CN1596647A - Carbendazin water dispersable particle agent and its formula - Google Patents
Carbendazin water dispersable particle agent and its formula Download PDFInfo
- Publication number
- CN1596647A CN1596647A CN 200410026345 CN200410026345A CN1596647A CN 1596647 A CN1596647 A CN 1596647A CN 200410026345 CN200410026345 CN 200410026345 CN 200410026345 A CN200410026345 A CN 200410026345A CN 1596647 A CN1596647 A CN 1596647A
- Authority
- CN
- China
- Prior art keywords
- sodium
- carbendazim
- prescription
- dispersible granules
- prescription according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 239000002245 particle Substances 0.000 title claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract 2
- 239000003795 chemical substances by application Substances 0.000 title 1
- 239000006013 carbendazim Substances 0.000 claims abstract description 33
- 239000000843 powder Substances 0.000 claims abstract description 28
- -1 disperser Substances 0.000 claims abstract description 16
- 239000007884 disintegrant Substances 0.000 claims abstract description 11
- 239000000080 wetting agent Substances 0.000 claims abstract description 11
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 claims description 32
- 239000004562 water dispersible granule Substances 0.000 claims description 18
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 15
- 239000011734 sodium Substances 0.000 claims description 13
- 229910052708 sodium Inorganic materials 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 10
- 239000002270 dispersing agent Substances 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- 239000007859 condensation product Substances 0.000 claims description 8
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 6
- 229920005610 lignin Polymers 0.000 claims description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims description 6
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 claims description 6
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- 125000003368 amide group Chemical group 0.000 claims description 3
- 229960000892 attapulgite Drugs 0.000 claims description 3
- 229910052625 palygorskite Inorganic materials 0.000 claims description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 3
- 239000004584 polyacrylic acid Substances 0.000 claims description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 229940077388 benzenesulfonate Drugs 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 230000001788 irregular Effects 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 239000000741 silica gel Substances 0.000 claims description 2
- 229910002027 silica gel Inorganic materials 0.000 claims description 2
- 239000002689 soil Substances 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 125000001924 fatty-acyl group Chemical group 0.000 claims 1
- 238000007873 sieving Methods 0.000 abstract description 8
- 240000007594 Oryza sativa Species 0.000 abstract description 3
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 3
- 235000009566 rice Nutrition 0.000 abstract description 3
- 241000209140 Triticum Species 0.000 abstract description 2
- 235000021307 Triticum Nutrition 0.000 abstract description 2
- 235000013399 edible fruits Nutrition 0.000 abstract description 2
- 238000003756 stirring Methods 0.000 abstract description 2
- 229920000742 Cotton Polymers 0.000 abstract 1
- 241000219146 Gossypium Species 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 201000010099 disease Diseases 0.000 abstract 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract 1
- 238000005338 heat storage Methods 0.000 description 9
- 230000002045 lasting effect Effects 0.000 description 8
- 239000000428 dust Substances 0.000 description 7
- 238000005469 granulation Methods 0.000 description 7
- 230000003179 granulation Effects 0.000 description 7
- 244000141359 Malus pumila Species 0.000 description 6
- 235000011430 Malus pumila Nutrition 0.000 description 6
- 235000015103 Malus silvestris Nutrition 0.000 description 6
- 230000001133 acceleration Effects 0.000 description 6
- 239000000470 constituent Substances 0.000 description 6
- 238000005187 foaming Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000012216 screening Methods 0.000 description 6
- 238000005303 weighing Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000000375 suspending agent Substances 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002190 fatty acyls Chemical group 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 241000235349 Ascomycota Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 235000014751 Gossypium arboreum Nutrition 0.000 description 1
- 241000218069 Kokia Species 0.000 description 1
- 241000918585 Pythium aphanidermatum Species 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 238000012395 formulation development Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000011278 mitosis Effects 0.000 description 1
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A granular carbendazin with high water dispersity for preventing and treating more diseases of fruit tree, cotton, rice and wheat is prepared from carbendazim powder, wetting agent, disperser, disintegrant, diluent and adhesive through proportional mixing, stirring, granulating, baking and sieving.
Description
Technical field
The present invention relates to a kind of disinfectant use in agriculture, particularly carbendazim water-dispersible granules and prescription.
Background technology
At present, disinfectant use in agriculture is a lot, and carbendazim is wherein a kind of.The systemic fungicide of carbendazim high-efficiency low-toxicity.Effective to sac fungi and imperfect fungus, have protection and therapeutic action.The mechanism of action is the formation of imitative hammer body in the mitosis of disturbing bacterium, thereby influences cell division.Carbendazim original powder is made generally in suspending agent in using at present and wetting powder uses.But because there is dust pollution in wetting powder in processing and use, serious harm environment and health, and shortcomings such as effective rate of utilization is low, lasting period weak point are the formulations that falls behind and be on the verge of to eliminate relatively in the present formulations of pesticide.Though suspending agent is the environmental protection preparation, in the production technology to the conditional request height, high-load preparation can not realize that its production, packing and cost of transportation are also higher, causes the increase of use cost.
Summary of the invention
Purpose of the present invention is exactly in order to overcome environmental pollution that prior art exists, to be detrimental to health and shortcoming such as use cost height and a kind of high-load of developing environment-friendly type, availability height, and carbendazim water-dispersible granules and prescription easy to use.Water-dispersible granules is to grow up on the basis of wetting powder and suspending agent, this formulation has overcome the various shortcoming of suspending agent and wetting powder, had both the low advantage of environmental protection and use cost, in processing and use, having reduced the pollution of environment and reduced peasant's use cost, is a main trend of present pesticidal preparations formulation development.
The objective of the invention is to realize that by following technical scheme the effective ingredient of carbendazim water-dispersible granules is a carbendazim, it is characterized in that carbendazim is rule or irregular particle shape.
The prescription of realizing the carbendazim water-dispersible granules is as follows by percentage to the quality:
Carbendazim original powder: 40～80%
Wetting agent: 2～8%
Dispersant: 3～10%
Disintegrant: 3～8%
Thinner: 5～40%
Binding agent: 3～10%.
Wherein:
Wetting agent can be a kind of of phenethyl phenol polyethenoxy ether condensation product, alkylphenol polyoxyethylene formaldehyde condensation products, sodium alkyl benzene sulfonate, sodium alkyl sulfate, alkyl phosphoric acid sodium, phenethyl phenol polyethenoxy ether sodium sulfate and alkylphenol-polyethenoxy base sodium sulphate;
Dispersant can be Fluhyzon formaldehyde condensation products sodium sulfonate, alkylphenol formaldehyde condensation product sodium sulphate, sodium lignin sulfonate, a kind of to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, polycarboxylic acids sodium;
Disintegrant can be a kind of of bentonite, Attapulgite, starch, inorganic sodium, white carbon and silica gel;
Thinner can be a kind of of kaolin, precipitated calcium carbonate, diatomite, potter's clay, white clouds tin soil;
Binding agent can be a kind of of denaturated sodium polyacrylate 80, No. 72, polyethylene glycol, No. 3, modified polyvinyl alcohol, No. 45, lignin, No. 54, lignin, modified polyacrylic acid sodium 50.
Owing to added the auxiliary agent of heterogeneity, make the present invention have the active component content height among the present invention, environmental pollution is little, and disintegration rate is fast, and dispersive property reaches heat storage steady performance well, bactericidal potency height in use, and safety is good.
Description of drawings
Accompanying drawing is preparation method's of the present invention process chart.
Embodiment
The present invention will be described in more detail below in conjunction with drawings and Examples:
Embodiment 1
Take by weighing carbendazim original powder 77%, wetting agent phenethyl phenol polyethenoxy ether formaldehyde 3%, dispersant sodium lignin sulfonate 3%, disintegrant white carbon 4%, thinner precipitated calcium carbonate 8%, it is pressed conventional method mix, after stirring, obtain female powder through the airslide disintegrating mill pulverizing, denaturated sodium polyacrylate 80 binding agents of female powder and 5% are mixed, granulation then, oven dry, sieving obtains about 96% 75% carbendazim water-dispersible granules.Through the check active constituent content is 76.8%, moisture≤2.5%, and pH value 7.8, screening (by 75 μ m sieve) 〉=98%, suspensibility 〉=65%, lasting foaming characteristic (1min)≤10mL, wetability≤1min, dust≤3.0%, the acceleration heat storage stability is qualified.Being used to prevent and treat apple tree ring spot dosage in force is 750～937.5mg/kg, and control efficiency is 73～88%.
Embodiment 2
Take by weighing carbendazim original powder 78%, wetting agent di-2-ethylhexylphosphine oxide benzene sulfonic acid sodium salt 3%, dispersant sodium lignin sulfonate 4%, disintegrant white carbon 5%, thinner precipitated calcium carbonate 5%, after it is mixed, pulverize through airslide disintegrating mill and to obtain female powder, No. 72 binding agents of polyethylene glycol of female powder and 5% are mixed granulation then, oven dry, sieving obtains about 96% 75% carbendazim water-dispersible granules.Through the check active constituent content is 75.5%, moisture≤2.5%, and pH value 7.3, screening (by 75 μ m sieve) 〉=98%, suspensibility 〉=65%, lasting foaming characteristic (1min)≤10mL, wetability≤1min, dust≤3.0%, the acceleration heat storage stability is qualified.Being used to prevent and treat apple tree ring spot dosage is 750～937.5mg/kg, and control efficiency is 79～92%.
Embodiment 3
Take by weighing carbendazim original powder 53%, wetting agent neopelex 6%, dispersant sodium lignin sulfonate 8%, Attapulgite disintegrant 6%, Barden 21%, after it is mixed, pulverize through airslide disintegrating mill and to obtain female powder, No. 72 binding agents of polyethylene glycol of female powder and 6% are mixed granulation then, oven dry, sieving obtains about 97% 50% carbendazim water-dispersible granules.Through the check active constituent content is 50.3%, moisture≤2.5%, and pH value 7.3, screening (by 75 μ m sieve) 〉=98%, suspensibility 〉=65%, lasting foaming characteristic (1min)≤10mL, wetability≤1min, dust≤3.0%, the acceleration heat storage stability is qualified.Being used to prevent and treat apple tree ring spot dosage is 750～937.5mg/kg, and control efficiency is 71～86%.
Embodiment 4
Take by weighing carbendazim original powder 54%, wetting agent neopelex 7%, dispersant sodium lignin sulfonate 9%, disintegrant sodium carbonate 6%, thinner diatomite 17%, after it is mixed, pulverize through airslide disintegrating mill and to obtain female powder, No. 54 binding agents of lignin of female powder and 7% are mixed granulation then, oven dry, sieving obtains about 96% 50% carbendazim water-dispersible granules.Through the check active constituent content is 51.2%, moisture≤2.5%, and pH value 6.8, screening (by 75 μ m sieve) 〉=98%, suspensibility 〉=65%, lasting foaming characteristic (1min)≤10mL, wetability≤1min, dust≤3.0%, the acceleration heat storage stability is qualified.Being used to prevent and treat apple tree ring spot dosage is 750～937.5mg/kg, and control efficiency is 73～91%.
Embodiment 5
Take by weighing carbendazim original powder 43%, wetting agent di-2-ethylhexylphosphine oxide benzene sulfonic acid sodium salt 8%, dispersant is to methyl fatty acid amide benzene sulfonic acid sodium salt 9%, disintegrant sodium carbonate 7%, thinner diatomite 24%, after it is mixed, pulverize through airslide disintegrating mill and to obtain female powder, modified polyacrylic acid sodium 50 binding agents of female powder and 9% are mixed granulation then, oven dry, sieving obtains about 95% 40% carbendazim water-dispersible granules.Through the check active constituent content is 40.8%, moisture≤2.5%, and pH value 6.9, screening (by 75 μ m sieve) 〉=98%, suspensibility 〉=65%, lasting foaming characteristic (1min)≤10mL, wetability≤1min, dust≤3.0%, the acceleration heat storage stability is qualified.Being used to prevent and treat apple tree ring spot dosage is 750～937.5mg/kg, and control efficiency is 69～83%.
Embodiment 6
Take by weighing carbendazim original powder 42%, wetting agent sodium methylene bis-naphthalene sulfonate 8%, is dispersant to methyl fatty acyl amido benzene sulfonic acid sodium salt 10%, disintegrant sodium chloride 8%, thinner diatomite 24%? after it is mixed, pulverize through airslide disintegrating mill and to obtain female powder, No. 54 binding agents of lignin of female powder and 8% are mixed granulation then, oven dry, sieving obtains about 96% 40% carbendazim water-dispersible granules.Through the check active constituent content is 40.6%, moisture≤2.5%, and pH value 7.5, screening (by 75 μ m sieve) 〉=98%, suspensibility 〉=65%, lasting foaming characteristic (1min)≤10mL, wetability≤1min, dust≤3.0%, the acceleration heat storage stability is qualified.Being used to prevent and treat apple tree ring spot dosage is 750～937.5mg/kg, and control efficiency is 72～89%.
In order to make those of ordinary skill in the art understand the present invention better, the invention provides the preparation method who is used for the carbendazim water-dispersible granules, following steps are arranged:
A), choose raw material, it is mixed according to the prescription of carbendazim water-dispersible granules;
B), after carrying out ultramicro grinding with above mixture, airslide disintegrating mill obtains female powder;
C), the female powder that obtains after the ultramicro grinding is mixed by prescription and binding agent;
D), above mixture is carried out granulation on comminutor;
E), above shot-like particle is dried;
F), the shot-like particle with oven dry promptly obtains the carbendazim water-dispersible granules after sieving.
The carbendazim water-dispersible granules that adopts prescription of the present invention to process, its implementation result show that this product has good dispersiveness, and working substance suspends indefinite duration; Disintegration rate is fast, and disintegration time is less than 3min; Heat storage stability is good; And the height of adhesion rate in use, lasting period are long.The present invention is the bactericidal potency height in production application, through evidence, all can reach more than 80% to control efficiency such as the scab of multiple fruit tree cotton paddy rice and wheat etc., ring spot, damping off, rice blast; Safety is good, and crops are not had poisoning.
Owing to added the auxiliary agent of heterogeneity, make the present invention have the active component content height among the present invention, environmental pollution is little, and disintegration rate is fast, and dispersive property reaches heat storage steady performance well, bactericidal potency height in use, and safety is good.
Claims (7)
1, a kind of carbendazim water-dispersible granules, its effective ingredient is a carbendazim, it is characterized in that carbendazim is rule or irregular particle shape.
2, realize the prescription of carbendazim water-dispersible granules, it is characterized in that this prescription is as follows by percentage to the quality:
Carbendazim original powder: 40%～80%
Wetting agent: 2%～8%
Dispersant: 3%～10%
Disintegrant: 3%～8%
Thinner: 5%～40%
Binding agent: 3%～10%.
3, prescription according to claim 3, it is characterized in that wherein: wetting agent can be a kind of of phenethyl phenol polyethenoxy ether condensation product, alkylphenol polyoxyethylene formaldehyde condensation products, sodium alkyl benzene sulfonate, sodium alkyl sulfate, alkyl phosphoric acid sodium, phenethyl phenol polyethenoxy ether sodium sulfate and alkylphenol-polyethenoxy base sodium sulphate;
4, prescription according to claim 3, it is characterized in that wherein: dispersant can be Fluhyzon formaldehyde condensation products sodium sulfonate, alkylphenol formaldehyde condensation product sodium sulphate, sodium lignin sulfonate, a kind of to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, polycarboxylic acids sodium;
5, prescription according to claim 3 is characterized in that, wherein: disintegrant can be a kind of of bentonite, Attapulgite, starch, inorganic sodium, white carbon and silica gel;
6, prescription according to claim 3 is characterized in that, wherein: thinner can be a kind of of kaolin, precipitated calcium carbonate, diatomite, potter's clay, white clouds tin soil;
7, prescription according to claim 3 is characterized in that, wherein: binding agent can be a kind of of denaturated sodium polyacrylate 80, No. 72, polyethylene glycol, No. 3, modified polyvinyl alcohol, No. 45, lignin, No. 54, lignin, modified polyacrylic acid sodium 50.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410026345 CN1596647A (en) | 2004-07-21 | 2004-07-21 | Carbendazin water dispersable particle agent and its formula |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410026345 CN1596647A (en) | 2004-07-21 | 2004-07-21 | Carbendazin water dispersable particle agent and its formula |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1596647A true CN1596647A (en) | 2005-03-23 |
Family
ID=34663919
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410026345 Pending CN1596647A (en) | 2004-07-21 | 2004-07-21 | Carbendazin water dispersable particle agent and its formula |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1596647A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101785456A (en) * | 2010-02-24 | 2010-07-28 | 深圳诺普信农化股份有限公司 | Benzimidazole-contained bactericide water dispersible granule and preparation method thereof |
| CN101238813B (en) * | 2007-08-07 | 2011-08-17 | 甘肃省农业科学院植物保护研究所 | Granule for preventing and controlling melon vegetable soil-borne disease of melon or vegetable |
| CN102228043A (en) * | 2011-05-06 | 2011-11-02 | 浙江泰达作物科技有限公司 | Bactericide water dispersible granules compounded from difenoconazole and pyraclostrobin and preparation method thereof |
| CN107041389A (en) * | 2017-06-15 | 2017-08-15 | 程艳秋 | A kind of composition pesticide of promotion agro based economic development |
| CN118489689A (en) * | 2024-07-19 | 2024-08-16 | 山东中新科农生物科技有限公司 | A kind of carbendazim wettable powder and its preparation method and application |
-
2004
- 2004-07-21 CN CN 200410026345 patent/CN1596647A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101238813B (en) * | 2007-08-07 | 2011-08-17 | 甘肃省农业科学院植物保护研究所 | Granule for preventing and controlling melon vegetable soil-borne disease of melon or vegetable |
| CN101785456A (en) * | 2010-02-24 | 2010-07-28 | 深圳诺普信农化股份有限公司 | Benzimidazole-contained bactericide water dispersible granule and preparation method thereof |
| CN101785456B (en) * | 2010-02-24 | 2014-04-16 | 深圳诺普信农化股份有限公司 | Benzimidazole-contained bactericide water dispersible granule and preparation method thereof |
| CN102228043A (en) * | 2011-05-06 | 2011-11-02 | 浙江泰达作物科技有限公司 | Bactericide water dispersible granules compounded from difenoconazole and pyraclostrobin and preparation method thereof |
| CN107041389A (en) * | 2017-06-15 | 2017-08-15 | 程艳秋 | A kind of composition pesticide of promotion agro based economic development |
| CN118489689A (en) * | 2024-07-19 | 2024-08-16 | 山东中新科农生物科技有限公司 | A kind of carbendazim wettable powder and its preparation method and application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100586284C (en) | Zhongshengmycin wettable powder and preparation method thereof | |
| CN101518236B (en) | Imidacloprid water dispersible granule | |
| CN102258037B (en) | Containing the bactericidal composition of benziothiazolinone and Tebuconazole | |
| CN101176448B (en) | Bismerthiazol water dispersible granula bactericide and preparation method thereof | |
| CN103704222B (en) | Zinc thiazole water dispersible granules and preparation method thereof | |
| CN101874491A (en) | Effervescent tablet containing propiconazole and preparation method thereof | |
| CN101999348A (en) | Preparation method of pesticide effervescent tablet | |
| CN102726379A (en) | Pyraclostrobin water dispersible granule and preparation method thereof | |
| CN1596647A (en) | Carbendazin water dispersable particle agent and its formula | |
| CN1278609C (en) | Thiophthanate methyl water dispersible granular agent and its formula | |
| CN100588322C (en) | Tebuconazole water dispersible granule and preparation method thereof | |
| CN1957704A (en) | Water dispersion granules agent of dithane | |
| CN1298644A (en) | Herbiciding effervescent tablet for paddy rice | |
| CN100588321C (en) | Diniconazole water dispersible granule and preparation method thereof | |
| CN101194608A (en) | Tiger glue adipic acid copper water dispersion granula | |
| CN101204151A (en) | Epoxiconazole water dispersant and preparation method thereof | |
| CN101204153A (en) | Triflumizole water dispersant and preparation method thereof | |
| CN101156590A (en) | copperoxychioride water dispersion granula and method for making same | |
| CN100348104C (en) | Water dispersive myclobutanil particle and formula | |
| CN102007934B (en) | Bactericidal composition containing phosethyl-Al and antibiotic compound | |
| CN101999397A (en) | Phosethy-Al and folpet water dispersible granule and preparation method thereof | |
| CN102204552A (en) | Antibacterial composition containing enestroburin and antibiotic compound | |
| CN101731222A (en) | Ethirimol water dispersible granules | |
| CN102047893B (en) | Bactericidal composition containing captan and antibiotic compound | |
| CN101167464B (en) | Clofentezine water dispersible granule and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |