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CN1320150C - Gray cast iron alloy and cast internal combustion engine component - Google Patents

Gray cast iron alloy and cast internal combustion engine component Download PDF

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Publication number
CN1320150C
CN1320150C CNB03811027XA CN03811027A CN1320150C CN 1320150 C CN1320150 C CN 1320150C CN B03811027X A CNB03811027X A CN B03811027XA CN 03811027 A CN03811027 A CN 03811027A CN 1320150 C CN1320150 C CN 1320150C
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CN
China
Prior art keywords
alloy
cast iron
grey cast
vanadium
exists
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB03811027XA
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Chinese (zh)
Other versions
CN1653202A (en
Inventor
马尔蒂·彭蒂宁
托比亚斯·比约克林德
卡尔·比约克曼
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Scania CV AB
Original Assignee
Scania CV AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Publication of CN1653202A publication Critical patent/CN1653202A/en
Application granted granted Critical
Publication of CN1320150C publication Critical patent/CN1320150C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/08Making cast-iron alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/06Cast-iron alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/10Cast-iron alloys containing aluminium or silicon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cylinder Crankcases Of Internal Combustion Engines (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)

Abstract

A substantially perlitic, grey cast iron alloy comprising, by weight, 3.2 - 3.49% carbon, 1.8 - 2.2% silicon, < 0.15% sulphur, < 0.15% phosphorus, 0.3 - 0.8% manganese, 0.2 - 0.4% chromium, 0.1 - 0.4% molybdenum, 0.03 - 0.3% vanadium, 0.3 - 1.0% copper, < 0.15% niobium, the balance iron and impurities.

Description

Grey cast iron alloy and casting internal combustion engine component
Technical field
The present invention relates to a kind of grey cast iron alloy.More particularly, the present invention relates to a kind of grey cast iron of pearly-lustre basically, it also comprises the alloy element that improves fatigue strength.
The invention still further relates to the internal combustion engine component that derives from grey cast iron alloy of the present invention.
Background technology
Grey cast iron is low relatively owing to cost, and functional even excellent, so it is the most attracting material that for example is used for the internal combustion (IC) engine airframe of transportation means.The compositing range of known in the past grey cast iron is quite wide, and these form normally the performance at material therefor, for example tensile strength, polishing machine etc. and processability, for example compromise between cost, the machinability etc.
Therefore, with regard to the casting internal combustion (IC) engine airframe, basic material 0120 has 1 the composition of being listed in the table below, and the composition of common standard alloy is also listed in table 1, and therefore the Scania standard alloy provides grey cast iron and zero defect (atresia) material with perlitic structure because of having high relatively carbon content.
Yet although can accept fully at present, replenishing of the existing performance of conduct needs the fatigue strength of raising at present, and expands the possible purposes of this existing grey cast iron.
An object of the present invention is to provide a kind of grey cast iron, it has flawless relatively structure and good workability is provided, and compares with standard alloy in addition to have the fatigue strength that improves greatly.
Another object of the present invention provides a kind of grey cast iron internal combustion engine component, engine body for example, and it is compared with standard alloy has the fatigue strength that improves greatly.
Summary of the invention
The objective of the invention is that grey cast iron alloy by following a kind of pearly-lustre basically realizes, described grey cast iron comprises by weight:
The carbon of 3.2-3.49%,
The silicon of 1.8-2.2%,
<0.15% sulphur,
<0.15% phosphorus,
The manganese of 0.3-0.8%,
The chromium of 0.2-0.4%,
The molybdenum of 0.1-0.4%,
The vanadium of 0.03-0.3%,
The copper of 0.3-1.0%,
<0.15% niobium,
The titanium of 0.007-0.015%,
The nitrogen of 0.005-0.017%,
The iron of surplus and impurity.
In addition, purpose of the present invention also realizes by a kind of oil engine casting engine parts.Described oil engine casting engine parts are made by the grey cast iron alloy of pearly-lustre basically, and described alloy comprises:
The carbon of 3.2-3.49%,
The silicon of 1.8-2.2%,
<0.15% sulphur,
<0.15% phosphorus,
The manganese of 0.3-0.8%,
The chromium of 0.2-0.4%,
The molybdenum of 0.1-0.4%,
The vanadium of 0.03-0.3%,
The copper of 0.3-1.0%,
The titanium of 0.007-0.013%,
<0.15% niobium,
The nitrogen of 0.005-0.015%,
<0.01% aluminium,
The iron of surplus and impurity.
Description of drawings
Fig. 1 has shown the W  hler fatigue curve of basic alloy, standard alloy and alloy of the present invention.
Embodiment
In the following description, all per-cents of element all provide with weight percent in the concrete alloy.
Alloy of the present invention is to have the grey cast iron of perlitic structure basically, and its carbon content is 3.2-3.49%.Higher carbon content has promoted a kind of zero defect structure.Add the chromium of 0.2-0.4%, it has perlite/carbide stability, and the purified perlitic structure is provided.
Add molybdenum, the 0.03-0.3% of 0.1-0.4% vanadium, 0.007-0.015% titanium and<0.15% niobium, except its carbide forms performance, also work the nuclear core that makes cast iron (as the sedimentary carbide of primary and secondary) have refined pearl-like structure and flake graphite structure.Molybdenum can also at high temperature be stablized perlite.
Preferred vanadium exists to be lower than 0.1% amount, and aluminium exists to be lower than 0.01% amount, and nickel exists to be lower than 0.1% amount, and tin exists to be lower than 0.1% amount.
Silicon exists with the amount of 1.8-2.2%, promotes grey iron to form.
The manganese of 0.3-0.8% exists as the perlite stablizer.
Copper, the amount with 0.3-1.0% exists here, promotes perlite to form and stablize this perlite, also promotes the formation of refining structure.
The content of sulphur and phosphorus should remain on below 0.15%.
Nitrogen content is 0.005-0.017%, and it compresses flake graphite and promotes perlite to form, and aluminium content be<0.01%, plays graphite formation agent.
The grey cast iron alloy also comprises the iron and the normal impurity of surplus.Titanium, nitrogen and aluminium still can be through preferred in the normal impurities scope.
A kind of preferred grey cast iron alloy of the present invention comprises: the carbon of 3.3-3.4%, the silicon of 1.8-2.2%,<0.1% sulphur,<0.05% phosphorus, the manganese of 0.4-0.6%, the chromium of 0.2-0.4%, the molybdenum of 0.2-0.3% and the vanadium of 0.05-0.1%.
Oil engine casting engine parts of the present invention are engine body parts or cylinder head sub-assembly preferably.
Embodiment
The preparation 1500kg batch of material, each batch of material is cast into the engine body of 4 300kg, cast in begin under 1420 ℃ and in casting cycle temperature reduce about 10 ℃.
Use basic alloy, ten various combinations of preparation molybdenum, vanadium, titanium and niobium and batch of material.
And the content of nitrogen and aluminium forms agent (Inoculant) with different nuclear cores and changes in 16 different batch of materials.
Water the foundry goods from each and to extract the Fatigue Test sample and to carry out fatigue measurement.
Further, preparation have the optimum that shows said determination composition batch of material and carry out fatigue measurement.
The results are shown in Fig. 1, curve 3 is corresponding to the composition in compositing range of the present invention, and this composition also is presented at table 1.
Grey cast iron of the present invention provides the fatigue strength than grey cast iron basic alloy high about 40%, and the fatigue strength than model engine body grey cast iron high about 30% is provided, and the grey cast iron that obtains high performance at aspects such as workability, zero defects is provided.
As mentioned above, grey cast iron alloy of the present invention is specially adapted to oil engine foundry goods engine parts, engine body parts for example, and described alloy has workability, zero defect and high fatigue strength simultaneously.This alloy also can be used for other parts, for example cylinder head etc.
The composition of table 1. prior art and grey cast iron of the present invention, weight %
Alloy
Compound Basic alloy 0120 Standard alloy Conventional alloy of the present invention Preferred implementation The embodiment alloy 3 of Fig. 1
C 3.2-3.5 ~3.4 3.2-3.49 3.3-3.4 3.37
Si 1.8-2.3 ~2.0 1.8-2.2 1.8-2.2 1.8
S 0.06-0.15 <0.14 <0.15 <0.1 0.1
P <0.20 <0.10 <0.15 <0.05 0.05
Mn 0.6-0.8 0.6-0.8 0.3-0.8 0.4-0.6 0.68
Cr 0.2-0.35 0.2-0.4 0.2-0.4 0.34
Mo 0.1-0.4 0.2-0.3 0.26
V 0.03-0.3 0.05-0.1 0.1
Cu 0.4-0.8 0.3-1.0 0.5-1.0 0.6
Ni <0.1 <0.1
Ti 0.007-0.015 0.007-0.013 0.013
Nb <0.15 <0.10 0.04
N 0.005-0.017 0.005-0.015 0.010
Sn <0.1 <0.1
Al <0.01 <0.01

Claims (8)

1, a kind of grey cast iron alloy of pearly-lustre basically comprises by weight:
The carbon of 3.2-3.49%,
The silicon of 1.8-2.2%,
<0.15% sulphur,
<0.15% phosphorus,
The manganese of 0.3-0.8%,
The chromium of 0.2-0.4%,
The molybdenum of 0.1-0.4%,
The vanadium of 0.03-0.3%,
The copper of 0.3-1.0%,
<0.15% niobium,
The titanium of 0.007-0.015%,
The nitrogen of 0.005-0.017%,
The iron of surplus and impurity.
2, alloy as claimed in claim 1 comprises
The carbon of 3.3-3.4%,
The silicon of 1.8-2.2%,
<0.1% sulphur,
<0.05% phosphorus,
The manganese of 0.4-0.6%,
The chromium of 0.2-0.4%,
The molybdenum of 0.2-0.3% and
The vanadium of 0.05-0.1%.
3, alloy as claimed in claim 1 or 2 is characterised in that vanadium exists to be lower than 0.1% amount.
4, alloy as claimed in claim 1 or 2 is characterised in that aluminium exists to be lower than 0.01% amount.
5, alloy as claimed in claim 1 or 2 is characterised in that nickel exists to be lower than 0.1% amount.
6, alloy as claimed in claim 1 or 2 is characterised in that tin exists to be lower than 0.1% amount.
7, a kind of oil engine casting engine parts, it is made by the grey cast iron alloy of pearly-lustre basically, and described alloy comprises:
The carbon of 3.2-3.49%,
The silicon of 1.8-2.2%,
<0.15% sulphur,
<0.15% phosphorus,
The manganese of 0.3-0.8%,
The chromium of 0.2-0.4%,
The molybdenum of 0.1-0.4%,
The vanadium of 0.03-0.3%,
The copper of 0.3-1.0%,
The titanium of 0.007-0.013%,
<0.15% niobium,
The nitrogen of 0.005-0.015%,
<0.01% aluminium,
The iron of surplus and impurity.
8, parts as claimed in claim 7 are characterised in that it is engine body parts or cylinder head sub-assembly.
CNB03811027XA 2002-05-13 2003-05-12 Gray cast iron alloy and cast internal combustion engine component Expired - Fee Related CN1320150C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE0201431A SE526903C2 (en) 2002-05-13 2002-05-13 Gray iron alloy and cast internal combustion engine component
SE02014314 2002-05-13

Publications (2)

Publication Number Publication Date
CN1653202A CN1653202A (en) 2005-08-10
CN1320150C true CN1320150C (en) 2007-06-06

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EP (1) EP1506323B1 (en)
JP (1) JP4137054B2 (en)
KR (1) KR100616649B1 (en)
CN (1) CN1320150C (en)
AT (1) ATE477347T1 (en)
AU (1) AU2003243063A1 (en)
BR (1) BR0309975B1 (en)
DE (1) DE60333748D1 (en)
DK (1) DK1506323T3 (en)
ES (1) ES2350478T3 (en)
SE (1) SE526903C2 (en)
SI (1) SI1506323T1 (en)
WO (1) WO2003095692A1 (en)

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SE0300752L (en) 2003-03-19 2004-09-20 Volvo Lastvagnar Ab Gray iron for engine cylinder blocks and top caps
DE102004010917C5 (en) 2004-03-05 2018-05-17 Federal-Mogul Burscheid Gmbh Cast iron material with high strength
KR100656470B1 (en) 2006-02-07 2006-12-11 주식회사 하이닉스반도체 Driver control device and method for semiconductor memory
US8333923B2 (en) * 2007-02-28 2012-12-18 Caterpillar Inc. High strength gray cast iron
FR2948744B1 (en) * 2009-07-29 2015-04-24 Peugeot Citroen Automobiles Sa CYLINDER SHOE FOR THE CUTTING OF THE CYLINDRICAL WALL OF A CYLINDER OF AN INTERNAL COMBUSTION ENGINE
CN102465230A (en) * 2010-11-17 2012-05-23 常州朗锐活塞有限公司 Alloy cast iron piston material
SE535043C2 (en) * 2010-12-02 2012-03-27 Scania Cv Ab Gray iron alloy and brake disc including gray iron alloy
CN102409246B (en) * 2011-12-09 2013-01-02 河南省中原内配股份有限公司 Bainite cylinder jacket lining and preparation method thereof
EP2816127B1 (en) * 2012-02-17 2017-03-15 Honda Motor Co., Ltd. Cast iron and brake part
CN102864369A (en) * 2012-09-05 2013-01-09 陈敏 Anti-fatigue cast iron alloy
CN102876963A (en) * 2012-09-05 2013-01-16 忻峰 Anti-fatigue cast iron alloy
CN102851567A (en) * 2012-09-14 2013-01-02 虞海香 Cast iron alloy
CN102864370A (en) * 2012-09-14 2013-01-09 黄宣斐 Grey cast iron alloy material
CN102864367A (en) * 2012-09-14 2013-01-09 虞海盈 Gray cast iron alloy
CN103572150A (en) * 2013-10-12 2014-02-12 广西玉柴机器股份有限公司 Engine air cylinder cover gray cast iron
CN104561750B (en) * 2013-10-25 2016-08-17 河南星鹏铸件有限责任公司 Ferrum liquid and the casting method of pressure disc foundry goods for casting pressure dish foundry goods
CN103834852A (en) * 2014-03-19 2014-06-04 四川大学 A kind of tin-niobium composite alloy gray cast iron and its production process
CN104313456A (en) * 2014-10-20 2015-01-28 熊荣鑫 Anti-fatigue iron alloy
CN104962839A (en) * 2015-05-22 2015-10-07 南京飞燕活塞环股份有限公司 Piston ring material high in wear resistance, fracture resistance, and hardness
CN104962820A (en) * 2015-06-11 2015-10-07 龙口市和义机械配件有限公司 Alloy steel for racing car brake disc and preparation method of alloy steel
KR101794876B1 (en) 2016-09-05 2017-11-07 티피알 가부시키가이샤 Cylindrical member made of flake graphite cast iron
CN108070778A (en) * 2016-11-18 2018-05-25 山东恒圆精工部件股份有限公司 Piston ring cast-iron alloy and its manufacturing method
CN107119221B (en) * 2017-04-26 2018-08-07 含山县朝霞铸造有限公司 A kind of micro alloyed high strength grey cast iron part and its method of smelting
CN108913985A (en) * 2018-06-06 2018-11-30 东风商用车有限公司 High-carbon-equivalent high-strength gray cast iron and preparation method thereof
CN109182890B (en) * 2018-10-19 2020-05-26 中车大连机车车辆有限公司 Gray cast iron and smelting method thereof
CN110079726B (en) * 2019-06-01 2021-04-06 亚新科国际铸造(山西)有限公司 Process for improving normal-temperature tension-compression fatigue strength of gray cast iron engine cylinder cover
CN111334705A (en) * 2020-04-07 2020-06-26 中原内配集团股份有限公司 High-strength pearlite antifriction cast iron and preparation method and application thereof
US11879168B2 (en) * 2021-08-31 2024-01-23 GM Global Technology Operations LLC High-modulus, high-strength, low alloy gray cast iron for cylinder liners and automotive applications

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US5242510A (en) * 1992-09-25 1993-09-07 Detroit Diesel Corporation Alloyed grey iron having high thermal fatigue resistance and good machinability
CN1100150A (en) * 1993-09-09 1995-03-15 株洲市机械工业研究所 Impact fatigue-resistant wear-proof alloy cast iron
US5972128A (en) * 1996-02-28 1999-10-26 Kabushiki Kaisha Riken Cast iron and piston ring

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Publication number Publication date
SE0201431D0 (en) 2002-05-13
CN1653202A (en) 2005-08-10
KR100616649B1 (en) 2006-08-28
BR0309975B1 (en) 2010-12-14
SE526903C2 (en) 2005-11-15
JP4137054B2 (en) 2008-08-20
ATE477347T1 (en) 2010-08-15
SI1506323T1 (en) 2011-01-31
EP1506323B1 (en) 2010-08-11
AU2003243063A1 (en) 2003-11-11
SE0201431L (en) 2003-11-14
ES2350478T3 (en) 2011-01-24
JP2005525468A (en) 2005-08-25
KR20050010796A (en) 2005-01-28
DE60333748D1 (en) 2010-09-23
DK1506323T3 (en) 2010-11-22
BR0309975A (en) 2005-02-22
WO2003095692A1 (en) 2003-11-20
EP1506323A1 (en) 2005-02-16

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