DD148233A5 - Kohleverfluessigungs-vergasungs-schwerbenzinreforming-verfahren - Google Patents
Kohleverfluessigungs-vergasungs-schwerbenzinreforming-verfahren Download PDFInfo
- Publication number
- DD148233A5 DD148233A5 DD79217596A DD21759679A DD148233A5 DD 148233 A5 DD148233 A5 DD 148233A5 DD 79217596 A DD79217596 A DD 79217596A DD 21759679 A DD21759679 A DD 21759679A DD 148233 A5 DD148233 A5 DD 148233A5
- Authority
- DD
- German Democratic Republic
- Prior art keywords
- fuel
- zone
- coal
- heavy
- amount
- Prior art date
Links
- 238000000034 method Methods 0.000 claims abstract description 340
- 230000008569 process Effects 0.000 claims abstract description 320
- 239000003245 coal Substances 0.000 claims abstract description 163
- 239000000446 fuel Substances 0.000 claims abstract description 153
- 239000007787 solid Substances 0.000 claims abstract description 91
- 238000002309 gasification Methods 0.000 claims abstract description 82
- 239000003502 gasoline Substances 0.000 claims abstract description 66
- 238000006243 chemical reaction Methods 0.000 claims abstract description 55
- 238000002407 reforming Methods 0.000 claims abstract description 44
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000002737 fuel gas Substances 0.000 claims abstract description 12
- 239000007789 gas Substances 0.000 claims description 140
- 229910052739 hydrogen Inorganic materials 0.000 claims description 122
- 239000001257 hydrogen Substances 0.000 claims description 119
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 113
- 238000003786 synthesis reaction Methods 0.000 claims description 86
- 230000015572 biosynthetic process Effects 0.000 claims description 85
- 239000002002 slurry Substances 0.000 claims description 55
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 49
- 239000007788 liquid Substances 0.000 claims description 49
- 239000011707 mineral Substances 0.000 claims description 47
- 229930195733 hydrocarbon Natural products 0.000 claims description 29
- 150000002430 hydrocarbons Chemical class 0.000 claims description 29
- 239000004215 Carbon black (E152) Substances 0.000 claims description 27
- 238000005984 hydrogenation reaction Methods 0.000 claims description 24
- 230000001965 increasing effect Effects 0.000 claims description 23
- 238000002485 combustion reaction Methods 0.000 claims description 21
- 239000002904 solvent Substances 0.000 claims description 18
- 101000588924 Anthopleura elegantissima Delta-actitoxin-Ael1a Proteins 0.000 claims description 17
- 229910052760 oxygen Inorganic materials 0.000 claims description 17
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 16
- 238000007254 oxidation reaction Methods 0.000 claims description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 14
- 230000007423 decrease Effects 0.000 claims description 14
- 230000003647 oxidation Effects 0.000 claims description 14
- 239000001301 oxygen Substances 0.000 claims description 14
- 230000006872 improvement Effects 0.000 claims description 12
- 238000009835 boiling Methods 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 8
- 230000009467 reduction Effects 0.000 claims description 8
- 150000002431 hydrogen Chemical class 0.000 claims description 7
- 230000008859 change Effects 0.000 claims description 3
- 239000010802 sludge Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 51
- 229910002091 carbon monoxide Inorganic materials 0.000 description 31
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 28
- 241000196324 Embryophyta Species 0.000 description 23
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 22
- 229910052799 carbon Inorganic materials 0.000 description 20
- 239000003054 catalyst Substances 0.000 description 14
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 14
- 238000004519 manufacturing process Methods 0.000 description 13
- 239000002253 acid Substances 0.000 description 12
- 230000008707 rearrangement Effects 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- 238000004090 dissolution Methods 0.000 description 10
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 10
- 238000000926 separation method Methods 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 8
- 206010021703 Indifference Diseases 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 238000006462 rearrangement reaction Methods 0.000 description 7
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000000571 coke Substances 0.000 description 6
- 239000000376 reactant Substances 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 5
- 238000004939 coking Methods 0.000 description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 5
- 238000005457 optimization Methods 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000002893 slag Substances 0.000 description 4
- 238000005292 vacuum distillation Methods 0.000 description 4
- 230000033228 biological regulation Effects 0.000 description 3
- 239000003575 carbonaceous material Substances 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 238000005194 fractionation Methods 0.000 description 3
- 239000000295 fuel oil Substances 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- QZYDAIMOJUSSFT-UHFFFAOYSA-N [Co].[Ni].[Mo] Chemical compound [Co].[Ni].[Mo] QZYDAIMOJUSSFT-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000006356 dehydrogenation reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000003134 recirculating effect Effects 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 101100323406 Caenorhabditis elegans apc-10 gene Proteins 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 101100298048 Mus musculus Pmp22 gene Proteins 0.000 description 1
- 101150009856 PIGC gene Proteins 0.000 description 1
- 241000282887 Suidae Species 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 239000010771 distillate fuel oil Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000010763 heavy fuel oil Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 201000002266 mite infestation Diseases 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000008450 motivation Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/006—Combinations of processes provided in groups C10G1/02 - C10G1/08
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/969,280 US4222846A (en) | 1978-12-13 | 1978-12-13 | Coal liquefaction-gasification process including reforming of naphtha product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DD148233A5 true DD148233A5 (de) | 1981-05-13 |
Family
ID=25515378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD79217596A DD148233A5 (de) | 1978-12-13 | 1979-12-12 | Kohleverfluessigungs-vergasungs-schwerbenzinreforming-verfahren |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4222846A (fr) |
| EP (1) | EP0018996A4 (fr) |
| JP (1) | JPS55500942A (fr) |
| AU (1) | AU5229379A (fr) |
| CA (1) | CA1128886A (fr) |
| DD (1) | DD148233A5 (fr) |
| PL (1) | PL220359A1 (fr) |
| WO (1) | WO1980001281A1 (fr) |
| ZA (1) | ZA795952B (fr) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2051855B (en) * | 1979-06-18 | 1983-09-14 | Sasol One Ltd | Converting coal into liquid products |
| US4411766A (en) * | 1982-02-25 | 1983-10-25 | Air Products And Chemicals, Inc. | Iron catalyzed coal liquefaction process |
| US4447310A (en) * | 1982-06-23 | 1984-05-08 | Mobil Oil Corporation | Production of distillates by the integration of supercritical extraction and gasification through methanol to gasoline |
| US4440622A (en) * | 1982-06-23 | 1984-04-03 | Mobil Oil Corporation | Integration of short-contact-time liquefaction and critical solvent deashing with gasification through methanol-to-gasoline |
| DE3246609A1 (de) * | 1982-12-16 | 1984-06-20 | GfK Gesellschaft für Kohleverflüssigung mbH, 6600 Saarbrücken | Verfahren zum hydrieren von kohle |
| US5200063A (en) * | 1990-06-21 | 1993-04-06 | Exxon Research And Engineering Company | Coal hydroconversion process comprising solvent enhanced pretreatment with carbon monoxide |
| US5433760A (en) * | 1993-05-13 | 1995-07-18 | Shell Oil Company | Method of quenching synthesis gas |
| US20080256852A1 (en) * | 2007-04-20 | 2008-10-23 | Schobert Harold H | Integrated process and apparatus for producing coal-based jet fuel, diesel fuel, and distillate fuels |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3071536A (en) * | 1956-06-21 | 1963-01-01 | Union Oil Co | Hydrocarbon conversion process |
| US3518182A (en) * | 1968-03-29 | 1970-06-30 | Chevron Res | Conversion of coal to liquid products |
| US3700586A (en) * | 1970-08-10 | 1972-10-24 | Exxon Research Engineering Co | Production of high octane gasoline from coal liquids |
| US4039424A (en) * | 1976-03-29 | 1977-08-02 | Arthur D. Little, Inc. | Process for producing fluid fuel from coal |
| US4075079A (en) * | 1976-06-09 | 1978-02-21 | Exxon Research & Engineering Co. | Process for the production of hydrocarbons from coal |
| US4050908A (en) * | 1976-07-20 | 1977-09-27 | The Ralph M. Parsons Company | Process for the production of fuel values from coal |
| JPS5948576B2 (ja) * | 1977-04-04 | 1984-11-27 | 富士通株式会社 | Ｔｄｍ／ｆｄｍ変換装置 |
| JPS5948577B2 (ja) * | 1977-04-04 | 1984-11-27 | 富士通株式会社 | Ｆｄｍ／ｔｄｍ変換装置 |
-
1978
- 1978-12-13 US US05/969,280 patent/US4222846A/en not_active Expired - Lifetime
-
1979
- 1979-10-22 WO PCT/US1979/000876 patent/WO1980001281A1/fr not_active Application Discontinuation
- 1979-10-22 JP JP50010379A patent/JPS55500942A/ja active Pending
- 1979-10-29 AU AU52293/79A patent/AU5229379A/en not_active Abandoned
- 1979-11-06 ZA ZA00795952A patent/ZA795952B/xx unknown
- 1979-11-20 CA CA340,183A patent/CA1128886A/fr not_active Expired
- 1979-12-12 DD DD79217596A patent/DD148233A5/de unknown
- 1979-12-12 PL PL22035979A patent/PL220359A1/xx unknown
-
1980
- 1980-07-01 EP EP19800900037 patent/EP0018996A4/fr not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| PL220359A1 (fr) | 1980-10-06 |
| EP0018996A4 (fr) | 1981-05-19 |
| EP0018996A1 (fr) | 1980-11-26 |
| JPS55500942A (fr) | 1980-11-13 |
| ZA795952B (en) | 1980-11-26 |
| CA1128886A (fr) | 1982-08-03 |
| WO1980001281A1 (fr) | 1980-06-26 |
| AU5229379A (en) | 1980-06-19 |
| US4222846A (en) | 1980-09-16 |
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