CN118730296A - Multi-pixel photon counter for front-illuminated single-photon imaging and manufacturing method thereof - Google Patents
Multi-pixel photon counter for front-illuminated single-photon imaging and manufacturing method thereof Download PDFInfo
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Abstract
本发明公开的正面照射式单光子成像的多像素光子计数器及其制造方法,包括衬底及其上方依次设置的外延层和金属网格层,外延层上对应金属网格层的开口区域阵列设置有若干第一富掺杂区,其上方共同设置有与其形成PN结且连接至金属网格层的第二富掺杂区,衬底内对应若干第一富掺杂区间隔区域通过开设隔离沟槽形成有阵列设置的若干柱状结构,其底端分别通过电极共同连接有信号读出电路。本发明中雪崩电流脉冲通过G‑APD单元下方衬底的柱状结构传输至信号读出电路,实现了正面入射模拟型MPPC的单光子探测与成像。由于探测器芯片表面无需电路结构与淬灭电阻,不占用面积,因此实现了高的填充因子,从而提高了探测器的探测效率。
The multi-pixel photon counter for front-illuminated single-photon imaging and its manufacturing method disclosed in the present invention include a substrate and an epitaxial layer and a metal grid layer sequentially arranged thereon, a plurality of first richly doped regions are arranged in an array in the opening area corresponding to the metal grid layer on the epitaxial layer, and a second richly doped region forming a PN junction with the first richly doped region and connected to the metal grid layer is arranged thereon, and a plurality of columnar structures arranged in an array are formed by opening isolation grooves in the substrate corresponding to the plurality of first richly doped region spacing areas, and the bottom ends of the columnar structures are respectively connected to a signal readout circuit through electrodes. In the present invention, the avalanche current pulse is transmitted to the signal readout circuit through the columnar structure of the substrate below the G‑APD unit, thereby realizing single-photon detection and imaging of the front-incident analog MPPC. Since the detector chip surface does not require circuit structure and quenching resistor, it does not occupy area, thus achieving a high fill factor, thereby improving the detection efficiency of the detector.
Description
技术领域Technical Field
本发明属于半导体光电探测芯片技术领域,具体涉及正面照射式单光子成像的多像素光子计数器。本发明还涉及正面照射式单光子成像的多像素光子计数器的制造方法。The present invention belongs to the technical field of semiconductor photoelectric detection chips, and in particular relates to a multi-pixel photon counter for front-illuminated single-photon imaging. The present invention also relates to a method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging.
背景技术Background Art
多像素光子计数器(multi-pixel photon counter,MPPC)是一种具有高灵敏度的单光子响应探测器,它将众多的工作在盖革模式的雪崩光电二极管(Geiger-ModeAvalanche Photo-diode,G-APD)单元阵列化集成在同一个单晶硅片上构成的固态光电探测器件,在高能物理、核探测、激光雷达、医学成像、荧光探测等多个弱光探测领域得到了应用。然而,现有的正面照射式模拟型MPPC无法实现单光子成像功能,只有背面照射式模拟型MPPC结合信号读出电路实现了单光子成像功能。专利(CN115084295A)提出了光线背面照式模拟型硅光电倍增管(Silicon photomultiplier,SiPM,是MPPC的别称)结构,克服了光入射面的填充因子受到表面淬灭电阻(RQ)、顶部引出电极以及像素隔离结构的布局影响的问题,并且原则上可以实现单光子成像,但是该种结构是深埋雪崩pn结结构,pn结结深和高场区都非常深,当短波长光子入射时,由于光子吸收深度很小,产生的光生电子空穴对会在表面重掺杂区域复合或吸收,无法到达高电场区,从而无法响应短波长光子(如紫外光子)。另一方面,该种MPPC结构内的沟槽隔离结构与高电场区相连,沟槽内的大量缺陷会大大增加暗计数率、后脉冲概率,降低MPPC的信噪比。进一步的,该种结构的MPPC需要将读出电子学晶体管硅衬底(512)以上的MPPC本体制作的非常薄,才能实现P型低掺杂区的全耗尽,工艺制作难度高。专利(CN109727970A)提出将传感器(即探测器)芯片和信号读出芯片通过倒装方式集成在一起,以实现所述传感器芯片的雪崩光电二极管和对应的淬灭电阻与所述信号读出芯片的信号数字读出电路电气连接,以通过信号数字读出电路读出从淬灭电阻取样的电信号。这种结构也属于光子背面照射式模拟型MPPC结构,虽然有利于提高填充因子(Filling Factor,FF),但必须采用倒装方式,光子必须从探测器背面射入,光子必须穿过较厚的衬底或者将衬底亦或是将外延层全耗尽,通过光生载流子的长距离漂移,才能进入雪崩光电二极管阵列的高场区,实现光子雪崩探测。这种探测的机理会导致短波长光子探测效率低下。与模拟型MPPC并行发展的数字型MPPC或单光子雪崩光电二极管阵列(SPAD阵列)能够实现正面照射式单光子成像,然而目前数字型MPPC是将信号处理电路制作在芯片上表面每个G-APD单元的旁边,信号处理电路是非光敏的,限制了探测器的几何填充因子,进而影响了单光子灵敏成像探测器整体的光子探测效率(参考文献Architecture-LevelOptimization on Digital Silicon Photomultipliers for Medical Imaging,Sensors2022,22,122)。Multi-pixel photon counter (MPPC) is a highly sensitive single-photon response detector. It integrates a large number of Geiger-mode avalanche photodiode (G-APD) units in an array on the same single-crystal silicon wafer to form a solid-state photodetector device. It has been applied in many weak-light detection fields such as high-energy physics, nuclear detection, laser radar, medical imaging, and fluorescence detection. However, the existing front-illuminated analog MPPC cannot realize the single-photon imaging function. Only the back-illuminated analog MPPC combined with the signal readout circuit can realize the single-photon imaging function. The patent (CN115084295A) proposes a light back-illuminated analog silicon photomultiplier (SiPM, another name for MPPC) structure, which overcomes the problem that the filling factor of the light incident surface is affected by the layout of the surface quenching resistor (R Q ), the top lead electrode and the pixel isolation structure, and in principle can achieve single-photon imaging, but this structure is a deeply buried avalanche pn junction structure, the pn junction depth and the high field region are very deep, when short-wavelength photons are incident, due to the small photon absorption depth, the generated photogenerated electron-hole pairs will recombine or absorb in the heavily doped surface area, unable to reach the high electric field area, and thus unable to respond to short-wavelength photons (such as ultraviolet photons). On the other hand, the trench isolation structure in this MPPC structure is connected to the high electric field area, and a large number of defects in the trench will greatly increase the dark count rate and the probability of after-pulses, reducing the signal-to-noise ratio of the MPPC. Furthermore, the MPPC of this structure needs to make the MPPC body above the silicon substrate (512) of the readout electronics transistor very thin in order to achieve full depletion of the P-type low-doped region, and the process manufacturing is difficult. Patent (CN109727970A) proposes to integrate the sensor (i.e., detector) chip and the signal readout chip together by flip-chip method, so as to realize the electrical connection between the avalanche photodiode and the corresponding quenching resistor of the sensor chip and the signal digital readout circuit of the signal readout chip, so as to read the electrical signal sampled from the quenching resistor through the signal digital readout circuit. This structure also belongs to the photon back-illuminated analog MPPC structure. Although it is beneficial to improve the filling factor (FF), it must adopt a flip-chip method, and the photons must be injected from the back of the detector. The photons must pass through a thicker substrate or fully deplete the substrate or the epitaxial layer, and can enter the high field area of the avalanche photodiode array through the long-distance drift of the photogenerated carriers to achieve photon avalanche detection. This detection mechanism will lead to low efficiency of short-wavelength photon detection. Digital MPPC or single-photon avalanche photodiode array (SPAD array), which is developed in parallel with analog MPPC, can realize front-illuminated single-photon imaging. However, the current digital MPPC makes the signal processing circuit next to each G-APD unit on the upper surface of the chip. The signal processing circuit is non-photosensitive, which limits the geometric fill factor of the detector, thereby affecting the overall photon detection efficiency of the single-photon sensitive imaging detector (reference Architecture-Level Optimization on Digital Silicon Photomultipliers for Medical Imaging, Sensors 2022, 22, 122).
发明内容Summary of the invention
本发明的目的在于提供正面照射式单光子成像的多像素光子计数器,解决了现有正面照射式模拟型MPPC无法实现单光子成像以及单光子灵敏成像器件光子探测效率低的问题。The purpose of the present invention is to provide a multi-pixel photon counter for front-illuminated single-photon imaging, which solves the problem that the existing front-illuminated analog MPPC cannot realize single-photon imaging and the single-photon sensitive imaging device has low photon detection efficiency.
本发明的另一目的在于提供正面照射式单光子成像的多像素光子计数器的制造方法。Another object of the present invention is to provide a method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging.
本发明所采用的第一种技术方案是:正面照射式单光子成像的多像素光子计数器,包括衬底,衬底上方依次设置有外延层和金属网格层,外延层上对应金属网格层的开口区域阵列设置有若干第一富掺杂区,若干第一富掺杂区上方共同设置有与其形成PN结且连接至金属网格层的第二富掺杂区,衬底内对应若干第一富掺杂区间隔区域通过开设隔离沟槽形成有阵列设置的若干柱状结构,若干柱状结构的底端分别通过电极连接至信号读出电路的电极阵列,无须在探测器正面制作淬灭电阻、信号处理电路,从而提高了成像探测器的填充因子,进而提高了成像探测器的光子探测效率。具体结构实现方式可以是:The first technical solution adopted by the present invention is: a multi-pixel photon counter for front-illuminated single-photon imaging, including a substrate, an epitaxial layer and a metal grid layer are sequentially arranged on the substrate, a plurality of first richly doped regions are arranged in an array in the opening area of the epitaxial layer corresponding to the metal grid layer, a second richly doped region is commonly arranged above the plurality of first richly doped regions to form a PN junction with the plurality of first richly doped regions and connected to the metal grid layer, a plurality of columnar structures arranged in an array are formed by opening isolation grooves in the corresponding interval areas of the plurality of first richly doped regions in the substrate, the bottom ends of the plurality of columnar structures are respectively connected to the electrode array of the signal readout circuit through electrodes, and there is no need to make a quenching resistor or a signal processing circuit on the front of the detector, thereby improving the filling factor of the imaging detector, and further improving the photon detection efficiency of the imaging detector. The specific structural implementation method may be:
1)短波长光灵敏的正面照射式单光子成像的多像素光子计数器,包括N+型硅衬底,N+型硅衬底上方依次设置有N-外延层和金属网格层,N-外延层上对应金属网格层的开口区域阵列设置有若干N+区,若干N+区上方共同设置有与其形成PN结且连接至金属网格层的P++区,N+型硅衬底内对应若干N+区间隔区域通过开设隔离沟槽形成有阵列设置的若干柱状结构,若干柱状结构的底端分别通过电极连接至信号读出电路的电极阵列。1) A multi-pixel photon counter for short-wavelength light-sensitive front-illuminated single-photon imaging, comprising an N+ type silicon substrate, an N- epitaxial layer and a metal grid layer arranged in sequence on the N+ type silicon substrate, a plurality of N+ regions arranged in an array in an opening area of the N- epitaxial layer corresponding to the metal grid layer, a P++ region forming a PN junction with the plurality of N+ regions and connected to the metal grid layer being arranged above the plurality of N+ regions, a plurality of columnar structures arranged in an array are formed by opening isolation grooves in an area corresponding to the plurality of N+ regions in the N+ type silicon substrate, and the bottom ends of the plurality of columnar structures are connected to an electrode array of a signal readout circuit through electrodes.
2)长波长光灵敏的正面照射式单光子成像的多像素光子计数器,包括P+型硅衬底,P+型硅衬底上方依次设置有P-外延层和金属网格层,P-外延层上对应金属网格层的开口区域阵列设置有若干P+区,若干P+区上方共同设置有与其形成PN结且连接至金属网格层的N++区,P+型硅衬底内对应若干P+区间隔区域通过开设隔离沟槽形成有阵列设置的若干柱状结构,若干柱状结构的底端分别通过电极连接至信号读出电路的电极阵列。2) A multi-pixel photon counter for front-illuminated single-photon imaging that is sensitive to long-wavelength light, comprising a P+ type silicon substrate, a P- epitaxial layer and a metal grid layer arranged in sequence on the P+ type silicon substrate, a plurality of P+ regions arranged in an array in an opening area of the P- epitaxial layer corresponding to the metal grid layer, an N++ region forming a PN junction with the plurality of P+ regions and connected to the metal grid layer being arranged above the plurality of P+ regions, a plurality of columnar structures arranged in an array are formed by opening isolation grooves in an area corresponding to the plurality of P+ regions in the P+ type silicon substrate, and the bottom ends of the plurality of columnar structures are connected to an electrode array of a signal readout circuit through electrodes.
本发明第一种技术方案的特点还在于,The first technical solution of the present invention is also characterized in that:
隔离沟槽内填充有绝缘介质。The isolation trench is filled with an insulating medium.
柱状结构的底端依次通过N++层/P++层、金属层和铟球连接至电极。The bottom end of the columnar structure is connected to the electrode through the N++ layer/P++ layer, the metal layer and the indium ball in sequence.
本发明所采用的第二种技术方案是:The second technical solution adopted by the present invention is:
上述1)短波长光灵敏的正面照射式单光子成像的多像素光子计数器的制造方法,包括以下步骤:The method for manufacturing the above-mentioned 1) short-wavelength light-sensitive front-illuminated single-photon imaging multi-pixel photon counter comprises the following steps:
步骤1、准备外延N-外延层的N+型硅衬底,清洗后在N+型硅衬底正反两面热氧化SiO2介质层;Step 1, prepare an N+ type silicon substrate for epitaxial N- epitaxial layer, and after cleaning, thermally oxidize SiO2 dielectric layer on both sides of the N+ type silicon substrate;
步骤2、在N+型硅衬底正面涂抹光刻胶光刻阵列窗口图形,刻蚀掉阵列窗口内的SiO2介质层,通过阵列窗口注入磷离子后形成N+区,去除光刻胶;Step 2, applying photoresist on the front side of the N+ type silicon substrate to pattern the array window, etching the SiO2 dielectric layer in the array window, injecting phosphorus ions through the array window to form an N+ region, and removing the photoresist;
步骤3、在N+型硅衬底正面涂抹光刻胶光刻大面积窗口图形,刻蚀掉大面积窗口内的SiO2介质层,通过大面积窗口注入硼离子后形成P++区,去除光刻胶与SiO2介质层;Step 3, applying photoresist on the front side of the N+ type silicon substrate to photolithograph a large area window pattern, etching away the SiO2 dielectric layer in the large area window, injecting boron ions through the large area window to form a P++ region, and removing the photoresist and SiO2 dielectric layer;
步骤4、在N+型硅衬底背面注入磷离子后形成全面积的N++层;Step 4, after implanting phosphorus ions on the back side of the N+ type silicon substrate, a full-area N++ layer is formed;
步骤5、通过退火工艺激活N-外延层和N+型硅衬底中的磷离子;Step 5, activating phosphorus ions in the N-epitaxial layer and the N+ type silicon substrate through an annealing process;
步骤6、在N+型硅衬底正面淀积SiO2介质层;Step 6: depositing a SiO2 dielectric layer on the front side of the N+ type silicon substrate;
步骤7、在N+型硅衬底正面涂抹光刻胶光刻与P++区对准的大面积窗口图形,并刻蚀干净图形内的SiO2;Step 7, apply photoresist on the front of the N+ type silicon substrate to form a large area window pattern aligned with the P++ area, and etch the SiO 2 in the pattern cleanly;
步骤8、正面淀积金属膜;Step 8, depositing a metal film on the front side;
步骤9、在N+型硅衬底正面涂抹光刻胶光刻与N+区对应的阵列窗口图形,并刻蚀掉未被光刻胶保护的金属膜,得到金属网格层;Step 9, applying photoresist on the front side of the N+ type silicon substrate to photoetch an array window pattern corresponding to the N+ area, and etching away the metal film not protected by the photoresist to obtain a metal grid layer;
步骤10、在N+型硅衬底背面淀积金属层;Step 10, depositing a metal layer on the back side of the N+ type silicon substrate;
步骤11、在N+型硅衬底背面涂抹光刻胶光刻若干柱状结构间的隔离沟槽图形;Step 11, applying photoresist on the back side of the N+ type silicon substrate to photoetch isolation groove patterns between a plurality of columnar structures;
步骤12、先刻蚀N+型硅衬底背面未被光刻胶保护的金属层,然后刻蚀未被光刻胶保护的N+型硅衬底至N-外延层下表面,形成隔离沟槽;Step 12, first etching the metal layer on the back side of the N+ type silicon substrate that is not protected by the photoresist, and then etching the N+ type silicon substrate that is not protected by the photoresist to the lower surface of the N- epitaxial layer to form an isolation trench;
步骤13、在隔离沟槽内填充绝缘介质;Step 13, filling the isolation trench with an insulating medium;
步骤14、将柱状结构下方的金属层通过铟球与信号读出电路的电极相连。Step 14: Connect the metal layer below the columnar structure to the electrode of the signal readout circuit through the indium ball.
上述2)长波长光灵敏的正面照射式单光子成像的多像素光子计数器的制造方法,包括以下步骤:The method for manufacturing the above-mentioned 2) multi-pixel photon counter for front-illuminated single-photon imaging that is sensitive to long-wavelength light comprises the following steps:
步骤1、准备外延P-外延层的P+型硅衬底,清洗后在P+型硅衬底正反两面热氧化SiO2介质层;Step 1, prepare a P+ type silicon substrate for epitaxial P- epitaxial layer, and after cleaning, thermally oxidize SiO2 dielectric layer on both sides of the P+ type silicon substrate;
步骤2、在P+型硅衬底正面涂抹光刻胶光刻阵列窗口图形,刻蚀掉阵列窗口内的SiO2介质层,通过阵列窗口注入磷离子后形成P+区,去除光刻胶;Step 2, applying photoresist on the front of the P+ type silicon substrate to pattern the array window, etching the SiO2 dielectric layer in the array window, injecting phosphorus ions through the array window to form a P+ region, and removing the photoresist;
步骤3、在P+型硅衬底正面涂抹光刻胶光刻大面积窗口图形,刻蚀掉大面积窗口内的SiO2介质层,通过大面积窗口注入硼离子后形成N++区,去除光刻胶与SiO2介质层;Step 3, applying photoresist on the front of the P+ type silicon substrate to photolithograph a large area window pattern, etching away the SiO2 dielectric layer in the large area window, injecting boron ions through the large area window to form an N++ region, and removing the photoresist and SiO2 dielectric layer;
步骤4、在P+型硅衬底背面注入磷离子后形成全面积的P++层;Step 4, after injecting phosphorus ions into the back side of the P+ type silicon substrate, a full-area P++ layer is formed;
步骤5、通过退火工艺激活P-外延层和P+型硅衬底中的磷离子;Step 5, activating phosphorus ions in the P-epitaxial layer and the P+ silicon substrate through an annealing process;
步骤6、在P+型硅衬底正面淀积SiO2介质层;Step 6: depositing a SiO2 dielectric layer on the front side of the P+ type silicon substrate;
步骤7、在P+型硅衬底正面涂抹光刻胶光刻与N++区对准的大面积窗口图形,并刻蚀干净图形内的SiO2;Step 7, apply photoresist on the front of the P+ type silicon substrate to form a large area window pattern aligned with the N++ area, and etch the SiO 2 in the pattern cleanly;
步骤8、正面淀积金属膜;Step 8, depositing a metal film on the front side;
步骤9、在P+型硅衬底正面涂抹光刻胶光刻与P+区对应的阵列窗口图形,并刻蚀掉未被光刻胶保护的金属膜,得到金属网格层;Step 9, applying photoresist on the front side of the P+ type silicon substrate to photoetch an array window pattern corresponding to the P+ area, and etching away the metal film not protected by the photoresist to obtain a metal grid layer;
步骤10、在P+型硅衬底背面淀积金属层;Step 10, depositing a metal layer on the back side of the P+ type silicon substrate;
步骤11、在P+型硅衬底背面涂抹光刻胶光刻若干柱状结构间的隔离沟槽图形;Step 11, applying photoresist on the back side of the P+ type silicon substrate to photoetch isolation groove patterns between a plurality of columnar structures;
步骤12、先刻蚀P+型硅衬底背面未被光刻胶保护的金属层,然后刻蚀未被光刻胶保护的P+型硅衬底至P-外延层下表面,形成隔离沟槽;Step 12, first etching the metal layer on the back side of the P+ type silicon substrate that is not protected by the photoresist, and then etching the P+ type silicon substrate that is not protected by the photoresist to the lower surface of the P- epitaxial layer to form an isolation trench;
步骤13、在隔离沟槽内填充绝缘介质;Step 13, filling the isolation trench with an insulating medium;
步骤14、将柱状结构下方的金属层通过铟球与信号读出电路的电极相连。Step 14: Connect the metal layer below the columnar structure to the electrode of the signal readout circuit through the indium ball.
本发明的有益效果是:本发明的正面照射式单光子成像的多像素光子计数器及其制造方法,雪崩电流脉冲通过G-APD单元下方衬底的柱状结构传输至信号读出电路,实现了正面入射模拟型MPPC的单光子探测与成像。由于探测器芯片表面无需电路结构与淬灭电阻,不占用面积,因此实现了高的填充因子,且由于能够探测正面入射的光子,从而提高了探测器的探测效率。The beneficial effects of the present invention are as follows: in the multi-pixel photon counter for front-illuminated single-photon imaging and the manufacturing method thereof, the avalanche current pulse is transmitted to the signal readout circuit through the columnar structure of the substrate below the G-APD unit, thereby realizing single-photon detection and imaging of the front-incident analog MPPC. Since the detector chip surface does not require a circuit structure and a quenching resistor and does not occupy an area, a high fill factor is achieved, and since the detector can detect front-incident photons, the detection efficiency of the detector is improved.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1是本发明的正面照射式单光子成像的多像素光子计数器的结构示意图;FIG1 is a schematic diagram of the structure of a multi-pixel photon counter for front-illuminated single-photon imaging according to the present invention;
图2是本发明的正面照射式单光子成像的多像素光子计数器的制造方法的流程示意图;FIG2 is a schematic flow chart of a method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging according to the present invention;
图3是本发明的正面照射式单光子成像的多像素光子计数器的制造方法中步骤2所得结构示意图;FIG3 is a schematic diagram of the structure obtained in step 2 of the method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging according to the present invention;
图4是本发明的正面照射式单光子成像的多像素光子计数器的制造方法中步骤3所得结构示意图;FIG4 is a schematic diagram of the structure obtained in step 3 of the method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging according to the present invention;
图5是本发明的正面照射式单光子成像的多像素光子计数器的制造方法中步骤4所得结构示意图;FIG5 is a schematic diagram of the structure obtained in step 4 of the method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging according to the present invention;
图6是本发明的正面照射式单光子成像的多像素光子计数器的制造方法中步骤6所得结构示意图;FIG6 is a schematic diagram of the structure obtained in step 6 of the method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging according to the present invention;
图7是本发明的正面照射式单光子成像的多像素光子计数器的制造方法中步骤7所得结构示意图;FIG7 is a schematic diagram of the structure obtained in step 7 of the method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging according to the present invention;
图8是本发明的正面照射式单光子成像的多像素光子计数器的制造方法中步骤8所得结构示意图;FIG8 is a schematic diagram of the structure obtained in step 8 of the method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging according to the present invention;
图9是本发明的正面照射式单光子成像的多像素光子计数器的制造方法中步骤9所得结构示意图;FIG9 is a schematic diagram of the structure obtained in step 9 of the method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging according to the present invention;
图10是本发明的正面照射式单光子成像的多像素光子计数器的制造方法中步骤10所得结构示意图;FIG10 is a schematic diagram of the structure obtained in step 10 of the method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging according to the present invention;
图11是本发明的正面照射式单光子成像的多像素光子计数器的制造方法中步骤11所得结构示意图;FIG11 is a schematic diagram of the structure obtained in step 11 of the method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging according to the present invention;
图12是本发明的正面照射式单光子成像的多像素光子计数器的制造方法中步骤12所得结构示意图;FIG12 is a schematic diagram of the structure obtained in step 12 of the method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging according to the present invention;
图13是本发明的正面照射式单光子成像的多像素光子计数器的制造方法中步骤13所得结构示意图;FIG13 is a schematic diagram of the structure obtained in step 13 of the method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging according to the present invention;
图14是本发明的正面照射式单光子成像的多像素光子计数器的制造方法中步骤14所得结构示意图。FIG. 14 is a schematic diagram of the structure obtained in step 14 of the method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging according to the present invention.
图中,1.光刻胶,2.SiO2介质层,3.N+区,4.N-外延层,5.N+型硅衬底,6.P++区,7.高阻耗尽区,8.N++层,9.金属网格层,10.金属层,11.绝缘介质,12.铟球,13.电极,14.信号读出电路。In the figure, 1. photoresist, 2. SiO2 dielectric layer, 3. N+ region, 4. N- epitaxial layer, 5. N+ type silicon substrate, 6. P++ region, 7. high resistance depletion region, 8. N++ layer, 9. metal grid layer, 10. metal layer, 11. insulating medium, 12. indium ball, 13. electrode, 14. signal readout circuit.
具体实施方式DETAILED DESCRIPTION
下面结合附图以及具体实施方式对本发明进行详细说明。The present invention is described in detail below with reference to the accompanying drawings and specific embodiments.
实施例1Example 1
本发明提供了正面照射式单光子成像的多像素光子计数器,如图1和图14所示,包括设置于MPPC表面的金属网格层9电极,在N-外延层4上方注入磷离子形成多个N+区3,得到若干G-APD单元构成的阵列,在N+区3上方大面积注入硼离子形成P++区6并共同构成PN结,N+区3之间通过P++区6与N-外延层4自发形成的高阻耗尽区7实现电学隔离。N-外延层4与下方的N+型硅衬底5相连,在衬底背面有N++层8、金属层10,衬底背面通过深槽刻蚀工艺被刻蚀为一根根孤立的柱状结构,柱状结构仅有一端(即上端)与N-外延层4连通,柱状结构与N-外延层4上的N+区3对准,与柱状结构下表面金属层10连接的有独立的铟球12、信号读出电路14的信号输入端电极13。The present invention provides a multi-pixel photon counter for front-illuminated single-photon imaging, as shown in FIG1 and FIG14, comprising a metal grid layer 9 electrode arranged on the surface of the MPPC, phosphorus ions are injected above the N-epitaxial layer 4 to form a plurality of N+ regions 3, and an array consisting of a plurality of G-APD units is obtained, boron ions are injected over a large area above the N+ region 3 to form a P++ region 6 and together form a PN junction, and the N+ regions 3 are electrically isolated through the high-resistance depletion region 7 spontaneously formed by the P++ region 6 and the N-epitaxial layer 4. The N-epitaxial layer 4 is connected to the N+ silicon substrate 5 below, and there are an N++ layer 8 and a metal layer 10 on the back of the substrate. The back of the substrate is etched into isolated columnar structures by a deep groove etching process, and only one end (i.e., the upper end) of the columnar structure is connected to the N-epitaxial layer 4, and the columnar structure is aligned with the N+ region 3 on the N-epitaxial layer 4. An independent indium ball 12 and a signal input terminal electrode 13 of a signal readout circuit 14 are connected to the metal layer 10 on the lower surface of the columnar structure.
G-APD单元下面的柱状结构和MPPC表面的金属网格状电极可以依据G-APD单元形状进行刻蚀,形状可以是方形、圆形、六边形等。The columnar structure under the G-APD unit and the metal grid electrode on the surface of the MPPC can be etched according to the shape of the G-APD unit, and the shape can be square, circular, hexagonal, etc.
在柱状结构之间的沟槽内可以填充绝缘介质11,用于增加机械强度,并提高每个G-APD单元下面柱状结构之间的电学隔离。在柱状结构机械强度足够的情况下,也可不填充绝缘介质11。The grooves between the columnar structures may be filled with an insulating medium 11 to increase the mechanical strength and improve the electrical isolation between the columnar structures under each G-APD unit. If the columnar structure has sufficient mechanical strength, the insulating medium 11 may not be filled.
本发明的原理是:针对现有的单光子雪崩光电二极管阵列大多将信号处理电路做在芯片上表面每个G-APD单元的旁边,限制了成像探测器的几何填充因子,进而影响了光子探测效率。本发明沿着G-APD单元的间隔,从低电阻率N+型硅衬底5背面刻槽,一直刻到高阻耗尽区7下表面,并且可在沟槽内填充绝缘介质11,实现每个单元下面衬底层的电学隔离,避免多个G-APD单元产生的雪崩电流信号向下汇集到衬底后,不同G-APD单元的雪崩电流信号混合无法分辨。这样通过N-外延层4上表面的金属网格层9电极给MPPC中所有的G-APD单元施加反向偏压,在P++区6与N+区3之间形成高电场雪崩区阵列,N+区3下方的中性区域可以实现G-APD单元雪崩电流的淬灭,从而形成雪崩电流脉冲,雪崩电流脉冲通过沟槽隔离的柱状结构及铟球12,输入到下面独立的多通道信号读出电路14或信号读出芯片中进行信号处理,实现单光子成像。通过上述方式,本发明无需采用将光子从传感器背面射入的倒装方式,能够探测正面入射的光子,实现了正面入射模拟型MPPC的单光子探测与成像。且由于探测器芯片表面无需电路结构与淬灭电阻,不占用面积,因此实现了高的填充因子,进一步提高了探测器的探测效率。The principle of the present invention is: most of the existing single-photon avalanche photodiode arrays place the signal processing circuit next to each G-APD unit on the upper surface of the chip, which limits the geometric filling factor of the imaging detector, thereby affecting the photon detection efficiency. The present invention carves grooves along the intervals of the G-APD units, from the back of the low-resistivity N+ type silicon substrate 5 to the lower surface of the high-resistance depletion region 7, and can fill the grooves with an insulating medium 11 to achieve electrical isolation of the substrate layer under each unit, thereby preventing the avalanche current signals generated by multiple G-APD units from being mixed and indistinguishable after being converged downward to the substrate. In this way, a reverse bias is applied to all G-APD units in the MPPC through the metal grid layer 9 electrode on the upper surface of the N-epitaxial layer 4, forming a high electric field avalanche region array between the P++ region 6 and the N+ region 3. The neutral region below the N+ region 3 can achieve quenching of the avalanche current of the G-APD unit, thereby forming an avalanche current pulse. The avalanche current pulse is input into the independent multi-channel signal readout circuit 14 or signal readout chip below through the trench-isolated columnar structure and the indium ball 12 for signal processing to achieve single-photon imaging. In the above manner, the present invention does not need to adopt a flip-chip method of injecting photons from the back of the sensor, and can detect photons incident from the front, thereby achieving single-photon detection and imaging of front-incident analog MPPC. And because the detector chip surface does not require circuit structure and quenching resistors, it does not occupy area, so a high fill factor is achieved, further improving the detection efficiency of the detector.
本发明提供的正面照射式单光子成像的多像素光子计数器,可将所述N型区域全部替换为相应浓度的P型区,并把P型区域全部替换为相应浓度的N型区,以实现长波长光子(如近红外光子)的高灵敏探测与成像。The multi-pixel photon counter for front-illuminated single-photon imaging provided by the present invention can replace all the N-type regions with P-type regions of corresponding concentration, and replace all the P-type regions with N-type regions of corresponding concentration, so as to achieve high-sensitivity detection and imaging of long-wavelength photons (such as near-infrared photons).
实施例2Example 2
本发明提供了正面照射式单光子成像的多像素光子计数器的制造方法,适合于短波长光子(如紫外光子、蓝紫光光子)的响应与成像,如图2所示,包括以下步骤:The present invention provides a method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging, which is suitable for the response and imaging of short-wavelength photons (such as ultraviolet photons and blue-violet photons), as shown in FIG2, comprising the following steps:
步骤1、准备外延N-外延层4的N+型硅衬底5,清洗后在N+型硅衬底5正反两面热氧化薄而致密的SiO2介质层2;Step 1, prepare an N+ type silicon substrate 5 for epitaxially growing an N- epitaxial layer 4, and after cleaning, thermally oxidize a thin and dense SiO2 dielectric layer 2 on both sides of the N+ type silicon substrate 5;
步骤2、如图3所示,在N+型硅衬底5正面涂抹光刻胶1光刻阵列窗口图形,刻蚀掉阵列窗口内的SiO2介质层2,通过阵列窗口注入磷离子后形成N+区3,去除光刻胶1;Step 2, as shown in FIG. 3, a photoresist 1 is applied to the front of the N+ type silicon substrate 5 to pattern the array window, the SiO2 dielectric layer 2 in the array window is etched away, phosphorus ions are injected through the array window to form an N+ region 3, and the photoresist 1 is removed;
步骤3、如图4所示,在N+型硅衬底5正面涂抹光刻胶1光刻大面积窗口图形,刻蚀掉大面积窗口内的SiO2介质层2,通过大面积窗口注入硼离子后形成P++区6,去除光刻胶1与SiO2介质层2;Step 3, as shown in FIG. 4 , a photoresist 1 is applied to the front of the N+ type silicon substrate 5 to form a large area window pattern, the SiO2 dielectric layer 2 in the large area window is etched away, boron ions are injected through the large area window to form a P++ region 6, and the photoresist 1 and the SiO2 dielectric layer 2 are removed;
步骤4、如图5所示,在N+型硅衬底5背面注入磷离子后形成全面积的N++层8;Step 4, as shown in FIG5 , phosphorus ions are implanted on the back side of the N+ type silicon substrate 5 to form a full-area N++ layer 8;
步骤5、通过退火工艺激活离子注入工艺进入N-外延层4和N+型硅衬底5中的磷离子;Step 5, activating the phosphorus ions implanted into the N- epitaxial layer 4 and the N+ type silicon substrate 5 by an annealing process;
步骤6、如图6所示,在N+型硅衬底5正面淀积200nm以上的SiO2介质层2;Step 6, as shown in FIG6 , depositing a SiO 2 dielectric layer 2 with a thickness of more than 200 nm on the front side of the N+ type silicon substrate 5;
步骤7、如图7所示,在N+型硅衬底5正面涂抹光刻胶1光刻与P++区6对准的大面积窗口图形,并刻蚀干净图形内的SiO2;Step 7, as shown in FIG. 7 , a photoresist 1 is applied to the front of the N+ type silicon substrate 5 to form a large area window pattern aligned with the P++ region 6, and SiO 2 in the pattern is etched cleanly;
步骤8、如图8所示,正面淀积金属膜;Step 8, as shown in FIG8 , depositing a metal film on the front side;
步骤9、如图9所示,在N+型硅衬底5正面涂抹光刻胶1光刻与N+区3对应的阵列窗口图形,并刻蚀掉未被光刻胶保护的金属膜,得到金属网格层9;Step 9, as shown in FIG. 9 , a photoresist 1 is applied to the front side of the N+ type silicon substrate 5 to photoetch an array window pattern corresponding to the N+ region 3, and the metal film not protected by the photoresist is etched away to obtain a metal grid layer 9;
步骤10、如图10所示,在N+型硅衬底5背面淀积金属层10;Step 10, as shown in FIG10 , depositing a metal layer 10 on the back side of the N+ type silicon substrate 5;
步骤11、如图11所示,在N+型硅衬底5背面涂抹光刻胶1光刻若干柱状结构间的隔离沟槽图形;Step 11, as shown in FIG. 11 , a photoresist 1 is applied to the back of the N+ type silicon substrate 5 to photoetch isolation groove patterns between a plurality of columnar structures;
步骤12、如图12所示,先刻蚀N+型硅衬底5背面未被光刻胶1保护的金属层10,控制刻蚀时间,然后刻蚀未被光刻胶1保护的N+型硅衬底5至N-外延层4下表面,形成隔离沟槽;Step 12, as shown in FIG. 12 , first etch the metal layer 10 on the back side of the N+ type silicon substrate 5 that is not protected by the photoresist 1, control the etching time, and then etch the N+ type silicon substrate 5 that is not protected by the photoresist 1 to the lower surface of the N- epitaxial layer 4 to form an isolation trench;
步骤13、如图13所示,在隔离沟槽内填充绝缘介质11;Step 13, as shown in FIG13 , filling the isolation trench with an insulating medium 11;
步骤14、如图14所示,将柱状结构下方的金属层10通过铟球12与信号读出电路14的电极13相连。Step 14, as shown in FIG. 14 , the metal layer 10 below the columnar structure is connected to the electrode 13 of the signal readout circuit 14 through the indium ball 12 .
实施例3Example 3
本发明提供了正面照射式单光子成像的多像素光子计数器的制造方法,适合于长波长光子(如近红外光子)的高灵敏探测与成像,包括以下步骤:The present invention provides a method for manufacturing a multi-pixel photon counter for front-illuminated single-photon imaging, which is suitable for high-sensitivity detection and imaging of long-wavelength photons (such as near-infrared photons), comprising the following steps:
步骤1、准备外延P-外延层的P+型硅衬底,清洗后在P+型硅衬底正反两面热氧化薄而致密的SiO2介质层;Step 1, prepare a P+ type silicon substrate for epitaxial P- epitaxial layer, and after cleaning, thermally oxidize a thin and dense SiO2 dielectric layer on both sides of the P+ type silicon substrate;
步骤2、在P+型硅衬底正面涂抹光刻胶光刻阵列窗口图形,刻蚀掉阵列窗口内的SiO2介质层,通过阵列窗口注入磷离子后形成P+区,去除光刻胶;Step 2, applying photoresist on the front of the P+ type silicon substrate to pattern the array window, etching the SiO2 dielectric layer in the array window, injecting phosphorus ions through the array window to form a P+ region, and removing the photoresist;
步骤3、在P+型硅衬底正面涂抹光刻胶光刻大面积窗口图形,刻蚀掉大面积窗口内的SiO2介质层,通过大面积窗口注入硼离子后形成N++区,去除光刻胶与SiO2介质层;Step 3, applying photoresist on the front of the P+ type silicon substrate to photolithograph a large area window pattern, etching away the SiO2 dielectric layer in the large area window, injecting boron ions through the large area window to form an N++ region, and removing the photoresist and SiO2 dielectric layer;
步骤4、在P+型硅衬底背面注入磷离子后形成全面积的P++层;Step 4, after injecting phosphorus ions on the back side of the P+ type silicon substrate, a full-area P++ layer is formed;
步骤5、通过退火工艺激活离子注入工艺进入P-外延层和P+型硅衬底中的磷离子;Step 5, activating the phosphorus ions implanted into the P-epitaxial layer and the P+ silicon substrate by an annealing process;
步骤6、在P+型硅衬底正面淀积200nm以上的SiO2介质层;Step 6: depositing a SiO2 dielectric layer with a thickness of more than 200 nm on the front side of the P+ type silicon substrate;
步骤7、在P+型硅衬底正面涂抹光刻胶光刻与N++区对准的大面积窗口图形,并刻蚀干净图形内的SiO2;Step 7, apply photoresist on the front of the P+ type silicon substrate to form a large area window pattern aligned with the N++ area, and etch the SiO 2 in the pattern cleanly;
步骤8、正面淀积金属膜;Step 8, depositing a metal film on the front side;
步骤9、在P+型硅衬底正面涂抹光刻胶光刻与P+区对应的阵列窗口图形,并刻蚀掉未被光刻胶保护的金属膜,得到金属网格层;Step 9, applying photoresist on the front side of the P+ type silicon substrate to photoetch an array window pattern corresponding to the P+ area, and etching away the metal film not protected by the photoresist to obtain a metal grid layer;
步骤10、在P+型硅衬底背面淀积金属层;Step 10, depositing a metal layer on the back side of the P+ type silicon substrate;
步骤11、在P+型硅衬底背面涂抹光刻胶光刻若干柱状结构间的隔离沟槽图形;Step 11, applying photoresist on the back side of the P+ type silicon substrate to photoetch isolation groove patterns between a plurality of columnar structures;
步骤12、先刻蚀P+型硅衬底背面未被光刻胶保护的金属层,控制刻蚀时间,然后刻蚀未被光刻胶保护的P+型硅衬底至P-外延层下表面,形成隔离沟槽;Step 12, first etching the metal layer on the back of the P+ type silicon substrate that is not protected by the photoresist, controlling the etching time, and then etching the P+ type silicon substrate that is not protected by the photoresist to the lower surface of the P- epitaxial layer to form an isolation trench;
步骤13、在隔离沟槽内填充绝缘介质;Step 13, filling the isolation trench with an insulating medium;
步骤14、将柱状结构下方的金属层通过铟球与信号读出电路的电极相连。Step 14: Connect the metal layer below the columnar structure to the electrode of the signal readout circuit through the indium ball.
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