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CN1446618A - External pressure pillar type hollow fiber films subassemblies capable of air blast - Google Patents

External pressure pillar type hollow fiber films subassemblies capable of air blast Download PDF

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Publication number
CN1446618A
CN1446618A CN03121949A CN03121949A CN1446618A CN 1446618 A CN1446618 A CN 1446618A CN 03121949 A CN03121949 A CN 03121949A CN 03121949 A CN03121949 A CN 03121949A CN 1446618 A CN1446618 A CN 1446618A
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membrane
flux
membrane module
hollow fiber
air
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CN1199717C (en
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文湘华
黄霞
俞开昌
卜庆杰
孙友峰
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Tsinghua University
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Tsinghua University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
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Abstract

一种可气冲的外压柱式中空纤维膜组件,涉及一种中空纤维膜组件的结构设计及其使用方法。本发明的主要技术特征是在膜组件底部的膜丝中间设有专用的气冲部件;并通过设定膜组件壳柱体的高径比,膜丝的长径比、膜组件的装填密度来合理规范气、水的运动轨迹和二相流的流态,同时使膜组件在选定的操作条件下的次临界通量操作区域工作。采用本发明可在维持较低的曝气量的情况下,有效地控制膜污染的发展,维持较高的膜通量,降低运行能耗,实现并维持膜组件的长期运行。

Figure 03121949

An air flushable external pressure column type hollow fiber membrane module relates to the structural design and use method of a hollow fiber membrane module. The main technical feature of the present invention is that a special air flushing part is arranged in the middle of the membrane filaments at the bottom of the membrane module; Reasonably standardize the trajectory of gas and water and the flow state of two-phase flow, and at the same time make the membrane module work in the subcritical flux operating area under the selected operating conditions. The invention can effectively control the development of membrane fouling while maintaining a low aeration rate, maintain high membrane flux, reduce operating energy consumption, and realize and maintain long-term operation of membrane modules.

Figure 03121949

Description

A kind of annoying external pressure pillar hollow fiber film assembly that dashes
Technical field
The present invention relates to a kind ofly, relate in particular to a kind of structure design and using method thereof of hollow fiber film assembly, belong to membrane bioreactor and wastewater treatment and reuse technical field at the employed membrane module of membrane bioreactor.
Background technology
(Membrane Bioreactor MBR) is a kind of new and effective wastewater treatment and reuse technology with membrane separation technique and the combination of traditional biological treatment technology to film-bioreactor.In the application of film-bioreactor, need the larger area film usually.The minimum unit that film is installed is called as membrane module.Membrane module has a variety of forms, can be divided into two big classes basically: tubular type and flat.Membrane module form commonly used has flat sheet membrane, tubular membrane, capillary membranes, hollow fiber film assembly or the like, and its performance sees Table 1-1.
Table 1-1 membrane module performance table look-up
Project Tubular membrane component Plate basket formula membrane module Rolled membrane module The capillary type membrane module Hollow fiber film assembly
External diameter ??6~25mm - ??- ??0.5~2mm ??40~500um
Feed liquid flows Walk in the pipe - ??- Walk in the pipe In walking to manage or outside the pipe
Supporting tube Have - ??- Do not have Do not have
Packing density Low Lower Medium High Very high
Membrane area Very little Medium Medium Medium Very big
The face shearing rate Very high Medium Medium Medium Very low
Membrane flux Greatly Greatly Medium Greatly Little
Cost High Medium Medium Low Very low
Pollution condition Be difficult for polluting Be difficult for polluting Be difficult for polluting Easily stop up Easily stop up
The cleaning situation Easy cleaning Easy cleaning Easy cleaning not Easy cleaning not Easy cleaning not
Range of application Micro-filtration, ultrafiltration, reverse osmosis Micro-filtration, ultrafiltration, reverse osmosis, gas delivery Reverse osmosis, nanofiltration, gas delivery, pervaporation Ultrafiltration, gas delivery, membrane distillation, pervaporation Micro-filtration, ultrafiltration, reverse osmosis
From table 1-1 as can be seen: because hollow-fibre membrane packing density and membrane area are very big, low price, and overcome the not withstand voltage shortcoming of capillary type membrane module, in wastewater treatment, be used widely at present.
For a membrane sepn process, select which type of membrane module to depend on two aspects: one is the character of film itself, and another is the singularity of process.In membrane bioreactor and since handle to as if mud, it is inevitably that film pollutes, and relatively more serious, the amount of sewage is all bigger simultaneously, so should select anti-pollution, kit form that membrane flux is big.Carrying out along with the membrane sepn process, macromolecular substance in the solution, dissolved substance are adsorbed to the film surface, and then enter inner fenestra and the depositional phenomenon of particulate matter on the film surface stopped up of fenestra and be called film and pollute, film promptly shows as the increase of membrane resistance and the decline of membrane flux after polluting.In general, in membrane bioreactor, make the two big class materials that mainly contain that film pollutes.One class is macromolecular substance, the dissolved matter (as microbial metabolites SMP) in the solution, and this class material can be adsorbed to film surface and form gel coat, perhaps and then enter the inner fenestra that stops up of fenestra, is called irreversible pollution.Another kind of material is granular material, carrying out along with the membrane sepn process, this class material can form cake layer at the film surface deposition, the film that grows up like this pollutes often to pollute in the total-resistance at film and occupies bigger ratio, but this pollution generally is a reversible, be called reversible pollution, development how to adopt effective physical means to control reversible pollution is that biological the sending out of film answered the key that controlling diaphragm pollutes in the device.
According to the position that is provided with of membrane module, film-bioreactor can be divided into separated type film-bioreactor and integral type (or immerseable, built-in) film-bioreactor two big classes.Traditional external membrane bioreactor generally adopts column-type film components, and takes the water power operator scheme of single-phase cross flow filter, the water-out manners of the film forming driving pressure of malleation shape that provides by recycle pump.It has, and membrane flux is big, film cleans convenient two main advantages.But, for controlling diaphragm effectively pollutes, often needing bigger crossflow velocity, required flow and lift are bigger, energy consumption also big (be built-in membrane bioreactor 4~6 times).Traditional integral type film biological reactor generally adopts curtain type film assembly, utilizes gas to put forward principle, forms an air water two-phase flow and flows district's circulation in the up-flow district with falling, and the film surface is washed away, and controlling diaphragm pollutes.The water-out manners of the film forming driving pressure of suction pump aspiration vacuum shape that adopts.Its major advantage is that energy consumption is relative to low than external placed type, and land used is economized, but its film cleans inconvenience, and it is higher that film cleans cost, and membrane flux is also less relatively.And, be suspension in the whole reactor because gas carries, the fluid section of air water two-phase flow is also bigger, and how reducing its energy consumption still is people's a significant concern point.About 1.0~the 2.4kwh/m of processing energy consumption of present integral type film biological reactor unit's water yield of using 3(turn round and look at equality, 2000, Chinese water supply and drainage Vol.16 (3), 5-8; Tatsuki Ueda and Kenji Hata 1999, waterreseach, 33,2888-2892).
Can design novel membrane module, external membrane bioreactor and built-in membrane bioreactor are organically combined, get separately the chief, mend shortage separately, make it have that energy consumption is low, flux big, film pollutes slower development, film cleans characteristics easily.
Summary of the invention
Purpose of the present invention just provides a kind of annoying external pressure pillar hollow fiber film assembly that dashes, under the situation of keeping lower aeration rate, higher membrane flux is kept in the development of controlling diaphragm pollution effectively, further reduce its operation energy consumption, realize and keep its long-time running.
The objective of the invention is to be achieved through the following technical solutions.
A kind of annoying external pressure pillar hollow fiber film assembly that dashes, mainly comprise membrane module shell cylinder, be arranged on the intravital U shape of shell post hollow-fibre membrane silk, the material liquid outlet at top, be arranged on the liquor inlet and fixed area that is used for fixing the adhesive film silk and permeate water outlet of bottom, it is characterized in that: in the middle of the film silk of hollow fiber film assembly bottom, is provided with special-purpose gas towards parts.
Gas described in the present invention can adopt boring aeration pipe, micropore aeration pipe or micro porous aeration head towards parts.
Feature of the present invention also is the fluidised form of the movement locus and the two-phase flow of reasonable standard gas, water.This mainly is that the length-to-diameter ratio of film silk, the packing density of membrane module realize by the aspect ratio of setting membrane module shell post.The aspect ratio of the shell cylinder of membrane module of the present invention is 5~20: 1; Described membrane module the length-to-diameter ratio of film silk be 50~300: 1; The film silk packing density of described membrane module is 500~1500m 2/ m 3
The present invention also provides a kind of using method of the annoying external pressure pillar hollow fiber film assembly that dashes, i.e. utilization " subcritical flux methodology " rationally, make the subcritical flux operating area work of membrane module under selected operational condition, described subcritical flux operating area adopts flux stepwise incremental method to determine, can carry out as follows:
(1) under the Xuan Ding operational condition, adopt the method for permanent flux to make a time period of film work Δ T be at least 30min, the variation of observation membrane operations pressure in Δ T, constant if membrane operations pressure keeps, regulate the progression of water outlet suction pump, make membrane flux increase a rank amount; Again observe the variation of membrane operations pressure in another Δ T, so continue, till membrane operations pressure occurring and in Δ T, can not stablizing;
(2) note membrane flux at this moment is F N+1, i.e. F N+1For under this operational condition, making the membrane flux of the minimum that membrane operations pressure goes up, F NMembrane flux for the maximum of membrane operations constant pressure under this operational condition; Then critical flux is between F N+1And F NBetween, greater than F N+1Flux regions be called overcritical flux regions under this operational condition, less than F NFlux regions be called subcritical flux regions under this operational condition, make membrane module in this subcritical flux operating area work.
The present invention compares with existing hollow fiber film assembly, has the following advantages and the high-lighting effect:
(1) flux is big, and its working flux can reach 15~30L/m 2H.The known membrane flux that generally is used for the hollow fiber film assembly of integral type film biological reactor only is 5~10L/m 2H.
(2) gas-water ratio can be reduced to 20~25: 1, thereby cuts down the consumption of energy.The known gas-water ratio that generally is used for the hollow fiber film assembly of integral type film biological reactor is 40~60: 1.
(3) reduce face cross-flow velocity to 0.04~0.1m/s greatly, thereby reduce circular flow and energy consumption.The known face cross-flow velocity that generally is used for separate film biological reactor is 2~4m/s.
(4) antifouling property is good, owing to directly concentrate aeration in membrane module, is 20~25: 1 o'clock at aeration rate like this, and its aeration intensity just can reach 125~200m 3/ m 2H.Therefore can increase the turbulent fluctuation of membrane module fluidic greatly, the control particulate matter improves the antifouling property of membrane module greatly in the deposition on film surface.
Description of drawings
Fig. 1 is the structural representation that is used for the external pressure pillar hollow fiber film assembly of separate film biological reactor provided by the invention.
Fig. 2 is the external pressure pillar hollow fiber film assembly structural representation that is used for integral type film biological reactor provided by the invention.
Fig. 3 represents that external pressure pillar hollow fiber film assembly is used for the process device figure of separate film biological reactor.
Fig. 4 represents that external pressure pillar hollow fiber film assembly is used for the process device figure of integral type film biological reactor.
Embodiment
Below in conjunction with drawings and Examples technical solution of the present invention is further described.
Fig. 1 is the structural representation that is used for the external pressure pillar hollow fiber film assembly of separate film biological reactor provided by the invention.Its main composition comprises that " U " shape hollow-fibre membrane silk 1, membrane module shell cylinder 2, gas export 5 towards liquor inlet 6, the permeate water of parts 3, bottom, the material liquid outlet 7 at top, piezometric tube interface 8 and film silk bonding fixed area 4.
Fig. 2 is the external pressure pillar hollow fiber film assembly structural representation that is used for integral type film biological reactor provided by the invention.Its main composition comprises that " U " shape hollow-fibre membrane silk 1, membrane module shell cylinder 2, gas export 5 towards liquor inlet 6, the permeate water of parts 3, bottom, the material liquid outlet 7 at top and film silk bonding fixed area 4.
Fig. 3 represents that external pressure pillar hollow fiber film assembly is used for the process device figure of separate film biological reactor.This installs by bio-reactor 9, circulating water inlet 13, recycle pump 14, air feeder 10, water outlet suction pump 11, top water inlet pipe 12, pressure warning unit 15 and external pressure pillar hollow fiber film assembly are formed, and the gas that is arranged on membrane module bottom is connected with air feeder 10 towards parts 3.Gas forms the air water two-phase flow with the water outlet of recycle pump and pollutes with controlling diaphragm in membrane module.And the air water two-phase flow flows into from reactor 9 bottoms, makes that on the one hand the feed liquid in the reactor is mixed fully, provides oxygen for the microorganisms in the reactor 9 on the other hand.Mix fully after circulating water inlet 13 is injected in the membrane modules by recycle pump 14 with reactor 9 interior feed liquids by the 12 former water that flow into.The film permeate water is discharged by water outlet suction pump 11 through seeing through water pipe 5.
Fig. 4 represents that external pressure pillar hollow fiber film assembly is used for the process device figure of integral type film biological reactor.This installs by bio-reactor 9, air feeder 10, and water outlet suction pump 11, top water inlet pipe 12 and external pressure pillar hollow fiber film assembly are formed.The gas that is arranged on membrane module bottom is connected with air feeder 10 towards parts 3.Membrane module shell side bottom is provided with opening, when air feeder is given the membrane module aeration, with membrane module shell post jamb is the water conservancy diversion ring flat-plate, in membrane module, form the ascending zone of air water two-phase flow, between membrane module shell post jamb and reactor wall, form the district that descends, thereby form round-robin air water two-phase flow.
The aspect ratio of membrane module shell cylinder is (5-20) among the present invention: 1, the fluidised form of air water unstable flow is a standard to form the Taylor bubble, plenum system can freely be evenly distributed on the membrane module cylinder transverse section bubble for using perforated pipe, micro-filtrate, micro porous aeration head or other vesicular material the centre of gas importing membrane module body skin inner membrance silk.
Unstable fluid motion is meant that in flow system relevant physical quantitys such as flow rate of fluid, pressure, density not only change with the position on each face, and time to time change.Compare with the stable state turbulent flow, unstable flow can both be played the intensive filtration effect under laminar flow and turbulence state, fluid unstable flow flowing mode is that a kind of strengthening effect is good, energy is lower, the simple practical technique of equipment, and efficient to designing, resistant to pollution membrane module has very big pushing effect.The air water two-phase flow is a kind of unstable flow, and appropriate membrane module shell cylinder aspect ratio makes the fluidised form of air water two-phase flow be able to effective development, even under the very little situation of quantity of circulating water, mixes with appropriate tolerance, also is enough to form the intensive unstable flow.
For hollow-fibre membrane, the length of film silk and the ratio of diameter directly influence fluidised form and the film silk axial flux of permeate water in the film silk and distribute.If film silk length-to-diameter ratio is excessive, then the non-outlet terminal membrane flux partly near the film silk will be little more a lot of than the outlet terminal membrane flux partly of film silk, cause the membrane flux skewness.If the film filament diameter is excessive, then can too reduce the specific surface area of film silk.The film silk length-to-diameter ratio that the present invention requires is: 50~300: 1.
The packing density of membrane module can exert an influence to the fluidised form of air water two-phase flow, and packing density is excessive, and the film silk does not just have enough vibration spaces, and turbulent fluctuation will weaken, and is unfavorable for controlling the deposition of particulate matter.The too small meeting of packing density causes the economy of membrane module to descend, and the membrane module packing density that the present invention requires is: 500~1500m 2/ m 3
When the present invention also requires membrane module work, continuous air feed, but membrane module adopts the intermittent suction water outlet.
The present invention rationally uses " subcritical flux methodology " to determine the membrane module using method of film working flux.Critical flux is one and film is polluted the notion that extremely important meaning is arranged, it is meant and has a threshold value in permanent flux filters, when membrane flux was worth greater than this, membrane operations pressure TMP (Transmembrane Pressure) rose rapidly, and film pollutes sharply development; When membrane flux was worth less than this, the film pollution did not take place or develops very slow.Critical flux is relevant with waterpower operational condition, membrane sepn operator scheme, feed liquid character and the character of film own.The subcritical operation of membrane bioreactor just is based on such notion, and under certain operational condition, it is following to obtain the operation of membrane bioreactor long-term stability to make membrane flux maintain critical flux.
Usually, polluted membrane two big class materials are arranged: a class is deliquescent macromolecular substance, as solvability microbial product (Soluble Microbial Products, be called for short SMP) and extracellular polymeric (Extracelluar Polymers, abbreviation ECP is along with the carrying out of membrane sepn, this class material can be adsorbed to the film surface and form gel coat (Gel Layer), it generally is irreversible polluting, but development is comparatively slow, is called irreversible pollution (Irreversible Fouling).Another kind of material is a particulate matter, as the mud flco, this class material forms sludge blanket (Cake Layer) at the film surface deposition, pollution is a reversible, be called reversible pollution (Reversible Fouling), this class is polluted and occupy very big deal (more than 80%) in dead-end filtration, and development rapidly, and it also is the main object of film polluted water kinetic control.In membrane bioreactor, critical flux is also at reversible pollution, and the dominant ideas of subcritical operation are exactly to make film in the process of operation, avoid as far as possible mud granule deposition, avoid reversible pollution.
Embodiment 1
Please refer to Fig. 3 external pressure pillar hollow fiber film assembly and be used for the separate film biological reactor process device figure.The shell cylinder aspect ratio of compression leg formula hollow fiber film assembly is 11: 1 in addition, hollow-fibre membrane silk length-to-diameter ratio 200: 1, film silk packing density 829m 2/ m 3, membrane area 0.5m 2When the mixed solution sludge concentration was 3~10g/L in the reactor, membrane flux can reach 20L/m 2H, recycle pump quantity of circulating water 200L/h, lift 2.0m, unit total efficiency 0.49, then the energy consumption of processed in units water yield water circulating pump is 0.21kwh/m 3Face cross-flow flow velocity can be controlled in 0.04~0.06m/s, and is little more a lot of than the cross-flow velocity 3~4m/s of known separate film biological reactor technology.Aeration rate 250L/h, the 20kPa that boosts, air blast efficient 0.44, then the energy consumption of processed in units water yield gas blower is 0.35kwh/m 3Gas-water ratio only is 25: 1, than the gas-water ratio (40~60: 1) little a lot of of known integral type film biological reactor.Suction pump flow 10L/h, lift 10m, unit total efficiency 0.49, then processed in units water yield suction pump energy consumption 0.06kwh/m 3Then processed in units water yield total energy consumption is 0.62kwh/m 3, than the processed in units water yield energy consumption 3.0~5.5kwh/m of known cross-flow separate film biological reactor 3Little a lot.
Concentrate aeration owing to adopt, make that the aeration intensity in the membrane module can reach 160 ~ 190m 3/ m 2H, the turbulent fluctuation that this has just increased the air water two-phase flow greatly helps controlling particulate matter reaches the reversible pollution of controlling diaphragm in the deposition on film surface purpose, and the rate of increase of the membrane operations pressure of system is 0.15kPa/d.Thereby realize the permanent stable operation of membrane bioreactor.
Embodiment 2
Please refer to Fig. 4 external pressure pillar hollow fiber film assembly and be used for the integral type film biological reactor process device figure.The shell cylinder aspect ratio of compression leg formula hollow fiber film assembly is 6: 1 in addition, hollow-fibre membrane silk length-to-diameter ratio 100: 1, film silk packing density 702m 2/ m 3, membrane area 1.0m 2When the mixed solution sludge concentration was 3~10g/L in the reactor, membrane flux can reach 15L/m 2H, aeration rate 390L/h, the 20kPa that boosts, air blast efficient 0.44, then the energy consumption of processed in units water yield gas blower is 0.49kwh/m 3Gas-water ratio only is 26: 1, than the gas-water ratio (40~60: 1) little a lot of of known integral type film biological reactor.Suction pump flow 15L/h, lift 10m, unit total efficiency 0.49, then processed in units water yield suction pump energy consumption 0.06kwh/m 3Then processed in units water yield total energy consumption is 0.55kwh/m 3, than the processed in units water yield energy consumption 1.0~2.4kwh/m of known integral type film biological reactor 3Little a lot.
But the aeration intensity in the membrane module can reach 130~150m 3/ m 2H, the turbulent fluctuation that this has just increased the air water two-phase flow greatly helps controlling particulate matter reaches the reversible pollution of controlling diaphragm in the deposition on film surface purpose, and the rate of increase of the membrane operations pressure of system is 0.25kPa/d.Thereby realize the permanent stable operation of membrane bioreactor.

Claims (6)

1.一种可气冲的外压柱式中空纤维膜组件,主要包括膜组件壳柱体,设置在壳柱体内的U状中空纤维膜丝,顶部的料液出口,设置在底部的料液进口和用于固定粘结膜丝的固定区以及透过水出口,其特征在于:在中空纤维膜组件的底部的膜丝中间设有专用的气冲部件。1. An air flushable external pressure column type hollow fiber membrane module, mainly including a shell cylinder of the membrane module, a U-shaped hollow fiber membrane thread arranged in the shell cylinder, a feed liquid outlet at the top, and a feed liquid outlet at the bottom The inlet, the fixing area for fixing the bonding membrane filaments and the permeated water outlet are characterized in that a special air flushing part is arranged in the middle of the membrane filaments at the bottom of the hollow fiber membrane module. 2.按照权利要求1所述的一种可气冲的外压柱式中空纤维膜组件,其特征在于:所述的气冲部件采用穿孔曝气管、微孔曝气管或微孔曝气头。2. According to claim 1, a kind of air flushable external pressure column type hollow fiber membrane module is characterized in that: said air flushing part adopts perforated aeration tube, microporous aeration tube or microporous aeration tube head. 3.按照权利要求1或2所述的一种可气冲的外压柱式中空纤维膜组件,其特征在于:所述膜组件壳柱体的高径比为5~20∶1。3. An air flushable external pressure column type hollow fiber membrane module according to claim 1 or 2, characterized in that: the aspect ratio of the casing column of the membrane module is 5-20:1. 4.按照权利要求3所述的一种可气冲的外压柱式中空纤维膜组件,其特征在于:所述膜组件的膜丝的长径比为50~300∶1。4. The air flushable external pressure column type hollow fiber membrane module according to claim 3, characterized in that: the aspect ratio of the membrane filaments of the membrane module is 50-300:1. 5.按照权利要求4所述的一种可气冲的外压柱式中空纤维膜组件,其特征在于:所述的膜组件的膜丝装填密度为500~1500m2/m35 . The air flushable external pressure column type hollow fiber membrane module according to claim 4 , wherein the packing density of the membrane filaments of the membrane module is 500-1500 m 2 /m 3 . 6.一种如权利要求1所述可气冲的外压柱式中空纤维膜组件的使用方法,其特征在于:该方法是使膜组件在选定的操作条件下的次临界通量操作区域工作,所述的次临界通量操作区域采用通量阶式递增法确定,可按如下步骤进行:6. A method of using an air flushable external pressure column type hollow fiber membrane module as claimed in claim 1, characterized in that: the method is to make the membrane module operate in the subcritical flux operating area under selected operating conditions Work, the described subcritical flux operating area is determined by the flux step-up method, which can be carried out as follows: (1)选定的操作条件下,采用恒通量的方法使膜工作一个时间段ΔT至少为30min,观测膜操作压力在ΔT内的变化,若膜操作压力保持恒定,调节出水抽吸泵的级数,使膜通量增加一个阶量;重新观测膜操作压力在另一个ΔT内的变化,如此继续,直到出现膜操作压力在ΔT内不能稳定为止;(1) Under the selected operating conditions, use the method of constant flux to make the membrane work for a time period ΔT of at least 30min, observe the change of the membrane operating pressure within ΔT, if the membrane operating pressure remains constant, adjust the stage of the effluent suction pump number, to increase the membrane flux by one order; re-observe the change of the membrane operating pressure in another ΔT, and so on, until the membrane operating pressure cannot be stabilized within ΔT; (2)记此时的膜通量为FN+1,即FN+1为在这个操作条件下使膜操作压力上涨的最小的膜通量,FN在这个操作条件下膜操作压力恒定的最大的膜通量;则临界通量介于FN+1和FN之间,大于FN+1的通量区域叫做此操作条件下的超临界通量区域,小于FN的通量区域叫做此操作条件下的次临界通量区域,使膜组件在该次临界通量操作区域工作。(2) Record the membrane flux at this time as F N+1 , that is, F N+1 is the minimum membrane flux that increases the operating pressure of the membrane under this operating condition, and the operating pressure of F N is constant under this operating condition The maximum membrane flux; the critical flux is between F N+1 and F N , the flux region greater than F N+1 is called the supercritical flux region under this operating condition, and the flux less than F N The region is called the subcritical flux region under this operating condition, so that the membrane module works in this subcritical flux operating region.
CNB031219497A 2003-04-18 2003-04-18 External pressure pillar type hollow fiber films subassemblies capable of air blast Expired - Fee Related CN1199717C (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101234819B (en) * 2008-03-07 2010-06-09 北京汉青天朗水处理科技有限公司 Hollow fiber membrane module, film bioreactor and water treatment device
CN101234294B (en) * 2006-11-14 2010-11-10 旭化成化学株式会社 Filtering film component
CN104689719A (en) * 2013-12-05 2015-06-10 北京大井易通科技发展有限公司 Air-blast-available external pressure type hollow fiber membrane module with one fixed end
CN105004967A (en) * 2015-06-11 2015-10-28 国网山东省电力公司泰安供电公司 Power grid fault detection method and system
CN104998547A (en) * 2015-08-11 2015-10-28 无锡桥阳机械制造有限公司 External-compression hollow fibrous membrane component
CN101422699B (en) * 2008-12-02 2016-07-06 北京坎普尔环保技术有限公司 Gas stripping internal circulation filter and filtering method of liquid film
CN107001086A (en) * 2014-09-08 2017-08-01 埃墨伏希有限公司 Module, reactor, system and method for handling water
CN107285459A (en) * 2017-08-16 2017-10-24 广东优信力达环境科技有限公司 A kind of membrane bioreactor

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Publication number Priority date Publication date Assignee Title
CN101234294B (en) * 2006-11-14 2010-11-10 旭化成化学株式会社 Filtering film component
CN101234819B (en) * 2008-03-07 2010-06-09 北京汉青天朗水处理科技有限公司 Hollow fiber membrane module, film bioreactor and water treatment device
CN101422699B (en) * 2008-12-02 2016-07-06 北京坎普尔环保技术有限公司 Gas stripping internal circulation filter and filtering method of liquid film
CN104689719A (en) * 2013-12-05 2015-06-10 北京大井易通科技发展有限公司 Air-blast-available external pressure type hollow fiber membrane module with one fixed end
CN107001086A (en) * 2014-09-08 2017-08-01 埃墨伏希有限公司 Module, reactor, system and method for handling water
CN105004967A (en) * 2015-06-11 2015-10-28 国网山东省电力公司泰安供电公司 Power grid fault detection method and system
CN104998547A (en) * 2015-08-11 2015-10-28 无锡桥阳机械制造有限公司 External-compression hollow fibrous membrane component
CN107285459A (en) * 2017-08-16 2017-10-24 广东优信力达环境科技有限公司 A kind of membrane bioreactor
CN107285459B (en) * 2017-08-16 2024-05-03 陕西雷光环保科技有限公司 Membrane bioreactor

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