CN1899044A - Pesticide composition of butene fipronil and organic phosphates - Google Patents
Pesticide composition of butene fipronil and organic phosphates Download PDFInfo
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- CN1899044A CN1899044A CN 200610047164 CN200610047164A CN1899044A CN 1899044 A CN1899044 A CN 1899044A CN 200610047164 CN200610047164 CN 200610047164 CN 200610047164 A CN200610047164 A CN 200610047164A CN 1899044 A CN1899044 A CN 1899044A
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Abstract
The pesticide composition of butane fipronil and organophosphorus pesticide contains effective components butane fipronil and organophosphorus pesticide auxiliary components. The pesticide composition of butane fipronil and organophosphorus pesticide reasonable effective component composition, broad pesticidal spectrum, high pest preventing and killing effect, low toxicity, cotoxicity coefficient of 100-145, fast acting and low cost. It may be used in preventing and killing rice field pests and vegetable pests, including striped rice borer, cabbage moth, paddy borer, etc.
Description
One, technical field:
The present invention relates to agricultural chemical insecticide, particularly a kind of have tag, the insecticides of stomach toxicity or systemic action.
Two, background technology:
Paddy rice, vegetables are staple food crops of China and country in Southeast Asia, are subjected to the harm of various pests in its process of growth, and various pests takes place simultaneously sometimes, serious threat the growth of paddy rice.Particularly snout moth's larva (striped rice borer, paddy stem borer, rice leaf roller) and plant hopper, big generation has in recent years brought great loss to agricultural production.The plant hopper of breaking out in a plurality of provinces in 2005 has been caused the total crop failure of many places paddy rice, and is very big to peasant's kind grain enthusiasm influence.
Butene-fipronil, its chemical name is: 5-amino-3-cyano group-1-(2.6-dichlor-4-trifluoromethyl phenyl)-4-trifluoromethyl sulfinyl pyrazole, its structural formula is:
Be mainly used in the control of paddy rice and vegetable-crop pest-insect, fine to striped rice borer, diamond-back moth effect, but its systemic action is poor, and the use cost height, limited the popularization and the use of this good insecticide greatly.And that organophosphorus insecticides is a kind of use cost is low, be widely used, the medicament good to the preventive effect of various insects, plant hopper great outburst in 2005, tool has played important effect in the control insect pest aspect drawing out, retrieving economic losses, such medicament is in China's large-scale production, cost is low, residual effect is moderate, and speed of action is fast, is used in a large number by the peasant.
Three, summary of the invention:
The objective of the invention is to overcome butene-fipronil to paddy stem borer, rice leaf roller, the anti-heterodyne of plant hopper, cost height, deficiency that interior absorption is not strong problem, the Pesticidal combination of a kind of butene-fipronil and organic phosphates is provided, and toxicity is moderate, with low cost, insecticidal spectrum is wide, the mode of action is various, quick-acting is good.
The technical scheme that the present invention is adopted for achieving the above object is: the Pesticidal combination of butene-fipronil and organic phosphates, comprise active ingredient and auxiliary element, and active ingredient is butene-fipronil and organophosphorus insecticide.
The percentage by weight that described active ingredient accounts for the Pesticidal combination total amount is: butene-fipronil 0.5-15%, organophosphorus insecticides 5-90%; Preferable active ingredient amount is butene-fipronil 1-5%, organophosphorus insecticides 10-80%; Best active ingredient amount is butene-fipronil 1-3%, organophosphorus insecticides 20-50%.
Described organophosphorus insecticides is selected from one or both in the following substances: O; O-dimethyl-S-(N-methylamino formyl methyl) thiophosphate (omethoate); O; O-dimethyl S (N-methylamino formyl methyl) phosphorodithioate (Rogor); O; O-diethyl-O-(quinoxaline-2-yl) thiophosphate (quinalphos); O; O-diethyl-O-alpha-cyano benzene fork amido thiophosphate (phoxim); 0; 0-diethyl-0-1-phenyl-1; 2; 4-triazole-3-thiophosphate (Hostathion); O; O-diethyl-O-(3; 5; the 6-trichloro-2-pyridyl) phosphorothionate (chlopyrifos); 2-N; N dimethylamine base-1-sodium thiosulfate base-3-propane thiosulfate (desinsection list); 2-N; N dimethylamine base-1; two (the thiosulfonic acid sodium base) propane (dimehypo) of 3-; O; S-dimethyl acetyl group thio-phosphamide ester (orthene); O-methyl-O-(neighbour-isopropoxy carbonyl phenyl) thio-phosphamide (isocarbophos); 0; 0-dimethyl-(2; 2; 2-three chloro-1-hydroxyethyls) phosphate (chlorophos); O-[2-(diethylin)-6-methyl-4-pyrimidine radicals]-O; O-systox (Diothyl); O, O-dimethyl-O-(2-diethylamino 6-methylpyrimidine-4-yl) thiophosphate (MDYL).Above product is domestic all production in enormous quantities.
The Pesticidal combination of described butene-fipronil and organic phosphates adopts routine fashion to be mixed with missible oil or suspending agent.
Described butene-fipronil is made through mixing to stir by the former medicine of active ingredient, solvent and emulsifier with the Pesticidal combination missible oil of organic phosphates.Wherein solvent is selected from a certain solvent in butanols, cyclohexanone, dimethyl formamide, dimethylbenzene or high boiling aromatic series or the hydro carbons; Emulsifier adopts various anionic surfactant and nonionic surface active agent, aliphatic alcohol sulfate as Sulfates, alkylol polyoxyethylene groups ether sodium sulfate, alkylol polyoxyethylene groups ether calcium sulphate, the sodium alkyl sulfonate of Sulfonates, alkylbenzenesulfonate, alkylnaphthalene sulfonate, dialkyl succinylsuccinate sulfonate, monoalkyl phenyl polyoxyethylene groups ether succinic acid sodium sulfonate, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol formaldehyde condensation product ethylene oxide adduct sulfonate, aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether, the anhydrous sorbitol fatty acid ester, anhydrous sorbitol aliphatic acid polyethenoxy base ether, alkylphenol formaldehyde condensation product polyoxyethylene groups ether, sulfonation castor-oil plant alkoxide, quaternary ammonium salt derivative, the condensation product of oxirane and nonyl or octyl phenol is main product or hydroxyl and the oxirane that does not dissociate by esterification, the alkalies and alkaline earth salt of sulfuric acid ester and sulfonic acid, as sulphonyl amber ester dinonyl (dioctyl) sodium, and such as the alkali of the macromolecule sulfonic acid derivative of sodium lignin sulfonate (calcium) and anhydrous sorbierite carboxylate that the alkali salt condensation forms solubility etc.That can give an example has farming breast No. 2000 series, petroleum sodium sulfonate, dodecyl sodium sulfates, draws back powder, lauryl alcohol polyethylene glycol oxide base ether sulfonic acid sodium, tween series etc.
The Pesticidal combination suspending agent of described butene-fipronil and organic phosphates is ground through sand mill by the former medicine of active ingredient, water or organic solvent and serial auxiliary agent and forms.Wherein organic solvent is selected from dimethylbenzene etc.; The series auxiliary agent is wetting agent, dispersion suspending agent, tackifier, stabilizing agent, antifreezing agent, anticorrosion colouring agent, defoamer, mineral wet goods.
The Pesticidal combination of butene-fipronil of the present invention and organic phosphates, active ingredient are selected for use rationally, and insecticidal spectrum is wide, can effectively prevent and kill off rice pest and vegetable-crop pest-insects such as striped rice borer, diamond-back moth, paddy stem borer, rice leaf roller and plant hopper, the control rice grub is effective, and preventive effect can reach more than 90%, and toxicity is low, its co-toxicity coefficient is 100-145, quick-acting is good, and the lasting effect phase, residual quantity was low more than 15 days, use cost is low, and every mu than the low 2-5 unit of butene-fipronil.
Four, embodiment:
The present invention is described in further detail below in conjunction with embodiment.In these examples, except that specified otherwise was arranged, all percentages all were weight percentage.
Prescription one: butene-fipronil 1.0%, Rogor 30.0% adds solvent toluene 51%, cosolvent DMF 10%, emulsifier alkylol polyoxyethylene groups ether sodium sulfate 8% makes the Pesticidal combination missible oil of butene-fipronil and organic phosphates.
Perhaps butene-fipronil 1%, and Rogor 30% adds wetting agent and dispersant 8%, filler white carbon 15%, and water 46% mixes the Pesticidal combination suspending agent that makes butene-fipronil and organic phosphates.
Prescription two: butene-fipronil 1.0%, omethoate 20.0%, solvent toluene 61%, cosolvent DMF 10%, emulsifier alkylol polyoxyethylene groups ether sodium sulfate 8% makes the Pesticidal combination missible oil of butene-fipronil and organic phosphates.
Perhaps butene-fipronil 1%, omethoate 20%, and wetting agent and dispersant 8%, filler white carbon 15%, water 56% makes the Pesticidal combination suspending agent of butene-fipronil and organic phosphates.
Prescription three: butene-fipronil 1%, quinalphos 29.0%, wetting agent and dispersant 8%, filler white carbon 16%, water 46% makes the Pesticidal combination suspending agent of butene-fipronil and organic phosphates.
Prescription four: butene-fipronil 1%, phoxim 29.0%, wetting agent and dispersant 8%, white carbon 16%, water 46% makes the Pesticidal combination suspending agent of butene-fipronil and organic phosphates.
Prescription five: butene-fipronil 1%, Hostathion 29.0%, 10% emulsifier, 2% stabilizing agent, 18% cosolvent, 2% antifreezing agent, remaining solvent toluene or dimethylbenzene adopt mechanical agitation or high speed shear mixing emulsifier evenly to disperse to make the Pesticidal combination missible oil of butene-fipronil and organic phosphates.
Prescription six: butene-fipronil 1.0%, chlopyrifos 29.0%, the Pesticidal combination missible oil that the sodium alkyl sulfonate 5% of solvent 20%, emulsifier Sulfonates, thickener 5%, antifreezing agent 3%, defoamer 0.5% and remaining solvent toluene or dimethylbenzene are mixed and form butene-fipronil and organic phosphates.
Prescription seven: butene-fipronil 1.0%, desinsection list 54.0%, a certain solvent 34% in dimethylbenzene or high boiling aromatic series or the hydro carbons, cosolvent dimethyl formamide (DMF) 6%, the condensation product of emulsifier oxirane and nonyl or octyl phenol are main product or the Pesticidal combination missible oil of making butene-fipronil and organic phosphates by free hydroxyl of esterification and oxirane 5%.
Prescription eight: butene-fipronil 1.0%, dimehypo 49.0%, organic solvent dimethyl formamide 20%, nonionic emulsifier 15%, surplus is the Pesticidal combination missible oil that water makes butene-fipronil and organic phosphates.
Prescription nine: butene-fipronil 1.0%, orthene 29.0%, organic solvent is butanols or cyclohexanone 60%, No. 2000 series 10% of emulsifier farming breast, and the percentage by weight weighing drops into and fully stirs the mixed Pesticidal combination missible oil that can get butene-fipronil and organic phosphates in the reactor.
Prescription ten: butene-fipronil 1.0%, isocarbophos 29.0%, solvent are dimethylbenzene 60%, synergist 2%, emulsifier anhydrous sorbitol fatty acid ester 8% makes the Pesticidal combination missible oil of butene-fipronil and organic phosphates.
Fill a prescription 11: butene-fipronil 1.0%, chlorophos 49.0%, emulsifier 12%, stabilizing agent 1%, synergist 1.5%, surplus is solvent butanols or ethyl acetate, makes total component reach the 100% Pesticidal combination missible oil that makes butene-fipronil and organic phosphates.
Fill a prescription 12: butene-fipronil 1.0%, Diothyl 29.0%, emulsifier 12%, stabilizing agent 1%, synergist 1.5%, surplus is solvent butanols or ethyl acetate, makes total component reach the 100% Pesticidal combination missible oil that makes butene-fipronil and organic phosphates.
Fill a prescription 13: butene-fipronil 1.0%, MDYL 24.0%, emulsifier 10%, stabilizing agent 1%, synergist 1.5%, surplus is solvent butanols or ethyl acetate, makes total component reach the 100% Pesticidal combination missible oil that makes butene-fipronil and organic phosphates.
Above-mentioned prescription and the agent of butene-fipronil list and the agent of organophosphorus insecticides list compare test, to co-toxicity coefficient and test of pesticide effectiveness data such as the following table 1 of striped rice borer:
Table 1
Butene-fipronil and organophosphorus insecticides mixed agent are to striped rice borer co-toxicity coefficient measurement result
| Insecticide | LC 50(mg/l) | Toxicity index (actual measurement) | Theoretical toxicity index | Co-toxicity coefficient (CTC) |
| Butene-fipronil | 0.0748 | |||
| Rogor | 15.3442 | |||
| Prescription one | 2.2850 | 3.2735 | 3.6926 | 88.65 |
| Omethoate | 5.7165 | |||
| Prescription two | 1.2139 | 6.1628 | 6.0081 | 102.58 |
| Quinalphos | 7.5664 | |||
| Prescription three | 1.8656 | 4.0095 | 4.2889 | 93.49 |
| Phoxim | 2.4592 | |||
| Prescription four | 1.0063 | 7.4332 | 6.2735 | 118.48 |
| Hostathion | 4.2558 | |||
| Prescription five | 1.1765 | 6.3583 | 5.0323 | 126.35 |
| Chlopyrifos | 0.5762 | |||
| Prescription six | 0.3966 | 18.8600 | 15.8829 | 118.75 |
| The desinsection list | 50.3216 | |||
| Prescription seven | 4.5738 | 1.6354 | 1.9640 | 83.27 |
| Dimehypo | 48.7737 | |||
| Prescription eight | 3.9224 | 1.9071 | 2.1503 | 88.69 |
| Orthene | 15.3579 | |||
| Prescription nine | 1.8180 | 4.1145 | 3.8041 | 108.16 |
| Isocarbophos | 9.7538 | |||
| Prescription ten | 1.8239 | 4.1015 | 4.0746 | 100.66 |
| Chlorophos | 25.0626 | |||
| Fill a prescription 11 | 1.9808 | 3.7762 | 2.2925 | 164.72 |
| Diothyl | 16.3847 | |||
| Fill a prescription 12 | 2.1596 | 3.4636 | 3.7746 | 91.76 |
| MDYL | 6.3484 | |||
| Fill a prescription 13 | 1.4482 | 5.1649 | 5.1311 | 100.66 |
The CTC value is a summation action near 100, is synergistic effect greater than 100.This shows that the present invention has all prescriptions all to have addition or synergistic effect.
Table 2 butene-fipronil and organophosphorus insecticides mixed agent are to striped rice borer control efficiency (field)
| The medicament title | Consumption (g, ai/ha) | The insect population radix | Behind the medicine 3 days | Behind the medicine 7 days | ||
| The survival borer population | Preventive effect (%) | Borer population alive | Preventive effect (%) | |||
| Butene-fipronil | 30 | 38 | 5 | 86.8 | 3 | 92.1 |
| Rogor | 600 | 36 | 9 | 75.0 | 7 | 80.6 |
| Prescription one | 500 | 41 | 8 | 82.5 | 6 | 85.4 |
| Omethoate | 375 | 46 | 7 | 84.7 | 6 | 87.0 |
| Prescription two | 200 | 45 | 7 | 84.4 | 5 | 88.9 |
| Quinalphos | 412 | 50 | 15 | 70.0 | 10 | 80.0 |
| Prescription three | 300 | 36 | 8 | 77.8 | 4 | 88.9 |
| Phoxim | 300 | 38 | 5 | 86.8 | 3 | 92.1 |
| Prescription four | 200 | 37 | 4 | 89.2 | 0 | 100 |
| Hostathion | 300 | 40 | 7 | 82.5 | 3 | 92.5 |
| Prescription five | 200 | 42 | 4 | 90.5 | 1 | 97.6 |
| Chlopyrifos | 360 | 43 | 5 | 88.3 | 3 | 93.0 |
| Prescription six | 250 | 45 | 3 | 93.3 | 1 | 97.8 |
| The desinsection list | 675 | 42 | 8 | 80.9 | 6 | 85.7 |
| Prescription seven | 450 | 41 | 7 | 82.9 | 4 | 90.2 |
| Dimehypo | 540 | 39 | 6 | 84.6 | 3 | 92.3 |
| Prescription eight | 400 | 39 | 6 | 84.6 | 2 | 94.8 |
| Orthene | 600 | 46 | 9 | 80.4 | 4 | 91.3 |
| Prescription nine | 400 | 30 | 3 | 90.0 | 1 | 96.6 |
| Isocarbophos | 450 | 38 | 10 | 73.7 | 6 | 84.2 |
| Prescription ten | 300 | 38 | 8 | 78.9 | 4 | 89.4 |
| Chlorophos | 1500 | 46 | 10 | 78.3 | 6 | 86.9 |
| Fill a prescription 11 | 800 | 36 | 5 | 86.1 | 0 | 100 |
| Diothyl | 600 | 39 | 9 | 76.9 | 7 | 82.1 |
| Fill a prescription 12 | 500 | 40 | 8 | 80.0 | 4 | 90.0 |
| MDYL | 600 | 37 | 7 | 81.0 | 6 | 83.8 |
| Fill a prescription 13 | 500 | 37 | 7 | 81.2 | 3 | 91.9 |
| Contrast | -- | 42 | 48 | -- | 55 | -- |
Still be significantly increased under the situation that effective dose reduces by the visible preventive effect of the present invention of last table 2, and increased quick-acting, reduced the effect cost, each prescription of confection to the production-increasing function of paddy rice also clearly.
Claims (8)
1, the Pesticidal combination of butene-fipronil and organic phosphates comprises active ingredient and auxiliary element, it is characterized in that: active ingredient is butene-fipronil and organophosphorus insecticide.
2, the Pesticidal combination of butene-fipronil according to claim 1 and organic phosphates is characterized in that: the percentage by weight that active ingredient accounts for the Pesticidal combination total amount is: butene-fipronil 0.5-15%, organophosphorus insecticides 5-90%.
3, the Pesticidal combination of butene-fipronil according to claim 1 and organic phosphates is characterized in that: the percentage by weight that active ingredient accounts for the Pesticidal combination total amount is: butene-fipronil 1-5%, organophosphorus insecticides 10-80%.
4, the Pesticidal combination of butene-fipronil according to claim 1 and organic phosphates is characterized in that: the percentage by weight that active ingredient accounts for the Pesticidal combination total amount is: butene-fipronil 1-3%, organophosphorus insecticides 20-50%.
5; Pesticidal combination according to arbitrary described butene-fipronil of claim 1-4 and organic phosphates; it is characterized in that: organophosphorus insecticides is one or both in following substances earlier: O; O-dimethyl-S-(N-methylamino formyl methyl) thiophosphate; O; O-dimethyl S (N-methylamino formyl methyl) phosphorodithioate; O; O-diethyl-O-(quinoxaline-2-yl) thiophosphate; O; O-diethyl-O-alpha-cyano benzene fork amido thiophosphate; 0; 0-diethyl-0-1-phenyl-1; 2; 4-triazole-3-thiophosphate; O; O-diethyl-O-(3; 5; the 6-trichloro-2-pyridyl) phosphorothionate; 2-N; N dimethylamine base-1-sodium thiosulfate base-3-propane thiosulfate; 2-N; N dimethylamine base-1; two (the thiosulfonic acid sodium base) propane of 3-; O; S-dimethyl acetyl group thio-phosphamide ester; O-methyl-O-(neighbour-isopropoxy carbonyl phenyl) thio-phosphamide; 0; 0-dimethyl-(2; 2; 2-three chloro-1-hydroxyethyls) phosphate; O-[2-(diethylin)-6-methyl-4-pyrimidine radicals]-O; the O-systox; O, O-dimethyl-O-(2-diethylamino 6-methylpyrimidine-4-yl) thiophosphate.
6, according to the Pesticidal combination of arbitrary described butene-fipronil of claim 1-4 and organic phosphates, it is characterized in that: Pesticidal combination is missible oil or suspending agent.
7, the Pesticidal combination of butene-fipronil according to claim 6 and organic phosphates, it is characterized in that: Pesticidal combination is a missible oil, it is made through mixing to stir by the former medicine of active ingredient, solvent and emulsifier, and wherein solvent is selected from a kind of solvent in butanols, cyclohexanone, dimethyl formamide, dimethylbenzene or high boiling aromatic series or the hydro carbons; Emulsifier adopts various anionic surfactant and nonionic surface active agent.
8, the Pesticidal combination of butene-fipronil according to claim 6 and organic phosphates, it is characterized in that: Pesticidal combination is that suspending agent is formed through the sand mill grinding by the former medicine of active ingredient, water or organic solvent and serial auxiliary agent, wherein organic solvent is a dimethylbenzene, and auxiliary agent is wetting agent, dispersion suspending agent, tackifier, stabilizing agent, antifreezing agent, anticorrosion colouring agent, defoamer, mineral oil.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101099481B (en) * | 2007-07-27 | 2010-04-14 | 浙江省农业科学院 | A kind of insecticide composition for controlling rice pests |
| CN102017978A (en) * | 2011-01-07 | 2011-04-20 | 陕西上格之路生物科学有限公司 | Pesticidal composition containing Sulfoxaflor and butene-fipronil |
| CN102919265A (en) * | 2012-10-10 | 2013-02-13 | 成都科利隆生化有限公司 | Pesticide composition containing butane fipronil and organic phosphorus insecticide |
| CN102960364A (en) * | 2012-12-19 | 2013-03-13 | 南京捷润科技有限公司 | Parasiticide composite containing butene-fipronil and chlorpyrifos and preparation method thereof |
| CN108477204A (en) * | 2018-05-09 | 2018-09-04 | 惠州市欧野科技有限公司 | A kind of composition pesticide of prevention wild cabbage diamondback moth |
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2006
- 2006-07-06 CN CN 200610047164 patent/CN1899044A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101099481B (en) * | 2007-07-27 | 2010-04-14 | 浙江省农业科学院 | A kind of insecticide composition for controlling rice pests |
| CN102017978A (en) * | 2011-01-07 | 2011-04-20 | 陕西上格之路生物科学有限公司 | Pesticidal composition containing Sulfoxaflor and butene-fipronil |
| CN102017978B (en) * | 2011-01-07 | 2013-07-24 | 陕西上格之路生物科学有限公司 | Pesticidal composition containing Sulfoxaflor and butene-fipronil |
| CN102919265A (en) * | 2012-10-10 | 2013-02-13 | 成都科利隆生化有限公司 | Pesticide composition containing butane fipronil and organic phosphorus insecticide |
| CN102960364A (en) * | 2012-12-19 | 2013-03-13 | 南京捷润科技有限公司 | Parasiticide composite containing butene-fipronil and chlorpyrifos and preparation method thereof |
| CN102960364B (en) * | 2012-12-19 | 2015-04-22 | 南京捷润科技有限公司 | Parasiticide composite containing butene-fipronil and chlorpyrifos and preparation method thereof |
| CN108477204A (en) * | 2018-05-09 | 2018-09-04 | 惠州市欧野科技有限公司 | A kind of composition pesticide of prevention wild cabbage diamondback moth |
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