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CN1186802C - Surface Planarization of Silicon Thin Films During and After Processing by Sequential Lateral Solidification Method - Google Patents

Surface Planarization of Silicon Thin Films During and After Processing by Sequential Lateral Solidification Method Download PDF

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CN1186802C
CN1186802C CNB008106878A CN00810687A CN1186802C CN 1186802 C CN1186802 C CN 1186802C CN B008106878 A CNB008106878 A CN B008106878A CN 00810687 A CN00810687 A CN 00810687A CN 1186802 C CN1186802 C CN 1186802C
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laser pulse
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CN1363117A (en
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J·S·艾姆
R·S·斯波西利
M·A·克劳德
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Columbia University in the City of New York
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/02Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
    • B23K26/06Shaping the laser beam, e.g. by masks or multi-focusing
    • B23K26/062Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam
    • B23K26/0622Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam by shaping pulses
    • H10P95/00
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    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/02Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
    • B23K26/06Shaping the laser beam, e.g. by masks or multi-focusing
    • B23K26/064Shaping the laser beam, e.g. by masks or multi-focusing by means of optical elements, e.g. lenses, mirrors or prisms
    • B23K26/066Shaping the laser beam, e.g. by masks or multi-focusing by means of optical elements, e.g. lenses, mirrors or prisms by using masks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
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    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/08Devices involving relative movement between laser beam and workpiece
    • B23K26/083Devices involving movement of the workpiece in at least one axial direction
    • B23K26/0853Devices involving movement of the workpiece in at least in two axial directions, e.g. in a plane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/352Working by laser beam, e.g. welding, cutting or boring for surface treatment
    • B23K26/3568Modifying rugosity
    • B23K26/3576Diminishing rugosity, e.g. grinding; Polishing; Smoothing
    • H10P14/3411
    • H10P14/381
    • H10P14/382
    • H10P34/42
    • H10P50/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2101/00Articles made by soldering, welding or cutting
    • B23K2101/36Electric or electronic devices
    • B23K2101/40Semiconductor devices

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Abstract

揭示了减小通过顺序横向固化工艺生产的多晶或单晶薄膜的表面粗糙度的系统和方法。在一个配置中,该系统包括用于产生具有预定注量的多个准分子激光脉冲的准分子激光器(110);用于可控地调节准分子激光脉冲的注量从而使该注量低于使薄膜完全融化所需的注量的能量密度调节器(120);用于把经调节的激光脉冲在一预定平面内均化的光束均化器(144);用于接收均化的激光脉冲以实行使多晶或单晶薄膜的部分相应于激光脉冲局部融化的样品台(170);用于可控地平移样品台(170)相对于激光脉冲的相对位置的平移装置;以及用于以样品台(170)的相对位置协调准分子脉冲的产生和注量调节从而通过样品台(170)相对于激光脉冲的顺序平移来加工多晶或单晶薄膜的计算机(110)。

A system and method for reducing the surface roughness of polycrystalline or single-crystal thin films produced by a sequential transverse curing process are disclosed. In one configuration, the system includes an excimer laser (110) for generating a plurality of excimer laser pulses with predetermined flux amounts; an energy density modulator (120) for controllably adjusting the flux amounts of the excimer laser pulses to a level below that required to completely melt the thin film; a beam homogenizer (144) for homogenizing the adjusted laser pulses in a predetermined plane; a sample stage (170) for receiving the homogenized laser pulses to perform partial local melting of the polycrystalline or single-crystal thin film corresponding to the laser pulses; a translation device for controllably translating the relative position of the sample stage (170) with respect to the laser pulses; and a computer (110) for coordinating the generation and flux amount adjustment of the excimer pulses with the relative position of the sample stage (170) to process the polycrystalline or single-crystal thin film by sequential translation of the sample stage (170) with respect to the laser pulses.

Description

顺序横向固化方法加工期间及其后硅薄膜的表面平面化Surface Planarization of Silicon Thin Films During and After Processing by Sequential Lateral Solidification Method

技术领域technical field

本发明涉及半导体加工技术,尤其涉及可在低温下执行的半导体加工。The present invention relates to semiconductor processing technology, and more particularly to semiconductor processing that can be performed at low temperatures.

背景技术Background technique

在半导体加工领域中,已多次尝试使用激光把非晶硅薄膜转变成多晶薄膜。James Im等人在“Crystalline Si Film for Integrated Active-MatrixLiquid-Crystal Display”(11 MRS Bulletin 39(1996))中概述了传统的准分子激光退火技术。在用于实行准分子激光退火的系统中,使准分子激光束形成长光束,其长度一般长达30cm,且宽度为500微米或更大。使成形的光束在非晶硅样品上进行扫描以促使其融化,并在样品重新固化时形成多晶硅。In the field of semiconductor processing, several attempts have been made to convert amorphous silicon films into polycrystalline films using laser light. Traditional excimer laser annealing techniques are outlined in "Crystalline Si Film for Integrated Active-Matrix Liquid-Crystal Display" (11 MRS Bulletin 39 (1996)) by James Im et al. In systems for performing excimer laser annealing, an excimer laser beam is formed into a long beam, typically up to 30 cm in length and 500 microns or more in width. A shaped beam is scanned over a sample of amorphous silicon to cause it to melt and form polysilicon as the sample resolidifies.

由于某些原因,使用传统的准分子激光退火技术来产生多晶或单晶硅会产生一些问题。首先,此过程中所产生的硅一般是具有任意微观结构的小晶粒,和/或晶粒的大小不均匀,这导致器件较差且不均匀,引起产量降低。其次,为了获得可接受的性能水平所需的加工技术需要把生产多晶硅的生产量保持在较低水平。此外,加工过程通常要求非晶硅样品具有受控气氛及进行预热,这导致生产率进一步降低。最后,所制造的薄膜通常表现出不可接受的表面粗糙度,这也可能对微电子器件的性能产生问题。For several reasons, the use of conventional excimer laser annealing techniques to produce polycrystalline or monocrystalline silicon can be problematic. First, the silicon produced during this process is typically small grains with an arbitrary microstructure, and/or the grains are non-uniform in size, which results in poor and non-uniform devices, resulting in lower yields. Second, the processing techniques required to achieve acceptable performance levels need to keep polysilicon production throughput low. In addition, processing typically requires controlled atmospheres and preheating of amorphous silicon samples, further reducing productivity. Finally, the fabricated films often exhibit unacceptable surface roughness, which can also cause problems for the performance of microelectronic devices.

在本领域中,需要以较大的生产率生产出质量较高的多晶硅和单晶硅薄膜。同时,还需要这样一种制造技术,以减小这些多晶和单晶硅薄膜的表面粗糙度,使之可用于制造诸如平板显示器等质量较高的器件。There is a need in the art to produce higher quality polysilicon and monocrystalline silicon thin films at greater throughput rates. At the same time, there is a need for a fabrication technique that reduces the surface roughness of these polycrystalline and monocrystalline silicon thin films so that they can be used to fabricate higher quality devices such as flat panel displays.

发明内容Contents of the invention

本发明的一个目的是提供使多晶和单晶硅薄膜半导体的表面平面化的技术。An object of the present invention is to provide a technique for planarizing the surface of polycrystalline and monocrystalline silicon thin film semiconductors.

本发明的另一个目的是提供可作为后加工步骤应用于顺序横向固化工艺期间所生产的多晶和单晶硅薄膜半导体的表面平面化技术。Another object of the present invention is to provide a surface planarization technique that can be applied as a post-processing step to polycrystalline and monocrystalline silicon thin film semiconductors produced during a sequential lateral solidification process.

本发明的再一个目的是提供可作为在顺序横向固化工艺中生产多晶和单晶硅薄膜半导体期间的一个加工步骤而应用的表面平面化技术。It is a further object of the present invention to provide a surface planarization technique that can be applied as a processing step during the production of polycrystalline and monocrystalline silicon thin film semiconductors in a sequential lateral solidification process.

本发明的又一个目的是提供制造可用于显示器和其他产品的制造的高质量半导体器件的技术。Yet another object of the present invention is to provide a technique for manufacturing high-quality semiconductor devices that can be used in the manufacture of displays and other products.

为了实现这些和参考以下说明将变得明显起来的其他目的,本发明提供了减小预先通过顺序横向固化工艺生产的多晶或单晶薄膜的表面粗糙度的系统和方法。在一个配置中,该系统包括用于产生具有预定注量(fluence)的多个准分子激光脉冲的准分子激光器;用于可控地调节准分子激光脉冲的注量从而使该注量低于使薄膜完全融化所需的注量的能量密度调节器;用于把经调节的激光脉冲在一预定平面内均化的光束均化器;用于接收均化的激光脉冲以实行使多晶或单晶薄膜的部分相应于均化的激光脉冲局部融化的样品台;用于可控地平移(translate)样品台相对于均化的激光脉冲的相对位置的平移装置;以及用于以样品台的相对位置协调准分子脉冲的产生和注量调节从而通过样品台相对于均化的激光脉冲的顺序平移来加工多晶或单晶薄膜的计算机。准分子激光器最好是用于产生紫外线准分子激光脉冲的紫外线准分子激光器。To accomplish these and other objects that will become apparent with reference to the description that follows, the present invention provides systems and methods for reducing the surface roughness of polycrystalline or monocrystalline thin films previously produced by a sequential lateral solidification process. In one configuration, the system includes an excimer laser for generating a plurality of excimer laser pulses with a predetermined fluence; for controllably adjusting the fluence of the excimer laser pulses such that the fluence is below An energy density adjuster for the fluence required to completely melt the film; a beam homogenizer for homogenizing the adjusted laser pulse in a predetermined plane; for receiving the homogenized laser pulse to perform polycrystalline or The portion of the single crystal thin film corresponds to a sample stage that is locally melted by the homogenized laser pulse; a translation device for controllably translating (translate) the relative position of the sample stage relative to the homogenized laser pulse; A computer that coordinates the generation of excimer pulses and fluence adjustment of relative positions to process polycrystalline or single crystal thin films by sequential translation of the sample stage relative to the homogenized laser pulses. The excimer laser is preferably an ultraviolet excimer laser for generating ultraviolet excimer laser pulses.

在一个配置中,光束均化器可用来使激光脉冲形成沿x和y方向的顶帽(tophat)分布。能量密度调节器可用来使准分子激光脉冲的注量衰减到近似于多晶或单晶薄膜的完全融化阈值的25%到75%。In one configuration, a beam homogenizer can be used to shape the laser pulses into a tophat distribution along the x and y directions. A fluence modulator can be used to decay the fluence of the excimer laser pulse to approximately 25% to 75% of the complete melting threshold of polycrystalline or single crystal thin films.

平移台有利地包括X方向的平移部分和Y方向的平移部分,每一部分都耦合到计算机且相互耦合,并允许沿相对于均化激光脉冲的两个正交方向移动,每一部分可由计算机控制,以沿所述两个正交方向可控地平移样品。此外,光束均化器可用来使所述经调制的激光脉冲形成沿x和y方向的顶帽分布,平移装置可用来沿与所述均化激光脉冲的方向正交的两个方向平移多晶或单晶薄膜,从而顺序均化的激光脉冲沿这两个方向入射到多晶或单晶薄膜的稍稍重叠区。The translation stage advantageously comprises an X-direction translation section and a Y-direction translation section, each section being coupled to the computer and to each other and allowing movement in two orthogonal directions relative to the homogenized laser pulses, each section being computer controllable, to controllably translate the sample in the two orthogonal directions. In addition, a beam homogenizer can be used to shape the modulated laser pulses into a top-hat distribution in the x and y directions, and a translation device can be used to translate the polycrystalline or single crystal thin films, whereby sequentially homogenized laser pulses are incident on slightly overlapping regions of polycrystalline or single crystal thin films along these two directions.

在另一个配置中,本发明提供了用于把非晶硅薄膜样品加工成表面粗糙度减小的多晶或单晶硅薄膜的系统和方法。在一个配置中,该方法包括在厚度足以承受顺序横向固化工艺中硅薄膜的融化和重新固化期间的收缩和膨胀的非晶硅薄膜样品上形成刚性覆盖层。该方法还包括产生一准分子激光脉冲序列;把该序列中的每个准分子激光脉冲可控地调节到预定注量;把该序列中每个经调节的激光脉冲在一预定平面内均化;遮蔽该序列中每个注量受控的均化激光脉冲的部分,以产生一具有被构图的子光束(beamlet)的注量受控的脉冲序列;以此注量受控的被构图的子光束序列辐照非晶硅薄膜样品,以使其部分融化;相对于具有被构图的子光束的每个所述注量受控的脉冲可控地顺序平移样品,从而把非晶硅薄膜样品加工成表面粗糙度减小的单晶或多晶硅薄膜;以及从所加工的单晶或多晶硅薄膜上除去所述覆盖层。In another configuration, the present invention provides systems and methods for processing amorphous silicon thin film samples into polycrystalline or single crystal silicon thin films with reduced surface roughness. In one configuration, the method includes forming a rigid capping layer on an amorphous silicon film sample thick enough to withstand shrinkage and expansion during melting and re-solidification of the silicon film in a sequential lateral solidification process. The method also includes generating a sequence of excimer laser pulses; controllably adjusting each excimer laser pulse in the sequence to a predetermined fluence; averaging each adjusted laser pulse in the sequence in a predetermined plane ; mask the portion of each fluence-controlled homogenization laser pulse in the sequence to produce a fluence-controlled pulse train with patterned sub-beams (beamlets); The sub-beam sequence irradiates the amorphous silicon thin film sample to partially melt it; the sample is controllably sequentially translated with respect to each of said fluence-controlled pulses with the patterned sub-beam, thereby turning the amorphous silicon thin film sample processing to a single crystal or polycrystalline silicon film with reduced surface roughness; and removing the capping layer from the processed single crystal or polycrystalline silicon film.

结合在本说明书中并构成其一部分的附图示出本发明的较佳实施例,且用来说明本发明的原理。The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate preferred embodiments of the invention and serve to explain the principles of the invention.

附图概述Figure overview

图1是用于执行对实现本发明的较佳工艺来实行较佳的顺序横向固化工艺的系统的功能图;Figure 1 is a functional diagram of a system for performing a preferred sequential lateral curing process for implementing the preferred process of the present invention;

图2是示出已被图1的顺序横向固化系统加工的典型薄膜的表面分布的图表;Figure 2 is a graph showing the surface profile of a typical film that has been processed by the sequential lateral curing system of Figure 1;

图3是依据本发明用于对顺序横向固化工艺期间产生的多晶或单晶薄膜的表面进行平面化的较佳系统的功能图;3 is a functional diagram of a preferred system for planarizing the surface of polycrystalline or monocrystalline thin films produced during a sequential lateral solidification process in accordance with the present invention;

图4a和4b是待由图3的系统使用窄光束加工的晶化硅膜的示意图;4a and 4b are schematic diagrams of a crystallized silicon film to be processed by the system of FIG. 3 using a narrow beam;

图5是待由图3的系统使用宽光束加工的晶化硅膜的示意图;5 is a schematic diagram of a crystallized silicon film to be processed by the system of FIG. 3 using a broad beam;

图6-7是示出图3的系统加工前后典型薄膜的表面分布的图表;6-7 are graphs showing the surface profiles of typical thin films before and after processing of the system of FIG. 3;

图8是依据本发明第二实施例的图1的系统所加工的晶化硅膜的剖面的示意图;8 is a schematic diagram of a cross-section of a crystalline silicon film processed by the system of FIG. 1 according to a second embodiment of the present invention;

图9是示出已依据本发明第二实施例加工的典型薄膜的表面分布的图表;Figure 9 is a graph showing the surface distribution of a typical film that has been processed according to a second embodiment of the present invention;

图10是示出依据本发明第一实施例在图3的系统中所实行的步骤的流程图;以及FIG. 10 is a flowchart showing the steps performed in the system of FIG. 3 according to the first embodiment of the present invention; and

图11是示出依据本发明第二实施例在图1的系统中实行的步骤的流程图。FIG. 11 is a flow chart showing steps performed in the system of FIG. 1 according to a second embodiment of the present invention.

本发明的较佳实施方式Preferred Embodiments of the Invention

本发明提供了使多晶和单晶薄膜半导体的表面平面化的技术。在较佳实施例中,把表面平面化技术用作在顺序横向固化工艺期间生产的多晶和单晶薄膜半导体的后加工步骤,或用作在顺序横向固化工艺中生产多晶和单晶薄膜半导体期间的加工步骤。相应地,为了完全理解这些技术,必须首先理解顺序横向固化工艺。The present invention provides techniques for planarizing the surface of polycrystalline and single crystalline thin film semiconductors. In a preferred embodiment, the surface planarization technique is used as a post-processing step for polycrystalline and monocrystalline thin film semiconductors produced during a sequential lateral solidification process, or as a method for producing polycrystalline and monocrystalline thin films during a sequential lateral solidification process Processing steps during semiconductor. Accordingly, in order to fully understand these techniques, one must first understand the sequential lateral curing process.

顺序横向固化工艺是一种通过使硅样品在准分子激光器发射的顺序脉冲中间小刻度地单向平移而产生大晶粒的硅结构的技术。在每个脉冲被样品吸收时,使样品的小区域完全融化,且沿横向重新固化成由一脉冲组的在先脉冲所产生的晶体区。The sequential lateral solidification process is a technique that produces large-grained silicon structures by making the silicon sample translate in small increments in one direction in the middle of sequential pulses emitted by an excimer laser. As each pulse is absorbed by the sample, a small region of the sample is completely melted and laterally resolidified into the crystalline region produced by the preceding pulse of a pulse set.

在我们1999年9月3日提交的题为“Systems and Methods usingSequential Lateral Solidification for Producing Single orPolycrystalline Silicon Thin Films at Low Temperatures”的共同待批专利申请09/390,537中,揭示了一种特别优越的顺序横向固化工艺以及执行该工艺的设备,在此引用作为参考。尽管上述技术的揭示是针对我们的共同待批专利申请中所述的特定技术来进行的,但应理解,可容易地将其它顺序横向固化技术应用于本发明。A particularly advantageous sequential lateral The curing process, as well as the equipment for performing the process, are incorporated herein by reference. Although the disclosure of the above techniques has been made with respect to the particular technique described in our co-pending patent application, it should be understood that other sequential lateral curing techniques can be readily applied to the present invention.

参考图1,我们的共同待批专利申请把一系统描述为较佳实施例,该系统包括准分子激光器110、快速地改变激光束111的能量密度的能量密度调节器120、光束衰减和光闸130、光学元件140、141、142和143、光束均化器144、透镜系统145、146和148、遮蔽系统150、透镜系统161、162、163、入射激光脉冲164、硅薄膜样品170、样品平移台180、花岗石块190、支撑系统191、192、193、194、195、196以及管理计算机100。可在计算机100的指挥下,通过遮蔽系统150内掩模710的移动或样品平移台180的移动来实现硅样品170的X和Y方向的平移。Referring to FIG. 1, our co-pending patent application describes as a preferred embodiment a system comprising an excimer laser 110, a fluence modulator 120 to rapidly vary the fluence of the laser beam 111, beam attenuation and a shutter 130 , optical elements 140, 141, 142 and 143, beam homogenizer 144, lens systems 145, 146 and 148, shielding system 150, lens systems 161, 162, 163, incident laser pulse 164, silicon thin film sample 170, sample translation stage 180 , granite block 190 , support systems 191 , 192 , 193 , 194 , 195 , 196 and management computer 100 . The translation of the silicon sample 170 in the X and Y directions can be achieved by moving the mask 710 in the masking system 150 or the movement of the sample translation stage 180 under the command of the computer 100 .

如我们的共同待批专利申请中所述,把非晶硅薄膜样品加工成单晶或多晶硅薄膜是通过:产生具有预定注量的多个准分子激光脉冲;可控地调节准分子激光脉冲的注量;把经调节的激光脉冲在一预定平面内均化;遮蔽经均化调节的激光脉冲的部分,而使之成为被构图的子光束;用被构图的子光束辐照非晶硅薄膜样品,使其部分相应于子光束而融化;以及相对于经构图的子光束且相对于可控调节可控地平移样品,从而通过相对于经构图的子光束顺序平移样品,以及通过在样品上的相应顺序位置处以注量变化的经构图的子光束辐照样品,把非晶硅薄膜样品加工成单晶或多晶硅薄膜。As described in our co-pending patent application, samples of amorphous silicon thin films are processed into single crystal or polycrystalline silicon thin films by: generating multiple excimer laser pulses with a predetermined fluence; Flux; average the adjusted laser pulse in a predetermined plane; shield the part of the averaged adjusted laser pulse to make it a patterned sub-beam; irradiate the amorphous silicon film with the patterned sub-beam the sample, having portions thereof melted corresponding to the beamlets; and controllably translating the sample relative to the patterned beamlets and with respect to the controllable adjustment, by sequentially translating the sample relative to the patterned beamlets, and by The sample is irradiated with patterned sub-beams with varying fluence at the corresponding sequential positions, and the amorphous silicon thin film sample is processed into a single crystal or polycrystalline silicon thin film.

虽然顺序横向固化工艺在产生单晶或大晶粒的多晶硅薄膜方面是非常有利的,但是所产生的晶体通常因晶体生长过程中固有的融化和固化的无理性本质而表现得表面粗糙。因而,如图2所示,一200nm厚的晶体将表现出在整个晶体长度上的高度变化。在图2中,高度0指示200nm厚的晶体中的最佳高度,在整个晶体长度上,从175nm变到225nm的高度被示为是平常的。注意,大凸起210靠近晶体的边界,在这里晶体厚度比200nm的最佳厚度超过350nm。While the sequential lateral solidification process is highly advantageous in producing single crystal or large-grain polysilicon thin films, the resulting crystals often exhibit rough surfaces due to the irrational nature of melting and solidification inherent in the crystal growth process. Thus, as shown in Figure 2, a 200nm thick crystal will exhibit height variations throughout the crystal length. In Figure 2, a height of 0 indicates the optimum height in a 200nm thick crystal, heights varying from 175nm to 225nm are shown to be common throughout the crystal length. Note that the large bump 210 is close to the boundary of the crystal where the crystal thickness is more than 350nm from the optimum thickness of 200nm.

参考图3和4,现在将描述本发明的第一实施例。图3示出用于对通过顺序横向固化工艺产生的多晶和单晶薄膜半导体进行平面化的后加工系统。该系统包括准分子激光器310、光束衰减器和光闸320、反射板330、收缩式透镜331、332、反射板333、光束均化器340、聚光透镜345、反射板347、向场(field)透镜350、样品360、样品平移台370、光学工作台380和管理计算机300。较佳的激光器310、衰减器320、收缩式透镜331、332、均化器340和能在正交方向移动样品平移台370在09/390,537号共同待批专利申请中都已作了描述。工作台380可以是该专利文件中所述的,或者可以是普通工作台。最好,使均化的光束346形成沿x和y方向的顶帽分布,光束能量密度必须低于使样品360完全融化所需的能量密度。Referring to Figures 3 and 4, a first embodiment of the present invention will now be described. Figure 3 shows a post-processing system for planarizing polycrystalline and single crystalline thin film semiconductors produced by a sequential lateral solidification process. The system includes an excimer laser 310, a beam attenuator and a shutter 320, a reflector 330, shrinkable lenses 331, 332, a reflector 333, a beam homogenizer 340, a condenser lens 345, a reflector 347, and a field (field) A lens 350 , a sample 360 , a sample translation stage 370 , an optical workbench 380 and a management computer 300 . A preferred laser 310, attenuator 320, pinch lenses 331, 332, homogenizer 340, and sample translation stage 370 capable of moving in orthogonal directions are all described in copending application Ser. No. 09/390,537. Workbench 380 may be as described in this patent document, or may be a common workbench. Preferably, for the homogenized beam 346 to form a top hat distribution in the x and y directions, the beam fluence must be lower than that required to completely melt the sample 360 .

参考图4a和4b,更详细地示出样品360。由于本实施例中的样品已经过加工,所以它已包括大量单晶区域,它们被示意地示为山形晶体365。所示的均化光束346入射到样品360的一部分361上,以使其局部融化。Referring to Figures 4a and 4b, the sample 360 is shown in more detail. As the sample in this example has been processed, it already includes a large number of single crystal regions, which are shown schematically as mountain-shaped crystals 365 . A homogenized beam 346 is shown incident on a portion 361 of a sample 360 to locally melt it.

对于200nm厚的硅薄膜,完全融化阈值近似于600mJ/cm2。因而,为了引起部分361的充分局部融化,应利用能量近似于完全融化阈值的25%到75%的光束346。如果该光束的能量更高,则准分子激光器中固有的能量波动将引起样品区域361完全融化的可能性。如果光束能量较低,则样品部分361将不能充分融化而达到令人满意的平面化。For a 200nm thick silicon film, the complete melting threshold is approximately 600mJ/cm2. Thus, to induce sufficiently localized melting of portion 361, beam 346 with an energy approximately 25% to 75% of the complete melting threshold should be utilized. If the energy of the beam is higher, the energy fluctuations inherent in excimer lasers will give rise to the possibility of complete melting of the sample region 361 . If the beam energy is low, sample portion 361 will not melt sufficiently to achieve satisfactory planarization.

如图4b所示,样品360包括氧化硅基底层400和硅层410。依据本发明,使硅层410的外表面融化到深度420。在重新固化时,粗糙表面430以更平面化的方式重整。As shown in FIG. 4 b , the sample 360 includes a silicon oxide base layer 400 and a silicon layer 410 . According to the invention, the outer surface of the silicon layer 410 is melted to a depth 420 . Upon re-solidification, rough surface 430 reforms in a more planar manner.

虽然能量近似于完全融化阈值的25%到75%的单个均化光束脉冲足以引起区域361的局部融化,但最好以多个光束脉冲辐照每个这样的区域。每个随后的光束脉冲将引起区域361的局部融化,据此重新固化将表现出更平面化的表面。因而,与使用单个脉冲相比,对每个区域361使用十个光束脉冲将产生光滑得多的表面。While a single homogenizing beam pulse of energy approximately 25% to 75% of the complete melting threshold is sufficient to cause localized melting of region 361, it is preferable to irradiate each such region with multiple beam pulses. Each subsequent beam pulse will cause localized melting of the region 361 whereby the re-solidification will exhibit a more planarized surface. Thus, using ten beam pulses per region 361 will produce a much smoother surface than using a single pulse.

回到图4a,在计算机300的控制下,把样品台370从右向左平移,以使均化光束346在样品360的顶部从左到右进行扫描450。然后,沿正交方向(示为Y方向)移动平台370以使样品重新定位在一新的位置460,并开始沿相反方向平移470。重复此过程,直到样品360的整个表面已被均化光束346扫描。Returning to FIG. 4 a , under the control of the computer 300 , the sample stage 370 is translated from right to left so that the homogenized beam 346 is scanned 450 from left to right on top of the sample 360 . Then, the platform 370 is moved in an orthogonal direction (shown as the Y direction) to reposition the sample in a new position 460, and translation 470 is initiated in the opposite direction. This process is repeated until the entire surface of the sample 360 has been scanned by the homogenizing beam 346 .

当沿Y方向平移样品台时,有利的是对准均化光束,以与样品360先前扫描的区域稍稍重叠。因而,如果区域361为1.2×1.2cm,则可利用1.15cm的Y方向平移来避免均化光束不规则所引起的边缘效应。同样,有利的是,与X方向的平移稍稍重叠。When translating the sample stage in the Y direction, it is advantageous to align the homogenizing beam to slightly overlap the area of the sample 360 that was previously scanned. Thus, if the area 361 is 1.2 x 1.2 cm, a Y-direction translation of 1.15 cm can be used to avoid edge effects caused by irregularities in the homogenized beam. Also, advantageously, there is a slight overlap with the translation in the X direction.

虽然以上相对于顶帽分布的方形均化光束进行了描述,但可利用其他形状的光束。因而,如图5所示,可利用宽到足以消除X方向平移需要的宽的均化光束500,其优点是使平移台360所需的移动较少,继而较大生产量。同样,如果在X平移之间进行较大的重叠,则可利用以沿X方向的高斯分布成形的光束。Although described above with respect to a square homogenized beam of top-hat distribution, other shaped beams may be utilized. Thus, as shown in FIG. 5, a homogenized beam 500 that is wide enough to eliminate the need for translation in the X direction can be utilized, with the advantage of requiring less movement of the translation stage 360 and thus greater throughput. Also, beams shaped with a Gaussian distribution along the X direction can be utilized if there is a large overlap between X translations.

如图6-7所示,示出参考图3-4a所述的工艺的结果。在图6a中示出依据顺序横向固化工艺制造的样品360的分布。该样品表现出离最佳200nm高度有+/-25nm的表面不规则度。如图6b所示,在依据本发明以单个激光脉冲进行后加工后,明显地减少了这些表面不规则。在图7中也示出这些结果,其中示出依据本发明的后加工所引起的表面粗糙度降低了超过100%。As shown in Figures 6-7, the results of the process described with reference to Figures 3-4a are shown. The distribution of samples 360 fabricated according to the sequential lateral curing process is shown in Fig. 6a. The sample exhibited surface irregularities +/- 25nm from the optimum 200nm height. As shown in Figure 6b, these surface irregularities are significantly reduced after post-processing according to the invention with a single laser pulse. These results are also shown in FIG. 7 , which shows a reduction in surface roughness of more than 100% as a result of the post-processing according to the invention.

再参考图8,将描述本发明的第二实施例。在本实施例中,通过在顺序横向固化工艺期间利用刚性覆盖层保持了硅薄膜表面的平面化。因而,图8示出由淀积在氧化硅基底层820上的近似50-200nm厚的非晶硅层810所形成的薄的硅样品。该样品覆盖有一厚的第二氧化硅层820,它近似2微米厚,且基本上是刚性的。覆盖层必须足够厚,以承受顺序横向固化工艺中硅层融化和成形固化期间的收缩和膨胀。Referring again to Fig. 8, a second embodiment of the present invention will be described. In this embodiment, the planarization of the silicon thin film surface is maintained by utilizing a rigid capping layer during the sequential lateral curing process. Thus, FIG. 8 shows a thin silicon sample formed from an approximately 50-200 nm thick amorphous silicon layer 810 deposited on a silicon oxide base layer 820 . The sample was covered with a thick second silicon oxide layer 820 which was approximately 2 microns thick and was substantially rigid. The overlay must be thick enough to withstand the shrinkage and expansion during the melting and shaping cure of the silicon layer during the sequential lateral curing process.

然后,替代样品170,在横向固化工艺中使用具有覆盖层830的样品,其完整描述包含在上述09/390,537号专利申请中。在此加工后,通过传统的湿式或干式蚀刻技术从样品上除去覆盖层830。如图9所示,示出参考图8所述的工艺的结果。Then, instead of sample 170, a sample with cover layer 830 was used in the lateral curing process, the full description of which is contained in the above-mentioned Ser. No. 09/390,537. After this processing, the capping layer 830 is removed from the sample by conventional wet or dry etching techniques. As shown in FIG. 9 , the result of the process described with reference to FIG. 8 is shown.

参考图10,将描述计算机300为控制图1的顺序横向固化工艺以及相对于图3所实行的表面平面化工艺而执行的步骤。由计算机300对系统的各电子设备进行初始化1000,以开始该工艺。然后,把样品装到样品平移台上1005。应注意,这种装载可以是手工的,或者是在计算机300的控制下自动地实现。接着,使用图1的设备依据顺序横向固化工艺对样品进行加工1010。把经加工的样品定位,以进行平面化1015。在必要时,使系统的各光学元件聚焦1020。然后,把激光器稳定到依据本发明的技术局部融化样品所需的能量水平和可靠率1025。如果需要,对激光脉冲的衰减进行细调1030。Referring to FIG. 10 , the steps performed by computer 300 to control the sequential lateral curing process of FIG. 1 and the surface planarization process performed with respect to FIG. 3 will be described. The electronics of the system are initialized 1000 by computer 300 to begin the process. Then, the sample is loaded onto the sample translation stage 1005 . It should be noted that this loading can be done manually or automatically under the control of computer 300 . Next, the sample is processed 1010 using the apparatus of FIG. 1 according to a sequential lateral curing process. The processed sample is positioned for planarization 1015. Optical elements of the system are brought into focus 1020 as necessary. The laser is then stabilized 1025 to the power level and reliability required to locally melt the sample according to the techniques of the present invention. Fine-tuning 1030 is made to the attenuation of the laser pulses, if desired.

接着,依据先前经顺序横向固化加工的样品区域,以预定的速度沿预定方向开始样品的平移1035。打开光闸1040,以使样品暴露于辐照并相应地开始平面化工艺。Next, translation 1035 of the sample is started at a predetermined speed along a predetermined direction according to the sample region previously processed by sequential lateral curing. The shutter 1040 is opened to expose the sample to radiation and start the planarization process accordingly.

继续样品平移和辐照,直到平面化已完成1045,105,此时计算机关闭光闸并停止平移1055、1060。如果指定对样品上的其他区域进行平面化,则把样品重新定位1065、1066,并在此新的区域上重复该工艺。如果指定没有区域需要平面化,则断开激光器1070,断开硬件1075,结束此工艺1080。Sample translation and irradiation is continued until planarization has been completed 1045, 105, at which point the computer closes the shutter and stops translation 1055, 1060. If other areas on the sample are specified to be planarized, the sample is repositioned 1065, 1066 and the process is repeated on this new area. If it is specified that no areas need to be planarized, then the laser is turned off 1070, the hardware is turned off 1075, and the process ends 1080.

接着参考图11,将描述计算机100以相对于图1实行的表面平面化步骤控制晶体生长过程所执行的步骤。图10是示出在图1的系统中使用图8所示的被覆盖样品所实行的基本步骤。在基底1100上淀积氧化层。然后,在氧化物缓冲层1110上淀积硅层,在样品1120的顶层淀积覆盖氧化物。Referring next to FIG. 11 , the steps performed by the computer 100 to control the crystal growth process with respect to the surface planarization step performed with respect to FIG. 1 will be described. FIG. 10 is a diagram illustrating the basic steps performed in the system of FIG. 1 using the covered sample shown in FIG. 8 . An oxide layer is deposited on the substrate 1100 . Then, a silicon layer is deposited on the oxide buffer layer 1110 and a capping oxide is deposited on top of the sample 1120 .

接着,使用图1的设备依据顺序横向固化工艺对样品进行加工。在加工后,例如通过稀释的氢氟酸溶液除去覆盖氧化物。Next, the samples were processed according to the sequential lateral curing process using the equipment of Figure 1. After processing, the covering oxide is removed, for example, by dilute hydrofluoric acid solution.

以上仅说明了本发明的原理。根据这里的公开,对所述实施例的各种修改和变化将对本领域内的技术人员变得明显起来。例如,虽然已揭示了使用稀释的氢氟酸溶液来除去覆盖层,但可通过诸如干式蚀刻等任何常规技术来除去覆盖层。因而,可理解,虽然这里未明确地示出或描述,但本领域内的技术人员能设计出实现本发明原理继而在本发明精神和范围内的各种系统和方法。The foregoing merely illustrates the principles of the invention. Various modifications and alterations to the described embodiments will become apparent to those skilled in the art from the disclosure herein. For example, although a dilute hydrofluoric acid solution has been disclosed for removal of the overburden, the overburden may be removed by any conventional technique, such as dry etching. It will thus be appreciated that those skilled in the art can devise various systems and methods which, although not explicitly shown or described herein, embody the principles of the invention while remaining within the spirit and scope of the invention.

Claims (21)

1. system that is used to reduce the surface roughness of polycrystalline by the sequential lateral solidifcation explained hereafter or monocrystal thin films comprises:
(a) excimer laser is used to produce a plurality of quasi-molecule laser pulses with predetermined fluence;
(b) optical coupled is to the energy density adjuster of described excimer laser, be used for controllably regulating the fluence of the described quasi-molecule laser pulse of described excimer laser emission, thereby described fluence is lower than and makes described polycrystalline or monocrystal thin films melt required fluence fully;
(c) be coupled to the beam homogenizer of described energy density adjuster optically, be used for described laser pulse homogenizing in a predetermined plane through regulating;
(d) sample stage is used to receive the laser pulse of described homogenizing, so that the part of described polycrystalline or monocrystal thin films is corresponding to the laser pulse of described homogenizing and local the thawing;
(e) be coupled to the translating device of described sample stage, be used for the relative position of the described sample stage of controllably translation with respect to the laser pulse of described homogenizing; And
(f) be coupled to described excimer laser, the computer of described energy density adjuster and described translating device, be used to control the controlled fluence adjusting of described quasi-molecule laser pulse and the described controlled relative position of described sample stage and described homogenizing laser pulse, and the generation of described quasi-molecule pulse and the adjusting of described fluence are coordinated with the described relative position of described sample stage and described homogenizing laser pulse, thereby pass through with respect to the described sample stage of described homogenizing laser pulse order translation, the respective sequence position on described polycrystalline or monocrystal thin films processes it.
2. the system as claimed in claim 1 is characterized in that described excimer laser is the ultraviolet excimer laser that is used to produce ultraviolet quasi-molecule laser pulse.
3. the system as claimed in claim 1 is characterized in that described beam homogenizer can be used to make described laser pulse to form along the top cap of x and y direction and distributes.
4. the system as claimed in claim 1 is characterized in that described energy density adjuster can be used to make that the described fluence of described quasi-molecule laser pulse decays to described polycrystalline or monocrystal thin films melts 25% to 75% of threshold value fully.
5. the system as claimed in claim 1, it is characterized in that described sample stage comprises Y direction translating sections, described Y direction translating sections, allow to move along direction with described homogenizing laser pulse quadrature, and can be by described computer control, with along described orthogonal direction controllably described polycrystalline of translation or monocrystal thin films.
6. system as claimed in claim 5, it is characterized in that described beam homogenizer can be used to make described modulated laser pulse to form at least along the top cap with the described direction of the direction quadrature of described modulated laser pulse and distributes, described translating device can be used to along with the described polycrystalline of described direction translation or the monocrystal thin films of the direction quadrature of described modulated laser pulse, thereby the laser pulse of order homogenizing incides on the overlapping region slightly of described polycrystalline or monocrystal thin films.
7. the system as claimed in claim 1, it is characterized in that described sample stage comprises directions X translating sections and Y direction translating sections, each part all is coupled to described computer and intercouples, described X and Y direction translating sections allow to move along two orthogonal directions with respect to described homogenizing laser pulse, each part can be by described computer control, with along described two orthogonal directions described sample of translation controllably.
8. system as claimed in claim 7, it is characterized in that described beam homogenizer can be used to make described modulated laser pulse to form along the top cap of x and y direction and distributes, described translating device can be used to along with the described polycrystalline of both direction translation or the monocrystal thin films of the direction quadrature of described homogenizing laser pulse, thereby the laser pulse of order homogenizing incides on the overlapping region slightly of described polycrystalline or monocrystal thin films along described both direction.
9. method that is used to reduce the surface roughness of polycrystalline by the sequential lateral solidifcation explained hereafter or monocrystal thin films may further comprise the steps:
(a) produce a plurality of quasi-molecule laser pulses with predetermined fluence;
(b) controllably regulate the fluence of the described quasi-molecule laser pulse of described excimer laser emission, thereby described fluence is lower than and makes described polycrystalline or monocrystal thin films melt required fluence fully;
(c) described laser pulse homogenizing in a predetermined plane through regulating;
(d) part that makes described polycrystalline or monocrystal thin films is corresponding to the laser pulse of described homogenizing and local the thawing;
(e) controllably described polycrystalline of translation or monocrystal thin films with respect to the relative position of described homogenizing laser pulse, with by with respect to the described sample stage of described homogenizing laser pulse order translation, the respective sequence position on described polycrystalline or monocrystal thin films processes it.
10. method as claimed in claim 9 is characterized in that described quasi-molecule laser pulse comprises ultraviolet quasi-molecule laser pulse.
11. method as claimed in claim 9 is characterized in that described homogenization step comprises that described modulated laser pulse is all changed into the top cap that has along x and y direction to distribute.
12. method as claimed in claim 9, what it is characterized in that described regulating step comprises that the described fluence that makes described quasi-molecule laser pulse decays to described polycrystalline or monocrystal thin films melts 25% to 75% of threshold value fully.
13. method as claimed in claim 9, it is characterized in that described translation step comprise along with a direction of the direction quadrature of described homogenizing laser pulse controllably described polycrystalline of translation or monocrystal thin films.
14. method as claimed in claim 13, it is characterized in that described homogenization step comprises that described modulated laser pulse is all changed into the top cap that has at least along with the described direction of the direction quadrature of described modulated laser pulse to distribute, described translation step comprise along with the described polycrystalline of described direction translation or the monocrystal thin films of the direction quadrature of described homogenizing laser pulse, thereby the laser pulse of order homogenizing incides on the overlapping region slightly of described polycrystalline or monocrystal thin films.
15. method as claimed in claim 9 is characterized in that described translation step comprises edge two orthogonal directions vertical with described homogenizing path that laser pulse forms controllably described polycrystalline of translation or monocrystal thin films.
16. method as claimed in claim 15, it is characterized in that described homogenization step comprises that the top cap that described modulated laser pulse is all changed on the described both direction that has with the direction quadrature of described modulated laser pulse distributes, described translation step comprise along with the described polycrystalline of both direction translation or the monocrystal thin films of the direction quadrature of described homogenizing laser pulse, thereby incide on the overlapping region slightly of described polycrystalline or monocrystal thin films along described both direction through the laser pulse of order homogenizing.
17. method as claimed in claim 9, it is characterized in that the described part of described translation step described polycrystalline that has been included at least two homogenizing laser pulse irradiation or monocrystal thin films after, described polycrystalline of translation or monocrystal thin films.
18. one kind is used for the amorphous silicon membrane sample is processed into the monocrystalline that surface roughness reduces or the method for polysilicon membrane, may further comprise the steps:
(a) be enough to bear that described silicon thin film is melting and form the rigidity cover layer on the amorphous silicon membrane sample of the pucker ﹠ bloat of setting up period again at thickness;
(b) produce an excimer laser pulse train;
(c) each quasi-molecule laser pulse in the described sequence controllably is adjusted to predetermined fluence;
(d) each laser pulse homogenizing in a predetermined plane in the described sequence through regulating;
(e) cover the part of the controlled homogenizing laser pulse of each fluence in the described sequence, have the controlled pulse train of fluence of patterned beamlet to produce one;
(f),, the part of described amorphous silicon membrane sample is melted with corresponding to the controlled patterned beamlet pulse of each fluence in the described pulse train of patterned beamlet with the controlled patterned beamlet sequence irradiation amorphous silicon membrane sample of described fluence;
(g) with respect to through the controlled pulse of each described fluence of patterned beamlet, the described sample of order translation controllably, thus described amorphous silicon membrane sample is processed into monocrystalline or polysilicon membrane; And
(h) remove described cover layer from described monocrystalline or polysilicon membrane.
19. method as claimed in claim 18 is characterized in that described quasi-molecule laser pulse comprises ultraviolet quasi-molecule laser pulse.
20. method as claimed in claim 18 is characterized in that being included on the described amorphous silicon membrane sample and forming silicon oxide layer forming the tectal described step of rigidity on the described amorphous silicon membrane sample.
21. method as claimed in claim 18 is characterized in that forming the silicon oxide layer that the tectal described step of rigidity is included in formation 2 micron thickness on the described amorphous silicon membrane sample on the described amorphous silicon membrane sample.
CNB008106878A 2000-03-21 2000-03-21 Surface Planarization of Silicon Thin Films During and After Processing by Sequential Lateral Solidification Method Expired - Fee Related CN1186802C (en)

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