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CN2250352Y - Biological film purifying device - Google Patents

Biological film purifying device Download PDF

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Publication number
CN2250352Y
CN2250352Y CN96229685U CN96229685U CN2250352Y CN 2250352 Y CN2250352 Y CN 2250352Y CN 96229685 U CN96229685 U CN 96229685U CN 96229685 U CN96229685 U CN 96229685U CN 2250352 Y CN2250352 Y CN 2250352Y
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water
activated carbon
composite filler
biofilm
purifier
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李田
张怀德
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Tongji University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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Abstract

一种新型的生物膜净水器,由进水管、出水收集管、池体等构成,主要特点是池体内的复合填料由母体材料与用胶粘剂粘结在其表面的颗粒活性炭层组成。母体材料可以是市售的堆积式填料,也可用塑料、陶瓷或金属等板材,按工艺要求设计加工。本实用新型的净化器因其复合填料的比表面积大,填料表面孔隙发达,有很好的吸附能力,具有挂膜快,抗冲击负荷能力强,对难降解及微量有机物处理效果好的特点,而具有特别好的净水效果。适合原水或废水的处理净化。

A new type of biofilm water purifier is composed of water inlet pipe, water outlet collection pipe, pool body, etc. The main feature is that the composite filler in the pool body is composed of parent material and granular activated carbon layer bonded on its surface with adhesive. The matrix material can be commercially available stacked packing, or plates such as plastic, ceramics or metal, and can be designed and processed according to technological requirements. The purifier of the utility model has the characteristics of large specific surface area of the composite filler, well-developed pores on the surface of the filler, good adsorption capacity, fast film formation, strong impact load resistance, and good treatment effect on refractory and trace organic matter. And has a particularly good water purification effect. It is suitable for the treatment and purification of raw water or waste water.

Description

一种新型的生物膜净化器A New Type of Biofilm Purifier

一种新型的生物膜净化器,涉及水和废水净化的生物处理装置制造技术。A novel biofilm purifier relates to the manufacturing technology of biological treatment devices for water and waste water purification.

在水和废水的处理领域中,生物膜法是一项被广泛采用的技术。该项技术是利用固着在载体表面的微生物,也称生物膜对水中有害物质进行转化、分离,使之无害化的过程。这里所用的生物膜载体材料统称填料。传统的生物膜净化器常使用砾石为填料。砾石有价格低廉的优点,但其重量大,对净化器的结构要求高,且表面光滑,不适合微生物的附着生长。生物陶粒因其密度较低,表面粗糙,在生物膜净化器中也被应用,但陶粒比表面积小,单位体积中有效生物量低,仍不能满足高效生物膜净化器对填料的要求。由此种类繁多的塑料填料被广泛用作新一代生物膜载体材料。塑料填料质轻,可制成理想的形状、尺寸,有较大的比表面积,但其表面光滑,不利于微生物的附着生长,使用这类填料的生物膜净化器启动阶段挂膜困难,启动时间长,水力负荷增加时,生物膜容易被冲刷脱落。Biofilm is a widely used technology in the field of water and wastewater treatment. This technology uses microorganisms fixed on the surface of the carrier, also known as biofilm, to transform and separate harmful substances in water to make them harmless. The biofilm carrier materials used here are collectively referred to as fillers. Traditional biofilm purifiers often use gravel as filler. Gravel has the advantage of low price, but its weight is heavy, the structure requirements of the purifier are high, and the surface is smooth, which is not suitable for the attachment and growth of microorganisms. Due to its low density and rough surface, biological ceramsite is also used in biofilm purifiers. However, ceramsite has a small specific surface area and low effective biomass per unit volume, which still cannot meet the requirements of high-efficiency biofilm purifiers for fillers. As a result, a wide variety of plastic fillers are widely used as a new generation of biofilm carrier materials. The plastic filler is light in weight and can be made into an ideal shape and size, and has a large specific surface area, but its surface is smooth, which is not conducive to the attachment and growth of microorganisms. It is difficult for the biofilm purifier using this kind of filler to form a film at the start-up stage, and the start-up time When the hydraulic load increases, the biofilm is easily washed off.

颗粒活性炭(GAC)表面粗糙,有发达的孔隙结构,为微生物的固着生长提供了理想的场所,因而颗粒活性碳成为一种常用的生物膜载体材料。以GAC为填料的生物膜净化器挂膜快、启动时间短,生物膜遭水力冲刷后恢复快,系统对水力负荷变化的适应能力强。另外多年的理论研究和生产经验均证实,在以活性炭为填料的生物膜净化器中,活性炭的吸附与生物膜的生物利用之间具有协同作用。这种协同作用表现为,活性炭的吸附为难降解有机物与生物膜提供了较长的接触时间;活性炭的富集作用提高了生物膜对微量有机物的去除能力;活性炭的吸附-解吸减缓了毒物冲击负荷对生物膜的破坏作用;生物膜的生物再生作用延长了活性炭的工作周期。因此,尽管GAC的价格明显高于砂、砾石等非吸附材料,却仍被广泛采用。然而,GAC作为生物膜载体也有其局限性。活性炭滤床的孔隙率低,滤层水头损失大,容易被堵塞。特别是进水水质差时。再者,GAC不宜在曝气充氧条件下使用,也就是GAC不能用作生物接触氧化反应器的填料。Granular activated carbon (GAC) has a rough surface and a well-developed pore structure, which provides an ideal place for the growth of microorganisms, so granular activated carbon has become a commonly used biofilm carrier material. The biofilm purifier with GAC as filler has fast film formation and short start-up time. The biofilm recovers quickly after being washed by hydraulic force, and the system has strong adaptability to changes in hydraulic load. In addition, many years of theoretical research and production experience have confirmed that in the biofilm purifier with activated carbon as filler, there is a synergistic effect between the adsorption of activated carbon and the bioutilization of biofilm. This synergistic effect is manifested in the fact that the adsorption of activated carbon provides a longer contact time for refractory organic matter and biofilm; the enrichment effect of activated carbon improves the ability of biofilm to remove trace organic matter; the adsorption-desorption of activated carbon slows down the impact load of toxic substances Destruction of biofilm; bioregeneration of biofilm prolongs the working cycle of activated carbon. Therefore, although the price of GAC is significantly higher than that of non-adsorbent materials such as sand and gravel, it is still widely used. However, GAC also has its limitations as a biofilm carrier. The porosity of the activated carbon filter bed is low, the head loss of the filter layer is large, and it is easy to be blocked. Especially when the influent water quality is poor. Furthermore, GAC should not be used under aeration and oxygenation conditions, that is, GAC cannot be used as a filler in a biological contact oxidation reactor.

本实用新型的目的在于设计一种挂膜快、水头损失小、耐水力冲刷和毒物冲击负荷、去除微量有机物能力强、能作为生物接触氧化反应器运行的生物膜净化器。The purpose of the utility model is to design a biofilm purifier with fast film formation, small water head loss, resistance to hydraulic erosion and poison impact load, strong ability to remove trace organic matter, and can operate as a biological contact oxidation reactor.

为了达到上述目的,本实用新型是通过下述方案实现的。净化器包括进水管、出水收集管、复合填料、复合填料支架、曝气管、排泥、放空管和池体,其结构要点是:池体内的复合填料由母体材料与用粘结剂粘结在其表面的颗粒活性炭层组成,母体材料可以是市售的堆积式填料,也可以按工艺要求自行设计加工母体材料。无论采用金属、陶瓷还是塑料,由于表面粘有一层颗粒活性炭,使复合填料具有粗糙的表面与发达的表面孔隙结构,为微生物的生长繁殖提供了理想的环境。原水或废水通过复合填料表面固着的微生物吸附、降解得到净化,合格清水从出水收集管排出,污泥和杂质从排泥、放空管排除。In order to achieve the above object, the utility model is achieved through the following schemes. The purifier includes water inlet pipe, water outlet collection pipe, composite filler, composite filler bracket, aeration pipe, mud discharge, vent pipe and pool body. It is composed of a granular activated carbon layer on its surface. The parent material can be a commercially available stacked filler, or it can be designed and processed according to the process requirements. Regardless of the use of metal, ceramics or plastics, the composite filler has a rough surface and a developed surface pore structure due to a layer of granular activated carbon sticking to the surface, providing an ideal environment for the growth and reproduction of microorganisms. Raw water or waste water is purified through the adsorption and degradation of microorganisms fixed on the surface of the composite filler. The qualified clean water is discharged from the water outlet collection pipe, and the sludge and impurities are discharged from the sludge discharge and vent pipe.

本实用新型的优点是:The utility model has the advantages of:

1.用表面粘结有活性炭层的复合填料组成的生物膜净化器,因其表面粗糙与孔隙发达,微生物挂膜快,启动时间短,对水力负荷变化的适应性强,活性碳吸附与生物膜氧化的协同作用对使得净化器对毒物及难降解或微量有机物的去除效率高。1. The biofilm purifier composed of composite filler with activated carbon layer bonded on the surface, because of its rough surface and developed pores, quick microbial film formation, short start-up time, strong adaptability to hydraulic load changes, activated carbon adsorption and biological The synergistic effect of membrane oxidation makes the purifier have high removal efficiency for poisons and refractory or trace organic substances.

2.采用市售堆积式填料或按工艺要求设计加工的材料为母体材料的本实用新型的复合填料,具有比表面积大、水头损失小、填料不易堵塞、应用范围广,适用于淋洒式、淹没暴气式及转盘式等各类生物膜净化器。2. The composite filler of this utility model adopts the commercially available stacked filler or the material designed and processed according to the technical requirements as the parent material, which has a large specific surface area, small water head loss, is not easy to block the filler, and has a wide range of applications. It is suitable for showering, Submerge all kinds of biofilm purifiers such as storm type and rotary type.

3.复合填料上生物膜有较强的恢复能力及填料的吸附能力产生的缓冲作用,使得生物处理工艺更适合容易发生毒物或水力冲击负荷的场合,以及经常中断运行的场合。3. The biofilm on the composite filler has a strong recovery ability and the buffering effect of the adsorption capacity of the filler, making the biological treatment process more suitable for occasions where poisons or hydraulic shock loads are prone to occur, and where operations are often interrupted.

附图为本实用新型的实施例Accompanying drawing is embodiment of the utility model

图1.为本实用新型的结构示意图。Fig. 1. is the structural representation of the utility model.

图2-1为复合填料的结构放大图Figure 2-1 is an enlarged view of the structure of the composite filler

图2-2为组合式复合填料的结构示意图Figure 2-2 is a schematic diagram of the structure of the combined composite filler

图2-3为堆积式复合填料的结构示意图Figure 2-3 is a schematic diagram of the structure of the stacked composite filler

结合附图对本实用新型作进一步的描述。The utility model will be further described in conjunction with the accompanying drawings.

本实用新型由进水管6、出水收集管7、复合填料8、复合填料支架9、曝气管10、排泥、放空管11、池体12构成。池体12上部设进水管6,中间设由复合填料支架9所支撑的复合填料8,下部设采集经处理合格水的出水收集管7,底部设排泥、放空管11,复合填料支架9与出水收集管7之间设有曝气管10。The utility model is composed of water inlet pipe 6, water outlet collecting pipe 7, composite filler 8, composite filler support 9, aeration pipe 10, mud discharge and emptying pipe 11, and pool body 12. The upper part of the pool body 12 is provided with a water inlet pipe 6, the middle is provided with a composite filler 8 supported by a composite filler bracket 9, the lower part is provided with an outlet collection pipe 7 for collecting treated qualified water, the bottom is provided with a mud discharge and emptying pipe 11, and a composite filler bracket 9 An aeration pipe 10 is arranged between the outlet water collecting pipe 7 .

用塑料、金属、陶瓷等板材或其它母体材料1上涂覆一层胶粘剂2,如环氧树脂胶粘剂,在胶粘剂固化之前,将活性炭颗粒3洒布在该表面上,压紧,待胶液固化,表面粘有颗粒活性炭层3的母体材料1按工艺要求自行设计加工拼结成组合式复合填料4;同样也可用于转盘式生物滤池的转盘制作。Coat a layer of adhesive 2, such as epoxy resin adhesive, on plastic, metal, ceramic and other plates or other matrix materials 1. Before the adhesive is cured, sprinkle activated carbon particles 3 on the surface, press it tightly, and wait for the glue to cure. , the parent material 1 with granular activated carbon layer 3 stuck on the surface is designed, processed and spliced into a combined composite filler 4 according to the process requirements; it can also be used for the production of the turntable of the turntable biofilter.

作为母体材料1的市售的堆积式标准填料,例如鲍尔环、拉西环等用环氧树脂胶液2涂浸环的表面,在胶液固化之前,将填料环投入经清洗烘干的颗粒活性炭中翻动,胶粘剂固化后,得到表面覆盖着颗粒活性炭3的堆积式复合填料8。本实用新型中采用的复合填料的表面颗粒活性炭可利用水处理,特别是给水处理中的废弃颗粒活性炭制造,这样可降低成本,而产品的使用效果基本不变。Commercially available stacked standard packing as the parent material 1, such as Pall rings, Raschig rings, etc., are coated with epoxy resin glue 2 to impregnate the surface of the ring, and before the glue is cured, put the packing ring into the cleaned and dried Stir in the granular activated carbon, and after the adhesive is cured, a stacked composite filler 8 whose surface is covered with granular activated carbon 3 is obtained. The surface granular activated carbon of the composite filler used in the utility model can be manufactured by using water treatment, especially waste granular activated carbon in water treatment, so that the cost can be reduced, and the use effect of the product is basically unchanged.

Claims (3)

1.一种新型的生物膜净化器,包括进水管(6)、出水收集管(7)、复合填料(8)、复合填料支架(9)、曝气管(10)、排泥、放空管(11)、池体(12),其特征在于:复合填料(8)是由母体材料(1)与用胶粘剂(2)粘结在其表面的颗粒活性炭层(3)构成。1. A new type of biofilm purifier, including water inlet pipe (6), outlet water collection pipe (7), composite filler (8), composite filler bracket (9), aeration pipe (10), mud discharge, and venting The pipe (11) and the pool body (12) are characterized in that the composite filler (8) is composed of a parent material (1) and a granular activated carbon layer (3) bonded on its surface with an adhesive (2). 2.根据权利要求1所述的净化器,其特征在于:所述的母体材料(1)可以是市售的堆积式填料,也可以按工艺要求自行设计加工。2. The purifier according to claim 1, characterized in that: said matrix material (1) can be a commercially available stacked packing, or can be designed and processed by itself according to technological requirements. 3.根据权利要求1所述的净化器,其特征在于:所述的颗粒活性碳(3)可以用给水处理使用过后废弃的活性碳。3. The purifier according to claim 1, characterized in that: the granular activated carbon (3) can use feed water to treat waste activated carbon after use.
CN96229685U 1996-04-19 1996-04-19 Biological film purifying device Expired - Fee Related CN2250352Y (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103130336A (en) * 2011-12-02 2013-06-05 新奥科技发展有限公司 Reinforced biological stuffing and preparation method thereof
CN104773815A (en) * 2015-03-23 2015-07-15 厦门大学 Method utilizing active carbon to control MBR membrane pollution
CN105565481A (en) * 2015-12-29 2016-05-11 广东石油化工学院 Method for modifying biological filler with oyster shell powder
CN108383335A (en) * 2018-05-08 2018-08-10 江苏省环境科学研究院 High-concentration organic wastewater treatment system and method
CN109200998A (en) * 2018-09-08 2019-01-15 天津大学 It discarded active carbon, preparation method in biological activated carbon method advanced water treatment technique and reapplies

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103130336A (en) * 2011-12-02 2013-06-05 新奥科技发展有限公司 Reinforced biological stuffing and preparation method thereof
CN104773815A (en) * 2015-03-23 2015-07-15 厦门大学 Method utilizing active carbon to control MBR membrane pollution
CN105565481A (en) * 2015-12-29 2016-05-11 广东石油化工学院 Method for modifying biological filler with oyster shell powder
CN105565481B (en) * 2015-12-29 2018-06-19 广东石油化工学院 A kind of method of oyster shell powder modification biological filler
CN108383335A (en) * 2018-05-08 2018-08-10 江苏省环境科学研究院 High-concentration organic wastewater treatment system and method
CN108383335B (en) * 2018-05-08 2023-09-19 江苏省环境科学研究院 High-concentration organic wastewater treatment system and method
CN109200998A (en) * 2018-09-08 2019-01-15 天津大学 It discarded active carbon, preparation method in biological activated carbon method advanced water treatment technique and reapplies

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