CN217591176U - Dielectric barrier discharge reactor capable of reducing temperature - Google Patents
Dielectric barrier discharge reactor capable of reducing temperature Download PDFInfo
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- CN217591176U CN217591176U CN202221515255.8U CN202221515255U CN217591176U CN 217591176 U CN217591176 U CN 217591176U CN 202221515255 U CN202221515255 U CN 202221515255U CN 217591176 U CN217591176 U CN 217591176U
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- 230000004888 barrier function Effects 0.000 title claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims abstract description 32
- 238000000746 purification Methods 0.000 claims abstract description 22
- 238000001816 cooling Methods 0.000 claims abstract description 21
- 239000003054 catalyst Substances 0.000 claims abstract description 16
- 239000002826 coolant Substances 0.000 claims abstract description 13
- 238000007789 sealing Methods 0.000 claims description 8
- 238000004891 communication Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 5
- 238000009776 industrial production Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 21
- 239000006227 byproduct Substances 0.000 description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
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Abstract
本实用新型公开了一种可降温介质阻挡放电反应器,其包括反应管、冷却管、净化管、高压电极、接地电极,反应管上部通过连通管与净化管上部连接,高压电极通过密封塞设置在反应管内,反应管底部设置有气体进口,接地电极套设在反应管外且与高压电极相对应,冷却管套设在接地电极外,冷却管上设置有冷却介质进口、冷却介质出口;净化管底部开有气体出口,净化管顶部密封,高压电极、接地电极与电源连接;本实用新型装置解决了在产生低温等离子体过程中反应器温度升高影响催化剂活性的问题,并且可以连续净化气体,本装置结构简单,适于工业化生产和市场推广应用。
The utility model discloses a temperature-reducing dielectric barrier discharge reactor, which comprises a reaction tube, a cooling tube, a purification tube, a high-voltage electrode and a grounding electrode. In the reaction tube, the bottom of the reaction tube is provided with a gas inlet, the ground electrode is sleeved outside the reaction tube and corresponds to the high-voltage electrode, the cooling tube is sleeved outside the ground electrode, and the cooling tube is provided with a cooling medium inlet and a cooling medium outlet; purification; There is a gas outlet at the bottom of the tube, the top of the purification tube is sealed, and the high-voltage electrode and the ground electrode are connected to the power supply; the device of the utility model solves the problem that the temperature of the reactor increases and affects the activity of the catalyst in the process of generating low-temperature plasma, and can continuously purify the gas , The device has a simple structure and is suitable for industrial production and market promotion and application.
Description
技术领域technical field
本实用新型属于低温等离子体技术领域,具体为一种可降温介质阻挡放电反应器。The utility model belongs to the technical field of low temperature plasma, in particular to a dielectric barrier discharge reactor capable of reducing temperature.
背景技术Background technique
低温等离子体中的高能电子轰击物质分子,可以打开分子键,使物质电离、解离和激发,引发了一系列物理、化学反应,甚至可以发生常规热力学不能进行的反应,在气体污染控制方面已受广泛的关注和研究。但是在产生低温等离子体的过程中部分电能会转化成热能,使得反应器温度升高,影响催化剂的活性,且低温等离子体协同催化剂处理目标气体的过程中,还会生成其它的副产物,需要进一步处理。High-energy electrons in low-temperature plasma bombard matter molecules, which can open molecular bonds, ionize, dissociate and excite matter, triggering a series of physical and chemical reactions, and even reactions that cannot be carried out by conventional thermodynamics. received extensive attention and research. However, in the process of generating low-temperature plasma, part of the electrical energy will be converted into heat energy, which will increase the temperature of the reactor and affect the activity of the catalyst. In the process of cooperating with the catalyst to treat the target gas, other by-products will also be generated. further processing.
实用新型内容Utility model content
为了克服在产生低温等离子体的过程中反应器温度升高,影响催化剂活性,并且经等离子体协同催化剂处理后,气体还需进一步除去副产物的问题,本实用新型提供了一种可降温介质阻挡放电反应器,本反应器还可以处理后续产生的杂志气体。In order to overcome the problem that the temperature of the reactor increases in the process of generating low-temperature plasma, which affects the activity of the catalyst, and the gas needs to further remove by-products after the plasma is treated with the catalyst, the utility model provides a cooling medium barrier Discharge reactor, this reactor can also process the subsequent produced magazine gas.
本可降温介质阻挡放电反应器包括反应管、冷却管、净化管、高压电极、接地电极,反应管上部通过连通管与净化管上部连接,放电电极通过密封塞设置在反应管内,反应管底部设置有气体进口,接地电极套设在反应管外且与放电电极相对应,冷却管套设在接地电极外,冷却管上设置有冷却介质进口、冷却介质出口;净化管底部开有气体出口,净化管顶部密封,高压电极、接地电极与电源连接。The temperature-reducing dielectric barrier discharge reactor includes a reaction tube, a cooling tube, a purification tube, a high-voltage electrode, and a ground electrode. The upper part of the reaction tube is connected to the upper part of the purification tube through a communication tube, the discharge electrode is set in the reaction tube through a sealing plug, and the bottom of the reaction tube is set There is a gas inlet, the grounding electrode is sleeved outside the reaction tube and corresponds to the discharge electrode, the cooling pipe is sleeved outside the grounding electrode, and the cooling pipe is provided with a cooling medium inlet and a cooling medium outlet; The top of the tube is sealed, and the high voltage electrode and the ground electrode are connected to the power supply.
所述接地电极为圆筒状电极,冷却管为夹层的圆筒。The ground electrode is a cylindrical electrode, and the cooling pipe is a sandwiched cylinder.
所述净化管顶部密封通过密封塞密封。The top of the purge tube is sealed with a sealing plug.
使用时,在反应管、净化管中放置常规催化剂,反应管中放置用于去除气体中目标物的常规催化剂,净化管中放置用于去除经过反应管处理后产生的其他副产气体的催化剂,在冷却管中通入常规冷却介质(水等)。When in use, a conventional catalyst is placed in the reaction tube and the purification tube, a conventional catalyst for removing the target in the gas is placed in the reaction tube, and a catalyst for removing other by-product gases generated after the treatment of the reaction tube is placed in the purification tube, A conventional cooling medium (water, etc.) is passed through the cooling pipe.
本实用新型的优点和技术效果:The advantages and technical effects of the present utility model:
采用本实用新型装置处理含多种杂质的待净化气体,气体经过放电区域被电离激发,同时在催化剂协同作用下去除气体中污染物,再进入净化管实现后续副产气体的净化,过程中放电区域部分电能转换成热能,通过冷却介质交换热量,控制放电区的温度;本装置可以避免在低温等离子体产生过程中反应器温度升高,影响催化剂活性的问题,本装置结构简单,适于工业化生产和市场推广应用。The device of the utility model is used to treat the gas to be purified containing a variety of impurities. The gas is ionized and excited through the discharge area, and at the same time, the pollutants in the gas are removed under the synergistic action of the catalyst, and then enters the purification tube to realize the purification of the subsequent by-product gas. Part of the electric energy in the area is converted into heat energy, and the heat is exchanged through the cooling medium to control the temperature of the discharge area; the device can avoid the problem that the temperature of the reactor increases during the low-temperature plasma generation process, which affects the activity of the catalyst. The device has a simple structure and is suitable for industrialization. Production and marketing applications.
附图说明Description of drawings
图1为本实用新型装置结构示意图;Fig. 1 is the structural representation of the utility model device;
图2为本装置使用状态结构示意图;Fig. 2 is a schematic diagram of the structure of the device in use;
图中:1-反应管;2-冷却管;3-净化管;4-高压电极;5-接地电极;6-连通管;7-密封塞;8-气体进口;9-冷却介质进口;10-冷却介质出口;11-气体出口;12-催化剂。In the figure: 1-reaction tube; 2-cooling tube; 3-purification tube; 4-high voltage electrode; 5-grounding electrode; 6-connecting tube; 7-sealing plug; 8-gas inlet; 9-cooling medium inlet; 10 - cooling medium outlet; 11 - gas outlet; 12 - catalyst.
具体实施方式Detailed ways
下面通过附图和实施例对本实用新型作进一步详细说明,但本实用新型保护范围不局限于所述内容。The present utility model will be described in further detail below through the accompanying drawings and embodiments, but the protection scope of the present utility model is not limited to the content.
实施例1:如图1所示,本可降温介质阻挡放电反应器包括反应管1、冷却管2、净化管3、高压电极4、接地电极5,反应管1为中空圆管,反应管顶部通过密封塞7(橡胶塞)密封,高压电极4穿过密封塞7设置在反应管1内,高压电极为不锈钢电极,反应管1底部设置有气体进口8,反应管1上部的出气口通过连通管6与净化管3上部的进气口连接,净化管3顶部通过密封塞密封,净化管3底部开有气体出口11,圆筒状不锈钢接地电极5套设在反应管1外且与高压电极相对应,冷却管2套设在接地电极5外,冷却管为夹层的圆筒,即接地电极夹在反应管外壁和冷却管内壁之间;冷却管2下部设置有冷却介质进口9、上部设置有冷却介质出口10且均与夹层连通,高压电极、接地电极与电源连接;Example 1: As shown in Figure 1, the temperature-reducing dielectric barrier discharge reactor includes a reaction tube 1, a
使用该反应器用于处理含COS的天然气,如图2所示,在反应管的放电区中填充用于去除COS的针对性催化剂,在净化管中填充用于去除SO2的催化剂12,将含有COS的待处理气体从气体进口8通入反应管1中,气体经过放电区,在低温等离子体和催化剂的共同作用下,气体中的COS被转化为SO2和CO等,反应过程中,在冷却管中通入25℃水,用于调节反应管温度,反应后气体通过连通管6进入净化管3中,在催化剂作用下进一步去除净化COS过程中产生的微量SO2副产物,净化后气体从气体出口11外排。This reactor is used to treat natural gas containing COS, as shown in Fig. 2, a targeted catalyst for removing COS is filled in the discharge area of the reaction tube, and a catalyst 12 for removing SO2 is filled in the purification tube, and the The gas to be treated of COS is introduced into the reaction tube 1 from the
最后应当说明的是,以上内容仅用于说明本实用新型的技术方案,并非对本实用新型保护范围进行限制,本领域的普通技术人员对本实用新型的技术方案进行的简单修改或者等同替换,均不脱离本实用新型技术方案的实质和范围。Finally, it should be noted that the above content is only used to illustrate the technical solution of the present invention, and does not limit the protection scope of the present invention. It deviates from the essence and scope of the technical solution of the present invention.
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