CN1230149A - Metallic object provided with areas of contrasting appearance - Google Patents
Metallic object provided with areas of contrasting appearance Download PDFInfo
- Publication number
- CN1230149A CN1230149A CN97197747A CN97197747A CN1230149A CN 1230149 A CN1230149 A CN 1230149A CN 97197747 A CN97197747 A CN 97197747A CN 97197747 A CN97197747 A CN 97197747A CN 1230149 A CN1230149 A CN 1230149A
- Authority
- CN
- China
- Prior art keywords
- layer
- nonferrous layer
- zone
- nonferrous
- metal base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 claims abstract description 24
- 239000000758 substrate Substances 0.000 claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims description 21
- 239000002184 metal Substances 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 235000013361 beverage Nutrition 0.000 claims description 6
- 239000003822 epoxy resin Substances 0.000 claims description 4
- 210000004276 hyalin Anatomy 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 239000011159 matrix material Substances 0.000 claims description 2
- 230000001678 irradiating effect Effects 0.000 claims 1
- 239000010410 layer Substances 0.000 description 29
- 238000000608 laser ablation Methods 0.000 description 10
- 239000003086 colorant Substances 0.000 description 6
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 4
- 239000003973 paint Substances 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000013532 laser treatment Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/24—Ablative recording, e.g. by burning marks; Spark recording
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/22—Removing surface-material, e.g. by engraving, by etching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
- B44C3/005—Removing selectively parts of at least the upper layer of a multi-layer article
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D1/00—Rigid or semi-rigid containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material or by deep-drawing operations performed on sheet material
- B65D1/12—Cans, casks, barrels, or drums
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
- B65D25/20—External fittings
- B65D25/205—Means for the attachment of labels, cards, coupons or the like
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Ceramic Engineering (AREA)
- Laminated Bodies (AREA)
- Details Of Rigid Or Semi-Rigid Containers (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Chemically Coating (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Wrappers (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
- Rigid Containers With Two Or More Constituent Elements (AREA)
- Physical Vapour Deposition (AREA)
Abstract
The present invention relates to a process for making visually contrasting structures on a metallic substrate , characterized in that the substrate which is coated with a single coloured layer is partially subjected to the energy of a laser beam in such a way that a transparent remainder of the layer is maintained on the treated area; a metallic substrate which is provided with visually contrasting structures, characterized in that a single coloured layer is present on part of the substrate, while on the remaining part of the substrate in place of this layer a single transparent layer which is substantially thinner as compared to the single coloured layer is present.
Description
The present invention relates to the metal base that the surface has different visible color zone, this metal base is suitable for making or the container of processing beverage bucket and so on.
Now, mode below the general using is being made sign with two kinds of colors, label etc. on the metal base: apply upper and lower two-layer epoxy resin enamelled coating with different colours on this metal base respectively, utilize laser ablation then, the enamelled coating that will be positioned at the superiors is partly removed, thereby the enamelled coating in some the superiors has been removed the zone that evaporates in other words, and the enamelled coating with another color that is positioned at the bottom is come out.
The cost of this method is very high because on metal base the process of coated with resins (paint), need in dividing other workflow, carry out twice.For for example being tabular or the base material of sheet, this flow process is very long and loaded down with trivial details, this is because because before the paint of coating equipment a kind of different colours under applying, must be by thoroughly cleaning is clean, therefore before second layer coating subsequently, equipment has to supspend work, and this greatly reduces the production efficiency of whole production line.But, up to now till, also nobody proposes a kind of better method that on a large scale lacquer of two kinds of different colours is coated on the metal base.
The objective of the invention is to propose a kind of, than existing, faster, cost is the lowland large scale production method more.
Purpose of the present invention passes through only to apply unique one deck nonferrous layer on metal base, and selecting the zone, utilizes laser ablation, and the thickness of this nonferrous layer of attenuate (evaporation) is finished.Have found that, utilize low power laser treatment one nonferrous layer of comparing with existing method, can this nonferrous layer of attenuate, make it the clear-coated film of the very thin shape of film in other words of only remaining one deck, because this layer coat film is translucent, therefore the color of metal base itself can display, thereby presents multiple different color on whole base material.
Describe the present invention below in conjunction with accompanying drawing.
Fig. 1 shows method of the present invention and final products.Figure 1A shows that wherein base material 1 is coated with a nonferrous layer 2 fully before laser ablation; Figure 1B shows, an appointed area 4, after by laser ablation these nonferrous layer 2 parts being evaporated, produces the hyaline layer that stays 3 that thickness is significantly smaller than nonferrous layer 2.
Figure 2 shows that the existing method mentioned in this paper front.Opposite with the present invention, shown in Fig. 2 A, under first nonferrous layer 2 ', comprise also that on this metal base 1 ' another one has second nonferrous layer 5 ' of different colours, this nonferrous layer 5 ' directly is coated on the base material.Shown in Fig. 2 B, the irradiation of laser beam causes being evaporated fully at the processed regional 4 ' nonferrous layer of locating 2 ', and most of thickness of second nonferrous layer 5 ' then is retained, thereby locates in zone 4 ', and the color of the second layer 5 ' is displayed.
In general, the thickness of nonferrous layer is optional, and depends on known consideration (intensity of anti-indentation, price or the like).In the prior art, the thickness of bottom nonferrous layer is generally about 3-4um, and superposed nonferrous layer thinner (for example at 0.5-2um), and unique one deck nonferrous layer of the present invention, can be for example identical or thinner slightly (for example approximately 2-4um, be preferably) less than 3um with the thickness of nonferrous layer in the existing method.By laser ablation, remaining is extremely thin one deck (remaining thickness is between the original 1/6-1/3).The nonferrous layer that is 3um for a thickness for example, through behind the laser ablation, remaining layer thickness that can be transparent is 0.6um.
In the method according to this invention, can adopt traditional laser ablation mode.For example obtain with the dot matrix mode of printing, letter, individual character, icon, pattern etc. are covered or the cuticula that only they come out or template are covered after on the metal base, carry out laser ablation.Needed laser power depends on the thickness of coat, and those of ordinary skill in the art fully can calculate.Certainly, powerful laser ablation can be removed the coat of big thickness.Than removing superposed coat in the prior art, the needed laser energy of coat that the present invention is unique even under situation about being of uniform thickness, also can significantly reduce.Therefore.For the present invention, use nitric oxide (NO) laser instrument can reach goal of the invention fully.The needed laser power of method of the present invention is, in zone selected, that expose, most of thickness of nonferrous layer is removed, thereby make one deck that stay, very thin become more transparent, therefore the color of metal base is able to come out as another color, thereby, like metallic substrate surface well and had two kinds of colors.
Utilize method of the present invention can produce the layer that stays of an actual transparency really, this fact can draw by the experience of utilizing copper sulphate to handle base material fully.
Unique one deck nonferrous layer can constitute by applying general for example epoxy resin shape paint.As for color, without any restriction, black is relatively good because this color can and the translucent background color of metal base (for example aluminium, steel) constitute contrast.
Because laser ablation of the present invention does not all evaporate the nonferrous layer composition of exposed region; so one deck colorless film that stay, very thin; can be used as protective layer protects metal base not to be subjected to the erosion of air; and as the barrier layer; resist of the erosion of other material to metal base; and, prevent that metal from getting rusty as overcoat.
The method according to this invention can be passed through a simple mode, produces novel metallic sheet, and this metallic sheet is anticorrosion and have a beautiful external form.Method of the present invention is except can being used to produce the planar metal base material, can also be used to produce canister, this canister can be to utilize method of the present invention to apply after moulding, also can be to utilize method of the present invention to apply back reshaping afterwards.As a kind of selection, also can be to utilize method of the present invention to handle in the specific region of container or bucket, for example the bottom of container or the draw ring of Beverage pail (perhaps being referred to as " pulling-on piece ") are handled, thereby on the back side of for example draw ring, can form a very little mark, with as distinguishing mark of the producer or internal staff etc.
Claims (11)
1, a kind of method that is used on metallic substrate surface, making different visible color zone, it is characterized in that, on described metal base, only apply unique one deck nonferrous layer, shine a zone of this described unique nonferrous layer then with laser, removing the segment thickness of this zone nonferrous layer, up to the described nonferrous layer in described zone become transparent till.
2, method as claimed in claim 2 is characterized in that, described nonferrous layer is made of epoxy resin coating.
3, method as claimed in claim 1 or 2 is characterized in that, in the implementation process of described method, and zone this nonferrous layer, that need not be subjected to the laser irradiation, diaphragm is stamped in lining.
4, method as claimed in claim 1 or 2 is characterized in that, the laser irradiation is carried out in the mode of dot matrix printing.
5, a kind of metal base, the surface has different visible color zone, it is characterized in that, only applies unique one deck nonferrous layer on the part of described base material, simultaneously only apply unique layer of transparent layer in other zone of described base material, described hyaline layer is thinner than the thickness of described nonferrous layer.
6, base material as claimed in claim 5 is characterized in that, described nonferrous layer is made of epoxy resin coating.
As claim 5 or 6 described base materials, it is characterized in that 7, described hyaline layer forms by divide nonferrous layer with laser irradiating part.
8, a kind of container is characterized in that, described container to small part is made of the described metal base of claim 5-7.
9, a kind of Beverage pail is characterized in that, described Beverage pail to small part is made of the described metal base of claim 5-7.
10, a kind of Beverage pail has draw ring, it is characterized in that, described draw ring to small part is made of the described metal base of claim 5-7.
11, Beverage pail as claimed in claim 10 is characterized in that, have described nonferrous layer at least on the back side of described draw ring, and described hyaline layer only is arranged on the back side of described draw ring.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19636763.8 | 1996-09-10 | ||
| DE19636763 | 1996-09-10 | ||
| DE19701547A DE19701547A1 (en) | 1996-09-10 | 1997-01-17 | Metallic background with contrasting visual structures |
| DE19701547.6 | 1997-01-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1230149A true CN1230149A (en) | 1999-09-29 |
Family
ID=26029223
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97197747A Pending CN1230149A (en) | 1996-09-10 | 1997-09-09 | Metallic object provided with areas of contrasting appearance |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP0923457B1 (en) |
| KR (1) | KR100488321B1 (en) |
| CN (1) | CN1230149A (en) |
| AT (1) | ATE203214T1 (en) |
| CZ (1) | CZ294792B6 (en) |
| DE (1) | DE29716186U1 (en) |
| DK (1) | DK0923457T3 (en) |
| ES (1) | ES2161476T3 (en) |
| PL (1) | PL185452B1 (en) |
| SK (1) | SK284674B6 (en) |
| TR (1) | TR199900518T2 (en) |
| WO (1) | WO1998010945A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109849459A (en) * | 2019-01-29 | 2019-06-07 | 大连盛维包装有限公司 | A kind of composite material and preparation method and gloss processing method with metal layer |
| CN112207446A (en) * | 2020-10-13 | 2021-01-12 | 萍乡安源包装有限公司 | Lacquer laser engraving process and application thereof |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW473429B (en) * | 1998-07-22 | 2002-01-21 | Novartis Ag | Method for marking a laminated film material |
| EP1225057A1 (en) * | 2001-01-22 | 2002-07-24 | Novartis AG | Method for marking a laminated film material |
| US8146768B2 (en) | 2009-02-04 | 2012-04-03 | Rexam Beverage Can Company | Tab with emboss and deboss beads |
| US8844747B2 (en) | 2010-03-19 | 2014-09-30 | Rexam Beverage Can Company | And temperature indicating can ends and tabs |
| US20130075401A1 (en) | 2011-09-23 | 2013-03-28 | Rexam Beverage Can Company | Stay-on tab for a beverage container |
| US9186924B2 (en) | 2012-04-17 | 2015-11-17 | Rexam Beverage Can Company | Decorated beverage can tabs |
| EP3354477A1 (en) * | 2017-01-25 | 2018-08-01 | Anheuser-Busch Inbev Sa/Nv | Printing process for a beverage container |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE421880B (en) * | 1981-06-17 | 1982-02-08 | Wladimir Wladimiroff | SUBJECT FOR LASER BRADING |
| US4547649A (en) * | 1983-03-04 | 1985-10-15 | The Babcock & Wilcox Company | Method for superficial marking of zirconium and certain other metals |
| JPS631483A (en) * | 1986-06-19 | 1988-01-06 | Mitsubishi Electric Corp | Coloration of metal decorative panel |
| FR2649628B3 (en) * | 1989-07-12 | 1991-07-05 | Duvicq Ets Charles | METHOD OF MARKING ALUMINUM PARTS BY PROJECTION OF A LASER RADIUS |
| GB9023243D0 (en) * | 1990-10-25 | 1990-12-05 | Cmb Foodcan Plc | Containers |
-
1997
- 1997-09-09 ES ES97944864T patent/ES2161476T3/en not_active Expired - Lifetime
- 1997-09-09 PL PL97331938A patent/PL185452B1/en not_active IP Right Cessation
- 1997-09-09 AT AT97944864T patent/ATE203214T1/en not_active IP Right Cessation
- 1997-09-09 CZ CZ1999811A patent/CZ294792B6/en not_active IP Right Cessation
- 1997-09-09 DE DE29716186U patent/DE29716186U1/en not_active Expired - Lifetime
- 1997-09-09 EP EP97944864A patent/EP0923457B1/en not_active Expired - Lifetime
- 1997-09-09 SK SK315-99A patent/SK284674B6/en unknown
- 1997-09-09 WO PCT/EP1997/004937 patent/WO1998010945A1/en active IP Right Grant
- 1997-09-09 DK DK97944864T patent/DK0923457T3/en active
- 1997-09-09 TR TR1999/00518T patent/TR199900518T2/en unknown
- 1997-09-09 CN CN97197747A patent/CN1230149A/en active Pending
- 1997-09-09 KR KR10-1999-7001992A patent/KR100488321B1/en not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109849459A (en) * | 2019-01-29 | 2019-06-07 | 大连盛维包装有限公司 | A kind of composite material and preparation method and gloss processing method with metal layer |
| CN112207446A (en) * | 2020-10-13 | 2021-01-12 | 萍乡安源包装有限公司 | Lacquer laser engraving process and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE29716186U1 (en) | 1997-11-06 |
| EP0923457B1 (en) | 2001-07-18 |
| ES2161476T3 (en) | 2001-12-01 |
| SK31599A3 (en) | 1999-10-08 |
| EP0923457A1 (en) | 1999-06-23 |
| CZ294792B6 (en) | 2005-03-16 |
| TR199900518T2 (en) | 1999-07-21 |
| WO1998010945A1 (en) | 1998-03-19 |
| PL331938A1 (en) | 1999-08-16 |
| KR20000036018A (en) | 2000-06-26 |
| PL185452B1 (en) | 2003-05-30 |
| ATE203214T1 (en) | 2001-08-15 |
| SK284674B6 (en) | 2005-09-08 |
| KR100488321B1 (en) | 2005-07-12 |
| CZ81199A3 (en) | 1999-10-13 |
| DK0923457T3 (en) | 2001-11-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| AD01 | Patent right deemed abandoned | ||
| C20 | Patent right or utility model deemed to be abandoned or is abandoned |