CN1693396A - Vacuum plating film coating - Google Patents
Vacuum plating film coating Download PDFInfo
- Publication number
- CN1693396A CN1693396A CN 200510034468 CN200510034468A CN1693396A CN 1693396 A CN1693396 A CN 1693396A CN 200510034468 CN200510034468 CN 200510034468 CN 200510034468 A CN200510034468 A CN 200510034468A CN 1693396 A CN1693396 A CN 1693396A
- Authority
- CN
- China
- Prior art keywords
- vacuum metallizing
- coating according
- metallizing coating
- coating
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007747 plating Methods 0.000 title description 3
- 239000007888 film coating Substances 0.000 title 1
- 238000009501 film coating Methods 0.000 title 1
- 229920000098 polyolefin Polymers 0.000 claims abstract description 21
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 15
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 15
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920000642 polymer Polymers 0.000 claims abstract description 13
- 150000008065 acid anhydrides Chemical class 0.000 claims abstract description 7
- 229920006243 acrylic copolymer Polymers 0.000 claims abstract description 7
- 238000000576 coating method Methods 0.000 claims description 59
- 239000011248 coating agent Substances 0.000 claims description 57
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 24
- 150000002148 esters Chemical class 0.000 claims description 21
- 239000012046 mixed solvent Substances 0.000 claims description 19
- 239000003921 oil Substances 0.000 claims description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 10
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical group OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 240000004528 Catalpa ovata Species 0.000 claims description 6
- 235000010005 Catalpa ovata Nutrition 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 239000010496 thistle oil Substances 0.000 claims description 6
- 235000013311 vegetables Nutrition 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 229940059574 pentaerithrityl Drugs 0.000 claims description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 5
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 5
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 4
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 claims description 4
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 claims description 4
- VLTOSDJJTWPWLS-UHFFFAOYSA-N pent-2-ynal Chemical compound CCC#CC=O VLTOSDJJTWPWLS-UHFFFAOYSA-N 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 229920001228 polyisocyanate Polymers 0.000 claims description 4
- 239000005056 polyisocyanate Substances 0.000 claims description 4
- 229920006389 polyphenyl polymer Polymers 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 239000002383 tung oil Substances 0.000 claims description 4
- CHIHQLCVLOXUJW-UHFFFAOYSA-N benzoic anhydride Chemical compound C=1C=CC=CC=1C(=O)OC(=O)C1=CC=CC=C1 CHIHQLCVLOXUJW-UHFFFAOYSA-N 0.000 claims description 3
- -1 oleum lini Substances 0.000 claims description 3
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 claims description 2
- 239000003973 paint Substances 0.000 abstract description 9
- 238000006136 alcoholysis reaction Methods 0.000 abstract description 8
- 229920003023 plastic Polymers 0.000 abstract description 6
- 239000004033 plastic Substances 0.000 abstract description 6
- 238000001771 vacuum deposition Methods 0.000 abstract description 3
- 239000012948 isocyanate Substances 0.000 abstract description 2
- 150000002513 isocyanates Chemical class 0.000 abstract description 2
- 238000007259 addition reaction Methods 0.000 abstract 1
- 239000010773 plant oil Substances 0.000 abstract 1
- 229920005862 polyol Polymers 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
- 239000011877 solvent mixture Substances 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 15
- 230000032050 esterification Effects 0.000 description 11
- 238000005886 esterification reaction Methods 0.000 description 11
- 229910021529 ammonia Inorganic materials 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 230000002950 deficient Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000010696 ester oil Substances 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- 230000004308 accommodation Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 231100000957 no side effect Toxicity 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
A paint for the vacuum deposition on plastics is proportionally prepared from plant oil, polyol, acid anhydride, rosin, acrylic copolymer, polyhydroxy polymer, modified polyolefin, isocyanate and solvent mixture through alcoholysis, esterifying, addition reaction and aminoesterifying.
Description
Technical field
The present invention relates to coating composition, specifically, relate to bottom and topcoating that a kind of vacuum coating technology adopts.
Background technology
Early stage vacuum metallizing coating, adopt ammonia ester oil, alkyd modified ammonia ester oil mostly, they are to be raw material with oleum lini, benzoyl oxide, tetramethylolmethane, modified phenolic resins, tolylene diisocyanate, and by alcoholysis, esterification, condensation, and it is formulated to add siccative.This coating very easily produces phenomenons such as illusion-colour, mute light under the desired severe condition of vacuum plating, paint film adhesion extreme difference, coating are extremely unstable after dilution, easily produces phenomenon such as to separate out, and influences construction effect; Partial coating even be siccative with heavy metallic salt such as leaded, toxicity is bigger." vacuum metallizing coating " of Chinese patent CN1168793C bulletin, by resol ammonia ester oil is carried out modification, though can partly improve the performance of coating, because prescription is improper, product is extremely unstable, can not fundamentally solve this class coating fragility, common fault such as be easy to separate out.
Summary of the invention
The vacuum metallizing coating that the purpose of this invention is to provide a kind of good stability, execution conditions gentleness, paint film property excellence.
This vacuum metallizing coating mainly is made up of vegetables oil, rosin ester, acrylic copolymer, polyhydroxylated polymer, isocyanic ester, mixed solvent and modified polyolefin, acid anhydrides, makes by reactions such as alcoholysis, esterification, addition, ammonia esterifications.This vacuum metallizing coating is made by following weight percentages:
Vegetables oil 20～28%;
Polyvalent alcohol 1～10%;
Acid anhydrides 0～5%;
Rosin ester 12～35%;
Acrylic copolymer 1～5%;
Polyhydroxylated polymer 0.1～3%;
Modified polyolefin 0～5%;
Isocyanic ester 2～4.5%;
Mixed solvent 35～60%.
Above-mentioned vegetables oil can be Thistle oil, Chinese catalpa oil, oleum lini, tung oil and composition thereof (proportioning arbitrarily).
Above-mentioned polyvalent alcohol can be ethylene glycol, glycerol, TriMethylolPropane(TMP), tetramethylolmethane or glycol ether.
Above-mentioned acid anhydrides can be maleic anhydride, benzoyl oxide, trimellitic acid 1,2-anhydride or Succinic anhydried.
Above-mentioned rosin ester can be ester gum, pentalyn or maleic anhydride modified rosin ester.
The aforesaid propylene acid copolymer comprise vinylformic acid and ester thereof or with other monomeric multipolymer, be vinylformic acid and other monomeric multipolymer, or acrylate and other monomeric multipolymer, or vinylformic acid, acrylate and other monomeric multipolymer, it is the low-molecular weight polymer that designs at the general-purpose plastics ground.
Above-mentioned polyhydroxylated polymer can be modified EVA resin, polyester polyhydroxylated polymer, Resins, epoxy or polyvinyl alcohol.
Above-mentioned modified polyolefin is single-ended carboxyl polyolefine, both-end carboxyl polyolefine or polyolefine grafts.
Above-mentioned isocyanic ester can be '-diphenylmethane diisocyanate, xylylene diisocyanate, tolylene diisocyanate or methylene radical polyphenyl polyisocyanate.
Above-mentioned mixed solvent is dimethylbenzene and 200
#Gasoline and/or 120
#Gasoline and/or terebinthine mixture, wherein the content of dimethylbenzene is 1～10% of mixed solvent.
The present invention has following characteristics:
(1) the present invention uses low polar materials such as vegetables oil, rosin ester in a large number, thereby prepared coating is soluble in varsol, overcome previous vacuum metallizing coating poorly soluble to varsol, disadvantage such as be easy to separate out.
(2) for improving the sticking power of coating to ground and coatings, the present invention is directed to the characteristic of general-purpose plastics and coating, add acrylic copolymer, polyhydroxylated polymer in composition, improved the sticking power of coating to ground and coatings greatly, the coating adherence is obviously improved.
(3) for adapting to harsh execution conditions, improve the planarization and the performances such as moisture-proof heat, gloss thereof of coating, the present invention has introduced has levelling property and the hot macromolecular material rosin ester of moisture-resistant in a large number, the execution of coating condition is more gentle, the use of can constructing under severe weather conditions such as high temperature, high humidity.
(4) free isocyanate of coating is zero, and the siccative that is added when using is transistion metal compound, has no side effect; Can adopt varsol as thinner in the coating application process, environmental pollution is little, compliance with environmental protection requirements.
(5) in the special-purpose vacuum metallizing coating of polyolefine, the present invention has introduced the polymer substance acrylic copolymer with reactive behavior and soft segment, can obviously improve the fragility of coating, further improves the mechanical property of paint film.
(6) coating wide accommodation of the present invention can be adapted to comprise the application of the general-purpose plastics and the reclaimed materials thereof of polyolefine, and need not to carry out surface treatment; Particularly selecting for use of modified polyolefin both can have been reduced the surface treatment of polyolefine application, can overcome again to use instability that chlorinatedpolyolefins brought, easily defective such as separate out.
(7) polyvalent alcohol is used for alcoholysis reaction, improves the adherence of coating.
(8) acid anhydrides is used to improve the tolerance and the fullness ratio of coating.
(9) isocyanic ester is used to improve hardness of paint film.
The present invention has following advantage:
(1) the present invention is fit to plastic vacuum coating, and salient features meets the whole process of vacuum plating, both can be used as priming paint, can be used as the protective cover of coating again.Compare with existing coating, the present invention's rosin ester substituted phenolic resin, product colour is lighter, is adapted to especially use as finish paint.
(2) paint stability of the present invention is good, is difficult for separating out;
(3) coating of the present invention oil is long shorter, helps improving the surface drying of coating, overcome existing coating time of drying long, energy consumption is big, under the big situation of humidity poor, the easy defective such as turn white of levelling property, can under mal-conditions such as hot and humid degree, construct.
(4) coating of the present invention can be with hydro carbons as thinner, and thinning ratio can reach 1: 10, and time limit of service reached more than 10 days, and paint film has high gloss, hardness, humidity resistance, resistance to acids and bases and the good transparency and dyeability.
(5) this coating adopts nontoxic transistion metal compound as siccative, has no side effect behind the drying varniss.
(6) this coating wide accommodation can be applicable to comprise the various plastics and the reclaimed materials thereof of polyolefine, does not need the surface treatment can direct application; Its form of construction work both can adopt traditional dip-coating method, also applicable to the spraying method of high-grade wrapping material, to improve coating quality, remedied the defective of dip-coating, improved product specification.
Embodiment
Embodiment 1
The vacuum metallizing coating of present embodiment, this vacuum metallizing coating of per 100 grams is made by the raw material of following weight:
Thistle oil 23 grams
TriMethylolPropane(TMP) 4 grams
Succinic anhydried 3 grams
Maleic anhydride modified rosin ester 15 grams
Vinylformic acid and other monomeric copolymer 1 .5 gram
Polyvinyl alcohol 0.8 gram
Methylene radical polyphenyl polyisocyanate 2.7 grams
Dimethylbenzene and 200
#Mixed solvent 50 grams of gasoline
Thistle oil, Succinic anhydried, maleic anhydride modified rosin ester, vinylformic acid and other monomeric multipolymer, polyvinyl alcohol, methylene radical polyphenyl polyisocyanate and mixed solvent (dimethylbenzene weight content be mixed solvent 5%) are made vacuum metallizing coating through reactions such as alcoholysis (TriMethylolPropane(TMP)), esterification, addition, ammonia esterifications.
Embodiment 2
The vacuum metallizing coating of present embodiment, this vacuum metallizing coating of per 100 grams is made by the raw material of following weight:
Mixture 25 grams of Chinese catalpa oil and oleum lini
Glycerol 3 grams
Pentalyn 20 grams
Acrylate and other monomeric multipolymer 3 grams
Modified EVA resin 1 gram
Tolylene diisocyanate 4 grams
Dimethylbenzene and 200
#Gasoline, 120
#Mixed solvent 44 grams of gasoline
Mixture, pentalyn, acrylate and other monomeric multipolymer, modified EVA resin, tolylene diisocyanate and the mixed solvent of Chinese catalpa oil and oleum lini (dimethylbenzene weight content be mixed solvent 8%) made vacuum metallizing coating through reactions such as alcoholysis (glycerol), esterification, addition, ammonia esterifications.
Embodiment 3
The vacuum metallizing coating of present embodiment, this vacuum metallizing coating of per 100 grams is made by the raw material of following weight:
Tung oil 27 grams
Tetramethylolmethane 4 grams
Maleic anhydride modified rosin ester 15 grams
Vinylformic acid, acrylate and other monomeric multipolymer 5 grams
Polyester polyhydroxylated polymer 1 gram
Both-end carboxyl polyolefine 3 grams
Xylylene diisocyanate 4.5 grams
Dimethylbenzene and 120
#Mixed solvent 40.5 grams of gasoline
Tung oil, maleic anhydride modified rosin ester, vinylformic acid and acrylate and other monomeric multipolymer, polyester polyhydroxylated polymer, both-end carboxyl polyolefine, xylylene diisocyanate and mixed solvent (dimethylbenzene weight content be mixed solvent 2%) are made vacuum metallizing coating through reactions such as alcoholysis (tetramethylolmethane), esterification, addition, ammonia esterifications.
Embodiment 4
The vacuum metallizing coating of present embodiment, this vacuum metallizing coating of per 100 grams is made by the raw material of following weight:
Mixture 21 grams of Thistle oil and Chinese catalpa oil
Glycol ether 4 grams
Maleic anhydride 4 grams
Ester gum 25 grams
Acrylate and other monomeric multipolymer 3 grams
Resins, epoxy 1 gram
Single-ended carboxyl polyolefine 2 grams
'-diphenylmethane diisocyanate 3.5 grams
Dimethylbenzene and 200
#Mixed solvent 36.5 grams of gasoline
The mixture of Thistle oil and Chinese catalpa oil, maleic anhydride, ester gum, acrylate and other monomeric multipolymer, Resins, epoxy, single-ended carboxyl polyolefine, '-diphenylmethane diisocyanate and mixed solvent (dimethylbenzene weight content be mixed solvent 7%) are made vacuum metallizing coating through reactions such as alcoholysis (glycol ether), esterification, addition, ammonia esterifications.
Claims (10)
1. vacuum metallizing coating is characterized in that being made by following weight percentages:
Vegetables oil 20～28%;
Polyvalent alcohol 1～10%;
Acid anhydrides 0～5%;
Rosin ester 12～35%;
Acrylic copolymer 1～5%;
Polyhydroxylated polymer 0.1～3%;
Modified polyolefin 0～5%;
Isocyanic ester 2～4.5%;
Mixed solvent 35～60%.
2. vacuum metallizing coating according to claim 1 is characterized in that: described vegetables oil be selected from Thistle oil, Chinese catalpa oil, oleum lini, tung oil, and composition thereof.
3. vacuum metallizing coating according to claim 1 is characterized in that: described polyvalent alcohol is ethylene glycol, glycerol, TriMethylolPropane(TMP), tetramethylolmethane or glycol ether.
4. vacuum metallizing coating according to claim 1 is characterized in that: described acid anhydrides is maleic anhydride, benzoyl oxide, trimellitic acid 1,2-anhydride or Succinic anhydried.
5. vacuum metallizing coating according to claim 1 is characterized in that: described rosin ester is ester gum, pentalyn or maleic anhydride modified rosin ester.
6. vacuum metallizing coating according to claim 1 is characterized in that: described acrylic copolymer is vinylformic acid and other monomeric multipolymer, or acrylate and other monomeric multipolymer, or vinylformic acid, acrylate and other monomeric multipolymer.
7. vacuum metallizing coating according to claim 1 is characterized in that: described polyhydroxylated polymer is modified EVA resin, polyester polyhydroxylated polymer, Resins, epoxy or polyvinyl alcohol.
8. vacuum metallizing coating according to claim 1 is characterized in that: described modified polyolefin is single-ended carboxyl polyolefine, both-end carboxyl polyolefine or polyolefine grafts.
9. vacuum metallizing coating according to claim 1 is characterized in that: described isocyanic ester is '-diphenylmethane diisocyanate, xylylene diisocyanate, tolylene diisocyanate or methylene radical polyphenyl polyisocyanate.
10. vacuum metallizing coating according to claim 1 is characterized in that: described mixed solvent is dimethylbenzene and 200
#Gasoline and/or 120
#Gasoline and/or terebinthine mixture, wherein the weight content of dimethylbenzene is 1～10% of a mixed solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100344683A CN1323122C (en) | 2005-05-09 | 2005-05-09 | Vacuum plating film coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100344683A CN1323122C (en) | 2005-05-09 | 2005-05-09 | Vacuum plating film coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1693396A true CN1693396A (en) | 2005-11-09 |
| CN1323122C CN1323122C (en) | 2007-06-27 |
Family
ID=35352528
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100344683A Expired - Fee Related CN1323122C (en) | 2005-05-09 | 2005-05-09 | Vacuum plating film coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1323122C (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100374614C (en) * | 2005-12-05 | 2008-03-12 | 中国化工建设总公司常州涂料化工研究院 | Paint for vacuum film coating and its preparation method |
| CN101182405B (en) * | 2007-12-13 | 2011-09-14 | 华南理工大学 | Preparation method of dual-component aqueous polyurethane adhesive agent |
| WO2013092539A1 (en) * | 2011-12-21 | 2013-06-27 | Akzo Nobel Coatings International B.V. | Water-based coating compositions |
| WO2013092541A1 (en) * | 2011-12-21 | 2013-06-27 | Akzo Nobel Coatings International B.V. | Solvent-based coating compositions |
| CN104559746A (en) * | 2014-12-31 | 2015-04-29 | 武汉工程大学 | Vacuum gold-plated primer |
| US9133292B2 (en) | 2009-03-05 | 2015-09-15 | Akzo Nobel Coatings International B.V. | Hydroxyl functional oil polyol acrylic graft copolymers |
| CN105238267A (en) * | 2015-10-27 | 2016-01-13 | 江门市国美化工有限公司 | Stain-removing and furniture-servicing film plating oil and preparation method therefor |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3658298B2 (en) * | 2000-08-24 | 2005-06-08 | 大日本インキ化学工業株式会社 | Printing ink composition |
| CN1156545C (en) * | 2002-04-30 | 2004-07-07 | 姚惠渥 | Nontoxic pollution-free polystyrene paint and its preparing process |
-
2005
- 2005-05-09 CN CNB2005100344683A patent/CN1323122C/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100374614C (en) * | 2005-12-05 | 2008-03-12 | 中国化工建设总公司常州涂料化工研究院 | Paint for vacuum film coating and its preparation method |
| CN101182405B (en) * | 2007-12-13 | 2011-09-14 | 华南理工大学 | Preparation method of dual-component aqueous polyurethane adhesive agent |
| US9133292B2 (en) | 2009-03-05 | 2015-09-15 | Akzo Nobel Coatings International B.V. | Hydroxyl functional oil polyol acrylic graft copolymers |
| WO2013092541A1 (en) * | 2011-12-21 | 2013-06-27 | Akzo Nobel Coatings International B.V. | Solvent-based coating compositions |
| CN104024293A (en) * | 2011-12-21 | 2014-09-03 | 阿克佐诺贝尔国际涂料股份有限公司 | Water-based coating compositions |
| WO2013092539A1 (en) * | 2011-12-21 | 2013-06-27 | Akzo Nobel Coatings International B.V. | Water-based coating compositions |
| US9260625B2 (en) | 2011-12-21 | 2016-02-16 | Akzo Nobel Coatings International B.V. | Water-based coating compositions |
| US9273226B2 (en) | 2011-12-21 | 2016-03-01 | Akzo Nobel Coatings International B.V. | Solvent-based coating compositions |
| CN104024293B (en) * | 2011-12-21 | 2016-08-17 | 阿克佐诺贝尔国际涂料股份有限公司 | Water base paint compositions |
| RU2606632C2 (en) * | 2011-12-21 | 2017-01-10 | Акцо Нобель Коатингс Интернэшнл Б.В. | Water-based coating compositions |
| CN104559746A (en) * | 2014-12-31 | 2015-04-29 | 武汉工程大学 | Vacuum gold-plated primer |
| CN105238267A (en) * | 2015-10-27 | 2016-01-13 | 江门市国美化工有限公司 | Stain-removing and furniture-servicing film plating oil and preparation method therefor |
| CN105238267B (en) * | 2015-10-27 | 2017-11-14 | 江门市国美化工有限公司 | A kind of plated film oil for removing spot and maintaining furniture and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1323122C (en) | 2007-06-27 |
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