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EP1976697B1 - Method for producing a cladding element - Google Patents

Method for producing a cladding element Download PDF

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Publication number
EP1976697B1
EP1976697B1 EP07702836A EP07702836A EP1976697B1 EP 1976697 B1 EP1976697 B1 EP 1976697B1 EP 07702836 A EP07702836 A EP 07702836A EP 07702836 A EP07702836 A EP 07702836A EP 1976697 B1 EP1976697 B1 EP 1976697B1
Authority
EP
European Patent Office
Prior art keywords
resin
paper layer
base board
paper
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP07702836A
Other languages
German (de)
French (fr)
Other versions
EP1976697A1 (en
Inventor
Herbert Ruhdorfer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Interglarion Ltd
Original Assignee
Interglarion Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Interglarion Ltd filed Critical Interglarion Ltd
Priority to SI200730736T priority Critical patent/SI1976697T1/en
Priority to PL07702836T priority patent/PL1976697T3/en
Publication of EP1976697A1 publication Critical patent/EP1976697A1/en
Application granted granted Critical
Publication of EP1976697B1 publication Critical patent/EP1976697B1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • B44C5/04Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0469Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper
    • B44C5/0492Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper containing wooden elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0008Electrical discharge treatment, e.g. corona, plasma treatment; wave energy or particle radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0012Mechanical treatment, e.g. roughening, deforming, stretching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/08Impregnating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • B44C5/04Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0469Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor

Definitions

  • the invention relates to a method for producing a cladding element, for example a floor panel, a wall cladding element, a furniture front panel or the like, wherein the cladding element comprises a base plate having on a surface, namely its visible surface or their contact surface opposite the viewing surface, with a resin-impregnated paper layer is provided.
  • the cladding element 10 comprises a base plate 12, which is preferably formed from a wood material, for example a chipboard or a fiberboard, such as an MDF (Medium Density Fiberboard) or HDF (High Density Fiberboard) board. If the trim element is used as a floor panel, it preferably has a thickness of about 5 mm to about 15 mm.
  • the base plate 12 On its visible surface 12 a, the base plate 12 is provided with a decorative paper layer 14 which comprises at least one decorative paper layer 16.
  • the decorative paper layer 14 or its uppermost decorative paper layer 16 is printed with a desired decor, for example a wood, stone, tile or similar materials or products imitating decor.
  • the paper used for the decorative paper layer 14 usually has a total grammage of about 45 g / m 2 to about 160 g / m 2 .
  • Such decorative papers are impregnated or impregnated with impregnating resin on special impregnating machines, which is described in US Pat Fig. 3 dotted is indicated.
  • the amount of impregnating resin applied, based on the raw paper weight of the decorative paper layer 14, is about 100% to about 140%.
  • the lining element 10 In order to be able to prevent deformation of the lining element 10 due to the tensions arising from the decorative paper layer 14, for example to a curvature which destroys its desired completely planar and planar shape, it can optionally be disposed opposite to that of the visible surface 12a of the base plate 12 Rear surface 12b of the base plate 12 aelles Krebspapierlage 18 may be arranged.
  • the Jacobzugpapierlage 18 is impregnated with impregnating resin, as in Fig. 3 indicated by the punctuation.
  • the countertransfer paper layer 18 With respect to the base paper weight, ie, the grammage of the paper used and the amount of impregnating resin applied, the countertransfer paper layer 18 substantially corresponds to the decor paper layer 14 to ensure that both paper layers 14 and 18 exert substantially canceling stresses on the base plate 12.
  • cover papers or overlay papers preferably have a raw paper weight of about 10 g / m 2 to about 80 g / m 2 and are thus, especially when impregnated with impregnating resin, transparent, so as not to look at the decor of the decorative paper layer 14 to hinder. Based on the raw paper weight, the amount of impregnating resin is between about 100% and about 300%.
  • the impregnating resin for the cover paper layer 20 may further be admixed with a suitable additive, for example corundum, preferably in an amount of about 5 g / m 2 to about 50 g / m 2 .
  • aminoplast resins for example urea resins or melamine resins or mixtures of urea and melamine resins, melamine resin preferably being used to impregnate the cover paper layer 20.
  • a decor paper 14 printed with a desired decor is provided.
  • This is impregnated in a step DI in a special impregnating machine with impregnating resin.
  • the impregnating resin can be applied in one or more stages on the decorative paper 14, penetrate into this and then dried.
  • the decorative paper 14 thus impregnated is then formatted in a further step DF, ie cut to a size matched to the size of the supplied base plates 12.
  • the decor paper 14 is now for further processing, especially the hot pressing with the base plate 12, finished and is fed in a step DL an intermediate storage 22, where it remains until further processing.
  • a base plate 12 is now conveyed in a step B, an impregnated and formatted decor paper 14, withdrawal paper 18 and cover paper 20 are removed from the associated intermediate storage 22, 24 and 26 in steps DS, RS and OS and in the above with reference to Fig. 3 described sequence stacked on each other.
  • this stack is fed to a hot press 28, in which the paper layers 14, 18 and 20 are pressed with the base plate 12 to form the desired end product, namely the lining element 10, using an elevated pressure and temperature.
  • thermoforming the hot press 28 in Fig. 2 roughly schematically in the form of two press plates, ie in the form of a stationary press, is indicated, it is understood that equally well as continuous or quasi-continuous presses, for example, continuous presses can be used.
  • the known method has the disadvantage that the papers impregnated with impregnating resin have only a limited shelf life. Namely, the impregnating resin must not already be thoroughly dried before hot pressing, but may only be so dry that the individual paper layers in the intermediate storage, for example, the Interim storage 22 for decorative paper 14, do not adhere to each other. In the interim storage the papers, in particular the impregnating resin with which they are impregnated, dry on, however, so that they reach a degree of drying when the storage time is too long, which does not permit proper hot pressing. Impregnated papers stored for too long must therefore be sorted out and disposed of, which is disadvantageous not least because of the high material costs for the aminoplast resins commonly used for impregnation.
  • WO 97/17214 A discloses a method for producing a cladding element with a base plate, on the visible surface of which a decorative layer is arranged, and the rear side of which carries a counteracting layer.
  • a resin molded body reinforced by a chipboard is manufactured together with decorative sheets.
  • the decorative layers are placed in the mold, after which the mold is filled with liquid resin and the cladding element is finally produced as a resin molding in the mold.
  • EP 0 745 478 A2 describes the coating of an endless web material, namely a Linoleumbahn, wherein on a coated with liquid paint Linoleumbahn a paper layer is rolled on.
  • the paper layer is thus not already impregnated with resin before the intermediate storage, but it is with the on the base plate applied resin brought into contact only during pressing of paper layer and base plate and thereby impregnated by the resin.
  • the actual impregnation of the paper layer thus takes place only during pressing.
  • the paper can therefore be stored as raw paper so that it is no longer subject to any time restrictions with regard to the intermediate storage time.
  • raw paper is also understood to mean paper already printed with a décor. Since the resin is applied to the base plate according to the invention, it is also ensured that resin is always consumed only when a base plate is actually available for further processing.
  • the resin can be applied to the visible surface and / or the contact surface, for example, with a basis weight of between about 50 g / m 2 and about 200 g / m 2 .
  • the order can be done for example by means of a known roller applicator.
  • a curing agent required for hardening hardener can be applied in a further development of the invention in the first step together with the resin on the surface of the base plate, preferably as a resin-hardener mixture.
  • the hardener and the resin are applied in two separate steps on the surface of the base plate.
  • the hardener is preferably applied to the surface of the base plate separately from the resin in a fourth step preceding the first step.
  • an ammonium chloride solution or an ammonium sulfate solution or a maleic anhydride solution can be used.
  • the paper layer can also be formatted in a fifth step preceding the second step, the difference to the prior art method being merely that the paper layer is in the base paper layer is formatted.
  • a decorative paper layer can be applied to the visible surface of the base plate by the method according to the invention.
  • the base plate is provided both on its visible surface and on its contact surface each with a paper layer, namely a decorative paper layer on the visible surface and a Gegenzugpapierlage on the contact surface.
  • the amount of resin applied to the visible surface of the base plate in the first step may preferably be such that it is sufficient for impregnating both the decorative paper layer and the cover paper layer during the pressing of the paper layers with the base plate in the third method step.
  • the base plate when the base plate is provided on its visible surface with both a decorative paper layer and a cover paper layer, the second steps of applying the two paper layers to the resinous visible surface of the base plate and / or the third steps of pressing the two Make paper layers with the base plate substantially simultaneously.
  • the resin may be an aminoplast resin, preferably a urea resin or a melamine resin or a urea resin-melamine resin mixture. Furthermore, the resin, in particular the for Impregnating the visible surface provided paper layers used resin, at least one abrasion resistance increasing substance, such as corundum, included.
  • each of the paper layers i. the decorative paper layer and / or the Gegenzugpapierlage and / or the cover paper layer may be formed by a plurality of paper layers.
  • the cladding element produced in this way can be supplied to a surface finish.
  • the surface of the decorative paper layer or optionally the surface of the cover paper layer is first subjected to a surface treatment.
  • This surface treatment may comprise a chemical treatment, for example the application of an adhesion promoter and / or a fluorination, and / or a mechanical treatment, for example surface grinding, and / or electrical treatment, for example corona treatment and / or plasma treatment.
  • a lacquer layer can then be applied and dried. If desired, this paint application can also be repeated several times, if necessary, with renewed previous surface treatment of the last applied paint layer.
  • Suitable adhesion promoters include, for example, the product sold by Henelit, Villach, Austria "Hydrohaftgrund E643" or organofunctional silane.
  • Organofunctional silanes are hybrid compounds having a reactive organic group and an inorganic alkyl silicate, in which both the organic functional group and the inorganic hydrolyzable alkoxy group can be tailored to the impregnating resin or aminoplast resin used and the lacquer used in order to achieve good adhesion-promoting properties.
  • the resin-impregnated decorative paper layer pressed with the base plate can be treated in a vacuum reactor.
  • evacuation and inerting the reactor ie removing any impurities still adhered or bound to reactor surfaces, for example by inert gas flushing, heating the reactor or the like, fluorine and inert gas are selectively added using a variable concentration profile of the fluorine mixture at ambient temperature during the treatment time can for best results.
  • the reactor is evacuated, rinsed and the decorative paper layer can be removed.
  • This so-called offline fluorination can be integrated as a post-treatment method in every production process. Due to the fluorination, the surface tension and thus the wetting of the surface is improved by a paint. In addition, a polar surface is achieved, which leads to better adhesion of a paint layer.
  • corona treatment air that is in the space between two electrodes is ionized. These ions then penetrate depending on their kinetic energy in the surface of the arranged between the electrodes to be treated decorative paper layer, for example, up to 10 microns deep. The resulting physical and chemical changes on the surface of the treated decorative paper layer can not yet be clearly explained. It is assumed, however, that oxidation processes at the surface play a role as well as physical and chemical changes of the surface caused by the bombardment with accelerated ions and electrons. However, it is a scientifically proven fact that corona treatment causes improved surface adhesion such that, as desired, a coated lacquer layer will adhere better to a decorative paper sheet so treated.
  • any desired surface reflection property can be achieved in a simple manner from matt gloss to high gloss.
  • highly polished surface is a panel element whose decorative paper layer is printed with a wood decor, practically indistinguishable from real wood.
  • a method according to the invention for producing a cladding element 10 will be explained in more detail, which has already been described in the introduction with reference to FIG Fig. 3 has explained structure, that is provided in particular on its visible surface 12a both with a decorative paper layer 14 and with a cover paper layer 20, and at its contact surface 12b with a Gegenzugpapierlage 18.
  • the decorative paper layer 14 is provided in a step D as raw paper and formatted in a step DF in a size matching the dimensions of the base plate 12 size.
  • a step DL The formatted decorative paper ply 14 is then fed to a buffer store 22, in which it is temporarily stored until further processing.
  • step D corresponding steps R and O provided as base paper Jacobpapierlagen 18 or cover paper layers 20 in the step DF corresponding steps RF or OF formatted in the step DL corresponding steps RL or OL a buffer 24 and 26 supplied.
  • the papers intermediately stored in the intermediate buffers 22, 24 and 26 are therefore not impregnated with resin. This eliminates the problem occurring in the known method that must be taken into account by the drying time of the resin, maximum intermediate storage times, completely.
  • a base plate 12 provided in a step B is provided in a step BID on its visible surface 12a with a layer of impregnating resin, more precisely with a layer of a impregnating resin-hardener mixture.
  • the base plate 12 may also be rear-side, i. be provided on its contact surface 12b, in a step BIR with a corresponding layer.
  • steps BID and BIR can each also be divided into two temporally spaced steps BHD and BAD or BHR and BAR, which in Fig. 1 indicated by dashed arrows.
  • steps BHD and BHR a hardener required for curing the impregnating resin is first applied to the visible surface 12a or the rear surface 12b of the base plate 12, and then the actual application of the impregnating resin takes place in the steps BAD and BAR.
  • the latter method variant is advantageous in view of the problem of the pot life of an impregnating resin-hardener mixture.
  • the steps BID and BIR or the steps BHD and BHR and the steps BAD and BAR may preferably be made substantially simultaneously.
  • the base plate 12 thus coated with resin on its two surfaces 12a, 12b is fed to a stacking process in step BS, in which a decorative paper layer 14 supplied in step DS to the visible surface 12a of the base plate 12 and optionally a cover paper layer 20 fed in a step OS is placed as well as optionally optionally on the contact surface 12b of the base plate 12, a fed in a feed step RS despreukpapierlage 18 is placed.
  • the stack thus formed is fed in a step HP a hot press 28, in which the various paper layers are pressed under increased pressure and elevated temperature with the base plate 12.
  • the resin applied to the base plate 12 penetrates into the various paper layers and impregnates or impregnates them. This gives a cladding element 10 with the in Fig. 3 layer structure shown.
  • the cladding element 10 produced in this way can then be subjected to a surface refinement.
  • the surface 14a of the decorative paper layer or optionally the surface 20a of the cover paper layer 20 is first subjected to a surface treatment.
  • This surface treatment may comprise a chemical treatment, for example the application of an adhesion promoter and / or a fluorination, and / or a mechanical treatment, for example surface grinding, and / or electrical treatment, for example corona treatment and / or plasma treatment.
  • On the surface prepared in this way can then be applied and dried a lacquer layer 30, the in Fig. 3 only indicated by dashed lines. If desired, this paint application can also be repeated several times, if necessary with prior surface treatment of the last applied paint layer.
  • the surface treatment initially comprises the application of an adhesion promoter, for example of the product sold by the company Henelit, Villach, Austria "Hydrohaftgrund E643", in an amount of between about 5 g / m 2 and about 30 g / m 2 .
  • This bonding agent is then cured by means of UV radiation.
  • the surface can then be sanded, if desired, even.
  • the paint can be applied as a roller paint or spray paint.
  • a polyurethane varnish or a UV varnish can be used as the varnish, for example the "UV Hydro Brilliant" varnish marketed by the company Henelit, Villach, Austria.
  • the paint application can be carried out in an amount of between about 15 g / m 2 and about 30 g / m 2 for the paint base layer and between about 5 g / m 2 and about 10 g / m 2 for other paint layers.
  • the paint may be admixed with a suitable additive, for example corundum, preferably in an amount of about 5 g / m 2 to about 50 g / m 2 . If the abrasion resistance of the lacquer layer applied in this way is sufficient, the use of a cover paper can be dispensed with. Since the lacquer layer does not lead to any additional stress in the layer structure applied to the visible surface 12a of the base plate 12, no special precautions need to be taken on the rear surface 12b of the base plate 12 in the countertraction paper layer 18.
  • a suitable additive for example corundum

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Plasma & Fusion (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • Laminated Bodies (AREA)
  • Finishing Walls (AREA)
  • Glass Compositions (AREA)
  • Floor Finish (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Piezo-Electric Or Mechanical Vibrators, Or Delay Or Filter Circuits (AREA)
  • Inorganic Insulating Materials (AREA)

Abstract

Method for producing a cladding element. The method includes applying a resin to a visible surface and to a contact surface of a wood material base board, applying at least one non-resin impregnated paper ply to the visible surface and at least one non-resin impregnated paper ply to the contact surface of the wood material base board, and pressing the at least one non-resin impregnated paper ply onto the resin applied visible surface and the at least one non-resin impregnated paper ply onto the resin applied contact surface. In this manner, the at least one paper ply on the visible surface and at least one paper ply on the contact surface are fully impregnated.

Description

Die Erfindung betrifft ein Verfahren zur Herstellung eines Verkleidungselements, beispielsweise eines Fußbodenpaneels, eines Wandverkleidungselements, eines Möbelsichtfrontelements oder dergleichen, wobei das Verkleidungselement eine Grundplatte umfasst, welche an einer Oberfläche, nämlich ihrer Sichtfläche oder ihrer der Sichtfläche entgegengesetzten Anlagefläche, mit einer mit Harz getränkten Papierlage versehen ist.The invention relates to a method for producing a cladding element, for example a floor panel, a wall cladding element, a furniture front panel or the like, wherein the cladding element comprises a base plate having on a surface, namely its visible surface or their contact surface opposite the viewing surface, with a resin-impregnated paper layer is provided.

Derartige Verfahren sind im Stand der Technik allgemein bekannt. Ein solches Verfahren soll nachfolgend mit Bezug auf Fig. 2 näher erläutert werden. Bereits an dieser Stelle sei aber schon vorausgeschickt, dass sich das nachfolgend beschriebene Verfahren des Standes der Technik hinsichtlich der verwendeten Materialien nicht von dem erfindungsgemäßen Verfahren unterscheidet. Sämtliche mit Bezug auf das bekannte Verfahren gemachten Materialangaben sowie Angaben zu sonstigen Parametern wie Schichtdicken, Grammaturen und dergleichen gelten daher auch für das erfindungsgemäße Verfahren in gleicher Weise fort.Such methods are well known in the art. Such a method is to be described below with reference to Fig. 2 be explained in more detail. However, it should already be stated at this point that the method of the prior art described below with respect to the materials used does not differ from the method according to the invention. All statements of material made with reference to the known method as well as information on other parameters such as layer thicknesses, grammages and the like therefore also apply equally to the method according to the invention.

Sowohl das bekannte Verfahren, dessen Verfahrensschritte in Fig. 2 schematisch dargestellt sind, als auch das später zu diskutierende erfindungsgemäße Verfahren haben die Herstellung eines Verkleidungselements 10 zum Ziel, wie es in Fig. 3 dargestellt ist:Both the known method, the method steps in Fig. 2 are shown schematically, as well as the inventive method to be discussed later, the production of a cladding element 10 to the goal, as shown in Fig. 3 is shown:

Das Verkleidungselement 10 umfasst eine Grundplatte 12, die vorzugsweise aus einem Holzwerkstoff gebildet ist, beispielsweise einer Spanplatte oder einer Faserplatte, etwa einer MDF-Platte (Medium Density Fiberboard) oder einer HDF-Platte (High Density Fiberboard). Falls das Verkleidungselement als Fußbodenpaneel eingesetzt wird, hat es vorzugsweise eine Dicke von etwa 5 mm bis etwa 15 mm.The cladding element 10 comprises a base plate 12, which is preferably formed from a wood material, for example a chipboard or a fiberboard, such as an MDF (Medium Density Fiberboard) or HDF (High Density Fiberboard) board. If the trim element is used as a floor panel, it preferably has a thickness of about 5 mm to about 15 mm.

An ihrer Sichtfläche 12a ist die Grundplatte 12 mit einer Dekorpapierlage 14 versehen, welche wenigstens eine Dekorpapierschicht 16 umfasst. An ihrer Sichtfläche 14a ist die Dekorpapierlage 14 bzw. deren oberste Dekorpapierschicht 16 mit einem gewünschten Dekor bedruckt, beispielsweise einem Holz, Stein, Fliesen oder dergleichen Materialien bzw. Produkte imitierenden Dekor. Das für die Dekorpapierlage 14 verwendete Papier weist üblicherweise eine Grammatur von insgesamt etwa 45 g/m2 bis etwa 160 g/m2 auf.On its visible surface 12 a, the base plate 12 is provided with a decorative paper layer 14 which comprises at least one decorative paper layer 16. On its visible surface 14a, the decorative paper layer 14 or its uppermost decorative paper layer 16 is printed with a desired decor, for example a wood, stone, tile or similar materials or products imitating decor. The paper used for the decorative paper layer 14 usually has a total grammage of about 45 g / m 2 to about 160 g / m 2 .

Solche Dekorpapiere werden an speziellen Imprägniermaschinen mit Imprägnierharz imprägniert bzw. durchtränkt, was in Fig. 3 gepunktet angedeutet ist. Die aufgebrachte Menge an Imprägnierharz beträgt bezogen auf das Rohpapiergewicht der Dekorpapierlage 14 etwa 100% bis etwa 140%.Such decorative papers are impregnated or impregnated with impregnating resin on special impregnating machines, which is described in US Pat Fig. 3 dotted is indicated. The amount of impregnating resin applied, based on the raw paper weight of the decorative paper layer 14, is about 100% to about 140%.

Um verhindern zu können, dass es aufgrund der von der Dekorpapierlage 14 herrührenden Spannungen zu einer Verformung des Verkleidungselements 10 kommt, beispielsweise zu einer Aufwölbung, die dessen gewünschte vollkommen ebene und flächige Gestalt zerstört, kann optional auf der der Sichtfläche 12a der Grundplatte 12 entgegengesetzt angeordneten Rückfläche 12b der Grundplatte 12 eine Gegenzugpapierlage 18 angeordnet sein. Auch die Gegenzugpapierlage 18 ist mit Imprägnierharz getränkt, wie in Fig. 3 durch die Punktierung angedeutet ist. Hinsichtlich des Rohpapiergewichts, d.h. der Grammatur des verwendeten Papiers und der Menge aufgebrachten Imprägnierharzes entspricht die Gegenzugpapierlage 18 im Wesentlichen der Dekorpapierlage 14, um sicherzustellen, dass beide Papierlagen 14 und 18 einander im Wesentlichen aufhebende Spannungseinflüsse auf die Grundplatte 12 ausüben.In order to be able to prevent deformation of the lining element 10 due to the tensions arising from the decorative paper layer 14, for example to a curvature which destroys its desired completely planar and planar shape, it can optionally be disposed opposite to that of the visible surface 12a of the base plate 12 Rear surface 12b of the base plate 12 a Gegenzugpapierlage 18 may be arranged. The Gegenzugpapierlage 18 is impregnated with impregnating resin, as in Fig. 3 indicated by the punctuation. With respect to the base paper weight, ie, the grammage of the paper used and the amount of impregnating resin applied, the countertransfer paper layer 18 substantially corresponds to the decor paper layer 14 to ensure that both paper layers 14 and 18 exert substantially canceling stresses on the base plate 12.

Um die Dekorpapierlage 14 gegenüber Abrieb zu schützen, was nicht nur bei Einsatz des Verkleidungselements 10 als Fußbodenpaneel, sondern auch bei dessen Einsatz als Wandverkleidungselement oder Möbelsichtfrontelement wichtig ist, kann ferner optional auf die Sichtfläche 14a der Dekorpapierlage 14 noch eine Deckpapierlage 20 (in der Fachsprache auch Overlay-Papierlage genannt) aufgebracht sein. Übliche Deckpapiere bzw. Overlay-Papiere haben vorzugsweise ein Rohpapiergewicht von etwa 10 g/m2 bis etwa 80 g/m2 und sind damit insbesondere dann, wenn sie mit lmprägnierharz getränkt sind, transparent, um den Blick auf das Dekor der Dekorpapierlage 14 nicht zu behindern. Bezogen auf das Rohpapiergewicht beträgt die Menge an Imprägnierharz zwischen etwa 100% und etwa 300%. Zur Erhöhung der Abriebbeständigkeit kann dem Imprägnierharz für die Deckpapierlage 20 ferner ein geeigneter Zuschlagsstoff, beispielsweise Korund, beigemengt sein, vorzugsweise in einer Menge von etwa 5 g/m2 bis etwa 50 g/m2.In order to protect the decorative paper layer 14 against abrasion, which is important not only when using the cladding element 10 as a floor panel, but also in its use as a wall cladding element or furniture front panel, may optionally also on the visible surface 14a of the decorative paper layer 14 nor a cover paper layer 20 (in the jargon also Overlay paper layer called) applied. Conventional cover papers or overlay papers preferably have a raw paper weight of about 10 g / m 2 to about 80 g / m 2 and are thus, especially when impregnated with impregnating resin, transparent, so as not to look at the decor of the decorative paper layer 14 to hinder. Based on the raw paper weight, the amount of impregnating resin is between about 100% and about 300%. To increase the abrasion resistance, the impregnating resin for the cover paper layer 20 may further be admixed with a suitable additive, for example corundum, preferably in an amount of about 5 g / m 2 to about 50 g / m 2 .

Als Imprägnierharze kommen bevorzugt Aminoplastharze zum Einsatz, beispielsweise Harnstoffharze oder Melaminharze oder Gemische von Harnstoff- und Melaminharzen, wobei zum Imprägnieren der Deckpapierlage 20 bevorzugt Melaminharz verwendet wird.As impregnating resins, preference is given to using aminoplast resins, for example urea resins or melamine resins or mixtures of urea and melamine resins, melamine resin preferably being used to impregnate the cover paper layer 20.

Das bekannte Verfahren zur Herstellung eines derartigen Verkleidungselements 10, dessen einzelne Verfahrensschritte schematisch in Fig. 2 dargestellt sind, ist auf den Takt der Herstellung der Grundplatte 12 ausgerichtet. Daher müssen sämtliche im Schichtaufbau des Verkleidungselements 10 verwendeten Papiere in Zwischenspeichern auf Vorrat gehalten werden, damit es bei der Produktion nicht zu Verzögerungen im Vorschub der Grundplatten 12 kommt.The known method for producing such a cladding element 10, whose individual process steps schematically in Fig. 2 are shown, is aligned with the timing of the preparation of the base plate 12. Therefore, all papers used in the layer structure of the cladding element 10 must be kept in temporary storage so that there is no delay in the feed of the base plates 12 during production.

In einem Schritt D wird beispielsweise ein mit einem gewünschten Dekor bedrucktes Dekorpapier 14 bereitgestellt. Dieses wird in einem Schritt DI in einer speziellen Imprägniermaschine mit Imprägnierharz imprägniert. Dabei kann das Imprägnierharz in einer oder mehreren Stufen auf das Dekorpapier 14 aufgebracht werden, in dieses eindringen und anschließend angetrocknet werden. Das so imprägnierte Dekorpapier 14 wird dann in einem weiteren Schritt DF formatiert, d.h. auf eine auf die Größe der zugeführten Grundplatten 12 abgestimmte Größe zurechtgeschnitten. Das Dekorpapier 14 ist nun für die weitere Verarbeitung, insbesondere die Heißverpressung mit der Grundplatte 12, fertig und wird in einem Schritt DL einem Zwischenlager 22 zugeführt, wo es bis zur Weiterverarbeitung verbleibt.In a step D, for example, a decor paper 14 printed with a desired decor is provided. This is impregnated in a step DI in a special impregnating machine with impregnating resin. In this case, the impregnating resin can be applied in one or more stages on the decorative paper 14, penetrate into this and then dried. The decorative paper 14 thus impregnated is then formatted in a further step DF, ie cut to a size matched to the size of the supplied base plates 12. The decor paper 14 is now for further processing, especially the hot pressing with the base plate 12, finished and is fed in a step DL an intermediate storage 22, where it remains until further processing.

In analoger Weise werden auch das Gegenzugpapier 18 und das Deckpapier 20 in dem Schritt D entsprechenden Schritten R und O als Rohpapier zugeführt, in dem Schritt DI entsprechenden Schritten RI und OI mit Imprägnierharz imprägniert, in dem Schritt DF entsprechenden Schritten RF und OF formatiert und in dem Schritt DL entsprechenden Schritten RL und OL dem Zwischenlager 22 entsprechenden Zwischenlagern 24 und 26 zugeführt.In an analogous manner, also the Gegenzugpapier 18 and the cover paper 20 in the step D corresponding steps R and O supplied as raw paper, in the step DI corresponding steps RI and OI impregnated with impregnating resin, in step DF corresponding steps RF and OF formatted and in Step DL corresponding steps RL and OL the intermediate storage 22 corresponding intermediate bearings 24 and 26, respectively.

Wird nun in einem Schritt B eine Grundplatte 12 angefördert, so werden in Schritten DS, RS und OS jeweils ein imprägniertes und formatiertes Dekorpapier 14, Gegenzugpapier 18 und Deckpapier 20 aus den zugehörigen Zwischenlagern 22, 24 und 26 entnommen und in der vorstehend mit Bezug auf Fig. 3 beschriebenen Reihenfolge aufeinander gestapelt. Anschließend wird dieser Stapel in einem Schritt HP einer Heißpresse 28 zugeführt, in der die Papierlagen 14, 18 und 20 zur Bildung des gewünschten Endprodukts, nämlich des Verkleidungselements 10, unter Anwendung eines erhöhten Drucks und einer erhöhten Temperatur mit der Grundplatte 12 verpresst werden.If a base plate 12 is now conveyed in a step B, an impregnated and formatted decor paper 14, withdrawal paper 18 and cover paper 20 are removed from the associated intermediate storage 22, 24 and 26 in steps DS, RS and OS and in the above with reference to Fig. 3 described sequence stacked on each other. Subsequently, in a step HP, this stack is fed to a hot press 28, in which the paper layers 14, 18 and 20 are pressed with the base plate 12 to form the desired end product, namely the lining element 10, using an elevated pressure and temperature.

Obgleich die Heißpresse 28 in Fig. 2 grob schematisch in Form zweier Pressplatten, d.h. in Form einer stationär arbeitenden Presse, angedeutet ist, versteht es sich, dass ebenso gut auch kontinuierlich oder quasikontinuierlich arbeitende Pressen, beispielsweise Durchlaufpressen, eingesetzt werden können.Although the hot press 28 in Fig. 2 roughly schematically in the form of two press plates, ie in the form of a stationary press, is indicated, it is understood that equally well as continuous or quasi-continuous presses, for example, continuous presses can be used.

Das bekannte Verfahren hat den Nachteil, dass die mit Imprägnierharz imprägnierten Papiere nur eine zeitlich begrenzte Lagerstabilität aufweisen. Das Imprägnierharz darf nämlich vor dem Heißpressen nicht schon vollständig durchgetrocknet sein, sondern darf lediglich so kontakttrocken sein, dass die einzelnen Papierlagen in den Zwischenlagern, beispielsweise dem Zwischenlager 22 für Dekorpapier 14, nicht aneinander anhaften. Im Zwischenlager trocknen die Papiere, insbesondere das Imprägnierharz, mit dem sie getränkt sind, jedoch weiter, so dass sie bei einer zu hohen Lagerdauer einen Trockungsgrad erreichen, der ein ordnungsgemäßes Heißverpressen nicht mehr zulässt. Zu lange gelagerte imprägnierte Papiere müssen daher ausgesondert und entsorgt werden, was nicht zuletzt aufgrund der hohen Materialkosten für die zum Imprägnieren üblicherweise verwendeten Aminoplastharze von Nachteil ist.The known method has the disadvantage that the papers impregnated with impregnating resin have only a limited shelf life. Namely, the impregnating resin must not already be thoroughly dried before hot pressing, but may only be so dry that the individual paper layers in the intermediate storage, for example, the Interim storage 22 for decorative paper 14, do not adhere to each other. In the interim storage the papers, in particular the impregnating resin with which they are impregnated, dry on, however, so that they reach a degree of drying when the storage time is too long, which does not permit proper hot pressing. Impregnated papers stored for too long must therefore be sorted out and disposed of, which is disadvantageous not least because of the high material costs for the aminoplast resins commonly used for impregnation.

WO 97/17214 A offenbart ein Verfahren zur Herstellung eines Verkleidungselements mit einer Grundplatte, auf deren Sichtfläche eine Dekorlage angeordnet ist, und deren Rückseite eine Gegenzuglage trägt. In einer Gussform wird ein Harzgusskörper, welcher durch eine Spanplatte verstärkt ist, zusammen mit Dekorlagen hergestellt. Die Dekorlagen werden in die Gussform eingelegt, woraufhin die Gussform mit flüssigem Harz gefüllt und das Verkleidungselement schließlich als Harzformkörper in der Gussform hergestellt wird. WO 97/17214 A discloses a method for producing a cladding element with a base plate, on the visible surface of which a decorative layer is arranged, and the rear side of which carries a counteracting layer. In a mold, a resin molded body reinforced by a chipboard is manufactured together with decorative sheets. The decorative layers are placed in the mold, after which the mold is filled with liquid resin and the cladding element is finally produced as a resin molding in the mold.

Zur Illustration des technischen Hintergrunds kann ferner auch auf die EP 0 745 478 A2 verwiesen werden, welche die Beschichtung eines endlosen Bahnmaterials, nämlich einer Linoleumbahn, beschreibt, wobei auf eine mit flüssigem Lack beschichtete Linoleumbahn eine Papierlage aufgewalzt wird.To illustrate the technical background can also on the EP 0 745 478 A2 be referred, which describes the coating of an endless web material, namely a Linoleumbahn, wherein on a coated with liquid paint Linoleumbahn a paper layer is rolled on.

Es ist Aufgabe der vorliegenden Erfindung, ein Verfahren der eingangs genannten Art anzugeben, mit welchem die Ausschussmengen reduziert, wenn nicht gar vollständig vermieden werden können.It is an object of the present invention to provide a method of the type mentioned, with which reduces the waste, if not completely avoided.

Diese Aufgabe wird erfindungsgemäß durch ein Verfahren gemäß Anspruch 1 gelöst.This object is achieved by a method according to claim 1.

Erfindungsgemäß wird die Papierlage also nicht schon vor der Zwischenlagerung mit Harz imprägniert, sondern sie wird mit dem auf die Grundplatte aufgebrachten Harz erst beim Verpressen von Papierlage und Grundplatte in Kontakt gebracht und dabei von dem Harz durchtränkt. Das eigentliche Imprägnieren der Papierlage erfolgt also erst beim Verpressen. Das Papier kann daher als Rohpapier zwischengelagert werden, sodass es keinerlei zeitlichen Beschränkungen mehr hinsichtlich der Zwischenlagerzeit unterworfen ist. Dabei wird unter Rohpapier im Falle der Dekorpapierlage auch bereits mit einem Dekor bedrucktes Papier verstanden. Da das Harz erfindungsgemäß auf die Grundplatte aufgetragen wird, ist zudem sichergestellt, dass Harz immer nur dann verbraucht wird, wenn auch tatsächlich eine Grundplatte zur weiteren Verarbeitung zur Verfügung steht. Das Harz kann auf die Sichtfläche oder/und die Anlagefläche beispielsweise mit einem Flächengewicht von zwischen etwa 50 g/m2 und etwa 200 g/m2 aufgetragen werden. Der Auftrag kann beispielsweise mittels eines an sich bekannten Walzenauftragswerks erfolgen.According to the paper layer is thus not already impregnated with resin before the intermediate storage, but it is with the on the base plate applied resin brought into contact only during pressing of paper layer and base plate and thereby impregnated by the resin. The actual impregnation of the paper layer thus takes place only during pressing. The paper can therefore be stored as raw paper so that it is no longer subject to any time restrictions with regard to the intermediate storage time. In the case of the decorative paper layer, raw paper is also understood to mean paper already printed with a décor. Since the resin is applied to the base plate according to the invention, it is also ensured that resin is always consumed only when a base plate is actually available for further processing. The resin can be applied to the visible surface and / or the contact surface, for example, with a basis weight of between about 50 g / m 2 and about 200 g / m 2 . The order can be done for example by means of a known roller applicator.

Ein zum Aushärten des Harzes erforderlicher Härter kann in Weiterbildung der Erfindung in dem ersten Schritt gemeinsam mit dem Harz auf die Oberfläche der Grundplatte aufgebracht werden, vorzugsweise als Harz-Härter-Gemisch. Alternativ ist es aber auch möglich und sogar vorteilhaft, wenn der Härter und das Harz in zwei voneinander getrennten Schritten auf die Oberfläche der Grundplatte aufgebracht werden. Und zwar wird der Härter vorzugsweise in einem dem ersten Schritt zeitlich vorangehenden vierten Schritt von dem Harz getrennt auf die Oberfläche der Grundplatte aufgebracht. Durch die letztgenannte Verfahrensvariante kann auch noch das Problem umgangen werden, dass ein einmal mit dem Härter vermischtes Harz innerhalb einer vorbestimmten Verarbeitungszeit, auch Topfzeit genannt, verarbeitet werden muss. Dies führt zu einer weiteren Reduzierung der Gefahr von Materialausschuss und trägt somit zu einer Senkung der Herstellungskosten der Verkleidungselemente bei.A curing agent required for hardening hardener can be applied in a further development of the invention in the first step together with the resin on the surface of the base plate, preferably as a resin-hardener mixture. Alternatively, it is also possible and even advantageous if the hardener and the resin are applied in two separate steps on the surface of the base plate. Namely, the hardener is preferably applied to the surface of the base plate separately from the resin in a fourth step preceding the first step. By the latter method variant can also be circumvented the problem that a once mixed with the hardener resin within a predetermined processing time, also called pot life, must be processed. This leads to a further reduction of the risk of material scrap and thus contributes to a reduction in the manufacturing cost of the cladding elements.

Als Härter kann beispielsweise eine Ammoniumchlorid-Lösung oder eine Ammoniumsulfat-Lösung oder eine Maleinsäureanhydrid-Lösung verwendet werden.As a hardener, for example, an ammonium chloride solution or an ammonium sulfate solution or a maleic anhydride solution can be used.

Wie dies aus dem Stand der Technik an sich bekannt ist, kann auch bei dem erfindungsgemäßen Verfahren die Papierlage in einem dem zweiten Schritt zeitlich vorangehenden fünften Schritt formatiert werden, wobei der Unterschied zum Verfahren des Standes der Technik lediglich darin besteht, dass die Papierlage als Rohpapierlage formatiert wird.As is known per se from the prior art, in the method according to the invention the paper layer can also be formatted in a fifth step preceding the second step, the difference to the prior art method being merely that the paper layer is in the base paper layer is formatted.

In Abhängigkeit des gewünschten Aufbaus des herzustellenden Verkleidungselements kann nach dem erfindungsgemäßen Verfahren lediglich eine Dekorpapierlage auf die Sichtfläche der Grundplatte aufgebracht werden. Im Hinblick auf die eingangs erläuterte Verformungsproblematik kann optional ferner auf der Anlagefläche der Grundplatte eine Gegenzugpapierlage vorgesehen werden.Depending on the desired structure of the cladding element to be produced, only a decorative paper layer can be applied to the visible surface of the base plate by the method according to the invention. in the With regard to the deformation problem explained at the outset, it is optionally also possible to provide a counterweight paper layer on the contact surface of the base plate.

Die Grundplatte ist sowohl an ihrer Sichtfläche als auch an ihrer Anlagefläche jeweils mit einer Papierlage versehen, nämlich einer Dekorpapierlage an der Sichtfläche und einer Gegenzugpapierlage an der Anlagefläche. In Weiterbildung der Erfindung ist es vorteilhaft, da zeitsparend, wenn die ersten Schritte des Aufbringens des jeweiligen Harzes auf die jeweilige Oberfläche oder/und die zweiten Schritte des Aufbringens der jeweiligen Papierlage auf die jeweilige mit Harz versehene Oberfläche im Wesentlichen gleichzeitig vorgenommen werden.The base plate is provided both on its visible surface and on its contact surface each with a paper layer, namely a decorative paper layer on the visible surface and a Gegenzugpapierlage on the contact surface. In a further development of the invention, it is advantageous to save time when the first steps of applying the respective resin to the respective surface and / or the second steps of applying the respective paper layer to the respective surface provided with resin substantially simultaneously.

Außerdem ist es im Hinblick auf die eingangs erläuterte Abnutzungs- bzw. Abriebproblematik optional ferner möglich, auf der Sichtseite der Grundplatte über der Dekorpapierlage noch eine Deckpapierlage vorzusehen. In diesem Fall kann die in dem ersten Schritt auf die Sichtfläche der Grundplatte aufgebrachte Harzmenge vorzugsweise derart bemessen sein, dass sie beim Verpressen der Papierlagen mit der Grundplatte im dritten Verfahrensschritt zum Durchtränken bzw. Imprägnieren sowohl der Dekorpapierlage als auch der Deckpapierlage ausreicht.In addition, with regard to the abrasion or abrasion problem explained above, it is optionally also possible to provide a cover paper layer on the visible side of the base plate above the decorative paper layer. In this case, the amount of resin applied to the visible surface of the base plate in the first step may preferably be such that it is sufficient for impregnating both the decorative paper layer and the cover paper layer during the pressing of the paper layers with the base plate in the third method step.

Darüber hinaus kann man dann, wenn die Grundplatte an ihrer Sichtfläche sowohl mit einer Dekorpapierlage als auch mit einer Deckpapierlage versehen ist, die zweiten Schritte des Aufbringens der beiden Papierlagen auf die mit Harz versehene Sichtfläche der Grundplatte oder/und die dritten Schritte des Verpressens der beiden Papierlagen mit der Grundplatte im Wesentlichen gleichzeitig vornehmen.Moreover, when the base plate is provided on its visible surface with both a decorative paper layer and a cover paper layer, the second steps of applying the two paper layers to the resinous visible surface of the base plate and / or the third steps of pressing the two Make paper layers with the base plate substantially simultaneously.

Wie eingangs bereits erwähnt, kann das Harz ein Aminoplastharz sein, vorzugsweise ein Harnstoffharz oder ein Melaminharz oder ein Harnstoffharz-Melaminharz-Gemisch. Ferner kann das Harz, insbesondere das zum Imprägnieren der sichtflächenseitig vorgesehenen Papierlagen verwendete Harz, wenigstens einen die Abriebfestigkeit erhöhenden Stoff, beispielsweise Korund, enthalten.As already mentioned, the resin may be an aminoplast resin, preferably a urea resin or a melamine resin or a urea resin-melamine resin mixture. Furthermore, the resin, in particular the for Impregnating the visible surface provided paper layers used resin, at least one abrasion resistance increasing substance, such as corundum, included.

Nachzutragen ist noch, dass jede der Papierlagen, d.h. die Dekorpapierlage oder/und die Gegenzugpapierlage oder/und die Deckpapierlage, von einer Mehrzahl von Papierschichten gebildet sein kann.It should be added that each of the paper layers, i. the decorative paper layer and / or the Gegenzugpapierlage and / or the cover paper layer may be formed by a plurality of paper layers.

Gewünschtenfalls kann das so hergestellte Verkleidungselement einer Oberflächenveredelung zugeführt werden. Hierzu wird die Oberfläche der Dekorpapierlage bzw. gegebenenfalls die Oberfläche der Deckpapierlage zunächst einer Oberflächenbehandlung unterzogen. Diese Oberflächenbehandlung kann eine chemische Behandlung, beispielsweise das Auftragen eines Haftvermittlers oder/und eine Fluorierung, oder/und eine mechanische Behandlung, beispielsweise das Anschleifen der Oberfläche, oder/und eine elektrische Behandlung, beispielsweise eine Coronabehandlung oder/und eine Plasmabehandlung, umfassen. Auf die so vorbereitete Oberfläche kann anschließend eine Lackschicht aufgebracht und getrocknet werden. Gewünschtenfalls kann dieser Lackauftrag auch mehrmals wiederholt werden, erforderlichenfalls unter erneuter vorheriger Oberflächenbehandlung der zuletzt aufgetragenen Lackschicht.If desired, the cladding element produced in this way can be supplied to a surface finish. For this purpose, the surface of the decorative paper layer or optionally the surface of the cover paper layer is first subjected to a surface treatment. This surface treatment may comprise a chemical treatment, for example the application of an adhesion promoter and / or a fluorination, and / or a mechanical treatment, for example surface grinding, and / or electrical treatment, for example corona treatment and / or plasma treatment. On the surface prepared in this way, a lacquer layer can then be applied and dried. If desired, this paint application can also be repeated several times, if necessary, with renewed previous surface treatment of the last applied paint layer.

Als Haftvermittler kommt beispielsweise das von Fa. Henelit, Villach, Österreich vertriebene Produkt "Hydrohaftgrund E643" oder organofunktionelles Silan in Frage. Organofunktionelle Silane sind hybride Verbindungen mit einer reaktiven organischen Gruppe und einem anorganischen Alkylsilikat, bei denen sowohl die organische funktionelle Gruppe als auch die anorganische hydrolisierbare Alkoxygruppe jeweils auf das verwendete Tränkharz bzw. Aminoplastharz und den verwendeten Lack abgestimmt werden können, um gute Haftvermittlungseigenschaften zu erreichen.Suitable adhesion promoters include, for example, the product sold by Henelit, Villach, Austria "Hydrohaftgrund E643" or organofunctional silane. Organofunctional silanes are hybrid compounds having a reactive organic group and an inorganic alkyl silicate, in which both the organic functional group and the inorganic hydrolyzable alkoxy group can be tailored to the impregnating resin or aminoplast resin used and the lacquer used in order to achieve good adhesion-promoting properties.

Bei der Fluorierung kann die mit der Grundplatte verpresste, harzgetränkte Dekorpapierlage in einem Vakuumreaktor behandelt werden. Nach dem Evakuieren und Inertisieren des Reaktors, d.h. dem Entfernen von etwaig noch an Reaktoroberflächen anhaftenden oder gebundenen Verunreinigungen, beispielsweise durch Spülen mit Inertgas, Erhitzen des Reaktors oder dergleichen, wird gezielt Fluor und Inertgas zugegeben, wobei ein variables Konzentrationsprofil des Fluorgemisches bei Umgebungstemperatur während der Behandlungszeit verwendet werden kann, um optimale Ergebnisse zu erzielen. Danach wird der Reaktor evakuiert, gespült und die Dekorpapierlage kann entnommen werden. Diese sogenannte Offline-Fluorierung kann als Nachbehandlungsmethode in jedes Produktionsverfahren integriert werden. Durch die Fluorierung wird die Oberflächenspannung und damit die Benetzung der Oberfläche durch einen Lack verbessert. Außerdem wird eine polare Oberfläche erreicht, was zu einer besseren Haftung einer Lackschicht führt.During fluorination, the resin-impregnated decorative paper layer pressed with the base plate can be treated in a vacuum reactor. After evacuation and inerting the reactor, ie removing any impurities still adhered or bound to reactor surfaces, for example by inert gas flushing, heating the reactor or the like, fluorine and inert gas are selectively added using a variable concentration profile of the fluorine mixture at ambient temperature during the treatment time can for best results. Thereafter, the reactor is evacuated, rinsed and the decorative paper layer can be removed. This so-called offline fluorination can be integrated as a post-treatment method in every production process. Due to the fluorination, the surface tension and thus the wetting of the surface is improved by a paint. In addition, a polar surface is achieved, which leads to better adhesion of a paint layer.

Bei einer Coronabehandlung wird Luft, die sich im Zwischenraum zwischen zwei Elektroden befindet, ionisiert. Diese Ionen dringen dann in Abhängigkeit ihrer kinetischen Energie in die Oberfläche der zwischen den Elektroden angeordneten zu behandelnden Dekorpapierlage ein, und zwar beispielsweise bis zu 10 µm tief. Die dadurch bewirkten physikalischen und chemischen Veränderungen an der Oberfläche der behandelten Dekorpapierlage können noch nicht eindeutig erklärt werden. Es wird allerdings davon ausgegangen, dass sowohl Oxidationsvorgänge an der Oberfläche eine Rolle spielen als auch durch den Beschuss mit beschleunigten Ionen und Elektronen verursachte physikalische und chemische Veränderungen der Oberfläche stattfinden. Es ist jedoch eine wissenschaftlich gesicherte Tatsache, dass eine Coronabehandlung eine verbesserte Adhäsion der Oberfläche bewirkt, so dass, wie gewünscht, eine aufgetragene Lackschicht an einer derart behandelten Dekorpapierlage besser haftet.In a corona treatment, air that is in the space between two electrodes is ionized. These ions then penetrate depending on their kinetic energy in the surface of the arranged between the electrodes to be treated decorative paper layer, for example, up to 10 microns deep. The resulting physical and chemical changes on the surface of the treated decorative paper layer can not yet be clearly explained. It is assumed, however, that oxidation processes at the surface play a role as well as physical and chemical changes of the surface caused by the bombardment with accelerated ions and electrons. However, it is a scientifically proven fact that corona treatment causes improved surface adhesion such that, as desired, a coated lacquer layer will adhere better to a decorative paper sheet so treated.

Ähnliche Effekte werden auch mit der Plasmabehandlung erzielt, wobei hier nicht der direkte elektrische Lichtbogen, der an den mit Hochspannung beaufschlagten Elektroden entsteht, zur Behandlung der Oberfläche genutzt wird, sondern mittels Ladungstrennung ein reaktiver, potentialfreier Partikelstrahl ionisierter Luft erzeugt und auf die Oberfläche der zu behandelnden Dekorpapierlage gerichtet wird.Similar effects are also achieved with the plasma treatment, in which case the direct electrical arc which is produced at the electrodes subjected to high voltage is not used for the treatment of the surface, but instead a reactive, potential-free particle beam by means of charge separation ionized air generated and is directed to the surface of the decorative paper sheet to be treated.

Durch entsprechendes Polieren der so nachbehandelten, insbesondere lackierten Oberfläche kann in einfacher Weise jede gewünschte Oberflächen-Reflektionseigenschaft von mattglänzend bis hin zu hochglänzend erzielt werden. Insbesondere bei hochglänzend polierter Oberfläche ist ein Verkleidungselement, dessen Dekorpapierlage mit einem Holzdekor bedruckt ist, von Echtholz praktisch nicht zu unterscheiden.By appropriate polishing of the thus treated, in particular painted surface, any desired surface reflection property can be achieved in a simple manner from matt gloss to high gloss. Especially with highly polished surface is a panel element whose decorative paper layer is printed with a wood decor, practically indistinguishable from real wood.

Die Erfindung wird im Folgenden mit Bezug auf die beigefügte Zeichnung an einem Ausführungsbeispiel näher erläutert werden. Es stellt dar:

Fig. 1
ein schematisches Ablaufdiagramm einer Ausführungsvariante des erfindungsgemäßen Verfahrens;
Fig. 2
eine Ansicht ähnlich Fig. 1 eines Herstellungsverfahrens nach dem Stand der Technik; und
Fig. 3
eine schematische Darstellung zur Erläuterung des Schichtaufbaus eines nach dem erfindungsgemäßen Verfahren herzustellenden Verkleidungselements.
The invention will be explained in more detail below with reference to the accompanying drawings of an embodiment. It shows:
Fig. 1
a schematic flow diagram of an embodiment of the method according to the invention;
Fig. 2
a view similar Fig. 1 a manufacturing method according to the prior art; and
Fig. 3
a schematic representation for explaining the layer structure of a produced by the process according to the invention cladding element.

Mit Bezug auf Fig. 1 wird im Folgenden ein erfindungsgemäßes Verfahren zur Herstellung eines Verkleidungselements 10 näher erläutert werden, das den eingangs bereits mit Bezug auf Fig. 3 erläuterten Aufbau aufweist, d.h. insbesondere an seiner Sichtfläche 12a sowohl mit einer Dekorpapierlage 14 als auch mit einer Deckpapierlage 20, und an seiner Anlagefläche 12b mit einer Gegenzugpapierlage 18 versehen ist.Regarding Fig. 1 In the following, a method according to the invention for producing a cladding element 10 will be explained in more detail, which has already been described in the introduction with reference to FIG Fig. 3 has explained structure, that is provided in particular on its visible surface 12a both with a decorative paper layer 14 and with a cover paper layer 20, and at its contact surface 12b with a Gegenzugpapierlage 18.

Wie in Fig. 1 dargestellt, wird die Dekorpapierlage 14 in einem Schritt D als Rohpapier bereitgestellt und in einem Schritt DF in einer zu den Abmessungen der Grundplatte 12 passenden Größe formatiert. In einem Schritt DL wird die formatierte Dekorpapierlage 14 dann einem Zwischenspeicher 22 zugeführt, in welchem sie bis zur weiteren Verarbeitung zwischengelagert wird.As in Fig. 1 illustrated, the decorative paper layer 14 is provided in a step D as raw paper and formatted in a step DF in a size matching the dimensions of the base plate 12 size. In a step DL The formatted decorative paper ply 14 is then fed to a buffer store 22, in which it is temporarily stored until further processing.

In analoger Weise werden in dem Schritt D entsprechenden Schritten R bzw. O als Rohpapier bereitgestellte Gegenzugpapierlagen 18 bzw. Deckpapierlagen 20 in dem Schritt DF entsprechenden Schritten RF bzw. OF formatiert und in dem Schritt DL entsprechenden Schritten RL bzw. OL einem Zwischenspeicher 24 bzw. 26 zugeführt. Im Unterschied zu dem eingangs erläuterten Verfahren des Standes der Technik sind die in den Zwischenspeichern 22, 24 und 26 zwischengelagerten Papiere also nicht mit Harz imprägniert. Hierdurch entfällt das bei dem bekannten Verfahren auftretende Problem, dass von der Trocknungszeit des Harzes herrührende, maximale Zwischenlagerzeiten beachtet werden müssen, vollständig.Analogously, in the step D corresponding steps R and O provided as base paper Gegenzugpapierlagen 18 or cover paper layers 20 in the step DF corresponding steps RF or OF formatted in the step DL corresponding steps RL or OL a buffer 24 and 26 supplied. In contrast to the method of the prior art explained in the introduction, the papers intermediately stored in the intermediate buffers 22, 24 and 26 are therefore not impregnated with resin. This eliminates the problem occurring in the known method that must be taken into account by the drying time of the resin, maximum intermediate storage times, completely.

Bei dem erfindungsgemäßen Verfahren wird eine in einem Schritt B bereitgestellte Grundplatte 12 in einem Schritt BID auf ihrer Sichtfläche 12a mit einer Schicht aus Imprägnierharz, genauer gesagt mit einer Schicht aus einem Imprägnierharz-Härter-Gemisch, versehen. Erforderlichenfalls kann die Grundplatte 12 auch rückseitig, d.h. auf ihrer Anlagefläche 12b, in einem Schritt BIR mit einer entsprechenden Schicht versehen werden.In the method according to the invention, a base plate 12 provided in a step B is provided in a step BID on its visible surface 12a with a layer of impregnating resin, more precisely with a layer of a impregnating resin-hardener mixture. If necessary, the base plate 12 may also be rear-side, i. be provided on its contact surface 12b, in a step BIR with a corresponding layer.

Alternativ können die Schritte BID und BIR jeweils auch in zwei im zeitlichen Abstand erfolgende Schritte BHD und BAD bzw. BHR und BAR aufgeteilt werden, was in Fig. 1 durch gestrichelte Pfeile angedeutet ist. In den Schritten BHD und BHR wird dabei zunächst ein zum Aushärten des Imprägnierharzes erforderlicher Härter auf die Sichtfläche 12a bzw. die Rückfläche 12b der Grundplatte 12 aufgebracht, und erfolgt anschließend in den Schritten BAD und BAR der eigentliche Auftrag des Imprägnierharzes. Die letztgenannte Verfahrensvariante ist im Hinblick auf das Problem der Topfzeit eines Imprägnierharz-Härter-Gemisches von Vorteil.Alternatively, the steps BID and BIR can each also be divided into two temporally spaced steps BHD and BAD or BHR and BAR, which in Fig. 1 indicated by dashed arrows. In steps BHD and BHR, a hardener required for curing the impregnating resin is first applied to the visible surface 12a or the rear surface 12b of the base plate 12, and then the actual application of the impregnating resin takes place in the steps BAD and BAR. The latter method variant is advantageous in view of the problem of the pot life of an impregnating resin-hardener mixture.

Die Schritte BID und BIR bzw. die Schritte BHD und BHR und die Schritte BAD und BAR können vorzugsweise im Wesentlichen zeitgleich vorgenommen werden.The steps BID and BIR or the steps BHD and BHR and the steps BAD and BAR may preferably be made substantially simultaneously.

Die so auf ihren beiden Oberflächen 12a, 12b mit Harz beschichtete Grundplatte 12 wird in einem Schritt BS einem Stapelungsvorgang zugeführt, in welchem auf die Sichtfläche 12a der Grundplatte 12 eine in einem Schritt DS zugeführte Dekorpapierlage 14 und optional eine in einem Schritt OS zugeführte Deckpapierlage 20 aufgelegt wird, sowie ferner optional auf die Anlagefläche 12b der Grundplatte 12 eine in einem Zuführschritt RS zugeführte Gegenzugpapierlage 18 aufgelegt wird. Der so gebildete Stapel wird in einem Schritt HP einer Heißpresse 28 zugeführt, in welcher die verschiedenen Papierlagen unter erhöhtem Druck und erhöhter Temperatur mit der Grundplatte 12 verpresst werden. Insbesondere dringt während dieses Pressvorgangs das auf die Grundplatte 12 aufgebrachte Harz in die verschiedenen Papierlagen ein und durchtränkt bzw. imprägniert diese. Man erhält so ein Verkleidungselement 10 mit dem in Fig. 3 dargestellten Schichtaufbau.The base plate 12 thus coated with resin on its two surfaces 12a, 12b is fed to a stacking process in step BS, in which a decorative paper layer 14 supplied in step DS to the visible surface 12a of the base plate 12 and optionally a cover paper layer 20 fed in a step OS is placed as well as optionally optionally on the contact surface 12b of the base plate 12, a fed in a feed step RS Gegenzugpapierlage 18 is placed. The stack thus formed is fed in a step HP a hot press 28, in which the various paper layers are pressed under increased pressure and elevated temperature with the base plate 12. In particular, during this pressing operation, the resin applied to the base plate 12 penetrates into the various paper layers and impregnates or impregnates them. This gives a cladding element 10 with the in Fig. 3 layer structure shown.

Anschließend kann das so hergestellte Verkleidungselement 10 gewünschtenfalls noch einer Oberflächenveredelung unterzogen werden. Hierzu wird die Oberfläche 14a der Dekorpapierlage bzw. gegebenenfalls die Oberfläche 20a der Deckpapierlage 20 zunächst einer Oberflächenbehandlung unterzogen. Diese Oberflächenbehandlung kann eine chemische Behandlung, beispielsweise das Auftragen eines Haftvermittlers oder/und eine Fluorierung, oder/und eine mechanische Behandlung, beispielsweise das Anschleifen der Oberfläche, oder/und eine elektrische Behandlung, beispielsweise eine Coronabehandlung oder/und eine Plasmabehandlung, umfassen. Auf die so vorbereitete Oberfläche kann anschließend eine Lackschicht 30 aufgebracht und getrocknet werden, die in Fig. 3 lediglich gestrichelt angedeutet ist. Gewünschtenfalls kann dieser Lackauftrag auch mehrmals wiederholt werden, erforderlichenfalls unter vorheriger Oberflächenbehandlung der zuletzt aufgetragenen Lackschicht.If desired, the cladding element 10 produced in this way can then be subjected to a surface refinement. For this purpose, the surface 14a of the decorative paper layer or optionally the surface 20a of the cover paper layer 20 is first subjected to a surface treatment. This surface treatment may comprise a chemical treatment, for example the application of an adhesion promoter and / or a fluorination, and / or a mechanical treatment, for example surface grinding, and / or electrical treatment, for example corona treatment and / or plasma treatment. On the surface prepared in this way can then be applied and dried a lacquer layer 30, the in Fig. 3 only indicated by dashed lines. If desired, this paint application can also be repeated several times, if necessary with prior surface treatment of the last applied paint layer.

Gemäß eines Ausführungsbeispiels umfasst die Oberflächenbehandlung zunächst das Aufbringen eines Haftvermittlers, beispielsweise des von Fa. Henelit, Villach, Österreich vertriebenen Produkts "Hydrohaftgrund E643", und zwar in einer Menge von zwischen etwa 5 g/m2 und etwa 30 g/m2. Dieser Haftvermittler wird anschließend mittels UV-Strahlung ausgehärtet. Zur weiteren Verbesserung der Haftfestigkeit des folgenden Lackauftrags kann die Oberfläche dann gewünschtenfalls auch noch angeschliffen werden. Der Lack kann als Walzlack oder Sprühlack aufgetragen werden. Als Lack kann beispielsweise ein Polyurethanlack oder ein UV-Lack verwendet werden, etwa der von Fa. Henelit, Villach, Österreich vertriebene "UV Hydro brillant"-Lack. Der Lackauftrag kann in einer Menge von zwischen etwa 15 g/m2 und etwa 30 g/m2 für die Lackgrundschicht und zwischen etwa 5 g/m2 und etwa 10 g/m2 für weitere Lackschichten erfolgen.According to one embodiment, the surface treatment initially comprises the application of an adhesion promoter, for example of the product sold by the company Henelit, Villach, Austria "Hydrohaftgrund E643", in an amount of between about 5 g / m 2 and about 30 g / m 2 . This bonding agent is then cured by means of UV radiation. To further improve the adhesion of the subsequent coating application, the surface can then be sanded, if desired, even. The paint can be applied as a roller paint or spray paint. For example, a polyurethane varnish or a UV varnish can be used as the varnish, for example the "UV Hydro Brilliant" varnish marketed by the company Henelit, Villach, Austria. The paint application can be carried out in an amount of between about 15 g / m 2 and about 30 g / m 2 for the paint base layer and between about 5 g / m 2 and about 10 g / m 2 for other paint layers.

Zur Erhöhung der Abriebbeständigkeit der Lackschicht kann dem Lack ein geeigneter Zuschlagsstoff beigemengt werden, beispielsweise Korund, vorzugsweise in einer Menge von etwa 5 g/m2 bis etwa 50 g/m2. Sofern die Abriebbeständigkeit der so aufgebrachten Lackschicht ausreicht, kann auf den Einsatz eines Deckpapiers verzichtet werden. Da die Lackschicht zu keiner zusätzlichen Spannung in dem auf die Sichtfläche 12a der Grundplatte 12 aufgebrachten Schichtaufbau führt, brauchen auf der Rückfläche 12b der Grundplatte 12 in der Gegenzugpapierlage 18 keine besonderen Vorkehrungen getroffen zu werden.To increase the abrasion resistance of the paint layer, the paint may be admixed with a suitable additive, for example corundum, preferably in an amount of about 5 g / m 2 to about 50 g / m 2 . If the abrasion resistance of the lacquer layer applied in this way is sufficient, the use of a cover paper can be dispensed with. Since the lacquer layer does not lead to any additional stress in the layer structure applied to the visible surface 12a of the base plate 12, no special precautions need to be taken on the rear surface 12b of the base plate 12 in the countertraction paper layer 18.

Claims (17)

  1. A method for producing a cladding element (10), for example a flooring panel, a wall cladding element, a furniture face element or the like, wherein the cladding element (10) comprises a base board (12) which on two surfaces, namely its visible surface (12a) and its contact surface (12b) opposite the visible surface, is provided with a respective paper layer (14,18) impregnated with resin,
    wherein in a first step (BID,BIR) the resin is applied to the surfaces (12a,12b) of the base board (12), in a second step (DS,RS) following in time the first step (BID,BIR) the paper layers (14,18) are applied to the surfaces (12a,12b) of the base board (12), and in a third step (HP) following in time the second step (DS,RS) the base board (12) provided with resin and the two paper layers (14,18) are pressed together substantially simultaneously,
    wherein both paper layers (14,18) are impregnated with the resin only in the third step (HP).
  2. A method according to Claim 1,
    characterised in that a hardener necessary for hardening the resin in the first step (BID,BIR) is applied jointly with the resin to the surface (12a,12b) of the base board (12), preferably as a resin-hardener mixture.
  3. A method according to Claim 1,
    characterised in that a hardener necessary for hardening the resin is applied separately from the resin to the surface (12a,12b) of the base board (12), preferably in a fourth step preceding in time the first step (BID, BIR) .
  4. A method according to any one of Claims 1 to 3,
    characterised in that the paper layer (14,18) is formatted in a fifth step preceding in time the second step (DS,RS).
  5. A method according to any one of Claims 1 to 4,
    characterised in that the first steps (BID,BIR) of applying the respective resin to the respective surface (12a,12b) and/or the second steps (DS,RS) of applying the respective paper layer (14,18) to the respective surface (12a,12b) provided with resin are carried out substantially simultaneously.
  6. A method according to any one of Claims 1 to 5,
    characterised in that if the base board (12) is provided on its visible surface (12a) both with a decorative paper layer (14) and with a covering paper layer (20), in the first step (BID) an amount of resin is applied to the visible surface (12a) of the base board (12) which is measured taking into account both paper layers (14,20).
  7. A method according to any one of Claims 1 to 6,
    characterised in that if the base board (12) is provided on its visible surface (12a) both with a decorative paper layer (14) and with a covering paper layer (20), the second steps (DS,OS) of applying the two paper layers (14,20) to the visible surface (12a) of the base board (12) provided with resin and/or the third steps (HP) of pressing the two paper layers (14,20) with the base board (12) are carried out substantially simultaneously.
  8. A method according to any one of Claims 1 to 7,
    characterised in that the resin is an amino resin, preferably a urea-formaldehyde resin or a melamine resin or a urea-formaldehyde melamine resin mixture.
  9. A method according to any one of Claims 1 to 8,
    characterised in that the resin contains at least one substance increasing abrasion resistance, for example corundum.
  10. A method according to the preamble of Claim 1 and, if desired, the characterising part of any one of Claims 1 to 9,
    characterised in that a visible surface (14a,20a) of the decorative paper layer or of the covering paper layer (20) is firstly subjected to at least one surface treatment, and in that at least one varnish layer (30) is then applied to this treated surface.
  11. A method according to Claim 10,
    characterised in that the at least one surface treatment comprises a chemical treatment.
  12. A method according to Claim 11,
    characterised in that the at least one surface treatment comprises the application of an adhesion promoter, for example of organofunctional silane, or a fluorination.
  13. A method according to any one of Claims 10 to 12,
    characterised in that the at least one surface treatment comprises an electrical treatment.
  14. A method according to Claim 13,
    characterised in that the at least one surface treatment comprises a corona treatment or a plasma treatment.
  15. A method according to any one of Claims 10 to 14, characterised in that the at least one surface treatment comprises a mechanical treatment.
  16. A method according to Claim 15,
    characterised in that the at least one surface treatment comprises a grinding of the surface.
  17. A method according to any one of Claims 10 to 16, characterised in that the varnish contains at least one substance increasing abrasion resistance, for example corundum.
EP07702836A 2006-01-18 2007-01-17 Method for producing a cladding element Active EP1976697B1 (en)

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CA2637415C (en) 2013-10-29
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AU2007207150A1 (en) 2007-07-26
HRP20110518T1 (en) 2011-09-30
ATE514554T1 (en) 2011-07-15
US20140158286A1 (en) 2014-06-12
RU2008133637A (en) 2010-02-27
ES2368791T3 (en) 2011-11-22
PL1976697T3 (en) 2011-11-30
EP1976697A1 (en) 2008-10-08
WO2007082732A1 (en) 2007-07-26
CN101374660A (en) 2009-02-25
CA2637415A1 (en) 2007-07-26
RU2423240C2 (en) 2011-07-10
US20100163160A1 (en) 2010-07-01
JP2009523933A (en) 2009-06-25
SI1976697T1 (en) 2011-11-30
AU2007207150B2 (en) 2011-07-28
JP5405833B2 (en) 2014-02-05
DE102006002417A1 (en) 2007-07-19
DK1976697T3 (en) 2011-10-10
CN101374660B (en) 2012-08-08

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