CN1629663A - Silicon-on-insulator ridge optical waveguide with new cross-sectional shape and its manufacturing method - Google Patents
Silicon-on-insulator ridge optical waveguide with new cross-sectional shape and its manufacturing method Download PDFInfo
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- 238000001039 wet etching Methods 0.000 claims abstract description 10
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- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 6
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052814 silicon oxide Inorganic materials 0.000 abstract description 5
- 230000008878 coupling Effects 0.000 abstract description 4
- 238000010168 coupling process Methods 0.000 abstract description 4
- 238000005859 coupling reaction Methods 0.000 abstract description 4
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- 229910052794 bromium Inorganic materials 0.000 description 1
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Abstract
本发明涉及光波导技术领域,特别是一种新截面形状的绝缘体上硅脊形光波导及其制作方法。该波导的脊形部分截面形状由一个矩形顶部和一个等腰梯形底部构成,波导对光的下限制层为绝缘层,波导的上表面由硅的氧化物和/或者氮化物覆盖。其制作方法包括:a.在SOI晶片上,通过光刻工艺制作光波导的掩膜;b.在顶层硅上用干法刻蚀一个截面为矩形的脊形波导;c.在原掩膜的基础上,用湿法刻蚀对矩形脊波导进行二次刻蚀;d.去除掩膜,在脊形波导上覆盖氧化物和/或者氮化物层。本发明的结构、制作相对简单、刻蚀表面光滑无损伤无聚合物残留、耦合效率相对较高,可以改善波导的光学性能和电学性能。
The invention relates to the field of optical waveguide technology, in particular to a silicon-on-insulator ridge-shaped optical waveguide with a new cross-sectional shape and a manufacturing method thereof. The cross-sectional shape of the ridge part of the waveguide is composed of a rectangular top and an isosceles trapezoidal bottom, the lower light limiting layer of the waveguide is an insulating layer, and the upper surface of the waveguide is covered by silicon oxide and/or nitride. Its manufacturing method includes: a. On the SOI wafer, the mask of the optical waveguide is made by photolithography; b. On the top layer of silicon, a ridge waveguide with a rectangular cross section is etched by dry method; c. On the basis of the original mask above, performing secondary etching on the rectangular ridge waveguide by wet etching; d. removing the mask, and covering the ridge waveguide with an oxide and/or nitride layer. The structure and manufacture of the invention are relatively simple, the etching surface is smooth without damage and polymer residue, the coupling efficiency is relatively high, and the optical performance and electrical performance of the waveguide can be improved.
Description
技术领域technical field
本发明涉及光波导技术领域,特别是一种新截面形状的绝缘体上硅(SOI,silicon-on-insulator)脊形光波导及其制作方法,可以应用在单多模SOI光波导以及SOI波导器件的制作中。The invention relates to the field of optical waveguide technology, in particular to a silicon-on-insulator (SOI, silicon-on-insulator) ridge optical waveguide with a new cross-sectional shape and a manufacturing method thereof, which can be applied to single-multimode SOI optical waveguides and SOI waveguide devices in the making.
背景技术Background technique
当前光器件的研究朝着材料、结构多元化的方向发展,其中硅基集成光学始终是人们研究的一个重要方向。SOI材料可用于制作高速CMOS器件,同时SOI材料的工艺十分成熟,顶层硅膜的厚度不受限制,可以制作各种尺寸的SOI光波导,SOI光波导工艺具有与CMOS电路工艺兼容的特点,因此SOI材料十分适合制作光电混合集成芯片。近年来各种SOI基光无源器件,例如SOI材料的波导耦合器、波导电光调制器、电/热光开关、AWG等光器件获得了越来越多的关注。而SOI基光波导是这些器件以及实现硅基集成光学互联的基础,设计和制作性能优良的SOI光波导具有十分重要的意义。SOI光波导通常采用湿法刻蚀或干法刻蚀制作,湿法刻蚀多采用各向异性的溶液进行刻蚀,可以得到如图1所示截面为梯形的波导,包括梯形截面的脊形波导1和绝缘层2,以及硅衬底3,波导侧壁和底面都比较光滑,刻蚀表面无损伤层,刻蚀残留物也很少。但湿法刻蚀得到的梯形截面的SOI脊形波导(一般为利用湿法在{100}硅片上沿<110>晶向光刻,此时刻蚀侧面是{111}面,{111}面和{100}面的夹角θ为54.74°)构成的一些光学器件,例如SOI材料的AWG,很难获得好的偏振相关损耗性能。干法刻蚀各向异性好,刻蚀速率与晶向无关,可以得到如图2所示矩形截面的脊形波导,包括矩形截面的脊形波导4和绝缘层2,以及硅衬底3,偏振不敏感,但是侧壁和底面的粗糙度要比湿法刻蚀的高很多,而刻蚀表面的粗糙度会对光的传输特性产生直接的影响,同时矩形截面的SOI单模波导在波导参数相近的情况下,与单模光纤耦合效率比梯形截面形状的SOI光波导略低。干法刻蚀必然在刻蚀表面形成一层或薄或厚的损伤层,在采取某些溴基或含碳氟基气体进行刻蚀时,刻蚀表面还会存在一薄层聚合物,这会对器件的光学和电学性都产生不好的影响。另外在制作一些波导器件时,例如制作热光或电光SOI开关时,如果波导侧壁底角处过于陡直,不利于电极的攀爬,电极很容易被烧毁,导致器件失效。The current research on optical devices is developing in the direction of diversification of materials and structures, and silicon-based integrated optics has always been an important research direction. SOI materials can be used to make high-speed CMOS devices. At the same time, the technology of SOI materials is very mature. The thickness of the top silicon film is not limited, and SOI optical waveguides of various sizes can be produced. The SOI optical waveguide process is compatible with CMOS circuit technology. Therefore, SOI materials are very suitable for making photoelectric hybrid integrated chips. In recent years, various SOI-based optical passive devices, such as waveguide couplers made of SOI materials, waveguided optical modulators, electro/thermo-optical switches, and AWGs, have gained more and more attention. SOI-based optical waveguides are the basis of these devices and the realization of silicon-based integrated optical interconnection, so it is of great significance to design and manufacture SOI-based optical waveguides with excellent performance. SOI optical waveguides are usually produced by wet etching or dry etching. Wet etching usually uses anisotropic solution for etching, and a waveguide with a trapezoidal cross-section can be obtained as shown in Figure 1, including ridges with a trapezoidal cross-section. The waveguide 1, the
发明内容Contents of the invention
本发明的目的在于提供一种结构、制作相对简单、刻蚀表面光滑无损伤无聚合物残留、耦合效率相对较高的SOI新截面形状的光波导,以改善波导的光学性能和电学性能。The object of the present invention is to provide a SOI optical waveguide with a new cross-sectional shape with relatively simple structure, smooth etched surface, no damage and no polymer residue, and relatively high coupling efficiency, so as to improve the optical and electrical properties of the waveguide.
为达到上述目的,本发明的技术解决方案是提供一种新截面形状的SOI脊形光波导,其结构包括:一硅衬底,一层在硅衬底顶上的氧化物层,以及一层在氧化物顶层上的单晶硅层,其中氧化物顶层上的硅层上有一脊形光波导,其波导的脊形部分截面形状由一个矩形顶部和一个等腰梯形底部构成,波导对光的下限制层为绝缘层,而波导的上表面由硅的氧化物或者氮化物覆盖。In order to achieve the above object, the technical solution of the present invention is to provide a kind of SOI ridge optical waveguide of new cross-sectional shape, and its structure comprises: a silicon substrate, one layer of oxide layer on the silicon substrate top, and a layer A single crystal silicon layer on the top layer of oxide, wherein there is a ridge-shaped optical waveguide on the silicon layer on the top oxide layer, and the cross-sectional shape of the ridge part of the waveguide is composed of a rectangular top and an isosceles trapezoidal bottom. The lower confinement layer is an insulating layer, and the upper surface of the waveguide is covered by silicon oxide or nitride.
所述的硅光波导,其所述脊形波导的矩形部分的高和梯形部分的高,占脊形总高度的比例可以改变。In the silicon optical waveguide, the ratio of the height of the rectangular portion and the height of the trapezoidal portion of the ridge waveguide to the total height of the ridge can be changed.
所述的硅光波导,其所述等腰梯形的底角为54.74°。In the silicon optical waveguide, the base angle of the isosceles trapezoid is 54.74°.
一种新截面形状的绝缘体上硅光波导的制作方法,其包括以下步骤:A method for fabricating a silicon-on-insulator optical waveguide with a new cross-sectional shape, comprising the following steps:
a.在SOI晶片上,通过光刻工艺,在顶层{100}硅晶面上制作沿<110>晶向的光波导掩膜;a. On the SOI wafer, an optical waveguide mask along the <110> crystal direction is fabricated on the top {100} silicon crystal surface through a photolithography process;
b.在顶层硅上用干法刻蚀一个截面为矩形的脊形波导;b. Dry etching a ridge waveguide with a rectangular cross-section on the top silicon;
c.在原掩膜的基础上,用湿法刻蚀对矩形脊波导进行二次刻蚀;c. On the basis of the original mask, the rectangular ridge waveguide is etched twice by wet etching;
d.去除掩膜,在脊形波导上覆盖氧化物和/或者氮化物层,作为波导上包层。d. Remove the mask, and cover the ridge waveguide with an oxide and/or nitride layer as an upper cladding layer of the waveguide.
所述的方法,其绝缘层上的硅层为{100}硅晶面,干法刻蚀方向沿<100>晶向。In the method, the silicon layer on the insulating layer is a {100} silicon crystal plane, and the dry etching direction is along the <100> crystal direction.
所述的方法,其用湿法对脊形波导进行二次刻蚀时,所用湿法刻蚀溶液为各向异性刻蚀溶液,所得到的梯形波导的侧面为{111}面,{111}面与{100}面的夹角为54.74°。In the method described above, when the ridge waveguide is etched twice by a wet method, the wet etching solution used is an anisotropic etching solution, and the side surfaces of the obtained trapezoidal waveguide are {111} planes, {111} The angle between the plane and the {100} plane is 54.74°.
所述的方法,其所述掩膜,材料可以采用金属和/或硅的氧化物和/或者硅的氮化物。The method, the mask, and the material can be metal and/or silicon oxide and/or silicon nitride.
所述的方法,其根据掩膜材料的不同,可以采用不同的各向异性湿法刻蚀溶液。According to the method, different anisotropic wet etching solutions can be used according to different mask materials.
所述的方法,其通过改变干法和湿法的刻蚀参数和刻蚀时间,可以改变脊形波导的矩形部分的高和梯形部分的高占脊形总高度的比例。In the method, by changing the etching parameters and etching time of the dry method and the wet method, the ratio of the height of the rectangular part of the ridge waveguide and the height of the trapezoidal part to the total height of the ridge can be changed.
本发明采用干湿法结合的方法,可以获得截面形状如附图3所示的SOI脊形光波导,对于现有技术存在的问题进行了解决或改善。The present invention adopts the dry-wet combination method to obtain the SOI ridge optical waveguide whose cross-sectional shape is shown in Fig. 3 , which solves or improves the problems existing in the prior art.
本发明的结构、制作相对简单、刻蚀表面光滑、无损伤、无聚合物残留、耦合效率相对较高,利于电极的攀爬,可以改善波导的光学性能和光波导器件的电学性能。The invention has relatively simple structure and manufacture, smooth etched surface, no damage, no polymer residue, relatively high coupling efficiency, is conducive to electrode climbing, and can improve the optical performance of the waveguide and the electrical performance of the optical waveguide device.
附图说明Description of drawings
图1常规各向异性湿法刻蚀波导截面示意图;Fig. 1 Schematic diagram of a conventional anisotropic wet-etched waveguide section;
图2常规干法刻蚀波导截面示意图;Fig. 2 Schematic diagram of conventional dry etching waveguide section;
图3本发明干湿法结合获得的波导截面示意图;Fig. 3 is a schematic diagram of a cross section of a waveguide obtained by combining dry and wet methods in the present invention;
图4-7为本发明工艺实施步骤示意图。4-7 are schematic diagrams of the implementation steps of the process of the present invention.
具体实施方式Detailed ways
如图4所示,首先通过光刻工艺在包括硅衬底3、绝缘层2的SOI材料的顶层{100}硅薄层8上制作沿<110>方向的光波导掩膜9,掩膜材料可以采用金属、硅的氧化物、硅的氮化物,然后通过干法刻蚀工艺沿<100>晶向刻蚀,获得如图5所示的截面形状为矩形的脊形波导10,所得矩形波导的侧壁为{110}晶面。根据采用掩膜材料的不同采用不同的刻蚀溶液或者改变溶液的配比,在干法刻蚀基础上进行二次刻蚀,在二次刻蚀的过程中由于采用了各向异性的刻蚀溶液,矩形波导的侧壁受到刻蚀,宽度变小,同时刻蚀向下进行,得到如图6所示的梯形波导11,其侧壁为{111}晶面。θ角是{100}面和{111}面的夹角,为54.74°。得到如图6所示截面形状的波导后,去除掩膜9,在波导上表面覆盖上硅的氧化物和/或氮化物层7,如图7所示。在波导制作过程中,通过改变干法和湿法刻蚀的刻蚀参数和刻蚀时间,可以获得不同矩形高和梯形波导高比例的脊形波导。As shown in FIG. 4, firstly, an
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN100406934C (en) * | 2005-08-04 | 2008-07-30 | 浙江大学 | A deep-etched silica ridge waveguide and its preparation process |
CN100430764C (en) * | 2005-11-18 | 2008-11-05 | 中国科学院半导体研究所 | A photonic crystal beam splitter based on SOI and its manufacturing method |
CN102096149A (en) * | 2011-01-19 | 2011-06-15 | 浙江大学 | Silicon-based long-wave infrared waveguide and preparation method thereof |
CN102540336A (en) * | 2010-12-24 | 2012-07-04 | 苏州东微半导体有限公司 | Manufacture method for planar lightwave circuit (PLC) light device |
CN101499552B (en) * | 2008-02-01 | 2013-01-02 | 南京理工大学 | Wideband substrate integrated ridge waveguide and analyzing method thereof |
CN105731352A (en) * | 2016-03-01 | 2016-07-06 | 南京大学 | On-chip integrated arsenic sulfide microdisk cavity and method for manufacturing same |
CN108254829A (en) * | 2018-01-04 | 2018-07-06 | 华南师范大学 | A kind of design method of the vertical pattern converter of double, asymmetrical |
CN110709775A (en) * | 2017-07-12 | 2020-01-17 | 应用材料公司 | Method for producing high refractive index waveguide |
CN112596158A (en) * | 2020-12-22 | 2021-04-02 | 浙江大学绍兴微电子研究中心 | Silicon-based magneto-optical nonreciprocal ridge optical waveguide |
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2003
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
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CN100406934C (en) * | 2005-08-04 | 2008-07-30 | 浙江大学 | A deep-etched silica ridge waveguide and its preparation process |
CN100430764C (en) * | 2005-11-18 | 2008-11-05 | 中国科学院半导体研究所 | A photonic crystal beam splitter based on SOI and its manufacturing method |
CN101499552B (en) * | 2008-02-01 | 2013-01-02 | 南京理工大学 | Wideband substrate integrated ridge waveguide and analyzing method thereof |
CN102540336A (en) * | 2010-12-24 | 2012-07-04 | 苏州东微半导体有限公司 | Manufacture method for planar lightwave circuit (PLC) light device |
CN102096149A (en) * | 2011-01-19 | 2011-06-15 | 浙江大学 | Silicon-based long-wave infrared waveguide and preparation method thereof |
CN102096149B (en) * | 2011-01-19 | 2012-08-15 | 浙江大学 | Silicon-based long-wave infrared waveguide and preparation method thereof |
CN105731352A (en) * | 2016-03-01 | 2016-07-06 | 南京大学 | On-chip integrated arsenic sulfide microdisk cavity and method for manufacturing same |
CN110709775A (en) * | 2017-07-12 | 2020-01-17 | 应用材料公司 | Method for producing high refractive index waveguide |
CN108254829A (en) * | 2018-01-04 | 2018-07-06 | 华南师范大学 | A kind of design method of the vertical pattern converter of double, asymmetrical |
CN112596158A (en) * | 2020-12-22 | 2021-04-02 | 浙江大学绍兴微电子研究中心 | Silicon-based magneto-optical nonreciprocal ridge optical waveguide |
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