CN100347375C - Coated paper possessing silky feel - Google Patents
Coated paper possessing silky feel Download PDFInfo
- Publication number
- CN100347375C CN100347375C CNB028253558A CN02825355A CN100347375C CN 100347375 C CN100347375 C CN 100347375C CN B028253558 A CNB028253558 A CN B028253558A CN 02825355 A CN02825355 A CN 02825355A CN 100347375 C CN100347375 C CN 100347375C
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- Prior art keywords
- paper
- coating
- coating composition
- adhesive
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011248 coating agent Substances 0.000 claims abstract description 20
- 238000000576 coating method Methods 0.000 claims abstract description 20
- 239000008199 coating composition Substances 0.000 claims abstract description 19
- 239000000049 pigment Substances 0.000 claims abstract description 14
- 229920002635 polyurethane Polymers 0.000 claims abstract description 7
- 239000004814 polyurethane Substances 0.000 claims abstract description 7
- 239000000853 adhesive Substances 0.000 claims description 14
- 230000001070 adhesive effect Effects 0.000 claims description 14
- 239000011806 microball Substances 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 229920003043 Cellulose fiber Polymers 0.000 claims description 3
- 238000010009 beating Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 239000011247 coating layer Substances 0.000 claims 2
- 238000000227 grinding Methods 0.000 abstract 1
- 239000011325 microbead Substances 0.000 abstract 1
- 238000007639 printing Methods 0.000 description 16
- 230000035807 sensation Effects 0.000 description 12
- 238000006253 efflorescence Methods 0.000 description 10
- 206010037844 rash Diseases 0.000 description 10
- 238000011109 contamination Methods 0.000 description 8
- 239000000976 ink Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
- D21H21/52—Additives of definite length or shape
- D21H21/54—Additives of definite length or shape being spherical, e.g. microcapsules, beads
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/42—Coatings with pigments characterised by the pigments at least partly organic
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/72—Coated paper characterised by the paper substrate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/254—Polymeric or resinous material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
- Y10T428/273—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
- Y10T428/273—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating
- Y10T428/277—Cellulosic substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
- Paints Or Removers (AREA)
Abstract
The invention concerns a coating composition for coated paper designed to be offset printed, characterized in that the coating pigments are polyurethane microbeads having a size less than 10 micrometers, and advantageously, close to 7 micrometers. The invention also concerns a paper having a silky feel, comprising at least one side coated with said coating composition, and advantageously, both sides. Said paper is characterized in that it can be offset printed with little, even without, set-off or powdering.
Description
Technical field
The present invention relates to a kind of coating composition that comprises polyaminoester microball, and at least one face, preferably on two faces, be coated with the paper of this coating composition.
Background technology
All kinds or the paper with various compositions can be coated with, to strengthen its surface property.
Normally used for this purpose coating composition is to comprise the dispersing of pigments body, and described pigment can be organic or inorganic pigment.
Coating composition also can comprise other additives.
The paper that is used to print, as be used for the paper of book, magazine, brochure or annual report perhaps is used to the paper packed, often by using a kind of or more kinds of apparatus for coating bodystock paper to make, then carries out press polish sometimes.
Use for it, final product should have higher surface characteristic usually.
These surfaces characteristic mainly are the improvement that is reflected in the paper outward appearance, for example the increase of its whiteness, gloss or opacity.
Research to some surface feel of applying cated page is new relatively.
In patent FR 2 791 368 formerly, applicant company mainly provides a kind of wrapping paper, and it has a kind of characteristic that can make the people recall packaging article characteristics, especially for the cosmetic product on skin to be administered.
Therefore, applicant company suggestion provides a kind of characteristic that the people is recalled finally answer land used (being skin), that is to say sensation or flexibility with skin.
Desirable sensation can obtain by apply a coating that comprises expandable thermoplastic microspheres on the page surface.
The purpose of this patent mainly is the problem aspect the machining property of these pages of solution during printing, and especially piles up the separation problem of page, and this is because institute's interpolation microballoon has anti-skidding character.
Generally, thin coated paper is in printing or the serious problem of paper conversion frequent generation of operating period, the most generally aspect hectographic printing: efflorescence and contamination.
Efflorescence is equivalent to during printing coating and breaks away from the form of dry powder, and along with page passing through continuously in printing machine or paper conversion machine, it is more obvious that this phenomenon will become.
The generation of this phenomenon is that wherein pigment is excessive greatly with respect to adhesive because the adhesive of difference/pigment measures.
It also might be because the size and dimension of granules of pigments causes.
Contamination is equivalent to printed article and is transferred on another page by a page, particularly when stacking.
Often can observe dense or light printing ink stain on the verso of page, Here it is is produced by the printing ink on the recto of following page.
When the page of pile up separately, can hear the creak sound that page is either large or small.
If lighter, then this phenomenon becomes contamination.
If the paper element participates in separating, and then is to be stained with sticking (picking).
If no longer these pages can be separated each other, then be the stack bonding.
Because might have poor printing ink ability to accept with the unmatched paper of printing ink, and the paper of surface irregularity is for the too much printing ink of correct printing needs, so paper also might participate in this phenomenon.
In view of these are considered, applicant company makes great efforts to provide a kind of paper with silk sensation, and it preferably all is coated with on two faces, and does not show aforesaid printing and machining property problem.
Summary of the invention
Therefore, first purpose of the present invention provides a kind of coating composition that is used for the coated paper of hectographic printing, it is characterized in that pigment used in this coating composition be average grain diameter less than 10 microns, be preferably about 7 microns polyaminoester microball.
Particularly, the invention is characterized in that used adhesive is the aqueous emulsion of polyurethane in the coating composition, preferably elongation is more than or equal to 500% flexible polyurethane.
Particularly, the invention is characterized in that with dry weight basis, adhesive is more than or equal to 40% with respect to the ratio of pigment, be preferably greater than or equal 200%.
Another object of the present invention provides a kind of coated paper with silk sensation, and it comprises at least one face with aforesaid coating composition coating, and preferred two faces all are coated with.
Described paper is characterised in that it can print in hectographic printing, have low even non-existent efflorescence and contamination.
This paper substrate is in cellulose fibre, and its grammes per square metre is at 70-500g/m
2Between, preferably at 100-300g/m
2Between.
As the case may be, this paper is transparent or semitransparent.
More specifically, this paper constitutes tracing paper.
Term " tracing paper " is interpreted as the paper according to the 6.94th part definition among the international standard ISO 4046-1978.
More specifically, the invention is characterized in that described paper is tracing paper, particularly by the cellulose fibre that constitutes this paper is carried out the tracing paper that heavy beating obtains.
Particularly, the invention is characterized in that with dry weight basis, the weight of the coating at least one face is at 2-10g/m
2Between, preferably at 3-6g/m
2Between.
The feature of described paper also is, the right page of its process coating and its also are less than or equal to 1.0 through the coefficient of kinetic friction between another left page of coating, this coefficient of kinetic friction is measured according to standard NF-Q-03-082, and wherein slide block weight is 200g.
The coefficient of kinetic friction has reflected the adhesive capacity of page when beginning to misplace.The coefficient of kinetic friction is high more, then makes the page in the page heap begin to move difficult more.
Description of drawings
Describe Comparative Examples and implement non-limiting example of the present invention below with reference to accompanying drawing, also can find out other advantages of the present invention thus.In the accompanying drawings:
Fig. 1 has shown the scanning electron microscope diagram (vertical view amplifies 200 times) of the paper that has the silk sensation according to the present invention, and
Fig. 2 has shown the scanning electron microscope diagram (sectional view amplifies 2000 times) of the paper that has the silk sensation according to the present invention.
Specific embodiments
Embodiment
Embodiment 1-5
To comprise the composition with polyaminoester microball of different-grain diameter as shown in table 1 with the air-blade type coating machine, to be coated on grammes per square metre be 100g/m
2The body paper page on, more specifically be meant the Conqueror CX 22 that applicant company sells, the coating ratio is every about 5g/m
2
Preparation comprises the composition of polyaminoester microball in water-bearing media, and comprises with dry weight basis:
-24.7 parts water
-0.1 part wetting agent
-33.3 parts aqueous polyurethane emulsion Witcobond 290 H
-20 parts polyaminoester microball
-0.5 part pH regulator agent
-1 part thickener
Embodiment 6-13
To comprise average grain diameter with the air-blade type coating machine is that to be coated on grammes per square metre be 100g/m for the composition of 7 microns polyaminoester microball
2The body paper page on, more specifically be meant the Conqueror CX 22 that applicant company sells, the coating ratio is counted every about 5g/m with dry weight
2, wherein the concentration of adhesive as shown in table 2 with respect to pigment weight and change.
Preparation comprises the composition of polyaminoester microball in water-bearing media, and comprises with dry weight basis:
-with the variable aqueous polyurethane emulsion Rolflex PAD of dry weight basis umber
-20 parts polyaminoester microball Daiplacoat RHU 5070
-0.5 part pH regulator agent
-1 part thickener
The enforcement of experiment
Assess the sensation of the face of the coating that comprises polyaminoester microball with hand.
Measure of the reaction of unworn paper, the tendency of coating fragmentation when in by machine, passing through with confirmation to the efflorescence experiment.The efflorescence experiment is carried out in such a way:
A) being of a size of 40mm * 40mm, weight with one is that the slide block of 2kg is installed on the roller, and cover a black woollen blanket of making by fabric (mixture of 70% wool and 30% polyamide), then this slide block is applied on one or more scraps of paper that are coated with described coating
B) on paper by once, covering the length of 6m altogether,
C) remove woollen blanket from slide block,
D) reflectivity (for undressed fabric, measured value is about 1.4) of use Elrepho measurement device woollen blanket.
Measure the reaction of paper printed, confirmed that during machinery is piled up paper has the tendency of contamination staiing.Staiing experiment carries out in such a way:
A) preparation paper specimen to be tested, width is 48mm, and length is 250mm,
B) use the Prufbau testing arrangement, it has station 1 that is used to print and the station 2 that is used for transfer printing,
C) pressure with station 1 is adjusted to 1000N, and the pressure of station 2 is adjusted to 400N,
D) speed with device is adjusted to 0.5m/sec,
E) ink roller of station 1 is coated with 30 seconds with Huber 408010 type blue inks,
F) conveying arrangement that has a specimen is positioned at before the station 1,
G) the roller of inking is not positioned on the station 2,
H) on station 1, print specimen,
I) after printing, start stopwatch immediately,
J) specimen of using adhesive tape on the blank roller of station 2, to place identical paper,
K) in case stopwatch was passed by 120 seconds, the conveying arrangement that has the specimen of having printed is entered in the blank roller,
L) specimen of station 2 is separated from its roller immediately,
M) use the measurement of Xrite opacimeter to transfer to the optical density of the blue pigment on the skip test sample.The result
Test result to embodiment 1-5 is shown in Table 1.
Can find that even most paper has gratifying substantially reaction in contamination and efflorescence experiment, but the microballoon that only has size to be lower than 10 microns can access the silk sensation that can make us accepting.
Can draw to draw a conclusion from the result that embodiment 6-13 is experimentized: when the size of the microballoon of selecting to access desirable silk sensation, for having correct efflorescence, the level of adhesive must be chosen as more than or equal to 40%, and be to have correct contamination, the level of adhesive must be chosen as more than or equal to 200%.
This is to be considered to gratifying because be lower than 2 efflorescence and be lower than 0.1 contamination.
From the viewpoint of applicant company, the scanning electron microscope diagram with paper of silk sensation is shown among Fig. 1 and 2.
This paper is by being 100g/m in grammes per square metre
2The two sides of Conqueror CX 22 body paper on the following coating composition of coating obtain:
2.8kg water
0.03kg wetting agent Texapon Z95P
The adhesive Rolflex PAD of 81kg, Lamberti company sells
6.1kg polyaminoester microball Daiplacoat RHU 5070, Promecome company sells
The thickener CMC Blanose 7M65 of 1kg, concentration is 2.5%, Aqualon company sells
With dry weight basis, ratio is every 5.4g/m
2, above-mentioned amount is represented with trade weight.
Subsequently the paper that obtains is carried out press polish.
These photos have been represented the vertical view that amplifies 200 times respectively and have been amplified 2000 times sectional view.
The paper that obtains all shows the silk sensation veritably at two faces.
According to standard NF-Q-03-082, be the coefficient of kinetic friction of the slide block measurement coated paper of 200g with weight, obtain 0.8 value.This value can guarantee that page mechanically has the favorable mechanical processability in printing or paper conversion.
Table 1
| The particle title | Daiplacoat | Decolam F7 | Decolam FT | Decolam F | Decolam W |
| Particle size (micron) | 7 | 10 | 28 | 28 | 50 |
| Silk-like handle | Be | By | Medium | Medium | Not |
| Efflorescence | 1.8 | 1.6 | 1.6 | 1.6 | 1.4 |
| Stain | 0.4 | 0.32 | 0.41 | 0.39 | 0.2 |
Table 2
| Adhesive % pigment | 10％ | 20％ | 30％ | 40％ | 50％ | 100％ | 150％ | 400％ |
| Silk-like handle | Be | Be | Be | Be | Be | Be | Be | Be |
| Efflorescence | 15.5 | 6 | 3.6 | 1.9 | 1.7 | 1.5 | 1.5 | 1.5 |
| Stain | 0.282 | 0.326 | 0.327 | 0.354 | 0.367 | 0.123 | 0.104 | 0.07 |
Claims (13)
1, a kind of coating composition that is used for coated paper, it comprises pigment and adhesive, it is characterized in that coating pigment is a particle diameter less than 10 microns polyaminoester microball.
2, coating composition as claimed in claim 1, the particle diameter that it is characterized in that described polyaminoester microball is 7 microns.
3, coating composition as claimed in claim 1 is characterized in that used adhesive is the aqueous emulsion of polyurethane.
4, coating composition as claimed in claim 3, the elongation that it is characterized in that used polyurethane is more than or equal to 500%.
5, coating composition as claimed in claim 3 is characterized in that adhesive is more than or equal to 40% with respect to the part by weight of pigment.
6, coating composition as claimed in claim 5 is characterized in that adhesive is more than or equal to 200% with respect to the part by weight of pigment.
7, a kind of paper, it comprises the face of at least one usefulness as the described coating composition coating of one of claim 1 to 6.
8, paper as claimed in claim 7 is characterized in that two face all is coated with described coating composition.
9, paper as claimed in claim 8, it is characterized in that the coefficient of kinetic friction between another left page of the right page of coating and also process coating is less than or equal to 1.0 in the described paper, this coefficient of kinetic friction is measured according to French Standard NF-Q-03-082, and wherein slide block weight is 200g.
As the described paper of one of claim 7 to 9, it is characterized in that 10, the weight of the coating layer at least one face is at 2-10g/m with dry weight basis
2Between.
11, paper as claimed in claim 10 is characterized in that with dry weight basis the weight of the coating layer at least one face is at 3-6g/m
2Between.
12,, it is characterized in that described paper is tracing paper as the described paper of one of claim 7 to 9.
13, paper as claimed in claim 12 is characterized in that described tracing paper is to obtain by the cellulose fibre that constitutes this paper is carried out heavy beating.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR01/16417 | 2001-12-18 | ||
| FR0116417A FR2833625B1 (en) | 2001-12-18 | 2001-12-18 | COATING PAPER HAVING A SILKY TOUCH |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1604980A CN1604980A (en) | 2005-04-06 |
| CN100347375C true CN100347375C (en) | 2007-11-07 |
Family
ID=8870662
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB028253558A Expired - Fee Related CN100347375C (en) | 2001-12-18 | 2002-12-17 | Coated paper possessing silky feel |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US20050031851A1 (en) |
| EP (1) | EP1458930B1 (en) |
| JP (1) | JP4669223B2 (en) |
| KR (2) | KR20080107481A (en) |
| CN (1) | CN100347375C (en) |
| AT (1) | ATE526455T1 (en) |
| AU (1) | AU2002364844B2 (en) |
| BR (1) | BR0207323B1 (en) |
| CA (1) | CA2469016C (en) |
| ES (1) | ES2372815T3 (en) |
| FR (1) | FR2833625B1 (en) |
| HU (1) | HUP0600861A2 (en) |
| MX (1) | MXPA04005869A (en) |
| NO (1) | NO20033545D0 (en) |
| NZ (1) | NZ533961A (en) |
| PT (1) | PT1458930E (en) |
| RU (1) | RU2294998C2 (en) |
| WO (1) | WO2003052203A2 (en) |
| ZA (1) | ZA200306262B (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6866906B2 (en) | 2000-01-26 | 2005-03-15 | International Paper Company | Cut resistant paper and paper articles and method for making same |
| WO2004025026A1 (en) | 2002-09-13 | 2004-03-25 | International Paper Company | Paper with improved stiffness and bulk and method for making same |
| CA2600801C (en) * | 2005-03-11 | 2012-07-10 | International Paper Company | Compositions containing expandable microspheres and an ionic compound, as well as methods of making and using the same |
| MX2008006146A (en) * | 2006-09-12 | 2009-01-29 | Meadwestvaco Corp | Paperboard containing microplatelet cellulose particles. |
| KR100845602B1 (en) * | 2007-01-31 | 2008-07-10 | 주식회사 케이에프텍 | Artificial leather |
| EP2199464A4 (en) * | 2007-10-12 | 2012-08-15 | Kao Corp | Method for production of coated paper |
| EP2328947A1 (en) | 2008-08-28 | 2011-06-08 | International Paper Company | Expandable microspheres and methods of making and using the same |
| FR2942169B1 (en) * | 2009-02-13 | 2011-04-01 | Arjo Wiggins Fine Papers Ltd | MULTILAYER PRINTABLE SHEET WITH SOFT OR SOYE TOUCH AND ITS MANUFACTURING METHOD |
| FR2960889B1 (en) * | 2010-06-03 | 2012-07-27 | Arjo Wiggins Fine Papers Ltd | PAPER END LAYER WITH SOFT TOUCH |
| CN104674596B (en) * | 2015-02-05 | 2016-12-07 | 骏源新材料（上海）有限公司 | A kind of preparation method of sense of touch paper |
| JP6971442B2 (en) * | 2018-03-13 | 2021-11-24 | ダイニック株式会社 | Suede-like coated paper |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999067310A1 (en) * | 1998-06-24 | 1999-12-29 | Akzo Nobel N.V. | Ionic polyurethanes |
| FR2791368A1 (en) * | 1999-03-26 | 2000-09-29 | Arjo Wiggins Sa | SHEET WITH HIGH PRICE PRINTABLE "SKIN" TOUCH AND MANUFACTURING AND PACKAGING METHOD THEREOF |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1401533A (en) * | 1972-08-02 | 1975-07-16 | British American Tobacco Co | Surface finishes |
| US4756950A (en) * | 1985-03-23 | 1988-07-12 | Mitsubishi Paper Mills, Ltd. | Gradation recording heat-transfer sheet |
| FR2635506B1 (en) * | 1988-08-12 | 1990-11-30 | Lembacel Sa | SHEET OF PAPER HAVING ANTI-SLIP PROPERTIES, MANUFACTURING METHOD AND APPLICATION IN PACKAGING |
| JPH02277899A (en) * | 1989-04-12 | 1990-11-14 | Ricoh Co Ltd | Transparent raw paper and electrostatic recording material using the same paper |
| JPH0450857A (en) * | 1990-06-15 | 1992-02-19 | Ricoh Co Ltd | Electrostatic recording paper for reproducible |
| JPH0482736A (en) * | 1990-07-25 | 1992-03-16 | Achilles Corp | Suede like sheet and preparation thereof |
| JPH04144743A (en) * | 1990-10-05 | 1992-05-19 | Dainippon Printing Co Ltd | Manufacture of suede-toned packing paper |
| JP3161053B2 (en) * | 1992-07-13 | 2001-04-25 | 大日本印刷株式会社 | Cloth-like makeup material |
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- 2001-12-18 FR FR0116417A patent/FR2833625B1/en not_active Expired - Fee Related
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- 2002-12-17 AT AT02801137T patent/ATE526455T1/en not_active IP Right Cessation
- 2002-12-17 CA CA2469016A patent/CA2469016C/en not_active Expired - Fee Related
- 2002-12-17 CN CNB028253558A patent/CN100347375C/en not_active Expired - Fee Related
- 2002-12-17 EP EP02801137A patent/EP1458930B1/en not_active Expired - Lifetime
- 2002-12-17 KR KR1020087026912A patent/KR20080107481A/en not_active Withdrawn
- 2002-12-17 RU RU2004121956/12A patent/RU2294998C2/en not_active IP Right Cessation
- 2002-12-17 ES ES02801137T patent/ES2372815T3/en not_active Expired - Lifetime
- 2002-12-17 JP JP2003553068A patent/JP4669223B2/en not_active Expired - Fee Related
- 2002-12-17 WO PCT/FR2002/004378 patent/WO2003052203A2/en active Application Filing
- 2002-12-17 NZ NZ533961A patent/NZ533961A/en not_active IP Right Cessation
- 2002-12-17 PT PT02801137T patent/PT1458930E/en unknown
- 2002-12-17 US US10/498,066 patent/US20050031851A1/en not_active Abandoned
- 2002-12-17 MX MXPA04005869A patent/MXPA04005869A/en active IP Right Grant
- 2002-12-17 HU HU0600861A patent/HUP0600861A2/en unknown
- 2002-12-17 AU AU2002364844A patent/AU2002364844B2/en not_active Ceased
- 2002-12-17 BR BRPI0207323-4A patent/BR0207323B1/en not_active IP Right Cessation
- 2002-12-17 KR KR1020047009271A patent/KR100956864B1/en not_active Expired - Fee Related
-
2003
- 2003-08-11 NO NO20033545A patent/NO20033545D0/en not_active Application Discontinuation
- 2003-08-13 ZA ZA2003/06262A patent/ZA200306262B/en unknown
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| WO1999067310A1 (en) * | 1998-06-24 | 1999-12-29 | Akzo Nobel N.V. | Ionic polyurethanes |
| FR2791368A1 (en) * | 1999-03-26 | 2000-09-29 | Arjo Wiggins Sa | SHEET WITH HIGH PRICE PRINTABLE "SKIN" TOUCH AND MANUFACTURING AND PACKAGING METHOD THEREOF |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2833625A1 (en) | 2003-06-20 |
| BR0207323B1 (en) | 2013-01-22 |
| KR20040066905A (en) | 2004-07-27 |
| AU2002364844A1 (en) | 2003-06-30 |
| WO2003052203A2 (en) | 2003-06-26 |
| EP1458930A2 (en) | 2004-09-22 |
| RU2294998C2 (en) | 2007-03-10 |
| WO2003052203A3 (en) | 2003-12-11 |
| KR100956864B1 (en) | 2010-05-11 |
| HUP0600861A2 (en) | 2007-05-02 |
| ES2372815T3 (en) | 2012-01-26 |
| US20050031851A1 (en) | 2005-02-10 |
| CN1604980A (en) | 2005-04-06 |
| CA2469016A1 (en) | 2003-06-26 |
| NZ533961A (en) | 2007-08-31 |
| PT1458930E (en) | 2011-12-15 |
| ZA200306262B (en) | 2005-04-26 |
| MXPA04005869A (en) | 2005-03-31 |
| ATE526455T1 (en) | 2011-10-15 |
| CA2469016C (en) | 2010-10-19 |
| KR20080107481A (en) | 2008-12-10 |
| NO20033545L (en) | 2003-08-11 |
| JP4669223B2 (en) | 2011-04-13 |
| RU2004121956A (en) | 2005-03-27 |
| AU2002364844B2 (en) | 2008-04-24 |
| BR0207323A (en) | 2004-02-10 |
| NO20033545D0 (en) | 2003-08-11 |
| FR2833625B1 (en) | 2004-03-05 |
| HK1076133A1 (en) | 2006-01-06 |
| JP2005513282A (en) | 2005-05-12 |
| EP1458930B1 (en) | 2011-09-28 |
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