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CN202591170U - Plasma free radical cleaning spray gun with normal-pressure double radio-frequency electrodes - Google Patents

Plasma free radical cleaning spray gun with normal-pressure double radio-frequency electrodes Download PDF

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Publication number
CN202591170U
CN202591170U CN 201220139232 CN201220139232U CN202591170U CN 202591170 U CN202591170 U CN 202591170U CN 201220139232 CN201220139232 CN 201220139232 CN 201220139232 U CN201220139232 U CN 201220139232U CN 202591170 U CN202591170 U CN 202591170U
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radio frequency
spray gun
electrodes
plasma
free radical
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贾少霞
王守国
杨景华
赵玲利
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Institute of Microelectronics of CAS
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Institute of Microelectronics of CAS
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Abstract

一种常压双射频电极的等离子体自由基清洗喷枪,包括两个射频电极、介质阻挡层、两个接地电极和一个射频电源,该喷枪呈长方体,其中一面接进气口,相对的面为喷口,除喷口面外,喷枪其余各面均为金属板,两个接地电极被介质阻挡层包覆,两个接地电极之间为两个射频电极,形成三个喷口,两个射频电极也被介质阻挡层包覆,工作气体从喷枪喷口喷出,在常压下,电源接通后,在三个喷口均产生辉光等离子体,等离子体中的自由基在气流的携带下向外喷出,该喷枪用于对硅片、玻璃等衬底表面的有机物进行清洗。

Figure 201220139232

A plasma free radical cleaning spray gun with dual radio frequency electrodes at normal pressure comprises two radio frequency electrodes, a dielectric barrier, two ground electrodes and a radio frequency power supply. Nozzle, except for the nozzle surface, the other sides of the spray gun are all metal plates, the two ground electrodes are covered by a dielectric barrier layer, and there are two radio frequency electrodes between the two ground electrodes, forming three nozzles, and the two radio frequency electrodes are also covered Coated with a dielectric barrier layer, the working gas is ejected from the nozzle of the spray gun. Under normal pressure, after the power is turned on, glow plasma is generated at the three nozzles, and the free radicals in the plasma are ejected outwards under the airflow , the spray gun is used to clean the organic matter on the surface of substrates such as silicon wafers and glass.

Figure 201220139232

Description

一种常压双射频电极的等离子体自由基清洗喷枪A Plasma Radical Cleaning Spray Gun with Double Radio Frequency Electrodes at Normal Pressure

技术领域 technical field

本实用新型涉及到一种常压双射频电极的等离子体自由基清洗喷枪,喷枪由双射频电极的介质阻挡放电产生等离子体,等离子体中的活性自由基在一定压力下从喷枪的三个喷口喷出,到达硅片、玻璃等衬底表面后,与衬底表面的有机物发生反应,达到清洗衬底表面的目的。  The utility model relates to a plasma free radical cleaning spray gun with double radio frequency electrodes at normal pressure. The spray gun generates plasma by the dielectric barrier discharge of the double radio frequency electrodes. After spraying out and reaching the surface of substrates such as silicon wafers and glass, it reacts with organic matter on the surface of the substrate to achieve the purpose of cleaning the surface of the substrate. the

背景技术 Background technique

半导体生产中,硅片必须严格清洗,即使是微量的污染也会导致器件失效,另外,其他衬底例如液晶玻璃平板等表面除了需要清洗有机污染物外,还需要改善材料表面的性能,增加材料表面的附着性。传统清洗方式是湿法化学方法,湿法化学方法存在不能精确控制、清洗不彻底、清洗溶液易对环境造成污染;已经出现的干法方法大多数是工作在真空状态下,设备操作复杂、成本高,而且在真空室中由于存在离子溅射,很容易使真空壁面上溅出金属原子;已出现的常压清洗技术存在易引入新的杂质,电极结构复杂等缺点。  In semiconductor production, silicon wafers must be cleaned strictly. Even a small amount of pollution will cause device failure. In addition, other substrates such as liquid crystal glass panels need to be cleaned of organic pollutants, and the performance of the material surface needs to be improved. surface adhesion. The traditional cleaning method is the wet chemical method. The wet chemical method cannot be accurately controlled, the cleaning is not thorough, and the cleaning solution is easy to pollute the environment; High, and due to ion sputtering in the vacuum chamber, it is easy to sputter metal atoms on the vacuum wall; the existing normal pressure cleaning technology has the disadvantages of easy introduction of new impurities and complex electrode structure. the

本实用新型介绍了一种常压双射频电极的等离子体自由基清洗喷枪。喷枪包括两个射频电极、两个接地电极,两个接地电极之间是两个相邻的射频电极,常压双射频电极的等离子体自由基清洗喷枪采用了介质阻挡的射频放电形式,以氩气和氧气的混合气体为工作气体,产生辉光放电,等离子体自由基束流从三个喷口喷出,在到达硅片等衬底表面上,束流主要成分为活性自由基,自由基与光刻胶或其它有机物发生反应,生成二氧化碳、水等产物,达到清洗目的,该喷枪除了可以对液晶玻璃平板等衬底进行清洗外,还可以改善其表面的粘附性。 The utility model introduces a plasma free radical cleaning spray gun with normal pressure double radio frequency electrodes. The spray gun includes two radio frequency electrodes, two ground electrodes, and two adjacent radio frequency electrodes between the two ground electrodes. The plasma radical cleaning spray gun with double radio frequency electrodes at atmospheric pressure adopts the form of dielectric barrier radio The mixed gas of gas and oxygen is the working gas, which produces glow discharge. The plasma free radical beam is ejected from three nozzles. When it reaches the surface of a substrate such as a silicon wafer, the main component of the beam is active free radicals. The free radicals and Photoresist or other organic substances react to produce carbon dioxide, water and other products to achieve the purpose of cleaning. In addition to cleaning substrates such as liquid crystal glass plates, the spray gun can also improve the adhesion of their surfaces.

常压双射频电极的等离子体自由基清洗喷枪的优点是射频电极之间的放电增大了放电面积、减少了引入的金属杂质、喷枪结构简单化。  The advantages of the plasma radical cleaning spray gun with dual radio frequency electrodes at atmospheric pressure are that the discharge between the radio frequency electrodes increases the discharge area, reduces the introduction of metal impurities, and simplifies the structure of the spray gun. the

实用新型内容Utility model content

常压双射频电极的等离子体自由基清洗喷枪,包括两个射频电极、介质阻挡层、两个接地电极和一个射频电源,其特征在于:该喷枪呈长方体,其中一面接进气口,相对的面为喷口,除喷口面外,喷枪其余各面均为金属板,两个接地电极被介质阻挡层包覆,两个接地电极之间为两个射频电极,形成三个喷口,两个射频电极被介质阻挡层包覆,工作气体从喷枪喷口喷出,在常压下,电源接通后,在三个喷口中均产生辉光等离子体,等离子体中的自由基在气流的携带下向外喷出。  The plasma free radical cleaning spray gun with dual radio frequency electrodes at normal pressure includes two radio frequency electrodes, a dielectric barrier layer, two ground electrodes and a radio frequency power supply. The surface is the nozzle, except the surface of the nozzle, the other sides of the spray gun are all metal plates, the two ground electrodes are covered by a dielectric barrier layer, and the two ground electrodes are two RF electrodes, forming three nozzles, two RF electrodes Covered by a dielectric barrier layer, the working gas is ejected from the nozzle of the spray gun. Under normal pressure, after the power is turned on, glow plasma is generated in the three nozzles, and the free radicals in the plasma are carried outward by the airflow. squirt. the

所述的常压双射频电极的等离子体自由基清洗喷枪,其特征在于:接地电极与射频电极的制作材料均为金属材料。  The plasma free radical cleaning spray gun with double radio frequency electrodes at normal pressure is characterized in that the ground electrode and the radio frequency electrode are made of metal materials. the

所述的常压双射频电极的等离子体自由基清洗喷枪,其特征在于:接地电极与射频电极以及射频电极与射频电极之间形成的三个喷口大小相等,宽度范围为0.5-2.0mm。  The plasma radical cleaning spray gun with double radio frequency electrodes at normal pressure is characterized in that: the ground electrode and the radio frequency electrode and the three nozzles formed between the radio frequency electrode and the radio frequency electrode are equal in size and the width range is 0.5-2.0 mm. the

所述的常压双射频电极的等离子体自由基清洗喷枪,其特征在于:两个接地电极之间是两个相邻的射频电极。  The plasma free radical cleaning spray gun with double radio frequency electrodes at normal pressure is characterized in that two adjacent radio frequency electrodes are located between the two ground electrodes. the

本实用新型一种常压双射频电极的等离子体自由基清洗喷枪产生的等离子体自由基束流,在喷射到硅片等衬底表面时,束流成分以自由基为主,高活性的自由基与衬底表面的光刻胶或其它有机物反应生成二氧化碳、水 等,可以直接排放到大气中,该喷枪除了可以对液晶玻璃平板等衬底进行清洗,还可以改善其表面的粘附性。  The utility model is a plasma free radical cleaning spray gun with double radio frequency electrodes at normal pressure. The substrate reacts with the photoresist or other organic matter on the surface of the substrate to generate carbon dioxide, water, etc., which can be directly discharged into the atmosphere. The spray gun can not only clean the substrates such as liquid crystal glass plates, but also improve the adhesion of the surface. the

常压双射频电极的等离子体自由基清洗喷枪的优点是射频电极之间的放电增大了放电面积、减少了引入的金属杂质、喷枪结构简单化。本实用新型的主要用途是清洗硅片上的光刻胶和有机污染物,或清洗玻璃等其他衬底表面的有机污染物。  The advantages of the plasma radical cleaning spray gun with dual radio frequency electrodes at atmospheric pressure are that the discharge between the radio frequency electrodes increases the discharge area, reduces the introduction of metal impurities, and simplifies the structure of the spray gun. The main purpose of the utility model is to clean the photoresist and organic pollutants on the silicon wafer, or to clean the organic pollutants on the surface of other substrates such as glass. the

附图说明 Description of drawings

图1为本实用新型一种常压双射频电极的等离子体自由基清洗喷枪原理示意图。  Fig. 1 is a schematic diagram of the principle of a plasma free radical cleaning spray gun with atmospheric pressure dual radio frequency electrodes of the present invention. the

图2为本实用新型一种常压双射频电极的等离子体自由基清洗喷枪外形图。  Fig. 2 is an outline view of a plasma free radical cleaning spray gun with atmospheric pressure dual radio frequency electrodes of the present invention. the

具体实施方式Detailed ways

请参阅图1,该常压双射频电极的等离子体自由基清洗喷枪,包括两个射频电极107、包覆射频电极的介质阻挡层106、两个接地电极108、包覆接地电极的介质阻挡层109、一个射频电源105、喷枪壳体104、供气源101、流量计102以及供气管路103。两个接地电极与喷枪壳体连接,介质阻挡层为石英或陶瓷等绝缘材料。供气源101提供氩气和氧气,气体经过流量计102时按一定比例形成混合气体,混合气体经供气管路103后,均匀的进入接地电极108与射频电极107之间的间隙以及两个射频电极之间的间隙,当射频电极107与射频电源105接通后,在三个喷口内都产生等离子体,等离子体自由基束流在气流的带动下,从喷口喷射出来,当到达衬底表面时,束流成分以自由基110为主,自由基与衬底表面的光刻胶或其它有机物反应,生成二氧化碳、水等产物,除了去除衬底表面光刻胶或其它有机物外,该喷枪还 可以对液晶平板等衬底表面进行改性。  Please refer to Fig. 1, the plasma free radical cleaning spray gun of this normal pressure dual radio frequency electrode, comprises two radio frequency electrodes 107, the dielectric barrier layer 106 of coating radio frequency electrode, two ground electrodes 108, the dielectric barrier layer of coating ground electrode 109 , a radio frequency power supply 105 , a spray gun housing 104 , an air supply source 101 , a flow meter 102 and an air supply pipeline 103 . The two ground electrodes are connected with the spray gun shell, and the dielectric barrier is made of insulating materials such as quartz or ceramics. The gas supply source 101 provides argon and oxygen. When the gas passes through the flow meter 102, a mixed gas is formed in a certain proportion. After passing through the gas supply pipeline 103, the mixed gas evenly enters the gap between the ground electrode 108 and the radio frequency electrode 107 and the two radio frequency electrodes. The gap between the electrodes, when the radio frequency electrode 107 is connected to the radio frequency power supply 105, plasma is generated in the three nozzles, and the plasma free radical beam is ejected from the nozzle under the drive of the air flow, and when it reaches the substrate surface At this time, the beam component is mainly free radicals 110, and the free radicals react with the photoresist or other organic substances on the substrate surface to generate carbon dioxide, water and other products. In addition to removing the photoresist or other organic substances on the substrate surface, the spray gun also The surface of substrates such as liquid crystal panels can be modified. the

请参阅图2,该常压双射频电极的等离子体自由基清洗喷枪,供气管路103与喷枪的进气口202连接,工作气体通过进气口202进入喷枪内部,射频电极107外面包覆着介质阻挡层,接地电极108外面包覆着介质阻挡层,射频电极之间以及射频电极与接地电极之间为三个喷口,喷枪工作时,在喷口喷出高密度的自由基束流,射频电极与壳体104之间由绝缘块201隔离。  Please refer to Fig. 2, the plasma free radical cleaning spray gun of this normal pressure double radio frequency electrode, the gas supply line 103 is connected with the air inlet 202 of spray gun, and working gas enters the inside of spray gun through air inlet 202, and the outside of radio frequency electrode 107 is coated with Dielectric barrier layer, the ground electrode 108 is covered with a dielectric barrier layer, between the radio frequency electrodes and between the radio frequency electrode and the ground electrode are three nozzles, when the spray gun is working, a high-density free radical beam is ejected at the nozzle, and the radio frequency electrode It is isolated from the housing 104 by an insulating block 201 . the

上面参考附图结合具体的实施例对本实用新型进行了描述,然而,需要说明的是,对于本领域的技术人员而言,在不脱离本实用新型的精神和范围的情况下,可以对上述实施做出许多改变和修改,这些改变和修改都落在本实用新型的权利要求限定的范围内。  The utility model has been described above in conjunction with specific embodiments with reference to the accompanying drawings. However, it should be noted that, for those skilled in the art, without departing from the spirit and scope of the utility model, the above-mentioned implementation can be There are many changes and modifications that fall within the scope of the claims of the present invention. the

Claims (4)

1.一种常压双射频电极的等离子体自由基清洗喷枪,包括两个射频电极、介质阻挡层、两个接地电极和一个射频电源,其特征在于:该喷枪呈长方体,其中一面接进气口,相对的面为喷口,除喷口面外,喷枪其余各面均为金属板,两个接地电极被介质阻挡层包覆,两个接地电极之间为两个射频电极,形成三个喷口,两个射频电极被介质阻挡层包覆,工作气体从喷枪喷口喷出,在常压下,电源接通后,在三个喷口中均产生辉光等离子体,等离子体中的自由基在气流的携带下向外喷出。 1. A plasma free radical cleaning spray gun with dual radio frequency electrodes at atmospheric pressure, comprising two radio frequency electrodes, a dielectric barrier, two ground electrodes and a radio frequency power supply, is characterized in that: the spray gun is a cuboid, one side of which is connected to the air inlet The opposite surface is the nozzle, except for the nozzle surface, the other sides of the spray gun are metal plates, the two ground electrodes are covered by a dielectric barrier layer, and the two ground electrodes are two radio frequency electrodes, forming three nozzles, The two radio frequency electrodes are covered by a dielectric barrier layer, and the working gas is ejected from the nozzle of the spray gun. Under normal pressure, after the power is turned on, glow plasma is generated in the three nozzles, and the free radicals in the plasma Spray outwards while carrying. 2.如权利1所述的常压双射频电极的等离子体自由基清洗喷枪,其特征在于:接地电极与射频电极的制作材料均为金属材料。 2. The plasma free radical cleaning spray gun with dual radio frequency electrodes at atmospheric pressure as claimed in claim 1, characterized in that: the ground electrode and the radio frequency electrode are made of metal materials. 3.如权利1所述的常压双射频电极的等离子体自由基清洗喷枪,其特征在于:接地电极与射频电极以及射频电极与射频电极之间形成的三个喷口大小相等,宽度范围为0.5-2.0mm。 3. the plasma free radical cleaning spray gun of normal pressure dual radio frequency electrodes as claimed in right 1, it is characterized in that: the size of three nozzles formed between the ground electrode and the radio frequency electrode and the radio frequency electrode and the radio frequency electrode is equal, and the width range is 0.5 -2.0mm. 4.如权利1所述的常压双射频电极的等离子体自由基清洗喷枪,其特征在于:两个接地电极之间是两个相邻的射频电极。  4. The plasma free radical cleaning spray gun with double radio frequency electrodes at atmospheric pressure as claimed in claim 1, characterized in that: two adjacent radio frequency electrodes are between the two ground electrodes. the
CN 201220139232 2012-04-05 2012-04-05 Plasma free radical cleaning spray gun with normal-pressure double radio-frequency electrodes Expired - Fee Related CN202591170U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013149482A1 (en) * 2012-04-05 2013-10-10 中国科学院微电子研究所 New normal-pressure dual radio frequency electrode plasma free radical cleaning spray gun
CN103889138A (en) * 2012-12-24 2014-06-25 中国科学院微电子研究所 Plasma discharge device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013149482A1 (en) * 2012-04-05 2013-10-10 中国科学院微电子研究所 New normal-pressure dual radio frequency electrode plasma free radical cleaning spray gun
CN103889138A (en) * 2012-12-24 2014-06-25 中国科学院微电子研究所 Plasma discharge device
CN103889138B (en) * 2012-12-24 2016-06-29 中国科学院微电子研究所 Plasma discharge device

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