CN1919802A - Humic acid highly effective composite fertilizer and preparation method thereof - Google Patents
Humic acid highly effective composite fertilizer and preparation method thereof Download PDFInfo
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- CN1919802A CN1919802A CN 200610053149 CN200610053149A CN1919802A CN 1919802 A CN1919802 A CN 1919802A CN 200610053149 CN200610053149 CN 200610053149 CN 200610053149 A CN200610053149 A CN 200610053149A CN 1919802 A CN1919802 A CN 1919802A
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Abstract
The invention discloses a high-effective composite fertilizer and preparing method of humic acid, which comprises the following parts: 0-50% nitrogenous fertilizer, 0-50% phosphatic fertilizer, 0-50% potassium fertilizer, 1-30% microelement, 10-60% humic acid, 1-15% adhesive and 2-15% water, wherein the fertilizer contains at least two kinds of nitrogenous fertilizer, phosphatic fertilizer and potassium fertilizer, which form the product through blending, graining and drying procedure.
Description
Technical field
The present invention relates to a kind of humic acid highly effective composite fertilizer and preparation method thereof.
Background technology
According to " Chinese humic acids net ": since the twenties in 20th century, along with development of industry and agriculture, the problem of environmental pollution that produces owing to the unreasonable use of industrial waste exhaust and agrochemicals also occurs thereupon.All be faced with the problem that soil and water pollution seriously hinder ecotope and agriculture production in many developing countries and developed country.Therefore the environment remediation problem becomes hot research in recent years, humic acids has slightly acidic, wetting ability, cationic exchange, complex ability and higher adsorptive power etc., and these polymer characteristicses that humic acids had have obtained environment in environmental technology and agriculture field scientific research person pay close attention to greatly and use.
Some investigators think to the result of study that heavy metal in soil is irritated in dirt, humic acids can change the confinement capabilities of soil to each form of heavy metal ion, make and have direct toxic heavy metal soluble state and sharply reduce, making heavy metal oxide combined, carbonate combined simultaneously and organically combining attitude increases, and reduces flowability, activity and the bioavailability of heavy metal in soil.Other indoor results of study then think, humic acids is dissolved with promoter action to Cu and Zn in extraction agent, and Pb and Cd are had inhibition, so can improve the efficient that the chemical extraction of Cu and Zn is repaired.Studies show that of quantification, humic acids to the influence of each form Cd content in the soil is: throw the increasing of people's ratio with it, soluble state Cd descends, and organic Cd rises, iron aluminium (manganese) oxidation state Cd and organic Cd are identical, and be the most obvious with soluble state Cd and organic Cd dependency with it.
Therefore, the research of Remixed humic acid fertilizer invention is arisen at the historic moment, and a kind of agricultural material product of environment-friendly high-efficiency is provided for agriculture production.
Chinese patent CN1181018C, " Remixed humic acid fertilizer " that provides, defective is also not contain trace element, is unfavorable for liking the growth of micro-crop, especially soil trace element lacks serious area, thereby its suitability is not strong.
Chinese patent CN1059187C, " Remixed humic acid fertilizer and the manufacture method thereof " that provides comprises rare earth in its component.As everyone knows, rare earth has the character of similar trace element, can promote the seed germination of farm crop, promotes root growth, promote photosynthesis of plants, thereby its advantage is conspicuous.But,, and increase manufacturing cost because the effect of increasing production of rare earth is not very remarkable.Another shortcoming of this invention is that its technology is very complicated, has further increased manufacturing cost, especially is not suitable for large-scale industrial production and agriculture large-area applications.
Summary of the invention
The present invention will solve is the above-mentioned defective that prior art exists, and aims to provide a kind of low cost, more easy to operate and humic acid complex fertilizer of being suitable for producing in enormous quantities and preparation method thereof.
The technical scheme that addresses the above problem employing is: a kind of humic acid highly effective composite fertilizer is characterized in that being made up of by weight following component:
Nitrogenous fertilizer 0-50 part phosphate fertilizer 0-50 part potash fertilizer 0-50 part
Trace element 1-30 part humic acids 10-60 part tackiness agent 1-15 part
Water 2-15 part
And described nitrogenous fertilizer, phosphate fertilizer, potash fertilizer is two kinds of existence simultaneously at least wherein.
Described humic acids is any or multiple combination wherein of coal humic acid, yellow humic acid, fulvic acid potassium, fulvic acid sodium, yellow humic acid zinc, potassium humate, calcium humate, Sodium salts humic acids, zinc humic acid, humic acids iron, ammonium humate, humic acids molybdenum, nitro humic acid, nitro-humic acid ammonium.
Described coal humic acid is peat, brown coal or weathered coal.
Described nitrogenous fertilizer is any or multiple combination wherein of urea, ammonium sulfate, ammonium chloride, ammonium nitrate, bicarbonate of ammonia.
Described phosphate fertilizer is any or multiple combination wherein of calcium superphosphate (being commonly called as general calcium), double superhosphate, monoammonium phosphate, diammonium phosphate, fused calcium-magnesium phosphate fertilizer, nitrophosphate fertilizer, phosphoric acid, peroxophosphoric acid.
Described potash fertilizer is Repone K and/or vitriolate of tartar.
Described trace element is any or multiple combination wherein of boron fertilizer, iron fertilizer, manganese fertilizer, zinc fertilizer, copper fertilizer, molydbenum fertilizer.
Described tackiness agent is any or multiple combination wherein of fused(calcium magnesium)phosphate, bentonite, calcium-magnesium powder or Fluorspar Powder.
A kind of preparation method of humic acid highly effective composite fertilizer, to mix by weight 0-50 part nitrogenous fertilizer, 0-50 part phosphate fertilizer, 0-50 part potash fertilizer, 1-30 part trace element, 10-60 part 60～200 order humic acidss, 1-15 part tackiness agent, 2-15 part water of preparation, through solid granulation, drying, make humic acid complex fertilizer.
Described granulation is disk granulation, extruder grain or drum granulating any prilling process wherein.
Humic acid complex fertilizer of the present invention and, nitrogen, phosphorus, potassium and micro-utilization ratio height, product is difficult for the moisture absorption, intensity height, and anti-storage.
The present invention also can directly be processed into pulvis or aqua foliage fertilizer without granulation.
Embodiment
In following embodiment, each component is pressed all by weight preparation.
Embodiment 1
25 parts in urea, 25 parts of monoammonium phosphates, 15 parts in Repone K, 6 parts in zinc sulfate, 2 parts of boraxs, 15 parts of humic acidss, 4 parts in tackiness agent, water are mixed fully for 8 parts, carry out complex reaction, through the disk granulation, dry, packing.This product is adapted at liking on zinc, the boron crop and uses.
Embodiment 2
25 parts of ammonium chlorides, 25 parts of diammonium phosphate, 15 parts of vitriolate of tartar, 5 parts of ammonium molybdates, 17 parts of humic acidss, 3 parts in tackiness agent, water are mixed fully for 8 parts, carry out complex reaction, through extruder grain, dry, packing.This product is adapted at using on soybean, the peanut.
Embodiment 3
35 parts in urea, 30 parts in Repone K, 5 parts in zinc sulfate, 20 parts of humic acidss, 4 parts in tackiness agent, water are mixed fully for 6 parts, carry out complex reaction, through drum granulating, dry, packing.This product belongs to the high nitrogen and potassium humic acid complex fertilizer, is adapted at using on rich phosphorus, the zinc deficient soil.
Embodiment 4
45 parts of calcium superphosphate, 30 parts in Repone K, 5 parts of boraxs, 10 parts of humic acidss, 3 parts in tackiness agent, water are mixed fully for 7 parts, carry out complex reaction, through the disk granulation, dry, packing.This product belongs to the middle high potassium humic acid complex fertilizer of phosphorus, is adapted at using on rich nitrogen, the boron deficient soil.
Embodiment 5
30 parts in urea, 30 parts of monoammonium phosphates, 10 parts in zinc sulfate, 5 parts in ferrous sulfate, 15 parts of humic acidss, 2 parts in tackiness agent, water are mixed fully for 8 parts, carry out complex reaction, through extruder grain, dry, packing.This product belongs to high nitrogen high phosphorus humic acid complex fertilizer.Be adapted at rich potassium, lack on zinc, the iron deficiency soil and use.
Embodiment 6
50 parts in ammonium sulfate, 15 parts of peroxophosphoric acid, 2 parts in copper sulfate, 30 parts of humic acidss, 10 parts in tackiness agent, water are mixed fully for 10 parts, carry out complex reaction, through extruder grain, dry, packing.
Embodiment 7
20 parts in ammonium nitrate, 50 parts of heavy peroxophosphoric acid, 20 parts in Repone K, 15 parts in zinc sulfate, 15 parts in ferrous sulfate, 30 parts of humic acidss, 10 parts in tackiness agent, water are mixed fully for 10 parts, carry out complex reaction, through extruder grain, dry, packing.
Embodiment 8
20 parts in bicarbonate of ammonia, 15 parts of nitrophosphate fertilizers, 20 parts in Repone K, 15 parts in zinc sulfate, 60 parts of humic acidss, 10 parts in tackiness agent, water are mixed fully for 15 parts, carry out complex reaction, through extruder grain, dry, packing.
Embodiment 9
10 parts in bicarbonate of ammonia, 5 parts of phosphatase 11s, 50 parts in Repone K, 15 parts in zinc sulfate, 30 parts of humic acidss, 8 parts in tackiness agent, water are mixed fully for 10 parts, carry out complex reaction, through extruder grain, dry, packing.
What should be understood that is: the foregoing description is just to explanation of the present invention, rather than limitation of the present invention, and any innovation and creation that do not exceed in the connotation scope of the present invention all fall within protection scope of the present invention.
Claims (10)
1, a kind of humic acid highly effective composite fertilizer is characterized in that being made up of by weight following component:
Nitrogenous fertilizer 0-50 part phosphate fertilizer 0-50 part potash fertilizer 0-50 part
Trace element 1-30 part humic acids 10-60 part tackiness agent 1-15 part
Water 2-15 part
And described nitrogenous fertilizer, phosphate fertilizer, potash fertilizer is two kinds of existence simultaneously at least wherein.
2, humic acid highly effective composite fertilizer as claimed in claim 1 is characterized in that described humic acids is any or multiple combination wherein of coal humic acid, yellow humic acid, fulvic acid potassium, fulvic acid sodium, yellow humic acid zinc, potassium humate, calcium humate, Sodium salts humic acids, zinc humic acid, humic acids iron, ammonium humate, humic acids molybdenum, nitro humic acid, nitro-humic acid ammonium.
3, humic acid highly effective composite fertilizer as claimed in claim 2 is characterized in that described coal humic acid is peat, brown coal or weathered coal.
4, humic acid highly effective composite fertilizer as claimed in claim 1 is characterized in that described nitrogenous fertilizer is any or multiple combination wherein of urea, ammonium sulfate, ammonium chloride, ammonium nitrate, bicarbonate of ammonia.
5, humic acid highly effective composite fertilizer as claimed in claim 1 is characterized in that described phosphate fertilizer is any or multiple combination wherein of calcium superphosphate, double superhosphate, monoammonium phosphate, diammonium phosphate, fused calcium-magnesium phosphate fertilizer, nitrophosphate fertilizer, phosphoric acid, peroxophosphoric acid.
6, humic acid highly effective composite fertilizer as claimed in claim 1 is characterized in that described potash fertilizer is Repone K and/or vitriolate of tartar.
7, humic acid highly effective composite fertilizer as claimed in claim 1 is characterized in that described trace element is any or multiple combination wherein of boron fertilizer, iron fertilizer, manganese fertilizer, zinc fertilizer, copper fertilizer, molydbenum fertilizer.
8, humic acid highly effective composite fertilizer as claimed in claim 1 is characterized in that described tackiness agent is any or multiple combination wherein of fused(calcium magnesium)phosphate, bentonite, calcium-magnesium powder or Fluorspar Powder.
9, the preparation method of humic acid highly effective composite fertilizer as claimed in claim 1, it is characterized in that and to mix by weight 0-50 part nitrogenous fertilizer, 0-50 part phosphate fertilizer, 0-50 part potash fertilizer, 1-30 part trace element, 10-60 part 60～200 order humic acidss, 1-15 part tackiness agent, 2-15 part water of preparation, through solid granulation, drying, make humic acid complex fertilizer, and described nitrogenous fertilizer, phosphate fertilizer, potash fertilizer at least wherein two kinds exist simultaneously.
10, the preparation method of the described humic acid highly effective composite fertilizer of claim 1 is characterized in that described granulation is disk granulation, extruder grain or drum granulating any prilling process wherein.
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| CN 200610053149 CN1919802A (en) | 2006-08-23 | 2006-08-23 | Humic acid highly effective composite fertilizer and preparation method thereof |
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| CN 200610053149 CN1919802A (en) | 2006-08-23 | 2006-08-23 | Humic acid highly effective composite fertilizer and preparation method thereof |
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Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967072A (en) * | 2010-08-11 | 2011-02-09 | 西北农林科技大学 | Organic-inorganic compound fertilizer |
| CN102120707A (en) * | 2010-12-15 | 2011-07-13 | 张向东 | Multielement fertilizer and preparation method thereof |
| CN102153412A (en) * | 2011-05-05 | 2011-08-17 | 山东省农业科学院农业资源与环境研究所 | Weathered coal activated organic and inorganic compound fertilizer and preparation method thereof |
| CN102173957A (en) * | 2011-02-14 | 2011-09-07 | 天润绿业（北京）环保技术有限公司 | Organic mineral fertilizer and preparation method thereof |
| CN102219589A (en) * | 2011-05-10 | 2011-10-19 | 福建省农业科学院土壤肥料研究所 | Special fertilizer for cold water paddy rice, and preparation and application method thereof |
| CN102249815A (en) * | 2011-05-25 | 2011-11-23 | 福建省农业科学院土壤肥料研究所 | Special fertilizer for sour regurgitation field rice as well as preparation and use methods thereof |
| CN102503702A (en) * | 2011-11-21 | 2012-06-20 | 四川省农业科学院植物保护研究所 | Organic potassium fertilizer for improving potassium utilization ratio and fertilizer efficiency slow release and preparation method thereof |
| CN103408345A (en) * | 2013-06-19 | 2013-11-27 | 中农舜天生态肥业有限公司 | Humic acid synergistic composite fertilizer and preparation method thereof |
| CN103508787A (en) * | 2013-07-18 | 2014-01-15 | 安徽省司尔特肥业股份有限公司 | Soil improvement type slow release fertilizer and preparation method thereof |
| CN103553826A (en) * | 2013-11-11 | 2014-02-05 | 双赢集团有限公司 | Fertilizer |
| CN103570474A (en) * | 2013-11-11 | 2014-02-12 | 双赢集团有限公司 | Fertilizer |
| CN103739375A (en) * | 2013-12-19 | 2014-04-23 | 山西惠亿农生物科技有限公司 | Microbial fermentation humic acid biological fertilizer and application and preparation method thereof |
| CN104276897A (en) * | 2014-10-27 | 2015-01-14 | 陆川县大鹏现代农业发展有限公司 | Specific fertilizer for radix millettiae speciosae |
| CN104609973A (en) * | 2015-01-30 | 2015-05-13 | 安徽惠禾壮有机肥科技有限公司 | Special organic-inorganic compound fertilizer for peanut and preparation method thereof |
| CN104649787A (en) * | 2015-02-09 | 2015-05-27 | 云南省农业科学院热带亚热带经济作物研究所 | Special amino acid water-soluble fertilizer for lemons and preparation method thereof |
| CN105347983A (en) * | 2015-12-23 | 2016-02-24 | 山东农业大学 | Special super-large-granule humic acid fertilizer for fruit trees and preparation method of special super-large-granule humic acid fertilizer |
| CN105565929A (en) * | 2015-12-11 | 2016-05-11 | 河南骏化发展股份有限公司 | Production method of multi-element synergic iron-humic acid compound fertilizer |
| CN108218616A (en) * | 2017-12-29 | 2018-06-29 | 广东拉多美化肥有限公司 | A kind of polyglutamic acid coated compound fertilizer |
| CN108934728A (en) * | 2018-09-07 | 2018-12-07 | 泉州永春新绿芦柑专业合作社 | A kind of ponkan plantation fertilizer and its ponkan implantation methods |
| CN111646839A (en) * | 2020-05-21 | 2020-09-11 | 河南捷农生化有限公司 | Humic acid compound fertilizer and preparation method thereof |
| CN112299915A (en) * | 2020-11-23 | 2021-02-02 | 安徽儒商生物科技有限公司 | Zinc humic acid long-acting formula fertilizer and preparation method thereof |
-
2006
- 2006-08-23 CN CN 200610053149 patent/CN1919802A/en active Pending
Cited By (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967072A (en) * | 2010-08-11 | 2011-02-09 | 西北农林科技大学 | Organic-inorganic compound fertilizer |
| CN101967072B (en) * | 2010-08-11 | 2013-11-06 | 西北农林科技大学 | Organic-inorganic compound fertilizer |
| CN102120707B (en) * | 2010-12-15 | 2013-06-12 | 张向东 | Multielement fertilizer and preparation method thereof |
| CN102120707A (en) * | 2010-12-15 | 2011-07-13 | 张向东 | Multielement fertilizer and preparation method thereof |
| CN102173957A (en) * | 2011-02-14 | 2011-09-07 | 天润绿业（北京）环保技术有限公司 | Organic mineral fertilizer and preparation method thereof |
| CN102153412A (en) * | 2011-05-05 | 2011-08-17 | 山东省农业科学院农业资源与环境研究所 | Weathered coal activated organic and inorganic compound fertilizer and preparation method thereof |
| CN102219589B (en) * | 2011-05-10 | 2013-01-16 | 福建省农业科学院土壤肥料研究所 | Special fertilizer for cold water paddy rice, and preparation and application method thereof |
| CN102219589A (en) * | 2011-05-10 | 2011-10-19 | 福建省农业科学院土壤肥料研究所 | Special fertilizer for cold water paddy rice, and preparation and application method thereof |
| CN102249815A (en) * | 2011-05-25 | 2011-11-23 | 福建省农业科学院土壤肥料研究所 | Special fertilizer for sour regurgitation field rice as well as preparation and use methods thereof |
| CN102249815B (en) * | 2011-05-25 | 2013-06-05 | 福建省农业科学院土壤肥料研究所 | Special fertilizer for sour regurgitation field rice as well as preparation and use methods thereof |
| CN102503702A (en) * | 2011-11-21 | 2012-06-20 | 四川省农业科学院植物保护研究所 | Organic potassium fertilizer for improving potassium utilization ratio and fertilizer efficiency slow release and preparation method thereof |
| CN103408345B (en) * | 2013-06-19 | 2015-05-20 | 中农舜天生态肥业有限公司 | Humic acid synergistic composite fertilizer and preparation method thereof |
| CN103408345A (en) * | 2013-06-19 | 2013-11-27 | 中农舜天生态肥业有限公司 | Humic acid synergistic composite fertilizer and preparation method thereof |
| CN103508787A (en) * | 2013-07-18 | 2014-01-15 | 安徽省司尔特肥业股份有限公司 | Soil improvement type slow release fertilizer and preparation method thereof |
| CN103508787B (en) * | 2013-07-18 | 2015-05-20 | 安徽省司尔特肥业股份有限公司 | Soil improvement type slow release fertilizer and preparation method thereof |
| CN103570474A (en) * | 2013-11-11 | 2014-02-12 | 双赢集团有限公司 | Fertilizer |
| CN103553826B (en) * | 2013-11-11 | 2015-04-08 | 双赢集团有限公司 | Fertilizer |
| CN103553826A (en) * | 2013-11-11 | 2014-02-05 | 双赢集团有限公司 | Fertilizer |
| CN103739375A (en) * | 2013-12-19 | 2014-04-23 | 山西惠亿农生物科技有限公司 | Microbial fermentation humic acid biological fertilizer and application and preparation method thereof |
| CN104276897A (en) * | 2014-10-27 | 2015-01-14 | 陆川县大鹏现代农业发展有限公司 | Specific fertilizer for radix millettiae speciosae |
| CN104609973A (en) * | 2015-01-30 | 2015-05-13 | 安徽惠禾壮有机肥科技有限公司 | Special organic-inorganic compound fertilizer for peanut and preparation method thereof |
| CN104649787A (en) * | 2015-02-09 | 2015-05-27 | 云南省农业科学院热带亚热带经济作物研究所 | Special amino acid water-soluble fertilizer for lemons and preparation method thereof |
| CN105565929A (en) * | 2015-12-11 | 2016-05-11 | 河南骏化发展股份有限公司 | Production method of multi-element synergic iron-humic acid compound fertilizer |
| CN105347983A (en) * | 2015-12-23 | 2016-02-24 | 山东农业大学 | Special super-large-granule humic acid fertilizer for fruit trees and preparation method of special super-large-granule humic acid fertilizer |
| CN108218616A (en) * | 2017-12-29 | 2018-06-29 | 广东拉多美化肥有限公司 | A kind of polyglutamic acid coated compound fertilizer |
| CN108934728A (en) * | 2018-09-07 | 2018-12-07 | 泉州永春新绿芦柑专业合作社 | A kind of ponkan plantation fertilizer and its ponkan implantation methods |
| CN111646839A (en) * | 2020-05-21 | 2020-09-11 | 河南捷农生化有限公司 | Humic acid compound fertilizer and preparation method thereof |
| CN112299915A (en) * | 2020-11-23 | 2021-02-02 | 安徽儒商生物科技有限公司 | Zinc humic acid long-acting formula fertilizer and preparation method thereof |
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