CN1259383C - Peelable type protective film for transparent pasted body - Google Patents
Peelable type protective film for transparent pasted body Download PDFInfo
- Publication number
- CN1259383C CN1259383C CN 200410008981 CN200410008981A CN1259383C CN 1259383 C CN1259383 C CN 1259383C CN 200410008981 CN200410008981 CN 200410008981 CN 200410008981 A CN200410008981 A CN 200410008981A CN 1259383 C CN1259383 C CN 1259383C
- Authority
- CN
- China
- Prior art keywords
- protective film
- propellant
- aerosol liquid
- glue
- solves
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 230000001681 protective effect Effects 0.000 title claims abstract description 11
- 239000003292 glue Substances 0.000 claims abstract description 13
- 239000000443 aerosol Substances 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 238000005507 spraying Methods 0.000 claims abstract description 6
- 239000003380 propellant Substances 0.000 claims description 12
- 239000003112 inhibitor Substances 0.000 claims description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 7
- 229920006122 polyamide resin Polymers 0.000 claims description 7
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 6
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 6
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims description 6
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 6
- 230000003068 static effect Effects 0.000 claims description 6
- 239000004902 Softening Agent Substances 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 239000002904 solvent Substances 0.000 abstract description 4
- 239000003517 fume Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract 2
- 239000002344 surface layer Substances 0.000 abstract 2
- 230000032683 aging Effects 0.000 abstract 1
- 239000005456 alcohol based solvent Substances 0.000 abstract 1
- 239000012752 auxiliary agent Substances 0.000 abstract 1
- 238000003889 chemical engineering Methods 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 238000005562 fading Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- -1 acetyl ricinoleic acid Chemical compound 0.000 description 3
- 230000003712 anti-aging effect Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 230000001857 anti-mycotic effect Effects 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 239000002543 antimycotic Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000006233 lamp black Substances 0.000 description 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- OSNIIMCBVLBNGS-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-2-(dimethylamino)propan-1-one Chemical compound CN(C)C(C)C(=O)C1=CC=C2OCOC2=C1 OSNIIMCBVLBNGS-UHFFFAOYSA-N 0.000 description 1
- IXAZNYYEGLSHOS-UHFFFAOYSA-N 2-aminoethanol;phosphoric acid Chemical compound NCCO.OP(O)(O)=O IXAZNYYEGLSHOS-UHFFFAOYSA-N 0.000 description 1
- CBECDWUDYQOTSW-UHFFFAOYSA-N 2-ethylbut-3-enal Chemical group CCC(C=C)C=O CBECDWUDYQOTSW-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- FKIOYBLZUCCLTL-UHFFFAOYSA-N 4-butyl-2-tert-butyl-5-methylphenol Chemical compound CCCCC1=CC(C(C)(C)C)=C(O)C=C1C FKIOYBLZUCCLTL-UHFFFAOYSA-N 0.000 description 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- JTHNLKXLWOXOQK-UHFFFAOYSA-N n-propyl vinyl ketone Natural products CCCC(=O)C=C JTHNLKXLWOXOQK-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229940037312 stearamide Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to strippable and transparent sticking type protective film which belongs to special paint in the field of chemical engineering. The protective film solves the problems of difficulty, frequency, harm to health, easy damage to impellers, roughness and layer shedding of the surface layer of a machine body, accelerated cycle of oil stain and shortened service life of a fume exhauster in the process of cleaning the fume exhauster by a wet method. The protective film also solves the problems of easy ageing, fading and dirtying and affection to bright and striking advertising effects due to poor outdoor weather resistance of the surfaces of outdoor advertising billboards. The protective film adopts the scheme that actually nontoxic high molecular materials are used as base materials mixed with non-hydrophilic alcohol solvents and auxiliary agents to form content glue solutions, and the content glue solutions and injecting agents form balanced aerosol liquid according to a ratio of 48 to 52. The solubility parameter of the solvents is equal to 11.4, the dielectric constant of dissolved substances is equal to 5.6, and the balanced aerosol liquid is filled in a spraying can. Glue solutions can be uniformly sprayed on surface layers of required objects and can form a film after being dried, and in this way, the sticking type protective film can be formed. The protective film can be easily stripped after being used for 2 years, and thus, the protective film solves the problems.
Description
Technical field: the invention belongs to chemical field, speciality coating.Its main application is in same invention structure, and being applicable to respectively in smoke exhaust ventilator and the kitchen needs anti-smeary object plane top layer and outdoor advertising exhibition board, lamp box, commercial board, pastes and need in word, the copper word that anti-aging is faded, dirty object plane top layer.
Technical problem solved by the invention is: (1) has solved smoke exhaust ventilator with in the wet-cleaned process, comparatively hardships of operation, frequent, impair one's health.The transient equilibrium of impeller is damaged, exhaust air rate is reduced, shake during running and can not using, and make body surface coarse, fluff, fade, delamination, and the problem of having accelerated again the cycle of sticking oil stain, having shortened lampblack absorber work-ing life.
(2) solved the use fumes from cleaning agent and cleaned, many because of consumption, hold imitate short, use frequently the problem of poor effect.
(3) solved because of oil smoke all-pervasively, and made filtering screen, can not block the problem that greasy dirt is sticky with casing inside.
(4) solved the automatic flushing device that lampblack absorber is furnished with, can only work at this rotating part of impeller, and to accounting for the body overwhelming majority, be sticky with greasy dirt equally, the inner and outer shell that can not rotate does not have the problem of efficient, simple and direct solution.
(5) solved outdoor advertisements a surname showpiece, thus the easy weather stain, the dirty problem that has influenced vivid, eye-catching advertising results that cause because of the outdoor weather resistance difference.
The technical solution used in the present invention is: (1) with initiatively protection, the guarantor newly keeps a public place clean, dry method is removed contamination, the completely new approach that sprays again usefulness again solves the problems referred to above.The scheme of specific implementation is, a kind of strippability, transparent fit protective film, it is characterized in that, form aerosol liquid by content glue and propellant, by in the content glue, charge propellant make aerosol liquid from jet stream cloud jar product, through sealed valve, atomizing spraying on required object plane top layer, drying and forming-film; Wherein, by weight, content glue: propellant=48: 52; The content glue is by forming based on the polyvinyl butyral acetal of the gross weight meter 7% of above-mentioned aerosol liquid, 4% TG series low-molecular-weight polyamide resin, 24% propyl carbinol, 12% food grade Pentyl alcohol, 0.4 softening agent, 0.1% flow agent, 0.1% oxidation inhibitor, 0.15% photostabilizer, 0.15% static inhibitor and 0.1% antiseptic-germicide; Propellant is a dme; The specific inductivity of polyvinyl butyral acetal and TG series low-molecular-weight polyamide resin is 5.6, and the solubility parameter of propyl carbinol and food grade Pentyl alcohol is 11.4.
(2) since in add after the softening agent, improve and strengthened the performance of solute, make the rete after the film forming can be in-40 ℃ to 100 ℃ scope, have waterproof, oil-resisting good efficacy, and can oil, water vapour soak repeatedly smoked down, can guarantee 2 years after, the feature that well divests that rete can be in blocks.
(3) since in add oxidation inhibitor and photostabilizer after, endurable anti-aging, resist corrosion and humidity, fast light photograph absorbs ultraviolet ray.Rete is had, keep color and luster vivid, improve the feature of outdoor weather resistance.
(4) since in add static inhibitor after, can make the film surface resistance value 10
9Below ohm, can loss static charge for a long time, reduced the frictional coefficient of film surface.Make rete have elimination static after the film forming, delay the feature of incrustation cycle and anti-scratch.
(5) since in add flow agent, the film surface after the film forming is had, level and smooth, transparent, fine and closely woven can be the feature of one with being coated with object plane good binding.
(6) since in add antiseptic-germicide, make the rete after the film forming have the feature of antimycotic antiseptic.
Background technology: once there were Japanese Patent " the used in air exchange fan overlay film forms agent ", publication number: clear and 55-69665 in the world.Its invention is a matrix by trimerization nylon, is the brush-type solution of solvent with ethanol.After the film forming, because the winter hardiness of rete is poor, easy crisp hard, and wetting ability is strong, and the usage period lacks and is not developed.Domestic " the ventilator greasy dirt protective agent " that the examination as to substances of not entering was once arranged, November 21 91 year applying date; Application number 91110892.0; Publication number CN1072431A." spary coating type, greasy-dirt separation film capable of stripping-off "; October 23 95 year applying date; Application number 95116588.7; Publication number CN1129237A.Its summary of the invention is to be that primary solvent is formed with very strong ethanol of the water absorbability of the polyvinyl butyral acetal of non-modified and employing and water complete miscibility and Virahol.Oil, water, steam soak repeatedly smoked down, can very fast generation whiting, expand, from protruding and lose due effect.And outstanding feature of the present invention is, after having added new solute TG series low-molecular-weight polyamide resin, improving under the effect of softening agent modification and strengthening rete in-40 ℃ to 100 ℃ scope, having the effect of aspects such as waterproof, anti-oil, raising outdoor weather resistance.Guaranteed the present invention after 2 years usage periods, every technical feature of rete and the good result of use of strippability.And increased rete at anti-aging, fast light photograph, raising outdoor weather resistance and functional character antistatic, antimycotic antiseptic.Therefore comparing obvious improvement with existing technology.And it is also different in the selection of use range and propellant.
Summary of the invention: raw material used in the present invention and composition weight percent ratio
1, solute: polyvinyl alcohol butyral 7.0
X=hydroxyl Y=vinyl butyral base Z=acetic acid vinyl
TG series low-molecular-weight polyamide resin 4.0
2, solvent: n-butanol 24.0
The positive amylalcohol 12.0 of food grade
3, plasticizer: acetyl ricinoleic acid fourth fat 0.25
18 alcohol 0.15
4, levelling agent: methyl alkyl polysiloxanes 0.1
5, oxidation inhibitor: 1,1,3 one three one (2-methyl-4-hydroxyl-5-tert-butyl-phenyl) butane
0.1
6, photostabilizer: two (2,2,6,6 one tetramethyl-piperidyl) sebate 0.1
2-(the 2-hydroxyl-3-tertiary butyl-5-aminomethyl phenyl)-5-chlorinated benzotriazole
0.05
7, static inhibitor: stearamide propyl dimethyl one beta-hydroxyethyl ammonium dihydrogen orthophosphate 0.1
N, two (2-hydroxyethyl) alkylamines 0.05 of N-
8, antiseptic-germicide: 2-n-octyl-4-isothiazoline-3-ketone 0.1
9, propellant: dme 52.0
Technical qualification: by weight percentage, content glue: propellant=48: 52;
The specific inductivity of polyvinyl butyral acetal and TG series low-molecular-weight polyamide resin is 5.6, and the solubility parameter of propyl carbinol and food grade Pentyl alcohol is 11.4.
Embodiment: the mode of realization has two operations: 1, raw material quantitatively and carry out the preparation of content glue in stirred vessel.2, the can service line of propellant and check, packing.The base technical process is: raw material quantitatively → stirring and dissolving → digestion filtration → can → seal → inflate → check → beat sign indicating number → packing.
Concrete operation method: 1, spraying object plane should be clean anhydrous.
2, spraying at twice, midfeather 15 minutes.
3, should dry in the air in spray more than 15 ℃.
The form of product: 1,300-700 milliliter capacity is canned from jet stream cloud, can be used for spraying voluntarily.
2, the sealing of 100-600 milliliter capacity is bottled, can be used for manual brushing.
3, the sealing barreled can be used for gas blowout, EFI and dip-coating.
Claims (1)
1, a kind of strippability, transparent fit protective film is characterized in that
Form aerosol liquid by content glue and propellant, by in the foregoing glue, charge above-mentioned propellant make aerosol liquid from jet stream cloud jar product, through sealed valve, atomizing spraying on required object plane top layer, drying and forming-film;
Wherein, by weight, content glue: propellant=48: 52;
The content glue is by forming based on the polyvinyl butyral acetal of the gross weight meter 7% of above-mentioned aerosol liquid, 4% TG series low-molecular-weight polyamide resin, 24% propyl carbinol, 12% food grade Pentyl alcohol, 0.4% softening agent, 0.1% flow agent, 0.1% oxidation inhibitor, 0.15% photostabilizer, 0.15% static inhibitor and 0.1% antiseptic-germicide;
Propellant is a dme;
The specific inductivity of polyvinyl butyral acetal and TG series low-molecular-weight polyamide resin is 5.6, and the solubility parameter of propyl carbinol and food grade Pentyl alcohol is 11.4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410008981 CN1259383C (en) | 2004-03-23 | 2004-03-23 | Peelable type protective film for transparent pasted body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410008981 CN1259383C (en) | 2004-03-23 | 2004-03-23 | Peelable type protective film for transparent pasted body |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1563225A CN1563225A (en) | 2005-01-12 |
| CN1259383C true CN1259383C (en) | 2006-06-14 |
Family
ID=34477755
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410008981 Expired - Fee Related CN1259383C (en) | 2004-03-23 | 2004-03-23 | Peelable type protective film for transparent pasted body |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1259383C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016201504A1 (en) * | 2015-06-16 | 2016-12-22 | Novapharm Research (Australia) Pty Ltd | Method and compositions for cleaning cooking range exhaust systems |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1295287C (en) * | 2005-03-07 | 2007-01-17 | 李仁洙 | Nonstick coating and method for preparing same |
| CN100350982C (en) * | 2006-06-07 | 2007-11-28 | 北京联合大学生物化学工程学院 | Liquid dressing for surgical department |
| CN107337887B (en) * | 2017-07-31 | 2021-11-09 | 韩山师范学院 | Liquid rapid film-forming agent for preventing pine wood nematode disease diffusion |
| CN110960444B (en) * | 2020-01-06 | 2021-03-16 | 浙江美之源化妆品有限公司 | Slow-release lasting antibacterial hand sanitizer and preparation method thereof |
| CN111763485B (en) * | 2020-07-20 | 2021-12-21 | 广东科力德新材料有限公司 | Anti-aging hot melt adhesive containing compound antioxidant |
-
2004
- 2004-03-23 CN CN 200410008981 patent/CN1259383C/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016201504A1 (en) * | 2015-06-16 | 2016-12-22 | Novapharm Research (Australia) Pty Ltd | Method and compositions for cleaning cooking range exhaust systems |
| US10487219B2 (en) | 2015-06-16 | 2019-11-26 | Novapharm Research (Australia) Pty Ltd | Method and compositions for cleaning cooking range exhaust systems |
| AU2016281190B2 (en) * | 2015-06-16 | 2021-07-01 | Novapharm Research (Australia) Pty Ltd | Method and compositions for cleaning cooking range exhaust systems |
| AU2016281190C1 (en) * | 2015-06-16 | 2021-10-28 | Novapharm Research (Australia) Pty Ltd | Method and compositions for cleaning cooking range exhaust systems |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1563225A (en) | 2005-01-12 |
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| ASS | Succession or assignment of patent right |
Owner name: QIAN DATONG Free format text: FORMER OWNER: QIAN DA Effective date: 20091023 |
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Effective date of registration: 20091023 Address after: Unit 4, building 6, 71 middle 238 Road, Xinshi District, Hebei, Baoding, 201 Patentee after: Qian Datong Address before: Unit 4, building 6, 71 middle 238 Road, Xinshi District, Hebei, Baoding, 201 Patentee before: Qian Da |
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Granted publication date: 20060614 Termination date: 20100323 |