenn die zum Innenraum zugekehrte Oberfläche entsprechend be schichtet ist, die Rückseite derartiger Holzformteile kann im wesentlichen unbeschichtet bleiben. Selbstverständlich sind auch Zwischenformen denkbar, wobei die Beschichtung auf der nach außen gekehrten Seite dicker ist als die Beschichtung auf der abgewandten Seite. Dies läßt sich durch eine entspre chend unsymmetrische Anordnung des Holzformteiles in dem Hohlraum erreichen.However, it is also possible in another embodiment Lich, that the area of the molded wood part in areas Telbar creates on the inner wall of the cavity, so that only in the remaining surface areas a gap between the surface to be coated and the inner wall of the cavity is arranged. This also allows a Be in some areas achieve stratification. In many cases it is enough for indoor clothing parts of motor vehicles, for example, if the surface facing the interior accordingly is layered, the back of such molded wood parts can in remain essentially uncoated. Of course intermediate forms are also conceivable, the coating on the the side facing outwards is thicker than the coating on the opposite side. This can be done by a corresponding Unsymmetrical arrangement of the molded wood part in the Reach cavity.
Die beschriebene Erfindung erstreckt sich selbstverständlich nicht nur auf das Verfahren, sondern auch auf Formteile, die unter Verwendung dieses Verfahrens hergestellt sind.The described invention extends of course not only on the process, but also on molded parts that are made using this method.
Die nachfolgende Beschreibung bevorzugter Ausführungsformen der Erfindung dient im Zusammenhang mit der Zeichnung der nä heren Erläuterung. Es zeigen:The following description of preferred embodiments the invention serves in connection with the drawing of the nä here explanation. Show it:
Fig. 1 eine Schnittansicht durch eine Form mit einem Hohlraum und einem eingelegten Formteil mit einem das Formteil allseitig umgebenden Spalt raum; Figure 1 is a sectional view through a mold with a cavity and an inserted molded part with a gap surrounding the molded part on all sides.
Fig. 2 eine Schnittansicht längs Linie 2-2 in Fig. 1 und Fig. 2 is a sectional view taken along line 2-2 in Fig. 1 and
Fig. 3 eine Ansicht ähnlich Fig. 1 mit einem einsei tig flächig an der Innenwand des Hohlraumes anliegenden Formteil. Fig. 3 is a view similar to FIG. 1 with a one-sided surface fitting on the inner wall of the cavity.
In der Zeichnung ist eine Form 1 gezeigt, die einen allseits geschlossenen Hohlraum 2 umgibt. In diesen Hohlraum 2 ist ein Formteil 3 eingelegt, beispielsweise ein Formteil aus Massiv holz oder aus Sperrholz oder ein Holzpreßteil mit einer fur nierten Oberfläche. Die Form des Hohlraumes 2 ist so gewählt, daß sie an die Form des Formteiles 3 angepaßt ist. Bei dem in Fig. 1 dargestellten Ausführungsbeispiel umgibt die Innen wand 4 des Hohlraumes 2 die Oberfläche 5 des Formteiles 3 allseits in einem gleich großen, insgesamt geringen Abstand, so daß zwischen der Oberfläche 5 einerseits und der Innenwand 4 andererseits ein das Formteil 3 allseits umgebender Spalt raum 6 ausgebildet wird. Die Dicke des Spaltraumes kann bei spielsweise zwischen 0,1 mm und 1,5 mm liegen, je nach der gewünschten Dicke der Oberflächenbeschichtung.In the drawing, a shape 1 is shown, which surrounds a cavity 2 which is closed on all sides. In this cavity 2 , a molded part 3 is inserted, for example a molded part made of solid wood or plywood or a pressed wood part with a surface for kidney. The shape of the cavity 2 is chosen so that it is adapted to the shape of the molded part 3 . In the embodiment shown in Fig. 1, the inner wall 4 of the cavity 2 surrounds the surface 5 of the molded part 3 on all sides at an equally large, overall small distance, so that between the surface 5 on the one hand and the inner wall 4 on the other hand, the molded part 3 on all sides Gap space 6 is formed. The thickness of the gap can be between 0.1 mm and 1.5 mm, for example, depending on the desired thickness of the surface coating.
Zur Halterung des Formteiles 3 in dieser symmetrischen Posi tion, bei der die Oberfläche 5 allseits von der Innenwand 4 entfernt ist, sind in der Form 1 Haltestifte 7 angeordnet (Fig. 2). Diese erzeugen nur ganz geringfügige Unter brechungen in der Beschichtung, die ohne weiteres akzeptabel sind, insbesondere wenn sie an den Rändern des Formteiles an geordnet sind, deren Oberflächen nicht nach außen hin in Er scheinung treten.To hold the molded part 3 in this symmetrical position, in which the surface 5 is removed on all sides from the inner wall 4 , 1 holding pins 7 are arranged in the mold ( FIG. 2). These produce only very slight interruptions in the coating, which are readily acceptable, especially if they are arranged on the edges of the molded part, the surfaces of which do not appear on the outside.
Die in den Fig. 1 und 2 dargestellte Form ist zweiteilig gestaltet, so daß durch Trennen der beiden Teile der Hohlraum 2 zum Einlegen und Entnehmen des Formteiles 3 zugänglich ist. Diese Zweiteiligkeit ist in der Zeichnung nur sehr schema tisch dargestellt, beispielsweise können die Trennlinien auch parallel zur Mittelebene des Formteiles 3 verlaufen.The shape shown in FIGS. 1 and 2 is designed in two parts, so that the cavity 2 is accessible for inserting and removing the molded part 3 by separating the two parts. This two-part is shown in the drawing only very schematically, for example, the dividing lines can also run parallel to the central plane of the molded part 3 .
Der Hohlraum 2 steht über einen Sauganschluß 8 mit einer in der Zeichnung nicht dargestellten Saugquelle in Verbindung, beispielsweise mit einer Pumpe. Der Sauganschluß 8 ist vor zugsweise am unteren Ende des Hohlraumes 2 angeordnet.The cavity 2 is connected via a suction connection 8 to a suction source, not shown in the drawing, for example to a pump. The suction port 8 is preferably arranged at the lower end of the cavity 2 .
Am oberen Ende mündet in den Hohlraum 2 ein Füllanschluß 9 ein, der mit einem Vorratsbehälter in Verbindung steht, in dem das verwendete Oberflächenbeschichtungsmaterial in flüssiger Form aufbewahrt wird. Es kann sich dabei beispiels weise um Kunstharze auf Polyurethanbasis, auf Polyesterbasis oder auf Acrylbasis handeln, die vorzugsweise durchsichtig sind.At the upper end, a filling connection 9 opens into the cavity 2 and is connected to a storage container in which the surface coating material used is kept in liquid form. It can be, for example, synthetic resins based on polyurethane, polyester-based or acrylic-based, which are preferably transparent.
Zur Beschichtung eines Formteiles 3 wird dies in den Hohlraum 2 eingelegt, der nach dem Verschließen der Form 1 über den Sauganschluß 8 evakuiert wird. Dabei wird der Druck im Hohl raum 2 abgesenkt.To coat a molded part 3 , this is inserted into the cavity 2 , which is evacuated via the suction connection 8 after the mold 1 has been closed. The pressure in the cavity 2 is lowered.
Bereits während dieses Absaugens oder unmittelbar danach wird über den Füllanschluß 9 flüssiges Oberflächenbeschichtungs material in den Hohlraum 2 eingefüllt, vorzugsweise unter er höhtem Druck, beispielsweise mit Hilfe einer Förderpumpe. Dieses flüssige Oberflächenmaterial füllt den Spaltraum 6 vollständig und homogen aus.Already during this suction or immediately thereafter, liquid surface coating material is filled into the cavity 2 via the filling connection 9 , preferably under elevated pressure, for example with the aid of a feed pump. This liquid surface material fills the gap space 6 completely and homogeneously.
Sobald der Spaltraum 6 vollständig gefüllt ist, härtet man das flüssige Oberflächenbeschichtungsmaterial aus, beispiels weise durch Erwärmen der Form oder durch Bestrahlen, vorzugs weise mit UV-Strahlung. Zu diesem Zweck werden Formen verwen det, deren Material für die verwendete Strahlung durchlässig ist, beispielsweise Formen aus Glas, Silikon oder einem transparenten Kunststoff. Wenn andere Aushärtungsmethoden verwendet werden, können die Formen beispielsweise auch aus Stahl, aus Aluminium oder aus nicht transparenten Kunstharzen bestehen.As soon as the gap 6 is completely filled, the liquid surface coating material is cured, for example by heating the mold or by irradiation, preferably with UV radiation. For this purpose, molds are used whose material is transparent to the radiation used, for example molds made of glass, silicone or a transparent plastic. If other curing methods are used, the molds can also be made of steel, aluminum or non-transparent synthetic resins, for example.
Nach dem Aushärten des Oberflächenbeschichtungsmaterials wird die Form geöffnet, das oberflächenbeschichtete Formteil 3 kann dann aus dem Hohlraum entnommen werden. In vielen Fällen zeigt es sich, daß eine Nachbearbeitung der Oberfläche nicht mehr notwendig ist, bei entsprechender Beschaffenheit der In nenwand 4 kann die Oberfläche des beschichteten Formteils un mittelbar für das Endprodukt verwendet werden.After the surface coating material has hardened, the mold is opened, and the surface-coated molded part 3 can then be removed from the cavity. In many cases it turns out that a reworking of the surface is no longer necessary, with the appropriate properties of the inner wall 4 , the surface of the coated molding can be used directly for the end product.
Die Innenwand 4 kann dabei vollständig glatt ausgebildet sein, so daß man eine hochglänzende Oberfläche erhält, es sind aber auch Strukturierungen möglich, so daß beispiels weise eine matte Oberfläche oder eine geriffelte Oberfläche entsteht.The inner wall 4 can be completely smooth, so that a high-gloss surface is obtained, but structuring is also possible, so that, for example, a matt surface or a corrugated surface is formed.
Bei dem in Fig. 1 dargestellten Ausführungsbeispiel umgibt der Spaltraum 6 das Formteil 3 allseits, so daß eine allsei tige Oberflächenbeschichtung erfolgt.In the embodiment shown in Fig. 1, the gap 6 surrounds the molded part 3 on all sides, so that an all-sided surface coating takes place.
Im Gegensatz dazu ist das Formteil bei dem Ausführungsbeispiel der Fig. 3 so in den Hohlraum 2 eingelegt, daß es einseitig flächig an der Innenwand 4 anliegt und nur auf der gegenüber liegenden Seite ein Spaltraum 6 ausgebildet ist. Sonst ist der Aufbau gleich. Beim Befüllen des Hohlraumes 2 mit dem flüssigen Oberflächenbeschichtungsmaterial gelangt dieses da durch nur auf einer Seite des Formteiles auf dessen Oberflä che, man erhält also eine einseitige Oberflächenbeschichtung. Sonst verläuft der Vorgang genau gleich.In contrast, the molded part in the embodiment of FIG. 3 is inserted into the cavity 2 in such a way that it lies flat against the inner wall 4 on one side and a gap space 6 is formed only on the opposite side. Otherwise the structure is the same. When filling the cavity 2 with the liquid surface coating material, this passes through only on one side of the molded part on its surface, thus giving a one-sided surface coating. Otherwise the process is exactly the same.
Es hat sich überraschenderweise herausgestellt, daß bei dem beschriebenen Verfahren gegenüber herkömmlichen Verfahren der Auftragung Materialeinsparungen am Beschichtungsmaterial von über 50% erreicht werden können. Außerdem ist es möglich, umweltbelastende Lösemittel zu vermeiden, so daß dieses Verfahren die großen Probleme der Lösemittel-Nachverbrennung und -Beseitigung auf einfachste Weise löst.It has surprisingly been found that the described methods compared to conventional methods of Application of material savings on the coating material from over 50% can be achieved. It is also possible to avoid polluting solvents, so this Process the big problems of solvent post-combustion and removal in the simplest way.
Claims (9)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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DE19934320893 DE4320893C2 (en) | 1993-06-24 | 1993-06-24 | Process for the surface coating of molded wood parts |
PCT/EP1994/001521 WO1995000308A1 (en) | 1993-06-24 | 1994-05-11 | Process for the surface coating of timber shaped parts |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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DE19934320893 DE4320893C2 (en) | 1993-06-24 | 1993-06-24 | Process for the surface coating of molded wood parts |
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DE4320893C1 true DE4320893C1 (en) | 1994-07-28 |
DE4320893C2 DE4320893C2 (en) | 1998-08-20 |
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DE19934320893 Expired - Lifetime DE4320893C2 (en) | 1993-06-24 | 1993-06-24 | Process for the surface coating of molded wood parts |
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WO (1) | WO1995000308A1 (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999055511A1 (en) * | 1998-04-29 | 1999-11-04 | Erwin Behr Gmbh & Co. Kg | Method for surface-coating an interior fitting and interior fitting produced according to this method |
EP0978369A1 (en) | 1998-08-05 | 2000-02-09 | Behr Automotive GmbH | Method and apparatus for coating an interior fitting for cars and interior fitting obtained thereby |
WO2001045860A3 (en) * | 1999-12-22 | 2002-05-23 | Behr Automotive Gmbh | Method and device for coating the surface of an interior component for motor vehicles |
WO2002064402A2 (en) | 2001-02-15 | 2002-08-22 | Erwin Behr Automotive Gmbh | Interior fitting for motor vehicles and method for producing one such interior fitting |
DE19961990B4 (en) * | 1999-12-22 | 2005-05-25 | Erwin Behr Automotive Gmbh | Method and device for coating an interior fitting for motor vehicles |
WO2010064733A1 (en) * | 2008-12-05 | 2010-06-10 | Erwin Behr Tec Co., Ltd. | Resin product coating method, apparatus and resin products |
DE102011001905A1 (en) | 2011-03-30 | 2012-10-04 | Firma Votteler Lackfabrik GmbH & Co. KG | Method and device for surface coating of three-dimensionally deformed components |
EP2583806A1 (en) * | 2011-10-17 | 2013-04-24 | Ludwig Schleicher | Method and device for producing laminar plastic components |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19808026C2 (en) * | 1998-02-26 | 2001-11-29 | Edscha Cabrio Dachsys Gmbh | Process for producing molded plastic parts, in particular car roofs, and device for carrying out this process |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4124297A1 (en) * | 1991-07-22 | 1993-01-28 | Pelz Ernst Empe Werke | Prodn. of impervious liner - by e.g. backing substrate with e.g. aluminium, placing combination in suitable mould, injecting e.g. acrylic polymer to cover face and edges |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1119503B (en) * | 1956-08-22 | 1961-12-14 | Johann Dombrovskis | Process for the production of objects encased in cast plastic |
CH557232A (en) * | 1972-09-05 | 1974-12-31 | Stella Werke Ag | INJECTION MOLDING PROCESS. |
AU8500482A (en) * | 1981-07-06 | 1983-01-13 | S.A. Block (sand Sales) (pty.) Ltd. | Injection moulding coating |
CH664924A5 (en) * | 1984-12-04 | 1988-04-15 | Stella Werke Ag | METHOD FOR PRODUCING DUROPLASTIC SHEET PANELS AND DEVICE FOR IMPLEMENTING THE METHOD. |
JPS6319780A (en) * | 1986-07-10 | 1988-01-27 | 矢崎総業株式会社 | Formation of covered layer at connection of wire |
-
1993
- 1993-06-24 DE DE19934320893 patent/DE4320893C2/en not_active Expired - Lifetime
-
1994
- 1994-05-11 WO PCT/EP1994/001521 patent/WO1995000308A1/en active Application Filing
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4124297A1 (en) * | 1991-07-22 | 1993-01-28 | Pelz Ernst Empe Werke | Prodn. of impervious liner - by e.g. backing substrate with e.g. aluminium, placing combination in suitable mould, injecting e.g. acrylic polymer to cover face and edges |
Non-Patent Citations (2)
Title |
---|
Handbuch der Plasttechnik, VEB Deutscher Verlag für Grundstoffindustrie, Leipzig, 1985, S. 343, 346-348 * |
ULLMANN: Ercyklopädie der technischen Chemie, 4. Aufl., Bd. 15, 1978, S. 316 * |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999055511A1 (en) * | 1998-04-29 | 1999-11-04 | Erwin Behr Gmbh & Co. Kg | Method for surface-coating an interior fitting and interior fitting produced according to this method |
DE19819133A1 (en) * | 1998-04-29 | 1999-11-11 | Behr Gmbh & Co Kg Erwin | Process for the surface coating of an interior fitting and interior fitting manufactured according to it |
EP0978369A1 (en) | 1998-08-05 | 2000-02-09 | Behr Automotive GmbH | Method and apparatus for coating an interior fitting for cars and interior fitting obtained thereby |
WO2001045860A3 (en) * | 1999-12-22 | 2002-05-23 | Behr Automotive Gmbh | Method and device for coating the surface of an interior component for motor vehicles |
DE19961990B4 (en) * | 1999-12-22 | 2005-05-25 | Erwin Behr Automotive Gmbh | Method and device for coating an interior fitting for motor vehicles |
US7214340B2 (en) | 1999-12-22 | 2007-05-08 | Erwin Behr Automotive Gmbh | Method and device for coating the surface of an interior component for motor vehicles |
US7384253B2 (en) | 1999-12-22 | 2008-06-10 | Erwin Behr Automotive Gmbh | Method and device for coating the surface of an interior component for motor vehicles |
WO2002064402A2 (en) | 2001-02-15 | 2002-08-22 | Erwin Behr Automotive Gmbh | Interior fitting for motor vehicles and method for producing one such interior fitting |
WO2010064733A1 (en) * | 2008-12-05 | 2010-06-10 | Erwin Behr Tec Co., Ltd. | Resin product coating method, apparatus and resin products |
DE102011001905A1 (en) | 2011-03-30 | 2012-10-04 | Firma Votteler Lackfabrik GmbH & Co. KG | Method and device for surface coating of three-dimensionally deformed components |
WO2012130717A1 (en) | 2011-03-30 | 2012-10-04 | Votteler Lackfabrik Gmbh & Co. Kg | Method and device for coating the surface of three-dimensionally shaped components |
EP2583806A1 (en) * | 2011-10-17 | 2013-04-24 | Ludwig Schleicher | Method and device for producing laminar plastic components |
Also Published As
Publication number | Publication date |
---|---|
DE4320893C2 (en) | 1998-08-20 |
WO1995000308A1 (en) | 1995-01-05 |
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