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CN203530318U - Biogas tank integrating heat preservation, heating and stirring - Google Patents

Biogas tank integrating heat preservation, heating and stirring Download PDF

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Publication number
CN203530318U
CN203530318U CN201320575170.3U CN201320575170U CN203530318U CN 203530318 U CN203530318 U CN 203530318U CN 201320575170 U CN201320575170 U CN 201320575170U CN 203530318 U CN203530318 U CN 203530318U
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biogas tank
biogas
heating
heat preservation
tank body
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刘洋
吕建
李宪莉
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Tianjin Chengjian University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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Abstract

本实用新型涉及一种集保温、加热和搅拌于一体的沼气罐,包括沼气罐本体,其特征是:所述沼气罐本体侧壁设有辅助出气口,所述辅助出气口通过管道连接有管道泵,所述管道泵下端与沼气罐本体的出料口管道连接,所述出料口管道一端通入沼气罐的底部中心,出料口管道另一端连接有阀门。有益效果:与现有技术相比,集保温与加热一体的沼气罐克服传统沼气罐因受温度影响而产气量减少的不足。适用于大型的养殖场和冬季室外气温较低的北方地区,可以充分利用各地的低品位热源。沼气罐内的换热盘管的换热面积大,可以采用间歇性的液体搅拌方式,大量节约电能。内壁材料高密度聚乙烯,具有较高的刚性、韧性和很好的机械强度,能够承受罐内沼气产生的压力。

Figure 201320575170

The utility model relates to a biogas tank integrating heat preservation, heating and stirring, including a biogas tank body, characterized in that: the side wall of the biogas tank body is provided with an auxiliary gas outlet, and the auxiliary gas outlet is connected with a pipeline through a pipeline pump, the lower end of the pipeline pump is connected to the outlet pipe of the biogas tank body, one end of the outlet pipe leads into the bottom center of the biogas tank, and the other end of the outlet pipe is connected with a valve. Beneficial effects: Compared with the prior art, the biogas tank integrated with heat preservation and heating overcomes the disadvantage of the traditional biogas tank that the gas production is reduced due to the influence of temperature. It is suitable for large-scale farms and northern regions where the outdoor temperature is low in winter, and can make full use of low-grade heat sources in various places. The heat exchange coil in the biogas tank has a large heat exchange area, and intermittent liquid stirring can be used to save a lot of electric energy. The inner wall is made of high-density polyethylene, which has high rigidity, toughness and good mechanical strength, and can withstand the pressure generated by the biogas in the tank.

Figure 201320575170

Description

集保温、加热和搅拌于一体的沼气罐A biogas tank integrating heat preservation, heating and stirring

技术领域technical field

本实用新型属于沼气罐,尤其涉及一种集保温、加热和搅拌于一体的沼气罐。The utility model belongs to a biogas tank, in particular to a biogas tank integrating heat preservation, heating and stirring.

背景技术Background technique

沼气发酵可在较为广泛的温度范围内进行,4~65℃都能产气。随着温度的升高,产气速度加快,但不呈线性关系,关系如图2所示。40~55℃是高温菌和中温菌的过渡区,50~55℃是高温厌氧菌活动区,产气速度最快。例如,10℃下发酵90天,但其产气率只有30℃下发酵27天的59%。温度的突然变化会对产气发生很大影响。大中型沼气发酵工程,尤其是恒温工程,温度是必需监控指标。温度变化超过5℃,产气量显著降低,若变化过大则产气停止。例如,一个35℃下正常产气的沼气池,温度突然下降到20℃,则产气几乎完全停止。由此可见,有一个适宜、稳定的发酵环境对沼气的产气量和产气速率是非常重要的。Biogas fermentation can be carried out in a relatively wide temperature range, and gas can be produced at 4-65 °C. As the temperature increases, the rate of gas production increases, but not in a linear relationship, as shown in Figure 2. 40-55°C is the transition zone between thermophilic bacteria and mesophilic bacteria, and 50-55°C is the active zone of hyperthermic anaerobic bacteria, with the fastest gas production rate. For example, fermentation at 10°C for 90 days, but its gas production rate is only 59% of that at 30°C for 27 days. Sudden changes in temperature can greatly affect gas production. For large and medium-sized biogas fermentation projects, especially constant temperature projects, temperature is a necessary monitoring indicator. If the temperature change exceeds 5°C, the gas production will decrease significantly, and if the change is too large, the gas production will stop. For example, if a biogas digester normally produces gas at 35°C, if the temperature suddenly drops to 20°C, the gas production will almost stop completely. It can be seen that a suitable and stable fermentation environment is very important to the gas production and gas production rate of biogas.

传统的户用沼气罐是用户根据需要在地下挖坑砌成的,保温不好做,管理不方便,且冬季气温低很难产气,所以很容易废弃。市场推出了玻璃钢沼气罐分为上、下两个半球,用螺栓拼接而成,有强度高、耐酸碱、抗老化、质量轻、无渗漏、施工简单、保温性能好等优点,但是结构不太合理,搅拌装置磨损严重,易漏气,所以不能广泛应用。Traditional household biogas tanks are built by users in the ground according to their needs. The insulation is not good, the management is inconvenient, and the temperature is low in winter, so it is difficult to produce gas, so it is easy to discard. The market has launched a fiberglass biogas tank that is divided into upper and lower hemispheres, which are spliced with bolts. It has the advantages of high strength, acid and alkali resistance, anti-aging, light weight, no leakage, simple construction, and good thermal insulation performance. It is unreasonable, the stirring device is seriously worn and easy to leak, so it cannot be widely used.

随着技术的发展,人类开始选用一种新型沼气加热系统——太阳能辅助加热沼气系统。这种系统利用了可再生能源——太阳能,阶段性的提高了沼气发酵温度,在一定程度上提高了沼气的产气量和产气效率。但是,太阳能辅助加热制沼气系统也存在一些不足:这种系统受用户所在地的太阳能资源和地理位置影响严重。在太阳能资源不足,用户住处遮挡严重等情况下,不能保证有稳定适宜的发酵温度,发酵产期效率低的问题也不能得到有效解决。With the development of technology, humans began to choose a new type of biogas heating system—solar-assisted heating biogas system. This system utilizes renewable energy—solar energy—to increase the temperature of biogas fermentation in stages, and to a certain extent, increase the gas production and efficiency of biogas. However, there are also some shortcomings in the solar-assisted heating biogas system: this system is seriously affected by the solar energy resources and geographical location of the user's location. In the case of insufficient solar energy resources and severe shading of users' residences, a stable and suitable fermentation temperature cannot be guaranteed, and the problem of low efficiency in the fermentation production period cannot be effectively solved.

实用新型内容Utility model content

本实用新型的目的在于克服上述技术的不足,提供一种集保温、加热和搅拌于一体的沼气罐,实现罐体保温与增温的一体化,采用间歇性的液体搅拌方式,在罐内形成涡流,使沼液混合均匀;同时不会因为室外温度的骤变而影响沼气产气速率,有利于沼气发酵和产量的提高。The purpose of this utility model is to overcome the deficiencies of the above-mentioned technologies, provide a biogas tank integrating heat preservation, heating and stirring, realize the integration of heat preservation and temperature increase of the tank body, adopt intermittent liquid stirring mode, and form a biogas tank in the tank The eddy current makes the biogas slurry mix evenly; at the same time, it will not affect the biogas production rate due to sudden changes in outdoor temperature, which is conducive to the improvement of biogas fermentation and production.

本实用新型为实现上述目的,采用以下技术方案:一种集保温、加热和搅拌于一体的沼气罐,包括沼气罐本体,其特征是:所述沼气罐本体侧壁设有搅拌进液口,所述搅拌进液口通过管道连接有管道泵,所述管道泵下端与沼气罐本体的出料口管道连接,所述出料口管道一端通入沼气罐的底部中心,出料口管道另一端连接有阀门。In order to achieve the above purpose, the utility model adopts the following technical scheme: a biogas tank integrating heat preservation, heating and stirring, including a biogas tank body, characterized in that: the side wall of the biogas tank body is provided with a stirring liquid inlet, The stirring liquid inlet is connected to a pipeline pump through a pipeline, and the lower end of the pipeline pump is connected to the outlet pipeline of the biogas tank body. One end of the outlet pipeline is connected to the bottom center of the biogas tank, and the other end of the outlet pipeline A valve is connected.

所述沼气罐本体紧贴其内层沿罐内壁设有换热盘管,所述换热盘管和沼气罐本体上的进水口及出水口通过螺纹连接。The body of the biogas tank is closely attached to its inner layer and a heat exchange coil is arranged along the inner wall of the tank, and the heat exchange coil is connected to the water inlet and the water outlet on the body of the biogas tank through threads.

所述沼气罐本体内壁置有带有热电偶的测温标杆,通过测温标杆上的热电偶读数控制换热热水的温度。The inner wall of the biogas tank body is provided with a temperature measuring pole with a thermocouple, and the temperature of the heat exchange hot water is controlled through the reading of the thermocouple on the temperature measuring pole.

所述沼气罐本体侧壁设有观察测温标杆上热电偶读数的测温孔。The side wall of the biogas tank body is provided with a temperature measuring hole for observing the reading of the thermocouple on the temperature measuring pole.

所述沼气罐本体包括自内向外依次连接的高密度聚乙烯的内壁层、硬质聚氨酯泡沫塑料的保温层和玻璃钢的保护外层。The biogas tank body includes an inner wall layer of high-density polyethylene, a thermal insulation layer of rigid polyurethane foam and a protective outer layer of glass fiber reinforced plastics which are sequentially connected from inside to outside.

所述内壁层采用高密度聚乙烯材料,保温层采用硬质聚氨酯泡沫塑料的材料,保护外层采用玻璃钢材料。The inner wall layer is made of high-density polyethylene, the insulation layer is made of rigid polyurethane foam, and the outer protective layer is made of glass fiber reinforced plastic.

所述沼气罐本体顶部呈圆拱形,顶部设有检测口和排气口,所述沼气罐本体侧壁底部设有进料口,进料口通过管道与送料漏斗连接。The top of the biogas tank body is arched, with a detection port and an exhaust port on the top, and a feed port is provided at the bottom of the side wall of the biogas tank body, and the feed port is connected to a feeding funnel through a pipeline.

有益效果:与现有技术相比,集保温、加热和搅拌于一体的沼气罐克服传统沼气罐因受温度影响而产气量减少的不足。适用于大型的养殖场和冬季室外气温较低的北方地区,可以充分利用各地的低品位热源。该沼气罐材料玻璃钢、硬质聚氨酯泡沫塑料和高密度聚乙烯都是较常见材料,生产工艺简单,便于大批量生产,因此价格低廉。使得该沼气罐的成本较低,产生沼气收益大,除投资回收期短。沼气罐内的换热盘管的换热面积大,可以采用间歇性的液体搅拌方式,在罐内形成涡流,从而使沼液混合均匀。大量节约电能。沼气罐材料玻璃钢和高密度聚乙烯本身都属于抗压材料且密度小,厚度也很小,安全可靠性。内壁材料高密度聚乙烯,具有较高的刚性、韧性和很好的机械强度,能够承受罐内沼气产生的压力。外壁材料玻璃钢密度只有碳钢的1/5,拉伸强度和碳钢接近,比强度可以和高级合金钢相比。其拉伸、弯曲和压缩强度均能达到400MP以上,具有很好的保护作用。Beneficial effects: Compared with the prior art, the biogas tank integrating heat preservation, heating and stirring overcomes the disadvantage of the traditional biogas tank that the gas production is reduced due to the influence of temperature. It is suitable for large-scale farms and northern regions where the outdoor temperature is low in winter, and can make full use of low-grade heat sources in various places. The biogas tank is made of fiberglass, rigid polyurethane foam and high-density polyethylene, all of which are relatively common materials. The production process is simple and convenient for mass production, so the price is low. The cost of the biogas tank is low, and the profit of biogas generation is large, except that the investment recovery period is short. The heat exchange coil in the biogas tank has a large heat exchange area, and the intermittent liquid stirring method can be used to form a vortex in the tank, so that the biogas slurry can be mixed evenly. Save a lot of power. Biogas tank materials FRP and high-density polyethylene are compressive materials with low density and small thickness, which are safe and reliable. The inner wall is made of high-density polyethylene, which has high rigidity, toughness and good mechanical strength, and can withstand the pressure generated by the biogas in the tank. The density of the outer wall material FRP is only 1/5 of that of carbon steel, its tensile strength is close to that of carbon steel, and its specific strength can be compared with that of high-grade alloy steel. Its tensile, bending and compressive strength can reach more than 400MP, which has a good protective effect.

附图说明Description of drawings

图1是本实用新型结构示意图;Fig. 1 is a structural representation of the utility model;

图2是沼气产气量与温度的关系图。Figure 2 is a graph showing the relationship between biogas production and temperature.

图中:1、沼气罐本体,2、搅拌进液口,3、管道,4、管道泵,5、出料口管道,6、阀门,7、换热盘管,8、进水口,9、出水口,10、测温标杆,11、内壁层,12、保温层,13、保护外层,14、压力测口,15、排气口,16、进料口,17、送料漏斗,18、压力表,19、测温孔,20、出料口。In the figure: 1. Biogas tank body, 2. Stirring liquid inlet, 3. Pipeline, 4. Pipeline pump, 5. Outlet pipe, 6. Valve, 7. Heat exchange coil, 8. Water inlet, 9. Water outlet, 10, temperature measurement benchmark, 11, inner wall layer, 12, insulation layer, 13, protective outer layer, 14, pressure measuring port, 15, exhaust port, 16, feeding port, 17, feeding funnel, 18, Pressure gauge, 19, temperature measuring hole, 20, discharge port.

具体实施方式Detailed ways

下面结合较佳实施例详细说明本实用新型的具体实施方式。The specific implementation of the utility model will be described in detail below in conjunction with the preferred embodiments.

实施例Example

本实用新型提供了一种适用于大型的养殖场和冬季室外气温较低的北方地区,集保温、加热和搅拌于一体的沼气罐,在沼气罐本体1侧壁设置搅拌进液口2,所述搅拌进液口通过管道3连接管道泵4,所述管道泵下端又与沼气罐本体的出料口管道5连接,所述出料口管道5一端通入沼气罐的底部中心,管道泵将流向顶部的液体反抽回到沼气罐的底部,抽回的液体冲击沉淀在底部的未发酵的原料,在罐内形成涡流,从而使沼液混合均匀。管道泵可以采用间歇式工作,减少连续工作所消耗的电能。出料口管道另一端连接有阀门6,需要时打开阀门通过出料口20将废料排出。The utility model provides a biogas tank which is suitable for large farms and northern regions where the outdoor temperature is low in winter and integrates heat preservation, heating and stirring. A stirring liquid inlet 2 is arranged on the side wall of the biogas tank body 1, so that The stirring liquid inlet is connected to the pipeline pump 4 through the pipeline 3, and the lower end of the pipeline pump is connected to the discharge pipeline 5 of the biogas tank body, and one end of the discharge pipeline 5 is connected to the bottom center of the biogas tank, and the pipeline pump will The liquid flowing to the top is pumped back to the bottom of the biogas tank, and the pumped liquid impacts the unfermented raw materials settled at the bottom, forming a vortex in the tank, so that the biogas slurry is evenly mixed. Pipeline pumps can work intermittently to reduce the power consumed by continuous work. The other end of the discharge port pipeline is connected with a valve 6, which can be opened to discharge the waste through the discharge port 20 when necessary.

本实用新型的优选结构是在沼气罐本体紧贴其内层沿罐内壁固定有螺旋状换热盘管7,所述换热盘管和沼气罐本体上的进水口8及出水口9通过螺纹连接,沼气罐本体上的进水口及出水口与供热水机构连接,形成循环内热式加热。由于沼气罐内的换热盘管的换热面积大,在获得相同热量时,可以利用相对较低的温度。它可以直接利用太阳能集热、地热、供暖回水余热等多种低品位热源,达到能源的合理利用。沼气罐本体内壁置有带有热电偶的测温标杆10,所述沼气罐本体侧壁设有观察测温标杆上热电偶读数的测温孔19,通过测温标杆上的热电偶读数控制换热热水的温度。The preferred structure of the utility model is that a spiral heat exchange coil 7 is fixed on the biogas tank body close to its inner layer along the inner wall of the tank, and the water inlet 8 and the water outlet 9 on the heat exchange coil and the biogas tank body are threaded Connection, the water inlet and outlet on the body of the biogas tank are connected with the hot water supply mechanism to form a circulating internal heating. Due to the large heat exchange area of the heat exchange coil in the biogas tank, a relatively lower temperature can be used when obtaining the same amount of heat. It can directly use various low-grade heat sources such as solar heat collection, geothermal heat, heating backwater waste heat, etc., to achieve rational utilization of energy. The inner wall of the biogas tank body is equipped with a temperature measuring pole 10 with a thermocouple, and the side wall of the biogas tank body is provided with a temperature measuring hole 19 for observing the readings of the thermocouples on the temperature measuring pole. The temperature of hot water.

本实用新型的优选结构是所述沼气罐本体包括自内向外依次连接的高密度聚乙烯的内壁层11、硬质聚氨酯泡沫塑料的保温层12和玻璃钢的保护外层13。所述内壁层采用高密度聚乙烯材料(HDPE),具有耐磨性、电绝缘性、韧性及耐寒性均较好,化学稳定性好,在室温条件下,不溶于任何有机溶剂,耐酸、碱和各种盐类的腐蚀等优点;保温层采用硬质聚氨酯泡沫塑料的材料,保护外层采用玻璃钢材料保温材料更是多孔材料,所以组合在一起的罐体质轻。如果低品位热源用太阳能集热,可以将罐体放在房顶,这样既减小管道散热,又防止了房屋或树木等对集热器的遮挡。同时,由于质轻,移动方便。所述沼气罐本体顶部呈圆拱形,顶部安装带有压力表18的检测口14和排气口15,所述沼气罐本体侧壁底部设有进料口16,进料口通过管道与送料漏斗17连接。The preferred structure of the utility model is that the biogas tank body includes an inner wall layer 11 of high-density polyethylene, a thermal insulation layer 12 of rigid polyurethane foam and a protective outer layer 13 of glass fiber reinforced plastics sequentially connected from inside to outside. The inner wall layer is made of high-density polyethylene (HDPE), which has good wear resistance, electrical insulation, toughness and cold resistance, and good chemical stability. It is insoluble in any organic solvent at room temperature and resistant to acids and alkalis. The corrosion of various salts and other advantages; the insulation layer is made of rigid polyurethane foam material, and the outer layer of protection is made of glass fiber reinforced plastic material. The insulation material is even more porous, so the tank body combined is light. If the low-grade heat source uses solar energy to collect heat, the tank body can be placed on the roof, which not only reduces the heat dissipation of the pipeline, but also prevents the house or trees from blocking the heat collector. At the same time, it is easy to move due to its light weight. The top of the biogas tank body is arched, and a detection port 14 and an exhaust port 15 with a pressure gauge 18 are installed on the top. Funnel 17 is connected.

以上所述,仅是本实用新型的较佳实施例而已,并非对本实用新型的结构作任何形式上的限制。凡是依据本实用新型的技术实质对以上实施例所作的任何简单修改、等同变化与修饰,均仍属于本实用新型的技术方案的范围内。The above descriptions are only preferred embodiments of the present utility model, and are not intended to limit the structure of the present utility model in any form. Any simple modifications, equivalent changes and modifications made to the above embodiments according to the technical essence of the present utility model still belong to the scope of the technical solution of the present utility model.

Claims (7)

1.一种集保温、加热和搅拌于一体的沼气罐,包括沼气罐本体,其特征是:所述沼气罐本体侧壁设有搅拌进液口,所述搅拌进液口通过管道连接有管道泵,所述管道泵下端与沼气罐本体的出料口管道连接,所述出料口管道一端通入沼气罐的底部中心,出料口管道另一端连接有阀门。1. A biogas tank integrating heat preservation, heating and stirring, including a biogas tank body, characterized in that: the side wall of the biogas tank body is provided with a stirring liquid inlet, and the stirring liquid inlet is connected to a pipeline through a pipeline pump, the lower end of the pipeline pump is connected to the outlet pipe of the biogas tank body, one end of the outlet pipe leads into the bottom center of the biogas tank, and the other end of the outlet pipe is connected with a valve. 2.根据权利要求1所述的集保温、加热和搅拌于一体的沼气罐,其特征是:所述沼气罐本体紧贴其内层沿罐内壁设有换热盘管,所述换热盘管和沼气罐本体上的进水口及出水口通过螺纹连接。2. The biogas tank integrating heat preservation, heating and stirring according to claim 1, characterized in that: the body of the biogas tank is closely attached to its inner layer and a heat exchange coil is arranged along the inner wall of the tank, and the heat exchange plate The water inlet and the water outlet on the pipe and the biogas tank body are connected by threads. 3.根据权利要求1或2所述的集保温、加热和搅拌于一体的沼气罐,其特征是:所述沼气罐本体内壁置有带有热电偶的测温标杆,通过测温标杆上的热电偶读数控制换热热水的温度。3. The biogas tank integrating heat preservation, heating and stirring according to claim 1 or 2, characterized in that: the inner wall of the biogas tank body is equipped with a temperature measuring pole with a thermocouple, and the The thermocouple reading controls the temperature of the heat exchange hot water. 4.根据权利要求3所述的集保温、加热和搅拌于一体的沼气罐,其特征是:所述沼气罐本体侧壁设有观察测温标杆上热电偶读数的测温孔。4. The biogas tank integrating heat preservation, heating and stirring according to claim 3, characterized in that: the side wall of the biogas tank body is provided with a temperature measuring hole for observing the reading of the thermocouple on the temperature measuring pole. 5.根据权利要求4所述的集保温、加热和搅拌于一体的沼气罐,其特征是:所述沼气罐本体包括自内向外依次连接的高密度聚乙烯的内壁层、硬质聚氨酯泡沫塑料的保温层和玻璃钢的保护外层。5. The biogas tank integrating heat preservation, heating and stirring according to claim 4, characterized in that: the biogas tank body comprises an inner wall layer of high-density polyethylene, a rigid polyurethane foam The insulation layer and the protective outer layer of fiberglass. 6.根据权利要求5所述的集保温、加热和搅拌于一体的沼气罐,其特征是:所述内壁层采用高密度聚乙烯材料,保温层采用硬质聚氨酯泡沫塑料的材料,保护外层采用玻璃钢材料。6. The biogas tank integrating heat preservation, heating and stirring according to claim 5, characterized in that: the inner wall layer is made of high-density polyethylene material, and the heat preservation layer is made of rigid polyurethane foam to protect the outer layer Made of fiberglass material. 7.根据权利要求6所述的集保温、加热和搅拌于一体的沼气罐,其特征是:所述沼气罐本体顶部呈圆拱形,顶部设有检测口和排气口,所述沼气罐本体侧壁底部设有进料口,进料口通过管道与送料漏斗连接。7. The biogas tank integrating heat preservation, heating and stirring according to claim 6, characterized in that: the top of the biogas tank body is in the shape of a round arch, and the top is provided with a detection port and an exhaust port, and the biogas tank A feed inlet is provided at the bottom of the side wall of the main body, and the feed inlet is connected with a feeding funnel through a pipeline.
CN201320575170.3U 2013-09-17 2013-09-17 Biogas tank integrating heat preservation, heating and stirring Expired - Fee Related CN203530318U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104928165A (en) * 2015-06-25 2015-09-23 南安市绿野沼气技术开发研究所 Biogas pool with temperature increase and retention function
CN106151672A (en) * 2015-03-30 2016-11-23 安徽春辉仪表线缆集团有限公司 A kind of thermal-insulating type regulation valve
CN108895872A (en) * 2018-06-06 2018-11-27 天津嘉立荷牧业集团有限公司 A kind of cattle farm refrigeration unit multistage heat recovery apparatus
CN115178216A (en) * 2022-08-02 2022-10-14 宁波昊祥新材料科技有限公司 Catalyst precipitation reaction kettle

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106151672A (en) * 2015-03-30 2016-11-23 安徽春辉仪表线缆集团有限公司 A kind of thermal-insulating type regulation valve
CN104928165A (en) * 2015-06-25 2015-09-23 南安市绿野沼气技术开发研究所 Biogas pool with temperature increase and retention function
CN104928165B (en) * 2015-06-25 2017-10-31 南安市绿野沼气技术开发研究所 A kind of temperature raising and maintaining methane-generating pit
CN108895872A (en) * 2018-06-06 2018-11-27 天津嘉立荷牧业集团有限公司 A kind of cattle farm refrigeration unit multistage heat recovery apparatus
CN115178216A (en) * 2022-08-02 2022-10-14 宁波昊祥新材料科技有限公司 Catalyst precipitation reaction kettle

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