DE204906C - - Google Patents
Info
- Publication number
- DE204906C DE204906C DENDAT204906D DE204906DA DE204906C DE 204906 C DE204906 C DE 204906C DE NDAT204906 D DENDAT204906 D DE NDAT204906D DE 204906D A DE204906D A DE 204906DA DE 204906 C DE204906 C DE 204906C
- Authority
- DE
- Germany
- Prior art keywords
- alkali salts
- mineral oils
- acids
- boiling
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002480 mineral oil Substances 0.000 claims description 12
- 150000001447 alkali salts Chemical class 0.000 claims description 11
- 238000009835 boiling Methods 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 6
- 150000007513 acids Chemical class 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- 239000000314 lubricant Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000004006 olive oil Substances 0.000 claims description 4
- 235000008390 olive oil Nutrition 0.000 claims description 4
- 239000003208 petroleum Substances 0.000 claims description 4
- 239000004359 castor oil Substances 0.000 claims description 3
- 235000019438 castor oil Nutrition 0.000 claims description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 3
- 230000003449 preventive effect Effects 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 241001133760 Acoelorraphe Species 0.000 claims description 2
- 244000025254 Cannabis sativa Species 0.000 claims description 2
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims description 2
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 244000000231 Sesamum indicum Species 0.000 claims description 2
- 235000003434 Sesamum indicum Nutrition 0.000 claims description 2
- 235000009120 camo Nutrition 0.000 claims description 2
- 235000005607 chanvre indien Nutrition 0.000 claims description 2
- 235000012343 cottonseed oil Nutrition 0.000 claims description 2
- 239000011487 hemp Substances 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 235000016068 Berberis vulgaris Nutrition 0.000 claims 1
- 241000335053 Beta vulgaris Species 0.000 claims 1
- 239000003513 alkali Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- REZQBEBOWJAQKS-UHFFFAOYSA-N triacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO REZQBEBOWJAQKS-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- 241000182341 Cubitermes group Species 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/20—Rosin acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Lubricants (AREA)
Description
DEUTSCHES REICHGERMAN EMPIRE
REICHSPATENTAMTREICH PATENT OFFICE
PATENTSCHRIFTPATENT LETTERING
- M 204906 KLASSE 23 c. GRUPPE- M 204906 CLASS 23 c. GROUP
Zusatz zum Patente 174906 vom 5. Januar 1905.Addendum to patent 174906 from January 5, 1905.
Patentiert Im Deutschen Reiche vom 4. April 1906 ab. Längste Dauer: 4. Januar 1920.Patented in the German Empire on April 4, 1906. Longest duration: January 4, 1920.
Gegenstand des Patentes 174906 ist ein Verfahren zur Herstellung eines Rostschutz- und Schmiermittels, das darin besteht, daß schwere Mineralöle mit Hilfe von ölsaurem Alkali und hoch siedenden Alkoholen emulgiert werden.The subject of patent 174906 is a method for producing a rust protection and Lubricant, which consists in making heavy mineral oils with the help of oleic alkali and high boiling alcohols are emulsified.
Es ist nun festgestellt worden, daß es auch mit Hilfe der Alkalisalze' der Fettsäuren, insbesondere der Ricinusölsäuren, gelingt, Mineralöle zu emulgieren und ein sehr brauchbares Rostschutz- oder Schmiermittel zu erhalten, und zwar gelingt es mit den Alkalisalzen der genannten Fettsäuren auch, die niedriger siedenden Mineralöle zu emulgieren. Es können demnach bei dem vorliegenden Verfahren alle Mineralöle vom Brennpetroleum einschließlich ab bis zu denen vom höchsten spezifischen Gewicht zur Herstellung des flüssigen Rostschutzmittels angewendet werden, was einen erheblichen Vorteil darstellt.It has now been found that it is also with the help of the alkali salts' of fatty acids, in particular of castor oil acids, succeeds in emulsifying mineral oils and is a very useful one To obtain rust preventive or lubricant, and it succeeds with the alkali salts of also called fatty acids to emulsify the lower-boiling mineral oils. It can accordingly, in the present process, all mineral oils from kerosene including up to those of the highest specific weight are used for the production of the liquid rust preventive, what represents a significant advantage.
ao Als Alkalisalze der Fettsäuren, die zur Herstellung der Emulsion dienen, kommen diejenigen in Betracht, die aus dem Ricinusöl und den Derivaten desselben sowie dem Hanf-, Palm-,Rüb-, Baumwollsamen-, Sesam-, Olivenölao As the alkali salts of the fatty acids that are used to produce the emulsion, there are those into consideration, those from the castor oil and its derivatives as well as the hemp, Palm, rapeseed, cottonseed, sesame, olive oil
*5 sowie aus den Harzsäuren durch Behandlung mit Alkali gewonnen werden. Das Olivenöl enthält neben etwa 66 Prozent ölsäuretriglycerid etwa 6 Prozent Lmolsäuretriglycerid und etwa 28 Prozent feste* Glyceride, unter denen das der Palmitinsäure vorherrscht. Das aus dem Olivenöl durch Alkali erhaltene Alkalisalz organischer Säuren eignet sich für die Emulgierung niedrig siedender Mineralöle.* 5 as well as from the resin acids by treatment can be obtained with alkali. The olive oil contains about 66 percent oleic acid triglyceride about 6 percent lmolic acid triglyceride and about 28 percent solid * glycerides, below where that of palmitic acid predominates. That obtained from the olive oil by alkali The alkali salt of organic acids is suitable for emulsifying low-boiling mineral oils.
3535
4040
Dagegen sind die Alkalisalze der reinen ölsäure für die Emulgierung von spezifisch leichten Fraktionen der Mineralöle, wie z. B. der Brennpetrole, ausgeschlossen, dagegen können sie als Zusätze zu den genannten harz- und fettsauren Alkalien für spezifisch schwerere Fraktionen verwendet werden.In contrast, the alkali salts of pure oleic acid are used for the emulsification of specifically light ones Fractions of mineral oils, such as. B. the fuel gun, excluded, however, can they are used as additives to the aforementioned resinous and fatty acid alkalis for specifically heavier ones Fractions are used.
Der Zusatz der hoch siedenden Alkohole kann in jedem Stadium der Mischung der genannten fetten öle, der Alkalien und der Mineralöle erfolgen, am besten werden sie aber in den Alkalisalzen der genannten Sauren gelöst. Die Lösung erfolgt unter geringem oder stärkerem Erwärmen, bis etwa 80" C, am Rückflußkühler unter Ersatz der verdampften Gewichtsteile der Alkohole oder unter Druck.The high-boiling alcohols can be added at any stage of the mixture of the fatty oils mentioned, the alkalis and the mineral oils, but it is best to dissolve them in the alkali salts of the acids mentioned. The solution is performed under low or greater heating to about 80 "C, under reflux, with the replacement of the evaporated parts by weight of the alcohols or under pressure.
Das Mengenverhältnis des Gesamtzusatzes von hoch siedendem Alkohol und der genannten Alkalisalze zu den Mineralölen beträgt bei Brennpetroleum etwa 2o-Prozent des Gesamtgewichtes und geht bei den spezifisch schwereren Fraktionen bis auf etwa 15 Prozent herab. Der Prozentsatz der hoch siedenden Alkohole zu den Alkalisalzen der organischen Säuren beträgt je nach dem spezifischen Gewicht der Mineralöle zwischen 25 und 35 Prozent ihrer Mischung miteinander, wobei der Zusatz mit dem spezifischen Gewicht der Mineralöle sich steigert.The ratio of the total addition of high-boiling alcohol and the above Alkali salts to the mineral oils make up about 2o percent of the total weight of kerosene and goes down to about 15 percent in the specifically heavier fractions. The percentage of high boiling alcohols to the alkali salts of organic acids depending on the specific weight of the mineral oils is between 25 and 35 percent of their Mixing with each other, the additive with the specific gravity of the mineral oils increases.
Es ist bereits bekannt (Verfahren von Li ν ac he), daß man Seife mit Hilfe von Myricyllalkohol, Holzgeist oder Amylalkohol Petroleum einverleiben kann. Es handelt sichIt is already known (method of Li ν ac he) that you can soap with the help of Myricyl alcohol, wood spirit or amyl alcohol can incorporate petroleum. It is about
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE204906T |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE204906C true DE204906C (en) |
Family
ID=5784342
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT174906D Active DE174906C (en) | |||
| DENDAT204906D Active DE204906C (en) |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT174906D Active DE174906C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (2) | DE204906C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3627508C1 (en) * | 1986-08-13 | 1987-10-22 | Sachsenwerk Ag | Clamping device for the energy storage of an electrical switch |
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0
- DE DENDAT174906D patent/DE174906C/de active Active
- DE DENDAT204906D patent/DE204906C/de active Active
Also Published As
| Publication number | Publication date |
|---|---|
| DE174906C (en) |
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