DE273877C - - Google Patents
Info
- Publication number
- DE273877C DE273877C DENDAT273877D DE273877DA DE273877C DE 273877 C DE273877 C DE 273877C DE NDAT273877 D DENDAT273877 D DE NDAT273877D DE 273877D A DE273877D A DE 273877DA DE 273877 C DE273877 C DE 273877C
- Authority
- DE
- Germany
- Prior art keywords
- mortar
- barium
- sand
- lime
- fluoride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- OYLGJCQECKOTOL-UHFFFAOYSA-L Barium fluoride Chemical compound [F-].[F-].[Ba+2] OYLGJCQECKOTOL-UHFFFAOYSA-L 0.000 claims description 7
- 229910001632 barium fluoride Inorganic materials 0.000 claims description 7
- 239000004576 sand Substances 0.000 claims description 7
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 6
- 235000015450 Tilia cordata Nutrition 0.000 claims description 6
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 6
- 239000004571 lime Substances 0.000 claims description 6
- 159000000009 barium salts Chemical class 0.000 claims description 2
- 239000011429 hydraulic mortar Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000004570 mortar (masonry) Substances 0.000 description 8
- KRHYYFGTRYWZRS-UHFFFAOYSA-N HF Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 150000002222 fluorine compounds Chemical class 0.000 description 3
- TZCXTZWJZNENPQ-UHFFFAOYSA-L Barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000002969 artificial stone Substances 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 208000010201 Exanthema Diseases 0.000 description 1
- 206010037844 Rash Diseases 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 150000001553 barium compounds Chemical class 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium(0) Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 201000005884 exanthem Diseases 0.000 description 1
- 230000002349 favourable Effects 0.000 description 1
- 239000011440 grout Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/08—Acids or salts thereof
- C04B22/12—Acids or salts thereof containing halogen in the anion
- C04B22/126—Fluorine compounds, e.g. silico-fluorine compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2/00—Lime, magnesia or dolomite
- C04B2/02—Lime
- C04B2/04—Slaking
- C04B2/06—Slaking with addition of substances, e.g. hydrophobic agents ; Slaking in the presence of other compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
Um die Entstehung von Ausschlägen bei Mörteln zu verhindern, benutzt der Erfinder Bariumfluorid in der Weise, daß der Kalk mit Sand und Bariumfluorid zusammen in der Wärme gelöscht wird. Dadurch wird nicht nur erreicht, daß die in den Bestandteilen des Mör- \ tels (Kalk, Sand, Gesteinsbrocken, Wasser) vor- ; handenen sowie die aus dem Mauerwerk in den Fugenmörtel oder den Putz dringenden ίο löslichen schwefelsäuren Salze unschädlich gemacht werden, sondern es wird auch der Sand geätzt und Kieselsäure aufgeschlossen.In order to prevent the development of rashes in mortars, the inventor uses barium fluoride in such a way that the lime is slaked together with sand and barium fluoride in the heat. This not only ensures that the in the components of the mortar \ tels (lime, sand, rocks, water) forward; Existing as well as the ίο soluble sulfuric acid salts that penetrate the grout or plaster from the masonry are rendered harmless, but the sand is also etched and silica is digested.
Um in hydraulischen Mörtelbildnern die Sulfate zu binden, hat man zwar schon vorgcschlagen, Bariumsalz, jedoch nicht Fluorid, einfach zuzumischen. Ein günstiger Einfluß der Barium verbindung im Sinne einer besseren Aufschließung, wie er bei vorliegender Zusammenlöschung in der Wärme eintritt, war dabei ausgeschlossen.In order to bind the sulfates in hydraulic mortar formers, it has already been suggested that Simply add barium salt, but not fluoride. A favorable influence the barium compound in the sense of a better unlocking, as it is with the present extinction occurs in the heat, was excluded.
Einzelne Fluorverbindungen sind auch mit anderem Zweck unter anderen Verhältnissen
in Mörtelbildnern und Kunststeinmassen ein-, geführt worden. Lösliche Fluoride sollten die
25] Abbindezeit regeln, Kieselfluorwasserstoffsäure eine Kittung erzeugen, andere lösliche Fluoride
eine Vorätzung eines Teiles der Kunststeinmasse bewirken. Den Wert des Bariumfluorides
hat man aber bisher noch nicht erkannt.
Die Bereitung des Mörtels nach der Erfindung geschieht durch Löschen des Kalkes in
Gegenwart des Sandes und des Bariumfluorides. Diesen in der Wärme, in einer Dampfatmosphäre,
verlaufenden Prozeß macht also das Bariumfluorid mit durch. Es werden in einer der üblichen, zum Zusammenhalten der Löschenergie
ganz oder teilweise geschlossenen Löschvorrichtungen für Mörtel Sand, Kalk, Wasser
und Bariumfluorid zusammen eingegeben.Individual fluorine compounds have also been introduced into mortar formers and artificial stone masses for a different purpose under different conditions. Soluble fluorides should regulate the setting time, hydrofluoric acid should produce a cement, other soluble fluorides should pre-etch part of the artificial stone mass. The value of barium fluoride has not yet been recognized.
The mortar according to the invention is prepared by slaking the lime in the presence of sand and barium fluoride. The barium fluoride also goes through this process, which takes place in the warmth, in a steam atmosphere. Sand, lime, water and barium fluoride are put together in one of the usual extinguishing devices for mortar that are completely or partially closed to hold the extinguishing energy together.
In der feuchten Wärme zersetzt sich das Fluorid teilweise und spaltet Flußsäure ab, durch die der Sand geätzt und Kieselsäure aufgeschlossen wird. Dadurch gewinnt der Mörtel hydraulische Eigenschaften. Gleichzeitig wird die vorhandene Schwefelsäure in Bariumsulfat verwandelt. Der Kalk macht das Barium leicht reaktionsfähig, und infolgedessen liegt dieses im fertigen Mörtel in einer Form vor, daß es sich unmittelbar mit herantretenden Sulfaten umsetzt.In the moist heat, the fluoride partially decomposes and splits off hydrofluoric acid, through which the sand is etched and silica is broken down. This wins the Mortar hydraulic properties. At the same time, the existing sulfuric acid is in Transformed barium sulfate. The lime makes the barium easily reactive, and consequently this is in the finished mortar in a form that it is directly with the approaching Converts sulfates.
Es ergibt sich also ein ausschlagfreier Mörtel mit gesteigerter Abbindungs- und Erhärtungsfähigkeit. The result is a rash-free mortar with increased setting and hardening properties.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE273877C true DE273877C (en) |
Family
ID=530294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT273877D Active DE273877C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE273877C (en) |
-
0
- DE DENDAT273877D patent/DE273877C/de active Active
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