CN1776085A - Anti-pilling finishing method of soybean fiber fabric - Google Patents
Anti-pilling finishing method of soybean fiber fabric Download PDFInfo
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- CN1776085A CN1776085A CN 200510122759 CN200510122759A CN1776085A CN 1776085 A CN1776085 A CN 1776085A CN 200510122759 CN200510122759 CN 200510122759 CN 200510122759 A CN200510122759 A CN 200510122759A CN 1776085 A CN1776085 A CN 1776085A
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- pilling
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- fiber fabrics
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- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 6
- 239000003995 emulsifying agent Substances 0.000 claims description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- -1 Diacrylic acid ester Chemical class 0.000 claims description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 2
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- 238000005096 rolling process Methods 0.000 claims 4
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- 238000002791 soaking Methods 0.000 claims 1
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 10
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Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
This invention discloses a fuzzing-pilling resisting finishing method for soybean fiber fabric. It makes grafting modification to soybean fiber fabric, finishes by resin finishing agent. The monomer for grafting modification is diacritic acid or methacrylate of diatomic alcohol or with other active group, the finishing agent is organic silicon modified polyacrylate dispersion or modified polyurethane like finishing agent. Said invention has fine washing resistance and no formaldehyde in process agent.
Description
Technical field
The present invention relates to a kind of method, belong to the textile dyeing and finishing technical field soybean fiber fabric lousiness-pilling-resistance finishing.
Background technology
Fibre and soya is a kind of new Regenerated Protein Fiber of Chinese science and technology personnel independent development, is formed through wet spinning by soybean protein and polyvinyl alcohol mixing liquid, has passed through the acetalation crosslinking Treatment in the back road processing of spinning.Fibre and soya can or interweave with conventional textile raw material blending such as wool, cashmere, silk, viscose glue, bamboo fibre, day silk, model, terylene, polyamide fibre.Moisture absorption is good, soft, gloss is soft, take good characteristics such as comfortable because fibre and soya has, and therefore, is used for development of new garment material and household textiles by textile industry, and is wherein in the majority with blended union class knit product.
At present, the fibre and soya product mainly is the staple fibre that is cut into certain-length, its surface is very smooth, frictional coefficient of fiber is little, fiber crimp is few, and cohesive force is little, and fibre and soya is very easily outwards slippage from yarn under external force, therefore, easily fluffing, the young pilose antler of generation continue wear in tied up in knots mutually just, rubbed into many spherical granules.The ball top of fabric face is very easily attached by dirt, dust, make fabric wear performance and outward appearance is had a strong impact on.
The factor that influences the fibre pick balling-up is a lot, generally can improve the anti-fluffing and anti-pilling performance of fabric by specification, fabric structure and the improvement dyeing and finishing technology condition of regulating yarn.For example, the yarn that the twist is high, interfibrous obvolvent is tight, and outstanding fiber can reduce, and has reduced the mobility of fiber, and yarn is when being subjected to rubbing, and fiber slippage in the yarn is relatively just few, and the pilling phenomenon will reduce; From fabric structure, hard-packed tissue is difficult for pilling than loose tissue, and the fabric that cloth cover is more smooth, smooth is difficult for pilling than the rough fabric of cloth cover; When pre-treatment and dyeing, add lubricant and can prevent friction, reduce the generation of balling-up.But, prevent the pilling of fabric in the process of taking, then should carry out anti-pilling finishing.
At present, the method for fabric anti-fluffing anti-pilling mainly contains biopolishing and RESIN FINISH method.Biopolishing is that profit has biology enzyme that fabric is carried out biopolishing, utilizes the hydrolysis of enzyme and the percussion of machinery jointly to remove the surperficial young pilose antler and the tip of fiber.The utilization biopolishing has obviously reduced pilling trend, and effect is lasting, even after repeating to wash in the family expenses washing machine, the fabric of biopolishing relatively still keeps no young pilose antler.But this method is mainly used in the anti-fluffing and anti-pilling of wool fabric and handles, but the polypeptide chain of specific protease catalytic decomposition wool fibre, thus removed the young pilose antler of fabric face and the tip of fiber, reach the anti-fluffing and anti-pilling effect.Because fibre and soya is a kind of novel fiber, also do not have at present to be developed at the biology enzyme of soybean fiber, therefore, can not adopt the biopolishing technology to carry out anti-pilling finishing.The RESIN FINISH method is to utilize the function of resin in the netted film forming of fiber surface interlinkage, makes the wear-resisting resin molding of fiber surface parcel one deck, and this resin molding weakens the slippage of fiber; Simultaneously, resin interlinkage equably condenses upon the top layer of yarn, and fibre end is adhered on the yarn, is difficult for pilling during friction, thereby can improves the pilling resistance of fabric effectively.Existing anti-pilling finishing agent and processing method are mainly used in wool, acrylic fibers, terylene short fiber BLENDED FABRIC etc., and this method need bake processing under hot conditions.And lower, the poor heat resistance of soybean fiber reactivity, xeothermic easily yellowing more than 120 ℃, powerful decline, fabric feeling hardens, and existing method can not be used for the arrangement of soybean fiber.And the general at present anti-pilling finishing agent that uses contains a certain amount of formaldehyde, does not meet the requirement of ecological textile, and feel, style to fabric after handling have bigger influence.
Summary of the invention
The objective of the invention is to overcome deficiency and limitation that prior art exists, provide a kind of effectively, the method for sorting of the soybean fiber fabric lousiness-pilling-resistance of environment-friendly type.
The technical solution adopted in the present invention is: a kind of method of soybean fiber fabric lousiness-pilling-resistance finishing is provided, it is characterized in that: earlier soybean fiber is carried out graft modification and handle, adopt resin finishing agent to handle again.
In described graft modification was handled, the monomer of graft modification was a kind of in the following compounds:
(1) general structure is
The double methacrylate of dihydroxylic alcohols; In the formula: R is CH
3Or H, n is 2～6;
(2) general structure is
Double methyl methacrylate; In the formula: R is CH
3Or H, n is 1～5;
(3) general structure is
Acrylate that has active group or methyl acrylic ester compound, in the formula: R is CH
3Or H, R
1For structure is
-CH
2OH ,-CH
2CH
2The active group of OH.
Described resin finishing agent is band reactive group silicone-modified polyacrylate emulsion or polyurethane class finishing agent.
Described graft modification is handled and is adopted infusion process, its process conditions are: it is with respect to 10～100% of fabric weight that the grafted monomers consumption is handled in grafting, catalyst amount is with respect to 1～10% of monomer weight, emulsifying agent consumption 1～10g/L, regulate pH to 2～5 of maceration extract; bath raio is 1: 10～100, and treatment temperature is 50～90 ℃, and the processing time is 20～90min.
Described catalyst is ammonium persulfate or potassium peroxydisulfate.
Described emulsifying agent is a kind of in the fatty alcohol polyethenoxy ether class non-ionic surface active agent or their mixture.
Infusion process is adopted in the use of described silicone-modified polyacrylate emulsion, process conditions are: silicone-modified polyacrylate emulsion 10～40g/L; bath raio 1: 10～50; after working solution is heated to 30～50 ℃; again soybean fiber is put into working solution; dipping 5～40min, centrifugal dehydration is dried under 80～120 ℃ of temperature conditions.
Padding method is adopted in the use of described silicone-modified polyacrylate emulsion, process conditions are: be prepared into dressing liquid with silicone-modified polyacrylate emulsion 10～60g/L, silicone softening agent 0～30g/L, fabric is carried out two to be soaked two and rolls arrangement, pick-up rate is 60～100%, bakes 1～5min again under 80～120 ℃ of temperature conditions.
Infusion process is adopted in the use of described modified polyurethane finishing agent, and process conditions are: finishing agent consumption 20～60g/L, and silicone softening agent 0～30g/L, dip time 5～40min after the centrifugal dehydration, is dried under 80～120 ℃ of conditions.
Padding method is adopted in the use of described modified polyurethane finishing agent, process conditions are: be prepared into dressing liquid with the finishing agent of 20～80g/L, the silicone softening agent of 0～30g/L, fabric is carried out two to be soaked two and rolls arrangement, pick-up rate is 60～100%, bakes 1～5min again under 80～120 ℃ of temperature conditions.
The present invention has the following advantages:
1, owing to adopted the grafting treatment technology, make grafted monomers and fibre and soya generation cross-linking reaction, produce crosslinked between the big molecule of fiber, on the basis that the fiber surface reactive group increases, adopt the arrangement of silicone-modified polyacrylate emulsion or polyurethane class finishing agent again, therefore, improve the anti-fluffing and anti-pilling performance of soybean fiber effectively, the anti-fluffing and anti-pilling performance of soybean fiber improves 2～3 grades, and has durability preferably.
2, the finishing agent that adopts the present invention to adopt does not contain free formaldehyde and other harmful substance, meets the ecological textile requirement.
3, the present invention is directed to low, the poor heat resistance of soybean fiber reactivity, in xeothermic easily yellowing more than 120 ℃, powerfully descend, characteristics that fabric feeling hardens, the arrangement process is carried out under lower temperature conditions, therefore, keep original feel of soybean fiber and style preferably, also do not influenced the color and luster and the COLOR FASTNESS of processed fabric.
The specific embodiment
Embodiment 1:
The method for sorting that present embodiment adopted is applicable to soybean fiber knitted thing.
Grafting is handled and is adopted infusion process, prepare maceration extract as follows: the monomer of graft modification is a glytidyl methacrylate, consumption be relative fabric heavy 50%, catalyst is a potassium peroxydisulfate, consumption be with respect to monomer heavy 2%, emulsifying agent is fatty alcohol-polyoxyethylene ether non-ionic surface active agent AEO9, consumption 2g/L; Regulate about treatment fluid pH to 3 with the about 1g/L of glacial acetic acid again.
The soybean knitted fabric is put into the grafting treatment fluid carry out the grafting processing, process conditions are: bath raio 1: 30,75 ℃ of grafting treatment temperatures, time 60min.Processing finishes the back dehydration, adds the Na of 0.5g/L again in temperature is water about 75 ℃
2HSO
3, the washing agent of 2g/L, unreacted monomer and oligomer on the eccysis fabric, dehydration, oven dry.
RESIN FINISH adopts infusion process: silicone-modified polyacrylate emulsion 20g/L, and bath raio 1: 20 is heated to working solution about 35 ℃, then soybean fiber knitted thing is put into working solution, and dipping 30min after the centrifugal dehydration, is dried under 120 ℃ of conditions.
Embodiment 2:
The method for sorting that present embodiment adopted is applicable to soybean fiber knitted thing.
Adopt infusion process grafting treatment process condition as follows: will put into the grafting treatment fluid through the soybean knitted fabric after the pre-treatment and carry out the grafting processing, treatment fluid consists of diglycol dimethylacrylate consumption 60% (heavy to fabric), potassium peroxydisulfate consumption 2% (heavy to monomer), fatty alcohol-polyoxyethylene ether non-ionic surface active agent AEO9 consumption 2g/L, regulate about treatment fluid pH to 3 with glacial acetic acid; bath raio 1: 30; 75 ℃ of grafting treatment temperatures, time 60min.Processing finishes the back dehydration, unreacted monomer and oligomer on the eccysis fabric, dehydration, oven dry.
RESIN FINISH adopts infusion process: modified polyurethane finishing agent consumption 40g/L, reactive silicone softening agent 10g/L floods 15min with the fabric that measures in dressing liquid, take out, and after the centrifugal dehydration, dries under 95 ℃ of conditions.
Embodiment 3:
The technical scheme that present embodiment adopted is applicable to soybean fiber knitted thing.
Adopt infusion process grafting treatment process condition as follows: the soybean knitted fabric to be put into the grafting treatment fluid adopt infusion process to carry out the grafting processing, the grafting treatment fluid consists of the monomer glytidyl methacrylate of graft modification, consumption 50% (heavy) to fabric, catalyst is a potassium peroxydisulfate, consumption 2% (heavy) to monomer, emulsifying agent is fatty alcohol-polyoxyethylene ether non-ionic surface active agent AEO9, consumption 2g/L, regulate about treatment fluid pH to 3.5 with glacial acetic acid; bath raio 1: 30; 75 ℃ of grafting treatment temperatures, time 60min.Processing finishes the back dehydration, unreacted monomer and oligomer on the eccysis fabric, dehydration, oven dry.
RESIN FINISH adopts infusion process: modified polyurethane finishing agent consumption 40g/L, reactive silicone softening agent 10g/L will flood 20min through the soybean fiber knitted thing after above-mentioned grafting is handled in dressing liquid, take out, after the centrifugal dehydration, under 95 ℃ of conditions, dry.
Embodiment 4
The technical scheme that present embodiment adopted is applicable to the fibre and soya woven fabric.
Adopt infusion process grafting treatment process condition as follows: the fibre and soya woven fabric to be put into the grafting treatment fluid carry out the grafting processing, the grafting treatment fluid consists of diglycol dimethylacrylate consumption 60% (heavy to fabric), potassium peroxydisulfate consumption 2% (heavy to monomer), fatty alcohol-polyoxyethylene ether non-ionic surface active agent AEO9 consumption 2g/L, regulate about treatment fluid pH to 4 with glacial acetic acid; bath raio 1: 30; 75 ℃ of grafting treatment temperatures, time 60min.Processing finishes the back dehydration, bath raio 1: 30 not on the eccysis fabric, 75 ℃ of grafting treatment temperatures, time 60min.Processing finishes the back dehydration, unreacted monomer and oligomer on the eccysis fabric, dehydration, oven dry.
RESIN FINISH adopts padding method: finishing agent consists of modified polyurethane finishing agent consumption 20～80g/L, silicone softening agent 0～30g/L, nonionic penetrant 0.5g/L.Fabric two soaks two and rolls in dressing liquid, 85%, 85 ℃ of oven dry of pick-up rate, and 120 ℃ bake 4min.
Embodiment 5
The technical scheme that present embodiment adopted is applicable to the fibre and soya woven fabric.
Adopt infusion process grafting treatment process condition as follows: the fibre and soya woven fabric to be put into the grafting treatment fluid carry out the grafting processing, the grafting treatment fluid consisted of glytidyl methacrylate consumption 50% (heavy to fabric), potassium peroxydisulfate consumption 2% (heavy to monomer), glacial acetic acid consumption 1g/L, fatty alcohol-polyoxyethylene ether non-ionic surface active agent AEO9 consumption 2g/L, bath raio 1: 30,75 ℃ of grafting treatment temperatures, time 60min.Processing finishes the back dehydration, unreacted monomer and oligomer on the eccysis fabric, dehydration, oven dry.
RESIN FINISH adopts padding method: finishing agent consists of silicone-modified polyacrylate emulsion consumption 40g/L, reactive silicone softening agent 10g/L, nonionic penetrant 0.5g/L.Fabric two soaks two and rolls in dressing liquid, 80%, 85 ℃ of oven dry of pick-up rate, and 120 ℃ bake 4min.
Technical solution of the present invention is not only applicable to soybean fiber knitted and woven fabric, is applicable to the fibre and soya to be the fibre and soya BLENDED FABRIC of main component yet, and fabric after treatment can improve 2～3 grades of anti-fluffing and anti-pilling performances, and has durability preferably.Use technical solutions according to the invention, also kept original feel of soybean fiber and style preferably, the color and luster of fabric and COLOR FASTNESS etc. all are not affected, and have improved the result of use of fibre and soya and have taken performance; Do not contain formaldehyde in the employed finishing agent, be a kind of effectively, the method for sorting of the soybean fiber fabric lousiness-pilling-resistance of environment-friendly type.
Claims (8)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101227598A CN100352994C (en) | 2005-12-01 | 2005-12-01 | Soybean fiber fabric lousiness-pilling-resistance finishing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101227598A CN100352994C (en) | 2005-12-01 | 2005-12-01 | Soybean fiber fabric lousiness-pilling-resistance finishing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1776085A true CN1776085A (en) | 2006-05-24 |
| CN100352994C CN100352994C (en) | 2007-12-05 |
Family
ID=36765782
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005101227598A Expired - Fee Related CN100352994C (en) | 2005-12-01 | 2005-12-01 | Soybean fiber fabric lousiness-pilling-resistance finishing method |
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| Country | Link |
|---|---|
| CN (1) | CN100352994C (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102433747A (en) * | 2011-09-19 | 2012-05-02 | 上海大学 | Method for reducing pilling performance of acrylic fabric by using active acrylate polymer |
| CN102433746A (en) * | 2011-09-19 | 2012-05-02 | 上海大学 | Method for improving anti-pilling performance of acrylic fabric |
| CN102587140A (en) * | 2012-02-13 | 2012-07-18 | 远纺工业(上海)有限公司 | Finishing agent resisting fiber hooking of polyester fabric and method |
| CN101503859B (en) * | 2008-02-04 | 2012-11-07 | 上海德桑精细化工有限公司 | Anti-fuzzing and anti-pilling finishing agent for fabric |
| CN103643484A (en) * | 2013-11-22 | 2014-03-19 | 江苏波波熊纺织品有限公司 | Knitted fabric anti-pilling finishing agent and preparation method thereof |
| CN103710986A (en) * | 2013-12-02 | 2014-04-09 | 常熟市新蕾针织有限公司 | Preparation method of knitwear suede-like material pile treatment agent |
| CN103866567A (en) * | 2012-12-11 | 2014-06-18 | 罗莱家纺股份有限公司 | Pilling resistant liquid, and method for improving pilling of woven cotton fabric |
| CN107938322A (en) * | 2017-11-30 | 2018-04-20 | 安徽中福毛纺制帽有限公司 | A kind of special water repellent Anti-Pilling Finishes liquid of wool cap |
| CN109734863A (en) * | 2018-12-29 | 2019-05-10 | 太仓宝霓实业有限公司 | Aqueous polyurethane and preparation method thereof and anti-gigging-pilling agent composition |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MXPA02010621A (en) * | 2000-04-28 | 2004-03-02 | Puradyn Filter Technologies In | Improved filtration efficiency. |
-
2005
- 2005-12-01 CN CNB2005101227598A patent/CN100352994C/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101503859B (en) * | 2008-02-04 | 2012-11-07 | 上海德桑精细化工有限公司 | Anti-fuzzing and anti-pilling finishing agent for fabric |
| CN102433747A (en) * | 2011-09-19 | 2012-05-02 | 上海大学 | Method for reducing pilling performance of acrylic fabric by using active acrylate polymer |
| CN102433746A (en) * | 2011-09-19 | 2012-05-02 | 上海大学 | Method for improving anti-pilling performance of acrylic fabric |
| CN102587140A (en) * | 2012-02-13 | 2012-07-18 | 远纺工业(上海)有限公司 | Finishing agent resisting fiber hooking of polyester fabric and method |
| CN103866567A (en) * | 2012-12-11 | 2014-06-18 | 罗莱家纺股份有限公司 | Pilling resistant liquid, and method for improving pilling of woven cotton fabric |
| CN103643484A (en) * | 2013-11-22 | 2014-03-19 | 江苏波波熊纺织品有限公司 | Knitted fabric anti-pilling finishing agent and preparation method thereof |
| CN103643484B (en) * | 2013-11-22 | 2015-07-01 | 江苏波波熊纺织品有限公司 | Knitted fabric anti-pilling finishing agent and preparation method thereof |
| CN103710986A (en) * | 2013-12-02 | 2014-04-09 | 常熟市新蕾针织有限公司 | Preparation method of knitwear suede-like material pile treatment agent |
| CN107938322A (en) * | 2017-11-30 | 2018-04-20 | 安徽中福毛纺制帽有限公司 | A kind of special water repellent Anti-Pilling Finishes liquid of wool cap |
| CN109734863A (en) * | 2018-12-29 | 2019-05-10 | 太仓宝霓实业有限公司 | Aqueous polyurethane and preparation method thereof and anti-gigging-pilling agent composition |
| CN109734863B (en) * | 2018-12-29 | 2021-01-15 | 太仓宝霓实业有限公司 | Waterborne polyurethane, preparation method thereof and anti-pilling agent composition |
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| CN100352994C (en) | 2007-12-05 |
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Assignee: Hanbang Chemical Co., Ltd., Tongxiang City Assignor: Soochow University Contract fulfillment period: 2007.12.20 to 2012.12.19 contract change Contract record no.: 2008330001620 Denomination of invention: Soybean fiber fabric lousiness-pilling-resistance finishing method Granted publication date: 20071205 License type: Exclusive license Record date: 2008.11.3 |
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