CN86105774A - The extracting method and the technology of the edible digestive juice of sea-tangle - Google Patents
The extracting method and the technology of the edible digestive juice of sea-tangle Download PDFInfo
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- CN86105774A CN86105774A CN198686105774A CN86105774A CN86105774A CN 86105774 A CN86105774 A CN 86105774A CN 198686105774 A CN198686105774 A CN 198686105774A CN 86105774 A CN86105774 A CN 86105774A CN 86105774 A CN86105774 A CN 86105774A
- Authority
- CN
- China
- Prior art keywords
- sea
- tangle
- natrium citricum
- sodium carbonate
- edible
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- 238000000034 method Methods 0.000 title claims abstract description 35
- 230000001079 digestive effect Effects 0.000 title claims abstract description 13
- 235000011389 fruit/vegetable juice Nutrition 0.000 title claims abstract description 13
- 238000005516 engineering process Methods 0.000 title claims description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 28
- 239000000284 extract Substances 0.000 claims abstract description 18
- 230000029087 digestion Effects 0.000 claims abstract description 17
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 14
- CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 claims abstract description 11
- 229940039790 sodium oxalate Drugs 0.000 claims abstract description 8
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims abstract description 7
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 claims abstract description 7
- 241001474374 Blennius Species 0.000 claims abstract description 6
- 235000017550 sodium carbonate Nutrition 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 8
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 7
- 239000000661 sodium alginate Substances 0.000 claims description 7
- 235000010413 sodium alginate Nutrition 0.000 claims description 7
- 229940005550 sodium alginate Drugs 0.000 claims description 7
- 238000007654 immersion Methods 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 4
- 235000009508 confectionery Nutrition 0.000 claims description 4
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- AKWCSUYPYAOZKY-UHFFFAOYSA-M sodium hydrogen carbonate oxalic acid Chemical compound C([O-])(O)=O.C(C(=O)O)(=O)O.[Na+] AKWCSUYPYAOZKY-UHFFFAOYSA-M 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims 3
- 238000005406 washing Methods 0.000 claims 2
- 238000000605 extraction Methods 0.000 claims 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims 1
- 238000004659 sterilization and disinfection Methods 0.000 claims 1
- 241000512259 Ascophyllum nodosum Species 0.000 abstract description 7
- 239000003513 alkali Substances 0.000 abstract description 4
- 238000007670 refining Methods 0.000 abstract description 3
- -1 sodium citrate-sodium oxalate-sodium carbonate Chemical compound 0.000 abstract description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 235000010443 alginic acid Nutrition 0.000 description 5
- 229920000615 alginic acid Polymers 0.000 description 5
- 235000016709 nutrition Nutrition 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 230000035764 nutrition Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 235000015067 sauces Nutrition 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000005911 diet Nutrition 0.000 description 2
- 230000037213 diet Effects 0.000 description 2
- 235000013373 food additive Nutrition 0.000 description 2
- 239000002778 food additive Substances 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 230000000050 nutritive effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 210000003097 mucus Anatomy 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
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- Edible Seaweed (AREA)
- Non-Alcoholic Beverages (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
The present invention is with the softening sea-tangle of natrium citricum, and it cooperates with sodium oxalate, sodium carbonate, to sea-tangle soften, digestion process, can make refining edible, medical, daily kelp extract, overall process is carried out mostly at normal temperatures.
The digestion of sea-tangle has two kinds of methods: 1. natrium citricum-sodium carbonate-citric acid method.2. sodium citrate-sodium oxalate-sodium carbonate.
With natrium citricum preliminary treatment sea-tangle, can save the digestion alkali charge, the digestive juice that makes, viscosity is big, and quality is good.It is a kind of up-and-coming seaweed industrial extracting method.
Description
The invention belongs to the seaweed industry extractive technique.
Sea-tangle is used for extracting products such as iodine, sweet mellow wine, sodium alginate industrial.Produce algin in the industrial production both at home and abroad, mostly digest sea-tangle with soda ash, alkali consumption is big.Tianjin Chinese system of weights iodine station-service normal temperature legal system is got algin new technology (in January, 1985 marine alga chemistry and seaweed industry data compilation) raw material digestion formaldehyde 3%, soda ash 15-20%.Haiyang Chemical Plant, Qingdao extracts sodium alginate (in January, 1985 marine alga chemistry and seaweed industry data compilation) with caustic soda.Foochow aquatic products processing station-service acetic acid is used 10% soda ash after handling again, digests (in January, 1985 marine alga chemistry and seaweed industry data compilation) under 55-60 ℃ of temperature.After steeping sea-tangle with sour calcium water logging, Qingdao Huanghai Sea aquatic products research institute survey report No. 238 (nineteen eighty-two) produces sodium alginate.External with the pretreatment procedure of acid soak as the marine alga glue, but adhesiveness descends.
Sea-tangle is except that having the important use industrial, and it still is that domestic and international people like the edible vegetable with nutritive value eaten, and up to the present, modal eating method is to clean to hot plate to cook to eat, but very difficult burning is mashed, edible back indigestibility.At present both at home and abroad edible kelp food mostly forms through machining, and as sea-tangle silk, powder, sauce, its nutritional labeling mainly is the alginic acid salt, and most of soluble nutrient is dissolved in the wash water in the process.
In order to overcome above-mentioned shortcoming, the present invention adopts a kind of new digestion sea-tangle method, make can be edible the sea-tangle digestive juice, it contains original a large amount of various nutritional labelings in the sea-tangle, is much higher than existing various kelp food as edible its nutritive value.In addition, because sea-tangle has carried out digestion process, the algin that insoluble difficulty is absorbed by human consumption is converted into the sodium alginate sylvite of solubility.Edible this extract can play the nutrition and health care effect to human body, and this is the edible important channel of sea-tangle, and this eating method is not also being seen at present.
Refining extract of the present invention can be made diet food additive, medicinal, commodity, kelp sauce can replace commercially available various kelp foods, also can be refined into dried sea-tangle powder, than the often edible sea-tangle powder nutrition height of states such as the present U.S., Japan, the Soviet Union, it is more being rich in nutrition also to make food additives than some materials that extract such as sodium alginate from sea-tangle.
Main points of the present invention are:
1. with natrium citricum (Na
3C
6H
5O
72H
2O) make pretreating agent, sea-tangle is softened, can economize on alkali number greatly like this, the digestive juice viscosity that makes is big, and quality is good.
2. generally produce with the normal temperature method, power consumption is few in the technical process.
3. do not produce waste water in the production technology of edible extract, waste residue can be done edible or make feed.
4. refining extract can be used in the diet product, medicine and commodity, and the kelp sauce that makes through digestion can replace commercially available kelp product, instant, nutrient inventory height.
5. be used the digestion sea-tangle with natrium citricum and sodium oxalate, sodium carbonate, can produce edible and the measured algin product of viscosity matter, and can economize on alkali number greatly.
Chemical reaction base reason of the present invention is:
Agents useful for same:
Sodium oxalate (Na
2C
2O
4); Sodium carbonate (Na
2CO
3); Natrium citricum (Na
3C
6H
5O
72H
2O); Citric acid (C
6H
8O
7H
2O).
Chemical equation is:
Ca·Alg+MA→M·Alg+Ca·A
↓????↓
Water-insoluble is water-soluble
In the formula
Alg-brown alga acidic group
The M-alkali metal ion
The A-anion
Be embodiments of the invention below:
The extracting method of sea-tangle digestive juice and technical process
One, natrium citricum-sodium carbonate-citric acid method:
1. air-dry sea-tangle water flush away silt is cut into silk again, is soaked in water, and washes the immersion sedimentation and removes foul, and supernatant is sterilized after filtration, obtains extract for the first time.
2. will embathe back sea-tangle silk, and add the 4%-6% natrium citricum of raw material weight, and carry out 3-4 hour under normal temperature 20-30 ℃, winter, room temperature was 10 ℃, through 3-4 days, made sea-tangle softening, can crumb with hand, and a large amount of mucus strippings are arranged.
3. the sea-tangle silk thin up after softening, by the nylon wire coarse filtration, centrifugal the getting of filtrate made with extra care extract for the second time.
4. the filter residue after softening the processing carries out digestion under the normal temperature with sodium carbonate, and the consumption of sodium carbonate is the 1%-3% of raw material weight.
5. after digestion is finished, thin up, the citric acid that adds concentration again and be 3%-4% is neutralized to PH7, centrifugal then refined liquid for the third time.
Above-mentioned three refined liquid merge and get promptly that sea-tangle eats, medical extract.
Two, natrium citricum-sodium oxalate-sodium carbonate method.
Sea-tangle wash water, immersion water are used for industrial iodine, the sweet mellow wine carried, and the sea-tangle silk after the immersion adds natrium citricum and sodium oxalate digests, and perhaps adds natrium citricum, sodium oxalate and three kinds of reagent mix of sodium carbonate and digests.Reagent dosage is respectively the 2-4% of raw material weight; 0.5-2%; 0.5-2%.Digestive juice is used for making edible sodium alginate through centrifugal or make extract by existing commercial run.
Mandatory declaration be that its technical process of extracting method of the edible digestive juice of sea-tangle is softened mostly at room temperature, digestion process.Promptly 20-30 ℃ through 2-4 hour, winter, 10 ℃ of room temperatures were through 3-4 days.Carry out for adding fast response, can handle under 30-50 ℃ condition winter, keeps getting final product in 2-3 hour.
Figure of description 1 is a process flow diagram of the present invention, and its symbol description is as follows:
1. raw material is washed the softening cylinders 6. digestion cylinders of pond 2. vegetable-choppers, 3. sea-tangle silk fermentation vats, 4. vibrating-dewatering screens 5. 7. organic bases and is dissolved No. 15. 3 extracts of cylinder 8. soda ash digestion pot 9.10. centrifuge 11. coarse filtration sieve 12. husky filter disinfecting and sterilizing device No. 13. extracts 14. secondary raffinates 16. and soak water and carry iodine, sweet mellow wine 17. waste residues.
Claims (4)
1, the extracting method and the technology of the edible digestive juice of sea-tangle the invention belongs to the seaweed industry extractive technique, and the digestion process sea-tangle is generally used soda ash, formaldehyde, sour calcium water, acid soak both at home and abroad.Feature of the present invention is to be used with natrium citricum and sodium oxalate, sodium carbonate, makes softening, the digestion of sea-tangle, thus make can be edible and industrial the sea-tangle digestive juice.The extraction of digestive juice has two kinds of schemes: (1) natrium citricum--sodium carbonate--citric acid method; (2) natrium citricum--sodium oxalate--sodium carbonate method.
2, according to claim 1-(1) described natrium citricum-sodium carbonate-citric acid method.Air-dry sea-tangle is through washing, immersion, and water is sterile-processed, it is characterized in that the water behind the soaking disinfection is made extract for the first time.It is softening that sea-tangle silk after soaking adds natrium citricum, and consumption is that the 4-6% of air-dry raw material (sea-tangle) weight makes extract for the second time.Sea-tangle after softening further digests with sodium carbonate again, and consumption is the 1-3% of raw material, gets extract for the third time.These No. three extracts merge through refinement treatment must eat, medicinal, daily refined liquid.
3, according to claim 1-(2) described natrium citricum-sodium oxalate method.Air-dry sea-tangle is through washing, immersion, and wash water is used for industry with immersion water and carries iodine, sweet mellow wine.Sea-tangle silk after it is characterized in that soaking adds natrium citricum, sodium oxalate and sodium carbonate and carries out digestion process, and actual amount is respectively the 2-4% of raw material weight; 0.5-2%; 0.5-2%.Digestive juice is centrifugal or make extract by existing commercial run, can be used for making edible sodium alginate.
4, according to its technical process of extracting method of the edible digestive juice of claim 2 and 3 sea-tangles all be soften at room temperature, digestion process.Promptly 20-30 ℃ through 2-4 hour, winter, 10 ℃ of room temperatures were through 3-4 days.Carry out for adding fast response, it is characterized in that under 30-50 ℃ condition, to handle winter, keep getting final product in 2-3 hour.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN198686105774A CN86105774A (en) | 1986-07-19 | 1986-07-19 | The extracting method and the technology of the edible digestive juice of sea-tangle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN198686105774A CN86105774A (en) | 1986-07-19 | 1986-07-19 | The extracting method and the technology of the edible digestive juice of sea-tangle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN86105774A true CN86105774A (en) | 1988-02-17 |
Family
ID=4802953
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN198686105774A Pending CN86105774A (en) | 1986-07-19 | 1986-07-19 | The extracting method and the technology of the edible digestive juice of sea-tangle |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN86105774A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1090920C (en) * | 1999-05-04 | 2002-09-18 | 中国科学院南海海洋研究所 | Kelp product and its production method and application |
| CN1098654C (en) * | 1999-05-04 | 2003-01-15 | 中国科学院南海海洋研究所 | Kelp product (II) and its production method and application |
| CN101461512A (en) * | 2009-01-12 | 2009-06-24 | 厦门新阳洲水产品工贸有限公司 | Method for processing sea-tangle sauce product |
| CN101785562A (en) * | 2010-03-09 | 2010-07-28 | 中国科学院过程工程研究所 | Method for preparing various products by separating kelp components and fully using biomass |
| CN105433301A (en) * | 2015-12-08 | 2016-03-30 | 大连工业大学 | Method for softening kelp |
-
1986
- 1986-07-19 CN CN198686105774A patent/CN86105774A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1090920C (en) * | 1999-05-04 | 2002-09-18 | 中国科学院南海海洋研究所 | Kelp product and its production method and application |
| CN1098654C (en) * | 1999-05-04 | 2003-01-15 | 中国科学院南海海洋研究所 | Kelp product (II) and its production method and application |
| CN101461512A (en) * | 2009-01-12 | 2009-06-24 | 厦门新阳洲水产品工贸有限公司 | Method for processing sea-tangle sauce product |
| CN101461512B (en) * | 2009-01-12 | 2013-05-22 | 厦门新阳洲水产品工贸有限公司 | Method for processing sea-tangle sauce product |
| CN101785562A (en) * | 2010-03-09 | 2010-07-28 | 中国科学院过程工程研究所 | Method for preparing various products by separating kelp components and fully using biomass |
| CN101785562B (en) * | 2010-03-09 | 2012-07-04 | 中国科学院过程工程研究所 | Method for preparing various products by separating kelp components and fully using biomass |
| CN105433301A (en) * | 2015-12-08 | 2016-03-30 | 大连工业大学 | Method for softening kelp |
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