CS209413B2 - Method of making liquid polymeres of high viscosity - Google Patents
Method of making liquid polymeres of high viscosity Download PDFInfo
- Publication number
- CS209413B2 CS209413B2 CS741793A CS179374A CS209413B2 CS 209413 B2 CS209413 B2 CS 209413B2 CS 741793 A CS741793 A CS 741793A CS 179374 A CS179374 A CS 179374A CS 209413 B2 CS209413 B2 CS 209413B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- olefins
- titanium tetrachloride
- viscosity
- polymerization
- polymer
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 46
- 239000007788 liquid Substances 0.000 title claims abstract description 5
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 28
- 239000004711 α-olefin Substances 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 10
- 238000005336 cracking Methods 0.000 claims abstract description 8
- 239000012298 atmosphere Substances 0.000 claims abstract description 5
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 4
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 33
- 239000003054 catalyst Substances 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 8
- 238000011065 in-situ storage Methods 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- -1 aluminum compound Chemical class 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 abstract description 29
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 19
- 239000001257 hydrogen Substances 0.000 abstract description 18
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 18
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 abstract description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 11
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract description 11
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 6
- 150000003623 transition metal compounds Chemical class 0.000 abstract description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 239000012263 liquid product Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 description 14
- 239000000945 filler Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000006722 reduction reaction Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 230000009918 complex formation Effects 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910010068 TiCl2 Inorganic materials 0.000 description 2
- 229910003074 TiCl4 Inorganic materials 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 229910010165 TiCu Inorganic materials 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 201000004792 malaria Diseases 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000005325 percolation Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Lubricants (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS79505A CS209414B2 (cs) | 1973-03-12 | 1979-01-23 | Způsob výroby kapalných polymerů o vysoké viskozitě |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT21456/73A IT981299B (it) | 1973-03-12 | 1973-03-12 | Produzione di polimeri liquidi ad altissima viscosita |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS209413B2 true CS209413B2 (en) | 1981-12-31 |
Family
ID=11182033
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS741793A CS209413B2 (en) | 1973-03-12 | 1974-03-12 | Method of making liquid polymeres of high viscosity |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US3950449A (it) |
| JP (1) | JPS5434426B2 (it) |
| AU (1) | AU476678B2 (it) |
| BE (1) | BE812156A (it) |
| CA (2) | CA1036585A (it) |
| CH (1) | CH615687A5 (it) |
| CS (1) | CS209413B2 (it) |
| DD (1) | DD111085A5 (it) |
| DE (1) | DE2411496C2 (it) |
| DK (1) | DK143985C (it) |
| FR (1) | FR2221467B1 (it) |
| GB (1) | GB1468723A (it) |
| HU (1) | HU170212B (it) |
| IT (1) | IT981299B (it) |
| LU (1) | LU69610A1 (it) |
| NL (1) | NL161465C (it) |
| NO (1) | NO141015C (it) |
| SE (1) | SE402463B (it) |
| YU (1) | YU35607B (it) |
| ZA (1) | ZA741554B (it) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1015582B (it) * | 1974-07-01 | 1977-05-20 | Snam Progetti | Processo per la polimerizzazione dell etilene |
| JPS60211750A (ja) * | 1984-04-04 | 1985-10-24 | Toshiba Corp | 回転陽極型ｘ線管 |
| US4724273A (en) * | 1985-02-13 | 1988-02-09 | Studiengesellschaft Kohle Mbh | Process for preparing alpha-olefin polymers and oligomers |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3151181A (en) * | 1958-02-18 | 1964-09-29 | Shell Oil Co | High molecular weight hydrocarbon polymers |
| US3113167A (en) * | 1962-05-08 | 1963-12-03 | Atlantic Refining Co | High viscosity synthetic lubricants from alpha-olefins |
| NL125866C (it) * | 1965-02-03 | |||
| CA937952A (en) * | 1969-12-30 | 1973-12-04 | Floris Telemaco | Process for the preparation of synthetic lubricating oils from olefines and products so obtained |
-
1973
- 1973-03-12 IT IT21456/73A patent/IT981299B/it active
-
1974
- 1974-03-08 AU AU66475/74A patent/AU476678B2/en not_active Expired
- 1974-03-11 GB GB1083174A patent/GB1468723A/en not_active Expired
- 1974-03-11 ZA ZA00741554A patent/ZA741554B/xx unknown
- 1974-03-11 HU HUSA2606A patent/HU170212B/hu unknown
- 1974-03-11 CA CA194,609A patent/CA1036585A/en not_active Expired
- 1974-03-11 YU YU652/74A patent/YU35607B/xx unknown
- 1974-03-11 DK DK132474A patent/DK143985C/da active
- 1974-03-11 BE BE141893A patent/BE812156A/xx not_active IP Right Cessation
- 1974-03-11 CH CH338474A patent/CH615687A5/it not_active IP Right Cessation
- 1974-03-11 LU LU69610A patent/LU69610A1/xx unknown
- 1974-03-11 FR FR7408206A patent/FR2221467B1/fr not_active Expired
- 1974-03-11 DE DE2411496A patent/DE2411496C2/de not_active Expired
- 1974-03-12 NO NO740867A patent/NO141015C/no unknown
- 1974-03-12 SE SE7403316A patent/SE402463B/xx unknown
- 1974-03-12 US US05/450,474 patent/US3950449A/en not_active Expired - Lifetime
- 1974-03-12 NL NL7403334.A patent/NL161465C/xx not_active IP Right Cessation
- 1974-03-12 DD DD177140A patent/DD111085A5/xx unknown
- 1974-03-12 CS CS741793A patent/CS209413B2/cs unknown
- 1974-03-12 JP JP2778474A patent/JPS5434426B2/ja not_active Expired
- 1974-03-12 CA CA194,796A patent/CA1009258A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| LU69610A1 (it) | 1974-09-25 |
| CA1036585A (en) | 1978-08-15 |
| AU476678B2 (en) | 1976-09-30 |
| GB1468723A (en) | 1977-03-30 |
| ZA741554B (en) | 1975-02-26 |
| DD111085A5 (it) | 1975-01-20 |
| FR2221467B1 (it) | 1977-06-17 |
| DK143985B (da) | 1981-11-09 |
| DE2411496C2 (de) | 1982-09-16 |
| NO141015C (no) | 1979-12-27 |
| CA1009258A (en) | 1977-04-26 |
| CH615687A5 (it) | 1980-02-15 |
| DE2411496A1 (de) | 1974-09-26 |
| NO740867L (no) | 1974-09-13 |
| FR2221467A1 (it) | 1974-10-11 |
| BE812156A (fr) | 1974-07-01 |
| SE402463B (sv) | 1978-07-03 |
| DK143985C (da) | 1982-04-19 |
| IT981299B (it) | 1974-10-10 |
| JPS502783A (it) | 1975-01-13 |
| YU65274A (en) | 1980-09-25 |
| NO141015B (no) | 1979-09-17 |
| AU6647574A (en) | 1975-09-11 |
| HU170212B (it) | 1977-04-28 |
| US3950449A (en) | 1976-04-13 |
| NL7403334A (it) | 1974-09-16 |
| JPS5434426B2 (it) | 1979-10-26 |
| NL161465C (nl) | 1980-02-15 |
| NL161465B (nl) | 1979-09-17 |
| YU35607B (en) | 1981-04-30 |
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