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CN1938621B - Optical mode noise averaging device - Google Patents

Optical mode noise averaging device Download PDF

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Publication number
CN1938621B
CN1938621B CN200580010448.0A CN200580010448A CN1938621B CN 1938621 B CN1938621 B CN 1938621B CN 200580010448 A CN200580010448 A CN 200580010448A CN 1938621 B CN1938621 B CN 1938621B
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optical fiber
fiber
multimode optical
temperature
multimode
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CN1938621A (en
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B.·P.·马斯特森
艾利克·C.·休尔森
伊恩·S.·史密斯
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Zhengdian Technology Co ltd
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Zolo Technologies Inc
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Abstract

一种光模式噪声平均装置(304),包括:多模光纤(302)和平均装置(308),用于平均该多模光纤(302)内传播的光模式噪声诱发的信号强度变化。在一个选取的时间段内,通过周期性改变多模光纤(302)的折射率,扰乱多模光纤(302)内的光分布,或二者,平均装置可以平均模式噪声诱发的信号强度变化。通过周期性改变多模光纤(302)的温度,可以周期性改变该多模光纤的折射率。或者,通过周期性操作多模光纤(302),可以改变折射率或可以扰乱该多模光纤内的光分布。

An optical mode noise averaging device (304), comprising: a multimode optical fiber (302) and an averaging device (308), used for averaging signal intensity variations induced by optical mode noise propagating in the multimode optical fiber (302). The averaging means may average modal noise induced signal strength variations by periodically varying the refractive index of the multimode fiber (302), perturbing the light distribution within the multimode fiber (302), or both, over a selected period of time. By periodically changing the temperature of the multimode fiber (302), the refractive index of the multimode fiber can be changed periodically. Alternatively, by periodically manipulating the multimode fiber (302), the refractive index can be changed or the light distribution within the multimode fiber can be disturbed.

Description

光模式噪声平均装置Optical Pattern Noise Averaging Device

技术领域 technical field

本发明涉及燃烧监测操作,具体涉及用于平均与多模光纤相关的模式噪声的设备和方法。The present invention relates to combustion monitoring operations, and more particularly to apparatus and methods for averaging modal noise associated with multimode optical fibers.

背景技术 Background technique

在美国产生的大部分电功率是在燃煤火力发电厂生产的。大多数全球性电产量同样地依靠煤作为主要的能源。只要长期的环境影响是来自核能生产厂的废物贮存以及与太阳能发电厂的低效率,在可以预见的未来,煤仍然可能作为主要的能源。此外,巨大的全球性煤炭贮存量在当前的消耗水平下足以维持至少200年。Most of the electrical power generated in the United States is produced at coal-fired thermal power plants. Most global electricity production also relies on coal as the primary source of energy. As long as the long-term environmental impacts are from waste storage at nuclear power plants and inefficiencies with solar power plants, coal is likely to remain the primary source of energy for the foreseeable future. Furthermore, the huge global coal stockpiles are sufficient to last at least 200 years at current consumption levels.

然而,现在和将来对于减少与燃煤发电相关的污染物排放以及增加燃煤发电过程的整体效率仍有很高的要求。传统上,在火力发电厂和其他工业燃烧设备中,燃烧过程的效率和污染物排放的水平是利用诸如非分散型红外线(NDIR)光度测量法的技术通过提取气体样本的测量而间接确定的。提取物抽样系统不是特别适合于闭环控制燃烧过程,因为在气体提取与最终分析的时间之间可以引入很大的时间延迟。此外,提取过程通常得到单点的测量结果,在高度变化和动态燃烧过程室内,该测量结果可能或不可能代表测量品种的实际浓度。However, there are still high demands now and in the future to reduce the pollutant emissions associated with coal-fired power generation and to increase the overall efficiency of the coal-fired power generation process. Traditionally, in thermal power plants and other industrial combustion facilities, the efficiency of the combustion process and the level of pollutant emissions have been determined indirectly through measurements taken from gas samples using techniques such as non-dispersive infrared (NDIR) photometry. Extractive sampling systems are not particularly well suited for closed-loop control of combustion processes, as significant time delays can be introduced between the time of gas extraction and final analysis. In addition, the extraction process typically results in a single-point measurement that may or may not represent the actual concentration of the species being measured within the highly variable and dynamic combustion process chamber.

最近以来,一直利用激光基光分子品种传感器解决与提取测量技术相关的问题。激光基测量技术可以在现场实现,它的另一个优点是适合于动态过程控制的高速反馈。一种用于测量燃烧气体成分,温度和其他燃烧参数的有前景技术是可调谐二极管激光吸收光谱术(TDLAS)。TDLAS非常适合于控制和监测燃煤的燃烧过程。TDLAS同样适合于监测其他的燃烧过程。具体地说,此处描述的光谱术适用于监测和控制喷气飞机发动机燃烧过程。TDLAS通常是利用在近红外和中红外光谱区工作的二极管激光器实现的。合适的激光器广泛地应用于电信工业,所以,在TDLAS应用中是容易获得的。人们已开发多多少少适合于检测和控制燃烧过程的各种TDLAS技术。众所周知的技术是波长调制光谱术,频率调制光谱术和直接吸收光谱术。这些技术中的每种技术是基于检测器接收的激光数量与性质之间的预定关系,这是发生在光传输通过燃烧过程室并在特定光谱带被吸收之后,光谱带是在该过程或燃烧室中气体的特征频谱带。检测器接收的吸收谱用于确定被分析气体品种的数量以及相关的燃烧参数,例如,温度。More recently, laser-based photomolecular species sensors have been used to solve problems associated with extraction measurement techniques. Another advantage of laser-based measurement technology, which can be implemented in the field, is high-speed feedback suitable for dynamic process control. One promising technique for measuring combustion gas composition, temperature and other combustion parameters is tunable diode laser absorption spectroscopy (TDLAS). TDLAS is well suited for controlling and monitoring coal-fired combustion processes. TDLAS is also suitable for monitoring other combustion processes. Specifically, the spectroscopy described here is suitable for monitoring and controlling combustion processes in jet aircraft engines. TDLAS is usually implemented using diode lasers operating in the near-infrared and mid-infrared spectral regions. Suitable lasers are widely used in the telecommunications industry and are therefore readily available in TDLAS applications. Various TDLAS techniques have been developed which are more or less suitable for monitoring and controlling combustion processes. Well known techniques are wavelength modulation spectroscopy, frequency modulation spectroscopy and direct absorption spectroscopy. Each of these techniques is based on a predetermined relationship between the amount and nature of the laser light received by the detector, which occurs after the light is transmitted through the combustion process chamber and is absorbed in a specific spectral band that occurs in the process or combustion process. The characteristic spectral bands of the gas in the chamber. The absorption spectrum received by the detector is used to determine the quantity of the gas species analyzed and the associated combustion parameters, eg temperature.

典型的燃煤火力发电厂中燃烧室的一侧尺寸是10-20米。火力发电厂的燃料是粉煤,它产生的燃烧过程因高度粉尘而使激光的传输受阻,而且还发出强光。其环境也是高度湍流的。由于粒子的宽带吸收,散射或由于折射率起伏造成的光束转向,光通过燃烧过程室的总体传输速率是随时间剧烈起伏的。从燃煤颗粒中还产生强烈的热背景辐射,该辐射可以干扰检测器的信号。火力发电厂锅炉以外的环境也使TDLAS检测或控制系统的实施产生问题。例如,任何电子元件,光学系统或其他的灵敏光谱术元件必须放置在远离强烈的热源,或采取合适的屏蔽和冷却措施。即使TDLAS系统在这些条件下的实施是极其困难的,TDLAS仍然是特别适合于监测和控制煤燃烧过程。The size of one side of the combustion chamber in a typical coal-fired thermal power plant is 10-20 meters. The fuel of the thermal power plant is pulverized coal, and the combustion process produced by it is blocked by the transmission of the laser due to the high degree of dust, and it also emits strong light. Its environment is also highly turbulent. The overall transmission rate of light through the combustion process chamber fluctuates wildly with time due to broadband absorption by particles, scattering or beam steering due to refractive index fluctuations. A strong thermal background radiation is also generated from the coal burning particles, which can interfere with the signal of the detector. Environments other than thermal power plant boilers also pose problems for the implementation of TDLAS detection or control systems. For example, any electronic components, optical systems or other sensitive spectroscopy components must be placed away from intense heat sources, or be suitably shielded and cooled. Even though the implementation of TDLAS systems under these conditions is extremely difficult, TDLAS is still particularly suitable for monitoring and controlling the coal combustion process.

如在2004年3月31日申请的International PatentApplication Serial Number PCT/US04/10048(Publication NumberWO2004/090496)中所详细地讨论的,其标题是“METHOD ANDAPPARATUS FOR THE MONITORING AND CONTROL OFCOMBUSION”,该申请全文合并在此供参考,光纤耦合对于实施TDLAS系统是特别有利的。在光纤耦合系统中,一个或多个探测光束传输到发射端光学设备并投射进入燃烧室,该光束可以由各种相关波长的复用光束构成。在传输通过燃烧室之后,探测光束是在接收端光学设备中被接收。如在International Patent Application SerialNumber PCT/US04/10048中所详细讨论的,在接收端光学系统中使用多模光纤是有利的。使用多模光纤必然产生模式噪声,模式噪声是被检测光的信号强度变化,它是在收集和传输光的多模光纤芯中非均匀的时间和波长变化的光分布产生的。接收端模式噪声可以妨碍有效TDLAS必须观察的吸收特征。As discussed in detail in International Patent Application Serial Number PCT/US04/10048 (Publication Number WO2004/090496), filed March 31, 2004, entitled "METHOD ANDAPPARATUS FOR THE MONITORING AND CONTROL OF COMBUSION", which application is incorporated in its entirety For reference herein, fiber optic coupling is particularly advantageous for implementing TDLAS systems. In a fiber-coupled system, one or more probe beams, which can be composed of multiplexed beams of various relevant wavelengths, are transmitted to the launch optics and projected into the combustion chamber. After passing through the combustion chamber, the probe beam is received in the receiver optics. As discussed in detail in International Patent Application Serial Number PCT/US04/10048, it is advantageous to use multimode fiber in the receiver optical system. The use of multimode fiber inevitably produces modal noise, which is the signal intensity variation of the detected light, which is generated by the non-uniform time and wavelength-varying light distribution in the multimode fiber core that collects and transmits light. Receive-side mode noise can interfere with the absorption characteristics that must be observed for effective TDLAS.

模式噪声的现象不限于TDLAS或由TDLAS装置造成的,TDLAS装置的特征是接收端多模光纤。与此相反,模式噪声不可避免地发生在有足够长度用于传输光的任何多模光纤中。模式噪声在多模光纤中是不可避免的,因为多模光纤与单模光纤比较有很大的截面直径,它可以使光沿多条光程或以多个模式传播。一些光程或模式比其他的光程或模式长或短。因此,必然发生相长干涉和相消干涉,从而在多模光纤的纤芯中产生非均匀的时间和波长变化的光分布,它造成典型的模式噪声散斑图形。因此,模式噪声发生在利用足够长度多模光纤的计算,电信,或其他的科学设备中。模式噪声是否影响给定光学系统的效率取决于特定系统的要求。The phenomenon of modal noise is not limited to TDLAS or is caused by TDLAS devices, which are characterized by multimode fibers at the receiving end. In contrast, modal noise inevitably occurs in any multimode fiber of sufficient length to transmit light. Mode noise is unavoidable in multimode fiber, because multimode fiber has a large cross-sectional diameter compared with single-mode fiber, which allows light to propagate along multiple optical paths or in multiple modes. Some pathlengths or modes are longer or shorter than others. Therefore, constructive interference and destructive interference must occur, resulting in a non-uniform time- and wavelength-varying light distribution in the core of the multimode fiber, which causes the typical mode noise speckle pattern. Thus, modal noise occurs in computing, telecommunications, or other scientific equipment that utilizes multimode fiber of sufficient length. Whether modal noise affects the efficiency of a given optical system depends on the requirements of the particular system.

本发明的目的是克服以上讨论的一个或多个问题。It is an object of the present invention to overcome one or more of the problems discussed above.

发明内容 Contents of the invention

本发明是一种光模式噪声平均装置,包括:多模光纤和平均装置,用于平均该多模光纤内传播的光模式噪声诱发的信号强度变化。在一个选取的时间段内,通过周期性改变多模光纤的折射率,扰乱多模光纤的光分布,或二者,平均装置可以平均模式噪声诱发的信号强度变化。通过周期性改变多模光纤的温度,可以周期性改变该多模光纤的折射率。通过周期性和实际操作多模光纤,可以改变折射率或可以扰乱该多模光纤内的光分布。The invention is an optical mode noise averaging device, comprising: a multimode optical fiber and an averaging device, which is used for averaging the signal intensity variation induced by the optical mode noise propagating in the multimode optical fiber. The averaging means may average modal noise induced signal strength variations by periodically varying the refractive index of the multimode fiber, perturbing the light distribution of the multimode fiber, or both over a selected period of time. By periodically changing the temperature of the multimode fiber, the refractive index of the multimode fiber can be changed periodically. By periodically and physically manipulating a multimode fiber, the refractive index can be changed or the light distribution within the multimode fiber can be disturbed.

通过热元件与多模光纤的热交换作用,可以改变该多模光纤的温度。用作热元件的合适装置包括,但不限于,热电模块,电阻加热器,红外线加热器,化学加热器,普通冷却装置,冷却到环境温度以下的流体源,或加热到环境温度以上的流体源。The temperature of the multimode fiber can be changed through the heat exchange between the heat element and the multimode fiber. Suitable devices for use as thermal elements include, but are not limited to, thermoelectric modules, resistive heaters, infrared heaters, chemical heaters, general cooling devices, fluid sources cooled below ambient temperature, or fluid sources heated above ambient temperature .

光学装置可以包括:与多模光纤热接触的温度传感器,例如,热电偶,和控制器,用于从温度传感器接收输入并控制热元件。The optical device may include a temperature sensor, such as a thermocouple, in thermal contact with the multimode fiber, and a controller for receiving input from the temperature sensor and controlling the thermal element.

在描述用于周期性操作多模光纤的另一个实施例中,该操作可以包括:扭曲多模光纤,拉伸多模光纤,或震动多模光纤。压电拉伸器可用于完成多模光纤的周期性拉伸。或者,电动机可以相对于光纤的纵轴和相对于该光纤的固定部分以交替的顺时针方向和逆时针方向周期性扭曲部分的多模光纤。In another embodiment described for periodically manipulating a multimode fiber, the manipulating may include twisting the multimode fiber, stretching the multimode fiber, or shaking the multimode fiber. Piezoelectric stretchers can be used to complete the periodic stretching of multimode fibers. Alternatively, the motor may periodically twist portions of the multimode fiber in alternating clockwise and counterclockwise directions relative to the longitudinal axis of the fiber and relative to the fixed portion of the fiber.

本发明还涉及一种在多模光纤中平均光模式噪声的方法,包括:耦合光到多模光纤的输入端,周期性改变多模光纤的折射率,和在多模光纤的输出端接收平均的光。模式噪声平均方法可以包括:通过周期性改变多模光纤的温度和周期性操作多模光纤的两种方法之一改变折射率。通过提供与多模光纤热交换的热元件,可以周期性改变多模光纤的温度。或者,通过扭曲多模光纤,拉伸多模光纤或震动多模光纤,可以周期性操作该多模光纤。The invention also relates to a method of averaging optical mode noise in a multimode fiber, comprising: coupling light to the input of the multimode fiber, periodically changing the refractive index of the multimode fiber, and receiving the averaged noise at the output of the multimode fiber of light. The modal noise averaging method may include changing the index of refraction by one of two methods of periodically changing the temperature of the multimode fiber and periodically operating the multimode fiber. The temperature of the multimode fiber can be periodically varied by providing a thermal element in thermal communication with the multimode fiber. Alternatively, the multimode fiber can be manipulated periodically by twisting the multimode fiber, stretching the multimode fiber, or shaking the multimode fiber.

附图说明 Description of drawings

图1是TDLAS检测`设备的示意图;Fig. 1 is the schematic diagram of TDLAS detection equipment;

图2是TDLAS检测`设备的示意图,它描述与燃烧室附近的元件光耦合的远程元件;Figure 2 is a schematic diagram of the TDLAS detection `device, which depicts remote components optically coupled to components near the combustion chamber;

图3是按照本发明光模式噪声平均装置的示意图;3 is a schematic diagram of an optical mode noise averaging device according to the present invention;

图4是温度基相移设备的分解图,其中加热到环境温度以上或冷却到环境温度以下的流体源作为热元件;Figure 4 is an exploded view of a temperature-based phase-shifting device with a fluid source heated above ambient temperature or cooled below ambient temperature as the thermal element;

图5是利用一系列热电装置作为热元件的温度基相移设备的分解图;Figure 5 is an exploded view of a temperature-based phase shifting device utilizing a series of thermoelectric devices as thermal elements;

图6是图5所示温度基相移设备的另一个分解图;Figure 6 is another exploded view of the temperature-based phase shifting device shown in Figure 5;

图7是利用电动机的光模式噪声平均装置示意图,该电动机用于机械操作多模光纤;Figure 7 is a schematic diagram of an optical mode noise averaging device using a motor for mechanically manipulating a multimode optical fiber;

图8是利用压电拉伸器的光模式噪声平均装置示意图,该拉伸器用于机械操作多模光纤;和Figure 8 is a schematic diagram of an optical mode noise averaging apparatus utilizing a piezoelectric stretcher for mechanically manipulating a multimode optical fiber; and

图9是发射端模式噪声减小装置的示意图。FIG. 9 is a schematic diagram of a transmitter mode noise reduction device.

具体实施方式 Detailed ways

A.概述A. Overview

本发明的优选实施例是一种光模式噪声平均设备。在以下的第E节,我们详细地描述该光模式噪声平均设备。光模式噪声平均设备特别适合于,但不限于,平均模式噪声,该噪声是在与光纤耦合的可调谐二极管激光吸收光谱术(TDLAS)检测设备相关的接收端多模光纤中固有的。在2004年3月31日申请的International PatentApplication Serial Number PCT/US04/10048(Publication NumberWO2004/090496)中详细地讨论这种检测设备的多个实施例,其标题是“METHOD AND APPARATUS FOR THE MONITORING ANDCONTROL OF COMBUSION”,全文合并在此供参考。此外,以下描述光纤耦合的TDLAS检测设备。本发明的优选实施例适用于在有模式噪声的任何光学系统中平均光模式噪声。具体地说,光模式噪声平均设备可以在任何的计算,电信,科学研究,或有足够长度的多模光纤传输光的其他系统中实现。该平均设备可用在任何的光学系统中,其中通过平均多模光纤内传输的光中固有的光模式噪声,可以提高该系统的效率。A preferred embodiment of the invention is an optical pattern noise averaging device. In Section E below, we describe the optical pattern noise averaging device in detail. The optical mode noise averaging device is particularly suitable for, but not limited to, averaging mode noise inherent in receive-end multimode fibers associated with fiber-coupled tunable diode laser absorption spectroscopy (TDLAS) detection devices. Multiple embodiments of such detection devices are discussed in detail in International Patent Application Serial Number PCT/US04/10048 (Publication Number WO2004/090496), filed March 31, 2004, entitled "METHOD AND APPARATUS FOR THE MONITORING AND CONTROL OF COMBUSION", the entire text of which is hereby incorporated by reference. In addition, fiber-coupled TDLAS detection equipment is described below. Preferred embodiments of the present invention are applicable to averaging optical pattern noise in any optical system having pattern noise. Specifically, the optical mode noise averaging device can be implemented in any computing, telecommunications, scientific research, or other system that has a sufficient length of multimode optical fiber to transmit light. The averaging device can be used in any optical system in which the efficiency of the system can be increased by averaging the optical mode noise inherent in light propagating within a multimode fiber.

B.检测设备B. Testing equipment

图1表示一个检测设备10的实施例,它适合于检测,监测和控制燃烧过程。利用一系列在近红外或中红外光谱中选取频率下可调谐二极管激光器12发射的激光,检测设备10完成可调谐二极管激光吸收光谱术(TDLAS)。每个可调谐二极管激光器12的输出端耦合到单个光纤,并被路由到复用器16,该光纤可以是单模光纤14。如此处所使用的术语,“耦合”,“光耦合”或“光通信”定义为各个元件之间的功能关系,其中光可以或通过或不通过中间元件或自由空间从第一元件传输到第二元件。在复用器16内产生的一些或所有频率的激光被复用成有多个选取频率的复用探测光束。复用探测光束耦合到发射端光纤18并传输到发射端光学元件20或准直器,它与图1所示的燃烧室22可操作地相关。Figure 1 shows an embodiment of a detection apparatus 10 suitable for monitoring, monitoring and controlling the combustion process. The detection device 10 performs Tunable Diode Laser Absorption Spectroscopy (TDLAS) using a series of laser light emitted by a tunable diode laser 12 at selected frequencies in the near-infrared or mid-infrared spectrum. The output of each tunable diode laser 12 is coupled to a single optical fiber, which may be a single-mode optical fiber 14 , and routed to a multiplexer 16 . As used herein, the terms "coupling", "optical coupling" or "optical communication" are defined as a functional relationship between individual elements in which light can be transmitted from a first element to a second with or without intermediate elements or free space. element. Some or all of the frequencies of laser light generated within multiplexer 16 are multiplexed into multiplexed probe beams having a plurality of selected frequencies. The multiplexed probe beam is coupled to launch fiber 18 and transmitted to launch optics 20 or collimator, which is operatively associated with combustion chamber 22 shown in FIG. 1 .

发射端光学元件20取向成投射复用探测光束通过燃烧室22。在燃烧室22中,接收端光学元件24与发射端光学元件20进行光通信。最好是,接收端光学元件24基本上是与发射端光学元件20相反的,且它的工作是与燃烧室22相关。接收端光学元件24的位置和取向是为了接收通过燃烧室22投射的复用探测光束。接收端光学元件24光耦合到接收端光纤26,该光纤传输部分的接收端光学元件24接收的复用探测光束到去复用器28。在去复用器28内,接收端光学元件24接收的部分复用探测光束被去复用,且每个波长的去复用激光被耦合到输出光纤30。每个输出光纤30再被光耦合到检测器32,该检测器通常是一个对选取激光频率敏感的光电检测器,它被复用成探测光束。基于在检测器频率下传输到检测器32的光性质和数量,检测器32产生一个电信号。来自每个检测器32的电信号通常是数字化信号,并在数据处理系统34中进行分析。如以下详细讨论的,数字化和被分析的数据可用于检测燃烧室内的物理参数,它包括,但不限于,燃烧室22内各种气体品种的浓度和燃烧温度。数据处理系统34还可用于通过反馈回路36发送信号到燃烧控制设备38,从而有源地控制选取的过程参数。在燃烧过程的情况下,过程控制参数可以包括:燃料(例如,粉煤)供给速率;氧气供给速率和催化剂或化学试剂供给速率。利用光纤耦合电子和光学元件到检测设备10的输入端和输出端可以使精密和温度灵敏的设备放置在有稳定工作环境的控制室内,例如,可调谐二极管激光器12,检测器32和数据处理系统34。因此,仅仅相对健壮的发射端光学元件20和接收端光学元件24需要放置在燃烧室22的有害环境附近。Transmit end optics 20 are oriented to project a multiplexed probe beam through combustion chamber 22 . In the combustion chamber 22 , the receiving optical element 24 is in optical communication with the transmitting optical element 20 . Preferably, receiver optics 24 are substantially opposite transmitter optics 20 and operate in relation to combustion chamber 22 . Receiver optics 24 are positioned and oriented to receive the multiplexed probe beam projected through combustion chamber 22 . The receiving optical element 24 is optically coupled to the receiving optical fiber 26 , and the multiplexed probe beam received by the receiving optical element 24 of the optical fiber transmission section is sent to the demultiplexer 28 . In the demultiplexer 28 , part of the multiplexed probe beam received by the optical element 24 at the receiving end is demultiplexed, and the demultiplexed laser light of each wavelength is coupled to the output optical fiber 30 . Each output fiber 30 is in turn optically coupled to a detector 32, typically a photodetector sensitive to a selected laser frequency, which is multiplexed into the probe beam. Detector 32 generates an electrical signal based on the nature and amount of light transmitted to detector 32 at the detector frequency. The electrical signal from each detector 32 is typically digitized and analyzed in a data processing system 34 . As discussed in detail below, the digitized and analyzed data can be used to monitor physical parameters within the combustion chamber including, but not limited to, concentrations of various gas species within the combustion chamber 22 and combustion temperatures. Data processing system 34 may also be used to actively control selected process parameters by sending signals through feedback loop 36 to combustion control device 38 . In the case of a combustion process, process control parameters may include: fuel (eg, pulverized coal) feed rate; oxygen feed rate, and catalyst or chemical reagent feed rate. The use of fiber optics to couple electronic and optical components to the input and output of the detection device 10 allows precision and temperature sensitive equipment to be placed in a control room with a stable operating environment, such as the tunable diode laser 12, the detector 32 and the data processing system 34. Therefore, only the relatively robust transmit-end optics 20 and receive-end optics 24 need be placed near the hostile environment of the combustion chamber 22 .

图2表示光纤耦合的复用检测系统40的整体元件布置示意图。检测系统40通常包括:系统机架42,中分盒44,有发射端光学元件48的发射器46,有接收端光学元件的接收器52,和连接光纤。系统机架42最好是放置在远程控制室内,例如,与燃烧室54相距1公里。远程控制室通常有合适的控制环境。系统机架42包含激光器56,检测器58,波长复用器60和波长去复用器62。系统机架42还安装系统电子元件和控制软件(图2中未画出)。任选地,系统机架42包含对准光源64。FIG. 2 shows a schematic diagram of the overall component arrangement of the fiber-coupled multiplexing detection system 40 . The detection system 40 generally includes: a system rack 42, an intermediate box 44, a transmitter 46 with a transmitter optics 48, a receiver 52 with a receiver optics, and connecting optical fibers. The system rack 42 is preferably located in a remote control room, eg, 1 km from the combustion chamber 54 . A remote control room usually has a suitable control environment. System rack 42 contains laser 56 , detector 58 , wavelength multiplexer 60 and wavelength demultiplexer 62 . System rack 42 also houses system electronics and control software (not shown in Figure 2). Optionally, the system chassis 42 contains an alignment light source 64 .

连接系统机架42与中分盒44的光纤通常是标准的单模电信光纤。这种类型的光纤是不昂贵,容易购买,和低损耗的光纤,并允许激光被引导到用于操作光的现成电信元件,例如,光开关,分束器,和波分复用器。若没有光纤耦合,则激光必须被直接引导通过自由空间直到燃烧室54,这是很难实现的,或者,灵敏的电子和光学元件必须非常接近燃烧室54。The optical fiber connecting the system rack 42 to the distribution box 44 is typically a standard single-mode telecommunications optical fiber. This type of fiber is an inexpensive, readily available, and low-loss fiber, and allows laser light to be directed to off-the-shelf telecommunications components for manipulating light, such as optical switches, beam splitters, and wavelength-division multiplexers. Without fiber coupling, the laser light must be directed directly through free space up to the combustion chamber 54, which is difficult to achieve, or sensitive electronic and optical components must be very close to the combustion chamber 54.

图2中还画出中分盒(breakout box)44。中分盒44是放置在锅炉附近的坚实密封装置。中分盒44包含光开关,分束器和耦合器(总体标号为66),如以下所讨论的,它可用于引导光信号到多个发射器-接收器头对。Also shown in Figure 2 is a breakout box 44. The split box 44 is a solid seal placed near the boiler. Splitter box 44 contains optical switches, beam splitters, and couplers (generally designated 66), which may be used to direct optical signals to multiple transmitter-receiver head pairs, as discussed below.

图2所示的第三组系统元件是发射器头46和接收器头50。发射器头46和接收器头50中的光学和电子元件必须把光纤68中的光转变成准直光束,精确地引导该准直光束通过燃烧室54,在燃烧室54的远端捕获该光束,并耦合该光束进入光纤70。完成这些工作的光学元件是由传输距离,燃烧区的湍流,它对传输光束质量的影响,和光纤70的纤芯尺寸确定。纤芯尺寸的选取是根据应用所确定的设计标准。较大的纤芯可以捕获较多的激光,但同时也捕获更多的背景光。在用于燃煤锅炉时,50微米的纤芯直径可以得到可接受的结果。接收(接收器)端上的光纤耦合有几个优点。具体地说,仅仅与激光相同位置并沿相同方向传播的光被聚焦进入光纤70。这可以大大降低被检测的背景光量。光可以被捕获进入几个接收器光纤中的一条光纤,而光开关或其他的光路由装置可以选取路由到检测器58中一条光纤的光。图2中仅画出一个接收端光学元件。A third group of system elements shown in FIG. 2 is transmitter head 46 and receiver head 50 . The optics and electronics in the transmitter head 46 and receiver head 50 must convert the light in the fiber optic 68 into a collimated beam that is precisely directed through the combustion chamber 54 where it is captured at the far end of the combustion chamber 54 , and couple the beam into the fiber 70. The optics to do this are determined by the transmission distance, the turbulence in the burn zone, its effect on the quality of the transmitted beam, and the fiber 70 core size. The core size is selected based on design criteria determined by the application. A larger core traps more laser light, but also traps more background light. A core diameter of 50 microns gives acceptable results when used in coal fired boilers. Fiber-optic coupling at the receiving (receiver) end has several advantages. Specifically, only light traveling in the same position and in the same direction as the laser light is focused into the optical fiber 70 . This can greatly reduce the amount of background light being detected. Light can be captured into one of several receiver fibers, while an optical switch or other light routing device can select the light routed to one of the detector fibers. Only one receiver optical element is shown in FIG. 2 .

利用接收端的光纤耦合要求精确保持发射器和接收器光学元件的对准容差(在发射器和接收器的方向上小于0.5毫弧度)。最好是,发射端光学元件48和接收端光学元件52是按照从660nm至1650nm的波长专门设计和校正象差的,因此,可以同时高效率发射和接收多个激光信号。Utilizing fiber optic coupling at the receive end requires precise maintenance of alignment tolerances of the transmitter and receiver optics (less than 0.5 mrad in the direction of the transmitter and receiver). Preferably, the optical element 48 at the transmitting end and the optical element 52 at the receiving end are specially designed and corrected for aberrations according to the wavelength from 660nm to 1650nm, so multiple laser signals can be transmitted and received with high efficiency at the same time.

C.可调谐二极管激光吸收光谱术C. Tunable Diode Laser Absorption Spectroscopy

利用激光光谱术领域中专业人员熟知的技术,可以完成可调谐二极管激光吸收光谱术(TDLAS)。一般地说,TDLAS是让激光传输通过目标环境,在此之后,通过检测特定波长下激光的吸收完成的,例如,一氧化碳或氧气的目标气体的吸收。频谱分析被检测的激光可以识别沿激光路径的气体类型和数量。在Teichert,Fernholz,and Ebert:“Simultaneous in situ Measurement of CO,H2O,and GasTemperature in a Full-Sized,Coal-Fired,Power Plant byNear-Infrared Diode Laser”(Applied Optics,42(12):2043,20April2003)中讨论直接光谱术的细节,全文合并在此供参考。激光吸收光谱术的非接触性质非常适合于恶劣的环境,例如,燃煤火力发电厂的燃烧区,或可燃性或有毒环境,其中不能利用其他的探测方法。使用激光可以提供高的亮度,这是在严重衰减情况下(通常是光的损失大于99.9%)接收可检测传输所必需的,在这样一些环境下可以看到这种衰减。为了更好地承受目标应用的恶劣条件,可以使激光通过铠装光纤进入目标环境。Tunable diode laser absorption spectroscopy (TDLAS) can be accomplished using techniques well known to those skilled in the art of laser spectroscopy. In general, TDLAS is accomplished by transmitting laser light through the target environment, after which it detects the absorption of the laser light at specific wavelengths, for example, the absorption of target gases such as carbon monoxide or oxygen. Spectral analysis of the detected laser light can identify the type and amount of gas along the path of the laser light. In Teichert, Fernholz, and Ebert: "Simultaneous in situ Measurement of CO, H 2 O, and GasTemperature in a Full-Sized, Coal-Fired, Power Plant by Near-Infrared Diode Laser" (Applied Optics, 42(12): 2043 Details of direct spectroscopy are discussed in , 20 April 2003), which is hereby incorporated by reference in its entirety. The non-contact nature of laser absorption spectroscopy is well suited for harsh environments, such as the combustion zone of coal-fired thermal power plants, or flammable or toxic environments, where other detection methods cannot be utilized. The use of lasers can provide high brightness, which is necessary to receive detectable transmissions under severe attenuation (typically greater than 99.9% loss of light), which can be seen in some environments. To better withstand the harsh conditions of the target application, laser light can be directed into the target environment through armored optical fibers.

有效检测温度或多个燃烧过程成分气体要求TDLAS具有多个宽间隔频率激光的性能。选取的频率必须匹配与被监测跃迁的吸收谱线。例如,可以在670nm波长下监测NO2以模拟发射的NO浓度。还可以在燃煤锅炉中监测氧气,水蒸汽(温度),和一氧化碳。基于这样的假设,通过燃烧室的激光探测路径长度等于10米和每个气体品种的克分子分数是CO(1%),O2(4%),CO2(10%),和H2O(10%),可以选取合适的吸收谱线,以及合适的激光频率。在选取频率时,可以假设过程温度是1800K,该温度略微高于通常在燃煤发电厂中观察到的温度,但是该缓冲(cushion)在计算中作为安全因子。Efficient detection of temperature or multiple combustion process constituent gases requires TDLAS with the capability of multiple widely spaced frequency lasers. The selected frequency must match the absorption line of the transition being monitored. For example, NO can be monitored at a wavelength of 670 nm to simulate the emitted NO concentration. Oxygen, water vapor (temperature), and carbon monoxide can also be monitored in coal-fired boilers. Based on the assumption that the laser detection path length through the combustion chamber is equal to 10 m and the mole fractions of each gas species are CO (1%), O 2 (4%), CO 2 (10%), and H 2 O (10%), you can choose a suitable absorption line, and a suitable laser frequency. In choosing the frequency, it can be assumed that the process temperature is 1800K, which is slightly higher than typically observed in coal-fired power plants, but this cushion is used in the calculations as a safety factor.

例如,可以选取用于TDLAS的三条水吸收谱线满足以下准则:For example, three water absorption lines for TDLAS can be chosen to meet the following criteria:

1.低态能量分别是~1000,2000,和3000cm-11. Low state energies are ~1000, 2000, and 3000cm -1 respectively;

2.提供的吸收系数是在0.1-0.4之间,它可以导致约20%的光束共振吸收;2. The provided absorption coefficient is between 0.1-0.4, which can lead to about 20% of beam resonance absorption;

3.最佳的情况是利用在1250nm至1650nm范围内的跃迁,在此范围内可以得到廉价,高功率,DFB二极管电信激光器;3. The best case is to use the transition in the range of 1250nm to 1650nm, where cheap, high power, DFB diode telecom lasers are available;

4.必须充分地分开各个跃迁以便于实现复用操作;和4. The individual transitions must be separated sufficiently to enable multiplexed operations; and

5.选取的波长必须能被现有的复用/去复用光栅有效地衍射。5. The selected wavelength must be efficiently diffracted by the existing multiplexing/demultiplexing grating.

合适的水谱线发生在以下的波长:Suitable water lines occur at the following wavelengths:

表1Table 1

  波长(nm) 波数(cm-1) 低态能量(cm-1)   光栅级次 在1800K和10M下的吸收        UNP光栅效率(模型)  1349.0849 7412.432 1806.67 6.87 19.7% 81% 1376.4507 7265.062 3381.662 6.73 28.1% 77% 1394.5305 7170.872 1045.058 6.65 6.8% 72% wavelength(nm) Wavenumber(cm -1 ) Low state energy (cm -1 ) Grating order Absorption at 1800K and 10M UNP grating efficiency (model) 1349.0849 7412.432 1806.67 6.87 19.7% 81% 1376.4507 7265.062 3381.662 6.73 28.1% 77% 1394.5305 7170.872 1045.058 6.65 6.8% 72%

可以预期没有来自任何其他燃烧气体的干涉。假设最可能干涉的品种是CO2,它在1.3微米-1.4微米区没有强烈的干涉谱线。No interference from any other combustion gases can be expected. Assuming that the species most likely to interfere is CO 2 , it has no strong interference lines in the 1.3 micron-1.4 micron region.

类似地,基于以上参照的Ebert工作,可以选取合适的一氧化碳谱线。利用燃煤锅炉中的R(24)谱线,可以在1559.562nm找到合适的一氧化碳谱线。选取这个谱线可以避免来自水和一氧化碳的干涉。已知的光栅在这个波长区是十分有效的,因为它是在光通信的C频带。预期CO在这个波长下的吸收系数是0.7%。Similarly, an appropriate carbon monoxide line can be selected based on the Ebert work referenced above. Using the R(24) spectral line in a coal-fired boiler, a suitable carbon monoxide spectral line can be found at 1559.562nm. This line was chosen to avoid interference from water and carbon monoxide. Known gratings are very effective in this wavelength region, since it is in the C-band of optical communication. The absorption coefficient of CO at this wavelength is expected to be 0.7%.

此外,可以在760.0932nm下测量氧气。在这个区中计算的优选复用/去复用光栅效率是40%,然而,在合理的测量效率下应当有合适的激光功率。Additionally, oxygen can be measured at 760.0932nm. The preferred mux/demux grating efficiency calculated in this region is 40%, however, at a reasonable measured efficiency there should be a suitable laser power.

如此处所讨论的,在TDLAS检测系统的发射端和接收端使用光纤耦合要求精确地对准发射端和接收端的光学系统。一个可能的对准波长是660nm,因为在这个频率下有高功率(45mW)二极管,而660nm是在第14级光栅工作的峰值附近。可以确定其他的对准波长是同样合适或更合适的。As discussed here, the use of fiber optic coupling at the transmit and receive ends of a TDLAS inspection system requires precise alignment of the transmit and receive optics. A possible alignment wavelength is 660nm, since there are high power (45mW) diodes at this frequency, and 660nm is near the peak of the 14th order grating operation. It may be determined that other alignment wavelengths are equally or more suitable.

总之,表2表示按照本发明实施例用于复用选取的合理波长集合作为TDLAS的探测光束。应当注意,这个波长集合是TDLAS检测设备的一个实施例,它适合于检测和控制燃煤火力发电厂。其他的波长集合也是同样合适的。In summary, Table 2 shows a set of reasonable wavelengths selected for multiplexing as probe beams for TDLAS according to an embodiment of the present invention. It should be noted that this set of wavelengths is an embodiment of TDLAS detection equipment, which is suitable for detection and control of coal-fired thermal power plants. Other sets of wavelengths are equally suitable.

表2Table 2

  目的 波长(nm) 对准 660 O2b-a频带 760.0932 H2O(中温度谱线) 1349.0849 H2O(高温度谱线) 1376.4507 H2O(低温度谱线) 1394.5305 R(2,0)谐波的CO R(24) 1559.562 Purpose wavelength(nm) alignment 660 O 2 ba band 760.0932 H 2 O (medium temperature spectrum) 1349.0849 H 2 O (high temperature line) 1376.4507 H 2 O (low temperature line) 1394.5305 CO R(24) of harmonics of R(2,0) 1559.562

D.TDLAS利用复用光束的具体优点D. TDLAS utilizes specific advantages of multiplexed beams

TDLAS利用波长复用探测光束的具体优点是可以提高温度测量的准确度。为了利用TDLAS准确测量浓度,必须知道被监测气体的温度。分子吸收的强度是温度的函数。因此,为了把吸收特征的幅度转换成浓度,必须知道该温度。测量燃烧品种浓度的某些以前尝试,例如,测量CO,遇到不能足够准确地测量温度的困难,从而导致定量测量的误差。这对于二极管激光基氨滑动(slip)监测器是特别正确的,这种监测器传统上完全不能测量温度。在本发明的检测系统中,通过测量两条或多条分子水谱线强度之比率,可以确定温度。两条谱线的集成强度之比率仅仅是温度的函数(假设恒定的总系统压力)。因此,在原则上,两条谱线提供准确的温度。然而,在非均匀温度分布的情况下(通常是在工业燃烧过程中的情况),两条谱线不足以确定温度分布。在这种非均匀温度分布的情况下,两条谱线仅能确定“光程平均”的温度。与此对比,测量多于两条(相同品种)谱线的集成幅度可以探测温度的非均匀性。这种技术的例子是Sanders,Wang,Jeffries and Hanson利用氧气作为探测分子说明的(AppliedOptics,40(24):4404,20August2001),全文合并在此供参考。优选的技术依靠这样的事实,沿视线测量的峰值强度分布不同于在平均温度500K下的光程上分布,例如,它的一半光程上是300K,和在另一半光程上是700K。A specific advantage of TDLAS using wavelength multiplexed probe beams is that it can improve the accuracy of temperature measurements. In order to accurately measure concentrations using TDLAS, the temperature of the gas being monitored must be known. The strength of molecular absorption is a function of temperature. Therefore, in order to convert the magnitude of the absorption feature to concentration, the temperature must be known. Some previous attempts to measure the concentration of combustion species, eg, measuring CO, have had difficulty measuring temperature with sufficient accuracy, leading to errors in quantitative measurements. This is especially true for diode laser based ammonia slip monitors, which traditionally cannot measure temperature at all. In the detection system of the present invention, temperature can be determined by measuring the ratio of the intensities of two or more molecular water lines. The ratio of the integrated intensities of the two lines is a function of temperature only (assuming a constant total system pressure). Therefore, in principle, two spectral lines provide accurate temperature. However, in the case of a non-uniform temperature distribution, as is usually the case in industrial combustion processes, two spectral lines are not sufficient to determine the temperature distribution. In the case of such a non-uniform temperature distribution, the two spectral lines can only determine the "path-averaged" temperature. In contrast, measuring the integrated magnitude of more than two (of the same species) spectral lines can detect temperature non-uniformities. An example of this technique is described by Sanders, Wang, Jeffries and Hanson using oxygen as a probe molecule (Applied Optics, 40(24):4404, 20 August 2001 ), which is hereby incorporated by reference in its entirety. The preferred technique relies on the fact that the peak intensity distribution measured along the line of sight differs from the distribution over the optical path at an average temperature of 500K, for example 300K over half the optical path and 700K over the other half.

除了具有更准确的温度测量的优点以外,使用复用探测光束可以同时监测多个燃烧气体的品种,从而可以更精确地控制燃烧过程。In addition to the advantage of more accurate temperature measurements, the use of multiplexed probe beams enables simultaneous monitoring of multiple combustion gas species, allowing for more precise control of the combustion process.

E.模式噪声E. Pattern noise

TDLAS系统的光学系统和要求复用宽间距波长信号的类似装置遭遇许多设计上的难题,这是由于存在减小模式噪声和高效率光收集的相反设计要求。此处,模式噪声的定义为被检测信号的信号强度变化,它是由于光纤纤芯中非均匀的时间和波长改变光分布的结果,该光纤用于收集和传输来往于被测量过程室中的光。Optical systems for TDLAS systems and similar devices requiring multiplexing of widely spaced wavelength signals suffer from many design challenges due to the opposing design requirements of reduced pattern noise and high efficiency light collection. Here, modal noise is defined as the signal intensity variation of the detected signal, which is the result of non-uniform time and wavelength-altered light distribution in the core of the fiber used to collect and transmit the light to and from the process chamber being measured. Light.

在多模光纤中,不同的模式因折射率变化而有不同的速度传播。光纤中的强度分布是散斑图形,它是所有传播模式干涉的结果,这些传播模式经历了不同的有效光程长。若我们收集和检测散斑图形中的所有光,则相长干涉和相消干涉准确地互相抵消,因此,总的传输功率是与波长或光纤的长度无关。若引入削波,渐晕或其他的损失,则不能实现准确的抵消,因此,被检测的功率是随波长和/或时间而变化。在上述的TDLAS检测系统中,模式噪声导致的功率变化是有问题的。某些光谱术依靠被研究气体品种对特定光波长的吸收。检测吸收是利用在临界波长上功率的减小。因此,模式噪声可以模仿与吸收相关的功率下降,从而混淆通过TDLAS收集的数据。被检测功率在传输一段光纤长度z之后的普遍公式是:In multimode fibers, different modes propagate at different speeds due to changes in the refractive index. The intensity distribution in an optical fiber is a speckle pattern that is the result of the interference of all propagating modes that experience different effective optical path lengths. If we collect and detect all the light in the speckle pattern, the constructive and destructive interference exactly cancel each other out, so the total transmitted power is independent of the wavelength or the length of the fiber. Accurate cancellation cannot be achieved if clipping, vignetting or other losses are introduced, so the detected power is wavelength and/or time dependent. In the TDLAS detection system described above, power variation due to pattern noise is problematic. Some spectroscopy relies on the absorption of specific wavelengths of light by the species of gas being studied. Detection of absorption utilizes a reduction in power at a critical wavelength. Pattern noise can thus mimic absorption-related power drops, confounding data collected via TDLAS. The general formula for the detected power after transmitting a length z of fiber is:

P=P0+∑ijcijEiEjcos[(2πv0Δnijz/c+ΔΦij(T,σ))]           (1)P=P 0 +∑ ij c ij E i E j cos[(2πv 0 Δn ij z/c+ΔΦ ij (T,σ))] (1)

其中P0=与波长无关的平均功率where P 0 = average power independent of wavelength

Ei=第n个横模的光幅度E i = light amplitude of the nth transverse mode

Cij=第i个与j第个横模之间的重叠积分C ij = overlap integral between the i-th and j-th transverse modes

Δnij=第i个与j第个横模之间的折射率差Δn ij = difference in refractive index between the i-th and j-th transverse modes

ΔΦij=第i个与j第个横模之间因温度和应力产生的相移ΔΦ ij = phase shift between the i-th and j-th transverse modes due to temperature and stress

在正交模式集合和没有损失的情况下,Cij=0。然而,若存在光束削波或渐晕或其他模式有关的损失,则它使一些Cij≠0。这可以导致平均发射功率中出现波纹。In the case of orthogonal mode sets and no loss, C ij =0. However, it makes some C ij ≠0 if there is beam clipping or vignetting or other mode related losses. This can cause ripples in the average transmit power.

在50微米纤芯的典型渐变型折射率光纤中,总的折射率变化Δn约为1%,但大部分模式花费的主要传输时间是在光纤纤芯的中心附近,所以,一般地说,Δnij<0.0005。现有的光纤GIF50约支持135个模式,假定合理的可实现的光束削波水平,在波长扫描期间,它足以产生显著的模式噪声。In a typical graded-index fiber with a 50-micron core, the total index change, Δn, is about 1%, but most modes spend the majority of their transit time near the center of the fiber core, so, generally speaking, Δn ij <0.0005. Existing fiber GIF50 supports approximately 135 modes, which is sufficient to generate significant mode noise during wavelength scanning, assuming reasonably achievable levels of beam clipping.

作为具体的模式噪声例子,我们可以考虑一个具有模式噪声的最简单系统:矩形波导,它在一个方向上仅支持最低的模式,而在其正交方向上仅支持两个最低的模式:As a concrete modal noise example, we can consider the simplest system with modal noise: a rectangular waveguide that supports only the lowest mode in one direction and the two lowest modes in its orthogonal direction:

最低的模式:E1=E1 0[exp i(kz-ωt)]cosπx/2aLowest mode: E 1 =E 1 0 [exp i(kz-ωt)]cosπx/2a

次低的模式:E2=E2 0[exp i(kz-ωt)]sinπx/aSecond lowest mode: E 2 =E 2 0 [exp i(kz-ωt)] sinπx/a

沿光纤方向上z点的强度是:The intensity at point z along the fiber direction is:

I(x)=|E1+E2|2和总功率是P=∫|E1+E2|2dx    (2)I(x) = |E 1 +E 2 | 2 and the total power is P=∫|E 1 +E 2 | 2 dx (2)

其中该积分必须包含削波效应和渐晕效应。Where the integral must include clipping and vignetting effects.

在没有削波的情况下,P~E1 2+E2 2,因此,它与波长无关。添加削波相当于改变积分的上下限。可以证明,削波之后得到一个附加项~E1E2cosΔΦ,其中ΔΦ=ΔKL=2πΔnL/λ。In the absence of clipping, P ~ E 1 2 +E 2 2 , therefore, it is independent of wavelength. Adding clipping is equivalent to changing the upper and lower bounds of the integral. It can be shown that an additional term ~E 1 E 2 cosΔΦ is obtained after clipping, where ΔΦ=ΔKL=2πΔnL/λ.

若单模光纤可用在接收端光学系统中,如上所述,则模式噪声就不成为问题。然而,多模光纤通常必须用在光纤耦合TDLAS系统的接收端光学系统中,它有两个原因。第一,在传输通过测量体积(测量路程超过10米的燃烧室)之后,初始的单模(高斯空间分布)光束的质量严重退化。因此,这个严重失真光束进入单模光纤的耦合效率是非常低。这是一个不可接受的情况,因为光束在传输通过测量体积之后衰减3-4个数量级,主要的原因是煤灰和飞尘造成的散射和昏暗。利用单模光纤导致的附加衰减能够妨碍测量的进行。第二,火球中折射光束的转向效应造成光束的位置和指向不稳定。在这些效应下,有规律地“击中”单模光纤的纤芯是很难的。If single-mode fiber is used in the receiver optics, as described above, then modal noise is not an issue. However, multimode fiber must generally be used in the receiver optics of fiber-coupled TDLAS systems for two reasons. First, the quality of the initial single-mode (Gaussian spatial distribution) beam is severely degraded after transmission through the measurement volume (combustion chamber with a measurement distance of more than 10 m). Therefore, the coupling efficiency of this severely distorted beam into the single-mode fiber is very low. This is an unacceptable situation because the beam is attenuated by 3-4 orders of magnitude after traveling through the measurement volume, mainly due to scattering and obscuration by soot and flying dust. The additional attenuation caused by the use of single-mode fiber can hinder the measurement. Second, the steering effect of the refracted beam in the fireball causes the position and pointing of the beam to be unstable. Under these effects, it is difficult to regularly "hit" the core of a single-mode fiber.

另一方面,多模光纤的纤芯至少是单模光纤目标横截面积的25倍。因此,可以大大减小光束转向的效应。此外,由于进入多模光纤的耦合效率是与光的空间模式无关,在传输通过火球之后得到的低光束质量就不是问题。On the other hand, the core of multimode fiber is at least 25 times the target cross-sectional area of singlemode fiber. Thus, the effects of beam steering can be greatly reduced. Furthermore, since the coupling efficiency into the multimode fiber is independent of the spatial mode of the light, the resulting low beam quality after transmission through the fireball is not an issue.

在计算,电信,或一般科学技术中的其他类型装置可能有其他的类似或完全无关的限制,它要求或有利于使用很长的多模光纤。在其他的装置中,模式噪声也可能是有问题的,它提出很大的数据收集或数据传输的难题。Other types of installations in computing, telecommunications, or general science and technology may have other similar or entirely unrelated constraints that require or facilitate the use of very long multimode fibers. In other installations, pattern noise can also be problematic, presenting significant data collection or data transmission challenges.

因此,发生在多模光纤系统中的模式有关损失是很大的设计难题。从多模光纤的纤芯中射出的光分布具有随机的散斑图形,即,由不同光纤模式之间相长干涉和相消干涉造成的明亮区和黑暗区的随机图形。若散斑图形作为时间和波长的函数是完全不变的,则它就不是问题。然而,若光束在多模接收端光学系统的任何地方被削波,则散斑图形作为波长的函数发生缓慢的变化可以产生模式噪声。这种削波是不可能避免的;仅仅可以减小削波。所以,必须采取减小模式噪声的其他措施以提高系统的检测灵敏度。Therefore, the mode-related losses that occur in multimode fiber systems are a major design challenge. The light distribution emerging from the core of a multimode fiber has a random speckle pattern, ie, a random pattern of bright and dark regions caused by constructive and destructive interference between different fiber modes. It is not a problem if the speckle pattern is completely invariant as a function of time and wavelength. However, if the beam is clipped anywhere in the multimode receiver optics, the slow variation of the speckle pattern as a function of wavelength can generate mode noise. This clipping cannot be avoided; it can only be reduced. Therefore, other measures to reduce pattern noise must be taken to improve the detection sensitivity of the system.

可以有几种减轻模式噪声的方法。根据以上的公式(2),可以通过以下的方法减小模式噪声:There can be several ways to mitigate pattern noise. According to the above formula (2), the mode noise can be reduced by the following methods:

1.减小模式有关的损失,即,减小削波以保持Cij很小;1. Reduce mode-dependent losses, i.e. reduce clipping to keep C ij small;

2.减小z,从而增大模式噪声的周期,使它远远大于有关的吸收谱线;2. Reduce z, thereby increasing the period of the mode noise, making it much larger than the relevant absorption line;

3.利用低色散光纤以减小Δnij3. Use low dispersion fiber to reduce Δn ij ;

4.扰乱或相移模式;但不是所有的模式扰乱或相移技术是同样有效的,如以下所描述的。4. Scrambling or phase-shifting patterns; but not all pattern-scrambling or phase-shifting techniques are equally effective, as described below.

最好是,光纤耦合TDLAS检测系统的接收端光学系统设计和制作成包含所有以上的方法以减小模式噪声。该光学系统设计成这样,给出几乎完美的系统对准,任何光束削波应当发生在低水平上。应当努力保持多模光纤有最小的长度;然而,在某些应用中,z必须足够长,为的是在环境控制的区域中有控制电路。利用最佳的低色散多模光纤,可以减小Δnij的数值。此外,通过周期性改变接收端多模光纤的折射率或机械操作,并从收集的平均光信号中提取数据,可以平均各个模式以得到最佳结果。Preferably, the receiver optics of the fiber-coupled TDLAS detection system are designed and fabricated to incorporate all of the above methods to reduce modal noise. The optical system is designed such that, given almost perfect system alignment, any beam clipping should occur at a low level. Efforts should be made to keep multimode fibers to a minimum length; however, in some applications z must be long enough to have control circuits in environmentally controlled areas. The value of Δn ij can be reduced by using the best low dispersion multimode fiber. Furthermore, by periodically varying the refractive index or mechanical manipulation of the multimode fiber at the receiving end and extracting data from the averaged optical signal collected, the individual modes can be averaged for optimal results.

多模光纤中的散斑图形是作为时间和波长的函数而变化,而且也作为该光纤机械位置的函数。传输时间和波长是受光纤折射率的影响。按照特定方式弯曲和操作光纤可以使散斑图形发生变化。若这些机械操作或折射率的周期性变化是在一个时间段内连续完成的,则从光纤中射出的光空间分布可以平均成相对均匀的图形。The speckle pattern in multimode fiber varies as a function of time and wavelength, but also as a function of the mechanical position of the fiber. Transit time and wavelength are affected by the refractive index of the fiber. Bending and manipulating the fiber in certain ways can cause changes in the speckle pattern. If these mechanical operations or periodic changes in the refractive index are completed continuously within a period of time, the spatial distribution of light emitted from the optical fiber can be averaged into a relatively uniform pattern.

通过有效的周期性相移或扰乱模式噪声,时间平均的测量结果产生均匀的信号强度。通过拉伸或扭曲光纤或改变光纤的温度,可以改变光纤的折射率。改变光纤的温度使第i个横模与第j个横模之间的折射率差Δnij发生变化。这种光纤折射率的变化可以按照公式(2)给出的函数cos(2πv0Δnijz)/c相移模式噪声。Time-averaged measurements yield uniform signal strengths through effective periodic phase shifting or scrambling pattern noise. The refractive index of a fiber can be changed by stretching or twisting the fiber or changing the temperature of the fiber. Changing the temperature of the fiber changes the refractive index difference Δn ij between the i-th transverse mode and the j-th transverse mode. This change in fiber refractive index can phase-shift the mode noise according to the function cos(2πv 0 Δn ij z)/c given by equation (2).

F.光模式噪声平均F. Optical Pattern Noise Averaging

如图3所示,利用光学装置300可以完成周期性相移或扰乱模式噪声以产生时间平均的测量结果。光学装置300可以包含有输入端304和输出端306的多模光纤302。光可以耦合到多模光纤302的输入端304,并大致沿图3所示的箭头方向传播通过该系统,该箭头联系输入端304和输出端306。As shown in FIG. 3, periodic phase shifting or scrambling pattern noise can be accomplished using optical arrangement 300 to produce time-averaged measurements. Optical device 300 may include a multimode optical fiber 302 having an input end 304 and an output end 306 . Light can be coupled to input end 304 of multimode fiber 302 and propagate through the system generally in the direction of the arrow shown in FIG. 3 , which connects input end 304 and output end 306 .

光学装置300还包含与多模光纤302相关的平均元件308。平均元件308可以包含这样一个设备,它在一个选取的时间段内周期性改变多模光纤302折射率。或者,平均元件308可以包含用于扰乱多模光纤302内光分布的一个设备。借助于平均元件308,通过周期性改变多模光纤302的温度,周期性操作多模光纤302,或二者,可以改变折射率或扰乱光分布。The optical device 300 also includes an averaging element 308 associated with the multimode fiber 302 . Averaging element 308 may comprise a device that periodically varies the index of refraction of multimode fiber 302 over a selected period of time. Alternatively, averaging element 308 may comprise a device for perturbing the distribution of light within multimode fiber 302 . By means of the averaging element 308, by periodically changing the temperature of the multimode fiber 302, by periodically operating the multimode fiber 302, or both, the refractive index can be changed or the light distribution disturbed.

在平均元件308完成周期性操作多模光纤302的实施例中,平均元件308可以扭曲,拉伸或震动多模光纤302。在平均元件308周期性改变多模光纤302温度的实施例中,可以提供与多模光纤热交换的各种热元件。影响多模光纤302温度的任何设备可以包含在平均元件308中。可用于影响多模光纤302温度的代表性装置包括:热电模块,电阻加热器,化学加热器,利用压缩流体和热交换器的普通冷却装置,化学冷却器,冷却到环境温度以下的流体源,和加热到环境温度以上的流体源。以下详细讨论这些装置中的一些装置。In embodiments where the averaging element 308 performs periodic operation of the multimode fiber 302 , the averaging element 308 may twist, stretch or vibrate the multimode fiber 302 . In embodiments where the averaging element 308 periodically varies the temperature of the multimode fiber 302, various thermal elements may be provided that are in thermal communication with the multimode fiber. Any device that affects the temperature of multimode fiber 302 may be included in averaging element 308 . Representative devices that can be used to affect the temperature of the multimode fiber 302 include: thermoelectric modules, resistive heaters, chemical heaters, conventional cooling devices utilizing compressed fluid and heat exchangers, chemical coolers, fluid sources cooled to below ambient temperature, and fluid sources heated above ambient temperature. Some of these devices are discussed in detail below.

在平均元件308造成多模光纤302周期性加热或冷却的实施例中,传感器310也可以放置成与多模光纤302热交换。传感器310可以提供信息给控制器312,而控制器312可以通过控制线314再控制平均元件308。In embodiments where the averaging element 308 causes the multimode fiber 302 to periodically heat or cool, the sensor 310 may also be placed in thermal communication with the multimode fiber 302 . Sensor 310 can provide information to controller 312 , and controller 312 can in turn control averaging element 308 via control line 314 .

G.温度基相移设备G. Temperature-Based Phase Shift Devices

温度基模式相移的有效性是与每单位时间的温度变化和暴露给温度变化的光纤长度z直接有关。温度基模式相移是一种处理模式噪声特别有效的方法,因为光纤温度的变化就改变所有横模的折射率,而温度变化可以发生在一段相当长的光纤上。因此,通过改变光纤的折射率,我们可以确保所有的横模发生相移,没有模式可以与信号保持“冻结”。The effectiveness of the temperature-based mode phase shift is directly related to the temperature change per unit time and the fiber length z exposed to the temperature change. Temperature-based mode phase shifting is a particularly effective way to deal with modal noise because a change in fiber temperature changes the refractive indices of all transverse modes, and temperature changes can occur over a considerable length of fiber. Therefore, by changing the refractive index of the fiber, we can ensure that all transverse modes are phase shifted and no mode can remain "frozen" with the signal.

实际上,任何类型的加热/冷却系统可以放置成与多模光纤302热交换,从而使光纤的温度发生周期性变化。电阻加热器,普通冷却装置,加热或冷却的流体,Peltier或其他的热电装置,红外线装置,或化学装置都可用于影响光纤的温度。Virtually any type of heating/cooling system can be placed in heat exchange with the multimode fiber 302 to cause periodic changes in the temperature of the fiber. Resistive heaters, conventional cooling devices, heated or cooled fluids, Peltier or other thermoelectric devices, infrared devices, or chemical devices can be used to affect the temperature of the fiber.

利用周期性温度变化的一个模式相移装置实施例是流体基模式相移装置(流体装置)400。图4表示流体装置的分解图。图4表示利用涡流空气管402A,402B交替地吹热空气和冷空气到光纤及其周围的流体装置400实施例。从压缩空气源(图4中未画出)传送的空气交替地传送到两个涡流管402A,402B中的一个涡流管。涡流管402A,402B耦合成与容器404的内部进行流体交换。如图4所示,容器404可以是由机壳406构成,机壳406有侧板408A,408B,顶板410,前入口412,和后入口414。整个机壳406可以适合于安装在典型的数据处理设备机架上。虽然可安装机架的机壳406是特别方便的,但是可以使用适合于放置卷盘416的任何机壳形状,类型或型式以形成流体装置400,其中卷盘416上缠绕一段多模光纤418。或者,可以使用没有机壳406的装置。One embodiment of a mode-shifting device that utilizes periodic temperature changes is a fluid-based mode-shifting device (fluidic device) 400 . Figure 4 shows an exploded view of the fluidic device. Figure 4 shows an embodiment of a fluidic device 400 utilizing vortex air tubes 402A, 402B to alternately blow hot and cold air to and around the optical fiber. Air delivered from a compressed air source (not shown in Figure 4) is delivered alternately to one of the two vortex tubes 402A, 402B. Vortex tubes 402A, 402B are coupled in fluid communication with the interior of vessel 404 . As shown in FIG. 4 , the container 404 may be formed from an enclosure 406 having side panels 408A, 408B, a top panel 410 , a front inlet 412 , and a rear inlet 414 . The entire enclosure 406 may be suitable for mounting in a typical data processing equipment rack. While a rack mountable housing 406 is particularly convenient, any housing shape, type or pattern suitable for housing a reel 416 on which a length of multimode optical fiber 418 is wound may be used to form fluidic device 400 . Alternatively, a device without housing 406 may be used.

涡流管402A,402B通过后入口414与机壳的内部进行流体交换,因此,它与卷盘416上缠绕的多模光纤418进行流体和热交换。所以,利用涡流管402A,402B使加热的空气到环境温度以上或冷却的空气到环境温度以下,可以周期性加热和/或冷却多模光纤418。The vortex tubes 402A, 402B are in fluid communication with the interior of the housing through the rear inlet 414 , and thus, are in fluid and heat communication with the multimode optical fiber 418 wound on the reel 416 . Thus, the multimode fiber 418 may be periodically heated and/or cooled by using the vortex tubes 402A, 402B to bring heated air above ambient temperature or cooled air below ambient temperature.

可以容易地购买合适的涡流管402A,402B。例如,可以从

Figure S05810448020061011D00016181419QIETU
Corporation购买
Figure S05810448020061011D00016181430QIETU
3230涡流管。这些或类似的涡流管工作在30ft3/minute的生产率下,它提供加热到+60°或冷却到-20°的空气,这与涡流管的取向有关。此外,利用涡流管可以相对容易地在加热的空气与冷却的空气之间循环。然而,重要的是注意到,周期性提供加热或冷却的流体与多模光纤418热交换的任何设备或方法适合于实现流体装置400的实施例。然而,加热和冷却的流体可以是以上讨论的空气,水,加热/冷却油,压缩气体,或可用于加热或冷却多模光纤的其他流体。Suitable vortex tubes 402A, 402B can be readily purchased. For example, from
Figure S05810448020061011D00016181419QIETU
Corporation purchase
Figure S05810448020061011D00016181430QIETU
3230 Vortex Tube. These or similar vortex tubes operate at a production rate of 30ft3 /minute, which provides air heated to +60° or cooled to -20°, depending on the orientation of the vortex tubes. Additionally, cycling between heated and cooled air is relatively easy with a vortex tube. However, it is important to note that any device or method that periodically provides a heated or cooled fluid in heat exchange with multimode optical fiber 418 is suitable for implementing the fluidic device 400 embodiment. However, the heating and cooling fluid can be air as discussed above, water, heating/cooling oil, compressed gas, or other fluids that can be used to heat or cool multimode optical fibers.

作为例子,而不是限制,在工作期间,一个涡流管402A,402B可以传送加热的空气,直至光纤到达高于入口温度约10℃的温度。光纤的温度可以由与该光纤接触而埋入的热电偶420或其他温度传感器确定。温度控制单元(图4中未画出)可以从热电偶420中接收输入并触发螺线管开关,使空气发送到用于冷却的另一个涡流管402A,402B。或者,因为由涡流管402A,402B提供给多模光纤418的加热空气绝对不会达到临界温度,可以不使用温度控制器,而是用定时中继器代替,用于周期性交换加热与冷却之间的涡流管402A,402B。在该装置工作期间,温度之间的循环最好是连续进行的。By way of example, and not limitation, during operation, one vortex tube 402A, 402B may deliver heated air until the fiber reaches a temperature about 10°C above the inlet temperature. The temperature of the fiber can be determined by a thermocouple 420 or other temperature sensor embedded in contact with the fiber. A temperature control unit (not shown in Figure 4) may receive input from the thermocouple 420 and trigger a solenoid switch, sending air to another vortex tube 402A, 402B for cooling. Alternatively, since the heated air supplied to the multimode fiber 418 by the vortex tubes 402A, 402B will never reach a critical temperature, the temperature controller may be omitted and replaced by a timed repeater for periodically exchanging between heating and cooling. Between the vortex tubes 402A, 402B. The cycling between temperatures is preferably continuous during operation of the device.

图5和图6表示一个优选实施例的模式相移装置,它是基于周期性改变多模光纤的温度。热电模式相移装置(热电装置)500包含卷盘502,用于缠绕一个选取长度的多模光纤504。一个或多个热电加热/冷却模块506放置成与多模光纤504热交换。在图5所示的实施例中,多个热电加热/冷却模块506是沿围绕卷盘502的内部径向设置。利用热电模块506的外表面与多模光纤504的线圈之间热电油脂形成热交换。在图5所示的实施例中,卷盘502的结构是有开口的边缘,它便于热电模块506与多模光纤504之间的接触,以及便于多模光纤504的缠绕。Figures 5 and 6 show a preferred embodiment of the mode phase shifting device, which is based on periodically varying the temperature of the multimode fiber. Thermoelectric mode phase shifting device (thermoelectric device) 500 includes a reel 502 for winding a selected length of multimode optical fiber 504 . One or more thermoelectric heating/cooling modules 506 are placed in thermal communication with the multimode optical fiber 504 . In the embodiment shown in FIG. 5 , a plurality of thermoelectric heating/cooling modules 506 are arranged radially around the interior of the reel 502 . Heat exchange is formed by thermoelectric grease between the outer surface of the thermoelectric module 506 and the coil of the multimode optical fiber 504 . In the embodiment shown in FIG. 5 , the reel 502 is configured with an open edge, which facilitates contact between the thermoelectric module 506 and the multimode fiber 504 and facilitates winding of the multimode fiber 504 .

图6表示热电模块506放置成与多模光纤504接触并相对于卷盘502放置的一个装置分解图。FIG. 6 shows an exploded view of the device with thermoelectric module 506 placed in contact with multimode optical fiber 504 and relative to reel 502 .

一个或多个热库508也可以设置成与热电模块506热交换。最好是,热库508是由高热导材料制成,例如,铝或铜,并有设计成增大每个热库508表面积的散热片或其他设备。风扇510的位置可以迫使或吸引空气通过热库508,从而促使从热电模块506中快速提取热量,以便快速加热或冷却多模光纤504。如图5和图6所示,可以利用有顶环514和底环516的框架512,它使热电装置500的各个元件之间保持合适的取向,而不妨碍空气流动通过热库508。最好是,在框架512中形成多个开孔以确保空气的自由流动。One or more thermal banks 508 may also be provided in heat exchange with the thermoelectric modules 506 . Preferably, thermal banks 508 are made of a high thermal conductivity material, such as aluminum or copper, with fins or other devices designed to increase the surface area of each thermal bank 508 . The location of the fan 510 can force or draw air through the thermal reservoir 508 to facilitate rapid extraction of heat from the thermoelectric module 506 for rapid heating or cooling of the multimode fiber 504 . As shown in FIGS. 5 and 6 , a frame 512 may be utilized with a top ring 514 and a bottom ring 516 that maintain proper orientation between the various elements of the thermoelectric device 500 without impeding air flow through the thermal store 508 . Preferably, a plurality of openings are formed in the frame 512 to ensure free flow of air.

图5和图6所示的实施例是利用基于Peltier原理的热电模块506。通过引线520给热电模块506提供直流电。利用工作在于Peltier原理下的热电模块506,热电模块506的两个相对表面加热或冷却,它取决于提供的直流电方向。因此,这些热电模块具有某些优点,因为通过有选择地交换提供给引线520的直流电极性,可以相当容易有选择地加热或冷却多模光纤504。然而,重要的是注意到,可以利用其他类型的装置实现加热和/或冷却多模光纤504。例如,电阻加热器,普通冷却装置,红外线加热装置,和/或化学反应基加热器和/或冷却器可用于改变多模光纤504的温度。The embodiment shown in Figures 5 and 6 utilizes a thermoelectric module 506 based on the Peltier principle. Direct current is provided to the thermoelectric module 506 through the leads 520 . With the thermoelectric module 506 operating under the Peltier principle, two opposing surfaces of the thermoelectric module 506 are heated or cooled, depending on the direction of the supplied direct current. Accordingly, these thermoelectric modules have certain advantages in that the multimode fiber 504 can be selectively heated or cooled relatively easily by selectively exchanging the polarity of the DC electricity provided to the lead wire 520 . It is important to note, however, that heating and/or cooling of multimode fiber 504 may be accomplished using other types of devices. For example, resistive heaters, conventional cooling devices, infrared heating devices, and/or chemical reaction based heaters and/or coolers may be used to vary the temperature of the multimode fiber 504 .

在这个优选实施例中,如图5和图6所示,可以从合适的功率源传送功率到安装在柱形装置上的热电模块506。电流交换电路可用于周期性反转传送给每个热电模块506的直流源极性。模式相移发生在一段多模光纤504上,最好是Premium GIF50多模光纤,它与热电模块506热交换。我们发现55m至100m是完成模式相移和平均操作的合适长度多模光纤。其他长度的多模光纤也是合适的。若使用100m的包层光纤,则约50%的光纤是与热电冷却器直接接触。应当注意,通过直接接触,除了热电油脂以外,在热电模块506与多模光纤504之间没有导电材料。这种配置可以减小该系统的热质量。通过减小系统的热质量,该系统的温度响应是快速的并产生更有效的模式相移。In this preferred embodiment, as shown in Figures 5 and 6, power may be delivered from a suitable power source to a thermoelectric module 506 mounted on a cylindrical device. A current switching circuit may be used to periodically reverse the polarity of the DC source delivered to each thermoelectric module 506 . Mode phase shifting occurs on a length of multimode fiber 504 , preferably Premium GIF50 multimode fiber, which is thermally exchanged with a thermoelectric module 506 . We have found that 55m to 100m is an appropriate length of multimode fiber for mode phase shifting and averaging. Other lengths of multimode fiber are also suitable. If 100m of cladding fiber is used, about 50% of the fiber is in direct contact with the thermoelectric cooler. It should be noted that with direct contact, there is no conductive material between thermoelectric module 506 and multimode fiber 504 other than thermoelectric grease. This configuration can reduce the thermal mass of the system. By reducing the thermal mass of the system, the temperature response of the system is fast and results in a more efficient mode phase shift.

一个或多个热电偶522或其他的温度测量装置可以安装在热电模块506与多模光纤504之间,并在所有时间监测多模光纤504的温度。温度控制单元(图5和图6中没有画出)可以接收热电偶测定的温度,并基于温度读数改变电流的方向。利用现有的热电模块,可以实现约35℃至50℃的合适范围。重要的是,光纤不能超过最高的85℃,否则可能使光纤损坏。利用从65℃至10℃温度变化的单侧冷却器和65℃至30℃温度变化的双侧冷却器完成测试操作。然而,一个完全的周期可以是任何选取的持续时间,我们发现约25秒的周期是有效的。One or more thermocouples 522 or other temperature measuring devices may be installed between the thermoelectric module 506 and the multimode fiber 504 and monitor the temperature of the multimode fiber 504 at all times. A temperature control unit (not shown in Figures 5 and 6) can receive the temperature measured by the thermocouple and change the direction of the current flow based on the temperature reading. With existing thermoelectric modules, a suitable range of about 35°C to 50°C can be achieved. It is important that the fiber does not exceed the maximum temperature of 85°C, otherwise the fiber may be damaged. The test operation was done using a single side cooler with a temperature change from 65°C to 10°C and a double side cooler with a temperature change from 65°C to 30°C. However, a full cycle can be of any chosen duration, we have found a cycle of about 25 seconds to be effective.

如上所述,借助于安装成与热电模块506热交换的热库508,热量可以耗散在热电模块506的相反面上。可以迫使空气进入或吸引通过热库的散热片,它有助于耗散与输入功率相当的热量。迫使空气通过散热片底部的开孔518,从而使空气流动通过该系统并从该单元的顶部流出,可以完成有效的热耗散。产生足够空气流的其他配置也是合适的。或者,热电装置500可以放入到冷却流体中,或利用其他的方法冷却。最好是,风扇在装置运行的同时连续地工作。可以利用任何合适的风扇或流体源耗散热量,然而,300CFM的风扇对于从图5和图6所示的系统中去除热量是有效的。As mentioned above, heat may be dissipated on the opposite side of the thermoelectric module 506 by means of the thermal store 508 mounted in heat exchange with the thermoelectric module 506 . Air can be forced into or drawn through a heat sink that helps dissipate as much heat as the input power. Effective heat dissipation can be accomplished by forcing air through the openings 518 in the bottom of the heat sink so that the air flows through the system and out the top of the unit. Other configurations that generate sufficient air flow are also suitable. Alternatively, the thermoelectric device 500 can be placed in a cooling fluid, or cooled using other methods. Preferably, the fan operates continuously while the device is in operation. The heat can be dissipated using any suitable fan or fluid source, however, a 300 CFM fan is effective for removing heat from the system shown in FIGS. 5 and 6 .

控制电路可以与热电模块506的加热和冷却相关。基于从热电偶518,温度计,或其他温度传感器的输入,反馈控制电路可以检测光纤的温度。此外,基于温度输入,控制器可以交换功率传送到热电模块506的电流方向,并调整加热和冷却循环的功率电平(加热通常是更加有效,它需要较少的功率)。此外,控制器可以控制传送到光纤光学系统的最大和最小功率,并在过热的情况下关断驱动电路。Control circuitry may be associated with heating and cooling of thermoelectric module 506 . Based on input from a thermocouple 518, thermometer, or other temperature sensor, the feedback control circuit can sense the temperature of the fiber. Additionally, based on the temperature input, the controller can swap the current direction of power delivered to the thermoelectric modules 506 and adjust the power levels of the heating and cooling cycles (heating is generally more efficient, it requires less power). In addition, the controller can control the maximum and minimum power delivered to the fiber optic system and shut down the drive circuit in case of overheating.

H.热电模块相移系统测试H. Thermoelectric module phase shift system test

利用上述的热电装置500完成测试。测试是借助于发射四个波段通过无吸收的氮气吹洗室完成的。在光程上没有吸收品种,激光在被参考信号分割之后应当展示线性波长响应。斜率线性的偏差主要是由模式噪声造成的。确定测量不准确度的普遍公式是由以下的公式给出:Testing was done using the thermoelectric device 500 described above. Testing is done by transmitting four bands through a non-absorbing nitrogen purge chamber. With no absorbing species in the optical path, the laser should exhibit a linear wavelength response after division by the reference signal. Deviations from slope linearity are mainly caused by pattern noise. A general formula for determining measurement inaccuracy is given by:

σx=[1/N∑(xi-fi(ax+b))2]1/2   (3)σ x =[1/N∑(x i -f i (ax+b)) 2 ] 1/2 (3)

其中xi=signali/tapi where x i =signal i /tap i

fi(ax+b)=x1-n的线性拟合Linear fitting of f i (ax+b)=x 1-n

由于发射端和接收端传播时间造成的时间延迟,可以忽略每个波长循环的开始和结束。这些时间延迟造成每个循环开始和结束时抽头与观察信号之间的重大变化。The start and end of each wavelength cycle can be ignored due to time delays due to propagation times at the transmitter and receiver. These time delays cause significant changes between the tapped and observed signals at the beginning and end of each cycle.

系统性能的测试是借助于热电装置500的实施例完成的,其中利用单侧和双侧热电模块506,多个平均时间,和不同的光纤长度。在所有的结果中,模式相移和平均操作产生减小的模式噪声信号偏差。噪声的减小取决于实验中所用的光纤长度,如在公式(3)中所给出的;较长光纤相对于较短光纤有更高的频率模式噪声偏差。因此,在较长光纤中可以看到模式相移的相对分辨率增强。以下给出各种配置的结果:Testing of system performance was done with an embodiment of the thermoelectric device 500 utilizing single-sided and double-sided thermoelectric modules 506, multiple averaging times, and different fiber lengths. In all results, pattern phase shifting and averaging operations yield reduced pattern noise signal bias. The reduction in noise depends on the fiber length used in the experiment, as given in equation (3); longer fibers have higher frequency mode noise deviations relative to shorter fibers. Consequently, relative resolution enhancement of mode phase shifts is seen in longer fibers. The results for various configurations are given below:

表3table 3

Figure S05810448020061011D000191
Figure S05810448020061011D000191

没有模式扰乱,关断TEMNo mode perturbation, turn off TEM

  3 1684 2394 3527 2647 2535 10 612 966 3013 0 1530 10 1229 1592 3084 0 1968 10 1434 1581 1823 0 1613 3 1684 2394 3527 2647 2535 10 612 966 3013 0 1530 10 1229 1592 3084 0 1968 10 1434 1581 1823 0 1613

单侧TEM,100m可工作光纤长度,270m光纤总长度,       191210℃-65℃温度范围Single-sided TEM, 100m working fiber length, 270m total fiber length, 191210℃-65℃ temperature range

                                                  平均 average

  10 3048 3896 2020 1871 2709 10 4213 2680 1856 3216 2991 10 3317 1742 2257 2838 2538 在转换点 1 4957 1628 1736 2939 2815 冷到热 1 2712 2490 1208 2345 2189 冷到热 1 3119 3559 4965 1921 3391 冷到热 1 2762 3163 3519 1541 2746 冷到热 1 2468 3388 1928 2887 2668 冷到热 1 3724 2479 2394 3005 2901 冷到热 1 2865 2363 2700 1917 2461 冷到热 1 5187 1924 2327 3633 3268 冷到热 1 3327 3392 1447 1777 2486 冷到热 1 4989 1556 2819 3090 3113 冷到热 1 2812 1985 1542 1642 1995 10 3048 3896 2020 1871 2709 10 4213 2680 1856 3216 2991 10 3317 1742 2257 2838 2538 at the transition point 1 4957 1628 1736 2939 2815 cold to hot 1 2712 2490 1208 2345 2189 cold to hot 1 3119 3559 4965 1921 3391 cold to hot 1 2762 3163 3519 1541 2746 cold to hot 1 2468 3388 1928 2887 2668 cold to hot 1 3724 2479 2394 3005 2901 cold to hot 1 2865 2363 2700 1917 2461 cold to hot 1 5187 1924 2327 3633 3268 cold to hot 1 3327 3392 1447 1777 2486 cold to hot 1 4989 1556 2819 3090 3113 cold to hot 1 2812 1985 1542 1642 1995

75m可工作多模光纤,245m光纤总长度,单侧TEM,          253165℃-10℃温度范围75m workable multimode fiber, 245m total fiber length, single-sided TEM, 253165°C-10°C temperature range

                                                    平均 average

  循环 10 3975 3465 2375 3014 3207 循环 10 2997 963 1408 2085 1863 冷到热 1 3111 1841 1538 2982 2368 冷到热 1 2268 1518 2365 2932 2271 cycle 10 3975 3465 2375 3014 3207 cycle 10 2997 963 1408 2085 1863 cold to hot 1 3111 1841 1538 2982 2368 cold to hot 1 2268 1518 2365 2932 2271

55m可工作多模光纤,225m光纤总长度,双侧TEM,          216765℃-30℃温度范围55m workable multimode fiber, 225m total fiber length, double-sided TEM, 216765°C-30°C temperature range

                                                     平均 average

机械操作基设备Mechanical operation base equipment

如以上所讨论的,通过周期性改变折射率或机械操作多模光纤并从收集的平均信号中提取数据,可以平均和平滑模式噪声。借助于周期性温度变化使多模光纤的折射率发生变化,以上讨论的温度基相移设备完成模式相移。如以下所讨论的,也可以利用机械操作多模光纤改变折射率。此外,机械操作可以导致平均和平滑模式噪声影响的信号,因为光不能够在被操作光纤的波导内完全跟随特定的模式。因此,通过相移和机械扰乱的组合,可以在一段多模光纤内平均和平滑模式噪声诱发的散斑图形。As discussed above, modal noise can be averaged and smoothed by periodically varying the refractive index or mechanically manipulating the multimode fiber and extracting data from the averaged signal collected. The temperature-based phase shifting devices discussed above accomplish mode phase shifting by varying the refractive index of a multimode fiber with periodic temperature changes. As discussed below, mechanical manipulation of multimode fibers can also be used to change the refractive index. Furthermore, mechanical manipulation can result in averaging and smoothing the signal affected by mode noise, because light is not able to follow a specific mode perfectly within the waveguide of the manipulated fiber. Thus, the mode noise-induced speckle pattern can be averaged and smoothed over a section of multimode fiber by a combination of phase shifting and mechanical perturbation.

一些特定模式的机械光纤操作在平均模式噪声方面比其他的方法更有效。具体地说,沿相对于光纤上一些其他点围绕纵轴(z)扭曲光纤可以使散斑图形发生变化。得到的主要变化是散斑图形围绕z轴的转动。重要的是,在利用机械方式转动光纤时,散斑图形围绕z轴的转动是不同的。二次效应是实际的光分布因转动而发生一些变化。散斑图形的转动主要不是由于应力诱发光纤的折射率变化,虽然这一点可以解释散斑强度图形的微小变化。相反地,在光纤发生扭曲运动时,散斑图形的转动是由于光不能够完全地跟随波导。Some specific modes of mechanical fiber manipulation are more effective at averaging mode noise than others. Specifically, twisting the fiber about the longitudinal axis (z) relative to some other point on the fiber can cause the speckle pattern to change. The main change obtained is the rotation of the speckle pattern around the z-axis. Importantly, the rotation of the speckle pattern around the z-axis is different when the optical fiber is rotated mechanically. The secondary effect is that the actual light distribution changes somewhat due to the rotation. The rotation of the speckle pattern is not primarily due to stress-induced changes in the refractive index of the fiber, although this could explain the small change in the speckle intensity pattern. Conversely, during twisting motion of the fiber, the speckle pattern rotates due to the inability of the light to follow the waveguide completely.

图7表示按照本发明一个实施例的机械模式噪声平均设备(机械装置)700的示意图。机械装置700利用空心轴电动机702放置和固定多模光纤704。光纤的远端部分706是相对于电动机702的轴位置被牢牢固定,而电动机是重复地经历从+360度到-360度的扭曲运动。这个运动的频率最好大于或等于10Hz,因此,它能够有效地平均传输的信号,并大大减小接收端模式噪声的效应。虽然多模光纤沿其纵轴的扭曲对于扰乱模式噪声是有效的,但是也可以利用其他的机械操作,例如,震动,拉伸,或弯曲。FIG. 7 shows a schematic diagram of a mechanical mode noise averaging apparatus (mechanical device) 700 according to one embodiment of the present invention. The mechanical device 700 utilizes a hollow shaft motor 702 to place and hold a multimode fiber 704 . The distal portion 706 of the optical fiber is fixed in position relative to the axis of the motor 702, which repeatedly undergoes twisting motion from +360 degrees to -360 degrees. The frequency of this motion is preferably greater than or equal to 10 Hz, so it effectively averages the transmitted signal and greatly reduces the effect of pattern noise at the receiver. While twisting of a multimode fiber along its longitudinal axis is effective for perturbing modal noise, other mechanical manipulations such as shaking, stretching, or bending can also be used.

压电拉伸器piezoelectric stretcher

拉伸光纤引起光纤折射率和长度的变化。利用压电拉伸器可以拉伸多模光纤。压电装置通常用于在单模光纤中引入调制时间延迟。多模光纤不用在压电拉伸装置中,因为多模光纤的时间延迟是不可控的,这是由于光可以传输多个光程或以多个模式传输。然而,虽然产生时间延迟是不切实际的,压电拉伸装置可用于引入模式相移。Stretching the fiber causes changes in the fiber's refractive index and length. Multimode fibers can be stretched using piezoelectric stretchers. Piezoelectric devices are commonly used to introduce modulation time delays in single-mode fibers. Multimode fibers are not used in piezoelectric stretching devices because the time delay of multimode fibers is not controllable due to the fact that light can travel multiple optical paths or in multiple modes. However, while it is impractical to create time delays, piezoelectric stretching devices can be used to introduce mode phase shifts.

在拉伸多模光纤时,在该光纤上引入的应力可以使光纤折射率和长度发生变化。如图8所示,压电装置800的工作是围绕半圆柱体804缠绕几米多模光纤802,然后以预定的振荡频率和距离振动半圆柱体804。当两个半圆柱体804之间的距离膨胀和收缩时,多模光纤802中的应力发生谐振。这种谐振使光纤802的折射率产生起伏。模式相移的有效性是光纤长度(z)变化和光纤中折射率变化(Δnij)的函数(公式1)。When a multimode fiber is drawn, the stress introduced on the fiber can cause changes in the fiber's refractive index and length. As shown in Figure 8, the piezoelectric device 800 works by winding a few meters of multimode fiber 802 around a half cylinder 804, and then vibrating the half cylinder 804 at a predetermined oscillation frequency and distance. As the distance between the two half cylinders 804 expands and contracts, the stress in the multimode fiber 802 resonates. This resonance causes the refractive index of the fiber 802 to fluctuate. The effectiveness of the mode phase shift is a function of the change in fiber length (z) and the change in the refractive index (Δn ij ) in the fiber (Equation 1).

利用压电装置800的两个技术之一可以完成模式相移。在第一个技术中,压电装置800有足够的光纤802,并配置成引入足够的应力以产生很大的模式变化,因此,通过平均许多模式可以获得均匀的信号强度。或者,因为压电装置800循环通过稳定的折射率变化,压电装置800能够按照这样的方式振荡,它在最小和最大拉伸距离上产生180°谐波的模式相移。利用这种方法,可以减小模式噪声,它不是通过时间平均许多模式相移,而是优化拉伸特形以实现180°相移。因此,可以在少至一个循环中平均模式噪声,从而在减小模式噪声的情况下实现快速的数据采集。Mode phase shifting can be accomplished using one of two techniques using piezoelectric device 800 . In the first technique, the piezoelectric device 800 has enough fibers 802 and is configured to introduce enough stress to produce large mode changes, so that uniform signal strength can be obtained by averaging many modes. Alternatively, because the piezoelectric device 800 cycles through a steady refractive index change, the piezoelectric device 800 can oscillate in such a way that it produces a 180° harmonic modal phase shift at minimum and maximum stretch distances. Using this approach, mode noise can be reduced by not temporally averaging the phase shifts of many modes, but by optimizing the stretch profile to achieve a 180° phase shift. Thus, pattern noise can be averaged in as little as one cycle, enabling fast data acquisition with reduced pattern noise.

发射端光学系统(Pitch-Side Optical Train)Transmitter optical system (Pitch-Side Optical Train)

光纤耦合的TDLAS检测设备的发射端光学系统也遇到重大的设计难题,这是由于需要在传输通过测量区的所有波长上产生单模光束。若在整个发射端光学系统中可以使用单模光纤,则模式噪声就不是一个问题。然而,光纤仅仅在有限的波长窗口上可以作为单模波导工作。在特定光纤的短波长截止以外,光可以有几个较高级空间模式传输通过该光纤。在从光纤中射出时,这些高级模式的干涉可以产生散斑图形。散斑图形是随时间和波长变化的。即使少量的光束削波可以在测量中产生噪声。The optics at the launch end of a fiber-coupled TDLAS detection device also suffers from significant design challenges due to the need to generate a single-mode beam at all wavelengths transmitted through the measurement region. Mode noise is not an issue if single-mode fiber can be used throughout the transmitter optics. However, optical fibers can only operate as single-mode waveguides over a limited wavelength window. Beyond the short wavelength cutoff of a particular fiber, light can have several higher order spatial modes propagating through that fiber. The interference of these higher order modes can produce a speckle pattern when exiting the fiber. Speckle patterns vary with time and wavelength. Even small amounts of beam clipping can introduce noise in the measurement.

与此相反,若选取有单模截止的光纤,它与需要传输的最短波长匹配,则较长的波长在耦合进入光纤时遭受重大的损失,且该光纤在长波长下具有很大的弯曲损失。In contrast, if a fiber is selected with a single-mode cutoff that matches the shortest wavelength that needs to be transmitted, longer wavelengths suffer significant losses when coupled into the fiber, and the fiber has significant bend losses at long wavelengths .

这个问题在光纤耦合的上述波长复用TDLAS检测和控制装置中可以是严重的,因为我们需要复用的波长可以长达1.67μm和短至760nm或670nm。现在还没有这样的商品化光纤,它在这种宽波长范围内可以提供单模运行,高耦合效率和低弯曲损失。在未来,光子晶体光纤可以解决这个难题,但目前晶体光纤技术仍处在它的初级阶段。This problem can be severe in the fiber-coupled wavelength-multiplexed TDLAS detection and control setup described above, because the wavelengths we need to multiplex can be as long as 1.67 μm and as short as 760 nm or 670 nm. There is no commercially available fiber that provides single-mode operation, high coupling efficiency, and low bend loss over such a broad wavelength range. In the future, photonic crystal fibers can solve this problem, but crystal fiber technology is still in its infancy.

如图9所示,利用多模光纤120的非常短传输部分,可以减轻从670nm或760nm到1670nm的单模光束中复用和发射光的问题,这种多模光纤不允许高级空间模式的波长短于单模光纤截止波长。参照以上的公式(1),若多模光纤的长度L较短,则可以减小模式噪声。在这种情况下,例如,若760nm的光耦合到截止波长为1280nm的短单模光纤中(例如,Corning SMF28),则760nm的光至少在几米距离内仍保持单模。所以,解决发射端模式噪声的问题是耦合760nm的光进入单模光纤,其波长大于1280nm,但也可以是760nm的多模光纤,在准直光传输通过测量区之前仅传输了很短的距离。As shown in Figure 9, the problem of multiplexing and launching light in a single-mode beam from 670nm or 760nm to 1670nm can be alleviated by using a very short transmission section of multimode fiber 120 that does not allow for higher spatial modes of wave The length is shorter than the cut-off wavelength of single-mode fiber. Referring to the above formula (1), if the length L of the multimode fiber is short, the modal noise can be reduced. In this case, for example, if 760nm light is coupled into a short single-mode fiber with a cutoff wavelength of 1280nm (for example, Corning SMF28), the 760nm light remains single-mode at least over distances of several meters. So, the solution to the problem of mode noise at the transmitter is to couple 760nm light into a single-mode fiber, which has a wavelength greater than 1280nm, but can also be a multimode fiber at 760nm, where the collimated light travels only a short distance before passing through the measurement region .

图9和图2表示这种系统的示意图。参照图9,在宽间隔激光频率下发射的多个二极管激光源902耦合到离散的单模光纤904A-904n。在波长1349nm与1670nm之间的二极管激光器发射的激光被复用器906复用。复用器906的输出耦合到有合适大小的发射端光纤908,发射激光的波长范围是从1349nm-1670nm,二者都没有很大的传输损失和没有引入模式噪声。这些波长下的合适光纤是Corning SMF28。然而,若被复用和耦合到SMF28光纤,则在传输通过相对短的距离之后,760nm的输入就变成多模。因此,760nm激光的输出耦合到其波长小于1280nm的单模光纤,例如,SMF750。输入光纤904n中传输的激光和在发射端光纤908中传输的复用激光可以在发射端光学元件910的附近耦合。耦合器912和发射端光学元件910最好是由一段短的传输光纤914连接,选取的传输光纤914可以没有损失地传输所有耦合和复用的波长。图9所示系统的合适传输光纤是Corning SMF28。只要传输光纤是相对地短,耦合到传输光纤914的760nm激光就没有严重的多模性能。在图9所示的系统和光纤中,为了避免引入严重的多模噪声,传输光纤的长度必须保持在等于或小于3米。Figures 9 and 2 show schematic diagrams of such a system. Referring to FIG. 9, a plurality of diode laser sources 902 emitting at widely spaced laser frequencies are coupled to discrete single-mode optical fibers 904A-904n. Laser light emitted by diode lasers at wavelengths between 1349 nm and 1670 nm is multiplexed by multiplexer 906 . The output of the multiplexer 906 is coupled to the fiber 908 at the transmitting end with a suitable size, and the wavelength range of the emitted laser is from 1349nm to 1670nm, neither of which has a large transmission loss and does not introduce mode noise. A suitable fiber at these wavelengths is Corning SMF28. However, if multiplexed and coupled into SMF28 fiber, the 760nm input becomes multimode after transmission over a relatively short distance. Therefore, the output of the 760nm laser is coupled to a single-mode fiber whose wavelength is less than 1280nm, for example, SMF750. The laser light transmitted in the input fiber 904n and the multiplexed laser light transmitted in the transmit fiber 908 may be coupled in the vicinity of the transmit optical element 910 . The coupler 912 and the transmitting optical element 910 are preferably connected by a short transmission fiber 914, which is selected to transmit all coupled and multiplexed wavelengths without loss. A suitable delivery fiber for the system shown in Figure 9 is Corning SMF28. As long as the delivery fiber is relatively short, the 760nm laser coupled to the delivery fiber 914 has no serious multimode performance. In the system and optical fiber shown in Figure 9, in order to avoid the introduction of severe multimode noise, the length of the transmission optical fiber must be kept equal to or less than 3 meters.

在图2所示的类似系统中,耦合器134是从760nm的二极管激光器中接收输入并从有很长波长的二极管激光器中接收复用光束。In a similar system to that shown in Figure 2, coupler 134 receives the input from a 760nm diode laser and receives the multiplexed beam from a diode laser with a much longer wavelength.

通过此处公开的实施例,我们已完全地明白本发明的目的。专业人员应当理解,在不偏离本发明重要功能的条件下,通过不同的实施例可以实现本发明的各种特征。这些具体的实施例仅仅是说明性的,而不是用于限制以下权利要求书所规定的本发明范围。Through the embodiments disclosed herein, we have fully understood the purpose of the present invention. Those skilled in the art should understand that various features of the present invention can be implemented through different embodiments without departing from the essential functions of the present invention. These specific examples are illustrative only, and are not intended to limit the scope of the invention, which is defined by the following claims.

Claims (15)

1. optical devices, comprising:
Multimode optical fiber; With
Equilibration device, the change in signal strength that the modal noise for the light propagated in this multimode optical fiber average brings out,
Wherein equilibration device comprises periodically-varied device, and the time period periodically for choosing at changes the refractive index of multimode optical fiber,
Wherein equilibration device comprises:
For the device of periodically-varied multimode optical fiber temperature.
2. according to the optical devices of claim 1, the device wherein for periodically-varied multimode optical fiber temperature comprises: with the thermal element of multimode optical fiber heat interchange, this thermal element at least comprises with one of lower device: well heater and refrigeratory.
3., according to the optical devices of claim 2, wherein this well heater is the fluid source being heated to more than environment temperature, and this refrigeratory is the fluid source being cooled to below environment temperature.
4., according to the optical devices of claim 1, also comprise:
With the temperature sensor of multimode optical fiber thermo-contact; With
Controller, inputs and the device controlled for periodically-varied multimode optical fiber temperature for receiving from temperature sensor.
5. a method for the change in signal strength of bringing out for time average modal noise in the multimode optical fiber having input end and output terminal, the method comprises:
Couple the light into the input end of multimode optical fiber;
The refractive index of periodically-varied multimode optical fiber; With
Receive the light of this multimode optical fiber output terminal,
Wherein by the temperature of periodically-varied multimode optical fiber, change the refractive index of multimode optical fiber.
6. optical devices for the change in signal strength of bringing out for the modal noise of average light, comprising:
Multimode optical fiber;
With the thermal element of this multimode optical fiber thermo-contact, for changing the temperature of this multimode optical fiber in the time period periodically chosen.
7., according to the optical devices of claim 6, also comprise:
With the temperature sensor of this multimode optical fiber thermo-contact; With
Controller, inputs for receiving from this temperature sensor and controls described thermal element.
8., according to the optical devices of claim 6, also comprise:
With the heat reservoir of described thermal element thermo-contact; With
The fan of fluid communication is carried out with this heat reservoir.
9. according to the optical devices of claim 6, also comprise: reel, for being wound around the multimode optical fiber that is chosen length, this multimode optical fiber and described thermal element thermo-contact.
10., according to the optical devices of claim 9, wherein the length of choosing of this multimode optical fiber is between 55m and 100m.
11. according to the optical devices of claim 6, wherein said thermal element at least comprises with one of lower device: electrothermal module, infrared heater, chemical heater, cooling device, with the fluid source being heated to more than environment temperature, for changing the temperature of this multimode optical fiber in the time period periodically chosen.
12. according to the optical devices of claim 11, and wherein electrothermal module is electric resistance heater, and cooling device is chemical refrigeratory or the fluid source being cooled to below environment temperature.
13. 1 kinds of combustion sensing apparatus comprising receiving end optical system, comprising:
Multimode optical fiber; With
Equilibration device, the change in signal strength that the modal noise for the light propagated in this multimode optical fiber average brings out,
Wherein equilibration device comprises periodically-varied device, and the time period periodically for choosing at changes the refractive index of multimode optical fiber,
Wherein equilibration device comprises:
For the device of periodically-varied multimode optical fiber temperature.
14. according to the combustion sensing apparatus of claim 13, and the device wherein for periodically-varied multimode optical fiber temperature comprises: with the thermal element of this multimode optical fiber heat interchange, this thermal element at least comprises with one of lower device: well heater and refrigeratory.
15. according to the combustion sensing apparatus of claim 14, and wherein this well heater is the fluid source being heated to more than environment temperature, and this refrigeratory is the fluid source being cooled to below environment temperature.
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CA2561711A1 (en) 2005-11-03
WO2005103781A1 (en) 2005-11-03
AU2005236385A1 (en) 2005-11-03
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CA2561711C (en) 2012-12-18
KR101212439B1 (en) 2012-12-14

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