[go: up one dir, main page]

CN119120119A - A dust-accumulating acid cleaning agent and its application - Google Patents

A dust-accumulating acid cleaning agent and its application Download PDF

Info

Publication number
CN119120119A
CN119120119A CN202411072924.2A CN202411072924A CN119120119A CN 119120119 A CN119120119 A CN 119120119A CN 202411072924 A CN202411072924 A CN 202411072924A CN 119120119 A CN119120119 A CN 119120119A
Authority
CN
China
Prior art keywords
cleaning agent
dust
acid cleaning
cleaning
photovoltaic panel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202411072924.2A
Other languages
Chinese (zh)
Inventor
邓绪铭
张磊
邹鹏
文慧峰
位承君
张恒
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xian Thermal Power Research Institute Co Ltd
Huaneng Hunan Yueyang Power Generation Co Ltd
Original Assignee
Xian Thermal Power Research Institute Co Ltd
Huaneng Hunan Yueyang Power Generation Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xian Thermal Power Research Institute Co Ltd, Huaneng Hunan Yueyang Power Generation Co Ltd filed Critical Xian Thermal Power Research Institute Co Ltd
Priority to CN202411072924.2A priority Critical patent/CN119120119A/en
Publication of CN119120119A publication Critical patent/CN119120119A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/34Derivatives of acids of phosphorus
    • C11D1/345Phosphates or phosphites
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/37Mixtures of compounds all of which are anionic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0047Other compounding ingredients characterised by their effect pH regulated compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/042Acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/06Phosphates, including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2072Aldehydes-ketones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses an acidic cleaning agent for dust accumulation and application thereof, and belongs to the technical field of cleaning agents. The dust accumulation acidic cleaning agent comprises, by mass, 1.0% -6.0% of sulfamic acid, 0.5% -4.0% of an alkaline pH regulator, 1.0% -4.0% of an anionic surfactant, 0.3% -0.5% of a foaming agent and the balance of desalted water. The dust accumulation acidic cleaning agent also comprises 1.0% -4.0% of acetone, 0.5% -1.0% of sodium chloride and 0.05% -0.1% of IS-129 hydrochloride retarder. The dust accumulation acidic cleaning agent also comprises 0.5% -4.0% of ammonium citrate and 1.0% -2.0% of laurinol polyoxyethylene ether. The cleaning agent is used for solving the problem that dust deposited on the photovoltaic panel in the factory is difficult to clean.

Description

Acid cleaning agent for dust accumulation and application
Technical Field
The invention belongs to the technical field of cleaning agents, and particularly relates to a dust accumulation acidic cleaning agent and application thereof.
Background
The power generation efficiency of the photovoltaic panel is significantly affected by the ash deposition phenomenon, which is a problem that cannot be ignored. To address this challenge, photovoltaic power plants commonly employ cleaning robots or manual methods for periodic ash removal. In non-factory areas, the photovoltaic panel ash deposition caused by natural sedimentation is usually loose, and can be easily removed by simple blowing or water washing.
However, the dust retention challenges faced by photovoltaic panels on or near the roof of a factory are particularly unique and complex. This is mainly due to the specific environmental contaminants generated by industrial production activities, which are more adherent and aggressive to the photovoltaic panels. Specifically, these contaminants include soot, metals and metal oxides, polycyclic aromatic hydrocarbons, oils and fats, and fibers, among others, are of a wide variety and complexity. They not only gradually absorb dust in the air to form a crystalline shell, but also tend to have strong adhesion, high hardness, and tightly adhere to the surface of the photovoltaic panel, and are difficult to remove by conventional physical ash removal means.
Even more troublesome is that for some long-term unwashed factory floor photovoltaic panels, the contaminants may be further solidified after the microorganisms carried on the dust are rain washed. During the growth of microorganisms they secrete mildew spots containing enzymes and organic acids which, when combined with contaminants, form stubborn dust which is difficult to remove by purging or water flushing. The dense and uneven dust accumulation not only can reduce the power generation efficiency of the photovoltaic panel, but also can generate a hot spot effect, damage the photovoltaic panel and even cause potential safety hazards such as fire disaster.
In addition, the heavy and light plant areas are different in production type, and pollution sources are different. This results in different types of plant area photovoltaic panel dust deposition components and characteristics, further increasing the difficulty and complexity of the ash removal. Therefore, it is important to develop a high-efficiency cleaning agent for the dust accumulation of the photovoltaic panels in different types of factories.
Although the types of toughened glass cleaning agents on the market are numerous, few products which can be effectively applied to the intractable dust collection cleaning of the photovoltaic panels in factories are available. Moreover, most cleaning agents are neutral or alkaline, which can corrode the glass and cause damage to the photovoltaic panel. Therefore, the development of the high-efficiency acidic chemical cleaning agent specially designed for the roof photovoltaic panel in the factory area has important significance. The cleaning agent needs to be capable of removing stubborn dust in a targeted manner, and meanwhile, protecting the photovoltaic panel from damage so as to ensure efficient operation of the photovoltaic system and improve the power generation efficiency. This not only helps to promote the economic benefits of the photovoltaic power plant, but also helps to promote the sustainable development of renewable energy sources.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention aims to provide a dust accumulation acidic cleaning agent and application thereof, which are used for solving the problem that dust accumulation of a photovoltaic panel in a factory is difficult to remove.
In order to achieve the above purpose, the invention is realized by adopting the following technical scheme:
The invention provides a dust-accumulation acidic cleaning agent, which comprises the following components in percentage by mass:
1.0% -6.0% of sulfamic acid, 0.5% -4.0% of alkaline pH regulator, 1.0% -4.0% of anionic surfactant, 0.3% -0.5% of foaming agent and the balance of desalted water.
In a specific embodiment, the dust accumulation acidic cleaning agent further comprises 1.0% -4.0% of acetone, 0.5% -1.0% of sodium chloride and 0.05% -0.1% of IS-129 hydrochloride corrosion inhibitor according to mass percentage.
In a specific embodiment, the dust accumulation acidic cleaning agent further comprises 0.5-4.0% of ammonium citrate and 1.0-2.0% of laureth by mass percent.
In specific embodiments, the alkaline pH regulator is one of disodium hydrogen phosphate or sodium citrate, the anionic surfactant is one or more of lauryl phosphate, dodecylbenzene sulfonic acid and alcohol ether phosphate surfactants, and the foaming agent is dinitroso pentamethylene tetramine foaming agent.
In a specific embodiment, the pH value of the dust accumulation acidic cleaning agent is 2.5-4.0.
The invention also provides application of the dust accumulation acidic cleaning agent in cleaning photovoltaic panels in factories.
In particular embodiments, the plant area is a heavy plant area, and the dust retention component of the heavy plant area photovoltaic panel comprises residual organics including metal oxides, carbonates, silicates, incomplete combustion of coal fines, polycyclic aromatic hydrocarbons, and fly ash.
In a specific embodiment, the factory area is a light factory area, the dust accumulation component of the photovoltaic panel of the light factory area is mainly light impurities, and the light impurities comprise inorganic dust, fiber filaments and wood chips.
In a specific embodiment, the cleaning process of the dust accumulation acidic cleaning agent for cleaning the photovoltaic panel in the factory area is as follows:
And cleaning the photovoltaic panel by using the dust-accumulation acidic cleaning agent, and then flushing the photovoltaic panel by using water, wherein the dosage of the dust-accumulation acidic cleaning agent for cleaning the photovoltaic panel with one square meter is 500-2000 mL.
In the specific embodiment, the residence time of the dust-accumulation acidic cleaning agent on the surface of the photovoltaic panel is 10-60 s, the washing times are 1-2 times, and the dosage ratio of the water to the dust-accumulation acidic cleaning agent is (1-2): 1.
Compared with the prior art, the invention has the following beneficial effects:
The invention provides a dust accumulation acidic cleaning agent, which comprises sulfamic acid, an alkaline pH regulator, an anionic surfactant and a foaming agent, wherein sulfamic acid can react with metal and metal oxide, has extremely strong calcium scale removal capability, can increase the cleaning capability of the metal oxide, and has extremely good removal effect on specific metal dust, carbonate and silicate particles in a factory area. The aqueous solution of the alkaline pH regulator is alkaline, so that the pH value of the cleaning agent can be effectively regulated, and the alkaline pH regulator is stabilized in the optimal pH use range of several anionic surfactants in the components, thereby improving the stability and the acid cleaning effect of each component. The anionic surfactant has excellent emulsifying, solubilizing, decontaminating, dispersing, cleaning, wetting, antistatic and antirust properties, is suitable for compatibility with other components of the acidic cleaning agent, and can meet the cleaning requirements of most factory scenes. The foaming agent has good stability, can play a role in foaming in the cleaning agent, and is beneficial to improving the cleaning effect. In conclusion, the components of the dust accumulation acidic cleaning agent cooperate to jointly improve the cleaning effect, stability and applicability of the cleaning agent. In addition, the acidic cleaner can treat inorganic dirt which is difficult to remove by the alkaline cleaner.
Furthermore, the dust acidic cleaning agent also comprises acetone, sodium chloride and IS-129 hydrochloric acid corrosion inhibitor, and IS suitable for cleaning dust of photovoltaic panels in heavy factories. The dust accumulation components of the photovoltaic panel in the heavy factory area are complex, and the dust accumulation components comprise metal oxides, carbonates, silicate, residual organic matters of incomplete combustion of coal dust, polycyclic aromatic hydrocarbon, fly ash and the like. Wherein, polycyclic aromatic hydrocarbon in the dust as an organic matter has hydrophobicity, and the hydrophobicity is gradually enhanced along with the increase of the ring number of the benzene ring. The cleaning agent composed of sulfamic acid, alkaline pH regulator, anionic surfactant and foaming agent can be used for removing the dust, but when acetone and sodium chloride are added on the basis of the cleaning agent, naCl reacts with sulfamic acid to generate hydrochloric acid, so that the reactivity of the cleaning agent to metal and oxide dust IS enhanced, the acetone IS used as an organic solvent, has fat solubility and water solubility, can effectively dissolve and remove various organic matters and adhesive matters on the surface of the photovoltaic panel, and the IS-129 hydrochloric acid corrosion inhibitor plays a role in avoiding the corrosion of the frame of the photovoltaic panel, so that the cleaning effect can be further improved.
Furthermore, the dust-accumulation acidic cleaning agent also comprises ammonium citrate and laurinol polyoxyethylene ether, and is suitable for dust-accumulation cleaning of photovoltaic panels in light factories. Because the organic matters in the dust accumulation of the photovoltaic panel in the light factory area are less, various fiber filaments, saw dust and the like are easy to fly and are adsorbed by the dust, so the ammonium citrate and the laurinol polyoxyethylene ether are added into the cleaning agent. The ammonium citrate has the effects of both the detergent and the permeation promoter, can reduce the diffusion resistance of the cleaning agent between fibers and reduce the adsorption of the cleaning agent on grease, and simultaneously, the laurinol polyoxyethylene ether is used as an antistatic agent, so that the electrostatic effect of the fibers can be further reduced. When the cleaning agent composed of sulfamic acid, alkaline pH regulator, anionic surfactant and foaming agent and the added ammonium citrate and laurinol polyoxyethylene ether are used simultaneously, the cleaning effect on dust deposit adhered to various fibers can be remarkably improved.
Detailed Description
So that those skilled in the art can appreciate the features and effects of the present invention, a general description and definition of the terms and expressions set forth in the specification and claims follows. Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs, and in the event of a conflict, the present specification shall control.
The theory or mechanism described and disclosed herein, whether right or wrong, is not meant to limit the scope of the invention in any way, i.e., the present disclosure may be practiced without limitation to any particular theory or mechanism.
All features such as values, amounts, and concentrations that are defined herein in the numerical or percent ranges are for brevity and convenience only. Accordingly, the description of a numerical range or percentage range should be considered to cover and specifically disclose all possible sub-ranges and individual values (including integers and fractions) within the range.
Herein, unless otherwise indicated, "comprising," "including," "having," or similar terms encompass the meanings of "consisting of," and "consisting essentially of," such as "a includes a" encompassing "a and other" and "a includes only a".
In this context, not all possible combinations of the individual technical features in the individual embodiments or examples are described in order to simplify the description. Accordingly, as long as there is no contradiction between the combinations of these technical features, any combination of the technical features in the respective embodiments or examples is possible, and all possible combinations should be considered as being within the scope of the present specification.
The invention provides a dust accumulation acidic cleaning agent and application thereof.
In one aspect, a dust-accumulation acidic cleaning agent is provided, which comprises the following components in percentage by mass:
1.0% -6.0% of sulfamic acid, 0.5% -4.0% of alkaline pH regulator, 1.0% -4.0% of anionic surfactant, 0.3% -0.5% of foaming agent and the balance of desalted water. The formulation component is hereinafter referred to simply as component A. The pH value of the dust accumulation acidic cleaning agent is 2.5-4.0, the sulfamic acid cleaning effect is optimal in the pH range of 2.5-4.0, and the stability of the rest components can be maintained.
On the one hand, acetone, sodium chloride and IS-129 hydrochloric acid corrosion inhibitor are added on the basis of the dust-accumulation acidic cleaning agent, and the dust-accumulation acidic cleaning agent specifically comprises 1.0% -6.0% of sulfamic acid, 0.5% -4.0% of alkaline pH regulator, 1.0% -4.0% of anionic surfactant, 0.3% -0.5% of foaming agent, 1.0% -4.0% of acetone, 0.5% -1.0% of sodium chloride, 0.05% -0.1% of IS-129 hydrochloric acid corrosion inhibitor and the balance of desalted water. Wherein, 1.0 to 4.0 percent of acetone, 0.5 to 1.0 percent of sodium chloride and 0.05 to 0.1 percent of IS-129 hydrochloride corrosion inhibitor are simply called as a component B in the following formula.
On the one hand, ammonium citrate and laureth are added on the basis of the dust accumulation acidic cleaning agent, and the dust accumulation acidic cleaning agent specifically comprises 1.0% -6.0% of sulfamic acid, 0.5% -4.0% of alkaline pH regulator, 1.0% -4.0% of anionic surfactant, 0.3% -0.5% of foaming agent, 0.5% -4.0% of ammonium citrate, 1.0% -2.0% of laureth and the balance of desalted water. Wherein, in the following formula, 0.5 to 4.0 percent of ammonium citrate and 1.0 to 2.0 percent of polyoxyethylene lauryl ether are abbreviated as component C.
In one embodiment, the alkaline pH regulator is one of disodium hydrogen phosphate or sodium citrate, and the anionic surfactant can be one or more of monolauryl phosphate, dodecylbenzene sulfonic acid and alcohol ether phosphate surfactants. In addition, the foaming agent is preferably dinitroso pentamethylene tetramine foaming agent.
The preparation method of the dust accumulation acidic cleaning agent comprises the steps of gradually adding each component into desalted water with calculated dosage, and finally adding an alkaline pH regulator to ensure that the pH value of the solution is 2.5-4.0, the sulfamic acid cleaning effect is optimal in the pH value range of 2.5-4.0, and the other components can keep the stability.
Preferably, when the dust-accumulation acidic cleaning agent is used, a small preheating device is suggested to be arranged in front of a water outlet of the equipment, the dust-accumulation acidic cleaning agent is heated to be not more than 50 ℃ for use, and the cleaning effect is better.
The invention further provides application of the dust accumulation acidic cleaning agent in cleaning of photovoltaic panels in factories.
Furthermore, for heavy factory areas such as coal-fired power plants, coking plants, steel plants, chemical plants, printing and dyeing plants and the like, the cleaning agent should be an acidic cleaning agent for accumulated dust formed by the component A and the component B. The dust-collecting component of the photovoltaic panel in the factory comprises fly ash, residual organic matters generated by incomplete combustion of the fly ash and the like, and besides metal oxides, the components of the dust-collecting component include carbonate, silicate, polycyclic aromatic hydrocarbon and the like, wherein the component B is required to be added to remove adsorbed organic matters and generate a small amount of hydrochloric acid to consume the generated carbonate.
In the dust accumulation acidic cleaning agent composed of the component A and the component B, 1) polycyclic aromatic hydrocarbon is taken as an organic matter, has certain hydrophobicity, and the hydrophobicity is gradually enhanced along with the increase of the ring number of benzene rings, so that certain difficulty is brought to cleaning the dust accumulation by only adopting the component A, and hydrochloric acid is generated by the simultaneous use of NaCl and sulfamic acid when the component A+the component B is adopted, so that the reactivity of the dust accumulation on metals and oxides thereof is increased. 2) Acetone is used as a fat-soluble and water-soluble organic solvent, and can dissolve various organic matters and adhesives adsorbed on the surface of the photovoltaic panel to desorb the organic matters and adhesives, and then quickly volatilize to enable the organic matters and adhesives to be adsorbed again by dust and finally removed.
Furthermore, for light industrial areas such as textile factories, building material factories, food factories and the like, the cleaning agent should use the dust-accumulation acidic cleaning agent composed of the component A and the component C. The dust accumulation component of the photovoltaic panel in the factory has fewer organic matters, and various fiber filaments, saw dust and the like are easy to fly away and are adsorbed by dust after rain and adhered to the photovoltaic panel. It is desirable to add component C, which contains a penetration aid and an antistatic agent, to facilitate removal of various types of fibers that are prone to static electricity generation.
In the dust accumulation acidic cleaning agent composed of the component A and the component C, 1) various fibers are easy to generate static electricity due to the effects of factors such as electric field induction and hot air drying, and ammonium citrate has the effects of a detergent and a permeation assisting agent, so that the diffusion resistance of the cleaning agent components among the fibers is reduced, the adsorption of the cleaning agent components on grease is reduced, and 2) laurinol polyoxyethylene ether (peregal O) is used as a nonionic surfactant, is acid and alkali resistant, so that the static effect of the fibers can be further lightened, and the cleaning effect of dust accumulation adhered to various fibers is improved when the component A+the component C is adopted.
For other types of less polluting plant areas, the cleaning agent is only a dust-accumulation acidic cleaning agent composed of the component A.
In the dust accumulation acidic cleaning agent formed by the component A, 1) sulfamic acid can react with metal and metal oxide, has extremely strong calcium scale removal capability, can increase the cleaning capability of the metal oxide, has extremely good removal effect on metal dust, carbonate and silicate particles which are special in a factory area, 2) an alkaline pH regulator (disodium hydrogen phosphate and sodium citrate aqueous solution) is alkaline, has the effect of regulating pH, can stabilize the pH value of the cleaning agent to be 2.5-4.0, and the optimal pH ranges of several anionic surfactants in the component are all 2.5-4.0, so that the stability of each component can be improved, and the acid cleaning effect is improved, and 3) the anionic surfactant is widely applied surfactant and is suitable for compatibility with other components of the acidic cleaning agent. The monolauryl phosphate surfactant has excellent emulsifying, solubilizing, antistatic and antirust performances, and the alcohol ether phosphate surfactant has excellent decontamination, emulsifying, dispersing, cleaning, wetting, antistatic and antirust performances, and is suitable for most factory scenes. 4) Dinitroso pentamethylene tetramine plays a role in foaming and has good stability.
In one embodiment, the cleaning process of the dust-accumulation acidic cleaning agent for cleaning the photovoltaic panel in the factory area comprises the steps of cleaning the photovoltaic panel by the dust-accumulation acidic cleaning agent and then flushing by water.
The volume of the acidic cleaning agent corresponds to the area of the photovoltaic panel (500-2000 mL), wherein the volume is 1m 2, the average contact time of the photovoltaic panel and the cleaning agent is 10-60 s, the acidic cleaning agent is washed by water for 1-2 times, and the water usage volume is 1-2 times of the cleaning agent usage volume.
The application will be further illustrated with reference to specific examples. It is to be understood that these examples are illustrative of the present application and are not intended to limit the scope of the present application. Furthermore, it should be understood that various changes and modifications can be made by one skilled in the art after reading the teachings of the present application, and such equivalents are intended to fall within the scope of the application as defined in the appended claims.
The following examples use instrumentation conventional in the art. The experimental methods, in which specific conditions are not noted in the following examples, are generally conducted under conventional conditions or under conditions recommended by the manufacturer. The following examples used various starting materials, unless otherwise indicated, were conventional commercial products, the specifications of which are conventional in the art. In the description of the present invention and the following examples, "%" means weight percent, and "parts" means parts by weight, and ratios means weight ratio, unless otherwise specified.
Example 1:
Cleaning a roof photovoltaic panel of a certain power plant factory, wherein the acidic cleaning agent comprises a component A and a component B, and comprises 1.0% of sulfamic acid, 0.5% of disodium hydrogen phosphate, 1.0% of monolauryl phosphate, 1.0% of acetone, 0.5% of sodium chloride, 0.3% of dinitroso pentamethylene tetramine, 0.05% of IS-129 hydrochloride retarder and the balance of desalted water, wherein the pH=4.0. The water tank provided with the cleaning agent is connected with a photovoltaic panel cleaning robot for cleaning, the volume of the acidic cleaning agent corresponds to 2000mL:1m 2 when the acidic cleaning agent is used, the temperature of an outlet heater is 50 ℃, the average contact time of the photovoltaic panel and the cleaning agent is 60s, and then the photovoltaic cleaning robot is connected with the water tank for flushing for 1 time.
After the cleaning is finished, the average dust removal rate of the surface of the photovoltaic panel is measured to be more than 95%.
Example 2:
the method comprises the steps of cleaning roof photovoltaic panels in a factory area of a certain chemical factory, wherein the acidic cleaning agent comprises a component A and a component B, and comprises 6.0% of sulfamic acid, 4.0% of disodium hydrogen phosphate, 4.0% of dodecylbenzene sulfonic acid, an isomeric tridecyl alcohol polyoxyethylene ether phosphate surfactant, 4.0% of acetone, 1.0% of sodium chloride, 0.5% of dinitroso pentamethylene tetramine, 0.1% of IS-129 hydrochloride corrosion inhibitor and the balance of desalted water, and the pH=2.5. The water tank provided with the cleaning agent is connected with a photovoltaic panel cleaning robot for cleaning, the volume of the acidic cleaning agent corresponds to 500mL:1m 2 of the area of the photovoltaic panel in use, the temperature of an outlet heater is 40 ℃, the average contact time of the photovoltaic panel and the cleaning agent is 10s, and then the photovoltaic cleaning robot is connected with the water tank for flushing for 2 times.
After the cleaning is finished, the average dust removal rate of the surface of the photovoltaic panel is measured to be more than 95%.
Example 3:
The roof photovoltaic panel of a certain coke-oven plant IS cleaned, the acidic cleaning agent comprises a component A and a component B, wherein the component A comprises 4.0 percent of sulfamic acid, 0.5 percent of sodium citrate, 2.0 percent of dodecylbenzene sulfonic acid, 2.0 percent of monolauryl phosphate surfactant, 1.5 percent of acetone, 0.7 percent of sodium chloride, 0.5 percent of dinitroso pentamethylene tetramine, 0.1 percent of IS-129 hydrochloride corrosion inhibitor and the balance of desalted water, and the pH=2.8. The water tank provided with the cleaning agent is connected with a photovoltaic panel cleaning robot for cleaning, the volume of the acidic cleaning agent corresponds to 1000mL:1m 2 when the acidic cleaning agent is used, the temperature of an outlet heater is 40 ℃, the average contact time of the photovoltaic panel and the cleaning agent is 10s, and then the photovoltaic cleaning robot is connected with the water tank for flushing for 2 times.
After the cleaning is finished, the average dust removal rate of the surface of the photovoltaic panel is measured to be more than 95%.
Example 4:
The method comprises the steps of cleaning roof photovoltaic panels of a certain coke plant area, wherein the acidic cleaning agent comprises a component A and a component B, and comprises 4.0% of sulfamic acid, 0.5% of sodium citrate, 0.5% of dodecylbenzenesulfonic acid, 0.5% of isomeric tridecanol polyoxyethylene ether phosphate surfactant, 1.5% of acetone, 0.7% of sodium chloride, 0.5% of dinitroso pentamethylene tetramine, 0.1% of IS-129 hydrochloride corrosion inhibitor and the balance of desalted water, and the pH=2.8. The water tank provided with the cleaning agent is connected with a photovoltaic panel cleaning robot for cleaning, the volume of the acidic cleaning agent corresponds to 500mL:1m 2 of the area of the photovoltaic panel in use, the temperature of an outlet heater is 40 ℃, the average contact time of the photovoltaic panel and the cleaning agent is 10s, and then the photovoltaic cleaning robot is connected with the water tank for flushing for 2 times.
After the cleaning is finished, the average dust removal rate of the surface of the photovoltaic panel is measured to be more than 95%.
Example 5:
The method comprises the steps of cleaning roof photovoltaic panels in a factory area of a textile mill, wherein the acidic cleaning agent comprises a component A and a component C, and comprises 1.0% of sulfamic acid, 1.0% of disodium hydrogen phosphate, 1.0% of dodecylbenzenesulfonic acid, JFC-1 surfactant, 0.3% of dinitroso pentamethylene tetramine, 0.5% of ammonium citrate, 1.0% of laureth and the balance of desalted water, wherein the pH=4.0. The water tank provided with the cleaning agent is connected with a photovoltaic panel cleaning robot for cleaning, the volume of the acidic cleaning agent corresponds to 1000mL:1m 2 of the area of the photovoltaic panel in use, the temperature of an outlet heater is 50 ℃, the average contact time of the photovoltaic panel and the cleaning agent is 60s, and then the photovoltaic cleaning robot is connected with the water tank for flushing for 1 time.
After the cleaning is finished, the average dust removal rate of the surface of the photovoltaic panel is measured to be more than 95%.
Example 6:
The method comprises the steps of cleaning the photovoltaic panels near a factory area of a building material factory, wherein the acidic cleaning agent comprises a component A and a component C, and comprises 6.0% of sulfamic acid, 4.0% of disodium hydrogen phosphate, 1.0% of dodecylbenzene sulfonic acid surfactant, 0.5% of dinitroso pentamethylene tetramine, 4.0% of ammonium citrate, 2.0% of laureth and the balance of desalted water, wherein the pH=2.5. The water tank provided with the cleaning agent is connected with a photovoltaic panel cleaning robot for cleaning, the volume of the acidic cleaning agent corresponds to 500mL:1m 2 of the area of the photovoltaic panel during use, the temperature of an outlet heater is 50 ℃, the average contact time of the photovoltaic panel and the cleaning agent is 30s, and then the photovoltaic cleaning robot is connected with the water tank for flushing for 2 times.
After the cleaning is finished, the average dust removal rate of the surface of the photovoltaic panel is measured to be more than 95%.
Example 7:
The method comprises the steps of cleaning the photovoltaic panels near a factory area of a building material factory, wherein the acidic cleaning agent comprises a component A and a component C, and comprises 2.0% of sulfamic acid, 4.0% of sodium citrate, 1.0% of monolauryl phosphate surfactant, 0.3% of dinitroso pentamethylene tetramine, 4.0% of ammonium citrate, 1.5% of laurinol polyoxyethylene ether and the balance of desalted water, wherein the pH=3.5. The water tank provided with the cleaning agent is connected with a photovoltaic panel cleaning robot for cleaning, the volume of the acidic cleaning agent corresponds to 500mL:1m 2 of the area of the photovoltaic panel during use, the temperature of an outlet heater is 50 ℃, the average contact time of the photovoltaic panel and the cleaning agent is 30s, and then the photovoltaic cleaning robot is connected with the water tank for flushing for 2 times.
After the cleaning is finished, the average dust removal rate of the surface of the photovoltaic panel is measured to be more than 95%.
Example 8:
The method comprises the steps of cleaning the photovoltaic panels near a factory area of a building material factory, wherein the acidic cleaning agent comprises a component A and a component C, and comprises 4.0% of sulfamic acid, 4.0% of sodium citrate, 1.0% of isomeric tridecanol polyoxyethylene ether phosphate surfactant, 0.3% of dinitroso pentamethylene tetramine, 4.0% of ammonium citrate, 1.5% of laurinol polyoxyethylene ether and the balance of desalted water, wherein the pH=4.0. The water tank provided with the cleaning agent is connected with a photovoltaic panel cleaning robot for cleaning, the volume of the acidic cleaning agent corresponds to 500mL:1m 2 of the area of the photovoltaic panel during use, the temperature of an outlet heater is 50 ℃, the average contact time of the photovoltaic panel and the cleaning agent is 30s, and then the photovoltaic cleaning robot is connected with the water tank for flushing for 2 times.
After the cleaning is finished, the average dust removal rate of the surface of the photovoltaic panel is measured to be more than 95%.
Example 9:
The cleaning of the photovoltaic panel near a small industrial garden factory area is carried out, and the acidic cleaning agent only comprises a component A, wherein the component A comprises 1.0% of sulfamic acid, 1.0% of disodium hydrogen phosphate, 1.0% of dodecylbenzene sulfonic acid surfactant, 0.3% of dinitroso pentamethylene tetramine and the balance of desalted water, and the pH=4.0. The water tank provided with the cleaning agent is connected with a photovoltaic panel cleaning robot for cleaning, the volume of the acidic cleaning agent corresponds to 500mL:1m 2 of the area of the photovoltaic panel in use, the average contact time of the photovoltaic panel and the cleaning agent is 60s, the temperature of an outlet heater is 50 ℃, and then the photovoltaic cleaning robot is connected with the water tank for flushing for 1 time.
After the cleaning is finished, the average dust removal rate of the surface of the photovoltaic panel is measured to be more than 95%.
Example 10:
the cleaning of the photovoltaic panels near a small industrial garden factory area is carried out, and the acidic cleaning agent only comprises a component A, wherein the component A comprises 6.0% of sulfamic acid, 4.0% of disodium hydrogen phosphate, 0.5% of monolauryl phosphate acid surfactant, 0.5% of dinitroso pentamethylene tetramine and the balance of desalted water, and the pH=2.5. The water tank provided with the cleaning agent is connected with a photovoltaic panel cleaning robot for cleaning, the volume of the acidic cleaning agent corresponds to 2000mL:1m 2 when the acidic cleaning agent is used, the average contact time of the photovoltaic panel and the cleaning agent is 10s, and then the photovoltaic cleaning robot is connected with the water tank for flushing for 2 times.
After the cleaning is finished, the average dust removal rate of the surface of the photovoltaic panel is measured to be more than 95%.
The above is only for illustrating the technical idea of the present invention, and the protection scope of the present invention is not limited by this, and any modification made on the basis of the technical scheme according to the technical idea of the present invention falls within the protection scope of the claims of the present invention.

Claims (10)

1.一种积尘酸性清洗剂,其特征在于,按质量百分数计,所述积尘酸性清洗剂包括:1. A dust acid cleaning agent, characterized in that, by mass percentage, the dust acid cleaning agent comprises: 1.0%~6.0%的氨基磺酸、0.5%~4.0%的碱性pH调节剂、1.0%~4.0%的阴离子型表面活性剂、0.3%~0.5%的发泡剂,余量为除盐水。1.0% to 6.0% of aminosulfonic acid, 0.5% to 4.0% of alkaline pH regulator, 1.0% to 4.0% of anionic surfactant, 0.3% to 0.5% of foaming agent, and the balance is desalted water. 2.根据权利要求1所述的积尘酸性清洗剂,其特征在于,按质量百分数计,所述积尘酸性清洗剂还包括1.0%~4.0%丙酮、0.5%~1.0%的氯化钠、0.05%~0.1%的IS-129盐酸缓蚀剂。2. The dust acid cleaning agent according to claim 1 is characterized in that, by mass percentage, the dust acid cleaning agent also includes 1.0% to 4.0% acetone, 0.5% to 1.0% sodium chloride, and 0.05% to 0.1% IS-129 hydrochloric acid corrosion inhibitor. 3.根据权利要求1所述的积尘酸性清洗剂,其特征在于,按质量百分数计,所述积尘酸性清洗剂还包括0.5%~4.0%的柠檬酸铵、1.0%~2.0%月桂醇聚氧乙烯醚。3. The dust acid cleaning agent according to claim 1 is characterized in that, in terms of mass percentage, the dust acid cleaning agent further comprises 0.5% to 4.0% of ammonium citrate and 1.0% to 2.0% of lauryl alcohol polyoxyethylene ether. 4.根据权利要求1至3任意一项所述的积尘酸性清洗剂,其特征在于,所述碱性pH调节剂是磷酸氢二钠或柠檬酸钠中的一种;所述阴离子型表面活性剂为单月桂基磷酸酯、十二烷基苯磺酸、醇醚磷酸酯类表面活性剂之中的一种或多种;所述发泡剂为二亚硝基五亚甲基四胺发泡剂。4. The dust acid cleaning agent according to any one of claims 1 to 3, characterized in that the alkaline pH regulator is one of disodium hydrogen phosphate or sodium citrate; the anionic surfactant is one or more of monolauryl phosphate, dodecylbenzene sulfonic acid, and alcohol ether phosphate surfactants; and the foaming agent is a dinitrosopentamethylenetetramine foaming agent. 5.根据权利要求1至3任意一项所述的积尘酸性清洗剂,其特征在于,所述积尘酸性清洗剂的pH值为2.5~4.0。5. The dust acid cleaning agent according to any one of claims 1 to 3, characterized in that the pH value of the dust acid cleaning agent is 2.5 to 4.0. 6.权利要求1至5任意一项所述的积尘酸性清洗剂在清洗工厂区光伏板中的应用。6. Use of the dust acid cleaning agent according to any one of claims 1 to 5 in cleaning photovoltaic panels in factory areas. 7.根据权利要求6所述的应用,其特征在于,所述工厂区为重工厂区,所述重工厂区光伏板的积尘组分包括含金属氧化物、碳酸盐、硅酸盐、煤粉不完全燃烧的残余有机物、多环芳烃和粉煤灰。7. The application according to claim 6 is characterized in that the factory area is a heavy industry area, and the dust components of the photovoltaic panels in the heavy industry area include metal oxides, carbonates, silicates, residual organic matter from incomplete combustion of coal powder, polycyclic aromatic hydrocarbons and fly ash. 8.根据权利要求6所述的应用,其特征在于,所述工厂区为轻工厂区,所述轻工厂区光伏板的积尘组分主要为轻质杂质,所述轻质杂质包括无机灰尘、纤维细丝、木屑。8. The application according to claim 6 is characterized in that the factory area is a light factory area, and the dust components of the photovoltaic panels in the light factory area are mainly light impurities, and the light impurities include inorganic dust, fiber filaments, and wood chips. 9.根据权利要求6所述的应用,其特征在于,所述积尘酸性清洗剂在清洗工厂区光伏板的清洗过程如下:9. The use according to claim 6, characterized in that the cleaning process of the dust acid cleaning agent in cleaning the photovoltaic panels in the factory area is as follows: 采用积尘酸性清洗剂对光伏板进行清洗,后使用水进行冲洗;其中,清洗一平方米光伏板的积尘酸性清洗剂用量为500~2000mL。The photovoltaic panels are cleaned with a dust acidic cleaning agent and then rinsed with water; the amount of dust acidic cleaning agent used to clean one square meter of photovoltaic panels is 500 to 2000 mL. 10.根据权利要求9所述的应用,其特征在于,所述积尘酸性清洗剂在光伏板表面停留的时间为10~60s;所述冲洗的次数为1~2次;所述水与积尘酸性清洗剂的用量比为(1~2):1。10. The use according to claim 9 is characterized in that the dust acid cleaning agent stays on the surface of the photovoltaic panel for 10 to 60 seconds; the number of flushing is 1 to 2 times; and the usage ratio of water to dust acid cleaning agent is (1 to 2):1.
CN202411072924.2A 2024-08-06 2024-08-06 A dust-accumulating acid cleaning agent and its application Pending CN119120119A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202411072924.2A CN119120119A (en) 2024-08-06 2024-08-06 A dust-accumulating acid cleaning agent and its application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202411072924.2A CN119120119A (en) 2024-08-06 2024-08-06 A dust-accumulating acid cleaning agent and its application

Publications (1)

Publication Number Publication Date
CN119120119A true CN119120119A (en) 2024-12-13

Family

ID=93764659

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202411072924.2A Pending CN119120119A (en) 2024-08-06 2024-08-06 A dust-accumulating acid cleaning agent and its application

Country Status (1)

Country Link
CN (1) CN119120119A (en)

Similar Documents

Publication Publication Date Title
CN101538512B (en) Water-based cleaner
EP2260094B1 (en) Use of citrate as cleaning aid for hard surfaces
US20030089381A1 (en) Enzymatic cleaner having high pH stability
US9228159B2 (en) Hard surface cleaning composition
CN100480365C (en) Detergent composition
CN103233239B (en) Normal-temperature degreasant and preparation method thereof
CN101892489B (en) Cleaning agent for flue dust scale on surface of gas heat exchanger of gas desulfurization system and preparation method thereof
CN112680289A (en) Carbon deposit cleaning agent for aviation engine and preparation method thereof
CN102071114A (en) Environmental cleaning agent
JP3267615B2 (en) Dye transfer control composition
CN108884332B (en) Compositions, methods, and articles comprising zwitterionic polymers for coating metal surfaces
CN119120119A (en) A dust-accumulating acid cleaning agent and its application
CN101165211A (en) Low-temperature metal cleaning agent
EP2853583B1 (en) Hard surface cleaning composition
US3810846A (en) Hard-surface treating compositions
US20200102526A1 (en) Wipes for coating surfaces and methods
JP2005068327A (en) Detergent
JPH11158492A (en) Detergent composition for steel sheet surface
CN102010229A (en) Granite rust remover
JP2001181688A (en) Detergent
Anderson et al. Removal of fatty soil from glass. Electrolyte detergent-builder effect
CN102168279B (en) Dusting cleaning antirusting agent and preparation method thereof
JP3391543B2 (en) Hydrophilizing agent and hydrophilizing method
JPH0525279B2 (en)
CN111849647A (en) Oil removing agent

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination