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CN207680368U - A kind of equipment for denitrifying flue gas based on temperature-compensating - Google Patents

A kind of equipment for denitrifying flue gas based on temperature-compensating Download PDF

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Publication number
CN207680368U
CN207680368U CN201721784667.0U CN201721784667U CN207680368U CN 207680368 U CN207680368 U CN 207680368U CN 201721784667 U CN201721784667 U CN 201721784667U CN 207680368 U CN207680368 U CN 207680368U
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temperature
flue gas
compensating
gas
equipment
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张艺
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BEIJING AVIC TIANYE TECHNOLOGY Co Ltd
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BEIJING AVIC TIANYE TECHNOLOGY Co Ltd
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Abstract

The utility model belongs to gas denitrifying technology field, provides a kind of equipment for denitrifying flue gas based on temperature-compensating, including hot-blast stove, wind mixed chamber, SCR reactors and air-introduced machine;The air inlet of wind mixed chamber is connected to admission line and hot-blast stove respectively, the gas outlet of wind mixed chamber is connected to by steam line with SCR reactors, and the spray ammonia mouth being connected to ammonia gas supply system is equipped in steam line, the gas outlet of SCR reactors is connected to by outlet pipe with air-introduced machine.The utility model enables to flue-gas temperature to stablize the optimal use temperature in final catalyst, and the effective denitration for being suitable for various operating mode flue gases purifies, and improves denitration efficiency with denitration quality.

Description

A kind of equipment for denitrifying flue gas based on temperature-compensating
Technical field
The utility model is related to gas denitrifying technology field more particularly to a kind of denitrating flue gas dresses based on temperature-compensating It sets.
Background technology
The 67% of China's nitrogen oxides (abbreviation NOx) discharge comes from coal burning, the emission source polluted according to SO2, NOx Survey data shows that the key industry of SO2, NOx pollution control is thermoelectricity, steel, cement etc..With " 12th Five-Year Plan ", " 13 The denitration of the propulsion of five " emission reduction works, thermal power plant has been completed substantially, but with the development of efforts at environmental protection, other industry Denitration work is more severe, and cement, steel, the denitration of chemical industry and some Industrial Stoves are extremely urgent, the flue gas of these industries Complicated component, temperature is different, cannot indiscriminately imitate the design of power plant's denitration, needs targetedly to carry out technological innovation.
Currently, ripe denitration technology is broadly divided into two major classes, one kind for without using the selective non-catalytic of catalyst also Former technology (SNCR), another kind of is the SCR technology (SCR) for using catalyst;Wherein SCR is most ripe at present Gas denitrifying technology, it is method of denitration after a kind of stove, be using reducing agent (NH3, urea) under metallic catalyst effect, It is selectively reacted with NOx and generates N2 and H2O, rather than aoxidized by O2, therefore be known as " selectivity ".Popular SCR works in the world Skill is broadly divided into 2 kinds of ammonia process SCR and urea method SCR, this 2 kinds of methods are all the restoring function to NOx using ammonia, in catalyst Under the action of be reduced to NOx (mainly NO) to be not much air the N2 and water of influence, reducing agent NH3.
In the prior art, applied to the SCR catalyst in denitrating flue gas can be divided into high temperature catalyst (345 DEG C~590 DEG C), Middle temperature catalyst (260 DEG C~380 DEG C) and low temperature catalyst (80 DEG C~300 DEG C), the suitable reaction temperature of different catalyst It is different.If reaction temperature is relatively low, the activity of catalyst can reduce, and denitration efficiency is caused to decline, and if catalyst continues Operation can make catalyst that permanent damage occur under low temperature;If reaction temperature is excessively high, NH3 is oxidized easily, and NOx generation amount increases Add, can also cause the phase transformation of catalyst material, the activity of catalyst is made to degenerate.Domestic and international SCR system mostly uses greatly high temperature, reacts Temperature range is 315 DEG C~400 DEG C, but since the flue-gas temperature from flue gas source emission is different, it is difficult to so that flue-gas temperature is stablized In the optimal use temperature of final catalyst, therefore existing equipment for denitrifying flue gas can not be suitable for having for various operating mode flue gases Denitration purification is imitated, denitration efficiency is still to be improved.
Therefore, a kind of equipment for denitrifying flue gas based on temperature-compensating is developed, not only there is urgent researching value, it may have Good economic benefit and commercial application potentiality, this is exactly where the power that the utility model is accomplished and basis.
Utility model content
In order to overcome the defect of the prior art as indicated above, the present inventor to have made intensive studies this, paying After a large amount of creative works, so as to complete the utility model.
Specifically, technical problem to be solved in the utility model is:It is de- to provide a kind of flue gas based on temperature-compensating Nitre device is suitable for the effective de- of various operating mode flue gases so that flue-gas temperature stablizes the optimal use temperature in final catalyst Nitre purifies, and improves denitration efficiency.
In order to solve the above technical problems, the technical solution of the utility model is:
A kind of equipment for denitrifying flue gas based on temperature-compensating, including hot-blast stove, wind mixed chamber, SCR reactors and air-introduced machine;Institute The air inlet for stating wind mixed chamber is connected to admission line and the hot-blast stove respectively, and the gas outlet of the wind mixed chamber passes through steam line It is connected to the SCR reactors, and is equipped with the spray ammonia mouth being connected to ammonia gas supply system in the steam line, the SCR is anti- The gas outlet of device is answered to be connected to the air-introduced machine by outlet pipe.
As an improvement technical solution, further include the heat exchanger for realizing the admission line smoke pre-heating, institute Heat exchanger is stated respectively to be connected with the admission line and the outlet pipe.
As an improvement technical solution, temperature sensor, the temperature are equipped at the gas outlet position of the wind mixed chamber Degree sensor is electrically connected with the hot-blast stove.
As an improvement technical solution, the spray ammonia mouth be gridiron.
As an improvement technical solution, TiO2 catalytic carriers are equipped in the SCR reactors, the TiO2 catalysis carries Body be it is cellular, board-like or corrugated in one kind.
As an improvement technical solution, the admission line is communicated with purifying and dedusting device, and passes through the purification Dust-extraction unit is connected to flue gas source.
As an improvement technical solution, the gas outlet of the air-introduced machine is communicated with chimney.
After using above-mentioned technical proposal, the utility model has the beneficial effects that:
1, the wind mixed chamber being equipped with is with hot-blast stove, the lower pending flue gas of temperature being discharged from target process, by air inlet Pipeline is sent into wind mixed chamber, is mixed with the high-temperature flue gas from hot-blast stove in wind mixed chamber, so that it is guaranteed that drawing from wind mixed chamber gas outlet The flue-gas temperature gone out stablizes the optimal use temperature in final catalyst, and in steam line and from ammonia gas supply system Ammonia mixes so that the NOx in flue gas enters SCR reactors, the work of final catalyst in SCR reactors after being mixed with ammonia Under, reduction reaction occurs, removes the nitrogen oxides contained in flue gas, generates nitrogen and water, is discharged from after the purification of SCR reactors Air-flow pass through the power that air-introduced machine provides later into heat exchanger, by smoke stack emission, to realize the purification to flue gas Processing reduces pollution of the flue gas to environment, compares traditional equipment for denitrifying flue gas, enable to the difference introduced from admission line The flue gas of temperature stablizes the optimal use temperature in final catalyst after mixed processing, to obtain the denitration effect of efficient stable Fruit improves to the denitration efficiency of different temperatures flue gas with denitration quality, and the effective denitration for being suitable for various operating mode flue gases purifies.
2, the heat exchanger being equipped with can recycle and two to the waste heat that carries in flue gas is discharged from SCR reactors Secondary utilization carries out heat exchange with the low-temperature flue gas in admission line, realizes the preheating to pending flue gas, and then realize to heat Make full use of, saved the energy.
3, the temperature of supplying gas of wind mixed chamber gas outlet is measured in real time by temperature sensor, and it is real-time to detect signal Hot-blast stove is fed back to, real-time monitoring is carried out to the mixed flue gas in wind mixed chamber by hot-blast stove again, it is ensured that lead in SCR reactors Flue-gas temperature all-the-time stable in rated range value, pass through temperature sensor and constitute closed-loop control, control method is ripe, is real Reliable guarantee now is provided to the denitration process of flue gas efficient stable.
4, the grid-like spray ammonia mouth being equipped with, it is ensured that the ammonia sprayed by ammonia-spraying grid can be sufficiently effective mixed with flue gas It closes, provides effective guarantee for the catalysis reduction of follow-up flue gas, it is ensured that the clean-up effect of flue gas.
5, the purifying and dedusting device that admission line is communicated with, the flue gas that target process can be discharged are dusted filtering, The solid particulate matters such as the dust impurity contained in flue gas are avoided to impact the denitrification apparatus, so that the denitrating system energy Enough effective operations steady in a long-term, service life are long.
6, the external discharge of gas, good to the emission effect of flue gas after being handled by chimney realization, reduces to empty nearby The influence in compression ring border.
Description of the drawings
It, below will be right in order to illustrate more clearly of specific embodiment of the present invention or technical solution in the prior art Specific implementation mode or attached drawing needed to be used in the description of the prior art are briefly described.In all the appended drawings, similar Element or part are generally identified by similar reference numeral.In attached drawing, each element or part might not be according to actual ratios It draws.
Fig. 1 is the structural schematic diagram of the utility model;
Reference numeral:1- hot-blast stoves;2- wind mixed chamber;3-SCR reactors;4- air-introduced machines;5- heat exchangers;6- chimneys;7- into Feed channel;8- steam lines;9- outlet pipes;10- sprays ammonia mouth.
Specific implementation mode
The utility model is further illustrated with reference to specific embodiment.But the purposes of these exemplary embodiments Only it is used for enumerating the utility model with purpose, any type of any limit not is constituted to the real protection scope of the utility model It is fixed, it is more non-that the scope of protection of the utility model is confined to this.
As shown in Figure 1, present embodiments provide a kind of equipment for denitrifying flue gas based on temperature-compensating, including it is hot-blast stove 1, mixed Air compartment 2, SCR reactors 3 and air-introduced machine 4;The air inlet of wind mixed chamber 2 is connected to admission line 7 and hot-blast stove 1 respectively, wind mixed chamber 2 Gas outlet be connected to SCR reactors 3 by steam line 8, and the spray that is connected to ammonia gas supply system is equipped in steam line 8 Ammonia mouth 10, SCR reactors 3 are interior to be equipped with TiO2 catalytic carriers, and TiO2 catalytic carriers are with V2O5 or V2O5-WO3 or V2O5-MoO3 Active constituent, be made it is cellular, board-like or corrugated in one kind, in the present embodiment, TiO2 catalytic carriers are tied using cellular The gas outlet of structure, SCR reactors 3 is connected to by outlet pipe 9 with air-introduced machine 4, and the gas outlet of air-introduced machine 4 is communicated with chimney 6, is led to The external discharge that chimney 6 realizes flue gas after denitration is crossed, in such a way that chimney 6 realizes flue gas high altitude discharge, emission effect is good, and Reduce the influence to neighbouring air environment.
To realize to the accuracy controlling of flue gas mixing temperature in mixing chamber, temperature is equipped at the gas outlet position of wind mixed chamber 2 Sensor, temperature sensor are electrically connected with hot-blast stove 1, are carried out to the temperature of supplying gas of 2 gas outlet of wind mixed chamber by temperature sensor Detection in real time, and signal Real-time Feedback will be detected to hot-blast stove 1, the mixed flue gas in wind mixed chamber 2 is carried out again by hot-blast stove 1 Real-time monitoring, it is ensured that lead to the flue-gas temperature all-the-time stable in SCR reactors 3 in rated range value, pass through temperature sensor Closed-loop control is constituted, control method is ripe, and reliable guarantee is provided to the denitration process of flue gas efficient stable to realize;This implementation In example, hot-blast stove 1 is the air supply system that high temperature gas flow is provided to wind mixed chamber 2, and temperature sensor can be with the pipe electromagnetic of hot-blast stove 1 Valve is electrically connected, and various media may be used as heat source, such as natural gas, liquefied petroleum gas, coal, industry production in hot-blast stove 1 Raw high heat exhaust gas (including blast furnace gas, coal gas of converter, coke-stove gas etc.), alcohol, biogas etc..
In the present embodiment, the optimal use temperature of foundation catalyst, the mixed flue gas sent out from the gas outlet of wind mixed chamber 2 Temperature controls within 320~380 DEG C of value ranges, i.e., the detection rated value of temperature sensor is 320~380 DEG C, to ensure pair The denitration effect of the stability and high efficiency of flue gas.
For ensure by spray ammonia that ammonia mouth 10 sprays can with flue gas is sufficiently effective mixes, in the present embodiment, spray ammonia Mouth 10 is gridiron, and the ammonia of ammonia-spraying grid injection can be realized to be mixed with the sufficiently effective of flue gas, is follow-up flue gas Catalysis reduction provide effective guarantee, it is ensured that the clean-up effect of flue gas.
The mixed airflow for the flue gas and ammonia that temperature is stablized is sent anti-to generation reduction in SCR reactors 3 through steam line 8 Answer, realize and the denitration of flue gas is purified, remove the nitrogen oxides contained in flue gas, wherein react in SCR reactors 3 as Under:
In the present embodiment, be additionally provided with to realize the heat exchanger 5 of 7 smoke pre-heating of admission line, heat exchanger 5 respectively with air inlet Pipeline 7 is connected with outlet pipe 9;The heat exchanger 5 being equipped with, can be to being discharged the waste heat carried in flue gas from SCR reactors 3 Recycle and the low-temperature flue gas in secondary use, with admission line 7 carry out heat exchange, realizes the preheating to pending flue gas, And then realize and heat is made full use of, save the energy.
Certainly, admission line 7 is also communicated with purifying and dedusting device, and is connected to flue gas source by purifying and dedusting device, energy It is enough that filtering is dusted to the flue gas that target process is discharged, avoid the solid particulate matters such as the dust impurity contained in flue gas de- to this Nitre device impacts, so that the denitrating system can effectively be run steadily in the long term, service life is long.
Wherein, structure identical with existing denitrification apparatus can be used in the purifying and dedusting device mentioned in the present embodiment, Since it is conventional technical means in the prior art, known together by those skilled in the art, and therefore not to repeat here.
In the present embodiment, ammonia gas supply system directly evaporates ammonium hydroxide using high-temperature hot-air, will by ammonium hydroxide metering conveying pump Ammonium hydroxide in tank used for storing ammonia is delivered to ammonium hydroxide evaporator, while under the action of the compressed air of compressed air line conveying, will Ammonium hydroxide is injected directly into ammonium hydroxide evaporator after being atomized by twin spray gun, the ammonium hydroxide after atomization with from ammonium hydroxide evaporator bottom end The heat smoke of introducing mixes, and under the action of high warm flue gas, and then realizes the vaporization to ammonium hydroxide, the ammonia after vaporization is through ammonia- Air pipe line is delivered to ammonia-spraying grid, and flue before SCR reactors 3, i.e. steam line 8 are uniformly sprayed by ammonia-spraying grid, realizes Ammonia is mixed with the uniform of pending flue gas, for being subsequently sent into 3 denitration purified treatment of SCR reactors, and ammonium hydroxide evaporator bottom Neat stress of the heat smoke after 3 denitration of SCR reactors introduced is held, by high-temperature hot-air wind turbine by 3 gas outlet of SCR reactors The high temperature neat stress being discharged at position is directly pumped to ammonium hydroxide evaporator and is used;The ammonium hydroxide vapo(u)rization system based on above-mentioned technique is real Existing ammonia supply, is compared traditional process evaporated to ammonium hydroxide using steam pipe coil, not only substantially increases the vapour of ammonium hydroxide Change efficiency, finally improve the denitration efficiency to flue gas, and realize recycling and the secondary use of waste heat, has saved the energy, dropped Low energy consumption, system flow more optimizes, is simple, while reducing floor space, effectively reduces entire flue gas denitrification system Operating cost.
It is somebody's turn to do the equipment for denitrifying flue gas based on temperature-compensating based on described above, in use, the temperature being discharged from target process Lower pending flue gas is spent, the preheating of heat exchanger 5 is first passed through, flue-gas temperature is increased, it is mixed then to pass through the feeding of admission line 7 Air compartment 2 mixes in wind mixed chamber 2 with the high-temperature flue gas from hot-blast stove 1, by the control of itself of hot-blast stove 1, so that it is guaranteed that from The flue-gas temperature that 2 gas outlet of wind mixed chamber is drawn stablizes the optimal use temperature in final catalyst, and in steam line 8 and comes It is mixed from the ammonia of ammonia gas supply system so that the NOx in flue gas enters SCR reactors 3 after being mixed with ammonia, is reacted in SCR In device 3 under the action of final catalyst, reduction reaction occurs, removes the nitrogen oxides contained in flue gas, generates nitrogen and water, from The air-flow that SCR reactors 3 are discharged after purifying, into heat exchanger 5, the power provided later by air-introduced machine 4, by 6 row of chimney It puts, to realize the purified treatment to flue gas, reduces pollution of the flue gas to environment.
Denitrification apparatus of this kind based on temperature-compensating, compares traditional equipment for denitrifying flue gas, enables to from admission line 7 The flue gas of the different temperatures of introducing stablizes the optimal use temperature in final catalyst after mixed processing, efficiently steady to obtain Fixed denitration effect is improved to the denitration efficiency of different temperatures flue gas with denitration quality, suitable for having for various operating mode flue gases Imitate denitration purification.
It should be appreciated that the purposes of these embodiments is merely to illustrate the utility model and is not intended to limitation the utility model Protection domain.In addition, it should also be understood that, after having read the technology contents of the utility model, those skilled in the art can be right The utility model makees various change, modification and/or variation, all these equivalent forms equally fall within right appended by the application and want Seek book within the limits of the protection.

Claims (7)

1. a kind of equipment for denitrifying flue gas based on temperature-compensating, it is characterised in that:Including hot-blast stove, wind mixed chamber, SCR reactors and Air-introduced machine;The air inlet of the wind mixed chamber is connected to admission line and the hot-blast stove respectively, and the gas outlet of the wind mixed chamber is logical It crosses steam line to be connected to the SCR reactors, and is equipped with the spray ammonia mouth being connected to ammonia gas supply system in the steam line, The gas outlet of the SCR reactors is connected to by outlet pipe with the air-introduced machine.
2. a kind of equipment for denitrifying flue gas based on temperature-compensating as described in claim 1, it is characterised in that:Further include to reality The heat exchanger of the existing admission line smoke pre-heating, the heat exchanger respectively with the admission line and the outlet pipe phase Even.
3. a kind of equipment for denitrifying flue gas based on temperature-compensating as claimed in claim 2, it is characterised in that:The wind mixed chamber Temperature sensor is equipped at the position of gas outlet, the temperature sensor is electrically connected with the hot-blast stove.
4. a kind of equipment for denitrifying flue gas based on temperature-compensating as claimed in claim 2, it is characterised in that:The spray ammonia mouth is Gridiron.
5. a kind of equipment for denitrifying flue gas based on temperature-compensating as described in claim 1, it is characterised in that:The SCR reactions Be equipped with TiO2 catalytic carriers in device, the TiO2 catalytic carriers be it is cellular, board-like or corrugated in one kind.
6. a kind of equipment for denitrifying flue gas based on temperature-compensating as described in claim 1, it is characterised in that:The admission line It is communicated with purifying and dedusting device, and is connected to flue gas source by the purifying and dedusting device.
7. a kind of equipment for denitrifying flue gas based on temperature-compensating as claimed in any one of claims 1 to 6, it is characterised in that:It is described The gas outlet of air-introduced machine is communicated with chimney.
CN201721784667.0U 2017-12-19 2017-12-19 A kind of equipment for denitrifying flue gas based on temperature-compensating Active CN207680368U (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108854531A (en) * 2018-08-06 2018-11-23 东方电气集团东方锅炉股份有限公司 A kind of SCR equipment for denitrifying flue gas with a variety of regulatory functions
CN109603526A (en) * 2018-12-29 2019-04-12 中冶南方都市环保工程技术股份有限公司 A biomass power plant flue gas treatment system
CN110368811A (en) * 2019-08-16 2019-10-25 北京首钢国际工程技术有限公司 A kind of SCR denitration Smoke-heating device for wearing secondary mixed wind
CN111054212A (en) * 2020-03-18 2020-04-24 山东中航天业科技有限公司 Heat-storage molecular sieve-regulated catalytic reduction denitration device
CN111473352A (en) * 2020-05-21 2020-07-31 武汉东衍环境工程技术有限公司 Purification and emission equipment for urban garbage incineration flue gas and purification treatment method thereof
CN111550797A (en) * 2020-05-21 2020-08-18 武汉东衍环境工程技术有限公司 Deep purification equipment for hazardous waste incineration flue gas and purification treatment method thereof
CN114011238A (en) * 2021-11-26 2022-02-08 苏州克兰茨环境科技有限公司 Catalytic denitration waste gas treatment system and working method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108854531A (en) * 2018-08-06 2018-11-23 东方电气集团东方锅炉股份有限公司 A kind of SCR equipment for denitrifying flue gas with a variety of regulatory functions
CN109603526A (en) * 2018-12-29 2019-04-12 中冶南方都市环保工程技术股份有限公司 A biomass power plant flue gas treatment system
CN110368811A (en) * 2019-08-16 2019-10-25 北京首钢国际工程技术有限公司 A kind of SCR denitration Smoke-heating device for wearing secondary mixed wind
CN111054212A (en) * 2020-03-18 2020-04-24 山东中航天业科技有限公司 Heat-storage molecular sieve-regulated catalytic reduction denitration device
CN111473352A (en) * 2020-05-21 2020-07-31 武汉东衍环境工程技术有限公司 Purification and emission equipment for urban garbage incineration flue gas and purification treatment method thereof
CN111550797A (en) * 2020-05-21 2020-08-18 武汉东衍环境工程技术有限公司 Deep purification equipment for hazardous waste incineration flue gas and purification treatment method thereof
CN114011238A (en) * 2021-11-26 2022-02-08 苏州克兰茨环境科技有限公司 Catalytic denitration waste gas treatment system and working method thereof

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