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CN1703564A - Laminated polymer with integrated lighting, sensors and electronics - Google Patents

Laminated polymer with integrated lighting, sensors and electronics Download PDF

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Publication number
CN1703564A
CN1703564A CN 03818999 CN03818999A CN1703564A CN 1703564 A CN1703564 A CN 1703564A CN 03818999 CN03818999 CN 03818999 CN 03818999 A CN03818999 A CN 03818999A CN 1703564 A CN1703564 A CN 1703564A
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CN
China
Prior art keywords
laminated polymer
solid
state lighting
lighting elements
transparent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 03818999
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Chinese (zh)
Inventor
T·C·奥布里恩
M·B·奥雷干
C·W·哈亚斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of CN1703564A publication Critical patent/CN1703564A/en
Pending legal-status Critical Current

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    • Y02B80/50

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  • Electroluminescent Light Sources (AREA)

Abstract

This invention relates to laminated polymer as a host for solid state lighting, sensors, energy generation and storage devices and other electronics that are contained within the transparent non-glass interlayers or air cavities of the laminated polymer.

Description

Laminated polymer with integrated illumination, sensor and electronic equipment
Technical field
The present invention relates to laminated polymer, it is made up of at least two transparent polymeric layer, described transparent polymeric layer is separated by transparent non-glass interlayer or air cavity, wherein comprises solid-state illumination, sensor, energy generation and memory device and other electronic equipment in transparent non-glass interlayer or air cavity.
Background technology
The development that obtains in solid-state illumination, sensor, energy generation and memory device and other electronic device field has caused having the appearance of the product of the vestige of minimizing and novel feature in these fields.For being introduced, these development for building, automobile and other application, have interest all the time in the attractive structure.
The objective of the invention is in laminated polymer, to use non-glass interlayer and/or air cavity, to comprise solid-state illumination, sensor, energy generation or memory device and other electronic equipment, so that improve the function and the aesthetic property of laminated polymer.
Summary of the invention
The invention provides laminated polymer, it is made up of at least two transparent polymeric layer, wherein Lin Jin transparent polymeric layer is separated by transparent solid non-glass interlayer or air cavity, and wherein at least one transparent non-glass interlayer or air cavity comprise by at least one and be selected from the device that following element is formed: solid-state lighting elements, heat sensor, optical sensor, pressure sensor, thin-film capacitor sensor, photocell, hull cell, LCD film, suspended particles device film and transparent electrical conductors.
Detailed Description Of The Invention
The present invention relates to laminated polymer, it is made up of transparent polymeric layer, this transparent polymeric layer is separated by transparent solid non-glass interlayer or air gap, the invention still further relates to the application between the transparent polymeric layer of laminated polymer of transparent solid non-glass interlayer or air cavity, in order to integrated various functions, thus the function and the aesthetic property of enhancing laminated polymer.Laminated polymer is made up of at least two transparent polymeric layer, and wherein Lin Jin transparent polymeric layer is separated by transparent solid non-glass interlayer or air cavity.One embodiment of the invention are laminated polymers, and it is made up of two transparent polymeric layer, and described transparent polymeric layer is separated by transparent solid non-glass interlayer.
Laminated polymer plays the effect of matrix, and it allows numeral and thin film technique to be integrated in the transparent solid non-glass interlayer or the next door, perhaps is integrated in the air cavity.This allows transparent solid non-glass interlayer to realize two kinds of possible purposes, and be laminated polymer mechanical strength is provided, and as the matrix that increases the device of additional function for laminated polymer.Similarly, it allows air cavity to realize two kinds of purposes, i.e. heat insulator, and conduct increases the matrix of the device of additional function for laminated polymer." transparent " as used herein, when being used in combination with transparent polymeric layer or transparent solid non-glass interlayer, refer to transmitted light and do not produce the polymeric layer or the solid non-glass interlayer of considerable scattering, and translucent, the i.e. partly polymeric layer of transmitted light or solid non-glass interlayer.The desired transmitance of transparent polymeric layer or transparent solid non-glass interlayer is usually by how using described laminated product to decide.If application requirements is transparent laminated product as far as possible fully, for example as window, described transparent polymeric layer and transparent solid non-glass interlayer should transmitted rays, and do not have considerable scattering.Use for other, partly the transparent polymeric layer of transmitted light and transparent solid non-glass interlayer may be very suitable.
The present invention stipulates that at least one transparent solid non-glass interlayer or air cavity comprise by at least one and is selected from the device that following element is formed: solid-state lighting elements, heat sensor, optical sensor, pressure sensor, thin-film capacitor sensor, photocell, hull cell, LCD film, suspended particles device film and transparent electrical conductors.When using transparent solid non-glass interlayer, described intermediate layer can be perforated, so that the space for the element use of described device to be provided.When light source was placed along the edge of transparent solid non-glass interlayer, this class perforation can also be as the light scattering center.Selectively, the element of described device can be adjacent to transparent solid non-glass interlayer.Preferably as transparent solid non-glass interlayer be Butacite  PVB (polyvinyl butyral resin) intermediate layer, it can derive from E.I.Du Pont de Nemours andCompany, Wilmington, DE.Transparent electrical conductors for example indium tin oxide can directly be deposited on the transparent polymer.
The form of the electrooptical device that solid-state lighting elements can be light emitting diode (LED), promptly be made up of p-n junction, its response luminous by the forward current of diode (ultraviolet ray, visible light or infrared radiation).LED uses inorganic materials.Solid-state lighting elements can also be the form of Organic Light Emitting Diode (OLED).OLED can be polymer LED (PLED) or little molecule Organic Light Emitting Diode (SMOLED).Transparent electrical conductors can be used for being provided for activation voltage is applied to means on single led or the OLED.Indium tin oxide is preferred transparent electrical conductors.Light source can also be the form of electroluminescent (EL) film.When light source was placed along the edge of transparent solid non-glass interlayer, it can be used for strengthening the image that prints on transparent solid non-glass interlayer.The part that the microprocessor chip that is used for controlling solid-state lighting elements can be used as the described device that is included at least one transparent solid non-glass interlayer or air cavity provides, and perhaps can be provided on the laminated polymer outside.Can programme to microprocessor chip, so that solid state lighting element sequence of display images.Image can be the illustrated or aesthstic demonstration or the form of literal.Motion detector can be used for detecting motion and therefore changes image.For example, when the thin-film capacitor sensor was made into the device part, the object for example motion of hand can change demonstration.Selectively, pressure sensor can detect the pressure that is applied to the laminated polymer surface, and variation is provided in demonstration.There is not solid-state lighting elements therein or wherein on the part of the laminated polymeric thing that is not activated of solid-state lighting elements, it is transparent that the laminated polymeric thing keeps.Wherein the part display image and the information of the laminated polymer that is activated of solid-state lighting elements, for example temperature, time, stock price or the like and programmable this paper and message.
When polymeric layer is enough thin, laminated polymer will be flexible, and can adapt to different shape and form.When the hope bending or other on-plane surface when showing, this class flexible laminated polymer is useful especially.According to amount of deflection, flexible laminated polymer may need to be attached on the carrier with desirable shape.Selectively, flexible laminated polymer can be contained in the glass carrier.When OLED was used as light source, glass container also provided moisture and oxygen barrier layer for OLED, had therefore improved the OLED life-span.
When the mechanical strength of polymer thickness raising and laminated polymer improved, laminated polymer was suitable for different shape and form.
When polymeric layer is enough thick, thereby when providing mechanical strength and stability for laminated polymer structure, laminated polymer can be used as outside or interior windows, as outside or interior walls or surface, perhaps as display surface.
The another kind of device that can be introduced into transparent non-glass interlayer is the device that the energy that will receive from the sun or other light source with the form of light is converted into electric energy, and described electric energy can be stored in the battery and be used for driving LED, OLED, electroluminescent film, LCD film, electricity and produce look suspended particles device film or the like.For example, described device can be sent a telegraph pressure surface plate, rechargeable film lithium cell and the transparent indium-tin-oxide film that conducts electricity is formed by film light between various elements.Selectively, described battery can be used for driving another not device in window.Increase the microprocessor be used to control illumination, be stored in dissimilar demonstrations is provided in window when energy in the battery is used in the different colour of sky.For example, described demonstration can provide information, advertisement or the like by day; Illumination is provided at night; It can serve as night light.Because lithium battery is opaque, and typically the photocell of reasonable price is opaque, and these elements are concentrated in a part of zone of transparent non-glass interlayer.Send a telegraph the embodiment that device that pressure surface plate and rechargeable film lithium cell form can also be used for other laminated polymer by film light.
The laminated polymer embodiment of forming by two transparent polymeric layer of being separated of the present invention by transparent solid non-glass interlayer, it is polymer-intermediate layer-polymer, perhaps by three transparent polymeric layer and two laminated polymer embodiments that transparent solid non-glass interlayer is formed, it is polymer-intermediate layer-polymer-intermediate layer-polymer, be particularly useful for illumination or show, and especially for the laminated polymer of the flexibility that is provided for these application.Transparent solid non-glass interlayer can be used in LED in the transparent solid non-glass interlayer or OLED illumination or by the LED or the OLED illumination at the edge that is positioned at transparent solid non-glass interlayer.By three transparent polymeric layer and two laminated polymers that transparent solid non-glass interlayer is formed, wherein each transparent solid non-glass interlayer comprises a lighting device, compare with the laminated polymer of forming by two transparent polymeric layer being separated by transparent solid non-glass interlayer, provide even a greater variety of illumination scheme.In laminated polymer, have two lighting devices, can obtain different illumination combinations.
Embodiment
This embodiment illustrates and uses flexible laminated polymer of the present invention as light source.The flexible laminated polymer that contains the PLED lighting device is made in such a way.Indium tin oxide (ITO) the film portion ground coating that is used as the anode of device gathers (ethylene glycol terephthalate) (PET) flexible parent metal of sheet material.In air, (PEDOT) mixture, CH8000 (can available from Bayer AG, Germany) be spun onto last 80 second of PET that ITO-applies, under the 000rpm, will to gather (3,4-ethylidene dioxy thiophene) 1.The film that obtains was descended dry 1 minute at 120 ℃ on heating panel, under vacuum, under 90 ℃, spend the night then.With Yellow luminous dose of PDY  132 solution (can be used as pre-made solution) available from Covion Organic Semiconductors, GmbH, Frankfurt, Germany in rotation coating 30 seconds under 330rpm on the PEDOT film, under 1000rpm 20 seconds then.Negative electrode and anode must with zone that power supply contacts in remove PEDOT and PDY  132.With low workfunction metal, Ca, steam are deposited on the film of PEDOT and PDY  132, reach 10 to 30 nano thickness.The aluminium lamination steam is deposited on the Ca layer, reaches the thickness of 300 nanometers, form complete negative electrode.On described device, cover UV-curable epoxy layer, but coated electrode contact area not.With one poly-(ethylene glycol terephthalate) (PET) sheet material place on the epoxy resin, and with the described epoxy resin of ultraviolet curing.When battery was connected to electrode, whole device sent sodium yellow.

Claims (15)

1. laminated polymer, it is made up of at least two transparent polymeric layer, wherein Lin Jin transparent polymeric layer is separated by transparent solid non-glass interlayer or air cavity, and wherein at least one described transparent non-glass interlayer or described air cavity comprise by at least one and be selected from the device that following element is formed: solid-state lighting elements, heat sensor, optical sensor, pressure sensor, thin-film capacitor sensor, photocell, hull cell, LCD film, suspended particles device film and transparent electrical conductors.
2. the laminated polymer of claim 1, it is made up of two transparent polymeric layer of being separated by transparent solid non-glass interlayer.
3. claim 1 or 2 laminated polymer, wherein said device comprises solid-state lighting elements.
4. the laminated polymer of claim 3, wherein said solid-state lighting elements is the form of at least a light emitting diode.
5. the laminated polymer of claim 3, wherein said solid-state lighting elements is the form of at least a Organic Light Emitting Diode.
6. the laminated polymer of claim 3, wherein said solid-state lighting elements is the form of electroluminescent film.
7. the laminated polymer of claim 3, wherein said device also comprises transparent electrical conductors, so that provide activation voltage is applied to means on the described solid-state lighting elements.
8. the laminated polymer of claim 7, wherein said transparent electrical conductors is an indium and tin oxide film.
9. the laminated polymer of claim 7, wherein said device also comprises microprocessor chip, it is programmed to control described solid-state lighting elements and to make described solid-state lighting elements show a series of images.
10. the laminated polymer of claim 9, wherein said microprocessor chip is programmed, so that described solid-state lighting elements display text.
11. the laminated polymer of claim 7 wherein provides microprocessor chip in described laminated polymer outside, it is programmed to control described solid-state lighting elements, makes described solid-state lighting elements show a series of images.
12. the laminated polymer of claim 11, wherein said microprocessor chip is programmed, so that described solid-state lighting elements display text.
13. the laminated polymer of claim 3, wherein laminated polymer is flexible and can adapts to different shape and form.
14. the laminated polymer of claim 13, wherein said solid-state lighting elements are the forms of at least a light emitting diode.
15. the laminated polymer of claim 13, wherein said solid-state lighting elements are the forms of at least a Organic Light Emitting Diode.
CN 03818999 2002-08-06 2003-08-06 Laminated polymer with integrated lighting, sensors and electronics Pending CN1703564A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US40125702P 2002-08-06 2002-08-06
US60/401,257 2002-08-06
US60/462,217 2003-04-11

Publications (1)

Publication Number Publication Date
CN1703564A true CN1703564A (en) 2005-11-30

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CN 200910009860 Pending CN101489341A (en) 2002-08-06 2003-08-06 Laminated glass and structural glass with integrated lighting, sensors and electronics

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8358064B2 (en) 2007-09-12 2013-01-22 Roger Seaman Light emitting and/or receiving apparatus
CN108086632A (en) * 2017-12-18 2018-05-29 王长贵 A kind of luminous brick system

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112019010703A2 (en) 2017-03-15 2019-10-01 Saint Gobain composite panel comprising an electrical consumer
CN111161647B (en) * 2019-12-30 2022-03-08 南京奥汀科技发展有限公司 Transparent floor tile screen with complete transparency and force perception

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8358064B2 (en) 2007-09-12 2013-01-22 Roger Seaman Light emitting and/or receiving apparatus
CN101828263B (en) * 2007-09-12 2013-03-13 罗格·西曼 Light emitting and/or receiving equipment
CN108086632A (en) * 2017-12-18 2018-05-29 王长贵 A kind of luminous brick system

Also Published As

Publication number Publication date
CN101489341A (en) 2009-07-22

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