CN101130718B - Compositions for cleaning ''scaly tetter'' and processes for producing same - Google Patents
Compositions for cleaning ''scaly tetter'' and processes for producing same Download PDFInfo
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- CN101130718B CN101130718B CN2006100200357A CN200610020035A CN101130718B CN 101130718 B CN101130718 B CN 101130718B CN 2006100200357 A CN2006100200357 A CN 2006100200357A CN 200610020035 A CN200610020035 A CN 200610020035A CN 101130718 B CN101130718 B CN 101130718B
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- composition
- cleaning
- methyl
- pyrrolidone
- diluent
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- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 9
- 238000004140 cleaning Methods 0.000 title abstract description 22
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000003973 paint Substances 0.000 claims abstract description 19
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000853 adhesive Substances 0.000 claims abstract description 15
- 230000001070 adhesive effect Effects 0.000 claims abstract description 15
- 239000003085 diluting agent Substances 0.000 claims abstract description 15
- 238000003756 stirring Methods 0.000 claims abstract description 14
- -1 Polyoxyethylene nonylphenol Polymers 0.000 claims description 13
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 201000004681 Psoriasis Diseases 0.000 abstract description 12
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 26
- 230000000052 comparative effect Effects 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000008595 infiltration Effects 0.000 description 3
- 238000001764 infiltration Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 208000017667 Chronic Disease Diseases 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 208000002193 Pain Diseases 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000011440 grout Substances 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The invention discloses a composition of psoriasis and making method, which is characterized by the following: adding n-butanol into N-methyl-2 pyrrolidone to stir; adding nitro diluent to stir; adding nonyl phenol polyoxyethylene ether to stir evenly; using the pot or tank or bottle with sprayer to can the composition to spray on the ink trace, paint trace and adhesive trace in the public placement and random someplace of living room; cleaning and stripping the trace within 5-10s without changing the object appearance. The invention overcomes the defect of slow cleaning speed, single cleaning object, narrow cleaning scale, incomplete cleaning and appearance keeping, which has good adaptability.
Description
Technical field
The present invention relates to a kind of sanitising agent, more particularly, the present invention relates to the composition and method of making the same of a kind of cleaning " psoriasis ".
Background technology
Disorderly paste, scrawl small advertisement, the illegal ad write is called for fun " psoriasis " always.
Because small advertisement, illegal ad producer printing ink commonly used, paint, nonvolatil mark ink, non-setting adhesive etc. are scribbled or are pasted, firm attachment in the communal facility surface (as buildings, bus stop board, road and bridge protects and blocks, electric power, telecommunications, postal facility, shops's cloth mark billboard and shutter door etc.).These small advertisements, illegal ad are difficult to thoroughly remove clean with common sanitising agent, what have have to use coating, grout covering, patch installing, causes new pollution so again, can not reach the purpose of removing.
Various small advertisements, illegal ad not only pollute city and rural environment, and interference civil order, also be the various delinquent greenhouses that grow, the formidable enemy of city city look and feel especially, become the chronic disease that each city, the whole nation is difficult to effect a radical cure, the difficult problem of government's headache, media spotlight, the major issue that common people have strong complaints, a pain in the neck of department such as the appearance of the city, municipal administration, environmental sanitation and Street Community.
In order to address the above problem, from Chinese patent network, do not find the cleanser compositions that can remove " psoriasis ", found the composition and the preparation method that can remove ink marks " chemical reagent preparation " book of publishing by Jiangsu science tech publishing house from publication.This method is to make two kinds of liquid: I liquid, with 20 the gram chlorinated lime be dissolved in 100 ml waters solution and 15 the gram salt of wormwood or 12 the gram yellow soda ash be dissolved in 100 milliliters aqueous solution, elimination is not tolerant.II liquid is dissolved in 5 gram oxalic acid in 100 ml waters. and be coated with II liquid during use earlier and be coated with I liquid again and can remove ironmould.But, adopt this method can only remove common ironmould, to printing ink, paint, the little poor effect of permanent mark ink effect.In addition, use two kinds of solution very inconvenient and not easy to operate at the scene.
Select in the existing from the market sanitising agent to try out, what have can only have certain effect to ink, printing ink, paint, non-setting adhesive etc. are wherein a kind of, but can not remove " psoriasis " completely comprehensive, comprehensively.
Summary of the invention
The objective of the invention is to provide the small advertisement that a kind of quick removing scribbles with printing ink, paint, permanent mark ink etc. and the multifunction detergent composition of adhesive label, to solve the problem that small advertisement is difficult to remove.Various inks, printing ink, paint be can remove fast with the composition of a kind of cleaning of the present invention " psoriasis " and advertisement and adhesive label on any object scribbled.
Another object of the present invention provides a kind of preparation method of above-mentioned composition.
The composition of a kind of cleaning of the present invention " psoriasis " by weight percentage, said composition is composed of the following components:
N-methyl-2 pyrrolidone 21%-40%
Propyl carbinol 18%-38%
Nitro-diluent 20%-40%
Polyoxyethylene nonylphenol ether 1%-2%
Or polyoxyethylene octylphenol ether 1%-2%
In above-mentioned composition, N-methyl-2 pyrrolidone (N-methyl-2pyrrolidone; NMP) relative molecular weight 99.13, are colourless liquid, can mix with alcohol, ketone equal solvent, and extremely strong water absorbability, weakly alkaline are arranged, and dissolving power is strong, are widely used in polymkeric substance and synthesize.In washing composition, being used for cooking stove sanitising agent, hard surface cleaner, coating remover, ink household cleanser etc. it plays a crucial role in said composition.Propyl carbinol (C4H100) structural formula is that CH3-CH2-CH2-CH2-OH is a colourless liquid, is soluble in ketone, is commonly used for solvent.Propyl carbinol and the combination of N-methyl-2 pyrrolidone can improve solubleness.Nitro-diluent is the volatile liquid of water white transparency, is used for paint, printing ink, paint solvent and thinner.Be used in the dissolving that can quicken paint, printing ink in the said composition, and volatilization fast, shorten in the action time of body surface, avoid damaging object.Polyoxyethylene nonylphenol ether is a nonionogenic tenside, have a series of high-performances such as wetting, emulsification, dispersion, infiltration, washing, and have pH value adjustability widely, be used in and improve the ability of removing the ink vestiges in the said composition, and improve the stability of composition.
In above-mentioned composition, N-methyl-2 pyrrolidone weight percent is preferably 23%-38%, the propyl carbinol weight percent is preferably 23%-37%, and the nitro-diluent weight percent is preferably 22%-38%, and the polyoxyethylene nonylphenol ether weight percent is preferably 1%-2%.
Aforesaid combination and percentage range make composition-sanitising agent of the present invention have that perviousness is strong, speed is fast, clean range is wide, to advantages such as the object original appearance do not change.
The preparation method of cleanser compositions of the present invention is made up of following steps successively:
Respectively that various raw material metering packing are standby by the weight percent of determining, clean stirred vessel and dry water.
N-methyl-2 pyrrolidone is poured into stirred vessel earlier start stirring.
Propyl carbinol slowly added in the stirred vessel stir.
Nitro-diluent was added in the stirred vessel restir ten minutes again.
Again polyoxyethylene nonylphenol ether is added in the stirred vessel and stir.
The cleanser compositions branch of making is installed in kettle or bottle or the jar.
Above-mentioned steps is all carried out under normal temperature and normal pressure and sealed state.
The composition of a kind of cleaning of the present invention " psoriasis ", the kettle of available band nozzle jar or bottle directly be sprayed onto 5-10 second on the body surface of cleaning behind the splendid attire, smear or the water flushing gets final product with cloth.
The composition of a kind of cleaning of the present invention " psoriasis " is applicable to the ink marks on public place and room and the advertisement cloth, the cleaning of painting mark, non-setting adhesive.
The present invention writes the composition of understanding the composition that cleans " psoriasis ".Each component structure, feature, effect, and composition in the weight percent that accounts for and preparation method, using appliance and using method and the scope of application of cleansing composition.
Embodiment
The following stated embodiment describes the present invention in detail.Cleaning speed represents that with " second " this numerical value is got over the bright cleaning speed of novel, and The faster the better in the following Examples and Comparative Examples; Ink marks, paint mark and non-setting adhesive clearance represent that with " % " these numerical value are high more good more.
Embodiment and Comparative Examples are listed as follows:
| Each component and performance | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative Examples 1 | Comparative Examples 2 |
| N-methyl-2 pyrrolidone % | 35 | 40 | 21 | 10 | 30 |
| Each component and performance | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative Examples 1 | Comparative Examples 2 |
| Propyl carbinol % | 30 | 18 | 38 | 30 | 58 |
| Nitro-diluent % | 33 | 40 | 40 | 58 | 11 |
| Polyoxyethylene nonylphenol ether % | 2 | 2 | 1 | 2 | 1 |
| Cleaning speed (second) | 5 | 10 | 12 | 15 | 20 |
| Infiltration ink marks clearance % | 99 | 95 | 90 | 70 | 95 |
| There is not infiltration ink marks clearance % | 100 | 100 | 100 | 90 | 100 |
| Paint mark clearance % | 100 | 99 | 98 | 90 | 70 |
| Non-setting adhesive clearance % | 100 | 95 | 95 | 80 | 85 |
[0032]Embodiment 1
At normal temperatures and pressures, by specified each weight percentages of components in the table propyl carbinol and the mixing of N-methyl-2 pyrrolidone are stirred respectively, add the nitro-diluent mixing again and stir, add polyoxyethylene nonylphenol ether again and mix stirring, make " psoriasis " sanitising agent.After this, this sanitising agent is arrived on-the-spot use test cleaning speed, ink marks clearance, paint clearance and non-setting adhesive clearance.In last table, listed test result.
Embodiment 2
Repeat the method for embodiment 1 by specified various weight percentages of components in the table.But increased N-methyl-2 pyrrolidone weight percent, reduced the propyl carbinol weight percent, in last table, listed the result of test.
Embodiment 3
Repeat the method for embodiment 1 by specified various weight percentages of components in the table.But reduced N-methyl-2 pyrrolidone weight percent and increased the propyl carbinol weight percent, in last table, listed the result of test.
Comparative Examples 1
At normal temperatures and pressures, N-methyl-2 pyrrolidone, propyl carbinol, nitro-diluent and polyoxyethylene nonylphenol ether are mixed stirring, make " psoriasis " sanitising agent by specified each weight percentages of components in the table.In composition, reduce N-methyl-2 pyrrolidone weight percent, increased the nitro-diluent weight percent.The cleanser compositions of making has been listed the result of test to on-the-spot use test cleaning speed, ink marks clearance, paint mark clearance and non-setting adhesive clearance in last table.
Comparative Examples 2
At normal temperatures and pressures, N-methyl-2 pyrrolidone is mixed with nitro-diluent, propyl carbinol is mixed with polyoxyethylene nonylphenol ether, again two groups of mixtures are mixed the back and stir, make detergent mixture by specified each weight percentages of components in the table.Increase the propyl carbinol weight percent in this mixture, reduced the nitro-diluent weight percent.After this, to on-the-spot use test cleaning speed, ink marks clearance, paint mark clearance and non-setting adhesive clearance, in last table, listed the result of test.
Can reach a conclusion from embodiment and Comparative Examples.N-methyl-2 pyrrolidone and nitro-diluent are slow more at the few more cleaning speed of component that composition accounts for.N-methyl-2 pyrrolidone is few more low more to being penetrated into object the inside ink marks clearance in the component that composition accounts for, and description effect is poor more.The more paint mark clearances that make of the component that propyl carbinol accounts in each composition low more more, and description effect is poor more.
In addition, Comparative Examples is different with the mixing stirring means of embodiment all influential to cleaning speed, ink marks clearance, paint mark clearance and non-setting adhesive clearance.
No matter on the single performance still on the over-all properties, cleansing composition of the present invention all has the cleansing composition that is better than Comparative Examples significantly for the test result of each embodiment and Comparative Examples cleaning speed, ink marks, paint mark, non-setting adhesive clearance explanation in the above-mentioned table.
Claims (5)
1. composition of removing printing ink, paint, inkblot and non-setting adhesive, said composition is composed of the following components by weight percentage:
N-methyl-2 pyrrolidone 21%-40%
Propyl carbinol 18%-38%
Nitro-diluent 20%-40%
Polyoxyethylene nonylphenol ether or polyoxyethylene octylphenol ether 1%-2%.
2. according to the described composition of claim 1, wherein the weight percent of N-methyl-2 pyrrolidone is 23%-38%.
3. according to the described composition of claim 1, wherein the propyl carbinol weight percent is 23%-37%.
4. according to the described composition of claim 1, wherein the weight percent of nitro-diluent is 22%-38%.
5. one kind according to the described preparation of compositions method of claim 1: this method comprises the steps:
(1) propyl carbinol is added in N-methyl-2 pyrrolidone and stir;
(2) under whipped state nitro-diluent being joined above-mentioned solution for continuous stirs;
(3) polyoxyethylene nonylphenol ether or polyoxyethylene octylphenol ether are joined above-mentioned solution for continuous stirring ten minutes;
Above steps is carried out under normal temperature and normal pressure and sealed state.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100200357A CN101130718B (en) | 2006-08-23 | 2006-08-23 | Compositions for cleaning ''scaly tetter'' and processes for producing same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100200357A CN101130718B (en) | 2006-08-23 | 2006-08-23 | Compositions for cleaning ''scaly tetter'' and processes for producing same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101130718A CN101130718A (en) | 2008-02-27 |
| CN101130718B true CN101130718B (en) | 2010-11-10 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006100200357A Expired - Fee Related CN101130718B (en) | 2006-08-23 | 2006-08-23 | Compositions for cleaning ''scaly tetter'' and processes for producing same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101130718B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102807933B (en) * | 2012-08-24 | 2014-04-09 | 刘杰 | Non-setting adhesive cleaning agent and preparation method thereof |
| CN103992891A (en) * | 2014-04-24 | 2014-08-20 | 章晓霞 | Cleanser of non-setting adhesive |
| CN105219542B (en) * | 2015-10-22 | 2021-08-06 | 西安文理学院 | An environmentally friendly and non-toxic self-adhesive residue scavenger and preparation method thereof |
| CN111454789B (en) * | 2020-04-07 | 2021-05-11 | 苏州健雄职业技术学院 | A kind of stamp adhesive cleaning agent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1114350A (en) * | 1994-06-29 | 1996-01-03 | 首钢总公司 | General-purpose hard surface detergent |
| CN1524939A (en) * | 2003-09-15 | 2004-09-01 | 李伟光 | Multifunctional scrubbing cleanser |
-
2006
- 2006-08-23 CN CN2006100200357A patent/CN101130718B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1114350A (en) * | 1994-06-29 | 1996-01-03 | 首钢总公司 | General-purpose hard surface detergent |
| CN1524939A (en) * | 2003-09-15 | 2004-09-01 | 李伟光 | Multifunctional scrubbing cleanser |
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| Publication number | Publication date |
|---|---|
| CN101130718A (en) | 2008-02-27 |
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Granted publication date: 20101110 Termination date: 20130823 |