CN1223270C - Bactericide composition - Google Patents
Bactericide composition Download PDFInfo
- Publication number
- CN1223270C CN1223270C CN 02109547 CN02109547A CN1223270C CN 1223270 C CN1223270 C CN 1223270C CN 02109547 CN02109547 CN 02109547 CN 02109547 A CN02109547 A CN 02109547A CN 1223270 C CN1223270 C CN 1223270C
- Authority
- CN
- China
- Prior art keywords
- composition
- syp
- protection effect
- bactericide
- control efficiency
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 164
- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 16
- 239000003899 bactericide agent Substances 0.000 title abstract description 14
- 239000005867 Iprodione Substances 0.000 claims abstract description 22
- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 claims abstract description 22
- CFZLNRGUBAVQNO-UHFFFAOYSA-N N-(3,5-Dichlorophenyl)succinimide Chemical compound ClC1=CC(Cl)=CC(N2C(CCC2=O)=O)=C1 CFZLNRGUBAVQNO-UHFFFAOYSA-N 0.000 claims abstract description 20
- QXJKBPAVAHBARF-BETUJISGSA-N procymidone Chemical compound O=C([C@]1(C)C[C@@]1(C1=O)C)N1C1=CC(Cl)=CC(Cl)=C1 QXJKBPAVAHBARF-BETUJISGSA-N 0.000 claims abstract description 20
- FSCWZHGZWWDELK-UHFFFAOYSA-N 3-(3,5-dichlorophenyl)-5-ethenyl-5-methyl-2,4-oxazolidinedione Chemical compound O=C1C(C)(C=C)OC(=O)N1C1=CC(Cl)=CC(Cl)=C1 FSCWZHGZWWDELK-UHFFFAOYSA-N 0.000 claims abstract description 16
- JDZSMXLTQNHBRF-UHFFFAOYSA-N Dichlozoline Chemical compound O=C1C(C)(C)OC(=O)N1C1=CC(Cl)=CC(Cl)=C1 JDZSMXLTQNHBRF-UHFFFAOYSA-N 0.000 claims abstract description 6
- 230000003641 microbiacidal effect Effects 0.000 claims description 15
- 229940124561 microbicide Drugs 0.000 claims description 15
- 239000002855 microbicide agent Substances 0.000 claims description 15
- WEQPBCSPRXFQQS-UHFFFAOYSA-N 4,5-dihydro-1,2-oxazole Chemical compound C1CC=NO1 WEQPBCSPRXFQQS-UHFFFAOYSA-N 0.000 claims description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 21
- 201000010099 disease Diseases 0.000 abstract description 20
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 abstract description 6
- 241000123650 Botrytis cinerea Species 0.000 abstract description 4
- 150000001412 amines Chemical class 0.000 abstract description 4
- IGUYEXXAGBDLLX-UHFFFAOYSA-N ethyl 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-1,3-oxazolidine-5-carboxylate Chemical compound O=C1C(C(=O)OCC)(C)OC(=O)N1C1=CC(Cl)=CC(Cl)=C1 IGUYEXXAGBDLLX-UHFFFAOYSA-N 0.000 abstract description 4
- 230000002195 synergetic effect Effects 0.000 abstract description 4
- FTCOKXNKPOUEFH-UHFFFAOYSA-N Myclozolin Chemical compound O=C1C(COC)(C)OC(=O)N1C1=CC(Cl)=CC(Cl)=C1 FTCOKXNKPOUEFH-UHFFFAOYSA-N 0.000 abstract description 3
- 241000221662 Sclerotinia Species 0.000 abstract description 2
- 150000003949 imides Chemical class 0.000 abstract 3
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 abstract 2
- 244000052616 bacterial pathogen Species 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 91
- 238000002360 preparation method Methods 0.000 description 46
- 230000001408 fungistatic effect Effects 0.000 description 26
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 22
- -1 carboxylic acid imide Chemical class 0.000 description 22
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
- 239000013543 active substance Substances 0.000 description 20
- 239000003814 drug Substances 0.000 description 17
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 15
- 244000052769 pathogen Species 0.000 description 14
- 230000001717 pathogenic effect Effects 0.000 description 14
- 239000000843 powder Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 12
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 240000003768 Solanum lycopersicum Species 0.000 description 11
- 210000000481 breast Anatomy 0.000 description 11
- 238000009313 farming Methods 0.000 description 11
- 239000003921 oil Substances 0.000 description 11
- 235000019198 oils Nutrition 0.000 description 11
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 241000894006 Bacteria Species 0.000 description 8
- 244000046052 Phaseolus vulgaris Species 0.000 description 8
- 239000006229 carbon black Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000007859 condensation product Substances 0.000 description 7
- 239000000417 fungicide Substances 0.000 description 7
- 239000000375 suspending agent Substances 0.000 description 7
- 238000009736 wetting Methods 0.000 description 7
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 235000002566 Capsicum Nutrition 0.000 description 6
- 240000008574 Capsicum frutescens Species 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- 239000001390 capsicum minimum Substances 0.000 description 6
- 239000013530 defoamer Substances 0.000 description 6
- 239000010440 gypsum Substances 0.000 description 6
- 229910052602 gypsum Inorganic materials 0.000 description 6
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 230000003385 bacteriostatic effect Effects 0.000 description 5
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- XUZHLZDRCCUWEV-UHFFFAOYSA-N formaldehyde;methyl naphthalene-1-sulfonate Chemical compound O=C.C1=CC=C2C(S(=O)(=O)OC)=CC=CC2=C1 XUZHLZDRCCUWEV-UHFFFAOYSA-N 0.000 description 5
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 5
- 238000011835 investigation Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
- 239000002023 wood Substances 0.000 description 5
- ZITVKGIRQCDOSX-UHFFFAOYSA-N 1h-cyclopropa[a]naphthalene Chemical compound C1=CC=CC2=C3CC3=CC=C21 ZITVKGIRQCDOSX-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 4
- 239000000779 smoke Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 4
- 239000004562 water dispersible granule Substances 0.000 description 4
- RQJQQSAYDFANNM-UHFFFAOYSA-N 2,3-dibutylnaphthalene-1-sulfonic acid;formaldehyde Chemical compound O=C.C1=CC=C2C(S(O)(=O)=O)=C(CCCC)C(CCCC)=CC2=C1 RQJQQSAYDFANNM-UHFFFAOYSA-N 0.000 description 3
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 3
- 235000019738 Limestone Nutrition 0.000 description 3
- 239000000020 Nitrocellulose Substances 0.000 description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- TWWCNXGLDZPFQV-XXAVUKJNSA-N [Na].CNCCS(=O)(=O)O.C(CCCCCCC\C=C/CCCCCCCC)(=O)O Chemical compound [Na].CNCCS(=O)(=O)O.C(CCCCCCC\C=C/CCCCCCCC)(=O)O TWWCNXGLDZPFQV-XXAVUKJNSA-N 0.000 description 3
- 235000019270 ammonium chloride Nutrition 0.000 description 3
- 239000006013 carbendazim Substances 0.000 description 3
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000006028 limestone Substances 0.000 description 3
- 229920001220 nitrocellulos Polymers 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- 244000291564 Allium cepa Species 0.000 description 2
- 241001465180 Botrytis Species 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 239000005747 Chlorothalonil Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 240000005373 Panax quinquefolius Species 0.000 description 2
- 235000003140 Panax quinquefolius Nutrition 0.000 description 2
- 206010034133 Pathogen resistance Diseases 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000012271 agricultural production Methods 0.000 description 2
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 2
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 229920005551 calcium lignosulfonate Polymers 0.000 description 2
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 244000038559 crop plants Species 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- AQEFLFZSWDEAIP-UHFFFAOYSA-N di-tert-butyl ether Chemical compound CC(C)(C)OC(C)(C)C AQEFLFZSWDEAIP-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 2
- 229940043264 dodecyl sulfate Drugs 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 125000006353 oxyethylene group Chemical group 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- 239000004323 potassium nitrate Substances 0.000 description 2
- 235000010333 potassium nitrate Nutrition 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- CDMGNVWZXRKJNS-UHFFFAOYSA-N 2-benzylphenol Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1 CDMGNVWZXRKJNS-UHFFFAOYSA-N 0.000 description 1
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 1
- DHTJFQWHCVTNRY-UHFFFAOYSA-N 3-[5-(4-chlorophenyl)-2,3-dimethyl-1,2-oxazolidin-3-yl]pyridine Chemical compound CN1OC(C=2C=CC(Cl)=CC=2)CC1(C)C1=CC=CN=C1 DHTJFQWHCVTNRY-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 235000005254 Allium ampeloprasum Nutrition 0.000 description 1
- 240000006108 Allium ampeloprasum Species 0.000 description 1
- 235000010167 Allium cepa var aggregatum Nutrition 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- 240000007087 Apium graveolens Species 0.000 description 1
- 235000015849 Apium graveolens Dulce Group Nutrition 0.000 description 1
- 235000010591 Appio Nutrition 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 244000056139 Brassica cretica Species 0.000 description 1
- 235000003351 Brassica cretica Nutrition 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000017647 Brassica oleracea var italica Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 240000003259 Brassica oleracea var. botrytis Species 0.000 description 1
- 235000003343 Brassica rupestris Nutrition 0.000 description 1
- 208000031968 Cadaver Diseases 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 241000208293 Capsicum Species 0.000 description 1
- 240000004160 Capsicum annuum Species 0.000 description 1
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 235000009854 Cucurbita moschata Nutrition 0.000 description 1
- 240000001980 Cucurbita pepo Species 0.000 description 1
- 235000009852 Cucurbita pepo Nutrition 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 235000016623 Fragaria vesca Nutrition 0.000 description 1
- 240000009088 Fragaria x ananassa Species 0.000 description 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 1
- 206010017533 Fungal infection Diseases 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- 235000003228 Lactuca sativa Nutrition 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 241000233855 Orchidaceae Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 235000002597 Solanum melongena Nutrition 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 235000010726 Vigna sinensis Nutrition 0.000 description 1
- 244000042314 Vigna unguiculata Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 1
- 239000012874 anionic emulsifier Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 244000046738 asparagus lettuce Species 0.000 description 1
- 235000006705 asparagus lettuce Nutrition 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000007957 coemulsifier Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 235000011950 custard Nutrition 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 210000005069 ears Anatomy 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000010460 mustard Nutrition 0.000 description 1
- 230000001069 nematicidal effect Effects 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229910001487 potassium perchlorate Inorganic materials 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000003516 soil conditioner Substances 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a bactericide composition which comprises gnotobiotic oxazole and at least one kind of imide bactericide. The proportion of the gnotobiotic oxazole to the imide bactericide is from 1: 100 to 100: 1 on the basis of the parts by weight of active components, and the weight percentage of the active components in the composition is 0.5 to 95 wt%. The imide bactericide comprises dimetachlone, procymidone, chlorobenzene gnotobiotic amine, iprodione, vinclozolin, dichlozoline, chlozolinate and myclozolin. The bactericide composition has obvious synergistic effects, and can be used for preventing and treating crop diseases caused by pathogenic bacteria of a botrytis cinerea and sclerotinia.
Description
Technical field
The present invention relates to contain the microbicide compositions of bactericide material, relate in particular to the preparation of compositions and the application that contain SYP-Z048 [chemical name is 5-(4-chlorphenyl)-2,3-dimethyl-3-(pyridin-3-yl) isoxazoline] and carboxylic acid imide fungicides.
Background technology
Since the last century the eighties, the gray mold of crops has and progressively increases the weight of the trend that takes place, especially on melon and fruit and vegetables.The economic loss that this disease causes is generally 20～30%, can reach more than 50% when serious.In the agricultural production, for a long time with benzimidazole germicide such as carbendazim, carboxylic acid imide fungicides such as iprodione, Sukeling etc. are main, prevent and treat such disease singlely, the variation frequency of pathogen self is big in addition, cause pathogen that these medicaments have been produced pesticide resistance in various degree, and its genetics of resistance is very stable.For example, the control efficiency when carbendazim uses the earliest can reach more than 90%, but has only below 30% now, even invalid substantially sometimes.Therefore, invent a kind of microbicide compositions that efficiently, also can delay the generation of pathogen pesticide resistance to a certain extent, become main purpose of the present invention.
SYP-Z048 (tentative Chinese common name is seen No. 018 file of the agricultural marking-up of the national pesticide standard Secretariat of technical committee (2001)) is a kind of new type bactericide with broad spectrum activity of fabulous bacteriostatic activity.Its preparation example is at Chinese patent (publication number: CN 1280767A) narration is arranged, also can find from European patent (EP1035122A).The chemical name of this compound: 5-(4-chlorphenyl)-2,3-dimethyl-3-(pyridin-3-yl) isoxazoline, structure is as follows:
In order to satisfy the needs of agricultural production, further improve the bactericidal effect of SYP-Z048, reduce agricultural cost and improve the safety of crop, inventor of the present invention is devoted to the invention of new microbicide compositions all the time, especially contains the developmental research of the multiple active components microbicide compositions of SYP-Z048.
Summary of the invention
Have now found that the use that is mixed of SYP-Z048 and carboxylic acid imide fungicides has extremely strong synergistic effect, not only can improve the control efficiency to corps diseases, and can also delay drug-fast generation of pathogen and development.The present invention proposes a kind of novel microbicide compositions, in said composition, contain SYP-Z048 and at least a carboxylic acid imide fungicides.
The example of carboxylic acid imide fungicides that is applicable to the present composition is as follows:
Dimethachlon (English common name: N-3,5-dichlorophenylsuccinimide), chemical name and structure are as follows: N-3,5-dichlorophenyl succimide,
Common name: dimethachlon molecular formula: C
10H
7Cl
2NO
2Molecular weight: 244
2. (English common name: procymidone), chemical name and structure are as follows: N-(3, the 5-dichlorophenyl)-1,2-dimethylcyclopropane-1,2-imidodicarbonic diamide for procymidone
Common name: procymidone molecular formula: C
13H
11Cl
2NO
2Molecular weight: 284.1
3. (English common name: iprodione), chemical name and structure are as follows: 1-isopropyl-carbamoyl-3-(3, the 5-dichlorophenyl) glycolylurea for iprodione
Common name: iprodione molecular formula: C
13H
13Cl
2N
3O
3Molecular weight: 330.2
4. (English common name: vinclozolin), chemical name and structure are as follows: 3-(3, the 5-dichlorophenyl)-5-methyl-5-vinyl-1,3 oxazolidine-2,4-diketone for vinclozolin
Common name: vinclozolin molecular formula: C
12H
9Cl
2NO
3Molecular weight: 286.1
5. chlorobenzene is coughed up bacterium amine (English common name: metomeclan), chemical name and structure is as follows: 3-(methoxy) 1-(3, the 5-dichlorophenyl)-pyrrolidines-2,5-diketone
Sclex (English common name: dichlozoline), chemical name and structure are as follows: 3-(3, the 5-dichlorophenyl)-5,5-dimethyl-1,3-oxazoline-2,4-diketone
Chlozolinate (English common name: chlozolinate), chemical name and structure are as follows: (RS)-3-(3, the 5-dichlorophenyl)-5-methyl-2,4-dioxo-oxazolidines-5-carboxylic acid, ethyl ester
Common name: chlozolinate molecular formula: C
13H
10Cl
2NO
5Molecular weight: 332.1 sulphate, alkylphenol polyoxyethylene phosphate, alkylphenol polyoxyethylene, castor oil ethylene oxide adduct, ethylene oxide-propylene oxide block copolymer, alkylphenol polyoxyethylene formaldehyde condensation products, octylphenol polyethylene oxyethylene group ether sulfate and methylcellulose etc.For example sodium lignin sulfonate, calcium lignosulfonate, methyl naphthalene sulfonate formaldehyde condensate, naphthalenesulfonic acid-formaldehyde condensate, methanonaphthalene sodium sulfonate, oleic acid methylamino ethylsulfonic acid sodium, epoxidized polyether, to tertbutyl ether, dibutyl naphthalene sulfonic acid-formaldehyde condensation product and calgon etc.
The wetting agent that is fit to preparation microbicide compositions of the present invention can be sldium lauryl sulfate, lauryl sodium sulfate, neopelex, Negel, sorbitan fatty acid ester polyoxyethylene groups ether etc.
The adhesive that is fit to preparation microbicide compositions of the present invention can be that synthesize or natural, for example xanthans, gelatin, gum Arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, phenolic resins, shellac, carboxymethyl cellulose and sodium alginate etc.Defoamer can be selected from bubble enemy, silicone, C
8～10Fatty alcohol, C
10～20Saturated fat acids (as capric acid) and acid amides etc.
The used oxidant of fumicants preparation in the composition of the present invention can be potassium bichromate, potassium chlorate, sodium chlorate, potassium perchlorate, potassium nitrate, potassium permanganate etc.Smoke agent can be ammonium chloride, carbamate, ammonium hydrogencarbonate etc.Fire retardant can be potter's clay, talcum powder, lime stone, gypsum etc.Cooling agent can be ammonium chloride, bentonite, white carbon black, diatomite etc.Fuel can be wood powder, charcoal, thiocarbamide, ammonium thiocyanate, nitrocellulose, genseng residue etc.
In addition, can also contain colouring agent in the composition of the present invention, for example inorganic pigment iron oxide, titanium oxide or Prussia orchid; Organic dyestuff alizarin, azo dyes, metal phthalocyanine or kiton colors etc.
Composition of the present invention can also have the medicament of weeding, desinsection or bactericidal property with other, particularly mixes use with protective fungicide, also can mix use with nematocide, protective agent, growth regulator, nutrient for plants or soil conditioner.
Composition of the present invention can be used by common method, and amount of application is with weather condition or crop state variation, use optimum period and be crop susceptible before or the susceptible initial stage.Its lasting period is relevant with the content of single agent in the composition, also relevant with extraneous factor usually.
Composition of the present invention can be used for preventing and treating the disease by Botrytis cinerea genus and the microbial crop of Sclerotinia cause of disease.These crops are rape, sunflower, grape, strawberry, cucumber, custard squash, capsicum, pimento, eggplant, tomato, Kidney bean, cowpea, leek, shallot, onion, celery, lettuce, asparagus lettuce, cabbage, broccoli class, mustard and some flower plants for example.
The present invention is the scene of the being included in method of catching and killing fungi also: handle this place with microbicide compositions of the present invention, be subjected to fungal infection or the plant of not infecting, the seed of these plants or the medium of plant growing wherein on-the-spot comprising.
Composition of the present invention has four advantages: the one, and said composition can show fabulous synergistic effect in certain ratio range, and its bactericidal effect is remarkable.The 2nd, said composition can reduce the mu using dosage of medicament in application, thereby both can reduce can significantly reduce agricultural cost again to influence degree.The 3rd, SYP-Z048 is a kind of bactericide of broad spectrum type in the composition, acyl 8. myclozolins (English common name: myclozolin), chemical name and structure are as follows: (RS)-and 3-(3, the 5-dichlorophenyl)-5-methoxy-5-methyl isophthalic acid, 3-oxazolidine-2, the 4-diketone
Common name: myclozolin molecular formula: C
12H
11Cl
2NO
4Molecular weight: 304.1
The relative scale that SYP-Z048 and carboxylic acid imide fungicides are mixed in the present composition is 1: 100 to 100: 1 based on the umber of active component weight, and preferable ratio is 1: 20 to 20: 1.
The content of active component depends on the dosage when bactericide uses separately in the present composition, also depends on the mixed ratio and the synergistic effect degree of a kind of bactericide and another kind of bactericide.Usually the weight percentage of active component is 0.5% to 95% of a gross weight in the composition, and preferable is 1% to 85%.The optimum range of active component content is different according to the preparation type of composition.Usually, the content of active component is 5～85% by weight in the solid pharmaceutical preparation; The content of active component is 1～70% by weight in the liquid preparation; The content of suspension preparation is 10～60% by weight.
Composition of the present invention by the user before use through the dilution or directly the use.Its preparation can after being about to active substance and liquid-carrier or solid carrier mixing, add one or more surfactants such as emulsifier, dispersant, stabilizing agent, wetting agent, adhesive or defoamer etc. by common processing method preparation.According to the difference of composition processing formulation, can also add oxidant, smoke agent, fire retardant, cooling agent, fuel or colouring agent etc. one or more.
The liquid-carrier that is fit to preparation microbicide compositions of the present invention comprises aromatic hydrocarbons, chlorinated aromatic hydrocarbons, chloro aliphatic hydrocarbon, aliphatic hydrocarbon, particularly suitable be polar solvent, as alcohols and their ether and ester.Also have vegetable oil and the molten fiber of methyl in addition.Simultaneously, mixtures of different liquids also is suitable for.
The solid carrier that is fit to preparation microbicide compositions of the present invention is any carrier that is generally used for preparing bactericide.For example diatomite, Magnesiumaluminumsilicate, atlapulgite, kaolin, clay, gypsum, bentonite, white carbon black, precipitated calcium carbonate, lime stone, hexamethylene diamine, cumarone resin, styrene polymer and copolymer, wood chip, corn starch, soluble starch and dry tobacco rods etc.
The emulsifier that is fit to preparation microbicide compositions of the present invention can be anionic and/or nonionic emulsifier, for example alkylphenol-polyethenoxy base ether, alkylphenol-polyethenoxy polyoxypropylene base ether, benzylphenol polyoxyethylene groups ether, polyoxyethylene fatty acid fat, polyoxyethylene aliphatic alcohol ether, polyoxyethylene fatty amine, alkyl phenol polyglycol ether etc.The newborn OP-10 of instantiation such as farming, farming breast 500
#, farming breast 600
#, Nongru-700
#, agricultural newborn OX-635, agricultural newborn OX-690, agricultural newborn OX-2511, farming breast 2201, agricultural newborn CS-7, farming breast 507
#, peaceful breast 36
#, agricultural newborn 0201B, agricultural newborn 0203B, agricultural newborn 0203C, agricultural newborn T-20 etc.
The dispersant that is fit to preparation microbicide compositions of the present invention can have high activity to ash arrhizus bacteria for alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, alkylphenol-polyethenoxy based phosphates, alkylphenol-polyethenoxy base ether formaldehyde condensation products imines series bactericidal agent, so its composition has more preventive and therapeutic effect targetedly to the crop gray mold.The 4th, there is not the problem of cross resistance in the mechanism of action difference of each single agent in the said composition, thereby the application of composition can delay drug-fast generation of pathogen and development, helps to prolong the service time of medicament.
Embodiment
The present invention that is elaborated of following instantiation, but the present invention only limits to these examples absolutely not.Percentage all is weight percentage in the proportioning of all preparations.
Preparation of compositions and biologically active example
1, the preparation of missible oil
By the prescription requirement, add solvent, former medicine, emulsifier respectively, mix, use the hot bath heating for dissolving in case of necessity, promptly obtain transparence missible oil.As example 1～6 prescription.
Example 1 (10% missible oil)
SYP-Z048 0.5%, dimethachlon 9.5%, agricultural newborn OP-10 2.8%, farming breast 2,201 6.5%, methyl alcohol 6%, dimethylbenzene complements to 100%.
Example 2 (15% missible oil)
SYP-Z048 7.5%, dimethachlon 7.5%, agricultural newborn OP-10 3.6%, farming breast 2,201 7.2%, methyl alcohol 6%, dimethylbenzene complements to 100%.
Example 3 (20% missible oil)
SYP-Z048 18%, iprodione 2%, agricultural newborn OX-635 5%, farming breast 2,201 7%, ethylene glycol 3%, dimethyl formamide 8%, dimethylbenzene complements to 100%.
Example 4 (25% missible oil)
SYP-Z048 5%, vinclozolin 20%, farming breast 507
#9%, agricultural newborn OX-690 3%, agricultural newborn OP-10 2%, methyl alcohol 10%, dimethylbenzene complements to 100%.
Example 5 (30% missible oil)
SYP-Z048 20%, procymidone 10%, farming breast 500
#10%, farming breast 600
#5%, Nongru-700
#3.8%, methyl alcohol 10%, dimethylbenzene complements to 100%.
Example 6 (40% missible oil)
SYP-Z048 38%, procymidone 2%, agricultural newborn 0201B 5.6%, agricultural newborn 0203B 5.2%, agricultural newborn OP-10 1.8%, methyl alcohol 10%, dimethylbenzene complements to 100%.
2, the preparation of wetting powder
By the prescription requirement, former medicine, various auxiliary agent and filler etc. are fully mixed, after ultrafine crusher is pulverized, promptly obtain converted products.As example 7～11 prescriptions
Example 7 (10% wetting powder)
SYP-Z048 1%, dimethachlon 9%, sldium lauryl sulfate 1%, white carbon black 5%, condensation compound of methyl naphthalene sulfonic acid and formaldehyde 5%, calcium lignosulfonate 3%, precipitated calcium carbonate complements to 100%.
Example 8 (20% wetting powder)
SYP-Z048 17.5%, vinclozolin 2.5%, lauryl sodium sulfate 1%, naphthalene sulfonic acid-formaldehyde condensation product 6.5%, sodium lignin sulfonate 3.5%, white carbon black 6%, precipitated calcium carbonate complements to 100%.
Example 9 (40% wetting powder)
SYP-Z048 12%, procymidone 28%, lauryl sodium sulfate 1.5%, methanonaphthalene sodium sulfonate 8.5%, sodium lignin sulfonate 4.3%, white carbon black 7%, precipitated calcium carbonate complements to 100%.
Example 10 (50% wetting powder)
SYP-Z048 5%, iprodione 45%, neopelex 2%, white carbon black 8%, oleic acid methylamino ethylsulfonic acid sodium 10%, to tertbutyl ether 3.2%, precipitated calcium carbonate complements to 100%.
Example 11 (60% wetting powder)
SYP-Z048 3%, iprodione 57%, neopelex 2%, white carbon black 10%, dibutyl naphthalene sulfonic acid-formaldehyde condensation product 10.6%, sodium lignin sulfonate 2.8%, precipitated calcium carbonate complements to 100%.
3, the preparation of aqueous emulsion
Former medicine, solvent, emulsifier added with co-emulsifier be in the same place, make it be dissolved into even oil phase.Water, antifreeze etc. is mixed, becomes the homogeneous water.Under high-speed stirred, water is joined oil phase or oil phase is joined water, form the aqueous emulsion of favorable dispersibility.As example 12～14 prescriptions.
Example 12 (10% aqueous emulsion)
SYP-Z048 8%, dimethachlon 2%, polyvinyl alcohol 0.8%, aryl polyoxyethylene poly-oxygen propylene aether 8.5%, hexadecanol 2.4%, agricultural newborn T-20 15%, dimethyl formamide 8%, methyl alcohol 5%, water complements to 100%.
Example 13 (15% aqueous emulsion)
SYP-Z048 3%, procymidone 12%, polyvinylpyrrolidone 0.8%, epoxy ethane-epoxy propane-the oxirane of phosphorylation-block copolymer 8.5%, octadecanol 0.8%, nonyl phenol gathers (30) glycol ether 12%, dimethyl formamide 12%, ethylene glycol 5%, water complements to 100%.
Example 14 (20% aqueous emulsion)
SYP-Z048 10%, iprodione 10%, polyvinyl alcohol 0.8%, aryl polyoxyethylene poly-oxygen propylene aether 12.3%, octadecanol 2.0%, agricultural newborn OX-2511 7.5%, dimethyl formamide 8.5%, methyl alcohol 5.5%, water complements to 100%.
4, the preparation of water-dispersible granules
Former medicine and powder carrier, wetting spreader-sticker and binding agent etc. are mixed pulverizing, after adding water again and mediating, add in the comminutor that the certain specification screen cloth is housed and carry out granulation.And then drying, screening (pressing the screen cloth scope) promptly get granular product.As example 15～17 prescriptions.
Example 15 (40% water-dispersible granules)
SYP-Z048 38%, dimethachlon 2%, methyl naphthalene sulfonate formaldehyde condensate 12%, epoxidized polyether 5%, soluble starch 15%, gypsum complements to 100%.
Example 16 (50% water-dispersible granules)
SYP-Z048 37.5%, vinclozolin 12.5%, naphthalenesulfonic acid-formaldehyde condensate 13.2%, dibutyl naphthalene sulfonic acid-formaldehyde condensation product 6.5%, soluble starch 12%, gypsum complements to 100%.
Example 17 (60% water-dispersible granules)
SYP-Z048 57%, iprodione 3%, methanonaphthalene sodium sulfonate 5%, oleic acid methylamino ethylsulfonic acid sodium 5%, sodium alginate 8%, octylphenol polyethylene oxyethylene group ether sulfate 12%, gypsum complements to 100%.
5, the preparation of suspending agent
By the prescription requirement, be medium with water, former medicine, dispersant, suspending agent and antifreezing agent etc. are added in the sand milling still, carry out porphyrize, make suspending agent.As example 18～21 prescriptions.
Example 18 (10% suspending agent)
SYP-Z048 1.25%, iprodione 8.75%, methyl naphthalene sulfonate formaldehyde condensate 5.5%, xanthans 0.1%, agricultural newborn 0203C 2.6%, ethylene glycol 4%, defoamer a little, water complements to 100%.
Example 19 (15% suspending agent)
SYP-Z048 1.5%, vinclozolin 13.5%, methyl naphthalene sulfonate formaldehyde condensate 5.5%, aluminium-magnesium silicate 0.1%, agricultural newborn 0201B 2.6%, ethylene glycol 4%, defoamer a little, water complements to 100%.
Example 20 (20% suspending agent)
SYP-Z048 1%, procymidone 19%, methyl naphthalene sulfonate formaldehyde condensate 5.5%, xanthans 0.1%, white carbon black 0.1%, ethylene glycol 4%, defoamer a little, water complements to 100%.
Example 21 (35% suspending agent)
SYP-Z048 7%, dimethachlon 28%, sodium lignin sulfonate 8.5%, methanonaphthalene sodium sulfonate 1.5%, atlapulgite 1.0%, glycerine 4%, defoamer a little, water complements to 100%.
6, the preparation of fumicants
Former medicine and various auxiliary agent are crushed to 80～100 orders respectively, mix in proportion, put into plastic sack, again with hot non-conductor external packings such as cardboard cylinder or thick bamboo tube, plain soil jar, crocks, lead-in wire is imbedded in the fumicants, spout is put portion or sidepiece, and seam crossing and venthole secure with paraffin paper, and the venthole paper slip of tearing during use gets final product.As example 22～24 prescriptions.
Example 22 (10% fumicants)
SYP-Z048 7.5%, iprodione 2.5%, potassium bichromate 10%, ammonium chloride 18%, nitrocellulose 10%, carboxymethyl cellulose 5%, potter's clay 8%, talcum powder 20%, wood powder complements to 100%.
Example 23 (15% fumicants)
SYP-Z048 5%, dimethachlon 10%, potassium chlorate 13%, carbonic hydroammonium 16%, nitrocellulose 12%, thiocarbamide 6%, lime stone 6.5%, talcum powder 18%, wood powder complements to 100%.
Example 24 (20% fumicants)
SYP-Z048 16%, procymidone 4%, carbamate 15%, potassium nitrate 20%, gypsum 8%, diatomite 20%, talcum powder 29%, wood powder complements to 100%.
7, the stripped fungistatic effect of composition
Measure the preparation of composition and SYP-Z048, dimethachlon, iprodione, vinclozolin, procymidone fungistatic effect indoor with toxic dielectric method to ash arrhizus bacteria (carbendazim resistance bacterial strain).Culture medium: PDA medium; Pathogen: eliminating vegetable botrytis bacterium; Test method: the PDA medium is adopted in test, with toxic dielectric method, measures the activity of medicament to the eliminating vegetable botrytis bacterium.Handle back 2h inoculation pathogen, cultivate, carry out result's investigation behind the 48h, obtain example 25～28 result of the tests 24 ℃ of unglazed photographs under the condition.
Example 25 (fungistatic effects of example 2 preparations)
| Active substance | Treatment dosage and bacteriostatic activity | ||||
| 1mg/L | 0.5mg/L | 0.25mg/L | 0.125mg/L | 0.0625mg/L | |
| Composition | 100 | 94.56％ | 78.57％ | 59.84％ | 36.17％ |
| SYP-Z048 | 100 | 91.12％ | 68.55％ | 57.51％ | 35.65％ |
| Dimethachlon | 72.47％ | 56.09％ | 26.61％ | 5.57％ | - |
Indicate: treatment dosage is the effective content of medicament, down together.
The fungistatic effect of composition 1mg/L is 100%; The fungistatic effect of composition 0.5mg/L is 94.56%; The fungistatic effect of composition 0.25mg/L is 78.57%; The fungistatic effect of composition 0.125mg/L is 59.84%; The fungistatic effect of composition 0.0625mg/L is 36.17%.
Example 26 (fungistatic effects of example 3 preparations)
| Active substance | Treatment dosage and bacteriostatic activity | ||||
| 1mg/L | 0.5mg/L | 0.25mg/L | 0.125mg/L | 0.0625mg/L | |
| Composition | 100 | 93.44％ | 74.86％ | 63.78％ | 39.62％ |
| SYP-Z048 | 100 | 91.12％ | 68.55％ | 57.51％ | 35.65％ |
| Iprodione | 63.20％ | 48.61％ | 20.98％ | 10.11％ | - |
The fungistatic effect of composition 1mg/L is 100%; The fungistatic effect of composition 0.5mg/L is 93.44%; The fungistatic effect of composition 0.25mg/L is 74.86%; The fungistatic effect of composition 0.125mg/L is 63.78%; The fungistatic effect of composition 0.0625mg/L is 39.62%.
Example 27 (fungistatic effects of example 4 preparations)
| Active substance | Treatment dosage and bacteriostatic activity | ||||
| 1mg/L | 0.5mg/L | 0.25mg/L | 0.125mg/L | 0.0625mg/L | |
| Composition | 100 | 87.09％ | 66.76％ | 53.18％ | 29.42％ |
| SYP-Z048 | 100 | 91.12％ | 68.55％ | 57.51％ | 35.65％ |
| Vinclozolin | 65.32％ | 43.87％ | 31.54％ | 17.65％ | - |
The fungistatic effect of composition 1mg/L is 100%; The fungistatic effect of composition 0.5mg/L is 87.09%; The fungistatic effect of composition 0.25mg/L is 66.76%; The fungistatic effect of composition 0.125mg/L is 53.18%; The fungistatic effect of composition 0.0625mg/L is 29.42%.
Example 28 (fungistatic effects of example 5 preparations)
| Active substance | Treatment dosage and bacteriostatic activity | ||||
| 1mg/L | 0.5mg/L | 0.25mg/L | 0.125mg/L | 0.0625mg/L | |
| Composition | 100 | 91.37％ | 75.92％ | 56.75％ | 33.69％ |
| SYP-Z048 | 100 | 91.12％ | 68.55％ | 57.51％ | 35.65％ |
| Procymidone | 58.11％ | 38.47％ | 22.05％ | 8.18％ | - |
The fungistatic effect of composition 1mg/L is 100%; The fungistatic effect of composition 0.5mg/L is 91.37%; The fungistatic effect of composition 0.25mg/L is 75.92%; The fungistatic effect of composition 0.125mg/L is 56.75%; The fungistatic effect of composition 0.0625mg/L is 33.96%.
8, composition is to the control efficiency of graw mold of tomato
In the greenhouse, adopt potted plant tomato seedling to measure the preparation of composition and SYP-Z048, dimethachlon, iprodione, vinclozolin, procymidone control efficiency to graw mold of tomato.Tomato variety: hair powder 402; Pathogen: botrytis cinerea; Test method: when tomato seedling grows to tri-leaf period, medicament is sprayed in the crop blade face, inoculate pathogen behind the 24h, preserve moisture behind the cultivation 24h, move into the greenhouse normal management, carry out result's investigation behind the 7d, obtain example 29～32 result of the tests with the crop sprayer.
Example 29 disease-controlling effects (protection effect of example 1 preparation)
| Active substance | Treatment dosage and control efficiency | ||||
| 300mg/L | 200mg/L | 100mg/L | 75mg/L | 50mg/L | |
| Composition | 100 | 95.87％ | 84.91％ | 68.96％ | 58.74％ |
| SYP-Z048 | 94.83％ | 88.64％ | 73.15％ | 54.36％ | 38.28％ |
| Dimethachlon | 98.57％ | 90.64％ | 79.37％ | 65.49％ | 51.60％ |
The protection effect of composition 300mg/L is 100%; The protection effect of composition 200mg/L is 95.87%; The protection effect of composition 100mg/L is 84.91%; The protection effect of composition 75mg/L is 68.96%; The protection effect of composition 50mg/L is 58.74%.
Example 30 disease-controlling effects (protection effects of example 6 preparations)
| Active substance | Treatment dosage and control efficiency | |||||
| 500mg/L | 400mg/L | 300mg/L | 200mg/L | 100mg/L | 75mg/L | |
| Composition | - | 100 | 96.52％ | 91.67％ | 79.31％ | 58.57％ |
| SYP-Z048 | - | 100 | 94.83％ | 88.64％ | 73.15％ | 54.36％ |
| Procymidone | 98.73％ | 90.47％ | 83.18％ | 70.31％ | 52.67％ | 34.62％ |
The protection effect of composition 400mg/L is 100; The protection effect of composition 300mg/L is 96.52%; The protection effect of composition 200mg/L is 91.67%; The protection effect of composition 100mg/L is 79.31%; The protection effect of composition 75mg/L is 58.57%.
Example 31 disease-controlling effects (protection effects of example 14 preparations)
| Active substance | Treatment dosage and control efficiency | ||||
| 400mg/L | 300mg/L | 200mg/L | 100mg/L | 75mg/L | |
| Composition | 100 | 98.48％ | 95.37％ | 84.27％ | 65.49％ |
| SYP-Z048 | 100 | 94.83％ | 88.64％ | 73.15％ | 54.36％ |
| Iprodione | 96.47％ | 87.05％ | 74.32％ | 53.86％ | 40.48％ |
The protection effect of composition 400mg/L is 100; The protection effect of composition 300mg/L is 98.48%; The protection effect of composition 200mg/L is 95.37%; The protection effect of composition 100mg/L is 84.27%; The protection effect of composition 75mg/L is 65.49%.
Example 32 disease-controlling effects (protection effects of example 19 preparations)
| Active substance | Treatment dosage and control efficiency | ||||
| 400mg/L | 300mg/L | 200mg/L | 100mg/L | 75mg/L | |
| Composition | 100 | 95.87％ | 92.18％ | 82.64％ | 63.48％ |
| SYP-Z048 | 100 | 94.83％ | 88.64％ | 73.15％ | 54.36％ |
| Vinclozolin | 94.52％ | 83.57％ | 69.84％ | 49.27％ | 38.39％ |
The protection effect of composition 400mg/L is 100; The protection effect of composition 300mg/L is 95.87%; The protection effect of composition 200mg/L is 92.18%; The protection effect of composition 100mg/L is 82.64%; The protection effect of composition 75mg/L is 63.48%.
9, composition is to the control efficiency of Kidney bean gray mold
In the greenhouse, adopt potted plant Kidney bean to measure the preparation of composition and SYP-Z048, dimethachlon, iprodione, procymidone control efficiency to the Kidney bean gray mold.Kidney bean kind: No. 5, distant beans; Pathogen: Kidney bean ash arrhizus bacteria; Test method: when Kidney bean grows to the colored Sheng phase, medicament is sprayed in crop plant, inoculate pathogen behind the 24h, preserve moisture behind the cultivation 24h, move into the greenhouse normal management, carry out result's investigation behind the 20d, obtain example 33～36 result of the tests with the crop sprayer.
Example 33 disease-controlling effects (protection effects of example 11 preparations)
| Active substance | Treatment dosage and control efficiency | ||||
| 400mg/L | 200mg/L | 150mg/L | 100mg/L | 75mg/L | |
| Composition | 98.81％ | 87.47％ | 83.26％ | 75.43％ | 64.58％ |
| SYP-Z048 | 100 | 91.74％ | 83.29％ | 76.96％ | 57.44％ |
| Iprodione | 95.16％ | 74.87％ | 68.43％ | 49.63％ | 40.42％ |
The protection effect of composition 400mg/L is 98.81%; The protection effect of composition 200mg/L is 87.47%; The protection effect of composition 150mg/L is 83.26%; The protection effect of composition 100mg/L is 75.43%; The protection effect of composition 75mg/L is 64.58%.
Example 34 disease-controlling effects (protection effects of example 12 preparations)
| Active substance | Treatment dosage and control efficiency | ||||
| 200mg/L | 150mg/L | 100mg/L | 75mg/L | 50mg/L | |
| Composition | 100 | 95.35％ | 89.47％ | 75.52％ | 61.65％ |
| SYP-Z048 | 91.74％ | 83.29％ | 76.96％ | 57.44％ | 41.25％ |
| Dimethachlon | 97.52％ | 89.31％ | 81.58％ | 64.83％ | 53.64％ |
The protection effect of composition 200mg/L is 100%; The protection effect of composition 150mg/L is 95.35%; The protection effect of composition 100mg/L is 89.47%; The protection effect of composition 75mg/L is 75.52%; The protection effect of composition 50mg/L is 61.65%.
Example 35 disease-controlling effects (protection effects of example 13 preparations)
| Active substance | Treatment dosage and control efficiency | ||||
| 400mg/L | 200mg/L | 150mg/L | 100mg/L | 75mg/L | |
| Composition | 100 | 93.38％ | 81.56％ | 79.27％ | 57.24％ |
| SYP-Z048 | 100 | 91.74％ | 83.29％ | 76.96％ | 57.44％ |
| Procymidone | 92.17％ | 79.46％ | 65.83％ | 57.63％ | 38.59％ |
The protection effect of composition 400mg/L is 100; The protection effect of composition 200mg/L is 93.38%; The protection effect of composition 150mg/L is 81.56%; The protection effect of composition 100mg/L is 79.27%; The protection effect of composition 75mg/L is 57.24%.
Example 36 disease-controlling effects (protection effects of example 15 preparations)
| Active substance | Treatment dosage and control efficiency | ||||
| 200mg/L | 150mg/L | 100mg/L | 75mg/L | 50mg/L | |
| Composition | 100 | 91.47％ | 86.82％ | 71.36％ | 57.38％ |
| SYP-Z048 | 91.74％ | 83.29％ | 76.96％ | 57.44％ | 41.25％ |
| Dimethachlon | 97.52％ | 89.31％ | 81.58％ | 64.83％ | 53.64％ |
The protection effect of composition 200mg/L is 100%; The protection effect of composition 150mg/L is 91.47%; The protection effect of composition 100mg/L is 86.82%; The protection effect of composition 75mg/L is 71.36%; The protection effect of composition 50mg/L is 57.38%.
10, composition is to the control efficiency of capsicum gray mold
In the greenhouse, adopt potted plant capsicum to measure the preparation of composition and SYP-Z048, dimethachlon, iprodione, vinclozolin, procymidone control efficiency to the capsicum gray mold.Capsicum variety: the ears of an ox or cow king; Pathogen: capsicum ash arrhizus bacteria; Test method: when capsicum grows to the colored Sheng phase, medicament is sprayed in crop plant, inoculate pathogen behind the 24h, preserve moisture behind the cultivation 24h, move into the greenhouse normal management, carry out result's investigation behind the 21d, obtain example 37～40 result of the tests with the crop sprayer.
Example 37 disease-controlling effects (protection effects of example 8 preparations)
| Active substance | Treatment dosage and control efficiency | ||||
| 400mg/L | 200mg/L | 150mg/L | 100mg/L | 75mg/L | |
| Composition | 100 | 100 | 93.60％ | 84.52％ | 67.49％ |
| SYP-Z048 | 100 | 94.43％ | 81.54％ | 76.16％ | 58.34％ |
| Vinclozolin | 95.62％ | 75.40％ | 62.57％ | 55.76％ | 44.60％ |
The protection effect of composition 200mg/L is 100%; The protection effect of composition 150mg/L is 93.60%; The protection effect of composition 100mg/L is 84.52%; The protection effect of composition 75mg/L is 67.49%.
Example 38 disease-controlling effects (protection effects of example 17 preparations)
| Active substance | Treatment dosage and control efficiency | ||||
| 400mg/L | 200mg/L | 150mg/L | 100mg/L | 75mg/L | |
| Composition | 100 | 100 | 91.74％ | 78.29％ | 61.63％ |
| SYP-Z048 | 100 | 94.43％ | 81.54％ | 76.16％ | 58.34％ |
| Iprodione | 97.37％ | 78.05％ | 70.63％ | 54.26％ | 49.12％ |
The protection effect of composition 200mg/L is 100%; The protection effect of composition 150mg/L is 91.74%; The protection effect of composition 100mg/L is 78.29%; The protection effect of composition 75mg/L is 61.63%.
Example 39 disease-controlling effects (protection effects of example 20 preparations)
| Active substance | Treatment dosage and control efficiency | ||||
| 400mg/L | 200mg/L | 150mg/L | 100mg/L | 75mg/L | |
| Composition | 100 | 91.38％ | 83.47％ | 73.45％ | 55.06％ |
| SYP-Z048 | 100 | 94.43％ | 81.54％ | 76.16％ | 58.34％ |
| Procymidone | 95.30％ | 83.15％ | 72.53％ | 64.28％ | 45.04％ |
The protection effect of composition 400mg/L is 100%; The protection effect of composition 200mg/L is 91.38%; The protection effect of composition 150mg/L is 83.47%; The protection effect of composition 100mg/L is 73.45%; The protection effect of composition 75mg/L is 55.06%.
Example 40 disease-controlling effects (protection effects of example 21 preparations)
| Active substance | Treatment dosage and control efficiency | ||||
| 200mg/L | 150mg/L | 100mg/L | 75mg/L | 50mg/L | |
| Composition | 100 | 98.56％ | 88.38％ | 71.20％ | 58.57％ |
| SYP-Z048 | 94.43％ | 81.54％ | 76.16％ | 58.34％ | 41.25％ |
| Dimethachlon | 100 | 91.54％ | 83.27％ | 68.41％ | 56.38％ |
The protection effect of composition 200mg/L is 100%; The protection effect of composition 150mg/L is 98.56%; The protection effect of composition 100mg/L is 88.38%; The protection effect of composition 75mg/L is 71.20%; The protection effect of composition 50mg/L is 58.57%.
11, composition in the field to the control efficiency of graw mold of tomato
The preparation of mensuration composition and chlorothalonil smoke are to the control efficiency of graw mold of tomato in protection ground.Tomato variety: hair powder 402; Pathogen: botrytis cinerea; Method: in the tomato protection ground that gray mold is fallen ill heavier year after year; handle in tomato early flowering season with medicament; be respectively 20g, 40g, three treatment dosage of 60g every mu time; contrast medicament chlorothalonil smoke is 40g; the 7d continuous use is three times at interval; carry out result's investigation behind the 30d, obtain example 41～43 result of the tests.
Example 41 disease-controlling effects (protection effects of example 22 preparations)
| Active substance | Treatment dosage (a.i.) and control efficiency | ||
| 60g/ mu | 40g/ mu | 20g/ mu | |
| Composition | 86.52％ | 72.36％ | 52.09％ |
| Tpn | - | 65.31％ | - |
The control efficiency of composition 60g/ mu is 86.52%; The control efficiency of composition 40g/ mu is 72.36%; The control efficiency of composition 20g/ mu is 52.09%.
Example 42 disease-controlling effects (protection effects of example 23 preparations)
| Active substance | Treatment dosage (a.i.) and control efficiency | ||
| 60/g mu | 40g/ mu | 20g/ mu | |
| Composition | 89.34％ | 75.21％ | 56.17％ |
| Tpn | - | 63.28％ | - |
The control efficiency of composition 60g/ mu is 89.34%; The control efficiency of composition 40g/ mu is 75.21%; The control efficiency of composition 20g/ mu is 56.17%.
Example 43 disease-controlling effects (protection effects of example 24 preparations)
| Active substance | Treatment dosage (a.i.) and control efficiency | ||
| 60/g mu | 40g/ mu | 20g/ mu | |
| Composition | 91.67％ | 78.86％ | 60.14％ |
| Tpn | - | 65.74％ | - |
The control efficiency of composition 60g/ mu is 91.67%; The control efficiency of composition 40g/ mu is 78.86%; The control efficiency of composition 20g/ mu is 60.14%.
Claims (2)
1, a kind of microbicide compositions, contain two kinds of active components of A, B, it is characterized in that: active component A is selected from SYP-Z048 [5-(4-chlorphenyl)-2,3-dimethyl-3-(pyridin-3-yl) isoxazoline], active component B be selected from dimethachlon (N-3,5-dichlorophenylsuccinimide), procymidone (procymidone), iprodione (iprodione), vinclozolin (vinclozolin) or sclex (dichlozoline); The ratio of A, B two components is 1: 20 to 20: 1 based on the parts by weight of active component; The active component weight percentage is 10-60% in the composition.
2, the described microbicide compositions of claim 1 is used to prevent and treat the purposes of crop gray mold.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02109547 CN1223270C (en) | 2002-04-26 | 2002-04-26 | Bactericide composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02109547 CN1223270C (en) | 2002-04-26 | 2002-04-26 | Bactericide composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1452865A CN1452865A (en) | 2003-11-05 |
| CN1223270C true CN1223270C (en) | 2005-10-19 |
Family
ID=29256718
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02109547 Expired - Lifetime CN1223270C (en) | 2002-04-26 | 2002-04-26 | Bactericide composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1223270C (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100382693C (en) * | 2005-08-26 | 2008-04-23 | 沈阳化工研究院 | SYP-Z048 bactericidal water agent |
| CN100382691C (en) * | 2005-09-15 | 2008-04-23 | 南京第一农药有限公司 | Efficient germicide composition containing prochloraz or its manganese salt and dimetachlone and its application |
| CN101485316B (en) * | 2009-03-04 | 2012-04-18 | 中国农业大学 | A compound fungicide for preventing and treating Botrytis cinerea |
| CN101779638B (en) * | 2009-12-31 | 2012-06-27 | 江苏省绿盾植保农药实验有限公司 | Disinfectant containing pyrimethanil and vinclozolin |
| CN101999360A (en) * | 2010-10-13 | 2011-04-06 | 山东农业大学 | Thermal aerosol for prevention and treatment of grey mould of vegetable in plastic shed and other facilities |
| CN102524284A (en) * | 2012-02-06 | 2012-07-04 | 山东禾宜生物科技有限公司 | Bactericide for preventing tomato grey moulds |
| CN103704220B (en) * | 2012-09-28 | 2015-01-14 | 深圳诺普信农化股份有限公司 | Compound antibacterial composition containing penthiopyrad |
| CN104186495B (en) * | 2014-08-20 | 2016-05-04 | 青岛农业大学 | A kind of SYP-Zo48-Osthole suspended emulsion and preparation method thereof |
| CN106889078A (en) * | 2015-12-18 | 2017-06-27 | 沈阳中化农药化工研发有限公司 | A kind of Fungicidal composition of double activated component and its application |
| US20170333305A1 (en) * | 2016-05-23 | 2017-11-23 | Microban Products Company | Topical skin product having retention property |
| CN112316976B (en) * | 2020-11-02 | 2022-09-13 | 江苏快达农化股份有限公司 | Quaternary ammonium salt modified mesoporous molecular sieve and its preparation method and use |
-
2002
- 2002-04-26 CN CN 02109547 patent/CN1223270C/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1452865A (en) | 2003-11-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1223270C (en) | Bactericide composition | |
| CN101080173A (en) | Herbicidal compositions | |
| CN1209017C (en) | Plant growth regulator composition with cold-resisting action | |
| CN1072817A (en) | Mixed agrochemical combination | |
| CN1066610C (en) | A plant-microbicidal composition having synergistic action, comprising at least two active ingredient components, eherein...... | |
| CN1596644A (en) | Bacteridal composition containing alkene oxime amine and triazole kind compound | |
| CN1175744C (en) | Azadirachtin and Antibiotic Insecticide Mixed Pesticide Preparation | |
| CN1418549A (en) | Composition for treating paddy rice seed | |
| CN1218637C (en) | Insecticide-disinfectant composition containing zarilamid | |
| CN101433199A (en) | Bactericidal composition | |
| CN1968604A (en) | Herbicidal composition | |
| CN1223273C (en) | Bactericide composition | |
| CN1150819C (en) | Plant growth regualting composition with drought resistance function | |
| CN101543221B (en) | Mancozeb and tea saponin compounded sterilizing composition and application thereof | |
| CN1225168C (en) | Process and composition for antiparasitic treatment of surroundings of animals | |
| CN1216531C (en) | Weedicide composite | |
| CN1043402C (en) | Herbicide tablets or capsules for paddy field application by throwing them into water | |
| CN100342787C (en) | Combination of insect disinfectations containing benzoate of Avermectin in methylamine group and azadirachtin | |
| CN1565182A (en) | Bactericidal compositions of flumorph and enostroburin and synergist | |
| CN1711840A (en) | Weeding composition, its application and method | |
| CN1297196C (en) | Insecticide composition containing methylamino Avermectin and matrine | |
| CN105638715B (en) | A kind of agricultural pesticide composition and application thereof | |
| CN1593143A (en) | Fenoxanil containing bactericide and insecticide compositions | |
| CN1312997C (en) | Flumorph and famoxadone sterilization compositions | |
| CN1918989A (en) | Bactericide composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: SINOCHEM CORPORATION; SHENYANG CHEMICAL ENGINEERI Free format text: FORMER OWNER: SHENYANG CHEMICAL ENGINEERING INST. Effective date: 20080711 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20080711 Address after: F6-F12, middle seat of Kai Chen World Trade Centre, 28 Fuxing Man Street, Xicheng District, Beijing, zip code: 100031 Co-patentee after: Shenyang Research Institute of Chemical Industry Patentee after: Sinochem Corp. Address before: No 8, Shen Liaodong Road, Tiexi District, Liaoning, Shenyang: 110021 Patentee before: Shenyang Research Institute of Chemical Industry |
|
| ASS | Succession or assignment of patent right |
Owner name: CHINA CHEMISTRY CO., LTD. Free format text: FORMER OWNER: SINOCHEM CORPORATION Effective date: 20091002 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| C56 | Change in the name or address of the patentee | ||
| CP03 | Change of name, title or address |
Address after: F6-F12, middle seat of Kai Chen World Trade Centre, 28 Fuxing Man Street, Xicheng District, Beijing, zip code: 100031 Co-patentee after: SHENYANG RESEARCH INSTITUTE OF CHEMICAL INDUSTRY Co.,Ltd. Patentee after: Sinochem Corp. Address before: F6-F12, middle seat of Kai Chen World Trade Centre, 28 Fuxing Man Street, Xicheng District, Beijing, zip code: 100031 Co-patentee before: Shenyang Research Institute of Chemical Industry Patentee before: Sinochem Corp. |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20091002 Address after: 28, Fuxing Man Street, Xicheng District, Beijing, zip code: 100031 Co-patentee after: SHENYANG RESEARCH INSTITUTE OF CHEMICAL INDUSTRY Co.,Ltd. Patentee after: SINOCHEM Corp. Address before: F6-F12, middle seat of Kai Chen World Trade Centre, 28 Fuxing Man Street, Xicheng District, Beijing, zip code: 100031 Co-patentee before: SHENYANG RESEARCH INSTITUTE OF CHEMICAL INDUSTRY Co.,Ltd. Patentee before: Sinochem Corp. |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160122 Address after: 110021 Liaodong Road, Tiexi District, Liaoning, No. 8-1, No. Patentee after: SHENYANG SINOCHEM AGROCHEMICALS R&D Co.,Ltd. Address before: 100031 Beijing, Xicheng District, the door of the revitalization of the main street, No. 28 Patentee before: SINOCHEM Corp. Patentee before: SHENYANG RESEARCH INSTITUTE OF CHEMICAL INDUSTRY Co.,Ltd. |
|
| CX01 | Expiry of patent term |
Granted publication date: 20051019 |
|
| CX01 | Expiry of patent term |