DE1242298B - Tragplatte fuer ein Sperrschichtelektrodensystem, das einen halbleitenden Einkristall aus Germanium oder Silizium enthaelt - Google Patents
Tragplatte fuer ein Sperrschichtelektrodensystem, das einen halbleitenden Einkristall aus Germanium oder Silizium enthaeltInfo
- Publication number
- DE1242298B DE1242298B DEN27010A DEN0027010A DE1242298B DE 1242298 B DE1242298 B DE 1242298B DE N27010 A DEN27010 A DE N27010A DE N0027010 A DEN0027010 A DE N0027010A DE 1242298 B DE1242298 B DE 1242298B
- Authority
- DE
- Germany
- Prior art keywords
- support plate
- single crystal
- germanium
- electrode system
- barrier electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000013078 crystal Substances 0.000 title claims description 10
- 229910052732 germanium Inorganic materials 0.000 title claims description 8
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 title claims description 8
- 230000004888 barrier function Effects 0.000 title claims description 7
- 229910052710 silicon Inorganic materials 0.000 title claims description 5
- 239000010703 silicon Substances 0.000 title claims description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 239000010937 tungsten Substances 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229910000679 solder Inorganic materials 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 239000004065 semiconductor Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000005476 soldering Methods 0.000 description 2
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- KGWWEXORQXHJJQ-UHFFFAOYSA-N [Fe].[Co].[Ni] Chemical compound [Fe].[Co].[Ni] KGWWEXORQXHJJQ-UHFFFAOYSA-N 0.000 description 1
- 239000000370 acceptor Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L24/00—Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
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- H01L24/26—Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
- H01L24/31—Structure, shape, material or disposition of the layer connectors after the connecting process
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
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- H01L23/488—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor consisting of soldered or bonded constructions
- H01L23/492—Bases or plates or solder therefor
- H01L23/4924—Bases or plates or solder therefor characterised by the materials
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- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
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- H01L2224/8319—Arrangement of the layer connectors prior to mounting
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Landscapes
- Engineering & Computer Science (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Electrodes Of Semiconductors (AREA)
- Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
- Die Bonding (AREA)
Description
BUNDESREPUBLIK DEUTSCHLAND
DEUTSCHES
PATENTAMT
AUSLEGESCHRIFT
Int. Cl.:
HOIl
Deutsche Kl.: 21 g -11/02
Nummer: 1242 298
Aktenzeichen: N 27010 VIII c/21 g
Anmeldetag: 28. Juni 1955
Auslegetag: 15. Juni 1967
Die Erfindung bezieht sich auf ein Sperrschichtelektrodensystem, das einen halbleitenden Einkristall
aus Germanium oder Silizium enthält, insbesondere Kristalldiode oder Transistor, wobei der halbleitende
Einkristall auf einer Wärme ableitenden Tragplatte festgelötet ist.
Es ist bekannt, daß bei solchen Systemen die Gefahr eines Bruches im Halbleiterkörper besteht,
unter anderem infolge seiner Sprödigkeit und seines abweichenden Ausdehnungskoeffizienten gegenüber
dem Material der Tragplatte. Man hat daher einen Einkristall aus Germanium auf einer Tragplatte befestigt,
die aus einer Legierung von 54 % Eisen, 29 % Nickel und 17% Kobalt besteht. Der lineare Ausdehnungskoeffizient
dieser Legierung beträgt 4 · 10~6 im harten Zustand und 6 · 10~6 im ausgeglühten Zustand.
Diese Werte nähern sich daher demjenigen für Germanium. So läßt sich im allgemeinen bei einem
bestimmten Halbleiter ein Metall oder eine Legierung mit einem angemessenen Ausdehnungskoeffizienten
für die Tragplatte wählen. An das Material für eine Tragplatte können aber noch weitere Anforderungen
gestellt werden. Zur Erzielung einer guten Kühlung ist eine hohe Wärmeleitfähigkeit erwünscht. Das
Material muß weiterhin gegen die Ätzflüssigkeiten in für praktische Zwecke ausreichendem Maß beständig
sein, durch die der halbleitende Körper nach dem Löten gewöhnlich gereinigt wird. Außerdem darf das
vom Ätzmittel etwa gelöste Material der Tragplatte nicht als störende Verunreinigung im Halbleiterkörper
wirken.
Diesen Anforderungen kann die obenerwähnte Eisen-Nickel-Kobalt-Legierung nicht entsprechen.
Bei dem Sperrschichtelektrodensystem nach der Erfindung wird daher eine Tragplatte verwendet, die
aus Molybdän, Wolfram oder Chrom besteht und vergoldet ist. Die Ausdehnungskoeffizienten dieser
Metalle sind:
2-10°
Chrom 6,8
Molybdän 4,9
Wolfram 4,3
Diese Ausdehnungskoeffizienten haben somit einen solchen Wert, daß für einen aufgelöteten Germaniumoder
Silizium-Einkristall die Bruchgefahr bei Temperaturschwankungen sehr gering ist.
Besonders geeignet sind Molybdän und Wolfram wegen ihrer hohen Wärmeleitfähigkeit, so daß die im
halbleitenden Körper bei Stromdurchgang entwickelte Wärme schnell abgeleitet werden kann.
Tragplatte für ein Sperrschichtelektrodensystem, das einen halbleitenden Einkristall aus
Germanium oder Silizium enthält
Germanium oder Silizium enthält
Anmelder:
N. V. Philips' Gloeilampenfabrieken,
Eindhoven (Niederlande)
Vertreter:
Dr. P. Roßbach, Patentanwalt,
Hamburg 1, Mönckebergstr. 7
Als Erfinder benannt:
Theo Willem Willemse, Delft (Niederlande)
Beanspruchte Priorität:
Niederlande vom 1. Juli 1954 (188 893)
Bei der üblichen Ätzbehandlung sind diese Metalle für praktische Zwecke hinreichend beständig, und sie
rufen keine störenden Verunreinigungen im Halbleiterkörper hervor.
Diese Metalle haben ferner eine hohe mechanische Festigkeit, so daß, wenn der halbleitende Körper
unter Zwischenfügung einer Tragplatte aus diesen Metallen auf einer anderen Platte, z. B. einer Kühlplatte
aus Kupfer, festgelötet wird, die Formänderung der Tragplatte gegenüber der Formänderung der
Kühlplatte aus Kupfer gering ist.
Für einen guten Wärmeübergang muß eine gut haftende Lötschicht zwischen dem halbleitenden Körper
und der Tragplatte angebracht werden. Molybdän, Wolfram und Chrom lassen sich praktisch nicht oder
nur schwierig löten.
Bei einem Sperrschichtelektrodensystem der eingangs erwähnten Art kann dieser Nachteil vermieden
werden, wenn eine nach der Erfindung vorgeschlagene Tragplatte vorgesehen ist.
Die Erfindung wird an Hand eines in der Zeichnung dargestellten Ausführungsbeispieles näher erläutert,
in der eine Diode in vergrößertem Maßstab dargestellt ist.
Mit 1 ist die Tragplatte bezeichnet, die z. B. aus Molybdän besteht. Diese Platte ist mit einer dünnen
Goldschicht 2 bedeckt, die zur besseren Haftung einer
.. ■ . 709 590/229
dünnen Lötschicht 3 dient, durch die der halbleitende Körper 4, z. B. ein Germanium-Einkristall, befestigt
ist. Die Goldschicht kann auf galvanischem Wege aufgebracht werden.
Als Lötmaterial kann Zinn verwendet werden, dem in an sich bekannter Weise Donatoren oder Akzeptoren
zugesetzt sein können.
Die Tragplatte ist selbst wieder auf einer Kühlplatte 5 festgelötet, die z. B. aus Kupfer, Aluminium,
Nickel oder Eisen besteht. Als Lötmittel 6 kann Silber verwendet werden.
Naturgemäß kann die Unterseite der Tragplatte wieder vergoldet sein; in diesem Fall ist die Zahl der
möglichen Lötmittel viel größer.
Claims (2)
1. Sperrschichtelektrodensystem, das einen halbleitenden Einkristall aus Germanium oder
Silizium enthält, wobei der halbleitende Einkristall auf einer Wärme ableitenden Tragplatte festgelötet
ist, dadurchge kennzeichnet, daß die Tragplatte aus Molybdän, Wolfram oder Chrom besteht und vergoldet ist.
2. Sperrschichtelektrodensystem nach Anspruch 1, dadurch gekennzeichnet, daß die Tragplatte
auf einer Kühlplatte festgelötet ist.
In Betracht gezogene Druckschriften:
Deutsche Auslegeschrift Nr. 1 212 639.
Deutsche Auslegeschrift Nr. 1 212 639.
Hierzu 1 Blatt Zeichnungen
709 590/229 6.67 © Bundesdruckerei Berlin
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL188893 | 1954-07-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE1242298B true DE1242298B (de) | 1967-06-15 |
Family
ID=19750670
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEN27010A Pending DE1242298B (de) | 1954-07-01 | 1955-06-28 | Tragplatte fuer ein Sperrschichtelektrodensystem, das einen halbleitenden Einkristall aus Germanium oder Silizium enthaelt |
DE19551212639 Pending DE1212639B (de) | 1954-07-01 | 1955-06-28 | Sperrschichtelektrodensystem, das einen halbleitenden einkristall aus germanium oder silizium enthaelt |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19551212639 Pending DE1212639B (de) | 1954-07-01 | 1955-06-28 | Sperrschichtelektrodensystem, das einen halbleitenden einkristall aus germanium oder silizium enthaelt |
Country Status (8)
Country | Link |
---|---|
US (1) | US2971251A (de) |
BE (1) | BE539442A (de) |
CH (1) | CH333704A (de) |
DE (2) | DE1242298B (de) |
ES (1) | ES222691A1 (de) |
FR (1) | FR1126817A (de) |
GB (1) | GB772583A (de) |
NL (1) | NL107577C (de) |
Families Citing this family (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL107577C (de) * | 1954-07-01 | |||
DE1285068B (de) * | 1957-01-11 | 1968-12-12 | Siemens Ag | Legierungskontakt auf mit einer Goldschicht versehenen Halbleiterkristallen |
US2922092A (en) * | 1957-05-09 | 1960-01-19 | Westinghouse Electric Corp | Base contact members for semiconductor devices |
US3000085A (en) * | 1958-06-13 | 1961-09-19 | Westinghouse Electric Corp | Plating of sintered tungsten contacts |
NL239159A (de) * | 1958-08-08 | |||
NL249694A (de) * | 1959-12-30 | |||
US3173451A (en) * | 1960-06-23 | 1965-03-16 | Owens Corning Fiberglass Corp | Cast manifold with liner |
DE1133834B (de) * | 1960-09-21 | 1962-07-26 | Siemens Ag | Siliziumgleichrichter und Verfahren zu dessen Herstellung |
DE1143588B (de) * | 1960-09-22 | 1963-02-14 | Siemens Ag | Gesinterter Kontaktkoerper fuer Halbleiteranordnungen |
US3141226A (en) * | 1961-09-27 | 1964-07-21 | Hughes Aircraft Co | Semiconductor electrode attachment |
US3235943A (en) * | 1962-01-04 | 1966-02-22 | Corning Glass Works | Method of making a flux free bonded article |
US3264074A (en) * | 1962-04-04 | 1966-08-02 | Lear Siegler Inc | Thin film electron emissive electrode |
US3214833A (en) * | 1962-09-25 | 1965-11-02 | George F Erickson | Ceramic to metal bonding process |
US3200490A (en) * | 1962-12-07 | 1965-08-17 | Philco Corp | Method of forming ohmic bonds to a germanium-coated silicon body with eutectic alloyforming materials |
US3241931A (en) * | 1963-03-01 | 1966-03-22 | Rca Corp | Semiconductor devices |
US3291578A (en) * | 1963-11-04 | 1966-12-13 | Gen Electric | Metallized semiconductor support and mounting structure |
US3342567A (en) * | 1963-12-27 | 1967-09-19 | Rca Corp | Low resistance bonds to germaniumsilicon bodies and method of making such bonds |
US3308353A (en) * | 1964-09-10 | 1967-03-07 | Talon Inc | Semi-conductor device with specific support member material |
GB1150356A (en) * | 1965-10-26 | 1969-04-30 | Int Nickel Ltd | Coating Bodies of Oxidisable Elements and Alloys with Gold Alloys |
US3367774A (en) * | 1966-11-10 | 1968-02-06 | Lambert & Brake Corp | Method of producing a composite friction member |
FR1518717A (fr) * | 1966-12-21 | 1968-03-29 | Radiotechnique Coprim Rtc | Perfectionnements aux diodes électroluminescentes |
DE1665969B1 (de) * | 1967-06-15 | 1972-01-20 | Siemens Ag | Dichte Durchfuehrung eines oder mehrerer elektrischer und/oder Waermeleiter durch einen Isolierkoerper |
US3620692A (en) * | 1970-04-01 | 1971-11-16 | Rca Corp | Mounting structure for high-power semiconductor devices |
US3753665A (en) * | 1970-11-12 | 1973-08-21 | Gen Electric | Magnetic film plated wire |
US3833425A (en) * | 1972-02-23 | 1974-09-03 | Us Navy | Solar cell array |
JPS51102565A (de) * | 1975-03-07 | 1976-09-10 | Hitachi Ltd | |
JPS5921032A (ja) * | 1982-07-26 | 1984-02-02 | Sumitomo Electric Ind Ltd | 半導体装置用基板 |
JPS59141248A (ja) * | 1983-01-31 | 1984-08-13 | Sumitomo Electric Ind Ltd | 半導体基板材料 |
JPS59141247A (ja) * | 1983-01-31 | 1984-08-13 | Sumitomo Electric Ind Ltd | 半導体基板材料 |
US4929516A (en) * | 1985-03-14 | 1990-05-29 | Olin Corporation | Semiconductor die attach system |
US4978052A (en) * | 1986-11-07 | 1990-12-18 | Olin Corporation | Semiconductor die attach system |
US4872047A (en) * | 1986-11-07 | 1989-10-03 | Olin Corporation | Semiconductor die attach system |
JPH07105464B2 (ja) * | 1992-12-04 | 1995-11-13 | 住友電気工業株式会社 | 半導体素子搭載用半導体装置 |
US5972737A (en) * | 1993-04-14 | 1999-10-26 | Frank J. Polese | Heat-dissipating package for microcircuit devices and process for manufacture |
US5886407A (en) * | 1993-04-14 | 1999-03-23 | Frank J. Polese | Heat-dissipating package for microcircuit devices |
US5686676A (en) * | 1996-05-07 | 1997-11-11 | Brush Wellman Inc. | Process for making improved copper/tungsten composites |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1212639B (de) * | 1954-07-01 | 1966-03-17 | Sperrschichtelektrodensystem, das einen halbleitenden einkristall aus germanium oder silizium enthaelt |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL136384B (de) * | 1943-05-01 | 1900-01-01 | ||
US2441603A (en) * | 1943-07-28 | 1948-05-18 | Bell Telephone Labor Inc | Electrical translating materials and method of making them |
US2391456A (en) * | 1944-01-29 | 1945-12-25 | Mallory & Co Inc P R | Spark plug electrode |
US2555001A (en) * | 1947-02-04 | 1951-05-29 | Bell Telephone Labor Inc | Bonded article and method of bonding |
US2567970A (en) * | 1947-12-24 | 1951-09-18 | Bell Telephone Labor Inc | Semiconductor comprising silicon and method of making it |
US2525565A (en) * | 1948-07-12 | 1950-10-10 | Eitel Mccullough Inc | Filamentary cathode for electron tubes |
US2690409A (en) * | 1949-07-08 | 1954-09-28 | Thompson Prod Inc | Binary coating of refractory metals |
US2763822A (en) * | 1955-05-10 | 1956-09-18 | Westinghouse Electric Corp | Silicon semiconductor devices |
-
0
- NL NL107577D patent/NL107577C/xx active
- BE BE539442D patent/BE539442A/xx unknown
-
1955
- 1955-06-20 US US516690A patent/US2971251A/en not_active Expired - Lifetime
- 1955-06-28 GB GB18648/55A patent/GB772583A/en not_active Expired
- 1955-06-28 DE DEN27010A patent/DE1242298B/de active Pending
- 1955-06-28 ES ES0222691A patent/ES222691A1/es not_active Expired
- 1955-06-28 DE DE19551212639 patent/DE1212639B/de active Pending
- 1955-06-29 FR FR1126817D patent/FR1126817A/fr not_active Expired
- 1955-07-01 CH CH333704D patent/CH333704A/de unknown
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1212639B (de) * | 1954-07-01 | 1966-03-17 | Sperrschichtelektrodensystem, das einen halbleitenden einkristall aus germanium oder silizium enthaelt |
Also Published As
Publication number | Publication date |
---|---|
CH333704A (de) | 1958-10-31 |
US2971251A (en) | 1961-02-14 |
FR1126817A (fr) | 1956-12-03 |
GB772583A (en) | 1957-04-17 |
BE539442A (de) | |
NL107577C (de) | |
ES222691A1 (es) | 1956-01-01 |
DE1212639B (de) | 1966-03-17 |
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