DE242571C - - Google Patents
Info
- Publication number
- DE242571C DE242571C DENDAT242571D DE242571DA DE242571C DE 242571 C DE242571 C DE 242571C DE NDAT242571 D DENDAT242571 D DE NDAT242571D DE 242571D A DE242571D A DE 242571DA DE 242571 C DE242571 C DE 242571C
- Authority
- DE
- Germany
- Prior art keywords
- mercury
- acid
- compounds
- oxide
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002253 acid Substances 0.000 claims description 10
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 7
- 229910052753 mercury Inorganic materials 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 4
- HIJSSUKZLPXDPU-UHFFFAOYSA-L mercury(2+);carbonate Chemical compound [Hg+2].[O-]C([O-])=O HIJSSUKZLPXDPU-UHFFFAOYSA-L 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 2
- 150000002731 mercury compounds Chemical class 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 description 6
- 229910000474 mercury oxide Inorganic materials 0.000 description 6
- UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical compound [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- -1 amide mercury compounds Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 2
- DCXYFEDJOCDNAF-UHFFFAOYSA-N Asparagine Natural products OC(=O)C(N)CC(N)=O DCXYFEDJOCDNAF-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- DCXYFEDJOCDNAF-REOHCLBHSA-N L-asparagine Chemical compound OC(=O)[C@@H](N)CC(N)=O DCXYFEDJOCDNAF-REOHCLBHSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- ZGSDJMADBJCNPN-UHFFFAOYSA-N [S-][NH3+] Chemical compound [S-][NH3+] ZGSDJMADBJCNPN-UHFFFAOYSA-N 0.000 description 1
- 229960001230 asparagine Drugs 0.000 description 1
- 235000009582 asparagine Nutrition 0.000 description 1
- 150000003857 carboxamides Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000009938 salting Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical compound NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/10—Mercury compounds
- C07F3/103—Mercury compounds without C-Mercury linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
Die bisher dargestellten Amidquecksilberverbindungen, wie z. B. das Formamid- oder das Asparaginquecksilber, gehören ausschließlich der Gruppe der Carbonsäureamide an.The amide mercury compounds shown so far, such as. B. the formamide or asparagine mercury belong exclusively to the group of carboxamides.
Nicht bekannt jedoch sind Verbindungen, in denen SulfamidwasserstofE durch Quecksilber ersetzt ist. Es wurde nun gefunden, daß man durch Einwirkung von sulfamidbenzoesäuren Salzen auf Quecksilberoxyd oder Quecksilbercarbonat technisch wertvolle Quecksilberverbindungen von großer Desinfektionskraft erhalten kann, die schwach basisch reagieren und sich durch außerordentlich größe Löslichkeit in kaltem Wasser auszeichnen.Not known, however, are compounds in which sulfamide hydrogen is replaced by mercury is replaced. It has now been found that the action of sulfamidobenzoic acids Salts on mercury oxide or mercury carbonate technically valuable mercury compounds of great disinfectant power, which have a weakly basic reaction and are characterized by extremely high solubility Mark in cold water.
. Von den drei möglichen isomeren sulfamidbenzoesäuren Salzen ist besonders das ortho- und das meta-sulfarnidbenzoesaure Salz in hohem Maße wasserlöslich, während das Salz der para-Säure wohl ebenfalls die Verbindung mit Quecksilberoxyd eingeht, jedoch bereits in der Kälte unter Abscheidung quecksilberhaltiger Niederschläge sich zersetzt. Dagegen ist ein Gehalt von para-Säure in der ortho-Säure nicht von schädlichem Einfluß, so daß auch Gemische von ortho- und para-Verbindungen in dem Verhältnis, wie- sie bei der Einwirkung von Chlorsulfonsäure auf Toluol und nachfolgender Oxydation des aus dem Sulfochlorid dargestellten Aniids entstehen, mit Quecksilberoxyd die leichtlösliche Verbindung liefern.. Of the three possible isomeric sulfamidobenzoic acids Salting is especially the ortho- and the meta-sulfarnidbenzoic acid salt in highly soluble in water, while the salt of the para-acid is probably also the compound with mercury oxide, but already in the cold with the separation of mercury-containing Precipitation decomposes. In contrast, there is a content of para acid in the ortho acid not of harmful influence, so that also mixtures of ortho and para compounds in the same proportion as when chlorosulphonic acid acts on toluene and subsequent oxidation of the aniide produced from the sulfochloride, provide the easily soluble compound with mercury oxide.
Die Lösungen der neuen Verbindungen fällen Eiweiß nicht und scheiden nur langsam auf Metallen Quecksilber ab. Durch Schwefelammonium wird in der Kälte Quecksilber-40 The solutions of the new compounds do not precipitate protein and only slowly deposit mercury on metals. In the cold, ammonium sulphide turns mercury into 40
sulfid gefällt. Die Salze, die in Alkohol und Äther unlöslich sind, entsprechen der"Zusammensetzung: sulfide like. The salts found in alcohol and Ethers are insoluble, correspond to the "composition:
C6 O4 COO . Me . SO2 NH- Hg - OH. C 6 O 4 COO . Me. SO 2 NH-Hg-OH.
Als Beispiel sei die Darstellung des oxyquecksilber - ο - sulfamidbenzoesäuren Natriums angeführt:An example is the representation of the oxymercury - ο - sulfamidbenzoic acid sodium listed:
30 Teile ο - Sulfamidbenzoesäure werden in 20Q Teilen Wasser gelöst und durch 12,5 Teile Natriumbicarbonat genau neutralisiert. Sodann werden bei Zimmertemperatur 34 Teile Quecksilberoxyd eingetragen und die Lösung zum Schluß noch einige Zeit auf etwa 80 °. erwärmt. Man läßt das überschüssige Quecksilberoxyd absetzen und filtriert die dekantierte Flüssigkeit. Die so erhaltene Lösung wird zur Trockne eingedampft, zweckmäßig im Vakuum. Man kann die Verbindung aus der Lösung auch durch Alkohol fällen. Die Analyse ergab als Durchschnittswert einen Quecksilbergehalt von 45,71 Prozent.30 parts of ο - sulfamidobenzoic acid are dissolved in 20Q parts of water and by 12.5 parts Sodium bicarbonate exactly neutralized. Then it becomes 34 parts at room temperature Mercury oxide entered and the solution at the end for some time at about 80 °. warmed up. The excess mercury oxide is allowed to settle and the decanted one is filtered Liquid. The solution thus obtained is evaporated to dryness, expediently in Vacuum. The compound can also be precipitated from the solution with alcohol. The analysis resulted in an average mercury content of 45.71 percent.
An Stelle von Quecksilberoxyd kann man auch Quecksilbercarbonat anwenden.Mercury carbonate can also be used in place of mercury oxide.
In analoger Weise wird die m-Verbindung dargestellt.The m-connection shown.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE242571C true DE242571C (en) |
Family
ID=501765
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT242571D Active DE242571C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE242571C (en) |
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0
- DE DENDAT242571D patent/DE242571C/de active Active
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