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CN1651910A - Capacitive relative humidity sensor - Google Patents

Capacitive relative humidity sensor Download PDF

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Publication number
CN1651910A
CN1651910A CN 200510037809 CN200510037809A CN1651910A CN 1651910 A CN1651910 A CN 1651910A CN 200510037809 CN200510037809 CN 200510037809 CN 200510037809 A CN200510037809 A CN 200510037809A CN 1651910 A CN1651910 A CN 1651910A
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capacitor
polar plate
humidity sensor
upper plate
relative humidity
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CN1278120C (en
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彭韶华
黄庆安
秦明
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Southeast University
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Southeast University
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Abstract

The present invention discloses a capacitive relative humidity sensor for microelectronic mechanical system. It is formed from substrate, capacitor upper polar plate and capacitor lower polar plate. Said capacitor lower polar plate is placed on the substrate, said capacitor upper polar plate is positioned over the capacitor lower polar plate, in the area outside of capacitor upper polar plate projection an oxide layer is set, and on the oxide layer the leads of capacitor upper polar plate and capacitor lower polar plate are set, and on the capacitor upper polar plate a humidity-sensing medium layer is set. Said invention has the advantage of providing deformation space for movable upper polar plate.

Description

电容式相对湿度传感器Capacitive relative humidity sensor

                              技术领域Technical field

本发明涉及一种相对湿度传感器,尤其是一种微电子机械系统的电容式相对湿度传感器。The invention relates to a relative humidity sensor, in particular to a capacitive relative humidity sensor of a micro-electromechanical system.

                              背景技术 Background technique

湿度测量在工农业生产、气象、环保、国防、科研、航空等部门都有重要的应用。湿度传感器作为湿度测量系统中重要的组成部分,已经发展了很多年。由最初的毛发计和干湿球湿度计发展到能够输出电信号的LiCl电解质湿度传感器。发展过程中出现了电解质湿度传感器,陶瓷湿度传感器,半导体结型及MOS型湿度传感器和新兴的高分子湿度传感器。基于MEMS技术的微型湿度传感器具有体积小,价格低,产品一致性好的特点,是近几年来湿度传感器研究的热点。1997年,Buchhold提出了利用MEMS技术制造压阻式湿度传感器,该湿度传感器为一可动敏感膜,膜上覆盖一层吸湿聚合物,当外界湿度变化,聚合物发生胀缩,从而带动可动膜发生形变,最终引起膜四边压敏电阻的阻值变化。电阻固有的较大的温度漂移特性使得其在温度变化很大的应用领域内有局限性。2002年Chatzandroulis利用硅微机械加工工艺制造了悬臂梁结构的湿度传感器,悬臂梁上覆盖了吸湿物质,当吸湿物质吸收了环境湿度后发生膨胀产生应力,并且重量增加,使得悬臂梁弯曲,从而使得悬臂梁与衬底间的电容发生变化。该传感器是电容式因此温度漂移较小,但是由于其存在一端固定的悬臂梁结构,可靠性比较差,并且悬臂梁在释放过程中由于残余应力的作用会发生不同程度的翘曲,产品一致性差。Humidity measurement has important applications in industrial and agricultural production, meteorology, environmental protection, national defense, scientific research, aviation and other departments. As an important part of the humidity measurement system, the humidity sensor has been developed for many years. From the initial hair meter and dry wet bulb hygrometer to the LiCl electrolyte humidity sensor that can output electrical signals. Electrolyte humidity sensor, ceramic humidity sensor, semiconductor junction type and MOS type humidity sensor and emerging polymer humidity sensor appeared in the development process. The miniature humidity sensor based on MEMS technology has the characteristics of small size, low price and good product consistency, and it is a hot spot in the research of humidity sensors in recent years. In 1997, Buchhold proposed the use of MEMS technology to manufacture a piezoresistive humidity sensor. The humidity sensor is a movable sensitive film covered with a layer of hygroscopic polymer. When the external humidity changes, the polymer expands and contracts, thereby driving the movable sensor. The membrane deforms, which eventually causes the resistance value of the piezoresistor on the four sides of the membrane to change. The inherent large temperature drift characteristics of resistors have limitations in applications where the temperature changes greatly. In 2002, Chatzandroulis used the silicon micromachining process to manufacture a humidity sensor with a cantilever beam structure. The cantilever beam is covered with a hygroscopic material. When the hygroscopic material absorbs the ambient humidity, it expands and generates stress, and the weight increases, causing the cantilever beam to bend. The capacitance between the cantilever and the substrate changes. The sensor is capacitive, so the temperature drift is small, but because of the cantilever beam structure with one end fixed, the reliability is relatively poor, and the cantilever beam will warp to varying degrees due to the residual stress during the release process, resulting in poor product consistency. .

                              发明内容Contents of Invention

本发明提供一种用于微电子机械系统的温漂小的电容式相对湿度传感器,本发明同时具有灵敏度高,和可靠性好的优点。The invention provides a capacitive relative humidity sensor with small temperature drift for micro-electromechanical systems. The invention has the advantages of high sensitivity and good reliability at the same time.

本发明采用如下技术方案:The present invention adopts following technical scheme:

一种用于微电子机械系统的电容式相对湿度传感器,由衬底、电容下极板和电容上极板组成,电容下极板设在衬底上,电容上极板位于电容下极板的上方,在电容上极板的电容上极板投影以外的区域设有氧化层,氧化层上设有电容上、下极板引线,在电容上极板上设有感湿介质层,其特征在于电容上极板通过其固定在氧化层上的四个方形锚区加连杆进行支撑。A capacitive relative humidity sensor for microelectromechanical systems, consisting of a substrate, a capacitor lower plate and a capacitor upper plate, the capacitor lower plate is arranged on the substrate, and the capacitor upper plate is located at the bottom of the capacitor On the top, an oxide layer is provided on the area other than the projection of the upper plate of the capacitor on the upper plate of the capacitor, the lead wires of the upper and lower plates of the capacitor are arranged on the oxide layer, and a moisture-sensitive medium layer is provided on the upper plate of the capacitor, which is characterized in that The upper plate of the capacitor is supported by four square anchor areas and connecting rods fixed on the oxide layer.

与现有技术相比,本发明具有如下优点:Compared with prior art, the present invention has following advantage:

本发明是用于感知环境湿度信号的可动薄膜电容式湿度传感器,由电容上下极板和连接电极板的引线组成。电容上极板为一可动薄膜,下极板为固定电极,上极板上覆盖一层吸湿物质,当环境湿度发生变化时,引起吸湿物质膨胀或收缩,从而带动电容上极板产生形变,从而引起电容值的变化。在电容上极板下方设有空腔,为可动上极板提供形变空间。The invention is a movable thin-film capacitive humidity sensor used for sensing environmental humidity signals, which consists of upper and lower capacitor plates and lead wires connecting the electrode plates. The upper plate of the capacitor is a movable film, the lower plate is a fixed electrode, and the upper plate is covered with a layer of hygroscopic material. When the ambient humidity changes, the hygroscopic material expands or contracts, thereby driving the deformation of the upper plate of the capacitor. This causes a change in capacitance value. A cavity is provided under the upper pole plate of the capacitor to provide a deformation space for the movable upper pole plate.

本发明可采用标准CMOS工艺与MEMS加工技术相结合进行制造,精度高,长期可靠性好。本发明中上极板下方的空腔是通过键合技术形成的,而传统工艺中一般采用先淀积LTO(低温二氧化硅)或PSG(磷掺杂的二氧化硅)作为牺牲层,然后释放牺牲层形成空腔,对于面积比较大的空腔这往往会造成被释放出来的结构与空腔底部粘连,使得器件失效,本发明采用键合技术将克服这一缺陷,大大增强了传感器的可靠性。上极板为四角固定的可动薄膜,整个上极板靠四个固定角进行支撑,与四边固定的薄膜相比,其灵敏度大为提高,并且可动薄膜四边悬空,并不与氧化层接触,这样可以有效降低边缘寄生电容。本传感器前端采用标准CMOS工艺,后端采用体加工技术,并且并不影响前端的IC工艺加工。保证了IC工艺的兼容性,有利于传感器的批量生产。后端体加工有利于增强可动薄膜的可靠性与强度,增大可动薄膜面积可以有效提高湿度敏感电容的变化量。本发明提出的基于MEMS技术制造的电容式湿度传感器有效提高了灵敏度和可靠性,温漂小,适用于环境相对湿度的高精度测量。The invention can be manufactured by combining standard CMOS technology and MEMS processing technology, and has high precision and good long-term reliability. In the present invention, the cavity below the upper plate is formed by bonding technology, while generally adopting to deposit LTO (low temperature silicon dioxide) or PSG (phosphorus-doped silicon dioxide) as a sacrificial layer in the traditional process, and then Release the sacrificial layer to form a cavity. For a cavity with a relatively large area, this will often cause the released structure to stick to the bottom of the cavity, making the device invalid. The bonding technology used in the present invention will overcome this defect and greatly enhance the performance of the sensor. reliability. The upper plate is a movable film with four corners fixed, and the whole upper plate is supported by four fixed corners. Compared with the film with four fixed sides, its sensitivity is greatly improved, and the four sides of the movable film are suspended and do not contact the oxide layer. , which can effectively reduce the edge parasitic capacitance. The front end of the sensor adopts standard CMOS technology, and the back end adopts body processing technology, which does not affect the IC process processing of the front end. The compatibility of the IC process is guaranteed, which is beneficial to the mass production of the sensor. The processing of the back-end body is beneficial to enhance the reliability and strength of the movable film, and increasing the area of the movable film can effectively increase the variation of the humidity-sensitive capacitance. The capacitive humidity sensor manufactured based on the MEMS technology proposed by the present invention effectively improves sensitivity and reliability, has small temperature drift, and is suitable for high-precision measurement of environmental relative humidity.

                        附图说明Description of drawings

图1是本发明的结构示意图。Fig. 1 is a structural schematic diagram of the present invention.

图2是本发明的俯视图。Figure 2 is a top view of the present invention.

图3是本发明的截面图。Fig. 3 is a cross-sectional view of the present invention.

                      具体实施方式 Detailed ways

一种用于微电子机械系统的电容式相对湿度传感器,由衬底1、电容下极板2和电容上极板5组成,电容下极板2设在衬底1上,电容上极板5位于电容下极板2的上方,在电容上极板5的电容上极板5投影以外的区域设有氧化层3,氧化层3上设有电容上、下极板引线41、42,在电容上极板5上设有感湿介质层,电容上极板5通过连杆固定在氧化层3上的四个方形锚区,在本实施例中,电容上极板5通过四个角固定在氧化层3上,感湿介质层为聚酰亚胺层。本实施例中衬底1为体硅,电容下极板2为磷重掺杂区,氧化层3为二氧化硅,电容上极板5为硼重掺杂区,电容上下极板引线41和42为铝。本发明可以用以下工艺来制作:准备两块硅片1#和2#。对硅片1#,在衬底1上进行磷离子注入,形成电容下极板2;CVD法淀积二氧化硅层3,对氧化层3进行光刻,形成供电容上极板运动的空腔和电容下极板引线通孔。对硅片2#进行硼离子注入,形成一导电层;将硅片1#带有腐蚀图形的面与硅片2#硼离子注入面进行键合;然后对硅片2#通过化学机械抛光和湿法腐蚀进行减薄,最后只剩下硼离子注入层;通过干法刻蚀形成电容上极板5,蒸铝并光刻形成电容上下极板引线41和42,利用旋转涂敷法涂一层聚酰亚胺,并光刻形成感湿介质层6,最后对聚酰亚胺进行亚胺化。本发明的感湿介质层6由于外界环境相对湿度的变化,吸附/脱附空气中的水气分子,使得感湿介质层6的体积发生膨胀或收缩,带动电容上极板5发生形变,电容上极板5和电容下极板2之间的电容值发生改变,环境相对湿度增大,感湿介质层6吸附水气分子,体积膨胀带动电容上极板向下弯曲,电容上极板5和电容下极板2之间的电容值增大。A capacitive relative humidity sensor for microelectromechanical systems, consisting of a substrate 1, a capacitor lower plate 2 and a capacitor upper plate 5, the capacitor lower plate 2 is set on the substrate 1, and the capacitor upper plate 5 Located above the capacitor lower plate 2, an oxide layer 3 is provided on the capacitor upper plate 5 outside the projection of the capacitor upper plate 5, and the oxide layer 3 is provided with capacitor upper and lower plate leads 41, 42. The upper pole plate 5 is provided with a moisture-sensitive medium layer, and the upper pole plate 5 of the capacitor is fixed on the four square anchor areas on the oxide layer 3 through connecting rods. In this embodiment, the upper pole plate 5 of the capacitor is fixed on the four corners of the On the oxide layer 3, the moisture-sensitive medium layer is a polyimide layer. In this embodiment, the substrate 1 is bulk silicon, the lower electrode plate 2 of the capacitor is a heavily phosphorus-doped region, the oxide layer 3 is silicon dioxide, the upper electrode plate 5 of the capacitor is a heavily boron-doped region, and the upper and lower capacitor plate leads 41 and 42 is aluminum. The present invention can be made with following technology: prepare two silicon wafers 1# and 2#. For silicon wafer 1#, phosphorus ion implantation is carried out on the substrate 1 to form the lower plate 2 of the capacitor; a silicon dioxide layer 3 is deposited by CVD, and photolithography is performed on the oxide layer 3 to form a space for the movement of the upper plate of the capacitor. cavity and capacitor bottom plate lead through hole. Carry out boron ion implantation to silicon wafer 2#, form a conductive layer; Silicon wafer 1# is bonded with the surface of silicon wafer 2# boron ion implanted surface with corrosion pattern; Then silicon wafer 2# is polished by chemical mechanical polishing and Thinning by wet etching, and finally only the boron ion implantation layer is left; the upper plate 5 of the capacitor is formed by dry etching, the upper and lower plate leads 41 and 42 of the capacitor are formed by steaming aluminum and photolithography, and a Layer polyimide, and photolithographically form the moisture-sensitive medium layer 6, and finally imidize the polyimide. Due to changes in the relative humidity of the external environment, the moisture-sensing medium layer 6 of the present invention absorbs/desorbs moisture molecules in the air, causing the volume of the moisture-sensing medium layer 6 to expand or shrink, which drives the capacitor upper plate 5 to deform, and the capacitor The capacitance value between the upper plate 5 and the lower plate 2 of the capacitor changes, the relative humidity of the environment increases, the moisture-sensitive medium layer 6 absorbs water vapor molecules, the volume expansion drives the upper plate of the capacitor to bend downward, and the upper plate of the capacitor 5 and the capacitance value between the lower plate 2 of the capacitor increases.

Claims (3)

1、一种用于微电子机械系统的电容式相对湿度传感器,由衬底(1)、电容下极板(2)和电容上极板(5)组成,电容下极板(2)设在衬底(1)上,电容上极板(5)位于电容下极板(2)的上方,在电容上极板(5)的电容上极板(5)投影以外的区域设有氧化层(3),氧化层(3)上设有电容上、下极板引线(41、42),在电容上极板(5)上设有感湿介质层,其特征在于电容上极板(5)通过其固定在氧化层(3)上的四个方形锚区加连杆进行支撑。1. A capacitive relative humidity sensor for MEMS, consisting of a substrate (1), a capacitor lower plate (2) and a capacitor upper plate (5), the capacitor lower plate (2) is located at On the substrate (1), the capacitor upper plate (5) is located above the capacitor lower plate (2), and an oxide layer ( 3), the oxide layer (3) is provided with capacitor upper and lower plate leads (41, 42), and a moisture-sensitive medium layer is provided on the capacitor upper plate (5), which is characterized in that the capacitor upper plate (5) It is supported by four square anchor areas and connecting rods fixed on the oxide layer (3). 2、根据权利要求1所述的电容式相对湿度传感器,其特征在于电容上极板(5)通过连杆固定在氧化层(3)上的四个方形锚区。2. The capacitive relative humidity sensor according to claim 1, characterized in that the capacitive upper plate (5) is fixed to four square anchor areas on the oxide layer (3) through connecting rods. 3、根据权利要求1或2所述的电容式相对湿度传感器,其特征在于感湿介质层为聚酰亚胺层。3. The capacitive relative humidity sensor according to claim 1 or 2, characterized in that the moisture-sensing medium layer is a polyimide layer.
CN 200510037809 2005-02-23 2005-02-23 Capacitance type relative moisture sensor Expired - Fee Related CN1278120C (en)

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CN1278120C CN1278120C (en) 2006-10-04

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101932928B (en) * 2007-10-26 2013-02-13 霍尼韦尔国际公司 Improved structure for capacitive balancing of integrated relative humidity sensor
US10585058B2 (en) 2016-05-13 2020-03-10 Honeywell International Inc. FET based humidity sensor with barrier layer protecting gate dielectric
US10677747B2 (en) 2015-02-17 2020-06-09 Honeywell International Inc. Humidity sensor
CN112461887A (en) * 2021-01-25 2021-03-09 南京高华科技股份有限公司 Humidity sensor based on MEMS structure

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101932928B (en) * 2007-10-26 2013-02-13 霍尼韦尔国际公司 Improved structure for capacitive balancing of integrated relative humidity sensor
US10677747B2 (en) 2015-02-17 2020-06-09 Honeywell International Inc. Humidity sensor
US10585058B2 (en) 2016-05-13 2020-03-10 Honeywell International Inc. FET based humidity sensor with barrier layer protecting gate dielectric
CN112461887A (en) * 2021-01-25 2021-03-09 南京高华科技股份有限公司 Humidity sensor based on MEMS structure
CN112461887B (en) * 2021-01-25 2021-04-20 南京高华科技股份有限公司 Humidity sensor based on MEMS structure

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