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CN1952020A - Chestnut shell natural dye preparation and its uses - Google Patents

Chestnut shell natural dye preparation and its uses Download PDF

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Publication number
CN1952020A
CN1952020A CN 200610154538 CN200610154538A CN1952020A CN 1952020 A CN1952020 A CN 1952020A CN 200610154538 CN200610154538 CN 200610154538 CN 200610154538 A CN200610154538 A CN 200610154538A CN 1952020 A CN1952020 A CN 1952020A
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Prior art keywords
dye
chestnut shell
dyeing
natural
mordant
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Chinese (zh)
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余志成
张伟伟
马廷方
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WANSHILI SILK SCIENCE-TECHNOLOGY Co Ltd HANGZHOU
Zhejiang Sci Tech University ZSTU
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WANSHILI SILK SCIENCE-TECHNOLOGY Co Ltd HANGZHOU
Zhejiang Sci Tech University ZSTU
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Priority to CN 200610154538 priority Critical patent/CN1952020A/en
Publication of CN1952020A publication Critical patent/CN1952020A/en
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Abstract

本发明公开了一种板栗壳天然染料的制备及其应用。先将板栗壳粉碎，在5～10倍pH为8～10的碳酸钠水溶液、95～100℃，60～90min条件下进行浸提，过滤得天然染料原液；再将天然染料原液浓缩、固化、粉碎，得粉末状天然染料。板栗壳天然染料宜采用予媒染、后媒染染色法，对蛋白质、纤维素、锦纶纤维，纱线或织物都具有良好的染色效果。本发明它从废弃板栗壳中提取天然染料，制备过程不会造成环境污染；染色后织物穿着安全，不会有致癌、致畸作用或引起过敏反应；与生态环境相容性好，可生物降解；而且板栗壳原料丰富，染料提取工艺简单，质量稳定，其市场前景将是十分广阔的。The invention discloses the preparation and application of a natural chestnut shell dye. First crush the chestnut shell, extract it in 5-10 times the sodium carbonate aqueous solution with a pH of 8-10, 95-100°C, and 60-90 minutes, and filter to obtain the natural dye stock solution; then concentrate and solidify the natural dye stock solution. Crush to obtain powdered natural dyes. Chestnut shell natural dyes should adopt pre-mordant and post-mordant dyeing methods, which have good dyeing effects on protein, cellulose, nylon fibers, yarns or fabrics. The invention extracts natural dyes from discarded chestnut shells, and the preparation process will not cause environmental pollution; the dyed fabrics are safe to wear, and will not cause carcinogenic, teratogenic or allergic reactions; they have good compatibility with the ecological environment and are biodegradable. ; And the chestnut shell is rich in raw materials, the dye extraction process is simple, and the quality is stable, and its market prospect will be very broad.

Description

The preparation of chestnut shell natural dye and application thereof
Technical field
The present invention relates to natural dyestuff and Application Areas thereof, particularly relate to a kind of preparation and application thereof of chestnut shell natural dye.
Background technology
Since the eighties in 20th century, along with the continuous enhancing of human environmental consciousness and to the growing interest of self health, the partial synthesis dyestuff is more and more noticeable to the harm that human health and ecotope are produced.Existing result of study shows; there are 23 kinds of carcinogenic aromatic amines, more than 100 synthetic dyestuff might produce carcinogenic substance; more than 20 synthetic dyestuff produce irritated to skin ... and deepening continuously along with science and technology development and dyestuff toxicologic study; so-called environmental protection of present stage or ecological dyestuff; whether also can enter into the ranks of forbidding dyestuff, people are also unknown.Therefore, synthetic dyestuff and painted textiles thereof are suspected the human consumer.Moreover, along with the continuous consumption of petroleum resources on the earth, be becoming tight by day for the raw material problem of synthetic dyestuff.
Natural dyestuff is meant root, leaf, bark, trunk, shell, flower or animal secretions from plant, the mineral substance and extracts that preparation process can not cause environmental pollution; Dyeing back fabric is worn safety, carcinogenic, teratogenesis is arranged unlike some synthetic dyestuff textiles or cause allergic reaction, and natural dyestuff and ecotope consistency is good, biodegradable; Except that the dyeing function, the part natural dyestuff also has the medicinal health-care function.Natural dyestuff is a renewable resources, does not have the exhausted problem of resource, has greatly enriched the dyestuff resource, can cooperatively interact with synthetic dyestuff, learn from other's strong points to offset one's weaknesses, and performance advantage separately, its market outlook will be very wide.
Chinese chestnut, being commonly called as chestnut, is China's special product, have the laudatory title of the king ＂ of ＂ thousand fruits, be a kind of protective foods that people extremely like, be rich in sugar, starch, protein, fat and multivitamin (vitamins C, VITMAIN B1) and mineral substance (phosphorus, calcium, iron etc.).The traditional Chinese medical science thinks that chestnut distinguishes the flavor of sweet warm in naturely, nontoxic, has that tonifying spleen is good for the stomach, the effect of the strong muscle of kidney tonifying.Along with deepening continuously of Chinese chestnut deep processing, chestnut shell quantity sharply increases, and the chestnut shell that abandons is countless, and is very unfortunate.Contain Flavonoid substances in the chestnut shell, not only can be used as a kind of natural brown dyestuff textiles is dyeed, also have functions such as antibacterial, ultraviolet radiation preventing.Therefore, extract a kind of brown natural dyestuff and be applied to textile dyeing from chestnut shell, chestnut shell is turned waste into wealth, China is developed a circular economy, building a resource-conserving and environment-friendly society has crucial meaning.
About the preparation and the application thereof of chestnut shell natural dye, have not yet to see report to some extent.
Summary of the invention
The object of the present invention is to provide a kind of preparation and application thereof of chestnut shell natural dye.
The technical solution adopted for the present invention to solve the technical problems is:
One, a kind of preparation of chestnut shell natural dye
The step of this method is as follows:
1) chestnut shell is cleaned, dried, mechanical disintegration joins then in 5～10 times of aqueous solution and soaks, treat that chestnut shell is fully wetting after, add yellow soda ash, the pH of regulator solution is 8～10, is warming up to 95～100 ℃, insulation 60～90min filters; It is 8～10 solution lixiviate that filter residue continues with containing yellow soda ash pH, filters, and merges vat liquor twice, natural dyestuff stoste;
2) the natural dyestuff stoste of extracting is concentrated, get the paste dyestuff;
3) gained paste dyestuff is cured, pulverizes, get Powdered natural dyestuff.
Two, a kind of application of chestnut shell natural dye
1. to protein, Mierocrystalline cellulose, nylon fibre, it is as follows that yarn or fabric carry out the painted step of pre-matchmaker:
1) pollutant is immersed in the water, make it fully wetting, take out then and extract, stand-by;
2) with Fe 2+, Fe 3+, Al 3+, Nd 3+Salt or its two kinds of mixtures as mordant, concentration is 0.1～10% of pollutant weight, under 40～80 ℃ of temperature, bath raio 1: 20～50 is handled 20～40min, cleans;
3) after the above-mentioned processing, put into the chestnut shell dyestuff again and dye, dyeing recipe is: dye strength be pollutant weight 0.1～10%, pH value 3-6, bath raio 1: 20～100,80～100 ℃ of temperature, time 30～90min; Dye completely, water cleans, oven dry.
2. to protein, Mierocrystalline cellulose, nylon fibre, it is as follows that yarn or fabric carry out the painted step of back matchmaker:
1) pollutant is immersed in the water, make it fully wetting, take out then and extract, stand-by;
2) after the above-mentioned processing, put into the chestnut shell dyestuff and dye, dyeing recipe is: dye strength be pollutant weight 0.1～10%, pH value 3-6, bath raio 1: 20～100,80～100 ℃ of temperature, time 30～90min; Dye completely, water cleans;
3) with Fe 2+, Fe 3+, Al 3+, Nd 3+Salt or its two kinds of mixtures as mordant, concentration is 0.1～10% of pollutant weight, under 40～80 ℃ of temperature, bath raio 1: 20～50 is handled 20～40min, cleans oven dry.
The beneficial effect that the present invention has is: the present invention extracts natural dyestuff from discarded chestnut shell, and to protein, Mierocrystalline cellulose, nylon fibre, yarn or fabric dye, and Color is good.Preparation process can not cause environmental pollution; Dyeing back fabric is worn safety, does not have carcinogenic, teratogenesis or causes allergic reaction; Good, biodegradable with the ecotope consistency; And the chestnut shell abundant raw material, the dyestuff extraction process is simple, steady quality, and its market outlook will be very wide.
Embodiment
Embodiment 1: the chestnut shell natural dye preparation
Chestnut shell is cleaned, dried, mechanical disintegration.Take by weighing the chestnut shell of a certain amount of pulverizing, with 10 times of water loggings bubble, treat that chestnut shell is fully wetting after, add the yellow soda ash of aequum, regulator solution pH is about 10, is warming up to 100 ℃, insulation 60min after-filtration.It is about 10 solution lixiviate that filter residue continues with containing yellow soda ash pH, filters, and merges vat liquor twice, natural dyestuff stoste; Concentrate, solidify, pulverize, promptly obtain Powdered chestnut shell natural dye.
The pre-mordant dyeing look of embodiment 2 cocoon fibers
1. cocoon fiber is immersed in the water, make it fully wetting.Take out then and extract, stand-by.
2. with the cocoon fiber of above-mentioned processing, join in the copperas solution of 10% (o.w.f) and carry out pre-mordant dyeing, bath raio is 1: 50,60 ℃ of temperature, treatment time 40min; Take out fabric, clean.
3. the chestnut shell dyestuff is made into dye liquor, dye strength is 10% (o.w.f), and the pH value is 4, bath raio 1: 50, and cocoon fiber is under 95 ℃ of temperature, and 90min dyes.Dye completely, water cleans, oven dry.
Mordant dyeing look behind embodiment 3 silk broadcloths
1. silk broadcloth is immersed in the water, make it fully wetting.Take out then and extract, stand-by.
2. the chestnut shell dyestuff is made into dye liquor, dye strength is 1% (o.w.f), and dye liquor pH value is 6, bath raio 1: 20, and silk broadcloth is under 85 ℃ of temperature, and 50min dyes.Dye completely, water cleans.
3. the back fabric that will dye joins and carries out back mordant dyeing processing in the aluminum potassium sulfate solution that contains 3% (o.w.f), and bath raio is 1: 40,80 ℃ of temperature, time 30min.Dye completely, water cleans, oven dry.
Mordant dyeing look behind embodiment 4 wool fabrics
1. wool fabric is immersed in the water, make it fully wetting.Take out then and extract, stand-by.
2. the chestnut shell dyestuff is made into dye liquor, dye strength is 0.2% (o.w.f), and dye liquor pH value is 3, bath raio 1: 100, and wool fabric is under 100 ℃ of temperature, and 30min dyes.Dye completely, water cleans.
3. DYED FABRICS is joined and carry out back mordant dyeing processing in the neodymium chloride solution that contains 1% (o.w.f), bath raio is 1: 30,40 ℃ of temperature, time 30min.Take out fabric after disposing, clean.
The pre-mordant dyeing look of embodiment 5 cottons
1. cotton is immersed in the water, make it fully wetting.Take out then and extract, stand-by.
2. with the cotton of above-mentioned processing, join in the copperas solution of 0.2% (o.w.f) and carry out pre-mordant dyeing, bath raio is 1: 20,60 ℃ of temperature, treatment time 20min; Take out yarn, clean.
3. the chestnut shell dyestuff is made into dye liquor, dye strength is 5% (o.w.f), and dye liquor pH value is 5, bath raio 1: 50,95 ℃ of dyeing 60min.Dye completely, water cleans, oven dry.
Mordant dyeing look behind embodiment 6 sodolins
1. sodolin is immersed in the water, make it fully wetting.Take out then and extract, stand-by.
2. the chestnut shell dyestuff is made into dye liquor, dye strength is 3% (o.w.f), and dye liquor pH value is 4, bath raio 1: 50, and after fabric immerses dye liquor, under 95 ℃ of temperature, dyeing 60min.Dye completely, water cleans.
3. DYED FABRICS joins in 2% (o.w.f) Tai-Ace S 150,3% copperas solution, carries out the back mordant dyeing and handles, and bath raio is 1: 50, and 60 ℃ of temperature are taken out fabric, washing behind the insulation 30min.
Mordant dyeing look behind embodiment 7 nylon fibres
1. nylon fibre is immersed in the water, make it fully wetting.Take out then and extract, stand-by.
2. the chestnut shell dyestuff is made into dye liquor, dye strength is 6% (o.w.f), and dye liquor pH value is 6, bath raio 1: 80, and after fiber immerses dye liquor, under 100 ℃ of temperature, dyeing 60min.Dye completely, water cleans.
3. dyeing back fiber joins in the copperas solution of 5% (o.w.f), carries out the back mordant dyeing and handles, and bath raio is 1: 50, and 50 ℃ of temperature are taken out fabric, washing behind the insulation 30min.

Claims (3)

1.一种板栗壳天然染料的制备，其特征在于该方法的步骤如下：1. a kind of preparation of chestnut shell natural dye is characterized in that the steps of the method are as follows: 1)将板栗壳洗净、晾干，机械粉碎，然后加入到5～10倍水溶液中浸泡，待板栗壳充分润湿后，加入碳酸钠，调节溶液的pH为8～10，升温至95～100℃，保温60～90min，过滤；滤渣继续用含碳酸钠pH为8～10的溶液浸提，过滤，合并两次浸提液，得天然染料原液；1) Wash the chestnut shell, dry it, crush it mechanically, and then add it to 5-10 times the aqueous solution for soaking. After the chestnut shell is fully wetted, add sodium carbonate, adjust the pH of the solution to 8-10, and heat up to 95-95. 100°C, keep warm for 60-90 minutes, and filter; continue to extract the filter residue with a solution containing sodium carbonate with a pH of 8-10, filter, and combine the two extractions to obtain a natural dye stock solution; 2)将提取的天然染料原液浓缩，得膏状染料；2) Concentrating the extracted natural dye stock solution to obtain paste dye; 3)对所得膏状染料进行固化，粉碎，得粉末状天然染料。3) solidify and pulverize the obtained pasty dye to obtain powdery natural dye. 2.一种板栗壳天然染料的应用，其特征在于对蛋白质、纤维素、锦纶纤维，纱线或织物进行预媒染色的步骤如下：2. an application of chestnut shell natural dye is characterized in that protein, cellulose, nylon fiber, yarn or fabric are carried out the step of pre-mordant dyeing as follows: 1)将被染物浸入水中，使其充分润湿，然后取出挤干，待用；1) Immerse the dyed object in water to make it fully wet, then take it out and squeeze it dry for use; 2)将Fe2+、Fe3+、Al3+、Nd3+的盐或其两种混合物作为媒染剂，浓度为被染物重量的0.1～10％，在40～80℃温度下，浴比1∶20～50，处理20～40min，洗净；2) Use the salt of Fe 2+ , Fe 3+ , Al 3+ , Nd 3+ or their two mixtures as a mordant, the concentration is 0.1-10% of the weight of the dyed object, at a temperature of 40-80°C, the bath ratio 1: 20~50, treat for 20~40min, wash; 3)上述处理后，再放入板栗壳染料中染色，染色配方为：染料浓度为被染物重量的0.1～10％、pH值3-6，浴比1∶20～100，温度80～100℃，时间30～90min；染毕，用水清洗，烘干。3) After the above treatment, put it into the chestnut shell dye for dyeing. The dyeing formula is: the dye concentration is 0.1-10% of the weight of the dyed object, the pH value is 3-6, the bath ratio is 1:20-100, and the temperature is 80-100°C , time 30-90min; after dyeing, wash with water and dry. 3.一种板栗壳天然染料的应用，其特征在于对蛋白质、纤维素、锦纶纤维，纱线或织物进行后媒染色的步骤如下：3. the application of a kind of chestnut shell natural dyestuff is characterized in that to protein, cellulose, nylon fiber, the step that yarn or fabric are carried out after mordant dyeing is as follows: 1)将被染物浸入水中，使其充分润湿，然后取出挤干，待用；1) Immerse the dyed object in water to make it fully wet, then take it out and squeeze it dry for use; 2)上述处理后，放入板栗壳染料中染色，染色配方为：染料浓度为被染物重量的0.1～10％、pH值3-6，浴比1∶20～100，温度80～100℃，时间30～90min；染毕，用水清洗；2) After the above treatment, put it into the chestnut shell dye for dyeing. The dyeing formula is: the dye concentration is 0.1-10% of the weight of the dyed object, the pH value is 3-6, the bath ratio is 1:20-100, and the temperature is 80-100°C. Time 30-90min; after dyeing, wash with water; 3)将Fe2+、Fe3+、Al3+、Nd3+的盐或其两种混合物作为媒染剂，浓度为被染物重量的0.1～10％，在40～80℃温度下，浴比1∶20～50，处理20～40min，洗净，烘干。3) Use the salt of Fe 2+ , Fe 3+ , Al 3+ , Nd 3+ or their two mixtures as a mordant, the concentration is 0.1-10% of the weight of the dyed object, at a temperature of 40-80°C, the bath ratio 1:20~50, treat for 20~40min, wash and dry.
CN 200610154538 2006-11-07 2006-11-07 Chestnut shell natural dye preparation and its uses Pending CN1952020A (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101177542B (en) * 2007-11-16 2010-06-09 浙江理工大学 A kind of preparation method of many natural dyes
CN101880468A (en) * 2010-07-01 2010-11-10 盐城纺织职业技术学院 The preparation method and application of the natural dye of Chive lotus capsule
CN102757663A (en) * 2011-04-26 2012-10-31 中国科学院沈阳应用生态研究所 Chestnut shell pigment grading method
CN102995462A (en) * 2012-12-25 2013-03-27 常州大学 Natural antibacterial coloured fabric and preparation method thereof
CN103790032A (en) * 2013-03-15 2014-05-14 辽东学院 Natural plant dye colored textile fiber knitted fabric and preparation method thereof
CN106221284A (en) * 2016-07-29 2016-12-14 黄毅 A kind of extraction process of vegetable dyeing agent
CN106283722A (en) * 2016-08-03 2017-01-04 南通纺织丝绸产业技术研究院 A kind of natural dye method to chitin fiber textile dyeing
CN107268304A (en) * 2017-08-04 2017-10-20 浙江理工大学 A kind of method that rare earth mordant dyeing modified dacron fabric is used based on the extraction by tea dye liquor
CN109371715A (en) * 2018-11-29 2019-02-22 刘日昇 A method of it extracting cordate houttuynia pigment and cotton-spinning fabric is dyed
CN109826029A (en) * 2019-01-20 2019-05-31 林燕 A method of it extracting cordate houttuynia pigment and cotton-spinning fabric is dyed
CN113480872A (en) * 2021-07-07 2021-10-08 苏州麻朵纺织科技有限公司 Method for preparing chestnut shell vegetable dye by subcritical method and dyeing method thereof
CN114395929A (en) * 2021-12-27 2022-04-26 珠海无用文化创意有限公司 Method for manufacturing novel imitation leather fabric
CN114575172A (en) * 2022-03-30 2022-06-03 浙江理工大学 Method for dyeing cotton yarn by using chestnut shell pigment
CN114606783A (en) * 2022-03-18 2022-06-10 德州学院 A process of dyeing hemp with ebony

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101177542B (en) * 2007-11-16 2010-06-09 浙江理工大学 A kind of preparation method of many natural dyes
CN101880468A (en) * 2010-07-01 2010-11-10 盐城纺织职业技术学院 The preparation method and application of the natural dye of Chive lotus capsule
CN102757663A (en) * 2011-04-26 2012-10-31 中国科学院沈阳应用生态研究所 Chestnut shell pigment grading method
CN102757663B (en) * 2011-04-26 2013-11-27 中国科学院沈阳应用生态研究所 A kind of grading method of chestnut shell pigment
CN102995462A (en) * 2012-12-25 2013-03-27 常州大学 Natural antibacterial coloured fabric and preparation method thereof
CN103790032A (en) * 2013-03-15 2014-05-14 辽东学院 Natural plant dye colored textile fiber knitted fabric and preparation method thereof
CN106221284A (en) * 2016-07-29 2016-12-14 黄毅 A kind of extraction process of vegetable dyeing agent
CN106283722B (en) * 2016-08-03 2018-08-21 南通纺织丝绸产业技术研究院 A method of with natural dye to chitin fiber textile dyeing
CN106283722A (en) * 2016-08-03 2017-01-04 南通纺织丝绸产业技术研究院 A kind of natural dye method to chitin fiber textile dyeing
CN107268304A (en) * 2017-08-04 2017-10-20 浙江理工大学 A kind of method that rare earth mordant dyeing modified dacron fabric is used based on the extraction by tea dye liquor
CN109371715A (en) * 2018-11-29 2019-02-22 刘日昇 A method of it extracting cordate houttuynia pigment and cotton-spinning fabric is dyed
CN109826029A (en) * 2019-01-20 2019-05-31 林燕 A method of it extracting cordate houttuynia pigment and cotton-spinning fabric is dyed
CN113480872A (en) * 2021-07-07 2021-10-08 苏州麻朵纺织科技有限公司 Method for preparing chestnut shell vegetable dye by subcritical method and dyeing method thereof
CN114395929A (en) * 2021-12-27 2022-04-26 珠海无用文化创意有限公司 Method for manufacturing novel imitation leather fabric
CN114606783A (en) * 2022-03-18 2022-06-10 德州学院 A process of dyeing hemp with ebony
CN114575172A (en) * 2022-03-30 2022-06-03 浙江理工大学 Method for dyeing cotton yarn by using chestnut shell pigment

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