DE279306C - - Google Patents
Info
- Publication number
- DE279306C DE279306C DENDAT279306D DE279306DA DE279306C DE 279306 C DE279306 C DE 279306C DE NDAT279306 D DENDAT279306 D DE NDAT279306D DE 279306D A DE279306D A DE 279306DA DE 279306 C DE279306 C DE 279306C
- Authority
- DE
- Germany
- Prior art keywords
- aniline
- react
- detergents
- product
- perphosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000344 soap Substances 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 6
- 239000003599 detergent Substances 0.000 claims description 5
- 125000005342 perphosphate group Chemical group 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims 2
- 229920000767 polyaniline Polymers 0.000 claims 2
- KJFMBFZCATUALV-UHFFFAOYSA-N Phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 claims 1
- 230000001476 alcoholic Effects 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 150000004965 peroxy acids Chemical class 0.000 claims 1
- RLOWWWKZYUNIDI-UHFFFAOYSA-N phosphinic chloride Chemical compound ClP=O RLOWWWKZYUNIDI-UHFFFAOYSA-N 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000011780 sodium chloride Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 239000000843 powder Substances 0.000 description 6
- 229910018663 Mn O Inorganic materials 0.000 description 4
- 239000011521 glass Substances 0.000 description 3
- XHXFXVLFKHQFAL-UHFFFAOYSA-N Phosphoryl chloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 2
- JBUKJLNBQDQXLI-UHFFFAOYSA-N Sodium perborate Chemical compound [Na+].[Na+].O[B-]1(O)OO[B-](O)(O)OO1 JBUKJLNBQDQXLI-UHFFFAOYSA-N 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 229960001922 sodium perborate Drugs 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N Sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- PNIJRIIGBGFYHF-UHFFFAOYSA-N perborate(2-) Chemical compound O[B-]1(O)OO[B-](O)(O)OO1 PNIJRIIGBGFYHF-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/42—Per-compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
■- JVr 279306-KLASSE Si. GRUPPE■ - JVr 279306-CLASS Si. GROUP
HUGO SIEBOLD in LINDENBERG, Algäu.HUGO SIEBOLD in LINDENBERG, Algäu.
Verfahren zur Herstellung haltbarer Sauerstoff-Waschmittel,Process for making durable oxygen detergents,
Sauerstoff-Waschmittel werden heute durch Mischen von Natriumperborat oder Natriumsuperoxyd mit Seifenpulver gewonnen.Oxygen detergents are now made by mixing sodium perborate or sodium peroxide obtained with soap powder.
Es wurde nun gefunden, daß man durch das Zusammenbringen von Perphosphat und Seifenpulver ein Waschmittel erhält, welches die vorzüglichen Eigenschaften besitzt, kräftig reinigend zu wirken und den aktiven Sauerstoff rationell auszunutzen. Besonders in der Wärme ist diese Mischung gegenüber einer Perborat-Mischung haltbarer.It has now been found that by bringing together perphosphate and Soap powder contains a detergent that has excellent properties to have a cleansing effect and to make efficient use of the active oxygen. Especially in the This mixture is more durable than a perborate mixture.
Vergleichsversuche ergaben folgendes Resultat :Comparative tests gave the following result:
Nr. i. 4 g Natriumperphosphat (Na4P2O8) und 6 g trockenes Seifenpulver wurden in 300 ecm Wasser gelöst.No. i. 4 g of sodium perphosphate (Na 4 P 2 O 8 ) and 6 g of dry soap powder were dissolved in 300 ecm of water.
Nr. 2. 4 g Natriumperborat und 6 g trockenes Seifenpulver wurden in 300 ecm Wasser gelöst.No. 2. 4 g of sodium perborate and 6 g of dry soap powder were dissolved in 300 ecm of water.
Nr. 2No. ι
No. 2
9,0 ecm K Mn O4-Lösung7, o ecm K Mn O 4 solution
9.0 ecm K Mn O 4 solution
0,5 ecm K Mn O4-Lösung6, o ecm K Mn O 4 solution
0.5 ecm K Mn O 4 solution
94,4 Prozent.14.2 percent
94.4 percent.
io kg Perphosphat werden mit 40 kg trockenem Seifenpulver gut vermischt.10 kg of perphosphate are combined with 40 kg of dry Soap powder mixed well.
10 kg Perphosphat, 2x/2 kg Borax, 2x/2 kg Natriumsilicat, pulverisiert, und 35 kg trockenes Seifenpulver werden gut gemischt.10 kg perphosphate, 2 x / 2 kg borax, 2 x / 2 kg sodium silicate, powdered, and 35 kg dry soap powder are mixed well.
Die Herstellung des in Betracht kommenden Perphosphates wurde wie folgt vorgenommen :The preparation of the perphosphate in question was carried out as follows :
30 g Phosphoroxychlorid (P O Cl3) werden in einen Glaskolben gebracht, welcher mit Eiswasser gekühlt wird. Als Verschluß besitzt dieser Kolben einen Stöpsel, welcher zwei Bohrungen enthält. Durch die eine Bohrung ist ein Trichter gesteckt, welcher mit Glashahn versehen ist und zur Aufnahme von H2O2 dient, und durch die andere geht ein Glasrohr, welches mit dem Vakuum verbunden ist, um die sich im Kolben entwickelnden Dämpfe abzusaugen. Im Trichter werden 11 g H2 O2 31 prozentig abgewogen, welche tropfweise dem P O Cl3 zugelassen werden. Während dieser Operation muß der Kolbeninhalt vorsichtig etwas durchgemischt werden und man muß darauf achten, daß das Vakuum gut funktioniert, damit die Chlorwasserstoffdämpfe gut abgezogen werden. 30 g of phosphorus oxychloride (PO Cl 3 ) are placed in a glass flask which is cooled with ice water. As a closure, this piston has a stopper which contains two bores. A funnel, which is provided with a glass tap and serves to take up H 2 O 2, is inserted through one hole, and a glass tube goes through the other, which is connected to the vacuum in order to suck off the vapors developing in the flask. In the funnel, 11 g of H 2 O 2 31 percent are weighed out, which are admitted drop by drop to the PO Cl 3 . During this operation, the contents of the flask must be carefully mixed a little and one must ensure that the vacuum works properly so that the hydrogen chloride vapors are drawn off properly.
Claims (1)
H2 O2 + 4H2 0 + 2P 0 Cl3 = H4 P2 O8 + 6H Cl.or
H 2 O 2 + 4H 2 0 + 2P 0 Cl 3 = H 4 P 2 O 8 + 6H Cl.
oder Na P O3 + H2 O2 Na 4 P 2 O 7 + H 2 O 2 , Na 2 HPO 4 + H 2 O 2
or Na PO 3 + H 2 O 2
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE279306C true DE279306C (en) |
Family
ID=535234
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT279306D Active DE279306C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE279306C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE943076C (en) * | 1933-12-09 | 1956-05-09 | Henkel & Cie Gmbh | Detergents and cleaning agents |
-
0
- DE DENDAT279306D patent/DE279306C/de active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE943076C (en) * | 1933-12-09 | 1956-05-09 | Henkel & Cie Gmbh | Detergents and cleaning agents |
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