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CN118142831A - An integrated waveguide piezoelectric micromechanical ultrasonic transducer and a method for manufacturing the same - Google Patents

An integrated waveguide piezoelectric micromechanical ultrasonic transducer and a method for manufacturing the same Download PDF

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CN118142831A
CN118142831A CN202410058708.6A CN202410058708A CN118142831A CN 118142831 A CN118142831 A CN 118142831A CN 202410058708 A CN202410058708 A CN 202410058708A CN 118142831 A CN118142831 A CN 118142831A
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ultrasonic transducer
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郑音飞
王泽欣
段会龙
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Zhejiang University ZJU
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B06GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS IN GENERAL
    • B06BMETHODS OR APPARATUS FOR GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS OF INFRASONIC, SONIC, OR ULTRASONIC FREQUENCY, e.g. FOR PERFORMING MECHANICAL WORK IN GENERAL
    • B06B1/00Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency
    • B06B1/02Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy
    • B06B1/06Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy operating with piezoelectric effect or with electrostriction

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Abstract

本发明提供了一种集成波导压电微机械超声换能器及其制备方法,属于微机械超声换能器技术领域。包括波导段和PMUT芯片,所述PMUT芯片包括由下到上依次层叠的衬底、AlN种子层、底部电极层、AlN压电层、顶部电极层、绝缘层和引线层,所述衬底为SOI衬底,所述SOI衬底包括由下到上依次层叠的底硅层、埋氧层和结构硅层,所述AlN种子层位于所述结构硅层的表面;所述波导段为空腔,所述空腔为所述底硅层经过离子刻蚀得到,所述空腔的深度等于底硅层的厚度。本发明中,所述波导段的存在能够引导声波、集中声波能量,更好地传递声能和实现系统小型化,同时提高发射性能。

The present invention provides an integrated waveguide piezoelectric micromechanical ultrasonic transducer and a preparation method thereof, belonging to the technical field of micromechanical ultrasonic transducers. It includes a waveguide section and a PMUT chip, the PMUT chip includes a substrate, an AlN seed layer, a bottom electrode layer, an AlN piezoelectric layer, a top electrode layer, an insulating layer and a lead layer stacked from bottom to top, the substrate is an SOI substrate, the SOI substrate includes a bottom silicon layer, a buried oxide layer and a structural silicon layer stacked from bottom to top, the AlN seed layer is located on the surface of the structural silicon layer; the waveguide section is a cavity, the cavity is obtained by ion etching the bottom silicon layer, and the depth of the cavity is equal to the thickness of the bottom silicon layer. In the present invention, the existence of the waveguide section can guide sound waves, concentrate sound wave energy, better transmit sound energy and realize system miniaturization, while improving the emission performance.

Description

一种集成波导压电微机械超声换能器及其制备方法An integrated waveguide piezoelectric micromechanical ultrasonic transducer and a method for manufacturing the same

技术领域Technical Field

本发明涉及微机械超声换能器技术领域,尤其涉及一种集成波导压电微机械超声换能器及其制备方法。The present invention relates to the technical field of micromechanical ultrasonic transducers, and in particular to an integrated waveguide piezoelectric micromechanical ultrasonic transducer and a preparation method thereof.

背景技术Background technique

由于微结构具有体积小、单位成本低、灵敏度高、功耗低、动态响应快等宝贵优势,微机电系统(MEMS)技术发展迅速,微机械超声换能器(MUT)是克服传统体换能器缺点的潜在解决方案。MUT具有两种转导机制:电容式微机械超声换能器(CMUT)和压电式微机械超声波换能器(PMUT)。相比于CMUT,PMUT不需要极化电压,降低了基于导管的超声应用的电路复杂性,也不需要小的电容间隙,降低了制造复杂性。PMUT的薄膜压电材料大多选择锆钛酸铅(PZT)和氮化铝(AlN),PZT具有更高的压电常数,但与互补金属氧化物半导体(CMOS)不兼容,且需要高达800℃的制造温度。而AlN是无铅的,沉积温度低(<400℃),且与适合大规模生产的CMOS制造工艺完全兼容。Micro-electromechanical systems (MEMS) technology has developed rapidly due to the valuable advantages of microstructures such as small size, low unit cost, high sensitivity, low power consumption, and fast dynamic response. Micromachined ultrasonic transducers (MUTs) are a potential solution to overcome the shortcomings of traditional body transducers. MUTs have two transduction mechanisms: capacitive micromachined ultrasonic transducers (CMUTs) and piezoelectric micromachined ultrasonic transducers (PMUTs). Compared with CMUTs, PMUTs do not require polarization voltages, which reduces the circuit complexity of catheter-based ultrasound applications, and do not require small capacitor gaps, which reduces manufacturing complexity. The thin film piezoelectric materials of PMUTs are mostly lead zirconate titanate (PZT) and aluminum nitride (AlN). PZT has a higher piezoelectric constant, but is incompatible with complementary metal oxide semiconductors (CMOS) and requires a manufacturing temperature of up to 800°C. AlN is lead-free, has a low deposition temperature (<400°C), and is fully compatible with CMOS manufacturing processes suitable for mass production.

MUT在弯曲振动模式(d31)下振动,柔顺薄膜结构使换能器的设计具有灵活性和紧凑性。然而,对于与人体组织直接接触的应用,MUT的精细薄膜结构带来了耐用性问题。一些研究人员尝试使用聚合物层涂覆MUT阵列来解决此问题,但该层增加了MUT成像器和成像表面之间的距离,继而导致衍射、散射和扩展效应,成像对比度和空间分辨率大大降低,也有利用PDMS(聚二甲基硅氧烷)作为硅膜和手指之间良好的声阻抗匹配介质,但该层需要直接暴露在环境中,且受限于脆性振动膜的鲁棒性。The MUT vibrates in a bending vibration mode (d31), and the compliant thin film structure makes the transducer design flexible and compact. However, for applications in direct contact with human tissue, the fine thin film structure of the MUT poses durability issues. Some researchers have tried to solve this problem by coating the MUT array with a polymer layer, but this layer increases the distance between the MUT imager and the imaging surface, which in turn leads to diffraction, scattering, and expansion effects, greatly reducing the imaging contrast and spatial resolution. PDMS (polydimethylsiloxane) is also used as a good acoustic impedance matching medium between the silicon membrane and the finger, but this layer needs to be directly exposed to the environment and is limited by the robustness of the brittle vibrating membrane.

发明内容Summary of the invention

有鉴于此,本发明的目的在于提供一种集成波导压电微机械超声换能器及其制备方法。本发明提出的基于AIN压电材料的波导PMUT能够晶圆级连接到CMOS电路上,能够实现对阵列中的每个MUT单元进行单独寻址的操作。In view of this, the object of the present invention is to provide an integrated waveguide piezoelectric micromechanical ultrasonic transducer and a method for manufacturing the same. The waveguide PMUT based on AIN piezoelectric material proposed in the present invention can be connected to a CMOS circuit at the wafer level, and can realize the operation of individually addressing each MUT unit in the array.

为了实现上述发明目的,本发明提供以下技术方案:In order to achieve the above-mentioned invention object, the present invention provides the following technical solutions:

本发明提供了一种集成波导压电微机械超声换能器,包括波导段和PMUT芯片,所述PMUT芯片包括由下到上依次层叠的衬底、AlN种子层、底部电极层、AlN压电层、顶部电极层、绝缘层和引线层,所述衬底为SOI衬底,所述SOI衬底包括由下到上依次层叠的底硅层、埋氧层和结构硅层,所述AlN种子层位于所述结构硅层的表面;The present invention provides an integrated waveguide piezoelectric micromechanical ultrasonic transducer, comprising a waveguide section and a PMUT chip, wherein the PMUT chip comprises a substrate, an AlN seed layer, a bottom electrode layer, an AlN piezoelectric layer, a top electrode layer, an insulating layer and a lead layer stacked in sequence from bottom to top, wherein the substrate is an SOI substrate, wherein the SOI substrate comprises a bottom silicon layer, a buried oxide layer and a structural silicon layer stacked in sequence from bottom to top, wherein the AlN seed layer is located on the surface of the structural silicon layer;

所述波导段为空腔,所述空腔为所述底硅层经过离子刻蚀得到,所述空腔的深度等于底硅层的厚度。The waveguide section is a cavity, and the cavity is obtained by ion etching the bottom silicon layer. The depth of the cavity is equal to the thickness of the bottom silicon layer.

优选地,所述空腔为长方体,所述长方体的底面为正方形,所述正方形的边长为所述集成波导压电微机械超声换能器的振动膜片边长。Preferably, the cavity is a cuboid, the bottom surface of the cuboid is a square, and the side length of the square is the side length of the vibrating diaphragm of the integrated waveguide piezoelectric micromechanical ultrasonic transducer.

优选地,所述底部电极层和顶部电极层的表面设置通孔开口。Preferably, through-hole openings are provided on the surfaces of the bottom electrode layer and the top electrode layer.

优选地,所述底部电极层和顶部电极层的材质独立地为Pt、Ti、Al或Mo。Preferably, the bottom electrode layer and the top electrode layer are independently made of Pt, Ti, Al or Mo.

优选地,所述绝缘层的材质为二氧化硅。Preferably, the insulating layer is made of silicon dioxide.

本发明还提供了上述技术方案所述的集成波导压电微机械超声换能器的制备方法,包括以下步骤:The present invention also provides a method for preparing the integrated waveguide piezoelectric micromechanical ultrasonic transducer described in the above technical solution, comprising the following steps:

在SOI衬底的表面进行沉积,依次形成AlN种子层、底部电极层前体、AlN压电层前体和顶部电极层前体,然后依次对所述顶部电极层前体、AlN压电层前体和底部电极层前体进行图案化,形成所述底部电极层、AlN压电层和顶部电极层;Depositing on the surface of the SOI substrate to sequentially form an AlN seed layer, a bottom electrode layer precursor, an AlN piezoelectric layer precursor, and a top electrode layer precursor, and then sequentially patterning the top electrode layer precursor, the AlN piezoelectric layer precursor, and the bottom electrode layer precursor to form the bottom electrode layer, the AlN piezoelectric layer, and the top electrode layer;

在所述底部电极层、AlN压电层和顶部电极层的表面进行沉积,形成所述绝缘层;Deposition is performed on the surfaces of the bottom electrode layer, the AlN piezoelectric layer and the top electrode layer to form the insulating layer;

在所述绝缘层的表面进行沉积,形成所述引线层,得到所述PMUT芯片;Deposition is performed on the surface of the insulating layer to form the lead layer, thereby obtaining the PMUT chip;

对底硅层进行离子刻蚀形成所述空腔,得到所述集成波导压电微机械超声换能器。The bottom silicon layer is ion-etched to form the cavity, thereby obtaining the integrated waveguide piezoelectric micromechanical ultrasonic transducer.

优选地,对所述顶部电极层前体和底部电极层前体进行图案化的方法为基于氟的等离子刻蚀,对所述AlN压电层前体进行图案化的方法为基于氯的等离子刻蚀。Preferably, the method for patterning the top electrode layer precursor and the bottom electrode layer precursor is fluorine-based plasma etching, and the method for patterning the AlN piezoelectric layer precursor is chlorine-based plasma etching.

优选地,所述顶部电极层前体图案化后的面积为集成波导压电微机械超声换能器的振动膜片面积的44.5%。Preferably, the area of the patterned top electrode layer precursor is 44.5% of the area of the vibrating diaphragm of the integrated waveguide piezoelectric micromechanical ultrasonic transducer.

优选地,形成所述绝缘层前还包括在所述底部电极层和顶部电极层的表面进行离子刻蚀,形成所述通孔开口。Preferably, before forming the insulating layer, the method further comprises performing ion etching on the surfaces of the bottom electrode layer and the top electrode layer to form the through hole openings.

优选地,所述离子刻蚀为深度反应离子蚀刻。Preferably, the ion etching is deep reactive ion etching.

本发明提供了一种集成波导压电微机械超声换能器,包括波导段和PMUT芯片,所述PMUT芯片包括由下到上依次层叠的衬底、AlN种子层、底部电极层、AlN压电层、顶部电极层、绝缘层和引线层,所述衬底为SOI衬底,所述SOI衬底包括由下到上依次层叠的底硅层、埋氧层和结构硅层,所述AlN种子层位于所述结构硅层的表面;所述波导段为空腔,所述空腔为所述底硅层经过离子刻蚀得到,所述空腔的深度等于底硅层的厚度。本发明提出了一种集成波导压电微机械超声换能器,所述波导段的存在能够引导声波、集中声波能量,更好地传递声能和实现系统小型化。The present invention provides an integrated waveguide piezoelectric micromechanical ultrasonic transducer, comprising a waveguide section and a PMUT chip, wherein the PMUT chip comprises a substrate, an AlN seed layer, a bottom electrode layer, an AlN piezoelectric layer, a top electrode layer, an insulating layer and a lead layer stacked from bottom to top, wherein the substrate is an SOI substrate, wherein the SOI substrate comprises a bottom silicon layer, a buried oxide layer and a structural silicon layer stacked from bottom to top, wherein the AlN seed layer is located on the surface of the structural silicon layer; wherein the waveguide section is a cavity, wherein the cavity is obtained by ion etching the bottom silicon layer, and wherein the depth of the cavity is equal to the thickness of the bottom silicon layer. The present invention proposes an integrated waveguide piezoelectric micromechanical ultrasonic transducer, wherein the existence of the waveguide section can guide sound waves, concentrate sound wave energy, better transmit sound energy and realize system miniaturization.

与现有技术相比,本发明的有益效果如下:Compared with the prior art, the present invention has the following beneficial effects:

本发明所提出的基于AIN压电材料的集成波导压电微机械超声换能器能够晶圆级连接到CMOS电路上,实现对阵列中的每个MUT芯片单元进行单独寻址的操作,相对于相控阵超声成像所需的复杂信号处理,波导段的存在能够做到逐个像素地读出超声图像,将每个PMUT的脉冲回波信号路径与其相邻的脉冲回波信号路径隔离开来,同时提高了集成波导压电微机械超声换能器的发射性能。The integrated waveguide piezoelectric micromechanical ultrasonic transducer based on AIN piezoelectric material proposed in the present invention can be connected to the CMOS circuit at the wafer level to realize the operation of individually addressing each MUT chip unit in the array. Compared with the complex signal processing required for phased array ultrasonic imaging, the existence of the waveguide section can read out the ultrasonic image pixel by pixel, isolate the pulse echo signal path of each PMUT from its adjacent pulse echo signal path, and at the same time improve the transmission performance of the integrated waveguide piezoelectric micromechanical ultrasonic transducer.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

图1为本发明集成波导压电微机械超声换能器的制备过程示意图;FIG1 is a schematic diagram of the preparation process of the integrated waveguide piezoelectric micromechanical ultrasonic transducer of the present invention;

图2为本发明实施例1制得的集成波导压电微机械超声换能器在进行超声成像时的截面图;FIG2 is a cross-sectional view of the integrated waveguide piezoelectric micromechanical ultrasonic transducer manufactured in Example 1 of the present invention when performing ultrasonic imaging;

图3中(a)为对比例的PMUT器件在75ns下的模拟声压图,(b)为对比例的PMUT器件在950ns下的模拟声压图,(c)为实施例1的PMUT器件在75ns下的模拟声压图,(d)为实施例1的PMUT器件在950ns下的模拟声压图;In FIG3 , (a) is a simulated sound pressure diagram of the PMUT device of the comparative example at 75 ns, (b) is a simulated sound pressure diagram of the PMUT device of the comparative example at 950 ns, (c) is a simulated sound pressure diagram of the PMUT device of Example 1 at 75 ns, and (d) is a simulated sound pressure diagram of the PMUT device of Example 1 at 950 ns;

图1和2中电极层包括底部电极层和顶部电极层。The electrode layer in Figures 1 and 2 includes a bottom electrode layer and a top electrode layer.

具体实施方式Detailed ways

本发明提供了一种集成波导压电微机械超声换能器,包括波导段和PMUT芯片,所述PMUT芯片包括由下到上依次层叠的衬底、AlN种子层、底部电极层、AlN压电层、顶部电极层、绝缘层和引线层,所述衬底为SOI衬底,所述SOI衬底包括由下到上依次层叠的底硅层、埋氧层和结构硅层,所述AlN种子层位于所述结构硅层的表面;The present invention provides an integrated waveguide piezoelectric micromechanical ultrasonic transducer, comprising a waveguide section and a PMUT chip, wherein the PMUT chip comprises a substrate, an AlN seed layer, a bottom electrode layer, an AlN piezoelectric layer, a top electrode layer, an insulating layer and a lead layer stacked in sequence from bottom to top, wherein the substrate is an SOI substrate, wherein the SOI substrate comprises a bottom silicon layer, a buried oxide layer and a structural silicon layer stacked in sequence from bottom to top, wherein the AlN seed layer is located on the surface of the structural silicon layer;

所述波导段为空腔,所述空腔为所述底硅层经过离子刻蚀得到,所述空腔的深度等于底硅层的厚度。The waveguide section is a cavity, and the cavity is obtained by ion etching the bottom silicon layer. The depth of the cavity is equal to the thickness of the bottom silicon layer.

在本发明中,所述PMUT芯片包括由下到上依次层叠的衬底、AlN种子层、底部电极层、AlN压电层、顶部电极层、绝缘层和引线层,所述衬底为SOI衬底,所述SOI衬底包括由下到上依次层叠的包括底硅层、埋氧层和结构硅层,所述AlN种子层位于所述结构硅层的表面。In the present invention, the PMUT chip includes a substrate, an AlN seed layer, a bottom electrode layer, an AlN piezoelectric layer, a top electrode layer, an insulating layer and a lead layer stacked in sequence from bottom to top, the substrate is an SOI substrate, and the SOI substrate includes a bottom silicon layer, a buried oxide layer and a structural silicon layer stacked in sequence from bottom to top, and the AlN seed layer is located on the surface of the structural silicon layer.

在本发明中,所述PMUT芯片包括SOI衬底。在本发明的具体实施例中,所述SOI衬底优选为4英寸的SOI衬底。In the present invention, the PMUT chip comprises an SOI substrate. In a specific embodiment of the present invention, the SOI substrate is preferably a 4-inch SOI substrate.

在本发明中,所述PMUT芯片包括层叠在所述结构硅层表面的AlN种子层。In the present invention, the PMUT chip includes an AlN seed layer stacked on the surface of the structural silicon layer.

在本发明中,所述AlN种子层的厚度优选为0.2μm。In the present invention, the thickness of the AlN seed layer is preferably 0.2 μm.

在本发明中,所述PMUT芯片包括层叠在所述AlN种子层表面的底部电极层。In the present invention, the PMUT chip includes a bottom electrode layer stacked on the surface of the AlN seed layer.

在本发明中,所述底部电极层的材质独立地优选为Pt、Ti、Al或Mo。In the present invention, the material of the bottom electrode layer is preferably independently Pt, Ti, Al or Mo.

在本发明中,所述底部电极层的厚度优选为0.2μm。In the present invention, the thickness of the bottom electrode layer is preferably 0.2 μm.

在本发明中,所述PMUT芯片包括层叠在所述底部电极层表面的AlN压电层。In the present invention, the PMUT chip includes an AlN piezoelectric layer stacked on the surface of the bottom electrode layer.

在本发明中,所述AlN压电层的厚度优选为1.5μm,所述AlN压电层优选采用002晶体取向。In the present invention, the thickness of the AlN piezoelectric layer is preferably 1.5 μm, and the AlN piezoelectric layer preferably adopts a 002 crystal orientation.

在本发明中,所述PMUT芯片包括层叠在所述AlN压电层表面的顶部电极层。In the present invention, the PMUT chip includes a top electrode layer stacked on the surface of the AlN piezoelectric layer.

在本发明中,所述顶部电极层的材质独立地优选为Pt、Ti、Al或Mo。In the present invention, the material of the top electrode layer is preferably independently Pt, Ti, Al or Mo.

在本发明中,所述顶部电极层的厚度优选为0.2μm。In the present invention, the thickness of the top electrode layer is preferably 0.2 μm.

在本发明中,所述顶部电极层的面积优选为集成波导压电微机械超声换能器的振动膜片面积的44.5%(轴向膜片覆盖面积率为44.5%),尺寸优选为具有67%的边长(相对于释放的膜片),将所述顶部电极层的尺寸和面积限定到上述范围内是由于:通过有限元分析,在此条件下能够实现与膜片的基本振动模态良好的耦合。In the present invention, the area of the top electrode layer is preferably 44.5% of the vibrating diaphragm area of the integrated waveguide piezoelectric micromechanical ultrasonic transducer (the axial diaphragm coverage area rate is 44.5%), and the size is preferably 67% of the side length (relative to the released diaphragm). The size and area of the top electrode layer are limited to the above range because: through finite element analysis, under this condition, good coupling with the basic vibration mode of the diaphragm can be achieved.

在本发明中,所述底部电极层和顶部电极层的表面优选设置通孔开口,所述通孔开口是为了让引线金属接触到底部电极层和顶部电极层,最终给电压到电极上。In the present invention, the surfaces of the bottom electrode layer and the top electrode layer are preferably provided with through-hole openings, and the through-hole openings are for allowing the lead metal to contact the bottom electrode layer and the top electrode layer, and finally applying voltage to the electrodes.

在本发明中,所述PMUT芯片包括层叠在所述顶部电极层表面的绝缘层。In the present invention, the PMUT chip includes an insulating layer stacked on the surface of the top electrode layer.

在本发明中,所述绝缘层的材质优选为二氧化硅。In the present invention, the material of the insulating layer is preferably silicon dioxide.

在本发明中,所述绝缘层的厚度优选为300nm。In the present invention, the thickness of the insulating layer is preferably 300 nm.

在本发明中,所述PMUT芯片包括层叠在所述绝缘层表面的引线层。In the present invention, the PMUT chip includes a lead layer stacked on the surface of the insulating layer.

在本发明中,所述引线层优选包括依次层叠的Ti和Au,所述Ti的厚度优选为20μm,所述Au的厚度优选为200μm,所述Ti优选层叠在所述绝缘层的表面。In the present invention, the lead layer preferably includes Ti and Au stacked in sequence, the thickness of the Ti is preferably 20 μm, the thickness of the Au is preferably 200 μm, and the Ti is preferably stacked on the surface of the insulating layer.

在本发明中,所述集成波导压电微机械超声换能器包括波导段,所述波导段为空腔,所述空腔为所述底硅层经过离子刻蚀得到,所述空腔的深度等于底硅层的厚度。In the present invention, the integrated waveguide piezoelectric micromechanical ultrasonic transducer includes a waveguide section, the waveguide section is a cavity, the cavity is obtained by ion etching the bottom silicon layer, and the depth of the cavity is equal to the thickness of the bottom silicon layer.

在本发明中,所述空腔优选为长方体,所述长方体的底面优选为正方形,所述正方形的边长优选为所述集成波导压电微机械超声换能器的振动膜片边长。In the present invention, the cavity is preferably a rectangular parallelepiped, the bottom surface of the rectangular parallelepiped is preferably a square, and the side length of the square is preferably the side length of the vibrating diaphragm of the integrated waveguide piezoelectric micromechanical ultrasonic transducer.

本发明还提供了上述技术方案所述的集成波导压电微机械超声换能器的制备方法,包括以下步骤:The present invention also provides a method for preparing the integrated waveguide piezoelectric micromechanical ultrasonic transducer described in the above technical solution, comprising the following steps:

在SOI衬底的表面进行沉积,依次形成AlN种子层、底部电极层前体、AlN压电层前体和顶部电极层前体,然后依次对所述顶部电极层前体、AlN压电层前体和底部电极层前体进行图案化,形成所述底部电极层、AlN压电层和顶部电极层;Depositing on the surface of the SOI substrate to sequentially form an AlN seed layer, a bottom electrode layer precursor, an AlN piezoelectric layer precursor, and a top electrode layer precursor, and then sequentially patterning the top electrode layer precursor, the AlN piezoelectric layer precursor, and the bottom electrode layer precursor to form the bottom electrode layer, the AlN piezoelectric layer, and the top electrode layer;

在所述底部电极层、AlN压电层和顶部电极层的表面进行沉积,形成所述绝缘层Deposition is performed on the surface of the bottom electrode layer, the AlN piezoelectric layer and the top electrode layer to form the insulating layer

在所述绝缘层的表面进行沉积,形成所述引线层,得到所述PMUT芯片;Deposition is performed on the surface of the insulating layer to form the lead layer, thereby obtaining the PMUT chip;

对底硅层进行离子刻蚀形成所述空腔,得到所述集成波导压电微机械超声换能器。The bottom silicon layer is ion-etched to form the cavity, thereby obtaining the integrated waveguide piezoelectric micromechanical ultrasonic transducer.

本发明在SOI衬底的表面进行沉积,依次形成AlN种子层、底部电极层前体、AlN压电层前体和顶部电极层前体,然后依次对所述顶部电极层前体、AlN压电层前体和底部电极层前体进行图案化,形成底部电极层、AlN压电层和顶部电极层。The present invention deposits on the surface of an SOI substrate to sequentially form an AlN seed layer, a bottom electrode layer precursor, an AlN piezoelectric layer precursor and a top electrode layer precursor, and then sequentially pattern the top electrode layer precursor, the AlN piezoelectric layer precursor and the bottom electrode layer precursor to form a bottom electrode layer, an AlN piezoelectric layer and a top electrode layer.

在本发明中,所述SOI衬底在使用前优选进行标准RCA清洁,本发明对所述标准RCA清洁的具体方式没有特殊的限定,采用本领域技术人员熟知的方式即可。In the present invention, the SOI substrate is preferably subjected to standard RCA cleaning before use. The present invention has no particular limitation on the specific method of the standard RCA cleaning, and a method well known to those skilled in the art may be used.

在本发明中,所述沉积优选为溅射沉积,本发明对所述溅射沉积的具体方式没有特殊的限定,采用本领域技术人员熟知的方式即可。In the present invention, the deposition is preferably sputtering deposition. The present invention has no special limitation on the specific method of the sputtering deposition, and a method well known to those skilled in the art may be used.

在本发明中,对所述顶部电极层前体和底部电极层前体进行图案化的方法优选为基于氟的等离子刻蚀,对所述AlN压电层前体进行图案化的方法优选为基于氯的等离子刻蚀。In the present invention, the method for patterning the top electrode layer precursor and the bottom electrode layer precursor is preferably fluorine-based plasma etching, and the method for patterning the AlN piezoelectric layer precursor is preferably chlorine-based plasma etching.

在本发明的具体实施例中,对所述顶部电极层前体进行图案化优选包括以下步骤:In a specific embodiment of the present invention, patterning the top electrode layer precursor preferably comprises the following steps:

在所述顶部电极层前体的表面旋涂负性光刻胶掩模,在显影液MF-319中显影得到光刻图案,将刻蚀气体SF6转化为等离子体,对所述顶部电极层前体进行刻蚀。A negative photoresist mask is spin-coated on the surface of the top electrode layer precursor, and developed in a developer MF-319 to obtain a photolithographic pattern. The etching gas SF6 is converted into plasma to etch the top electrode layer precursor.

在本发明中,所述旋涂的厚度优选为1.25μm。In the present invention, the spin coating thickness is preferably 1.25 μm.

在本发明的具体实施例中,对所述AlN压电层前体进行图案化优选包括以下步骤:In a specific embodiment of the present invention, patterning the AlN piezoelectric layer precursor preferably includes the following steps:

在所述AlN压电层前体的表面旋涂1.25μm厚的负性光刻胶掩模,在显影液MF-319中显影得到光刻图案,将刻蚀气体Cl2转化为等离子体,对所述AlN压电层前体进行刻蚀。A negative photoresist mask with a thickness of 1.25 μm was spin-coated on the surface of the AlN piezoelectric layer precursor, and a photolithographic pattern was obtained by developing in a developer MF-319. The etching gas Cl 2 was converted into plasma to etch the AlN piezoelectric layer precursor.

在本发明的具体实施例中,对所述底部电极层前体进行图案化优选包括以下步骤:In a specific embodiment of the present invention, patterning the bottom electrode layer precursor preferably comprises the following steps:

在所述底部电极层前体的表面旋涂负性光刻胶掩模,在显影液MF-319中显影得到光刻图案,将刻蚀气体SF6转化为等离子体,对所述底部电极层前体进行刻蚀。A negative photoresist mask is spin-coated on the surface of the bottom electrode layer precursor, and developed in a developer MF-319 to obtain a photolithographic pattern. The etching gas SF6 is converted into plasma to etch the bottom electrode layer precursor.

在本发明中,所述旋涂的厚度优选为1.25μm。In the present invention, the spin coating thickness is preferably 1.25 μm.

在本发明中,所述顶部电极层前体图案化后的面积优选为集成波导压电微机械超声换能器的振动膜片面积的44.5%。In the present invention, the area of the patterned top electrode layer precursor is preferably 44.5% of the area of the vibrating diaphragm of the integrated waveguide piezoelectric micromechanical ultrasonic transducer.

形成所述底部电极层、AlN压电层和顶部电极层后,本发明在所述底部电极层、AlN压电层和顶部电极层的表面进行沉积,形成所述绝缘层。After forming the bottom electrode layer, the AlN piezoelectric layer and the top electrode layer, the present invention performs deposition on the surfaces of the bottom electrode layer, the AlN piezoelectric layer and the top electrode layer to form the insulating layer.

在本发明中,形成所述绝缘层前优选还包括在所述底部电极层和顶部电极层的表面进行离子刻蚀,形成所述通孔开口。In the present invention, before forming the insulating layer, it is preferred that the method further comprises performing ion etching on the surfaces of the bottom electrode layer and the top electrode layer to form the through hole openings.

本发明优选通过等离子体化学气相沉积(PCVD)形成所述绝缘层。In the present invention, the insulating layer is preferably formed by plasma chemical vapor deposition (PCVD).

形成绝缘层后,本发明在所述绝缘层的表面进行沉积,形成所述引线层,得到所述PMUT芯片。After forming the insulating layer, the present invention performs deposition on the surface of the insulating layer to form the lead layer to obtain the PMUT chip.

本发明优选使用焊盘掩模模板在所述绝缘层的表面沉积并绘制所述引线层。The present invention preferably uses a pad mask template to deposit and draw the lead layer on the surface of the insulating layer.

在本发明中,所述绝缘层中SiO2上的Au-Ge共晶键为PMUT提供了机械锚定和电气接触,PMUT在SOI MEMS晶圆上形成,该晶圆与提供信号处理电子器件的CMOS晶圆结合。In the present invention, the Au-Ge eutectic bond on SiO2 in the insulating layer provides mechanical anchoring and electrical contact for the PMUT, which is formed on a SOI MEMS wafer that is combined with a CMOS wafer that provides the signal processing electronics.

在本发明中,所述PMUT芯片组成的阵列通过导线连接到刚性或柔性PCB上,所制备的阵列中的每个PMUT芯片都有一个专用的接收(Rx)放大器,该放大器在接收阶段连接到底部电极层,每个PMUT芯片的顶部电极层在发射阶段连接到24V发射放大器(Tx)。为了保护Rx放大器免受高压信号的影响,在传输阶段,发射/接收转换开关将每个底部电极层连接到地,图2展示了实施例1所述集成波导压电微机械超声换能器在进行超声成像时的截面图,MEMS晶片和CMOS晶片使用Au-Ge共晶片接合在一起,蚀刻到MEMS晶片的300μm厚高的Si结构层中的波导用于将超声引导向成像目标。In the present invention, the array composed of the PMUT chips is connected to a rigid or flexible PCB through wires. Each PMUT chip in the prepared array has a dedicated receiving (Rx) amplifier, which is connected to the bottom electrode layer in the receiving stage, and the top electrode layer of each PMUT chip is connected to a 24V transmitting amplifier (Tx) in the transmitting stage. In order to protect the Rx amplifier from the influence of high-voltage signals, the transmitting/receiving conversion switch connects each bottom electrode layer to the ground in the transmission stage. FIG2 shows a cross-sectional view of the integrated waveguide piezoelectric micromechanical ultrasonic transducer described in Example 1 during ultrasonic imaging. The MEMS chip and the CMOS chip are bonded together using an Au-Ge common chip, and the waveguide etched into the 300μm thick Si structure layer of the MEMS chip is used to guide ultrasound to the imaging target.

得到所述PMUT芯片后,本发明对所述底硅层进行离子刻蚀形成所述空腔,得到所述集成波导压电微机械超声换能器。After obtaining the PMUT chip, the present invention performs ion etching on the bottom silicon layer to form the cavity, thereby obtaining the integrated waveguide piezoelectric micromechanical ultrasonic transducer.

在本发明中,所述离子刻蚀优选为深度反应离子蚀刻(DRIE),本发明从晶片的背面释放振动层,形成声波导。本发明对所述深度反应离子蚀刻的具体方式没有特殊的限定,采用本领域技术人员熟知的方式即可。In the present invention, the ion etching is preferably deep reactive ion etching (DRIE), and the present invention releases the vibration layer from the back side of the wafer to form an acoustic waveguide. The present invention has no particular limitation on the specific method of the deep reactive ion etching, and a method well known to those skilled in the art can be used.

下面将结合本发明中的实施例,对本发明中的技术方案进行清楚、完整地描述。显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the present invention will be described clearly and completely below in conjunction with the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, not all of them. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.

实施例1Example 1

制备集成波导压电微机械超声换能器,包括以下步骤:The integrated waveguide piezoelectric micromachined ultrasonic transducer is prepared, comprising the following steps:

步骤1:首先,选择一块4英寸的SOI衬底,并使用标准RCA清洁SOI膜的表面。Step 1: First, select a 4-inch SOI substrate and clean the surface of the SOI film using standard RCA.

该工艺始于图1中(a),先溅射沉积0.2μm厚的氮化铝(AlN)层作为种子层,通过磁控溅射工艺在种子层上生长厚度为0.2μm的Mo底部电极层前体,将1.5μm AlN(采用002晶体取向)磁控溅射到Mo底部电极极上作为压电层前体,然后将0.2μm Mo磁控溅射到AlN压电层上作为顶电部极层前体。The process starts with (a) in Figure 1, where a 0.2 μm thick aluminum nitride (AlN) layer is sputtered as a seed layer, a 0.2 μm thick Mo bottom electrode layer precursor is grown on the seed layer by magnetron sputtering, 1.5 μm AlN (with 002 crystal orientation) is magnetron sputtered onto the Mo bottom electrode as a piezoelectric layer precursor, and then 0.2 μm Mo is magnetron sputtered onto the AlN piezoelectric layer as a top electrode layer precursor.

步骤2:如图1中(b)所示,利用基于氟的等离子体蚀刻对顶部电极层前体进行图案化(具体步骤为:在顶部电极层前体的表面旋涂1.25μm厚的负性光刻胶掩模,在显影液MF-319中显影得到光刻图案,将刻蚀气体SF6转化为等离子体,对顶部电极层前体进行刻蚀),AlN压电层前体被图案化(具体步骤为:在AlN压电层前体的表面旋涂1.25μm厚的负性光刻胶掩模,在显影液MF-319中显影得到光刻图案,将刻蚀气体Cl2转化为等离子体,对AlN压电层前体进行刻蚀)以产生振动边界并使用基于氯的等离子体蚀刻来访问底部电极层(具体步骤为:在底部电极层前体的表面旋涂1.25μm厚的负性光刻胶掩模,在显影液MF-319中显影得到光刻图案,将刻蚀气体SF6转化为等离子体,对底部电极层前体进行刻蚀),为了提高与振膜基本振动模式的良好耦合,所述顶部电极层设计为具有44.5%的面积振膜覆盖率。Step 2: As shown in FIG. 1( b), the top electrode layer precursor is patterned using fluorine-based plasma etching (specific steps are: spin coating a 1.25 μm thick negative photoresist mask on the surface of the top electrode layer precursor, developing in a developer MF-319 to obtain a photolithography pattern, converting the etching gas SF 6 into plasma, and etching the top electrode layer precursor), the AlN piezoelectric layer precursor is patterned (specific steps are: spin coating a 1.25 μm thick negative photoresist mask on the surface of the AlN piezoelectric layer precursor, developing in a developer MF-319 to obtain a photolithography pattern, converting the etching gas Cl 2 into plasma, and etching the AlN piezoelectric layer precursor) to generate vibration boundaries and using chlorine-based plasma etching to access the bottom electrode layer (specific steps are: spin coating a 1.25 μm thick negative photoresist mask on the surface of the bottom electrode layer precursor, developing in a developer MF-319 to obtain a photolithography pattern, converting the etching gas SF 6 is converted into plasma and the bottom electrode layer precursor is etched). In order to improve the good coupling with the basic vibration mode of the diaphragm, the top electrode layer is designed to have an area diaphragm coverage rate of 44.5%.

步骤3:如图1中(c)所示,在导电介质中工作时,保护PMUT传感器芯片的上表面电极并防止短路,在其表面沉积300nm的等离子体化学气相沉积(PCVD)SiO2膜作为绝缘层。Step 3: As shown in Figure 1(c), to protect the upper surface electrode of the PMUT sensor chip and prevent short circuit when working in a conductive medium, a 300nm plasma chemical vapor deposition (PCVD) SiO2 film is deposited on its surface as an insulating layer.

步骤4:如图1中(d)所示,通过SiO2的反应离子蚀刻(RIE)来图案化通孔开口。Step 4: As shown in Figure 1(d), the via openings are patterned by reactive ion etching (RIE) of SiO2 .

步骤5:如图1中(e)所示,使用焊盘掩模模板在Mo顶部电极层的表面沉积并绘制金属焊盘(Ti/Au=20/200μm),从而完成PMUT芯片制备。在这一步骤,SiO2上的Au-Ge共晶键为PMUT提供了机械锚定和电气接触,PMUT在SOI MEMS晶圆上形成,该晶圆与提供信号处理电子器件的CMOS晶圆结合。Step 5: As shown in Figure 1 (e), a pad mask template is used to deposit and draw metal pads (Ti/Au=20/200μm) on the surface of the Mo top electrode layer to complete the PMUT chip preparation. In this step, the Au-Ge eutectic bond on SiO2 provides mechanical anchoring and electrical contact for the PMUT, which is formed on the SOI MEMS wafer, which is combined with the CMOS wafer that provides signal processing electronics.

步骤6:如图1中(f)所示,在CMOS-MEMS晶圆键合之后,通过深度反应离子蚀刻(DRIE),从晶片的背面释放振动层,形成底面边长为108μm、的正方形、高度为300μm的空腔。Step 6: As shown in (f) in Figure 1, after the CMOS-MEMS wafer is bonded, the vibration layer is released from the back of the wafer by deep reactive ion etching (DRIE) to form a cavity with a bottom side length of 108 μm, a square shape and a height of 300 μm.

对比例Comparative Example

与实施例1相同,区别仅在于不形成空腔。The same as the first embodiment, the only difference is that no cavity is formed.

评估实施例和对比例制得的压电微机械超声换能器在液体中器件的传输模式脉冲响应和性能,利用商业软件COMSOL Multiphysics 5.6,使用有限元分析方法,分别针对有波导(实施例1)和无波导(对比例)的PMUT器件建立了声-压电-力多物理场建模,并进行瞬态分析。图3显示了在1V、20MHz正弦波驱动下,取时间t=75ns和950ns观察声脉冲距离PMUT表面近(~100μm)和远(~700μm)的模拟声压情况,图3中(a)为对比例的PMUT器件在75ns下的模拟声压图,(b)为对比例的PMUT器件在950ns下的模拟声压图,(c)为实施例1的PMUT器件在75ns下的模拟声压图,(d)为实施例1的PMUT器件在950ns下的模拟声压图,可知,对于无波导的PMUT,从100μm时的4kPa降至700μm时的1.5kPa,峰值压力降低了近2.7倍。相比之下,有波导的PMUT显示,声能在波导段种传播,峰值压力几乎没有变化,从100μm处的140kPa到600μm处的120kPa,声压幅值几乎不变。The transmission mode pulse response and performance of the piezoelectric micromechanical ultrasonic transducer prepared in the embodiment and the comparative example in liquid were evaluated. The commercial software COMSOL Multiphysics 5.6 was used to establish acoustic-piezoelectric-force multi-physics field modeling for PMUT devices with waveguide (Example 1) and without waveguide (Comparative example), and transient analysis was performed. FIG3 shows the simulated sound pressure of the acoustic pulse near (~100μm) and far (~700μm) from the PMUT surface under the 1V, 20MHz sine wave drive, at time t=75ns and 950ns. FIG3 (a) is the simulated sound pressure diagram of the PMUT device of the comparative example at 75ns, (b) is the simulated sound pressure diagram of the PMUT device of the comparative example at 950ns, (c) is the simulated sound pressure diagram of the PMUT device of Example 1 at 75ns, and (d) is the simulated sound pressure diagram of the PMUT device of Example 1 at 950ns. It can be seen that for the PMUT without waveguide, the peak pressure is reduced by nearly 2.7 times from 4kPa at 100μm to 1.5kPa at 700μm. In contrast, the PMUT with waveguide shows that the peak pressure is almost unchanged when the acoustic energy propagates in the waveguide section, and the sound pressure amplitude is almost unchanged from 140kPa at 100μm to 120kPa at 600μm.

综上,本发明所提出的基于AIN压电材料的波导PMUT能够晶圆级连接到CMOS电路上,实现对阵列中的每个MUT芯片进行单独寻址的操作。相对于相控阵超声成像所需的复杂信号处理,波导的存在能够做到逐个像素地读出超声图像,因为波导将每个PMUT芯片的脉冲回波信号路径与其相邻的脉冲回波信号路径隔离开来。In summary, the waveguide PMUT based on AIN piezoelectric material proposed in the present invention can be connected to the CMOS circuit at the wafer level to realize the operation of individually addressing each MUT chip in the array. Compared with the complex signal processing required for phased array ultrasonic imaging, the existence of the waveguide can read out the ultrasonic image pixel by pixel because the waveguide isolates the pulse echo signal path of each PMUT chip from its adjacent pulse echo signal path.

以上所述仅是本发明的优选实施方式,并非对本发明作任何形式上的限制。应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。The above description is only a preferred embodiment of the present invention and does not limit the present invention in any form. It should be pointed out that for ordinary technicians in this technical field, several improvements and modifications can be made without departing from the principle of the present invention, and these improvements and modifications should also be regarded as the protection scope of the present invention.

Claims (10)

1. The integrated waveguide piezoelectric micromachined ultrasonic transducer is characterized by comprising a waveguide section and a PMUT chip, wherein the PMUT chip comprises a substrate, an AlN seed layer, a bottom electrode layer, an AlN piezoelectric layer, a top electrode layer, an insulating layer and a lead layer which are sequentially stacked from bottom to top, the substrate is an SOI substrate, the SOI substrate comprises a bottom silicon layer, an oxygen-buried layer and a structural silicon layer which are sequentially stacked from bottom to top, and the AlN seed layer is positioned on the surface of the structural silicon layer;
The waveguide section is a cavity, the cavity is formed by ion etching of the bottom silicon layer, and the depth of the cavity is equal to the thickness of the bottom silicon layer.
2. The integrated waveguide piezoelectric micromachined ultrasonic transducer of claim 1, wherein the cavity is a cuboid, a bottom surface of the cuboid is a square, and a side length of the square is a side length of a vibrating diaphragm of the integrated waveguide piezoelectric micromachined ultrasonic transducer.
3. The integrated waveguide piezoelectric micromachined ultrasonic transducer of claim 1, wherein surfaces of the bottom electrode layer and the top electrode layer are provided with via openings.
4. An integrated waveguide piezoelectric micromachined ultrasonic transducer according to claim 1 or 3, wherein the material of the bottom electrode layer and the top electrode layer is independently Pt, ti, al or Mo.
5. The integrated waveguide piezoelectric micromachined ultrasonic transducer of claim 1, wherein the insulating layer is silicon dioxide.
6. The method for manufacturing an integrated waveguide piezoelectric micromechanical ultrasonic transducer according to any one of claims 1-5, characterized by comprising the steps of:
Depositing on the surface of the SOI substrate, sequentially forming an AlN seed layer, a bottom electrode layer precursor, an AlN piezoelectric layer precursor and a top electrode layer precursor, and then sequentially patterning the top electrode layer precursor, the AlN piezoelectric layer precursor and the bottom electrode layer precursor to form the bottom electrode layer, the AlN piezoelectric layer and the top electrode layer;
depositing on the surfaces of the bottom electrode layer, the AlN piezoelectric layer and the top electrode layer to form the insulating layer;
depositing on the surface of the insulating layer to form the lead layer, thereby obtaining the PMUT chip;
and performing ion etching on the bottom silicon layer to form the cavity, thereby obtaining the integrated waveguide piezoelectric micro-mechanical ultrasonic transducer.
7. The method of manufacturing according to claim 6, wherein the method of patterning the top electrode layer precursor and the bottom electrode layer precursor is fluorine-based plasma etching, and the method of patterning the AlN piezoelectric layer precursor is chlorine-based plasma etching.
8. The method of manufacturing according to claim 6 or 7, wherein the area of the patterned top electrode layer precursor is 44.5% of the vibrating diaphragm area of the integrated waveguide piezoelectric micromechanical ultrasonic transducer.
9. The method of manufacturing according to claim 6, further comprising ion etching the surfaces of the bottom electrode layer and the top electrode layer to form the via openings before forming the insulating layer.
10. The method of claim 6, wherein the ion etching is deep reactive ion etching.
CN202410058708.6A 2024-01-16 2024-01-16 An integrated waveguide piezoelectric micromechanical ultrasonic transducer and a method for manufacturing the same Pending CN118142831A (en)

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