DE1102083B - Antifoam agents for the yeast and sugar industries - Google Patents
Antifoam agents for the yeast and sugar industriesInfo
- Publication number
- DE1102083B DE1102083B DESCH19562A DESC019562A DE1102083B DE 1102083 B DE1102083 B DE 1102083B DE SCH19562 A DESCH19562 A DE SCH19562A DE SC019562 A DESC019562 A DE SC019562A DE 1102083 B DE1102083 B DE 1102083B
- Authority
- DE
- Germany
- Prior art keywords
- yeast
- parts
- antifoam agents
- water
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 240000004808 Saccharomyces cerevisiae Species 0.000 title claims description 5
- 239000002518 antifoaming agent Substances 0.000 title claims description 5
- 239000003795 chemical substances by application Substances 0.000 title claims description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 229920001296 polysiloxane Polymers 0.000 claims description 9
- -1 Polydimethylsiloxanes Polymers 0.000 claims description 8
- 239000003921 oil Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 4
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 claims description 3
- UHUSDOQQWJGJQS-UHFFFAOYSA-N glycerol 1,2-dioctadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)OC(=O)CCCCCCCCCCCCCCCCC UHUSDOQQWJGJQS-UHFFFAOYSA-N 0.000 claims description 3
- RZRNAYUHWVFMIP-HXUWFJFHSA-N glycerol monolinoleate Natural products CCCCCCCCC=CCCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-HXUWFJFHSA-N 0.000 claims description 3
- 238000005504 petroleum refining Methods 0.000 claims description 3
- 239000007762 w/o emulsion Substances 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 238000013459 approach Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 239000005662 Paraffin oil Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 125000003010 ionic group Chemical group 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002569 water oil cream Substances 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D23/00—Mine roof supports for step- by- step movement, e.g. in combination with provisions for shifting of conveyors, mining machines, or guides therefor
- E21D23/0047—Mine roof supports for step- by- step movement, e.g. in combination with provisions for shifting of conveyors, mining machines, or guides therefor without essential shifting devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
Landscapes
- Engineering & Computer Science (AREA)
- Mining & Mineral Resources (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Colloid Chemistry (AREA)
Description
Antischaummittel für die Hefe- und Zuckerindustrie Zusatz zum Patent 1 050 289 Im Hauptpatent wird ein Antischaummittel beschrieben, das aus einer Mischung von Ölen aus der Erdölraffination mit Silikonen, insbesondere Polydimethylsiloxanen, in Form einer Wasser-in-Öl-Emulsion, besteht. Die Emulsion der Öle in Wasser wird dabei mit einer Emulsion der Silikone vermischt bzw. dieses Gemisch durch Druck bei 10 bis 20 atü homogenisiert. Antifoam agent for the yeast and sugar industry. Patent addition 1 050 289 The main patent describes an antifoam that consists of a mixture of oils from petroleum refining with silicones, especially polydimethylsiloxanes, in the form of a water-in-oil emulsion. The emulsion of the oils in water becomes mixed with an emulsion of the silicone or this mixture by pressure Homogenized at 10 to 20 atm.
Es wurde nun gefunden, daß das Einkapseln der Silikone durch Melasse oder alkalische Medien, wie Rohrsaft bei der Zuckergewinnung, Würze bei der Hefegewinnung, und damit das Unwirksamwerden der Silikone noch weiterhin verringert werden kann, wenn man dem gemäß Patent 1 050289, das aus einer Mischung von Olen aus der Erdölraffination mit Silikonen, insbesondere Polydimethylsiloxanen, in Form einer Wasser-in-Öl-Emulsion besteht, noch einen Zusatz von Stearinsäure, Äthylenglykol, Glycerinmonooleat, Glycerindistearat, Stearyl-, Mondecyl- oder Arachylalkohol allein oder in Mischung miteinander gibt. It has now been found that the encapsulation of the silicones by molasses or alkaline media, such as cane juice when extracting sugar, wort when extracting yeast, and so that the ineffectiveness of the silicones can be further reduced, if one considers that according to patent 1 050289, which consists of a mixture of oils from petroleum refining with silicones, especially polydimethylsiloxanes, in the form of a water-in-oil emulsion consists, nor an addition of stearic acid, ethylene glycol, glycerol monooleate, glycerol distearate, There are stearyl, mondecyl or arachyl alcohol alone or in admixture with one another.
Die so erhaltenen Antischaummittel sind gegenüber Säuren und Alkalien üblicher Konzentration beständig und voll wirksam; für die Anwendung genügen schon geringe Mengen, z. B. 0,3 O/o, bezogen auf fertige Hefe. The antifoams obtained in this way are resistant to acids and alkalis usual concentration constant and fully effective; enough for the application small amounts, e.g. B. 0.3 O / o, based on finished yeast.
1. 30Teile Fettalkohol C20-C22 werden auf 700 C erwärmt und mit 50 Teilen eines Weißöls (Paraffinbasis) versetzt. Zu diesem Ansatz werden Silikone (Polydimethylsiloxanreihe und Methylsiloxanreihe) unter hoher Tourenzahl (S= 000 bis 14000) eingebracht. Die so erhaltene Mischung wird mit 0,5 bis 6/0 eines Emulgators der nichtionogenen Gruppe (z. B. ein Polyglykolätherderivat) vermengt. In einem zweiten Gefäß werden 150 Teile Wasser mit 2 Gewichtsteilen des Gesamtansatzes Äthylenglykol und 1 bis 2 Gewichtsteilen (vom Gesamtansatz) eines Polyglykolätherfettalkohols innig vermischt. Bei einer Umdrehungszahl von 12000 bis 14000 pro Minute wird dem Öl-Silikon-Ansatz der Wasseransatz beigegeben. 1. 30 parts of fatty alcohol C20-C22 are heated to 700 C and mixed with 50 Parts of a white oil (paraffin base) are added. Silicones become this approach (Polydimethylsiloxane series and methylsiloxane series) with a high number of revolutions (S = 000 up to 14000). The mixture obtained in this way is mixed with 0.5 to 6/0 of an emulsifier the non-ionic group (e.g. a polyglycol ether derivative). In one The second vessel is 150 parts of water with 2 parts by weight of the total batch of ethylene glycol and 1 to 2 parts by weight (of the total batch) of a polyglycol ether fatty alcohol intimately mixed. At a speed of 12,000 to 14,000 per minute, the Oil-silicone approach added to the water approach.
Die Bildung der Wasser-Ol-Emulsion ist nach etwa 2 bis 3 Minuten vollzogen. Die so erhaltene Emulsion ist im Bereich von 28 bis +800 C (vorübergehend bis + 1100 C) beständig.The formation of the water-oil emulsion is complete after about 2 to 3 minutes. The emulsion obtained in this way is in the range from 28 to +800 C (temporarily to + 1100 C) resistant.
2. 16,5 Teile Glycerindistearat werden mit 33 bis 44 Teilen Glvcerinmonooleat auf 700 C erwärmt und mit 220 Teilen Weißöl (Basis Paraffinöl) gemischt. 2. 16.5 parts of glycerol distearate are mixed with 33 to 44 parts of glycerol monooleate heated to 700 ° C. and mixed with 220 parts of white oil (based on paraffin oil).
Diesem Ansatz werden 2 bis 21 Teile Silikone der Reihen wie in 1 beschrieben bei Umdrehungszahlen von 12 000 bis 14000 pro Minute zugesetzt. This approach uses 2 to 21 parts of silicone in the series as in 1 described added at speeds of 12,000 to 14,000 per minute.
In einem zweiten Behälter werden 240 Teile Wasser mit 2 bis 11 Teilen Emulgator der nichtionogenen Gruppe (wie unter 1 geschildert) und 2,2 Teile Äthylenglykol gemischt. In a second container, 240 parts of water are mixed with 2 to 11 parts Emulsifier of the nonionic group (as described under 1) and 2.2 parts of ethylene glycol mixed.
Beide Ansätze werden nach dem Schema Wasserin-Öl bei einer Umdrehungszahl von 12000 bis 14000 pro Minute zusammengegeben. Die Emulsionsbildung ist nach etwa 2 Minuten abgeschlossen. Both approaches are based on the water-in-oil scheme at one speed put together from 12,000 to 14,000 per minute. The emulsification is after about 2 minutes completed.
Das nach dieser Rezeptur erhaltene Antischaummittel ist von -28 bis +1100 C (vorübergehend bis + 1160 C) beständig. The antifoam obtained according to this recipe is from -28 to +1100 C (temporarily up to + 1160 C) resistant.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DESCH19562A DE1102083B (en) | 1956-02-11 | 1956-02-11 | Antifoam agents for the yeast and sugar industries |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DESCH19562A DE1102083B (en) | 1956-02-11 | 1956-02-11 | Antifoam agents for the yeast and sugar industries |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1102083B true DE1102083B (en) | 1961-03-16 |
Family
ID=7428517
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DESCH19562A Pending DE1102083B (en) | 1956-02-11 | 1956-02-11 | Antifoam agents for the yeast and sugar industries |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE1102083B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE663065C (en) * | 1935-09-27 | 1938-07-28 | Goldschmidt Ag Th | Process for the production of emulsions |
| DE752917C (en) * | 1937-01-19 | 1952-11-24 | Herbert Schou | Process for the production of dispersants for the production of plastic oil and fat dispersions |
-
1956
- 1956-02-11 DE DESCH19562A patent/DE1102083B/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE663065C (en) * | 1935-09-27 | 1938-07-28 | Goldschmidt Ag Th | Process for the production of emulsions |
| DE752917C (en) * | 1937-01-19 | 1952-11-24 | Herbert Schou | Process for the production of dispersants for the production of plastic oil and fat dispersions |
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