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CN1604980A - Coated paper possessing silky feel - Google Patents

Coated paper possessing silky feel Download PDF

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Publication number
CN1604980A
CN1604980A CNA028253558A CN02825355A CN1604980A CN 1604980 A CN1604980 A CN 1604980A CN A028253558 A CNA028253558 A CN A028253558A CN 02825355 A CN02825355 A CN 02825355A CN 1604980 A CN1604980 A CN 1604980A
Authority
CN
China
Prior art keywords
paper
coating
coating composition
coated
equal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA028253558A
Other languages
Chinese (zh)
Other versions
CN100347375C (en
Inventor
格尔·德普雷斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arjo Wiggins Dessin et Papiers Fins SA
Original Assignee
Arjo Wiggins Dessin et Papiers Fins SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arjo Wiggins Dessin et Papiers Fins SA filed Critical Arjo Wiggins Dessin et Papiers Fins SA
Publication of CN1604980A publication Critical patent/CN1604980A/en
Application granted granted Critical
Publication of CN100347375C publication Critical patent/CN100347375C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • D21H19/42Coatings with pigments characterised by the pigments at least partly organic
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
    • D21H21/52Additives of definite length or shape
    • D21H21/54Additives of definite length or shape being spherical, e.g. microcapsules, beads
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/72Coated paper characterised by the paper substrate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254Polymeric or resinous material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/27Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
    • Y10T428/273Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/27Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
    • Y10T428/273Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating
    • Y10T428/277Cellulosic substrate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention concerns a coating composition for coated paper designed to be offset printed, characterized in that the coating pigments are polyurethane microbeads having a size less than 10 micrometers, and advantageously, close to 7 micrometers. The invention also concerns a paper having a silky feel, comprising at least one side coated with said coating composition, and advantageously, both sides. Said paper is characterized in that it can be offset printed with little, even without, set-off or powdering.

Description

Coated paper with silk sensation
Technical field
The present invention relates to a kind of coating composition that comprises polyaminoester microball, and at least one face, preferably on two faces, be coated with the paper of this coating composition.
Background technology
All kinds or the paper with various compositions can be coated with, to strengthen its surface property.
Normally used for this purpose coating composition is to comprise the dispersing of pigments body, and described pigment can be organic or inorganic pigment.
Coating composition also can comprise other additives.
The paper that is used to print, as be used for the paper of book, magazine, brochure or annual report perhaps is used to the paper packed, often by using a kind of or more kinds of apparatus for coating bodystock paper to make, then carries out press polish sometimes.
Use for it, final product should have higher surface characteristic usually.
These surfaces characteristic mainly are the improvement that is reflected in the paper outward appearance, for example the increase of its whiteness, gloss or opacity.
Research to some surface feel of applying cated page is new relatively.
In patent FR 2 791 368 formerly, applicant company mainly provides a kind of wrapping paper, and it has a kind of characteristic that can make the people recall packaging article characteristics, especially for the cosmetic product on skin to be administered.
Therefore, applicant company suggestion provides a kind of characteristic that the people is recalled finally answer land used (being skin), that is to say sensation or flexibility with skin.
Desirable sensation can obtain by apply a coating that comprises expandable thermoplastic microspheres on the page surface.
The purpose of this patent mainly is the problem aspect the machining property of these pages of solution during printing, and especially piles up the separation problem of page, and this is because institute's interpolation microballoon has anti-skidding character.
Generally, thin coated paper is in printing or the serious problem of paper conversion frequent generation of operating period, the most generally aspect hectographic printing: efflorescence and contamination.
Efflorescence is equivalent to during printing coating and breaks away from the form of dry powder, and along with page passing through continuously in printing machine or paper conversion machine, it is more obvious that this phenomenon will become.
The generation of this phenomenon is that wherein pigment is excessive greatly with respect to adhesive because the adhesive of difference/pigment measures.
It also might be because the size and dimension of granules of pigments causes.
Contamination is equivalent to printed article and is transferred on another page by a page, particularly when stacking.
Often can observe dense or light printing ink stain on the verso of page, Here it is is produced by the printing ink on the recto of following page.
When the page of pile up separately, can hear the creak sound that page is either large or small.
If lighter, then this phenomenon becomes contamination.
If the paper element participates in separating, and then is to be stained with sticking (picking).
If no longer these pages can be separated each other, then be the stack bonding.
Because might have poor printing ink ability to accept with the unmatched paper of printing ink, and the paper of surface irregularity is for the too much printing ink of correct printing needs, so paper also might participate in this phenomenon.
In view of these are considered, applicant company makes great efforts to provide a kind of paper with silk sensation, and it preferably all is coated with on two faces, and does not show aforesaid printing and machining property problem.
Summary of the invention
Therefore, first purpose of the present invention provides a kind of coating composition that is used for the coated paper of hectographic printing, it is characterized in that pigment used in this coating composition be average grain diameter less than 10 microns, be preferably about 7 microns polyaminoester microball.
Particularly, the invention is characterized in that used adhesive is the aqueous emulsion of polyurethane in the coating composition, preferably elongation is more than or equal to 500% flexible polyurethane.
Particularly, the invention is characterized in that with dry weight basis, adhesive is more than or equal to 40% with respect to the ratio of pigment, be preferably greater than or equal 200%.
Another object of the present invention provides a kind of coated paper with silk sensation, and it comprises at least one face with aforesaid coating composition coating, and preferred two faces all are coated with.
Described paper is characterised in that it can print in hectographic printing, have low even non-existent efflorescence and contamination.
This paper substrate is in cellulose fibre, and its grammes per square metre is at 70-500g/m 2Between, preferably at 100-300g/m 2Between.
As the case may be, this paper is transparent or semitransparent.
More specifically, this paper constitutes tracing paper.
Term " tracing paper " is interpreted as the paper according to the 6.94th part definition among the international standard ISO 4046-1978.
More specifically, the invention is characterized in that described paper is tracing paper, particularly by the cellulose fibre that constitutes this paper is carried out the tracing paper that heavy beating obtains.
Particularly, the invention is characterized in that with dry weight basis, the weight of the coating at least one face is at 2-10g/m 2Between, preferably at 3-6g/m 2Between.
The feature of described paper also is, the right page of its process coating and its also are less than or equal to 1.0 through the coefficient of kinetic friction between another left page of coating, this coefficient of kinetic friction is measured according to standard NF-Q-03-082, and wherein slide block weight is 200g.
The coefficient of kinetic friction has reflected the adhesive capacity of page when beginning to misplace.The coefficient of kinetic friction is high more, then makes the page in the page heap begin to move difficult more.
Description of drawings
Describe Comparative Examples and implement non-limiting example of the present invention below with reference to accompanying drawing, also can find out other advantages of the present invention thus.In the accompanying drawings:
Fig. 1 has shown the scanning electron microscope diagram (vertical view amplifies 200 times) of the paper that has the silk sensation according to the present invention, and
Fig. 2 has shown the scanning electron microscope diagram (sectional view amplifies 2000 times) of the paper that has the silk sensation according to the present invention.
Specific embodiments
Embodiment
Embodiment 1-5
To comprise the composition with polyaminoester microball of different-grain diameter as shown in table 1 with the air-blade type coating machine, to be coated on grammes per square metre be 100g/m 2The body paper page on, more specifically be meant the Conqueror CX 22 that applicant company sells, the coating ratio is every about 5g/m 2
Preparation comprises the composition of polyaminoester microball in water-bearing media, and comprises with dry weight basis:
-24.7 parts water
-0.1 part wetting agent
-33.3 parts aqueous polyurethane emulsion Witcobond 290 H
-20 parts polyaminoester microball
-0.5 part pH regulator agent
-1 part thickener
Embodiment 6-13
To comprise average grain diameter with the air-blade type coating machine is that to be coated on grammes per square metre be 100g/m for the composition of 7 microns polyaminoester microball 2The body paper page on, more specifically be meant the Conqueror CX 22 that applicant company sells, the coating ratio is counted every about 5g/m with dry weight 2, wherein the concentration of adhesive as shown in table 2 with respect to pigment weight and change.
Preparation comprises the composition of polyaminoester microball in water-bearing media, and comprises with dry weight basis:
-with the variable aqueous polyurethane emulsion Rolflex PAD of dry weight basis umber
-20 parts polyaminoester microball Daiplacoat RHU 5070
-0.5 part pH regulator agent
-1 part thickener
The enforcement of experiment
Assess the sensation of the face of the coating that comprises polyaminoester microball with hand.
Measure of the reaction of unworn paper, the tendency of coating fragmentation when in by machine, passing through with confirmation to the efflorescence experiment.The efflorescence experiment is carried out in such a way:
A) being of a size of 40mm * 40mm, weight with one is that the slide block of 2kg is installed on the roller, and cover a black woollen blanket of making by fabric (mixture of 70% wool and 30% polyamide), then this slide block is applied on one or more scraps of paper that are coated with described coating
B) on paper by once, covering the length of 6m altogether,
C) remove woollen blanket from slide block,
D) reflectivity (for undressed fabric, measured value is about 1.4) of use Elrepho measurement device woollen blanket.
Measure the reaction of paper printed, confirmed that during machinery is piled up paper has the tendency of contamination staiing.Staiing experiment carries out in such a way:
A) preparation paper specimen to be tested, width is 48mm, and length is 250mm,
B) use the Prufbau testing arrangement, it has station 1 that is used to print and the station 2 that is used for transfer printing,
C) pressure with station 1 is adjusted to 1000N, and the pressure of station 2 is adjusted to 400N,
D) speed with device is adjusted to 0.5m/sec,
E) ink roller of station 1 is coated with 30 seconds with Huber 408010 type blue inks,
F) conveying arrangement that has a specimen is positioned at before the station 1,
G) the roller of inking is not positioned on the station 2,
H) on station 1, print specimen,
I) after printing, start stopwatch immediately,
J) specimen of using adhesive tape on the blank roller of station 2, to place identical paper,
K) in case stopwatch was passed by 120 seconds, the conveying arrangement that has the specimen of having printed is entered in the blank roller,
L) specimen of station 2 is separated from its roller immediately,
M) use the measurement of Xrite opacimeter to transfer to the optical density of the blue pigment on the skip test sample.
The result
Test result to embodiment 1-5 is shown in Table 1.
Can find that even most paper has gratifying substantially reaction in contamination and efflorescence experiment, but the microballoon that only has size to be lower than 10 microns can access the silk sensation that can make us accepting.
Can draw to draw a conclusion from the result that embodiment 6-13 is experimentized: when the size of the microballoon of selecting to access desirable silk sensation, for having correct efflorescence, the level of adhesive must be chosen as more than or equal to 40%, and be to have correct contamination, the level of adhesive must be chosen as more than or equal to 200%.
This is to be considered to gratifying because be lower than 2 efflorescence and be lower than 0.1 contamination.
From the viewpoint of applicant company, the scanning electron microscope diagram with paper of silk sensation is shown among Fig. 1 and 2.
This paper is by being 100g/m in grammes per square metre 2The two sides of Conqueror CX 22 body paper on the following coating composition of coating obtain:
2.8kg water
0.03kg wetting agent Texapon Z95P
The adhesive Rolflex PAD of 81kg, Lamberti company sells
6.1kg polyaminoester microball Daiplacoat RHU 5070, Promecome company sells
The thickener CMC Blanose 7M65 of 1kg, concentration is 2.5%, Aqualon company sells
With dry weight basis, ratio is every 5.4g/m 2, above-mentioned amount is represented with trade weight.
Subsequently the paper that obtains is carried out press polish.
These photos have been represented the vertical view that amplifies 200 times respectively and have been amplified 2000 times sectional view.
The paper that obtains all shows the silk sensation veritably at two faces.
According to standard NF-Q-03-082, be the coefficient of kinetic friction of the slide block measurement coated paper of 200g with weight, obtain 0.8 value.This value can guarantee that page mechanically has the favorable mechanical processability in printing or paper conversion.
Table 1
The particle title Daiplacoat ?Decolam?F7 ?Decolam?FT ?Decolam?F ?Decolam?W
Particle size (micron) ????7 ????10 ????28 ????28 ????50
Silk-like handle Be By Medium Medium Not
Efflorescence ????1.8 ????1.6 ????1.6 ????1.6 ????1.4
Stain ????0.4 ????0.32 ????0.41 ????0.39 ????0.2
Table 2
Adhesive % pigment ??10% ??20% ??30% ??40% ??50% ??100% ??150% ??400%
Silk-like handle Be Be Be Be Be Be Be Be
Efflorescence ??15.5 ??6 ??3.6 ??1.9 ??1.7 ??1.5 ??1.5 ??1.5
Stain ??0.282 ??0.326 ??0.327 ??0.354 ??0.367 ??0.123 ??0.104 ??0.07

Claims (7)

1, a kind ofly be used for the coated paper of hectographic printing and comprise pigment and the coating composition of adhesive, it is characterized in that described pigment be particle diameter less than 10 microns, be preferably about 7 microns polyaminoester microball.
2, coating composition as claimed in claim 1 is characterized in that used adhesive is the aqueous emulsion of polyurethane, and this polyurethane preferably has the elongation more than or equal to 500%.
3, coating composition as claimed in claim 2, it is characterized in that adhesive with respect to the weight ratio of pigment for more than or equal to 40%, and be preferably greater than or equal 200%.
4, a kind of coated paper with silk sensation, it comprises at least one usefulness face of the described coating composition coating of arbitrary claim as described above, preferred two faces all are coated with.
5, paper as claimed in claim 4, it is characterized in that the coefficient of kinetic friction between another left page of the right page of coating and also process coating is less than or equal to 1.0 in the described paper, this coefficient of kinetic friction is measured according to standard NF-Q-03-082, and wherein slide block weight is 200g.
6, as claim 4 or 5 described paper, it is characterized in that with dry weight basis the weight of the coating layer at least one face is at 2-10g/m 2Between, preferably at 3-6g/m 2Between.
7,, it is characterized in that described paper is tracing paper, particularly by the cellulose fibre that constitutes this paper is carried out the tracing paper that heavy beating obtains as the described paper of one of claim 4-6.
CNB028253558A 2001-12-18 2002-12-17 Coated paper possessing silky feel Expired - Fee Related CN100347375C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0116417A FR2833625B1 (en) 2001-12-18 2001-12-18 COATING PAPER HAVING A SILKY TOUCH
FR01/16417 2001-12-18

Publications (2)

Publication Number Publication Date
CN1604980A true CN1604980A (en) 2005-04-06
CN100347375C CN100347375C (en) 2007-11-07

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CNB028253558A Expired - Fee Related CN100347375C (en) 2001-12-18 2002-12-17 Coated paper possessing silky feel

Country Status (20)

Country Link
US (1) US20050031851A1 (en)
EP (1) EP1458930B1 (en)
JP (1) JP4669223B2 (en)
KR (2) KR20080107481A (en)
CN (1) CN100347375C (en)
AT (1) ATE526455T1 (en)
AU (1) AU2002364844B2 (en)
BR (1) BR0207323B1 (en)
CA (1) CA2469016C (en)
ES (1) ES2372815T3 (en)
FR (1) FR2833625B1 (en)
HK (1) HK1076133A1 (en)
HU (1) HUP0600861A2 (en)
MX (1) MXPA04005869A (en)
NO (1) NO20033545D0 (en)
NZ (1) NZ533961A (en)
PT (1) PT1458930E (en)
RU (1) RU2294998C2 (en)
WO (1) WO2003052203A2 (en)
ZA (1) ZA200306262B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101821454B (en) * 2007-10-12 2012-09-12 花王株式会社 Method for production of coated paper
CN104674596A (en) * 2015-02-05 2015-06-03 骏源新材料(上海)有限公司 Preparation method of touch paper

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US6866906B2 (en) 2000-01-26 2005-03-15 International Paper Company Cut resistant paper and paper articles and method for making same
AU2003272481A1 (en) 2002-09-13 2004-04-30 Yang, Sen Paper with improved stiffness and bulk and method for making same
EP2357279A1 (en) * 2005-03-11 2011-08-17 International Paper Company Compositions containing expandable microspheres and an ionic compound as well as methods of making the same
KR100845602B1 (en) * 2007-01-31 2008-07-10 주식회사 케이에프텍 Artificial leather
CN104032622A (en) 2008-08-28 2014-09-10 国际纸业公司 Expandable Microspheres And Methods Of Making And Using The Same
FR2942169B1 (en) * 2009-02-13 2011-04-01 Arjo Wiggins Fine Papers Ltd MULTILAYER PRINTABLE SHEET WITH SOFT OR SOYE TOUCH AND ITS MANUFACTURING METHOD
FR2960889B1 (en) * 2010-06-03 2012-07-27 Arjo Wiggins Fine Papers Ltd PAPER END LAYER WITH SOFT TOUCH
JP6971442B2 (en) * 2018-03-13 2021-11-24 ダイニック株式会社 Suede-like coated paper

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101821454B (en) * 2007-10-12 2012-09-12 花王株式会社 Method for production of coated paper
CN104674596A (en) * 2015-02-05 2015-06-03 骏源新材料(上海)有限公司 Preparation method of touch paper

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Publication number Publication date
HUP0600861A2 (en) 2007-05-02
PT1458930E (en) 2011-12-15
FR2833625A1 (en) 2003-06-20
HK1076133A1 (en) 2006-01-06
ZA200306262B (en) 2005-04-26
WO2003052203A2 (en) 2003-06-26
JP4669223B2 (en) 2011-04-13
BR0207323B1 (en) 2013-01-22
CA2469016C (en) 2010-10-19
BR0207323A (en) 2004-02-10
NZ533961A (en) 2007-08-31
RU2004121956A (en) 2005-03-27
KR100956864B1 (en) 2010-05-11
KR20040066905A (en) 2004-07-27
WO2003052203A3 (en) 2003-12-11
NO20033545L (en) 2003-08-11
EP1458930A2 (en) 2004-09-22
ATE526455T1 (en) 2011-10-15
EP1458930B1 (en) 2011-09-28
ES2372815T3 (en) 2012-01-26
MXPA04005869A (en) 2005-03-31
CN100347375C (en) 2007-11-07
CA2469016A1 (en) 2003-06-26
US20050031851A1 (en) 2005-02-10
RU2294998C2 (en) 2007-03-10
FR2833625B1 (en) 2004-03-05
NO20033545D0 (en) 2003-08-11
KR20080107481A (en) 2008-12-10
AU2002364844A1 (en) 2003-06-30
JP2005513282A (en) 2005-05-12
AU2002364844B2 (en) 2008-04-24

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