CN211111203U - Portable degassing unit of integral type - Google Patents
Portable degassing unit of integral type Download PDFInfo
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- CN211111203U CN211111203U CN201921421071.3U CN201921421071U CN211111203U CN 211111203 U CN211111203 U CN 211111203U CN 201921421071 U CN201921421071 U CN 201921421071U CN 211111203 U CN211111203 U CN 211111203U
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- 238000007872 degassing Methods 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002131 composite material Substances 0.000 claims abstract description 9
- 230000001954 sterilising effect Effects 0.000 claims abstract description 9
- 150000001875 compounds Chemical class 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 4
- 238000007789 sealing Methods 0.000 claims description 4
- 238000004146 energy storage Methods 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims 1
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 26
- 229910052751 metal Inorganic materials 0.000 abstract description 10
- 239000002184 metal Substances 0.000 abstract description 10
- 239000000447 pesticide residue Substances 0.000 abstract description 9
- 239000000575 pesticide Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 10
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 229910052697 platinum Inorganic materials 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 229910052741 iridium Inorganic materials 0.000 description 3
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
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- 239000000956 alloy Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 1
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- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
- 229950001327 dichlorvos Drugs 0.000 description 1
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
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Abstract
Description
技术领域technical field
本实用新型涉及一种一体式便携水消毒装置。The utility model relates to an integrated portable water disinfection device.
背景技术Background technique
臭氧具有较强的氧化性,臭氧在水中可发生氧化还原反应,生成具有较高反应活性的羟基自由基、超氧阴离子自由基及氢化臭氧自由基等。因此,臭氧在水中具有极佳的杀菌作用,能够杀死细菌、真菌及其孢子、病毒和原生生物等绝大多数微生物。有鉴于此,在消毒领域中,臭氧被广泛应用。与此同时,就臭氧的发生方式来看,目前有一种技术是以水为媒介,采用电化学的方式利用金属电极的氧化还原作用来产生臭氧并进行消毒,也有相关的消毒装置进入市场销售。Ozone has strong oxidizing properties, and ozone can undergo redox reactions in water to generate hydroxyl radicals, superoxide anion radicals and hydrogenated ozone radicals with high reactivity. Therefore, ozone has an excellent bactericidal effect in water and can kill most microorganisms such as bacteria, fungi and their spores, viruses and protists. In view of this, in the field of disinfection, ozone is widely used. At the same time, in terms of the way of ozone generation, there is currently a technology that uses water as the medium, and uses the redox effect of metal electrodes to generate ozone and disinfect it electrochemically. There are also related disinfection devices that are sold in the market.
然而,纵观现有的电化学消毒装置,有以下几个方面存在显著的问题需要解决:(1)目前的电压输出为线性输出,即为恒定电压输出,当电压较低时,传统的片状金属电极(不锈钢、钛、铂等材料制备)的响应电流较低,臭氧生成效率低,导致消毒效率也低;(2)当电压高时,虽然响应电流变高,但是片状金属电极表面会不断产生大量气泡,气泡在破灭之前会隔绝片状金属电极表面与水接触,从而降低消毒的效率;(3)一段时间使用后,片状金属电极表面会覆盖水垢,从而影响臭氧生成,降低消毒效率;进一步地,时间一久,就会造成该片状金属电极无法使用,需要更换新的片状金属电极。However, looking at the existing electrochemical disinfection devices, there are significant problems that need to be solved in the following aspects: (1) The current voltage output is a linear output, that is, a constant voltage output. When the voltage is low, the traditional chip The response current of the metal electrode (made of stainless steel, titanium, platinum, etc.) is low, the ozone generation efficiency is low, and the disinfection efficiency is also low; (2) When the voltage is high, although the response current becomes high, the surface of the sheet metal electrode is high. A large number of air bubbles will continue to be generated, and before the bubbles burst, the surface of the sheet metal electrode will be isolated from contact with water, thereby reducing the efficiency of disinfection; (3) After a period of use, the surface of the sheet metal electrode will be covered with scale, which will affect the generation of ozone and reduce the Disinfection efficiency; further, over time, the sheet metal electrode will become unusable, and a new sheet metal electrode needs to be replaced.
发明内容SUMMARY OF THE INVENTION
为了克服上述技术缺陷,本实用新型提供了一种一体式便携水消毒装置,该装置由上防水外壳、控制单元、电极单元和下防水外壳组成,通过复合频率和极性切换的电压输出模式以及金属膜处理后的电极,相比于现有技术手段能够大幅度提高电流强度、提升杀菌的效率,同时可以减少电极片表面的水垢沉积,延长使用寿命。与此同时,该装置还能够清除水中物体(水果、蔬菜等)表面的残留农药。In order to overcome the above technical defects, the present utility model provides an integrated portable water disinfection device, which is composed of an upper waterproof casing, a control unit, an electrode unit and a lower waterproof casing. Compared with the existing technical means, the electrode treated with the metal film can greatly increase the current intensity and improve the efficiency of sterilization, and at the same time, it can reduce the scale deposition on the surface of the electrode sheet and prolong the service life. At the same time, the device can also remove residual pesticides on the surface of objects (fruits, vegetables, etc.) in the water.
为实现上述目的,本实用新型提供如下技术方案:To achieve the above object, the utility model provides the following technical solutions:
一种一体式便携消毒装置,包括上防水外壳、控制单元、电极单元和下防水外壳;其中,上防水外壳和下防水外壳通过螺丝相互对接固定,能够实现防水功能;控制单元由电源、充电插口、控制电路和开关组成,通过螺丝固定在下防水外壳内部,能够实现开关机、充电、电压复合频率和极性切换输出功能;电极单元由上电极外壳、上电极、垫片、下电极和下电极外壳组成,通过电极单元连接口固定在上下防水外壳之间,能够实现通电后在水中生成臭氧的功能。An integrated portable disinfection device includes an upper waterproof casing, a control unit, an electrode unit and a lower waterproof casing; wherein, the upper waterproof casing and the lower waterproof casing are butted and fixed with each other by screws, which can realize the waterproof function; the control unit is composed of a power supply, a charging socket It consists of a control circuit and a switch, which is fixed inside the lower waterproof shell by screws, which can realize the functions of switching on and off, charging, voltage compound frequency and polarity switching; the electrode unit consists of an upper electrode shell, an upper electrode, a gasket, a lower electrode and a lower electrode. It consists of a shell, which is fixed between the upper and lower waterproof shells through the electrode unit connection port, which can realize the function of generating ozone in the water after power-on.
上防水外壳包含一个悬挂孔、一个圆形电极孔、一个开关孔、四个螺丝孔和密封圈;下防水外壳包含一个悬挂孔、一个电极外壳孔、一个上防水外壳的圆形电极孔大小形状一致的圆形电极孔、一个充电插口孔、四个与上防水外壳对应的螺丝孔、两根电源固定柱、两个控制电路固定螺丝孔、一个开关固定螺丝孔、一个电极单元连接口。The upper waterproof shell contains a hanging hole, a circular electrode hole, a switch hole, four screw holes and a sealing ring; the lower waterproof shell contains a hanging hole, an electrode shell hole, and a circular electrode hole size and shape of the upper waterproof shell Consistent circular electrode hole, a charging socket hole, four screw holes corresponding to the upper waterproof shell, two power supply fixing posts, two control circuit fixing screw holes, a switch fixing screw hole, and an electrode unit connection port.
控制单元中的充电插口通过螺纹固定在下防水外壳的充电插口孔中,并与电源连接,能够与外部充电线连接,实现外部电能输入至电源;电源通过两根电源固定柱固定在下防水外壳中,通过导线与控制电路、开关以及电极单元相连,实现电能储存和电能输出;控制电路通过螺丝与两个固定螺丝孔固定在下防水外壳中,通过导线与电源连接,实现控制电源以正级10、100、1000Hz复合频率和负极1000、100、10Hz复合频率的循环方式输出电压给电极单元;开关通过螺丝与一个固定螺丝孔固定在下防水外壳中,同时与上防水外壳的开关孔契合,控制装置的开机和关机。The charging socket in the control unit is fixed in the charging socket hole of the lower waterproof shell by threads, and is connected with the power supply, which can be connected with an external charging line to realize the input of external power to the power supply; the power supply is fixed in the lower waterproof shell through two power supply fixing posts, It is connected with the control circuit, switch and electrode unit through wires to realize electric energy storage and electric energy output; the control circuit is fixed in the lower waterproof casing through screws and two fixing screw holes, and is connected with the power supply through wires to realize the control power supply with positive level 10, 100 , 1000Hz composite frequency and negative 1000, 100, 10Hz composite frequency cycle mode to output voltage to the electrode unit; the switch is fixed in the lower waterproof casing by screws and a fixing screw hole, and at the same time fits with the switch hole of the upper waterproof casing to control the startup of the device. and shutdown.
电极单元按照上电极外壳、上电极、垫片、下电极和下电极外壳的顺序组装;其中,上电极外壳外周形状与下防水外壳的电极外壳孔一致,中间含有一个大小与上防水外壳的圆形电极孔一致的圆孔,内部含有三根固定杆;上电极为含有正方形筛格的圆形,底端有电源连接片,圆形大小与上电极外壳中间的圆孔一致,筛格边长为1.5毫米;垫片为圆形,大小与上电极一致,内部含有三根固定杆;下电极为含有正方形筛格的圆形,底端有电源连接片,圆形大小与下电极外壳中间的圆孔一致,筛格边长为1.5毫米;下电极外壳外周形状与下防水外壳的电极外壳孔一致,中间含有一个大小与下防水外壳的圆形电极孔一致的圆孔,内部含有三根固定杆。The electrode unit is assembled in the order of the upper electrode shell, the upper electrode, the gasket, the lower electrode and the lower electrode shell; wherein, the outer shape of the upper electrode shell is consistent with the electrode shell hole of the lower waterproof shell, and there is a circle in the middle with the size of the upper waterproof shell. It is a round hole with the same shape as the electrode holes, and contains three fixed rods inside; the upper electrode is a circle with a square grid, and there is a power connection piece at the bottom. The size of the circle is the same as the hole in the middle of the upper electrode shell. 1.5 mm; the gasket is circular, the size is the same as the upper electrode, and contains three fixing rods; the lower electrode is a circle with a square grid, and the bottom end has a power connection piece, the size of the circle is the same as the round hole in the middle of the lower electrode shell Consistent, the side length of the screen grid is 1.5 mm; the outer shape of the lower electrode shell is consistent with the electrode shell hole of the lower waterproof shell, and there is a circular hole in the middle with the same size as the circular electrode hole of the lower waterproof shell, and there are three fixed rods inside.
上电极和下电极的构成材料为钛基底,表面按照2:1:1的含量比例覆盖铂、钯和铱,厚度为0.2至0.5微米。The constituent material of the upper electrode and the lower electrode is a titanium substrate, and the surface is covered with platinum, palladium and iridium according to the content ratio of 2:1:1, and the thickness is 0.2 to 0.5 microns.
本实用新型具有以下优点及有益效果:The utility model has the following advantages and beneficial effects:
相比于现有的技术及产品,本实用新型提供的技术方案具有以下几个显著的优点和进步:Compared with the existing technology and products, the technical solution provided by the present utility model has the following significant advantages and progress:
1、本实用新型技术方案采用正级10、100、1000Hz复合频率和负极1000、100、10Hz复合频率的循环方式输出电压给电极单元工作,一方面,可以让上下电极交替工作,从而减少单一电极产生气泡并阻碍消毒的时间,提升电极消毒和清除农残的效率;另一方面,通过正负变频电压交替施加的方式,迅速帮助电极表面脱附水体杂质,延缓水垢沉积,延长电极的使用寿命。1. The technical scheme of the present utility model adopts the cyclic mode of the compound frequency of positive level 10, 100, 1000Hz and the compound frequency of negative pole 1000, 100, 10Hz to output voltage to the electrode unit to work. On the one hand, the upper and lower electrodes can work alternately, thereby reducing the number of single electrodes. Generates bubbles and hinders the disinfection time, improving the efficiency of electrode disinfection and removal of pesticide residues; on the other hand, by alternately applying positive and negative variable frequency voltages, it quickly helps the electrode surface to desorb water impurities, delay scale deposition, and prolong the life of the electrode. .
2、本实用新型技术方案采用筛格式双层电极,相比于传统的片式电极,可以增加电极与水体的接触维度,进而提升消毒效率和清除农残的效率。2. The technical solution of the present utility model adopts a mesh-type double-layer electrode, which can increase the contact dimension between the electrode and the water body compared with the traditional sheet-type electrode, thereby improving the efficiency of disinfection and removal of pesticide residues.
3、本实用新型技术方案采用钛基底表面覆盖铂、钯和铱的合金式电极材料,可以增强电极在低电压条件下的响应电流,增加消毒和清除农残的效率,同时提高电极的耐腐蚀性,延长使用寿命。3. The technical scheme of the present utility model adopts the alloy electrode material in which the surface of the titanium base is covered with platinum, palladium and iridium, which can enhance the response current of the electrode under low voltage conditions, increase the efficiency of disinfection and removal of pesticide residues, and improve the corrosion resistance of the electrode at the same time. properties and prolong the service life.
为进一步说明本实用新型的结构特点和作用,以下结合附图以及实施例对本实用新型作进一步描述。In order to further illustrate the structural features and functions of the present utility model, the present utility model will be further described below with reference to the accompanying drawings and embodiments.
附图说明Description of drawings
图1是本实用新型具体实施例1的一体式便携消毒装置的结构示意图。FIG. 1 is a schematic structural diagram of an integrated portable disinfection device according to a specific embodiment 1 of the present invention.
图2是图1所示上防水外壳的结构示意图。FIG. 2 is a schematic structural diagram of the upper waterproof casing shown in FIG. 1 .
图3是图1所示下防水外壳的结构示意图。FIG. 3 is a schematic structural diagram of the lower waterproof casing shown in FIG. 1 .
图4是图1所示控制单元的结构示意图。FIG. 4 is a schematic structural diagram of the control unit shown in FIG. 1 .
图5是图1所示电极单元的结构示意图。FIG. 5 is a schematic structural diagram of the electrode unit shown in FIG. 1 .
其中,in,
1—上防水外壳,11—悬挂孔,12—圆形电极孔,13—开关孔,14—螺丝孔,15—密封圈;1—upper waterproof shell, 11—hanging hole, 12—circular electrode hole, 13—switch hole, 14—screw hole, 15—sealing ring;
2—下防水外壳,21—悬挂孔,22—电极外壳孔,23—圆形电极孔,24—充电插口孔,25—螺丝孔,26—电源固定柱,27—控制电路固定螺丝孔,28—开关固定螺丝孔,29—电极单元连接口2—lower waterproof case, 21—hanging hole, 22—electrode case hole, 23—circular electrode hole, 24—charging socket hole, 25—screw hole, 26—power fixing post, 27—control circuit fixing screw hole, 28 - Switch fixing screw hole, 29 - Electrode unit connection port
3—控制单元,31—电源,32—充电插口,33—控制电路,34—开关;3—control unit, 31—power supply, 32—charging socket, 33—control circuit, 34—switch;
4—电极单元,41—上电极外壳,42—上电极,43—垫片,44—下电极,45—下电极外壳。4—electrode unit, 41—upper electrode case, 42—upper electrode, 43—gasket, 44—lower electrode, 45—lower electrode case.
具体实施方式Detailed ways
如图1-图5所示,本实用新型的一种便携式消毒装置,包括上防水外壳1、下防水外壳2、控制单元3和电极单元4。其中,上防水外壳1和下防水外壳2通过螺丝相互对接固定,能够实现防水功能。As shown in FIGS. 1-5 , a portable disinfection device of the present invention includes an upper waterproof casing 1 , a lower
上防水外壳1包含一个悬挂孔11、一个圆形电极孔12、一个开关孔13、四个螺丝孔14和密封圈15。下防水外壳2包含一个悬挂孔21、一个电极外壳孔22、一个与上防水外壳1的圆形电极孔12大小形状一致的圆形电极孔23、一个充电插口孔24、四个与上防水外壳对应的螺丝孔25、两根电源固定柱26、两个控制电路固定螺丝孔27、一个开关固定螺丝孔28、一个电极单元连接口29。The upper waterproof casing 1 includes a
控制单元3由电源31、充电插口32、控制电路33和开关34组成,通过螺丝固定在下防水外壳2内部。其中,充电插口32通过螺纹固定在下防水外壳的充电插口孔24中,并与电源31连接,能够与外部充电线连接,实现外部电能输入至电源;电源31通过两根电源固定柱26固定在下防水外壳2中,通过导线与控制电路33、开关34以及电极单元4相连,实现电能储存和电能输出;控制电路33通过螺丝与两个固定螺丝孔27固定在下防水外壳2中,通过导线与电源31连接,实现控制电源31以正级10、100、1000Hz复合频率和负极1000、100、10Hz复合频率的循环方式输出电压给电极单元4;开关34通过螺丝与一个固定螺丝孔28固定在下防水外壳2中,同时与上防水外壳1的开关孔13契合,控制装置的开机和关机。The
电极单元4按照上电极外壳41、上电极42、垫片43、下电极44和下电极外壳45的顺序组装而成,通过电极单元连接口29固定在上防水外壳1和下防水外壳2之间。其中,上电极外壳41外周形状与下防水外壳2的电极外壳孔22一致,中间含有一个大小与上防水外壳1的圆形电极孔12一致的圆孔,内部含有三根固定杆;上电极42为含有正方形筛格的圆形,底端有电源连接片,圆形大小与上电极外壳41中间的圆孔一致,筛格边长为1.5毫米;垫片43为圆形,大小与上电极42一致,内部含有三根固定杆;下电极44与上电极42形状大小一致,为含有正方形筛格的圆形,底端有电源连接片,圆形大小与下电极外壳45中间的圆孔一致,筛格边长为1.5毫米;下电极外壳45外周形状与下防水外壳2的电极外壳孔22一致,中间含有一个大小与下防水外壳2的圆形电极孔23一致的圆孔,内部含有三根固定杆。上电极42和下电极45的构成材料为钛基底,表面按照2:1:1的含量比例覆盖铂、钯和铱,厚度为0.4微米。The
使用时,在容器中装5-10L水,将需要消毒或清除农残的物体放入水中后,打开装置开关,放入容器中。装置的控制电路控制电压以正级10、100、1000Hz复合频率和负极1000、100、10Hz复合频率的循环方式输出给上电极和下电极,以水为媒介,产生臭氧并对水体、水中的物体进行消毒或农残清除。When using, put 5-10L of water in the container, put the objects that need to be disinfected or remove pesticide residues into the water, turn on the switch of the device, and put it into the container. The control circuit of the device controls the voltage to be output to the upper electrode and the lower electrode in a cyclic manner of positive 10, 100, 1000 Hz composite frequency and negative 1000, 100, 10 Hz composite frequency, using water as a medium to generate ozone and affect the water body and objects in the water. Disinfection or pesticide residue removal.
为了更好地与现有技术及市售产品进行比较,分别以现有技术中的单片铂金电极消毒装置、正负级金属电解板消毒装置以及本实用新型技术方案装置,同时对相同的水体进行杀菌效率和水垢生成时间的对比。同时以蔬菜为样品,对本实用新型技术方案的清除农残效率进行测试。上述结果如表1所示:In order to better compare with the existing technology and the commercially available products, the single-piece platinum electrode disinfection device, the positive and negative metal electrolytic plate disinfection device and the technical solution device of the present invention in the prior art were used to treat the same water body at the same time. The sterilization efficiency and the scale generation time were compared. At the same time, taking vegetables as samples, the pesticide residue removal efficiency of the technical solution of the utility model is tested. The above results are shown in Table 1:
表1不同技术方案的水体杀菌效率、水垢生产时间和农残清除结果Table 1 Water sterilization efficiency, scale production time and pesticide residue removal results of different technical solutions
注1:指达到《GB 5749-2006生活饮用水卫生标准》微生物要求所需的时间。Note 1: Refers to the time required to meet the microbial requirements of "GB 5749-2006 Sanitation Standard for Drinking Water".
注2:指连续通电使用20分钟后断电10分钟为1次试验,肉眼可见观察到电极表面有水垢生成的次数。Note 2: Refers to the number of times of scale formation on the surface of the electrode that is observed with the naked eye.
注3:农药包括:乐果、敌敌畏和甲萘威Note 3: Pesticides include: dimethoate, dichlorvos and carbaryl
从表1中可以看出,相比于现有技术装置,采用本实用新型技术方案提供的电化学消毒装置能够在更短的时间内完成消毒,显著提高了消毒效率;同时,显著延长了电极表面水垢生成的时间,能够延长装置的使用寿命。进一步地,本实用新型技术方案的消毒装置能够在6分钟内对常见的农药残留达到99.4%的清除率,快速有效。As can be seen from Table 1, compared with the prior art device, the electrochemical disinfection device provided by the technical solution of the present utility model can complete the disinfection in a shorter time, significantly improving the disinfection efficiency; at the same time, significantly extending the electrode The time for scale formation on the surface can prolong the service life of the device. Further, the disinfection device of the technical solution of the present invention can achieve a removal rate of 99.4% for common pesticide residues within 6 minutes, which is fast and effective.
以上所述仅是本实用新型的特定实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本实用新型原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本实用新型的保护范围。The above are only specific implementations of the present invention. It should be pointed out that for those skilled in the art, without departing from the principles of the present invention, several improvements and modifications can also be made. These improvements and Retouching should also be regarded as the protection scope of the present invention.
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