CN1284200C - Method of spray coating three color luminescent powers onto plasma display and used mask plate - Google Patents
Method of spray coating three color luminescent powers onto plasma display and used mask plate Download PDFInfo
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- CN1284200C CN1284200C CN 03121551 CN03121551A CN1284200C CN 1284200 C CN1284200 C CN 1284200C CN 03121551 CN03121551 CN 03121551 CN 03121551 A CN03121551 A CN 03121551A CN 1284200 C CN1284200 C CN 1284200C
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Abstract
本发明公开了一种等离子体显示器的三色荧光粉喷涂方法，适用于导电栅网板结构等离子体显示器和障壁型等离子体显示器的荧光粉的制作。该方法利用压力喷枪喷涂或静电喷枪喷涂的原理，通过喷枪平面xy方向的二维运动或喷枪阵列的一维运动，同时采用特别设计制作的镂空掩模，通过掩模与导电栅网板或障壁型等离子体显示器的后板的精确对位，分别将配制的红、绿、蓝三色荧光粉浆料依次喷涂在导电栅网板的网孔内壁上或障壁的内壁表面，形成三色荧光粉的精确套色喷涂。本发明相对现有等离子体显示器中荧光粉层的制作方法而言，具有设备简单、制作效率高、色纯好、白场性能好、利于荧光粉发光性能的维持等优点。
The invention discloses a three-color fluorescent powder spraying method for a plasma display, which is suitable for making fluorescent powder of a plasma display with a conductive grid structure and a barrier-type plasma display. This method uses the principle of pressure spray gun spraying or electrostatic spray gun spraying, through the two-dimensional movement of the xy direction of the spray gun plane or the one-dimensional movement of the spray gun array, and at the same time using a specially designed hollow mask, through the mask and the conductive grid or barrier. For the precise alignment of the rear plate of the plasma display, the prepared red, green, and blue phosphor pastes are sprayed sequentially on the inner wall of the mesh of the conductive grid plate or the inner wall surface of the barrier to form a three-color phosphor. Precise color registration spraying. Compared with the manufacturing method of the fluorescent powder layer in the existing plasma display, the present invention has the advantages of simple equipment, high manufacturing efficiency, good color purity, good white field performance, and the maintenance of the luminous performance of the fluorescent powder.
Description
(1) technical field
The invention belongs to the manufacturing technology of fluorescent powder layer of plasma display, relate in particular to the manufacture method of the three fluorescence bisque in conductive grid plate structure plasma scope and the barrier type plasma scope.
(2) background of invention
In existing plasma scope, the formation of header board is respectively transparency conductive electrode layer, bus electrode layer and dielectric layer from glass substrate, and the formation of back plate is respectively the signal electrode layer from glass substrate, dielectric layer and barrier layer.Form high and narrow a series of grooves by technological means such as printing or sandblasts on the dielectric layer surface by glass powder with low melting point, at last through being sintered into barrier, this class plasma scope is a barrier type plasma scope.The barrier height is between 100～200 μ m, and face width is between 20～100 μ m, and the fluorescent material preparation is at the inner surface of barrier.The luminescence mechanism of this structure plasma scope is, the discharge cell between header board and the back plate is when applied voltage is higher than firing voltage, and the discharge of catching fire makes the ultraviolet excitation light-emitting phosphor of neon xenon mist generation.Therefore, except the luminescent properties of fluorescent material itself, the preparation method of fluorescent material and the luminescent properties of plasma scope are closely related.At present phosphor powder layer prepares the method that adopts silk screen printing, fluorescent material is mixed with printable slurry, method by silk screen printing is printed fluorescent powder paste material in the barrier of metacoxal plate, finish printing and leave standstill curtain coating, in the high temperature pre-burning more than 400 ℃, to remove organic solvent and the bonding agent in the slurry, fluorescent material finally forms phosphor powder layer at the inwall conjunctiva of barrier unit.Adopt this mode to make phosphor powder layer, mainly have following two problems:
One, uniformity is relatively poor.Adopt the mode of silk screen printing, fluorescent powder paste material at first enters the top of barrier inwall, by regulating the viscosity of fluorescent powder paste material, trickle with the weight of fluorescent powder paste material self and to leave standstill levelling to the bottom of barrier inwall, because fluorescent powder paste material enters the state that how much relies on screen process press of barrier, can not be fully evenly; Barrier inner wall surface state influences flowing of slurry simultaneously, therefore, the phosphor powder layer uniformity that forms in barrier inwall and bottom also just can not be consistent, causes the phosphor powder layer variable thickness after the high temperature pre-burning to cause, thereby influence the uniformity of device discharge, increased the driving difficulty.
Two, deterioration appears in the light-emitting phosphor performance.Adopt the fluorescent powder paste material silk screen printing, must be by the high temperature pre-burning more than 400 ℃, could remove organic solvent and bonding agent in the slurry, and some atmosphere and high temperature itself that this pyroprocess produces can make fluorescent material poisoning deterioration or decline, blue colour fluorescent powder is especially outstanding.
(3) summary of the invention
The objective of the invention is to, the one, prepare the problem that phosphor powder layer exists at barrier type plasma scope method for printing screen, the 2nd, at the characteristics of conductive grid plate structure plasma scope, be that its barrier is the independent gate web plate that is made of conductive material, propose the spraying method of three-color phosphor.This method is utilized the principle of Spray Gun Of The Pressure spraying or electrostatic gun, two dimensional motion or the motion in one dimension of spray gun array by single spray gun plane xy direction, utilize special mask, be sprayed on the mesh inwall of conductive gate web plate the fluorescent powder paste material of preparation or the inner wall surface of barrier, form the color fluorescence bisque.Compare with existing silk screen printing fluorescent material manufacture method, have higher work efficiency, better uniformity, and luminescent properties does not produce deterioration, is beneficial to the raising of display performance simultaneously.
The spraying method of three fluorescence bisque among the present invention, its key step is as follows.
The first step, batching, with the fluorescent material of institute desire preparation according to a certain percentage with water or organic solvent or mixed solvent, as mixing such as acetone, ethanol, concentration range can be added an amount of bonding agent such as all kinds of cellulose or resin moderated viscosity between the 1-1000 grams per liter.
Second step, stir, the fluorescent powder paste material that is made into fully stirs.
In the 3rd step, charging is packed fluorescent powder paste material in the hopper 2 of spray gun 1 into.
In the 4th step, spray gun is shelved, and spray gun 1 and hopper 2 are installed on the support 7 of spray gun controller 6, adjusts the various parameters of spray gun 1, makes it to enter operating state.
The 5th step, the making of mask plate 8, mask plate 8 is made of metal or nonmetallic materials, the surface is by the method for corrosion or photoetching, be made into the panel of forming by the cell orifice of rows of complete hollow outs, pitch between its cell orifice row is sprayed 3 times of parts 9 cell columns pitches, the element mesh hole shape of mask plate 8 is the hollow out through hole of the bowl-shape or ship shape that upper surface is big, lower surface is little, and the overall dimension of mask plate mesh lower surface requires it to differ scope within ± 30% than big by the overall dimension of spraying parts 9 unit upper surfaces.
The 6th step was sprayed parts 9 and is shelved with mask 8 contrapositions, fitted tightly with the lower surface of mask 8 and by the upper surface of spraying parts 9, and was fixed on by on the spraying part stent 10.Fixed with mechanical system with being sprayed part stent 10 peripheries by spraying parts 9,, fix with magnetic material or alternate manner at middle spraying area.By light microscope or have the monitor of CCD system, with the first module hole row of mask 8 with by spraying parts 9 first column unit hole row centerings.
The 7th step, spraying red fluorescence bisque.
Under the effect of spray gun controller 6, spray gun 1 is at first done horizontal movement in the x direction, from left to right or turn left at the uniform velocity mobile from the right side, spray gun 1 is with the red fluorescence powder slurry ejection of hopper 2 simultaneously, on by spraying parts 9, form a phosphor area with a certain size, its size drops on by the bundle spot size of spraying parts 9 relevant with spray gun 1, when the motion of finishing x direction one-period, formed a phosphor powder layer band by spraying parts 9 with certain width, spray gun 1 remakes the motion of y direction, move a step as at the uniform velocity moving from the top down or from bottom to top, continue the motion of x direction, said process constantly repeats, and through the effect of blocking of mask 8, is being needed accurately to be formed uniformly the red fluorescence bisque on the spray area by spraying parts 9 selectively.
The 8th step was sprayed parts 9 and is shelved with mask 8 contrapositions for the second time, fitted tightly with the lower surface of mask 8 and by the upper surface of spraying parts 9, and was fixed on by on the spraying part stent 10.Fixed with mechanical system with being sprayed part stent 10 peripheries by spraying parts 9,, fix with magnetic material or alternate manner at middle spraying area.By light microscope or have the monitor of CCD system, with the first module hole row of mask 8 with by spraying parts 9 secondary series cell orifice row centerings.
The 9th step, the spraying green phosphor layer.
Through cleaning, the red fluorescence powder slurry in the hopper 2 is replaced by the green emitting phosphor slurry.Under the effect of spray gun controller 6, spray gun 1 is at first done horizontal movement in the x direction, from left to right or turn left at the uniform velocity mobile from the right side, spray gun 1 is with the green emitting phosphor slurry ejection of hopper 2 simultaneously, on by spraying parts 9, form a phosphor area with a certain size, its size drops on by the bundle spot size on the spraying parts 9 relevant with spray gun 1, when the motion of finishing x direction one-period, formed a phosphor powder layer band by spraying parts 9 with certain width, spray gun 1 remakes the motion of y direction, move a step as at the uniform velocity moving from the top down or from bottom to top, continue the motion of x direction, said process constantly repeats, and through the effect of blocking of mask 8, is being needed accurately to be formed uniformly green phosphor layer on the spray area by spraying parts 9 selectively.
The tenth step was sprayed parts 9 and is shelved with mask 8 contraposition for the third time, fitted tightly with the lower surface of mask 8 and by the upper surface of spraying parts 9, and was fixed on by on the spraying part stent 10.Fixed with mechanical system with being sprayed part stent 10 peripheries by spraying parts 9,, fix with magnetic material or alternate manner at middle spraying area.By light microscope or have the monitor of CCD system, with the first module hole row of mask 8 with by spraying parts 9 the 3rd column unit hole row centering.
The 11 step, the spraying blue phosphor layer.
Through cleaning, the green emitting phosphor slurry in the hopper 2 is replaced by the blue colour fluorescent powder slurry.Under the effect of spray gun controller 6, spray gun 1 is at first done horizontal movement in the x direction, from left to right or turn left at the uniform velocity mobile from the right side, spray gun 1 is with the green emitting phosphor slurry ejection of hopper 2 simultaneously, on by spraying parts 9, form a phosphor area with a certain size, its size drops on by the bundle spot size on the spraying parts 9 relevant with spray gun 1, when the motion of finishing x direction one-period, formed a phosphor powder layer band by spraying parts 9 with certain width, spray gun 1 remakes the motion of y direction, move a step as at the uniform velocity moving from the top down or from bottom to top, continue the motion of x direction, said process constantly repeats, and through the effect of blocking of mask 8, is being needed accurately to be formed uniformly blue phosphor layer on the spray area by spraying parts 9 selectively.
In the 12 step, unload and get by spraying parts 9.
To be separated with mask 8 by spraying parts 9, take off being sprayed part stent 10 from quilt by spraying parts 9, and dry.
Through above-mentioned 12 steps, can utilize the two dimensional motion of single spray gun plane xy direction and the accurate chromatography spraying that single kind mask is finished three-color phosphor.
(4) description of drawings:
Fig. 1 is the schematic diagram of spray gun and hopper.
Fig. 2 is the schematic diagram of spray gun controller and support.
Fig. 3 is sprayed parts and is sprayed the schematic diagram of part stent.
Fig. 4 is the block diagram that single rifle prepares the preparation process of color fluorescence bisque.
Fig. 5 is a mask, concerns schematic diagram between conductive gate web plate and mesh.
Fig. 6 is that schematic diagram is shelved in conductive gate web plate and mask contraposition.
Fig. 7 is the block diagram that single rifle list mask prepares the preparation process of color fluorescence bisque.
Fig. 8 is that spray gun array, hopper array constitute schematic diagram.
Fig. 9 is spray gun array, hopper array and controller and support framework schematic diagram.
Figure 10 is that spray gun array, hopper array constitute schematic diagram.
Figure 11 is spray gun array, hopper array and controller and support framework schematic diagram.
Figure 12 is the schematic diagram that the two green arrangement modes in conductive gate web plate diagonal angle and each pixel are arranged.
Figure 13 shelves schematic diagram for the arrangement of red mask plate cell orifice and with the contraposition of conductive gate web plate.
Figure 14 shelves schematic diagram for the arrangement of green mask plate cell orifice and with the contraposition of conductive gate web plate.
Figure 15 shelves schematic diagram for the arrangement of blue mask plate cell orifice and with the contraposition of conductive gate web plate.
Figure 16 utilizes three kinds of masks to finish the step block diagram of the accurate chromatography spraying of three-color phosphor.
Figure 17 is the Pareto diagram of each pixel in the Chinese character pin-shaped arrangement mode of conductive gate web plate.
Figure 18 is that the arrangement of red mask plate cell orifice reaches and schematic diagram is shelved in the contraposition of conductive gate web plate.
Figure 19 is that the arrangement of green mask plate cell orifice reaches and schematic diagram is shelved in the contraposition of conductive gate web plate.
Figure 20 is that the arrangement of blue mask plate cell orifice reaches and schematic diagram is shelved in the contraposition of conductive gate web plate.
Figure 21 a is bar shaped mask and metacoxal plate barrier unit graph of a relation.
Figure 21 b is grid mask and metacoxal plate barrier unit graph of a relation.
Figure 22 a is that schematic diagram is shelved in the metacoxal plate and the mask contraposition of mask strip barrier.
Figure 22 b is that schematic diagram is shelved in the metacoxal plate and the mask contraposition of mask grid shape barrier unit.
Figure 23 finishes the step block diagram that the accurate chromatography of barrier type plasma scope three-color phosphor sprays for single mask of planting.
The major advantage of the inventive method has:
One, colour purity is high. Fluorescent powder paste material is painted on by on the spraying parts 9 cell orifice inwalls, compares with the preparation method of existing fluorescent material, and effects on surface need not to carry out also not need to make black matrix processing, so colour purity is high, and chroma characteristic is good, can reduce cost of manufacture.
Two, keep good luminescent properties. Fluorescent powder paste material on by spraying parts 9 cell orifice inwalls, forms phosphor powder layer by spray gun spraying, need not through the high temperature pre-burning, thereby has kept the original luminescent properties of fluorescent material, has avoided the deteriorated of phosphor powder layer in the preparation of phosphor layer process.
Three, cost of manufacture is low, and efficient is high. This kind mode only need be used special-purpose spray equipment, and extremely the short time is made the color fluorescence bisque, must improve manyfold through the work efficiency of high-temperature process than every phosphor powder layer of the same colour in the existing printing process.
Four, spraying method improves the yield rate of plasma scope. The fluorescent material of barrier type plasma display panel structure is produced on the barrier inwall, and barrier and rear plate are indivisible. Adopt method for printing screen to prepare phosphor powder layer, in case the preparation of phosphor layer failure affects whole rear plate. And adopt spraying method to prepare phosphor powder layer, owing to need not high-temperature process, even prepare unsuccessfully, also can reclaim again spraying. For conductive grid plate structure plasma scope, conductive gate web plate wherein is individualism in addition, and phosphor powder layer is produced on the conductive gate web plate inwall, owing to need not high-temperature process, even prepare unsuccessfully, only needs to reclaim the conductive gate web plate and again sprays. Therefore, spraying method prepares the raising that phosphor powder layer is beneficial to the plasma scope yield rate very much.
On the basis of foregoing invention, further consider concrete structure, propose following various embodiment, and, further specify the distinctive advantage of each embodiment by specific embodiment.
First kind of embodiment of the present invention, according to above-mentioned principle, utilize Spray Gun Of The Pressure list rifle to do two dimensional motion, utilize single mask of planting the three-color phosphor slurry to be sprayed on the conductive gate web plate cell orifice inwall of conductive grid plate structure plasma scope, form the color fluorescence layer on x, y plane.Its step is as described below.
The first step, batching, the red fluorescence powder that institute's desire is prepared mixes with acetone according to a certain percentage, and concentration range is added alkyd resins and is regulated viscosity between the 1-1000 grams per liter.With green, the blue phosphor slurry of quadrat method allotment.
Second step, stir, the fluorescent powder paste material that is made into fully stirs.
In the 3rd step, charging is packed fluorescent powder paste material in the hopper 2 of spray gun 1 into.The structure of spray gun mainly is made up of nozzle, the body of a gun and handle.Spray gun forms the atomizing ejection by dispersed structure with fluorescent powder paste material, its process is that fluorescent powder paste material 3 is inserted in the hopper 2, under the effect of compressed air 4, form negative pressure at spray nozzle front end, with fluorescent powder paste material 3 sucking-offs that flow between tungsten pin 5 and the gun barrel wall, under the effect of air pressure, with vaporific ejection, tungsten pin 5 can be regulated front and back, and fluorescent powder paste material 3 dischargings what are controlled.
The 4th step, spray gun is shelved, spray gun 1 and hopper 2 are installed on the support 7 of spray gun controller 6, adjust the various parameters of spray gun 1, make it to enter operating state, cross the compressed air of the cleaning of water-oil separating to the nozzle warp let-off of spray gun 1, front portion at nozzle forms negative pressure, fluorescent powder paste material is extracted out from hopper 2, be transported to the spray nozzle part of spray gun 1, the state with atomizing sprays slurry then.The compressed-air actuated pressure that offers spray gun is adjustable at 0.1～10MPa, and pulp jets speed is adjustable in 0.01～10 milliliters/second.
The 5th step, the making of mask 8, mask 8 is made of metal or nonmetallic materials, the surface is by the method for corrosion or photoetching, the panel that making is made up of the cell array of complete hollow out, pitch between its cell orifice row is 3 times of conductive gate web plate Unit 9, the element mesh hole shape of mask 8 is the hollow out through hole of the bowl-shape or ship shape that upper surface is big, lower surface is little, and the overall dimension of the overall dimension of mask plate mesh lower surface and conductive gate web plate 9 unit upper surfaces is close, requires it to differ scope within ± 30%.。
In the 6th step, conductive gate web plate 9 is shelved with mask 8 contrapositions.
The lower surface of mask 8 and the upper surface of conductive gate web plate 9 are fitted tightly, and be fixed on the conductive grid board mount 10.Conductive gate web plate 9 is fixed with mechanical system with conductive grid board mount 10 peripheries, and is at middle spraying area, fixing with magnetic material such as magnetic stripe etc.By light microscope or have the monitor of CCD system, with the first module hole row and the conductive gate web plate 9 first column unit hole row centerings of mask 8.
The 7th step, spraying red fluorescence bisque.
Under the effect of spray gun controller 6, spray gun 1 is at first done horizontal movement in the x direction, from left to right or turn left at the uniform velocity mobile from the right side, spray gun 1 is with the red fluorescence powder slurry ejection of hopper 2 simultaneously, on conductive gate web plate 9, form a phosphor area with a certain size, its size is relevant with the bundle spot size that spray gun 1 drops on the conductive gate web plate 9, when the motion of finishing x direction one-period, form a phosphor powder layer band at conductive gate web plate 9 with certain width, spray gun 1 remakes the motion of y direction, move a step as at the uniform velocity moving from the top down or from bottom to top, continue the motion of x direction, said process constantly repeats, and through the effect of blocking of mask 8, needs accurately to be formed uniformly the red fluorescence bisque on the spray area at conductive gate web plate 9 selectively.
In the 8th step, conductive gate web plate 9 is shelved with mask 8 contrapositions for the second time.
The lower surface of mask 8 and the upper surface of conductive gate web plate 9 are fitted tightly, and be fixed on the conductive grid board mount 10.Conductive gate web plate 9 is fixed with mechanical system with conductive grid board mount 10 peripheries, and is at middle spraying area, fixing with magnetic material such as magnetic stripe etc.By light microscope or have the monitor of CCD system, with the first module hole row and the conductive gate web plate 9 secondary series cell orifice row centerings of mask 8.
The 9th step, the spraying green phosphor layer.
Through cleaning, the red fluorescence powder slurry in the hopper 2 is replaced by the green emitting phosphor slurry.Under the effect of spray gun controller 6, spray gun 1 is at first done horizontal movement in the x direction, from left to right or turn left at the uniform velocity mobile from the right side, spray gun 1 is with the green emitting phosphor slurry ejection of hopper 2 simultaneously, on conductive gate web plate 9, form a phosphor area with a certain size, its size is relevant with the bundle spot size that spray gun 1 drops on the conductive gate web plate 9, when the motion of finishing x direction one-period, form a phosphor powder layer band at conductive gate web plate 9 with certain width, spray gun 1 remakes the motion of y direction, move a step as at the uniform velocity moving from the top down or from bottom to top, continue the motion of x direction, said process constantly repeats, and through the effect of blocking of mask 8, needs accurately to be formed uniformly green phosphor layer on the spray area at conductive gate web plate 9 selectively.
In the tenth step, conductive gate web plate 9 is shelved with mask 8 contraposition for the third time.
The lower surface of mask 8 and the upper surface of conductive gate web plate 9 are fitted tightly, and be fixed on the conductive grid board mount 10.Conductive gate web plate 9 is fixed with mechanical system with conductive grid board mount 10 peripheries, and is at middle spraying area, fixing with magnetic material such as magnetic stripe etc.By light microscope or have the monitor of CCD system, with the first module hole row and conductive gate web plate 9 the 3rd column unit hole row centering of mask 8.
The 11 step, the spraying blue phosphor layer.
Through cleaning, the green emitting phosphor slurry in the hopper 2 is replaced by the blue colour fluorescent powder slurry.Under the effect of spray gun controller 6, spray gun 1 is at first done horizontal movement in the x direction, from left to right or turn left at the uniform velocity mobile from the right side, spray gun 1 is with the green emitting phosphor slurry ejection of hopper 2 simultaneously, on conductive gate web plate 9, form a phosphor area with a certain size, its size is relevant with the bundle spot size that spray gun 1 drops on the conductive gate web plate 9, when the motion of finishing x direction one-period, form a phosphor powder layer band at conductive gate web plate 9 with certain width, spray gun 1 remakes the motion of y direction, move a step as at the uniform velocity moving from the top down or from bottom to top, continue the motion of x direction, said process constantly repeats, and through the effect of blocking of mask 8, needs accurately to be formed uniformly blue phosphor layer on the spray area at conductive gate web plate 9 selectively.
In the 12 step, unload and get conductive gate web plate 9.
Conductive gate web plate 9 is separated with mask 8, conductive gate web plate 9 is taken off from conductive grid board mount 10, and dry.
Through above-mentioned 12 steps, can utilize the two dimensional motion of single spray gun plane xy direction and single kind mask is finished three-color phosphor on the conductive gate web plate accurate chromatography spraying.Above-mentioned steps can be used the block representation of Fig. 7.
Above method is that single spray gun of employing is done the motion of xy planar and mask plate uses together, spraying color fluorescence bisque.For efficient is improved, can use the spray gun array to do motion in one dimension, form the color fluorescence bisque.Therefore second kind of embodiment of the present invention comprises the spraying method of three-color phosphor in three look spray gun arrays 11 and controller 12 thereof and the conductive grid plate structure plasma scope.
The first step, batching.
With the first step among first embodiment.
In second step, stir.
With second step among first embodiment.
The 3rd step, charging.
In the hopper row 14 that the red fluorescence powder slurry is packed into the spray gun row 13 of crimson look fluorescent powder paste material link to each other; Same method, in the hopper row 16 that the green emitting phosphor slurry is packed into the spray gun row 15 of spray green emitting phosphor slurry link to each other, with the blue colour fluorescent powder slurry pack into with hopper row 18 that the spray gun row 17 that spray the blue colour fluorescent powder slurry link to each other in.
The 4th step, the spray gun array is shelved, according to the required area size of sprayed with fluorescent powder, the number of the spray gun of decision spraying three-color phosphor slurry, its three kinds of spray gun numbers can be respectively between 1-100, and the spray gun row of three kinds of purposes of some are formed spray gun array 11, and each hopper row is formed hopper array 19, spray gun is linked to each other with hopper array 19, shelve on the support 20 of controller 12.Conductive gate web plate 9 is motionless, and moves on the guide rail 21 of spray gun array 11 in support 20, and the length of guide rail 21 is greater than the length of conductive gate web plate 9.Adjust the various parameters of spray gun array 11, make it to enter operating state, the pressure of spray gun is adjustable at 0.1～10MPa, and pulp jets speed is adjustable in 0.01～10 milliliters/second.
The 5th step, the making of single mask 8.
With the 5th step among first embodiment.
In the 6th step, conductive gate web plate 9 is shelved with mask 8 contrapositions.
With the 6th step among first embodiment.
The 7th step, spraying red fluorescence bisque, under the effect of spray gun controller 12, spray gun array 11 is done the motion of x direction on the guide rail 21 of support 20, from left to right or at the uniform velocity mobile from left to right, spray gun row 13 work simultaneously with red fluorescence powder slurry in the hopper row 14 with vaporific ejection, through the effect of blocking of mask 8, need accurately be formed uniformly the red fluorescence bisque on the spray areas at conductive gate web plate 9 selectively.
In the 8th step, conductive gate web plate 9 is shelved with mask 8 contrapositions for the second time.
With the 8th step among first embodiment.
The 9th step, the spraying green phosphor layer, under the effect of spray gun controller 12, spray gun array 11 is at the uniform velocity mobile from left to right on the guide rail 21 of support 20, spray gun row 15 work simultaneously with green fluorescent powder paste material in the hopper row 16 with vaporific ejection, effect through mask 8 accurately is formed uniformly green phosphor layer selectively on conductive gate web plate 9.
In the tenth step, conductive gate web plate 9 is shelved with mask 8 contraposition for the third time.
With the tenth step among first embodiment.
The 11 step, the spraying blue phosphor layer.Under the effect of spray gun controller 12, spray gun array 11 is at the uniform velocity mobile from left to right on the guide rail 21 of support 20, spray gun row 17 work simultaneously with hopper row 18 Smalt fluorescent powder paste materials with vaporific ejection, effect through mask 8 accurately is formed uniformly blue phosphor layer selectively on conductive grid.
In the 12 step, unload and get conductive gate web plate 9.
With the 12 step among first embodiment.
Through above-mentioned 12 steps, can utilize spray gun array and single kind mask to finish the accurate chromatography spraying of three-color phosphor.
In above-mentioned two kinds of embodiment, Spray Gun Of The Pressure is used instead electrostatic gun, or single rifle does xy planar motion, or the spray gun array does motion in one dimension and mask plate uses together, electrostatic spraying forms the color fluorescence bisque.In second kind of embodiment, the Spray Gun Of The Pressure array used instead the electrostatic gun array is done motion in one dimension and mask plate uses together, preparation color fluorescence bisque constitutes the third embodiment of the present invention.Comprise electrostatic gun array 22, electrostatic gun array control unit 23 and color fluorescence bisque preparation method.
The first step, batching.
With the first step among second kind of embodiment.
In second step, stir.
With second step among second kind of embodiment.
In the 3rd step, charging is in the hopper row 24a that the red fluorescence powder slurry is packed into the spray gun row 22a of crimson look fluorescent powder paste material links to each other; Same method, in the hopper row 24b that the green emitting phosphor slurry is packed into the spray gun row 22b of spray green emitting phosphor slurry links to each other, with the blue colour fluorescent powder slurry pack into with hopper row 24c that the spray gun row 22c that sprays the blue colour fluorescent powder slurry links to each other in.
The 4th step, the spray gun array is shelved, according to the required area size of sprayed with fluorescent powder, the number of the spray gun of decision spraying three-color phosphor slurry, its three kinds of spray gun numbers can be respectively between 1-100, and the spray gun row of three kinds of purposes of some are formed spray gun array 22, and each hopper row is formed hopper array 24, spray gun array 22 is linked to each other with hopper array 24, shelve on the support 20 of controller 23.Conductive gate web plate 9 is motionless, and moves on the guide rail 21 of spray gun array 22 in support 20, and the length of guide rail 21 is greater than the length of conductive gate web plate 9.Adjust the various parameters of spray gun array 22, make it to enter operating state, the compressed air of the cleaning of water-oil separating is crossed in the nozzle warp let-off of row that use in spray gun array 22, front portion at nozzle forms negative pressure, fluorescent powder paste material required row from hopper array 24 are extracted out, be transported to the spray nozzle part that is listed as that spray gun array 22 uses, state with atomizing sprays slurry then, under the effect of electrostatic field, the fluorescent powder grain of vaporific ejection is charged, the nozzle of the row that fluorescent powder grain uses from spray gun array 22 moves on the conductive gate web plate 9.The compressed-air actuated pressure that offers spray gun array 22 is adjustable at 0.1～10MPa, and the output voltage of high-voltage DC power supply 25 is adjustable at 1kV-50kV, and pulp jets speed is adjustable in 0.01～10 milliliters/second.
In the 5th step, single mask is made.
With the 5th step among second kind of embodiment.
In the 6th step, conductive gate web plate 9 is shelved with mask 8 contrapositions.
In the casing of fluorescent powder paste material electrostatic spraying, conductive gate web plate 9 is installed on the conductive grid board mount 10, the upper surface of the lower surface of mask 8 and conductive gate web plate 9 fits tightly, conductive gate web plate 9 is in the face of spray gun array 22, to be fixed on the conductive grid board mount 10 around the conductive gate web plate 9 with Magnetic strip, the phosphor area that produces during 22 work of corresponding spray gun array is placed the magnetic stripe 26 of some, fixing conductive gate web plate 9 is fixed on the surface of mask 8.Conductive gate web plate 9 keeps certain distance with spray gun, and is adjustable within 0.05～1 meter, decides on the phosphor area size of electrostatic field intensity, spray speed and formation.By light microscope or have the monitor of CCD system, with the first module hole row and the conductive gate web plate 9 first column unit hole row centerings of mask 8.
The 7th step, spraying red fluorescence bisque.Under the effect of spray gun controller 23, spray gun array 22 is at the uniform velocity mobile from left to right on the guide rail 21 of support 20, under electrostatic field, spray gun row 22a works red fluorescence powder slurry among the hopper row 24a with vaporific ejection, on conductive gate web plate 9, form a phosphor area with certain width, its width is relevant with the bundle spot size that spray gun row 22a drops on the conductive gate web plate 9, length covers the height of conductive gate web plate 9, spray gun row 22a at the uniform velocity moves from left to right and moves a step, repeat said process, the cell orifice that whole conductive gate web plate 9 is appeared up to fluorescent powder paste material be coated with covered with.The effect of blocking through mask 8 accurately is formed uniformly the red fluorescence bisque selectively on conductive gate web plate 9.
In the 8th step, conductive gate web plate 9 is shelved with mask 8 contrapositions for the second time.
Open the magnetic control switch or remove magnetic stripe, the lower surface of mask 8 and the upper surface of conductive gate web plate 9 are fitted tightly, by light microscope or have the monitor of CCD system, with the secondary series cell orifice row centering of cell orifice row with the conductive gate web plate 9 of mask 8, absorption is fixing again again.
The 9th step, the spraying green phosphor layer, under the effect of spray gun controller 23, spray gun array 22 is at the uniform velocity mobile from left to right on the guide rail 21 of support 20, under electrostatic field, spray gun row 22b works green fluorescent powder paste material among the hopper row 24b with vaporific ejection, on conductive gate web plate 9, form a phosphor area with certain width, its width is relevant with the bundle spot size that spray gun row 22b drops on the conductive gate web plate 9, length covers the height of conductive gate web plate 9, spray gun row 22b at the uniform velocity moves from left to right and moves a step, and repeats said process, the cell orifice that whole conductive gate web plate 9 is appeared up to fluorescent powder paste material be coated with covered with.The effect of blocking through mask 8 accurately is formed uniformly green phosphor layer selectively on conductive gate web plate 9.
The tenth step, conductive gate web plate 9 is shelved with mask 8 contraposition for the third time, open the magnetic control switch or remove magnetic stripe, the lower surface of mask 8 and the upper surface of conductive gate web plate 9 are fitted tightly, by light microscope or have the monitor of CCD system, with the cell orifice row of mask 8 and the 3rd column unit hole row centering of conductive gate web plate 9, absorption is fixing again again.
The 11 step, the spraying blue phosphor layer.Under spray gun controller 23 effects, spray gun array 22 is at the uniform velocity mobile from left to right on the guide rail 21 of support 20, under electrostatic field, spray gun row 22c works hopper row 24c Smalt fluorescent powder paste material with vaporific ejection, on conductive gate web plate 9, form a phosphor area with certain width, its width is relevant with the bundle spot size that spray gun row 22c drops on the conductive gate web plate 9, length covers the height of conductive gate web plate 9, spray gun row 22c at the uniform velocity moves from left to right and moves a step, repeat said process, the cell orifice that whole conductive gate web plate 9 is appeared up to fluorescent powder paste material be coated with covered with.The effect of blocking through mask 8 accurately is formed uniformly blue phosphor layer selectively on conductive gate web plate 9.
In the 12 step, unload and get conductive gate web plate 9.
Conductive gate web plate 9 is separated with mask 8, conductive gate web plate 9 is taken off from conductive grid board mount 10, and dry.
Through above-mentioned 12 steps, can adopt electrostatic spray, utilize single accurate chromatography spraying that mask is finished three-color phosphor of planting.
Use three kinds of masks instead if will singly plant mask, can utilize the spraying of Spray Gun Of The Pressure or electrostatic gun to realize the preparation of colored phosphor powder layer in the conductive grid plate structure plasma scope equally.The color fluorescence bisque that adopts the spraying of Spray Gun Of The Pressure array, three kinds of masks to prepare the conductive gate web plate constitutes the 4th kind of embodiment of the present invention, comprises the spraying method of the two green arrangement three-color phosphor in diagonal angle in red mask plate 27a, green mask plate 27b and blue mask plate 27c and the conductive grid plate structure plasma scope.
The first step, batching.
With the first step among second embodiment.
In second step, stir.
With second step among second embodiment.
The 3rd step, charging.
With the 3rd step among second embodiment.
In the 4th step, the spray gun array is shelved.
With the 4th step among second embodiment.
The 5th step, the making of red mask plate 27a.
The 6th step, the making of green mask plate 27b, green mask plate 27a is made of metal or nonmetallic materials, and the surface is by the method for corrosion or photoetching, the panel that making is made up of the cell array of complete hollow out, the arrangement of its cell orifice determines according to the fluorescent material arrangement mode.As adopt the two green arrangements in diagonal angle, per two row two are classified a pixel as, the unit, diagonal angle is a green emitting phosphor in each pixel, another unit, diagonal angle is respectively red fluorescence powder and blue colour fluorescent powder, pitch between the then green mask plate 27b odd column is 2 times of conductive gate web plate 28 mesh column pitch, pitch between the green mask plate 27b even column is also 2 times of conductive gate web plate 28 mesh column pitch, and the pitch of green mask plate 27b between capable is identical with the capable pitch of conductive gate web plate 28 mesh, the initial order of cell orifice on the row is respectively an even column, odd column, even column, odd column ... the element mesh hole shape of mask plate is that upper surface is big, the hollow out through hole of the bowl-shape or ship shape that lower surface is little, and the overall dimension of the overall dimension of mask plate mesh lower surface and conductive grid expanded metals hole upper surface is close, requires it to differ scope within ± 30%.
The 7th step, the making of blue mask plate 27c, blue mask plate 27c is made of metal or nonmetallic materials, and the surface is by the method for corrosion or photoetching, the panel that making is made up of the cell array of complete hollow out, the arrangement of its cell orifice determines according to the fluorescent material arrangement mode.As adopt the two green arrangements in diagonal angle, per two row two are classified a pixel as, the unit, diagonal angle is a green emitting phosphor in each pixel, another unit, diagonal angle is respectively red fluorescence powder and blue colour fluorescent powder, pitch between the then blue mask plate 27c row is 2 times of conductive gate web plate 28 mesh column pitch, pitch between blue mask plate 27c is capable is 2 times of the capable pitch of conductive gate web plate 28 mesh, the element mesh hole shape of mask plate is that upper surface is big, the hollow out through hole of the bowl-shape or ship shape that lower surface is little, and the overall dimension of the overall dimension of mask plate mesh lower surface and conductive grid expanded metals hole upper surface is close, requires it to differ scope within ± 30%.
In the 8th step, conductive gate web plate 28 is shelved with red mask plate 27a contraposition for the first time, the lower surface of red mask plate 27a and the upper surface of conductive gate web plate 28 is fitted tightly, and be fixed on the conductive grid board mount 10.By light microscope or have the monitor of CCD system, with each column unit hole and the conductive gate web plate 28 odd column cell orifice centerings of red mask plate 27a.
The 9th step, spraying red fluorescence bisque.
With the 7th step among second embodiment.
In the tenth step, take off red mask plate 27a.
In the 11 step, conductive gate web plate 28 is shelved with green mask plate 27b contraposition for the second time, the lower surface of green mask plate 27b and the upper surface of conductive gate web plate 28 is fitted tightly, and be fixed on the conductive grid board mount 10.By light microscope or have the monitor of CCD system, with the cell orifice row centering of each row of first cell orifice that has been listed as of green mask plate 27b and conductive gate web plate 28, each capable cell orifice row centering of first row, second cell orifice of go and conductive gate web plate 28.
The 12 step, the spraying green phosphor layer.
With the 9th step among second embodiment.
In the 13 step, take off green mask plate 27b.
In the 14 step, conductive gate web plate 28 is shelved with blue mask plate 27c contraposition for the third time.
The lower surface of blue mask plate 27c and the upper surface of conductive gate web plate 28 are fitted tightly, and be fixed on the conductive grid board mount 10.By light microscope or have the monitor of CCD system, blueness is covered the even column cell orifice centering that first of plate 27c has been listed as cell orifice and conductive gate web plate 28.
The 15 step, the spraying blue phosphor layer.
With the 11 step among second embodiment.
In the 16 step, take off blue mask plate 27c.
In the 17 step, unload and get conductive gate web plate 28.
Conductive gate web plate 28 is taken off from conductive grid board mount 10, and dry.
Through above-mentioned 17 steps, can utilize three kinds of masks to finish the accurate chromatography spraying of the two green arrangement three-color phosphor in diagonal angle.Above-mentioned steps can be used the block representation of Figure 18.
Three kinds of masks are changed into different arrangement modes, adopt the spraying of Spray Gun Of The Pressure array, realize the preparation of conductive gate web plate color phosphor layer, then constitute the 5th kind of embodiment of the present invention, comprise the spraying method of red mask plate 29a, green mask plate 29b and blue mask plate 29c and the Chinese character pin-shaped arrangement three-color phosphor of conductive gate web plate.
The first step, batching.
With the first step among second embodiment.
In second step, stir.
With second step among second embodiment.
The 3rd step, charging.
With the 3rd step among second embodiment.
In the 4th step, the spray gun array is shelved.
With the 4th step among second embodiment.
The 5th step, the making of red mask plate 29a, red mask plate 29a is made of metal or nonmetallic materials, and the surface is by the method for corrosion or photoetching, the panel that making is made up of the cell array of complete hollow out, the arrangement of its cell orifice is according to the arrangement mode decision of phosphor pixel point.As adopt Chinese character pin-shaped arrangement mode, and three powder points of RGB constitute the pixel of a Chinese character pin-shaped arrangement, and the centre-to-centre spacing of three unit forms an equilateral triangle in each pixel, and the length of side is 1.2-1.5 a times of a powder dot element diameter.Pitch between the red mask plate 29a row is 3 times of conductive gate web plate 30 mesh column pitch, pitch between red mask plate 29a is capable is identical with the capable pitch of conductive gate web plate 30 mesh, the element mesh hole shape of red mask plate 29a is the bowl-shape hollow out through hole that upper surface is big, lower surface is little, and the overall dimension of the overall dimension of mask plate mesh lower surface and conductive grid expanded metals hole upper surface is close, requires it to differ scope within ± 30%.
The 6th step, the making of green mask plate 29b, green mask plate 29b is made of metal or nonmetallic materials, and the surface is by the method for corrosion or photoetching, the panel that making is made up of the cell array of complete hollow out, the arrangement of its cell orifice determines according to the fluorescent material arrangement mode.Adopt Chinese character pin-shaped arrangement mode, three powder points of RGB constitute the pixel of a Chinese character pin-shaped arrangement, and the centre-to-centre spacing of three unit forms an equilateral triangle in each pixel, and the length of side is 1.2-1.5 a times of a powder dot element diameter.Then green mask plate 29b column pitch is 3 times of conductive gate web plate 30 mesh column pitch, pitch between green mask plate 29b is capable is identical with the capable pitch of conductive gate web plate 30 mesh, the element mesh hole shape of mask plate is the bowl-shape hollow out through hole that upper surface is big, lower surface is little, and the overall dimension of the overall dimension of mask plate mesh lower surface and conductive grid expanded metals hole upper surface is close, requires it to differ scope within ± 30%.
The 7th step, the making of blue mask plate 29c, blue mask plate 29c is made of metal or nonmetallic materials, and the surface is by the method for corrosion or photoetching, the panel that making is made up of the cell array of complete hollow out, the arrangement of its cell orifice determines according to the fluorescent material arrangement mode.As adopt Chinese character pin-shaped arrangement mode, and three powder points of RGB constitute the pixel of a Chinese character pin-shaped arrangement, and the centre-to-centre spacing of three unit forms an equilateral triangle in each pixel, and the length of side is 1.2-1.5 a times of a powder dot element diameter.Pitch between the then blue mask plate 29c row is 3 times of conductive gate web plate 30 mesh column pitch, pitch between blue mask plate 29c is capable is identical with the capable pitch of conductive gate web plate 30 mesh, the element mesh hole shape of mask plate is the bowl-shape hollow out through hole that upper surface is big, lower surface is little, and the overall dimension of the overall dimension of mask plate mesh lower surface and conductive grid expanded metals hole upper surface is close, requires it to differ scope within ± 30%.
In the 8th step, conductive gate web plate 30 is shelved with red mask plate 29a contraposition for the first time.
The lower surface of red mask plate 29a and the upper surface of conductive gate web plate 30 are fitted tightly, and be fixed on the conductive grid board mount 10.By light microscope or have the monitor of CCD system, with 1,4,7 of the column unit hole of red mask plate 29a and conductive gate web plate 30 ... Deng the cell orifice centering of row, the cell orifice centering of each row cell orifice of red mask plate 29a and each row of conductive gate web plate 30.
The 9th step, spraying red fluorescence bisque.
With the 7th step among second embodiment.
In the tenth step, take off red mask plate 29a.
In the 11 step, conductive gate web plate 30 is shelved with green mask plate 29b contraposition for the second time.
The lower surface of green mask plate 29b and the upper surface of conductive gate web plate 30 are fitted tightly, and be fixed on the conductive grid board mount 10.By light microscope or have the monitor of CCD system, with 2,5,8 of green mask plate 29b column unit hole and conductive gate web plate 30 ... Deng the cell orifice centering of row, each row cell orifice of green mask plate 29b and conductive gate web plate 30 each row cell orifice centering.
The 12 step, the spraying green phosphor layer.
With the 9th step among second embodiment.
In the 13 step, take off green mask plate 29b.
Green mask plate 29b is taken off from support conductive gate web plate 10.
In the 14 step, conductive gate web plate 30 is shelved with the contraposition for the third time of blue mask plate 29.
The lower surface of blue mask plate 29c and the upper surface of conductive gate web plate 30 are fitted tightly, and be fixed on the conductive grid board mount 10.By light microscope or have the monitor of CCD system, blueness is covered 3,6,9 of plate 29c column unit hole and conductive gate web plate 30 ... Deng the cell orifice centering of row, each row cell orifice of blue mask plate 29c and conductive gate web plate 30 each row cell orifice centering.
The 15 step, the spraying blue phosphor layer.
With the 11 step among second embodiment.
In the 16 step, take off blue mask plate 29c.
In the 17 step, unload and get conductive gate web plate 30.
Conductive gate web plate 30 is taken off from conductive grid board mount 10, and dry.
Through above-mentioned 17 steps, can utilize three kinds of masks to finish the accurate chromatography spraying of Chinese character pin-shaped three-color phosphor in the conductive grid plate structure plasma scope.
The Spray Gun Of The Pressure spraying method is not only applicable to the preparation of the color fluorescence bisque of conductive grid plate structure plasma scope, and is applicable to barrier type structure plasma scope.Therefore adopt Spray Gun Of The Pressure array spraying method, utilize single kind mask to prepare barrier type structure plasma scope color fluorescence bisque and constitute the 6th kind of embodiment of the present invention, comprise single spraying method of planting three-color phosphor in mask plate 31 and the barrier type structure plasma scope.
The first step, batching.
With the first step among second embodiment.
In second step, stir.
With second step among second embodiment.
The 3rd step, charging.
With the 3rd step among second embodiment.
In the 4th step, the spray gun array is shelved.
According to the required area size of sprayed with fluorescent powder, the number of the spray gun of decision spraying three-color phosphor slurry, its three kinds of spray gun numbers can be respectively between 1-100, the spray gun row of three kinds of purposes of some are formed spray gun array 11, each hopper row is formed hopper array 19, spray gun is linked to each other with hopper array 19, shelve on the support 20 of controller 12.Metacoxal plate 32 is motionless, and moves on the guide rail 21 of spray gun array 11 in support 20, and the length of guide rail 21 is greater than the length of metacoxal plate 32.Adjust the various parameters of spray gun array 11, make it to enter operating state, the pressure of spray gun is adjustable at 0.1～10MPa, and pulp jets speed is adjustable in 0.01～10 milliliters/second.
In the 5th step, single mask is made.
Mask 31 is made of metal or nonmetallic materials, the surface is by the method for corrosion or photoetching, the panel that making is made up of the cell array of complete hollow out, pitch between its cell orifice row is 3 times of metacoxal plate 32 barrier cell columns pitches, and the pitch between mask 31 cell orifices are capable is identical with metacoxal plate 32 barrier cell row pitches.The element mesh hole shape of mask 31 is the hollow out through hole that upper surface is big, lower surface is little, and its shape depends on the shape of metacoxal plate 32 barrier unit, as grid barrier unit or strip barrier unit etc.The overall dimension of the overall dimension of mask 31 mesh lower surfaces and metacoxal plate 32 barrier unit upper surfaces is close, requires it to differ scope within ± 30%.
(a) being that mask 31a is the strip barrier unit, (b) is that mask 31b is grid barrier unit.
In the 6th step, metacoxal plate 32 is shelved with mask 31 contrapositions.
The lower surface of mask 31 and the upper surface of metacoxal plate 32 barrier unit are fitted tightly, and be fixed on the metacoxal plate support 33.By light microscope or have the monitor of CCD system, with the first module hole row and the metacoxal plate 32 first row barrier cell columns centerings of mask 31.
The 7th step, spraying red fluorescence bisque.
Under the effect of spray gun controller 12, spray gun array 11 is at the uniform velocity mobile in the guide rail 21 upper edge x horizontal directions of support 20, spray gun row 13 work simultaneously with red fluorescence powder slurry in the hopper row 14 with vaporific ejection, the effect of blocking through mask 31 accurately is formed uniformly the red fluorescence bisque selectively on metacoxal plate 32 barrier unit inwalls.
In the 8th step, metacoxal plate 32 is shelved with mask 31 contrapositions for the second time.
The lower surface of mask 31 and the upper surface of metacoxal plate 32 barrier unit are fitted tightly, and be fixed on the metacoxal plate support 33.By light microscope or have the monitor of CCD system, with mask 31 displacements one row, with the cell orifice row and the metacoxal plate 32 barrier secondary series cell columns centerings of mask 31.
The 9th step, the spraying green phosphor layer.
Under the effect of spray gun controller 12, spray gun array 11 is at the uniform velocity mobile in the guide rail 21 upper edge x horizontal directions of support 20, spray gun row 15 work simultaneously with green fluorescent powder paste material in the hopper row 16 with vaporific ejection, effect through mask 31 accurately is formed uniformly green phosphor layer selectively on metacoxal plate 32 barrier unit inwalls.
In the tenth step, metacoxal plate 32 is shelved with mask 31 contraposition for the third time.
The lower surface of mask 31 and the upper surface of metacoxal plate 32 barrier unit are fitted tightly, and be fixed on the metacoxal plate support 33.By light microscope or have the monitor of CCD system, with mask 31 displacements one row, with the cell orifice row and metacoxal plate 32 barriers the 3rd column unit row centering of mask 31.
The 11 step, the spraying blue phosphor layer.
Under the effect of spray gun controller 12, spray gun array 11 is at the uniform velocity mobile in the guide rail 21 upper edge x horizontal directions of support 20, spray gun row 17 work simultaneously with hopper row 18 Smalt fluorescent powder paste materials with vaporific ejection, effect through mask 31 accurately is formed uniformly blue phosphor layer selectively on metacoxal plate 32 barrier unit inwalls.
In the 12 step, unload and get metacoxal plate 32.
Through above-mentioned 12 steps, can utilize single accurate chromatography spraying that mask is finished barrier type plasma scope three-color phosphor of planting.Above-mentioned steps can be used the block representation of Figure 25.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03121551 CN1284200C (en) | 2003-04-02 | 2003-04-02 | Method of spray coating three color luminescent powers onto plasma display and used mask plate |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03121551 CN1284200C (en) | 2003-04-02 | 2003-04-02 | Method of spray coating three color luminescent powers onto plasma display and used mask plate |
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| CN1463022A CN1463022A (en) | 2003-12-24 |
| CN1284200C true CN1284200C (en) | 2006-11-08 |
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| CN 03121551 Expired - Fee Related CN1284200C (en) | 2003-04-02 | 2003-04-02 | Method of spray coating three color luminescent powers onto plasma display and used mask plate |
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| CN100511555C (en) * | 2007-04-26 | 2009-07-08 | 南京华显高科有限公司 | Method for finishing jointing counterpoint between working shadow mask and mask shadow quickly and accurately |
| CN101406871B (en) * | 2008-10-14 | 2010-12-08 | 南京华显高科有限公司 | Hollowed spray-finishing method |
| CN103579461B (en) * | 2013-11-08 | 2016-04-13 | 中国科学院半导体研究所 | Prepare the method for wafer scale full-color LED display array |
| CN109781596A (en) * | 2019-02-19 | 2019-05-21 | 南京银纳新材料科技有限公司 | A kind of automatic heating and dehumidification inserted sheet preparation method of miniature controllable temperature |
| JPWO2022038862A1 (en) * | 2020-08-21 | 2022-02-24 |
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