DE4102115A1 - Sheets which utilise domestic scrap - have two e.g. wood FRP or metal skins bonded to core made of two mutually incompatible thermoplastics mixed with non-thermoplastic particles - Google Patents
Sheets which utilise domestic scrap - have two e.g. wood FRP or metal skins bonded to core made of two mutually incompatible thermoplastics mixed with non-thermoplastic particlesInfo
- Publication number
- DE4102115A1 DE4102115A1 DE19914102115 DE4102115A DE4102115A1 DE 4102115 A1 DE4102115 A1 DE 4102115A1 DE 19914102115 DE19914102115 DE 19914102115 DE 4102115 A DE4102115 A DE 4102115A DE 4102115 A1 DE4102115 A1 DE 4102115A1
- Authority
- DE
- Germany
- Prior art keywords
- layer
- thermoplastic particles
- plate according
- thermoplastic
- layer plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 56
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 55
- 239000002245 particle Substances 0.000 title claims abstract description 24
- 239000002023 wood Substances 0.000 title claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 title claims description 5
- 239000002184 metal Substances 0.000 title claims description 5
- 239000000203 mixture Substances 0.000 claims abstract description 10
- -1 polyethylene Polymers 0.000 claims abstract description 9
- 229920000573 polyethylene Polymers 0.000 claims abstract description 7
- 239000004698 Polyethylene Substances 0.000 claims abstract description 6
- 239000002313 adhesive film Substances 0.000 claims abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003063 flame retardant Substances 0.000 claims abstract description 5
- 239000004743 Polypropylene Substances 0.000 claims abstract description 3
- 239000004793 Polystyrene Substances 0.000 claims abstract description 3
- 229920001155 polypropylene Polymers 0.000 claims abstract description 3
- 229920002223 polystyrene Polymers 0.000 claims abstract description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 3
- 229910000831 Steel Inorganic materials 0.000 claims abstract 2
- 239000010445 mica Substances 0.000 claims abstract 2
- 229910052618 mica group Inorganic materials 0.000 claims abstract 2
- 239000010959 steel Substances 0.000 claims abstract 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 238000004026 adhesive bonding Methods 0.000 claims description 4
- 239000011888 foil Substances 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical class [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- 238000004049 embossing Methods 0.000 claims description 2
- 229920001038 ethylene copolymer Polymers 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- 238000010422 painting Methods 0.000 claims description 2
- 238000007639 printing Methods 0.000 claims description 2
- 229920002430 Fibre-reinforced plastic Polymers 0.000 claims 1
- 230000002146 bilateral effect Effects 0.000 claims 1
- 239000011151 fibre-reinforced plastic Substances 0.000 claims 1
- 239000010419 fine particle Substances 0.000 claims 1
- 238000009827 uniform distribution Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000010791 domestic waste Substances 0.000 abstract description 2
- 229920001187 thermosetting polymer Polymers 0.000 abstract description 2
- 239000005030 aluminium foil Substances 0.000 abstract 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000002699 waste material Substances 0.000 description 6
- 239000000123 paper Substances 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000010893 paper waste Substances 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000013502 plastic waste Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000010786 composite waste Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000010104 thermoplastic forming Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 239000002916 wood waste Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/0026—Recovery of plastics or other constituents of waste material containing plastics by agglomeration or compacting
- B29B17/0042—Recovery of plastics or other constituents of waste material containing plastics by agglomeration or compacting for shaping parts, e.g. multilayered parts with at least one layer containing regenerated plastic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/082—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/18—Layered products comprising a layer of metal comprising iron or steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B19/00—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica
- B32B19/04—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica next to another layer of the same or of a different material
- B32B19/045—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
- B32B21/04—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B21/08—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/03—3 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/10—Properties of the layers or laminate having particular acoustical properties
- B32B2307/102—Insulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2311/00—Metals, their alloys or their compounds
- B32B2311/24—Aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2311/00—Metals, their alloys or their compounds
- B32B2311/30—Iron, e.g. steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2317/00—Animal or vegetable based
- B32B2317/12—Paper, e.g. cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2317/00—Animal or vegetable based
- B32B2317/16—Wood, e.g. woodboard, fibreboard, woodchips
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/04—Polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/10—Polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2325/00—Polymers of vinyl-aromatic compounds, e.g. polystyrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2327/00—Polyvinylhalogenides
- B32B2327/06—PVC, i.e. polyvinylchloride
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
Description
Die Erfindung betrifft eine vom Verfahren her in der Länge nicht beschränkte Dreischichtplatte, bestehend aus einer Mittellage und beiderseitigen dehnsteifen Deckschichten, wobei die Mittellage aus miteinander unverträglichen Thermoplasten besteht, denen kleinteilige, bevorzugt flächige, nicht-thermoplastische Teilchen ungefähr gleichmäßig verteilt, zugefügt sind.The invention relates to a method which is not limited in length by the method Three-layer board, consisting of a middle layer and double-sided elastic Cover layers, the middle layer of mutually incompatible thermoplastics consists of small, preferably flat, non-thermoplastic particles are distributed approximately evenly.
Bekanntgeworden ist eine Dreischichtplatte mit Alu-Deckschichten, deren Mittel lage aus reinem Polyethylen besteht. Es ist ferner bekannt, daß Kunststoff- Formkörper aus Mischungen unterschiedlicher Thermoplaste keinen praktischen Gebrauchswert haben, da die Festigkeitseigenschaften solcher Mischungen nur sehr gering sind. Bislang ist es nicht möglich, gebrauchstüchtige Gegenstände, geschweige denn Platten, aus unterschiedlichen Thermoplasten wie Mischungen aus Polyethylen, Polystyrol, Polypropylen und Polyvinylchlorid herzustellen.A three-layer panel with aluminum cover layers, their means, has become known layer consists of pure polyethylene. It is also known that plastic Moldings made from mixtures of different thermoplastics are not practical Have utility value, since the strength properties of such mixtures only are very low. So far it is not possible to use usable objects, let alone plates made of different thermoplastics such as mixtures from polyethylene, polystyrene, polypropylene and polyvinyl chloride.
Im Zuge des dualen Abfall-Sammelsystems werden jedoch aus den Haushalten in er heblichem Umfang die oben erwähnten Thermoplaste anfallen. Dabei wird eine Sor tierung in sortenreine Thermoplastabfälle nicht möglich sein. Außerdem werden Verbundkunststoffe anfallen, Verbunde aus Polyethylen, Papier und Alu-Folie. Eine Trennung nach diesem Sammelsystem ist nur für die Gruppen Metall, Glas, Papier und Kunststoff vorgesehen.In the course of the dual waste collection system, however, households are turned into it the above-mentioned thermoplastics occur to a considerable extent. A Sor categorization into unmixed thermoplastic waste may not be possible. Also be Composite plastics are created, composites made of polyethylene, paper and aluminum foil. A separation according to this collection system is only for the groups metal, glass, Paper and plastic provided.
Für diese Gruppen ist vom Gesetzgeber eine Wiederverwertung zu neuen Produkten in erheblichem Umfang gesetzlich vorgeschrieben worden.For these groups, the law requires recycling for new products have been required by law to a significant extent.
Für Glas und Metall sind Recycling-Verfahren bekannt, die eine Wiederverwertung der Abfälle ermöglichen. Dasselbe gilt für Papierabfälle, nur daß hier die anfallenden Mengen an Papierabfällen den Bedarf aus recyceltem Papier über schreiten. Die Forderung, aus den gesammelten in Mischung vorliegenden Kunststoffabfällen neue Produkte herzustellen, kann bisher noch nicht ent sprochen werden.Recycling processes are known for glass and metal, which are for recycling of waste. The same applies to paper waste, only that here the amount of paper waste generated from recycled paper stride. The demand from the collected mixed It is not yet possible to produce plastic waste from new products be spoken.
Deshalb hat sich die Erfindung die Aufgabe gestellt, aus den gemischten Thermo plastabfällen, wie sie beispielsweise bei der Sammlung von Haushaltabfällen anfallen, eine Dreischichtplatte zu entwickeln unter Verwendung von Kunststoff abfällen verschiedenartiger Thermoplaste unter Zumischung weiterer Abfälle in Form von Altpapier, Sägespäne, feinteiligem Holz aus Holzabfällen als Mittel lage, die beiderseits mit dehnsteifen Deckschichten verbunden ist.Therefore, the invention has set itself the task of mixed thermo plastic waste, such as that used for the collection of household waste to develop a three-layer board using plastic waste of various types of thermoplastics with the addition of further waste in the form of waste paper, sawdust, finely divided wood from wood waste as a means layer, which is connected on both sides with rigid outer layers.
Der Grund für die mangelnde Gebrauchstüchtigkeit von Formkörpern aus Mischungen unterschiedlicher Thermoplaste liegt in ihren unterschiedlichen Oberflächen-, resp. Grenzflächenspannungen. Bekanntlich werden Thermoplaste in der Schmelze zu Formkörpern verformt, z. B. nach dem Spritzgieß- oder nach dem Extrusionsver fahren. Die unterschiedlichen Grenzflächenspannungen führen in der Schmelze dazu, daß der eine Thermoplast sich im anderen kugelförmig zu sog. "Blasen" zusammen zieht. Eine Durchdringung des einen Thermoplasten in den anderen findet nicht statt. Dies führt dazu, daß die Grenze zwischen den beiden Thermoplasten wie ein Haarriß wirkt. Beide Thermoplaste haften nur aneinander.The reason for the lack of suitability for use of molded articles from mixtures different thermoplastics lies in their different surface, resp. Interfacial tensions. Thermoplastics are known to melt deformed into moldings, e.g. B. after the injection molding or after the extrusion process drive. The different interfacial tensions in the melt lead to that the one thermoplastic in the other spherical to so-called "bubbles" together pulls. There is no penetration of one thermoplastic into the other instead of. This causes the boundary between the two thermoplastics to look like one Hairline cracks. Both thermoplastics only stick together.
Unter geringen Belastungen resp. Dehnungen bricht der Formkörper an den Grenz flächen. Dies gilt insbesondere für Platten, bei denen eine "Blase" in ihrer Ausdehnung die Dicke der Platte erreichen kann.Under low loads resp. The molded article breaks at the limits surfaces. This is especially true for plates that have a "bubble" in their Expansion can reach the thickness of the plate.
Die Lösung der gestellten Aufgabe zur Überwindung dieses physikalischen Hindernis besteht nun darin,The solution of the task to overcome this physical obstacle now consists in
- 1. Die "Blasen"-Bildung des einen Thermoplasten im anderen Thermoplasten zu unter drücken, indem kleinteiligen nicht-thermoplastische Teilchen wie Papier- resp. Vliesschnitzel, kleinteiliges Holz wie Sägespäne oder Holzmehl oder Blähglim mer mit ca. 70 Gew. -% oder mehr, bevorzugt 100 Gew.-% oder mehr der Thermo plastmischung (=100%) zugegeben werden, wobei die nicht-thermoplastischen Teilchen mit ihrer größten Ausdehnung parallel oder im wesentlichen parallel zur Ober fläche der Dreischichtplatte in ungefähr gleichmäßigem Abstand zueinander im Thermoplastgemisch liegen.1. The "bubble" formation of one thermoplastic in the other thermoplastic to under press by small-sized non-thermoplastic particles such as paper resp. Fleece chips, small pieces of wood such as sawdust or wood flour or expanded glass 70% by weight or more, preferably 100% by weight or more of the thermo plast mixture (= 100%) are added, the non-thermoplastic particles with their greatest extent parallel or essentially parallel to the upper surface of the three-layer board at an approximately uniform distance from each other lie in the thermoplastic mixture.
- 2. Die Mittellage beiderseitig mit dehnsteifen dünnen Deckschichten verbunden ist mit einem Verhältnis der Deckschichtdicke zur Dicke der Mittellage zwischen 1 : 4 bis 1 : 20 (je Deckschicht).2. The middle layer is connected on both sides with thin, rigid top layers is between a ratio of the cover layer thickness to the thickness of the middle layer 1: 4 to 1: 20 (per top layer).
Die Zumischung der nicht-thermoplastischen Teilchen zu der Mischung verschieden artiger Thermoplaste bewirkt bei der oben beschriebenen Verteilung, daß statt der "Blasen" nur dünnschichtige Plättchen entstehen können, deren Dicke höchstens dem Abstand der nicht-thermoplastischen Teilchen entsprechen. Dabei haften die Plättchen an den nicht-thermoplastischen Teilchen, die dabei die Grenzflächen der unterschiedlichen Thermoplaste überbrücken. Die Zugfestigkeit richtet sich somit nicht mehr nach der Haftfestigkeit der unterschiedlichen Thermoplaste an einander oder nach der Schwächung des die Matrix bildenden Thermoplasten, sondern nach dem Haftvermögen der Thermoplaste an den nicht-thermoplastischen Teilchen. Evntl. Fehlstellen des Überbrückungsmechanismus können u. U. zu einer Reduktion der Festigkeit führen.The admixture of the non-thermoplastic particles to the mixture is different like thermoplastics causes in the distribution described above that instead the "bubbles" can only form thin-layered platelets, the maximum thickness of which correspond to the distance of the non-thermoplastic particles. The are liable Platelets on the non-thermoplastic particles, making the interfaces bridging the different thermoplastics. The tensile strength depends therefore no longer according to the adhesive strength of the different thermoplastics each other or after the weakening of the thermoplastic forming the matrix, but on the adherence of the thermoplastics to the non-thermoplastic particles. Possibly. Defects in the bridging mechanism can U. to a reduction of strength.
Dies wird jedoch kompensiert durch die zugfesten und dehnsteifen Deckschichten, wie sie z. B. dünne Schichtstoffpreßmassen darstellen. Diese Deckschichten wirken wie Membrane, die von der Mittelschicht auch unter Biege- und Beulbelastung auf Ab stand gehalten werden, wobei die Mittellage die Druckspannungen aufnimmt.However, this is compensated for by the tensile and stretch-resistant cover layers, as they e.g. B. represent thin laminate molding compounds. These cover layers look like Membrane that extends from the middle layer to Ab be maintained, with the middle layer absorbing the compressive stresses.
Der Mittellage können flammhemmende Zusätze etwa auf Bromgrundlage oder Alu hydroxid zugesetzt werden, desgleichen Farbstoffe.The middle layer can contain flame retardant additives such as bromine or aluminum hydroxide are added, as are dyes.
Die Beimischung duroplastischer Teilchen oder Schmutzteilchen, wie es bei der Sammlung von Haushalt-Kunststoffteilen möglich ist, verändern nicht die vorteil haften Eigenschaften der Dreischichtplatte nach der Erfindung. Die Dreischicht platte bleibt steif auch bei dünner Gesamtdicke, die zwischen 1,5 und 20 mm liegt, vorzugsweise zwischen 3 und 12 mm.The admixture of thermosetting particles or dirt particles, as is the case with Collection of household plastic parts is possible, do not change the advantage adhere properties of the three-layer board according to the invention. The three-layer plate remains stiff even with a thin overall thickness that is between 1.5 and 20 mm is preferably between 3 and 12 mm.
Die Wasseraufnahme der Dreischichtplatte liegt unter 1%. Damit eignet sich die Platte vorzüglich für den Möbel- und Hausbau unter feuchten Bedingungen.The water absorption of the three-layer board is less than 1%. This makes the Plate ideal for furniture and house building under damp conditions.
Bei Verwendung von Schichtstoffpreßplatten als Deckschichten läßt sich die Oberfläche durch Lackieren, Prägen und Bedrucken finishieren.When using laminate press plates as cover layers, the Finish the surface by painting, embossing and printing.
Die Verbindung der Deckschichten zur Mittellage erfolgt durch Kleben. Erfahrungs gemäß beträgt der Hauptanteil an Abfall-Thermoplasten Polyethylen. Dieser Thermo plast läßt sich infolge seiner unpolaren Struktur nur nach Vorbehandlung verkle ben. Dies geschieht durch Beflammen der Oberfläche oder durch ionisierende Strah len. Bei der Mittellage nach der Erfindung ist dies nicht erforderlich. Die nicht thermoplastischen Teilchen an der Oberfläche der Mittellage ergeben die erforder liche Haftung.The cover layers are connected to the middle layer by gluing. Experience the majority of waste thermoplastics is polyethylene. This thermo Due to its non-polar structure, plast can only be coated after pretreatment ben. This is done by flaming the surface or by ionizing radiation len. In the middle position according to the invention, this is not necessary. They don't thermoplastic particles on the surface of the middle layer give the required liability.
Bevorzugt werden entweder Kleber auf wässeriger Grundlage oder Klebefilme wegen der einschränken den Arbeitsplatzvorschriften bei Klebern auf Lösungsmittelbasis. Geeignet ist ein konfektionierter Harnstoffharzleim oder Ethylenmischpolymerisat-Klebefolien.Either water-based adhesives or adhesive films are preferred because of the restrictions the workplace regulations for solvent-based adhesives. Suitable is a ready-made urea resin glue or ethylene copolymer adhesive films.
Eine beispielhafte Ausführung zeigen die Fig. 1 und Fig. 2.An exemplary embodiment of Figs. 1 and FIG. 2.
Fig. 1 zeigt einen Schnitt durch einen Teil einer Dreischichtplatte und Fig. 2 zeigt vergrößert einen Teil aus dem Schnitt nach Fig. 1. FIG. 1 shows a section through part of a three-layer plate and FIG. 2 shows an enlarged part of the section according to FIG. 1.
Im einzelnen stellen dar:
1 und 2 die beiden Deckschichten, 3 die Mittellage, 7 den Kleberfilm.In detail:
1 and 2 the two cover layers, 3 the middle layer, 7 the adhesive film.
In Fig. 2: 1 die Deckschicht, 4 einen Thermoplastanteil der Thermoplastmischung und 5 einen zweiten Thermoplasten. 6 zeigt ein von vielen nicht-thermoplastischen Teilen.In Fig. 2: 1 the cover layer, 4 a thermoplastic portion of the thermoplastic mixture and 5 a second thermoplastic. 6 shows one of many non-thermoplastic parts.
Wie bereits erwähnt gibt es Kunststoff-Verbundabfälle, bei denen Thermoplaste mit Alu-Folien verbunden sind. Die Mittellage der Dreischichtplatte kann bis über 40 Gew.-% Alu-Folie enthalten. Dies ergibt Dreischichtplatte, die wegen ihrer hohen Wichte sich für schalldämmende Zwecke eignen. Außerdem fallen solche Platten unter die Brandklasse B2. Solche Platten laden sich elektrisch nicht auf. Bei einem Einsatz im Möbelbau ziehen sie keinen Staub an.As already mentioned, there is plastic composite waste in which thermoplastics are connected with aluminum foils. The middle layer of the three-layer board can contain up to over 40% by weight of aluminum foil. This results in three-layer panels, which are suitable for soundproofing purposes due to their high weight. In addition, such plates are covered by the fire class B2. Such plates do not charge electrically. When used in furniture construction, they do not attract dust.
Unter dehnsteifer Deckschicht werden hier neben der bevorzugten Schichtpreßstoff platte auch Platten aus den Werkstoffen wie Metall, Holz, Papier und faserver stärktem Kunststoff beispielhaft verstanden.In addition to the preferred laminate, a rigid top layer is used here plate also plates made of materials such as metal, wood, paper and fiber strengthened plastic understood as an example.
Claims (24)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19914102115 DE4102115C2 (en) | 1991-01-25 | 1991-01-25 | Three-layer board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19914102115 DE4102115C2 (en) | 1991-01-25 | 1991-01-25 | Three-layer board |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE4102115A1 true DE4102115A1 (en) | 1992-08-06 |
| DE4102115C2 DE4102115C2 (en) | 1996-01-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19914102115 Expired - Fee Related DE4102115C2 (en) | 1991-01-25 | 1991-01-25 | Three-layer board |
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| Country | Link |
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| DE (1) | DE4102115C2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4226837A1 (en) * | 1992-04-22 | 1994-02-17 | Schnause Rolf Dipl Ing | Cooling sheet of extruded thermoplastic and paper waste - uses endless steel band to support sheet while cooling |
| DE4228409A1 (en) * | 1992-08-26 | 1994-03-03 | Messing Oliver | Plate for panelling, sepn. or support purposes - has with its core of waste material a cpd. comprising thin layered metal and plastic material. |
| DE4231097A1 (en) * | 1992-09-17 | 1994-03-24 | Evd Gmbh | Process for producing a composite particle body and the body produced according to this |
| DE4333187A1 (en) * | 1993-05-25 | 1995-02-09 | Tesch G H | Moulding with a web containing paper |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2314146A1 (en) * | 1972-03-23 | 1973-10-04 | Mitsubishi Petrochemical Co | PROCESS FOR EXTRUDING THERMOPLASTIC PLASTIC WITH A HIGH FILL MATERIAL CONTENT |
| DE2340505A1 (en) * | 1973-08-10 | 1975-02-20 | Regal Packaging Ltd | Flat plastic products from thermoplastic scrap - by heating-pressing mat formed from granulated raw material |
| DE7440735U (en) * | 1974-12-06 | 1975-10-30 | Lesti Klaus | PreBstoffplatte |
| AT327519B (en) * | 1972-02-14 | 1976-02-10 | Rhenodur Gmbh | METHOD FOR MANUFACTURING COMPRESSED PLATES OR MOLDED BODIES |
| DE2402976B2 (en) * | 1974-01-22 | 1977-12-29 | Ets. Paturle S.A, St-Laurent-du-Pont (Frankreich) | CONSTRUCTION MATERIAL AND METHOD FOR ITS MANUFACTURING |
| US4250222A (en) * | 1974-12-31 | 1981-02-10 | Institut National De Recherche Chimique Appliquee | Process for manufacturing finished and semi-finished products from mixtures of various synthetic resin scrap materials |
| DE3242120A1 (en) * | 1981-11-19 | 1983-07-21 | Artiaga Rodriguez, Maria-Soledad, Madrid | Process for the production of articles or objects |
| DE3837125A1 (en) * | 1988-11-02 | 1990-05-03 | Signode System Gmbh | Process for the production of mouldings from metal and a thermoplastic |
-
1991
- 1991-01-25 DE DE19914102115 patent/DE4102115C2/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT327519B (en) * | 1972-02-14 | 1976-02-10 | Rhenodur Gmbh | METHOD FOR MANUFACTURING COMPRESSED PLATES OR MOLDED BODIES |
| DE2314146A1 (en) * | 1972-03-23 | 1973-10-04 | Mitsubishi Petrochemical Co | PROCESS FOR EXTRUDING THERMOPLASTIC PLASTIC WITH A HIGH FILL MATERIAL CONTENT |
| DE2340505A1 (en) * | 1973-08-10 | 1975-02-20 | Regal Packaging Ltd | Flat plastic products from thermoplastic scrap - by heating-pressing mat formed from granulated raw material |
| DE2402976B2 (en) * | 1974-01-22 | 1977-12-29 | Ets. Paturle S.A, St-Laurent-du-Pont (Frankreich) | CONSTRUCTION MATERIAL AND METHOD FOR ITS MANUFACTURING |
| DE7440735U (en) * | 1974-12-06 | 1975-10-30 | Lesti Klaus | PreBstoffplatte |
| US4250222A (en) * | 1974-12-31 | 1981-02-10 | Institut National De Recherche Chimique Appliquee | Process for manufacturing finished and semi-finished products from mixtures of various synthetic resin scrap materials |
| DE3242120A1 (en) * | 1981-11-19 | 1983-07-21 | Artiaga Rodriguez, Maria-Soledad, Madrid | Process for the production of articles or objects |
| DE3837125A1 (en) * | 1988-11-02 | 1990-05-03 | Signode System Gmbh | Process for the production of mouldings from metal and a thermoplastic |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4226837A1 (en) * | 1992-04-22 | 1994-02-17 | Schnause Rolf Dipl Ing | Cooling sheet of extruded thermoplastic and paper waste - uses endless steel band to support sheet while cooling |
| DE4228409A1 (en) * | 1992-08-26 | 1994-03-03 | Messing Oliver | Plate for panelling, sepn. or support purposes - has with its core of waste material a cpd. comprising thin layered metal and plastic material. |
| DE4231097A1 (en) * | 1992-09-17 | 1994-03-24 | Evd Gmbh | Process for producing a composite particle body and the body produced according to this |
| DE4333187A1 (en) * | 1993-05-25 | 1995-02-09 | Tesch G H | Moulding with a web containing paper |
Also Published As
| Publication number | Publication date |
|---|---|
| DE4102115C2 (en) | 1996-01-11 |
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