CN1184523A - Exhaust purification device for internal combustion engines - Google Patents
Exhaust purification device for internal combustion engines Download PDFInfo
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- CN1184523A CN1184523A CN96193993A CN96193993A CN1184523A CN 1184523 A CN1184523 A CN 1184523A CN 96193993 A CN96193993 A CN 96193993A CN 96193993 A CN96193993 A CN 96193993A CN 1184523 A CN1184523 A CN 1184523A
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- 238000002485 combustion reaction Methods 0.000 title claims description 49
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2807—Metal other than sintered metal
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N1/00—Silencing apparatus characterised by method of silencing
- F01N1/08—Silencing apparatus characterised by method of silencing by reducing exhaust energy by throttling or whirling
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
- F01N13/009—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
- F01N13/0097—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series the purifying devices are arranged in a single housing
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2260/00—Exhaust treating devices having provisions not otherwise provided for
- F01N2260/10—Exhaust treating devices having provisions not otherwise provided for for avoiding stress caused by expansions or contractions due to temperature variations
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2470/00—Structure or shape of gas passages, pipes or tubes
- F01N2470/02—Tubes being perforated
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2470/00—Structure or shape of gas passages, pipes or tubes
- F01N2470/24—Concentric tubes or tubes being concentric to housing, e.g. telescopically assembled
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Exhaust Gas After Treatment (AREA)
- Exhaust Silencers (AREA)
Abstract
排气净化装置,在从发动机(3)的排气口(4)延伸的排气管(5)断面的中央部位,设置有带催化剂金属的薄壁钢板(22)。即是说,由于在排气温度比较高的排气管(5)断面的中央部位配置催化剂金属,因此除了能够充分发挥排出气体的净化作用之外,还可以使装置低成本化。
The exhaust purification device is provided with a thin-walled steel plate (22) with catalyst metal on the central part of the section of the exhaust pipe (5) extending from the exhaust port (4) of the engine (3). That is to say, since the catalyst metal is arranged at the central part of the cross-section of the exhaust pipe (5) where the exhaust temperature is relatively high, in addition to fully exerting the purifying effect of the exhaust gas, the cost of the device can also be reduced.
Description
技术领域technical field
本发明涉及一种用于净化从内燃机即发动机排出的排出气体的排气净化装置的改进。The present invention relates to an improvement of an exhaust gas cleaning device for cleaning exhaust gases from an internal combustion engine, ie, an engine.
背景技术Background technique
以往,作为内燃机的排气净化装置,例如日本特许公开平第3-85316号公报所揭示的“内燃机的排气净化装置”及日本特许公开平第4-287821号公报所公开的“摩托车等的排气净化装置”,已是公开技术。Conventionally, as an exhaust purification device for an internal combustion engine, for example, "exhaust purification device for an internal combustion engine" disclosed in Japanese Patent Publication No. 3-85316 and "motorcycle, etc." disclosed in Japanese Patent Publication No. 4-287821. Exhaust purification device" is a public technology.
上述日本特许公开平第3-85316号公报所揭示的“内燃机的排气净化装置”如图17及图18所示,排气管100与安装在摩托车等上的小型内燃机的排气口相连,沿着该排气管100的内壁设置有以与排气管100相同方向延伸的由多孔板制成的内管101,在该内管101的壁面上附有含催化剂载体102。The above-mentioned Japanese Patent Publication No. 3-85316 discloses the "exhaust gas purification device for an internal combustion engine" as shown in Figures 17 and 18. The
上述日本特许公开平第4-287821号公报所公开的“摩托车等的排气净化装置”如图19、图20及图21所示,排气消声器110与安装在摩托车等上的小型内燃机的排气口相连,该排气消声器(相当于排气管)110的断面中央部设置有催化剂管111,在该催化剂管111内安装有催化剂本体112。催化剂本体112在蜂窝状结构的催化剂元件上附着有催化剂物质。The "exhaust purification device for motorcycles and the like" disclosed in the above-mentioned Japanese Patent Publication No. 4-287821 is shown in Fig. 19, Fig. 20 and Fig. 21. The exhaust port of the exhaust muffler (corresponding to the exhaust pipe) 110 is provided with a
一般来说,为了充分发挥催化剂的活性化作用,必须使催化剂在高温下活性化。但是,对于小型内燃机来说,为了达到催化剂活性化的程度而提高排气温度是很困难的。为此,不仅需要考虑尽可能提高催化剂的温度,而且还需要考虑经过排气管流动的排出气体温度在管的断面中央部位比较高,而在管壁附近相对较低的这一事实。In general, in order to fully exert the activation effect of the catalyst, it is necessary to activate the catalyst at a high temperature. However, for small internal combustion engines, it is difficult to increase the exhaust gas temperature to the extent that the catalyst is activated. Therefore, it is necessary not only to increase the temperature of the catalyst as much as possible, but also to consider the fact that the temperature of the exhaust gas flowing through the exhaust pipe is relatively high in the center of the cross section of the pipe and relatively low near the pipe wall.
但是,图17及图18所示的“内燃机的排出气体的净化装置”,由于沿排气管100的内壁设有带催化剂的内管101,因而很难充分发挥净化作用。However, the "exhaust gas purification device of an internal combustion engine" shown in Fig. 17 and Fig. 18 has a catalyst-carrying
图19~图21所示的“摩托车等的排气净化装置”,在排气消声器110断面的中央部位设置有催化剂本体112,由于排气温度比较高,很容易发挥净化作用。但是,由蜂窝状结构的催化剂元件构成的催化剂本体112,与上述图17及图18所示的多孔板制成的内管101相比较,其压力损失大,经过排气消声器110流动的排出气体的流速在管断面中央部位比较高,因而压力损失更大。结果,压力损失给内燃机性能带来很大影响,特别是对摩托车这样的低输出的内燃机来说,这是不可忽视的要素。另外,由蜂窝状结构的催化剂元件构成的催化剂本体112安装在催化剂管111中的这种结构,与上述图17及图18所示的内管101配置在排气管100内的结构相比较,更增加了制造成本。In the "exhaust purification device for motorcycles and the like" shown in Figures 19 to 21, a
发明的揭示disclosure of invention
因此,本发明的目的是提供一种(1)充分发挥净化作用、(2)尽量不对内燃机的性能造成影响、(3)费用低的内燃机的排气净化装置。Therefore, it is an object of the present invention to provide an exhaust gas purification device for an internal combustion engine that (1) fully exerts the purification effect, (2) minimizes the influence on the performance of the internal combustion engine, and (3) is inexpensive.
本发明在从该内燃机的排气口延伸的排气管断面的大致中央部位设置有带催化剂金属的薄壁钢板。因此,在排气管中将催化剂金属设置在排气温度高的断面的大致中央部位,可以使催化剂金属活性化,充分发挥排出气体的净化作用。According to the present invention, a thin-walled steel plate with a catalyst metal is provided approximately in the center of the cross section of the exhaust pipe extending from the exhaust port of the internal combustion engine. Therefore, by disposing the catalytic metal in the approximate center of the cross-section where the exhaust temperature is high in the exhaust pipe, the catalytic metal can be activated and the purifying effect of the exhaust gas can be sufficiently exhibited.
作为前述薄壁钢板,由于最好是沿前述排气管轴向延伸的筒体,因此,可以减少排出气体经过时的压力损失。The thin-walled steel plate is preferably a cylindrical body extending in the axial direction of the exhaust pipe, so that the pressure loss when the exhaust gas passes through can be reduced.
前述筒体是由多孔板构成的,筒体的排气上游侧最好被封住。也就是说,由于排出气体经过开设在筒体壁上的数个孔,因而,排出气体能与第二载体内外表面上的催化剂金属接触。结果,可以增大排出气体与催化剂金属接触的面积,提高排出气体的净化作用。The aforementioned cylindrical body is constituted by a perforated plate, and the exhaust gas upstream side of the cylindrical body is preferably sealed. That is, since the exhaust gas passes through the holes provided in the wall of the cylinder, the exhaust gas can contact the catalyst metal on the inner and outer surfaces of the second carrier. As a result, the area where the exhaust gas contacts the catalyst metal can be increased, and the purification effect of the exhaust gas can be improved.
更进一步,本发明在从内燃机的排气口延伸的排气管断面的大致中央部位,设置有沿排气管轴向延伸的带催化剂金属的由薄壁钢板制成的筒体,在前述排气管内,支撑有前述薄壁钢板制成的筒体,并且,设有用于封闭前述薄壁钢板制成的筒体与排气管之间的通路的隔板。也即是说,隔板将其前后隔开,限制了来自内燃机的排出气体的脉动,使得流动大致成为平滑稳定的流动。这样,排气净化装置的净化能力不会改变,因而提高了净化作用。另外由于利用限制排出气体脉动的隔板来支撑薄壁钢板制成的筒体,因此不需要使用专门的支撑部件。Furthermore, in the present invention, in the substantially central part of the section of the exhaust pipe extending from the exhaust port of the internal combustion engine, a cylindrical body made of thin-walled steel plate with catalyst metal extending in the axial direction of the exhaust pipe is provided. In the air pipe, the cylinder body made of thin-walled steel plate is supported, and a partition plate for closing the passage between the cylinder body made of thin-walled steel plate and the exhaust pipe is provided. That is, the partition plate separates it from the front to the rear, restricts the pulsation of the exhaust gas from the internal combustion engine, and makes the flow generally smooth and stable. In this way, the purification capability of the exhaust gas purification device does not change, thereby improving the purification effect. In addition, since the cylinder body made of thin-walled steel plate is supported by the partition plate that restricts the pulsation of the exhaust gas, it is not necessary to use a special support member.
再者,前述薄壁钢板制成的筒体,相对于前述排气管沿轴向可伸缩地安装着,因而,可以吸收随着热膨胀而发生在薄壁钢板制成的筒体与排气管之间的延伸量之差。Furthermore, the cylindrical body made of the thin-walled steel plate is telescopically installed in the axial direction with respect to the aforementioned exhaust pipe, so that the thermal expansion that occurs between the cylindrical body and the exhaust pipe made of the thin-walled steel plate can be absorbed. The difference in the amount of extension between.
更进一步,本发明的内燃机的排气净化装置,沿着从该内燃机排气口延伸的排气管的内壁附近设置有带催化剂金属的第一载体,在该第一载体断面的大致中央部位配置具有催化剂金属的第二载体。也就是说,在排气管的内壁附近及断面的大致中央部位两个位置处设置有带催化剂金属的载体,因此,不会对内燃机的性能产生负面影响,可以进一步提高排出气体的净化作用。Furthermore, in the exhaust gas purification device of an internal combustion engine according to the present invention, a first carrier with a catalyst metal is provided along the vicinity of the inner wall of an exhaust pipe extending from an exhaust port of the internal combustion engine, and is disposed approximately in the center of the cross section of the first carrier. A second support with a catalyst metal. In other words, since the catalyst metal-carrying carrier is provided near the inner wall of the exhaust pipe and approximately in the center of the cross section, the purification effect of exhaust gas can be further improved without adversely affecting the performance of the internal combustion engine.
图面的简单说明A brief description of the graphics
图1是装有本发明第一实施例的内燃机的排气净化装置的摩托车的侧面图。Fig. 1 is a side view of a motorcycle equipped with an exhaust purification system for an internal combustion engine according to a first embodiment of the present invention.
图2是本发明排气管第一实施例的侧面图。Fig. 2 is a side view of the first embodiment of the exhaust pipe of the present invention.
图3是图2中的A-A断面图。Fig. 3 is a sectional view of A-A in Fig. 2 .
图4是图3中的B-B断面图。Fig. 4 is a B-B sectional view in Fig. 3 .
图5是本发明第二排气净化装置的第一实施例的立体图。Fig. 5 is a perspective view of the first embodiment of the second exhaust purification device of the present invention.
图6是图2中的C-C断面图。Fig. 6 is a C-C sectional view in Fig. 2 .
图7是图6中的D-D断面图。Fig. 7 is a D-D sectional view in Fig. 6 .
图8是图6中的E-E断面图。Fig. 8 is an E-E sectional view in Fig. 6 .
图9A~图9E是本发明第二载体的第一实施例的组装说明图。9A to 9E are diagrams illustrating assembly of the first embodiment of the second carrier of the present invention.
图10A~图10D是本发明第二载体的第一实施例的变形例示意图。10A to 10D are schematic diagrams of modifications of the first embodiment of the second carrier of the present invention.
图11A~图11H是本发明第二载体的第一实施例支撑结构的变形例示意图。11A to 11H are schematic diagrams of modified examples of the supporting structure of the first embodiment of the second carrier of the present invention.
图12是第二实施例的第二排气净化装置的立体图。Fig. 12 is a perspective view of a second exhaust purification device of the second embodiment.
图13是图12中的F-F断面图。Fig. 13 is a sectional view taken along line F-F in Fig. 12 .
图14是第二实施例的第二排气净化装置的变形例示意图。Fig. 14 is a schematic diagram of a modified example of the second exhaust purification device of the second embodiment.
图15是图14中的G-G断面图。Fig. 15 is a G-G sectional view in Fig. 14 .
图16A~图16E第三实施例的排气净化装置的结构简图。Fig. 16A to Fig. 16E are schematic structural diagrams of the exhaust purification device of the third embodiment.
图17是现有技术的排气管横断面图。Fig. 17 is a cross-sectional view of an exhaust pipe in the prior art.
图18是现有技术的排气管局部纵断面图。Fig. 18 is a partial longitudinal sectional view of a prior art exhaust pipe.
图19是现有技术的排气消声器的平面图。Fig. 19 is a plan view of a prior art exhaust muffler.
图20是现有技术的排气净化装置的局部断面立体图。Fig. 20 is a partial sectional perspective view of a conventional exhaust purification device.
图21是表示现有技术的催化剂管附近结构的纵断面图。Fig. 21 is a longitudinal sectional view showing the structure of the vicinity of the catalyst tube in the prior art.
实施发明的最佳形式Best form for carrying out the invention
下面根据附图叙述本发明的实施例。首先参照图1~图9说明第一实施例。Embodiments of the present invention are described below according to the accompanying drawings. First, a first embodiment will be described with reference to FIGS. 1 to 9 .
在图1中,摩托车1在车体2中央附近装有二冲程型发动机(内燃机)3,发动机3的排气口4连接有排气管5,该排气管5的后部连接有消声器6。In Fig. 1, a
图2示出了本发明的排气管5。该排气管5由薄壁钢板做成断面为圆形的结构,其一端部5a由法兰连接在发动机3的排气口4(参照图1)上,另一端部5b通过法兰连接有消声器6(参照图1),其内部装有排气上游侧的第一排气净化装置10及排气下游侧的第二排气净化装置20。第一排气净化装置10是前级净化装置,第二排气净化装置20是后级净化装置。排气管5的配置排气下游侧的第二排气净化装置20的部分比其它部分的直径大。Figure 2 shows the
图3示出了前述第一排气净化装置10的断面结构。FIG. 3 shows a cross-sectional structure of the aforementioned first
第一排气净化装置10由设置在排气管5内的内管11组成。该内管11是沿着排气管5内壁的与该排气管5同方向延伸的圆筒体,并由薄壁钢板制成的多孔板构成。内管11其一端部11a通过焊接固定在排气管5上,另一端11b由支撑部件13支撑,可相对于排气管5沿轴向伸缩。这样,可以吸收随着热膨胀产生在排气管5与内管11之间的轴向延伸量之差。The first
内管11在带有多个孔11c的壁面上,设有铂或铑等具有催化剂功能的贵金属(通过涂敷含贵金属的溶液等方法附着)。排气管5的中间部的大小为可与内管11之间设有空隙5c。The
图4中的排气管5做成径向分割的半圆筒状,在内装有内管11的状态下,将这两个半圆筒状部分焊接成一体。The
支撑部件13通过将波形板(波纹板)卷成圆筒状并将重合面用点焊固定而做成沿圆周方向的波状结构。因此,支撑部件13通过弹性变形可相对于排气管5在径向伸缩,吸收因热膨胀引起的排气管5与内管11之间的延伸量差。但是,支撑部件13并不限于由前述波形板构成的结构,还可以采用例如通过编入不锈钢线材而做成环状的结构。The supporting
符号14、14表示用于覆盖高温排气管5的保护件,做成沿径向分割的一对。该保护件14、14用螺栓固定在焊接于排气管5外周面上的数个螺母15上。
在图5中,示出了本发明第二排气净化装置20。该第二排气净化装置20沿着排气管5的内壁面附近设置有一对第一载体21、21,该第一载体21、21的断面的大致中央部(排气管5的大致中央部)配置有第二载体22,第一载体21、21及第二载体22沿着排气管5的轴向延伸。In FIG. 5, the second
第一载体21、21由径向分割的一对半圆筒体构成,第二载体22由直径小于第一载体21、21的柱状圆筒体构成,第一载体21、21及第二载体22由薄壁钢板制成的多孔板构成。第一载体21、21及第二载体22分别在带有多个孔(21a、22c)的壁面上设有铂或铑等具有催化剂功能的贵金属(通过涂敷含贵金属的溶液等方法附着)。排气管5的大小做成与第一载体21、21之间具有间隙的结构。The
在图6中,在排气管5内的排气上游侧(该图的左侧)设有支撑部件23,用于支撑第二载体22的一端部22a,使第二载体22可相对于排气管5沿轴向伸缩。该支撑部件23具有支撑第二载体22的一端部22a并使该一端部22a可穿过的缓冲部件24、用于安装该缓冲部件24的环状支座25及将该支座25固定在排气管5上的托架26。因此,可以吸收随着热膨胀而发生在排气管5与第二载体22之间的轴向延伸量之差。In FIG. 6, a
在排气管5内的排气下游侧(该图的右侧)设有用于支撑第二载体22并堵住该第二载体22与排气管5之间的通路的隔板27。由薄壁钢板做成的端板(略呈碟形的端板)所构成的前述隔板27,通过将其法兰部27a塞焊固定在排气管5上,并让第二载体22的另一端部22b插入且焊接在断面的大致中央部位的通孔27b中而固定。第二载体22的一端(排气上游侧)22a由盖28堵住。A
在图7中,缓冲部件24通过将波形板(波纹板)卷成圆筒状并将重合面用点焊固定而做成沿圆周方向的波状结构。因此,缓冲部件24通过弹性变形可相对于排气管5在径向伸缩,吸收因热膨胀引起的排气管5与第二载体22之间的延伸量差。In FIG. 7, the cushioning
如图8所示,一对第一载体21、21各自的两端部通过点焊固定在径向分割的排气管5的边缘部附近。As shown in FIG. 8 , both end portions of the pair of
下文根据图6及图9A~图9E叙述上述结构的第二载体22的组装顺序。The following describes the assembly sequence of the
首先,如图9A所示,将盖28嵌合在第二载体22的一端部22a上,接着如图9B所示,将第二载体22的一端部22a与盖28的边缘部通过点焊而固定,并把一端部22a堵住。First, as shown in FIG. 9A, the
然后,如图9C所示,将第二载体22的另一端部22b插入隔板27的通孔27b中,并通过焊接固定在一起。Then, as shown in FIG. 9C, the
随后,如图9D所示,将安装缓冲部件24(参照图6)的支座25插入第二载体22的一端部22a,组装成9E所示的姿势。Then, as shown in FIG. 9D , the
最后,将如图9E所示姿势的第二载体22定位在图6所示的半分割状排气管5的下半部之内,将支座25焊接在预先固定的托架26上,用排气管5的上半部分盖住并把所述上下两个半部焊接在一起,将排气管5与隔板27的法兰部27a通过塞焊连接在一起,便完成了组装作业。Finally, position the
下文根据图2、图6叙述第一排气净化装置10及第二排气净化装置20的作用。The functions of the first
如图2所示,发动机的排出气体从排气管5的一端部5a侧流入并通过第一排气净化装置10时,与内管11上的贵金属接触发生反应,净化后到达第二排气净化装置20。As shown in Figure 2, when the exhaust gas from the engine flows in from the side of one end 5a of the
如图6所示,在第二排气净化装置20中,排出气体从该图的左侧流动。但是,由于第二载体22的一端部22a由盖28堵住,因此排出气体不能从这一端部22a流入。As shown in FIG. 6 , in the second
排气管5设置有第二排气净化装置20的部分比其它部分的直径大,通过由隔板27对其前后的分隔,使排气上游侧成为膨胀室29。因此,利用膨胀室29可以限制来自发动机3的排出气体的脉动,使排出气体的流动大致成为平滑稳定的流动。从而,排出气体沿图6箭头所示方向顺着排气管5的管壁附近流动,该排出气体与第一载体21、21上的贵金属接触反应以达净化之目的。The part of the
更进一步,排出气体通过开设在第二载体22壁上的数个孔22c进入第二载体22内,通过另一端部22b从排气管的排气下游侧排放到大气中。排出气体经过第二载体22时,与第二载体22上的贵金属接触发生反应,使之净化。Furthermore, the exhaust gas enters the
在这种场合,由于排出气体通过开设在第二载体22壁上的数个孔22c,与第二载体22内外表面上的催化剂金属接触,因而可以增大排出气体与催化剂金属的接触面积,充分发挥催化剂金属的净化作用。In this case, since the exhaust gas passes through
如上述,为了能够充分发挥催化剂金属的净化作用,必须在高温下使催化剂活性化。另一方面,经过排气管5流动的排出气体的温度在管的断面中央部位比较高。由于经过排气管5的断面中央部位流动的温度比较高的排出气体,也是在与催化剂金属接触下通过的,因此,第二载体22可以使催化剂温度增高并充分活性化,充分发挥了净化作用。另外,由于第二载体22是由多孔板制成的筒体构成的,因此,可以减少排出气体通过时的压力损失,减少对发动机性能的影响。As described above, in order to fully exert the purifying effect of the catalyst metal, the catalyst must be activated at high temperature. On the other hand, the temperature of the exhaust gas flowing through the
这样,排出气体与第一载体21、21及第二载体22上的贵金属接触,发生反应而净化,因而净化效率高。另外,由于排出气体的流动大致为平滑稳定流动,因此第二排气净化装置20的净化能力不变,净化效率高。In this way, the exhaust gas contacts with the noble metals on the
第二载体22通过反应热等使其温度高于排气管5的温度。由于第二载体22的另一端部22b由隔板27固定在排气管5上,因而随着热膨胀在排气管5与第二载体22之间发生延伸量差时,该第二载体22的一端部22a可以沿空心箭头方向延伸,从而用该第二载体22来吸收这一延伸量的差。排气管5与第二载体22之间的径向延伸量差可以通过缓冲部件24的弹性变形来吸收。The temperature of the
前述第二载体22采用了排出气体上游侧封闭的结构,但是,也可以采用例如图10A~图10D所示的结构。The above-mentioned
图10A~图10D示出了关于上述第一实施例的第二载体22的变形例。10A to 10D show modifications of the
图10A示出了第二载体22的一端部22a由盖31封闭的结构,盖31由向排气上游侧鼓出的多孔板制成,并通过冲压成形而形成。Fig. 10A shows a structure in which one
图10B示出了第二载体22的一端部22a通过挤压做成扁平的作为盖32的结构。FIG. 10B shows a structure in which one
阻10C示出了在第二载体22的一端部22a安装有数枚多孔板制成的板的结构,该数枚多孔板制成的板安装成螺旋状(风车状)并作为盖33,以增加排出气体的流动阻力。Resistor 10C shows the structure that several pieces of perforated plates are installed on one
图10D示出了在第二载体22的一端部22a由平板状的多孔板制成的盖34封闭的结构。代替安装的平板状多孔板制成的盖34,还可以采用将一端部22a本身朝第二载体22中心一侧折缘构成平板状的盖以封闭排气上游侧的结构。FIG. 10D shows a structure in which one
于是,图10A~图10D示出的各盖31、32、33、34具有与第一实施例的结构同样的作用,并且,由于是由多孔板制成的,因此通过设置各盖31、32、33、34,与第一实施例的结构相比,可以进一步减少压力损失。Therefore, each
第二载体22的支撑结构是,第二载体22的一端相对于排气管5沿轴向可伸缩地支撑着,另一端固定在排气管5上,例如可采用图11A~图11H所示的结构。The supporting structure of the
图11A~图11H示出了第一实施例的第二载体22支撑结构的变形例。排出气体沿着这些图中箭头所示的方向流动,第二载体22的一端部22a由热膨胀引起沿空心箭头所示方向的伸长。11A to 11H show modified examples of the supporting structure of the
图11A示出的第二载体22的支撑结构是,第二载体22的一端部22a从支撑部件23朝排气上游侧延伸,一端部22a由平板状的盖28封闭。The supporting structure of the
图11B示出的第二载体22的支撑结构,采用支撑部件23的排气上游侧(该图的左侧)由盖36封闭的结构。一端部22a与盖36之间具有大于第二载体22因热膨胀引起的伸长量的间隙S1。在这种场合,不需要在第二载体22的一端部22a上安装盖。The supporting structure of the
图11C示出的第二载体22的支撑结构,采用支撑部件23的支座25沿着排气管5轴向的长度比托架26更长的结构。The supporting structure of the
图11D示出的第二载体22的支撑结构,采用第二载体22仅由隔板27支撑其一端的结构。支撑部件37由缓冲部件38、容纳该缓冲部件38的支座39及将该支座39固定在排气管5上的隔板27构成,缓冲部件38支撑着第二载体22的另一端部22b,使该另一端部22b可沿排气管5的轴向伸缩。在另一端部22b与支座39的凸缘39a之间具有间隙S2,该间隙S2将另一端部22b的移动量及伸长量限制在该间隙S2的范围内。The supporting structure of the
图11E示出了图11D结构的变形例,缓冲部件38及支座39的长度比图11D的结构更短一些。FIG. 11E shows a modified example of the structure in FIG. 11D , and the lengths of the
图11F示出的第二载体22的支撑结构,采用了第二载体22的一端部22a由托架41固定在排气管5上、第二载体22的另一端部22b由支撑部件42支撑、可沿排气管5的轴向伸缩的两端支撑的结构。支撑部件42由缓冲部件43、容纳缓冲部件43的支座44及将支座44固定在排气管5上的隔板27构成,缓冲部件43支撑着第二载体22的另一端部22b,使该另一端部22b可沿排气管5的轴向伸缩。另一端部22b从支撑部件42朝排气下游侧(该图的左侧)延伸。The supporting structure of the
图11G示出的第二载体22的支撑结构,是图11F结构的变形例,采用在第二载体22的一端部22a安装盖45,封闭该一端部22a的结构,所述盖45带有冲切爪。The supporting structure of the
图11H是上述缓冲部件24、38、43的变形例,采用了通过编入不锈钢线材做成环状的缓冲部件48。例如,支撑部件46由卷绕在第二载体22另一端部22b上的座板47、插在该座板47上并支撑着另一端部22b使该另一端部22b可沿排气管5的轴向伸缩的前后两个缓冲部件48、用于容纳该两个缓冲部件48的圆筒状支座49及将该支座49固定在排气管5上的隔板27构成。Fig. 11H is a modified example of the above-mentioned
下文根据图12及图13叙述第二排气净化装置的第二实施例。The second embodiment of the second exhaust purification device will be described below based on FIGS. 12 and 13 .
在图12中,第二排气净化装置50沿着排气管5的内壁面附近设置有第一载体51,该第一载体51的断面的大致中央部(排气管5的断面的大致中央部)设置有第二载体52。第一载体51及第二载体52沿排气管5的轴向延伸。In FIG. 12 , the second
前述第一载体51由圆筒体构成,其轴向两端部带有圆锥部51a、51a,该圆锥部51a、51a的一方或两方通过焊接固定在排气管5上。第二载体52由平板构成,其长度方向的一端或两端通过焊接固定在第一载体51内。The aforementioned
第一载体51及第二载体52由薄壁钢板制成的多孔板构成。第一载体51及第二载体52分别在带有多个孔51c、52a的壁面上,设有铂或铑等具有催化剂功能的贵金属(通过涂敷含贵金属的溶液等方法附着)。The
图13示出了由平板构成的第二载体52在第一载体51内竖起的状态。FIG. 13 shows a state in which the
下文参照图12叙述上述第二实施例的第二排气净化装置50的作用。The action of the second
发动机的排出气体沿该图中箭头所示的方向流动,经过管壁附近流动的排出气体,通过开设在第一载体51壁上的数个孔51c流动,经过断面大致中央部位流动的排出气体穿过开设在第二载体52壁上的数个孔52a流动。因此,该排出气体与第一载体51及第二载体52上的贵金属接触反应以达净化之目的。The exhaust gas of the engine flows in the direction indicated by the arrow in the figure, the exhaust gas flowing near the tube wall flows through
在这种场合,由于排出气体通过开设在第二载体52壁上的数个孔52a,与第二载体52内外表面上的催化剂金属接触,因而可以增大排出气体与催化剂金属的接触面积,充分发挥催化剂金属的净化作用。In this case, since the exhaust gas passes through
第二载体52上的贵金属因与经过排气管5的断面中央部位流动的温度比较高的排出气体接触,可以变成高温,充分活性化,完全发挥净化作用。The precious metal on the
由于第二载体52是由沿排气管5轴向延伸的平板构成的,因此,与前述第一实施例的结构相比,可进一步减少排出气体通过时的压力损失。Since the
上述第二实施例的第二排气净化装置50还可以采用图14及15的结构。The second
即是说,图14示出了第二实施例的第二排气净化装置50的变形例。第一载体51的断面形状是带缺口的圆断面,是将圆筒体径向的一部分(例如图14的下部)切去而形成的。That is, FIG. 14 shows a modified example of the second
在图15中,第一载体51的由带缺口的断面两边缘弯折而形成的凸缘部51b、51b连接在排气管5的内壁上。第二载体52贯穿第一载体51的缺口部分而连接在排气管5的内壁上。In FIG. 15 , flange portions 51 b , 51 b formed by bending both edges of the notched section of the
图16A~16E示出了本发明第三实施例的排气净化装置的简要结构。16A to 16E show a schematic structure of an exhaust purification device according to a third embodiment of the present invention.
图16A的排气净化装置61采用在排气管5内设置有前后两级净化装置的结构,前级净化装置与后级净化装置之间装有用于调节排气量的调节阀(例如蝶阀)62。前级净化装置采用前述图3所示的第一排气净化装置10的结构,后级净化装置采用前述图12所示的第二排气净化装置50的结构。The exhaust purification device 61 of Fig. 16A adopts the structure that two-stage purification devices are arranged in the
图16B中的排气净化装置63采用在排气管5内设置有前后三级净化装置的结构。前级净化装置采用前述图3所示的第一排气净化装置10的结构,中间一级的净化装置采用前述图12所示的第二排气净化装置50的结构,后级净化装置采用从排气管5的另一端部5b延伸到排气管5内的导出管64的结构。该导出管64由薄壁钢板制成的多孔板构成,在带有多个孔的壁面上,设有铂或铑等具有催化剂功能的贵金属(通过涂敷含贵金属的溶液等方法附着)。The exhaust purification device 63 in FIG. 16B adopts a structure in which three stages of purification devices are installed in the
图16C的排气净化装置65采用在排气管5的断面大致中央部设置沿排气管5轴向延伸的载体66的结构。该载体66是由薄壁钢板制成的多孔板构成的平板,在带有多个孔的壁面上,设有铂或铑等具有催化剂功能的贵金属(通过涂敷含贵金属的溶液等方法附着)。The exhaust purification device 65 in FIG. 16C has a structure in which a carrier 66 extending in the axial direction of the
图16D的排气净化装置67是上述图16C所示排气净化装置的变形例,代替平板状结构,载体66采用波形板(波纹板)结构。The exhaust
图16E的排气净化装置68采用配置半圆筒状载体69的结构,半圆筒状载体69沿着排气管5轴向延伸的轴向两端被封闭住。载体69的径向敞开端69a配置在排气管5的断面大致中央部。载体69由薄壁钢板制成的多孔板构成,在带有多个孔的壁面上,设有铂或铑等具有催化剂功能的贵金属(通过涂敷含贵金属的溶液等方法附着)。The exhaust purification device 68 in FIG. 16E adopts a structure in which a semi-cylindrical carrier 69 is arranged, and the axial ends of the semi-cylindrical carrier 69 extending axially along the
图16C、图16D及图16E所示的载体66、69也适用于图16A及图16B所示的在排气管5内配置多级净化装置的结构。The carriers 66 and 69 shown in FIG. 16C , FIG. 16D and FIG. 16E are also applicable to the structure in which multi-stage purification devices are arranged in the
上述第一、第二、第三实施例及其变形例中的带有催化剂金属的“薄壁钢板”,是设置在排气管5的断面大致中央部或第一载体21、51的断面大致中央部的,作为具体的例子,对于如图1~图9所示的第一实施例及图10、图11所示的变形例,采用由多孔板制成的筒体构成的第二载体22的结构,对于图12、图13所示的第二实施例、图14、图15所示的变形例以及图16A、图16B所示的第三实施例采用由多孔板制成的平板构成的第二载体52的结构,对于图16C、图16D及图16E所示的第三实施例,采用由多孔板制成的平板、波形板或半筒状构成的载体66、69的结构。The "thin-walled steel plate" with the catalyst metal in the above-mentioned first, second, third embodiments and their modified examples is installed in the approximate center of the cross section of the
这样,在本发明中, “薄壁钢板”并不限于上述各实施例或其变形例的结构,并且对多孔板的结构也没有任何限定,多孔板的孔形状、孔大小及数量可以是任意的。In this way, in the present invention, "thin-walled steel plate" is not limited to the structures of the above-mentioned embodiments or modifications thereof, and there is no limitation on the structure of the perforated plate, and the hole shape, hole size and number of the perforated plate can be arbitrary. of.
工业上的应用可能性Industrial Applicability
上述本发明的内燃机的排气净化装置,由于从内燃机的排气口延伸的排气管断面的大致中央部位设置有带催化剂金属的薄壁钢板,这样,使得催化剂金属设置在排气温度高的断面的大致中央部位,因此,可使催化剂金属活性化,充分发挥其排气净化作用,而且,可以降低成本。In the above-mentioned exhaust purification device for an internal combustion engine of the present invention, since the thin-walled steel plate with the catalyst metal is provided in the approximate center of the section of the exhaust pipe extending from the exhaust port of the internal combustion engine, the catalyst metal is placed at a place where the exhaust gas temperature is high. Therefore, the catalytic metal can be activated to fully exert its exhaust gas purification effect, and the cost can be reduced.
此外,本发明的内燃机的排气净化装置,由于薄壁钢板是沿排气管轴向延伸的筒体,因而可以减少排气经过时的压力损失,其优点是对内燃机的性能不会产生影响。In addition, the exhaust gas purification device of the internal combustion engine of the present invention, because the thin-walled steel plate is a cylinder extending axially along the exhaust pipe, can reduce the pressure loss when the exhaust gas passes through, and has the advantage that it will not affect the performance of the internal combustion engine .
再者,本发明的内燃机的排气净化装置,由于筒体是由多孔板构成,将筒体的排气上游侧封住,使排出气体经过筒体壁上开设的多个孔,因此,排出气体与第二载体内外表面上的催化剂金属接触。结果,可以增大排出气体与催化剂金属接触的面积,更进一步提高排气净化作用。Furthermore, the exhaust purification device of the internal combustion engine of the present invention, since the cylinder body is made of a perforated plate, the exhaust gas upstream side of the cylinder body is sealed, and the exhaust gas passes through a plurality of holes opened on the cylinder body wall, so that the exhaust gas is exhausted. The gas contacts the catalyst metal on the inner and outer surfaces of the second support. As a result, the area where the exhaust gas contacts the catalyst metal can be increased, and the exhaust gas purification effect can be further improved.
进一步,本发明的内燃机的排气净化装置,由于从内燃机的排气口延伸的排气管断面的大致中央部位,设置有沿排气管轴向延伸的带催化剂金属的由薄壁钢板制成的筒体,薄壁钢板制成的筒体支撑在排气管内,并且该薄壁钢板制成的筒体与排气管之间的通路由隔板封闭,这样,使得催化剂金属设置在排气温度高的断面的大致中央部位,因此,可使催化剂金属活性化,充分发挥其排气净化作用,而且,可以降低成本。还有,由于利用隔板将其前后隔开,限制了来自内燃机的排出气体的脉动,使得流动成为基本稳定的平滑流动,因此,不会改变排气净化装置的净化能力,可充分发挥其净化作用。另外,由于利用限制排出气体脉动的隔板支撑薄壁钢板制成的筒体,因而不需要专门的支撑部件,可以简化支撑结构。Furthermore, in the exhaust purification device of the internal combustion engine of the present invention, since the substantially central part of the section of the exhaust pipe extending from the exhaust port of the internal combustion engine is provided with a thin-walled steel plate with catalyst metal extending in the axial direction of the exhaust pipe. The cylinder made of thin-walled steel plate is supported in the exhaust pipe, and the passage between the cylinder made of thin-walled steel plate and the exhaust pipe is closed by a partition, so that the catalyst metal is arranged in the exhaust pipe. Therefore, the catalyst metal can be activated to fully exert its exhaust gas purification effect, and the cost can be reduced. In addition, since the front and rear are separated by the partition, the pulsation of the exhaust gas from the internal combustion engine is limited, and the flow becomes a basically stable and smooth flow. Therefore, the purification ability of the exhaust purification device will not be changed, and its purification can be fully utilized effect. In addition, since the cylinder body made of thin-walled steel plate is supported by the partition plate that restricts the pulsation of the exhaust gas, special support members are not required, and the support structure can be simplified.
另外,本发明的内燃机的排气净化装置,由于薄壁钢板制成的筒体相对于排气管沿轴向可伸缩地安装着,因此,很容易吸收随热膨胀而引起的筒体与排气管之间的延伸量之差。In addition, in the exhaust purification device of an internal combustion engine of the present invention, since the cylinder body made of thin-walled steel plate is telescopically installed in the axial direction relative to the exhaust pipe, it is easy to absorb the cylinder body and exhaust gas caused by thermal expansion. The difference in elongation between tubes.
还有,本发明的内燃机的排气净化装置,沿着从内燃机的排气口延伸的排气管内壁面附近设置有带催化剂金属的第一载体,在第一载体断面的大致中央部位设置带催化剂金属的第二载体,这样,使得带催化剂金属的载体设置在排气管内壁面附近及其断面的大致中央部位两个位置,因此,在不影响内燃机性能的条件下,进一步提高排气净化作用,具有可进一步降低成本的优点。In addition, in the exhaust gas purification device of an internal combustion engine according to the present invention, a first carrier with a catalyst metal is provided along the vicinity of the inner wall surface of the exhaust pipe extending from the exhaust port of the internal combustion engine, and a catalyst-carrying metal is provided at the approximate center of the cross-section of the first carrier. The second carrier of the metal, so that the carrier with the catalyst metal is arranged at two positions near the inner wall surface of the exhaust pipe and at the approximate center of the cross section, so that the exhaust gas purification effect can be further improved without affecting the performance of the internal combustion engine. It has the advantage that the cost can be further reduced.
Claims (8)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP12689695A JP3614206B2 (en) | 1995-05-25 | 1995-05-25 | Exhaust gas purification device for internal combustion engine |
JP126896/95 | 1995-05-25 |
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Publication Number | Publication Date |
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CN1184523A true CN1184523A (en) | 1998-06-10 |
CN1080370C CN1080370C (en) | 2002-03-06 |
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Application Number | Title | Priority Date | Filing Date |
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CN96193993A Expired - Fee Related CN1080370C (en) | 1995-05-25 | 1996-05-24 | Exhaust emission control device for internal combustion engines |
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Country | Link |
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EP (1) | EP0831211B1 (en) |
JP (1) | JP3614206B2 (en) |
KR (1) | KR100401948B1 (en) |
CN (1) | CN1080370C (en) |
TW (1) | TW371013U (en) |
WO (1) | WO1996037691A1 (en) |
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CN106437946A (en) * | 2015-08-10 | 2017-02-22 | 佛吉亚排放控制技术德国有限公司 | Component of an exhaust system |
CN113382802A (en) * | 2019-02-05 | 2021-09-10 | 株式会社科特拉 | Metal base material for exhaust gas purification and exhaust gas purification device using same |
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US8062990B2 (en) | 1998-05-01 | 2011-11-22 | Basf Corporation | Metal catalyst carriers and catalyst members made therefrom |
EP1286768B1 (en) * | 2000-06-02 | 2007-12-26 | Engelhard Corporation | Pliable metal catalyst carriers, conformable catalyst members made therefrom and methods of installing the same |
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DE102011016170A1 (en) * | 2011-04-05 | 2012-10-11 | Faurecia Emissions Control Technologies, Germany Gmbh | Exhaust gas device and method for its production |
JP6526997B2 (en) * | 2015-03-26 | 2019-06-05 | 本田技研工業株式会社 | Motorcycle |
DE102016101693A1 (en) | 2016-02-01 | 2017-08-03 | Eberspächer Exhaust Technology GmbH & Co. KG | Silencer for an exhaust system |
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US10920661B2 (en) * | 2017-09-06 | 2021-02-16 | Superturbo Technologies, Inc. | Turbine bypass for engine with driven turbocharger |
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JPS51131517U (en) * | 1975-04-15 | 1976-10-23 | ||
JPS53110617U (en) * | 1977-02-09 | 1978-09-04 | ||
JPS54118912A (en) * | 1978-03-07 | 1979-09-14 | Yamaha Motor Co Ltd | Catalytic convertor of exhaust purifier |
JPS62160726A (en) * | 1986-01-09 | 1987-07-16 | Mitsubishi Electric Corp | Laser trimming apparatus for optical device |
JPS62160726U (en) * | 1986-03-31 | 1987-10-13 | ||
JPS6383417U (en) * | 1986-11-21 | 1988-06-01 | ||
JP2816989B2 (en) | 1989-08-29 | 1998-10-27 | スズキ株式会社 | Exhaust gas purification device for internal combustion engine |
JP2816991B2 (en) * | 1989-08-29 | 1998-10-27 | スズキ株式会社 | Exhaust gas purification device for internal combustion engine |
KR920007887B1 (en) * | 1989-08-29 | 1992-09-18 | 스즈키 지도오샤 고오교오 가부시키가이샤 | Exhaust gas cleaning device for internal combustion engine |
EP0441062A1 (en) * | 1989-12-27 | 1991-08-14 | Nippon Shokubai Co., Ltd. | Method for purification of exhaust gas and apparatus therefor |
JP2943366B2 (en) | 1991-03-18 | 1999-08-30 | スズキ株式会社 | Exhaust gas purification equipment for motorcycles, etc. |
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-
1995
- 1995-05-25 JP JP12689695A patent/JP3614206B2/en not_active Expired - Fee Related
-
1996
- 1996-05-24 WO PCT/JP1996/001382 patent/WO1996037691A1/en active IP Right Grant
- 1996-05-24 KR KR1019970706385A patent/KR100401948B1/en not_active IP Right Cessation
- 1996-05-24 TW TW085220080U patent/TW371013U/en unknown
- 1996-05-24 EP EP96914422A patent/EP0831211B1/en not_active Expired - Lifetime
- 1996-05-24 CN CN96193993A patent/CN1080370C/en not_active Expired - Fee Related
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106437946A (en) * | 2015-08-10 | 2017-02-22 | 佛吉亚排放控制技术德国有限公司 | Component of an exhaust system |
CN106437946B (en) * | 2015-08-10 | 2020-06-16 | 佛吉亚排放控制技术德国有限公司 | Component of an exhaust system |
CN113382802A (en) * | 2019-02-05 | 2021-09-10 | 株式会社科特拉 | Metal base material for exhaust gas purification and exhaust gas purification device using same |
Also Published As
Publication number | Publication date |
---|---|
EP0831211A1 (en) | 1998-03-25 |
EP0831211B1 (en) | 2010-09-29 |
EP0831211A4 (en) | 2006-06-14 |
TW371013U (en) | 1999-09-21 |
CN1080370C (en) | 2002-03-06 |
WO1996037691A1 (en) | 1996-11-28 |
KR19980702977A (en) | 1998-09-05 |
JP3614206B2 (en) | 2005-01-26 |
KR100401948B1 (en) | 2004-03-24 |
JPH08319824A (en) | 1996-12-03 |
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