[go: up one dir, main page]

CN117125955A - Quick hardening early strength material applied to emulsified asphalt slurry seal layer and preparation method thereof - Google Patents

Quick hardening early strength material applied to emulsified asphalt slurry seal layer and preparation method thereof Download PDF

Info

Publication number
CN117125955A
CN117125955A CN202310726925.3A CN202310726925A CN117125955A CN 117125955 A CN117125955 A CN 117125955A CN 202310726925 A CN202310726925 A CN 202310726925A CN 117125955 A CN117125955 A CN 117125955A
Authority
CN
China
Prior art keywords
parts
emulsified asphalt
mpc
strength material
slurry seal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202310726925.3A
Other languages
Chinese (zh)
Inventor
张华胜
裴妍
张庆松
李志鹏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong University
Shandong Jiaotong University
Original Assignee
Shandong University
Shandong Jiaotong University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong University, Shandong Jiaotong University filed Critical Shandong University
Priority to CN202310726925.3A priority Critical patent/CN117125955A/en
Publication of CN117125955A publication Critical patent/CN117125955A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/34Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
    • C04B28/344Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders the phosphate binder being present in the starting composition solely as one or more phosphates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B12/00Cements not provided for in groups C04B7/00 - C04B11/00
    • C04B12/02Phosphate cements
    • C04B12/025Phosphates of ammonium or of the alkali or alkaline earth metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Sealing Material Composition (AREA)

Abstract

本发明涉及一种应用于乳化沥青稀浆封层的快硬早强材料及制备方法,属于路面养护复合材料领域。本发明针对现有技术的不足,提供一种能够快速开放交通的稀浆封层材料,由磷酸镁水泥基体粉料、乳化沥青、拌合水、机制砂、粗集料及抗分散剂配制而成,具备MPC的快硬早强特性及乳化沥青材料的柔性。此种材料只需简单拌合便可使用,同时具备早期强度高、凝结时间短、耐高温性能优异的特性,有利于缩短养护时间,同时提升养护处的耐高温性能。The invention relates to a quick-hardening and early-strength material applied to emulsified asphalt slurry sealing layer and a preparation method, and belongs to the field of pavement maintenance composite materials. In view of the shortcomings of the existing technology, the present invention provides a slurry sealing material that can quickly open to traffic. It is prepared from magnesium phosphate cement matrix powder, emulsified asphalt, mixing water, machine-made sand, coarse aggregate and anti-dispersion agent. , possessing the rapid hardening and early strength characteristics of MPC and the flexibility of emulsified asphalt materials. This kind of material can be used with simple mixing. It also has the characteristics of high early strength, short setting time and excellent high temperature resistance, which is helpful to shorten the curing time and improve the high temperature resistance of the curing area.

Description

一种应用于乳化沥青稀浆封层的快硬早强材料及制备方法A fast-hardening and early-strength material applied to emulsified asphalt slurry sealing layer and its preparation method

技术领域Technical field

本发明属于路面养护复合材料技术领域,具体涉及一种应用于乳化沥青稀浆封层的快硬早强材料及其制备方法。The invention belongs to the technical field of pavement maintenance composite materials, and specifically relates to a quick-hardening and early-strength material used in emulsified asphalt slurry sealing layer and a preparation method thereof.

背景技术Background technique

公开该背景技术部分的信息仅仅旨在增加对本发明的总体背景的理解,而不必然被视为承认或以任何形式暗示该信息构成已经成为本领域一般技术人员所公知的现有技术。The information in this Background section is disclosed solely for the purpose of increasing understanding of the general background of the invention and is not necessarily considered to be an admission or in any way implying that the information constitutes prior art that is already known to a person of ordinary skill in the art.

沥青路面在较高等级公路上的应用愈加普遍,其具有的独特粘弹性使其对温度变化较为敏感:在夏季温度较高时,表现为流态、强度低、弹性模量低,容易产生车辙变形等病害;在冬季低温条件下,沥青路面弹性模量增大变为刚性材料,易产生脆性收缩裂缝等病害;在雨水偏多的季节,沥青路面也易受到水损害而产生集料松散剥落等现象,继而形成坑槽。更糟糕的是,沥青路面会长期受到车辆荷载反复作用,同时受到水温耦合作用,使得其产生各种病害的状况更为频繁和严重。而稀浆封层工艺属于表面处置路面的一种预防性养护施工方法。旧的沥青路面经常出现裂缝和坑洼,当表面受到磨损后,在路面上用乳化沥青稀浆封层混合料摊铺成薄层,并使其尽快固化,从而使沥青混凝土路面得到养护。稀浆封层厚度一般在3cm以下。它是以恢复路面功能为目的,防止进一步损坏的维修养护,以起到有效延长高速道路路面的使用寿命,降低修复成本的目的。Asphalt pavement is increasingly used on higher-grade highways. Its unique viscoelasticity makes it more sensitive to temperature changes: when the temperature is high in summer, it exhibits a fluid state, low strength, and low elastic modulus, and is prone to rutting. Deformation and other diseases; under low temperature conditions in winter, the elastic modulus of asphalt pavement increases and becomes a rigid material, which is prone to brittle shrinkage cracks and other diseases; in seasons with heavy rainfall, asphalt pavement is also susceptible to water damage, resulting in loose and peeling aggregates. and other phenomena, and then form pits. To make matters worse, asphalt pavement will be subject to repeated vehicle loads for a long time and is also subject to water temperature coupling, making various diseases more frequent and serious. The slurry sealing process is a preventive maintenance construction method for surface treatment of pavement. Old asphalt pavements often have cracks and potholes. When the surface is worn, emulsified asphalt slurry sealing mixture is spread on the pavement into a thin layer and allowed to solidify as quickly as possible, so that the asphalt concrete pavement can be maintained. The thickness of the slurry sealing layer is generally less than 3cm. It is maintenance and repair with the purpose of restoring the function of the road surface and preventing further damage, so as to effectively extend the service life of the highway pavement and reduce the cost of repair.

对于高速公路或城市快车道上铺筑稀浆封层时,应选用优质乳化沥青或聚合物改性乳化沥青,以增加沥青和矿料之间的黏结强度。要求乳化沥青与矿料拌合后和拌合过程中不离析,对矿料裹附性好,处于良好的流动状态,摊铺后又能快速凝结,开放交通。而常用的乳化沥青稀浆摊铺后成型时间在4-5h以上,这严重阻碍了开放交通的时间,使得交通堵塞,威胁行车安全。When laying slurry seals on highways or urban express lanes, high-quality emulsified asphalt or polymer-modified emulsified asphalt should be used to increase the bonding strength between asphalt and mineral materials. It is required that the emulsified asphalt does not segregate after mixing with the mineral materials and during the mixing process, has good adhesion to the mineral materials, is in a good flow state, and can quickly solidify after paving to open traffic. The commonly used emulsified asphalt slurry takes more than 4-5 hours to form after paving, which seriously hinders the opening time for traffic, causing traffic jams and threatening driving safety.

化学结合磷酸镁胶结材料(MPC)是由氧化镁与可溶性磷酸盐、外加剂以及矿物掺合料按照一定比例,在酸性条件下通过酸碱化学反应及物理作用生成的以磷酸盐为粘结相的新型无机胶凝材料,具有高早强、凝结时间快且粘结性能出色的特点。发明人的在先研究中,将乳化沥青与MPC材料结合,复合后的材料同时具备无机材料的刚性与有机材料的柔性,提供了一种环境友好、操作简便的灌缝材料,能够有效缩短道路病害修复时间。然而,稀浆封层与灌缝材料的施用方式具有明显不同,对复合材料的性能要求也存在显著差异,直接转用无法满足施工要求,因此,提供一种适用于稀浆封层的复合材料具有重要的研究意义。Chemically bound magnesium phosphate cementing material (MPC) is produced by magnesium oxide, soluble phosphate, admixtures and mineral admixtures in a certain proportion under acidic conditions through acid-base chemical reactions and physical effects, with phosphate as the binding phase. The new inorganic cementitious material has the characteristics of high early strength, fast setting time and excellent bonding performance. In the inventor's previous research, emulsified asphalt was combined with MPC materials. The composite material has both the rigidity of inorganic materials and the flexibility of organic materials, providing an environmentally friendly and easy-to-operate joint filling material that can effectively shorten roads. Disease repair time. However, the application methods of slurry seal and grouting materials are significantly different, and the performance requirements for composite materials are also significantly different. Direct conversion cannot meet the construction requirements. Therefore, a composite material suitable for slurry seal is provided. It has important research significance.

发明内容Contents of the invention

针对上述技术问题,本发明提供了一种适用于沥青路面养护的稀浆封层复合材料,该材料具有快硬早强的特点,摊铺后早期强度高、凝结时间短,有利于缩短路面养护工作的施工时间。In view of the above technical problems, the present invention provides a slurry seal composite material suitable for asphalt pavement maintenance. This material has the characteristics of rapid hardening and early strength. It has high early strength and short setting time after paving, which is beneficial to shortening pavement maintenance. Construction time of the job.

本发明技术思路如下:The technical idea of the present invention is as follows:

本发明第一方面,提供一种应用于乳化沥青稀浆封层的快硬早强材料,包括如下重量份的各原料:磷酸镁水泥基体粉料、乳化沥青、拌合水、机制砂、粗集料及抗分散剂;A first aspect of the present invention provides a fast-hardening early-strength material applied to emulsified asphalt slurry sealing layer, including the following raw materials in parts by weight: magnesium phosphate cement matrix powder, emulsified asphalt, mixing water, machine-made sand, coarse Aggregates and anti-dispersion agents;

其中,所述磷酸镁水泥基体粉料由重烧氧化镁、硼砂、磷酸二氢铵、矿粉、硅灰、粉煤灰配制而成;Wherein, the magnesium phosphate cement matrix powder is prepared from dead burned magnesium oxide, borax, ammonium dihydrogen phosphate, mineral powder, silica fume, and fly ash;

所述抗分散剂包括纤维素醚、纳米SiO2及超细粉煤灰。The anti-dispersion agent includes cellulose ether, nano-SiO 2 and ultra-fine fly ash.

传统的稀浆封层材料在实际应用中存在强度差,强度形成时间长且粘结性能不足的缺点,难以真正起到道路养护的目的。本发明将磷酸镁水泥基体材料(MPC)加入乳化沥青形成有机-无机复合体系,通过磷酸镁水泥的水化可以消耗乳化沥青中的水分,且水泥水化释放出来的水化热也可以加速乳化沥青的破乳速度,而乳化沥青经过破乳过程后,能恢复原有的粘结性能,并与MPC材料发生交互作用,形成介于MPC材料和乳化沥青之间的一种半刚性的胶凝材料,利用MPC-乳化沥青体系的机械咬合作用和混合料之间嵌合作用共同形成强度,完成快速作业。In practical applications, traditional slurry sealing materials have the disadvantages of poor strength, long strength formation time and insufficient bonding performance, making it difficult to truly achieve the purpose of road maintenance. In the present invention, magnesium phosphate cement matrix material (MPC) is added to emulsified asphalt to form an organic-inorganic composite system. The water in the emulsified asphalt can be consumed through the hydration of magnesium phosphate cement, and the hydration heat released by cement hydration can also accelerate emulsification. The demulsification speed of asphalt. After the emulsified asphalt undergoes the demulsification process, it can restore its original bonding properties and interact with the MPC material to form a semi-rigid gel between the MPC material and the emulsified asphalt. The material uses the mechanical interlocking effect of the MPC-emulsified asphalt system and the interlocking effect between the mixture to jointly form strength and complete rapid operations.

进一步地,乳化沥青按照MPC总质量的40%~70%添加,总水灰比W/C=0.15~0.45调节。乳化沥青掺量过少会导致MPC材料不能被完全包裹,出现离析现象,使得材料的均匀性受到影响,乳化沥青掺量过多,导致材料的力学性能及凝结时间大打折扣,材料失去自身的性能优势,经查阅相关文献及试验测试得,乳化沥青掺量在40%~70%之间时材料性能优势明显。Further, the emulsified asphalt is added according to 40% to 70% of the total mass of MPC, and the total water-cement ratio W/C=0.15-0.45 is adjusted. If the amount of emulsified asphalt is too small, the MPC material cannot be completely wrapped and segregation occurs, which affects the uniformity of the material. If the amount of emulsified asphalt is too much, the mechanical properties and setting time of the material will be greatly reduced, and the material will lose its own performance. Advantages. After reviewing relevant literature and experimental tests, it was found that when the emulsified asphalt content is between 40% and 70%, the material performance advantages are obvious.

所述的抗分散剂中,纤维素醚为羟丙基甲基纤维素,其在水泥基材料体系中可以起到多种作用,包括保水分散、增稠增粘、引气润滑和缓凝作用。前期研究结果表明,纤维素醚在掺量大于0.15%时会显著增大材料体系的稠度,并降低材料的力学性能。而低掺量的纤维素醚可以很好地分散悬浊液中的颗粒,提高材料的稳定性。前期研究表明,抗分散剂中的纤维素醚在基体材料中的质量百分数为0.05%-0.5%较为合理;纳米SiO2被证明可以改善水泥基材料的悬浮稳定性、粘结强度、耐候性等,前期研究表明,其掺量过高时,会对力学性能带来不利影响,抗分散剂中的纳米材料掺量在1%~3%中;超细粉煤灰作为超细粉体,少量掺加能提升材料的稳定性,避免镁磷比较小时,氧化镁因重力作用发生沉淀,导致材料的不均匀,同时一定掺量的粉煤灰还可以提高材料的结构致密性,加强材料的流动性能和力学性能,建议掺量为不超过磷酸镁水泥基体粉料的20%。Among the anti-dispersants, the cellulose ether is hydroxypropyl methylcellulose, which can play a variety of roles in cement-based material systems, including water retention and dispersion, thickening and viscosity, air entrainment lubrication and retardation. Preliminary research results show that when the dosage of cellulose ether is greater than 0.15%, it will significantly increase the consistency of the material system and reduce the mechanical properties of the material. The low dosage of cellulose ether can well disperse the particles in the suspension and improve the stability of the material. Preliminary research shows that the mass percentage of cellulose ether in the anti-dispersion agent in the matrix material is 0.05%-0.5%, which is more reasonable; nano-SiO 2 has been proven to improve the suspension stability, bonding strength, weather resistance, etc. of cement-based materials. , Preliminary research shows that when the dosage is too high, it will have adverse effects on mechanical properties. The dosage of nanomaterials in the anti-dispersion agent is 1% to 3%; ultrafine fly ash is an ultrafine powder, and a small amount Adding can improve the stability of the material and prevent magnesium oxide from precipitating due to gravity when the ratio of magnesium to phosphorus is small, resulting in uneven material. At the same time, a certain amount of fly ash can also improve the structural density of the material and enhance the flow of the material. Performance and mechanical properties, the recommended dosage is no more than 20% of the magnesium phosphate cement matrix powder.

本发明还提供上述快硬早强材料的制备方法,将MPC干料及抗分散剂加入液体中混均中再加入粗集料等,混合后材料摊铺在路面上形成沥青封层,经过裹覆、破乳、析水、蒸发和固化等过程与原路面牢固地结合在一起,形成密实、坚固、耐磨和道路表面封层,大大提高路面使用性能。The present invention also provides a method for preparing the above-mentioned fast-hardening and early-strength materials. MPC dry material and anti-dispersion agent are added to the liquid and mixed, and then coarse aggregates, etc. are added. After mixing, the materials are spread on the road to form an asphalt sealing layer, and after coating , demulsification, water separation, evaporation and solidification processes are firmly combined with the original road surface to form a dense, strong, wear-resistant and road surface seal, which greatly improves the performance of the road surface.

以上一个或多个技术方案的有益效果是:The beneficial effects of one or more of the above technical solutions are:

1、本发明提供的稀浆封层,其凝结时间相比现有沥青路面修复材料显著缩短,硬化时间控制在2小时之内,有效缩短了路面养护施工实现,开放交通快,早期强度发展迅速。1. The setting time of the slurry seal provided by the present invention is significantly shorter than that of existing asphalt pavement repair materials. The hardening time is controlled within 2 hours, effectively shortening the road maintenance construction, opening up to traffic quickly, and developing rapid early strength. .

2、本发明提供的稀浆封层材料,其制备原料均为绿色环保的原材料,避免了对环境及地下水的污染,实现了绿色修补。2. The raw materials for preparing the slurry sealing material provided by the present invention are all green and environmentally friendly raw materials, which avoids pollution to the environment and groundwater, and realizes green repair.

具体实施方式Detailed ways

应该指出,以下详细说明都是例示性的,旨在对本发明提供进一步的说明。除非另有指明,本文使用的所有技术和科学术语具有与本发明所属技术领域的普通技术人员通常理解的相同含义。It should be noted that the following detailed description is illustrative and is intended to provide further explanation of the present invention. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.

需要注意的是,这里所使用的术语仅是为了描述具体实施方式,而非意图限制根据本发明的示例性实施方式。如在这里所使用的,除非上下文另外明确指出,否则单数形式也意图包括复数形式,此外,还应当理解的是,当在本说明书中使用术语“包含”和/或“包括”时,其指明存在特征、步骤、操作、器件、组件和/或它们的组合。It should be noted that the terms used herein are for the purpose of describing specific embodiments only, and are not intended to limit the exemplary embodiments according to the present invention. As used herein, the singular forms are also intended to include the plural forms unless the context clearly indicates otherwise. Furthermore, it will be understood that when the terms "comprises" and/or "includes" are used in this specification, they indicate There are features, steps, operations, means, components and/or combinations thereof.

正如背景技术所介绍的,现有技术中针对沥青路面养护的材料还存在施工时间长的缺陷,为了解决如上的技术问题,本发明提出了一种应用于乳化沥青稀浆封层的快硬早强材料,具体方案如下:As introduced in the background art, the existing materials for asphalt pavement maintenance still have the disadvantage of long construction time. In order to solve the above technical problems, the present invention proposes a quick-hardening early-stage sealant for emulsified asphalt slurry seal. Strong materials, the specific plans are as follows:

本发明第一方面,提供一种应用于乳化沥青稀浆封层的快硬早强材料,其原料为以下重量份的各组分:磷酸镁水泥基体粉料21~50份、乳化沥青10~25份、拌合水5~15份、机制砂5~20份、粗集料40~60份,抗分散剂0.5~1份;A first aspect of the present invention provides a fast-hardening early-strength material used in emulsified asphalt slurry sealing layers. The raw materials are the following components by weight: 21 to 50 parts of magnesium phosphate cement matrix powder, 10 to 50 parts of emulsified asphalt. 25 parts, mixing water 5-15 parts, machine-made sand 5-20 parts, coarse aggregate 40-60 parts, anti-dispersion agent 0.5-1 part;

所述磷酸镁水泥粉料由重烧氧化镁10~20份,硼砂1~4份、磷酸二氢铵5~10份、矿粉0~3份、硅灰0~3份、粉煤灰5~10份配制而成。The magnesium phosphate cement powder consists of 10 to 20 parts of dead burnt magnesium oxide, 1 to 4 parts of borax, 5 to 10 parts of ammonium dihydrogen phosphate, 0 to 3 parts of mineral powder, 0 to 3 parts of silica fume, and 5 parts of fly ash. ~Made for 10 servings.

针对第一方面,本发明还提供如下优选的技术方案:For the first aspect, the present invention also provides the following preferred technical solutions:

乳化沥青:本发明中乳化沥青为固含量为55%~60%的阳离子型聚合物改性乳化沥青,符合《微表处和稀浆封层技术指南》(JTG/T F40-02-2005)中BCR型的规定。Emulsified asphalt: The emulsified asphalt in the present invention is a cationic polymer-modified emulsified asphalt with a solid content of 55% to 60%, which complies with the "Technical Guidelines for Microsurfacing and Slurry Sealing" (JTG/T F40-02-2005) Medium BCR type regulations.

拌合水:拌合水即将上述各组分混合进行拌合用水,按水源可分为饮用水、地表水、地下水、海水,以及经适当处理或处置后的工业废水;通常情况下,拌合水的来源对混凝土材料的强度几乎没有影响,技术人员可依据建筑规范要求进行常规选择,本发明提供的实施方式中,所述拌合水采用自来水即可。Mixing water: Mixing water is the mixing water used to mix the above components. According to the water source, it can be divided into drinking water, surface water, groundwater, sea water, and industrial wastewater after appropriate treatment or disposal; usually, mixing water The source of water has almost no impact on the strength of concrete materials, and technicians can make routine selections according to the requirements of building regulations. In the embodiment provided by the present invention, tap water can be used as the mixing water.

机制砂:机制砂是通过制砂机和其它附属设备加工而成的砂子,与河砂相比,机制砂对MPC材料拌合物的性能影响不大。同时,机制砂还具有节能减排、污染小、制造成本低等一系列优势,因此在该体系中使用机制砂作为骨料较好。机制砂的粒径为40-80目。Machine-made sand: Machine-made sand is sand processed through a sand making machine and other ancillary equipment. Compared with river sand, machine-made sand has little impact on the performance of the MPC material mixture. At the same time, machine-made sand also has a series of advantages such as energy saving and emission reduction, low pollution, and low manufacturing cost. Therefore, it is better to use machine-made sand as aggregate in this system. The particle size of machine-made sand is 40-80 mesh.

粗集料:本发明优选采用与阳离子乳化沥青适配性更好的玄武岩,级配选用骨架密实结构SMA-13,按照JTG E42-2005《公路工程集料试验规程》对集料进行筛分。Coarse aggregate: This invention preferably uses basalt that is better compatible with cationic emulsified asphalt. The gradation uses SMA-13 with a dense skeleton structure. The aggregate is screened in accordance with JTG E42-2005 "Highway Engineering Aggregate Test Regulations".

抗分散剂:所述抗分散剂中包括如下重量份的各组分:纤维素醚0.05~0.15份,纳米SiO2 1~3份,超细粉煤灰0~5份。其中,超细粉煤灰起到维持浆液稳定性的作用,且对流动性影响较小,在纤维素醚及纳米SiO2添加后起到辅助作用,如果施工现场对流动性有一定要求,可加大超细粉煤灰掺量并减少纤维素醚及纳米SiO2的掺量。Anti-dispersion agent: The anti-dispersion agent includes the following components by weight: 0.05 to 0.15 parts of cellulose ether, 1 to 3 parts of nano-SiO 2 , and 0 to 5 parts of ultrafine fly ash. Among them, ultrafine fly ash plays a role in maintaining the stability of the slurry and has little impact on the fluidity. It plays an auxiliary role after the addition of cellulose ether and nano- SiO2 . If the construction site has certain requirements on fluidity, it can be Increase the amount of ultrafine fly ash and reduce the amount of cellulose ether and nano- SiO2 .

涉及磷酸镁水泥粉料,本发明还提供如下优选的方案:Relating to magnesium phosphate cement powder, the present invention also provides the following preferred solutions:

重烧氧化镁:本发明采用的重烧氧化镁是菱镁矿经高温煅烧后再经过破碎、粉磨后获得,外观为淡黄色,纯度为90%及以上,细度不大于200目;具体的实例中,氧化镁的纯度大约为91%。Dead-burned magnesium oxide: The dead-burned magnesium oxide used in the present invention is obtained by calcining magnesite at high temperature and then crushing and grinding. It has a light yellow appearance, a purity of 90% and above, and a fineness of no more than 200 mesh; specifically In the example, the purity of magnesium oxide is approximately 91%.

硼砂:本发明中硼砂作为材料中的缓凝剂发挥作用,多选用十水硼砂,为结晶性白色粉末,密度1.72g/cm3,纯度大于95%。Borax: In the present invention, borax functions as a retarder in the material. Borax decahydrate is often used, which is a crystalline white powder with a density of 1.72g/cm 3 and a purity greater than 95%.

磷酸二氢氨:工业级,为白色粉末颗粒,NH4H2PO4含量为99%。Ammonium dihydrogen phosphate: industrial grade, white powder particles, NH 4 H 2 PO 4 content is 99%.

矿粉:细度小于1μm的占80%以上,平均粒径在0.1-0.3μm。Ore powder: more than 80% of the mineral powder has a fineness less than 1 μm, and the average particle size is 0.1-0.3 μm.

硅灰:硅灰的平均粒径为0.1-0.15μm。Silica fume: The average particle size of silica fume is 0.1-0.15μm.

粉煤灰:其平均粒径分布约为8~20μm,比表面积为300~600m2/kg;进一步地,粗集料按照磷酸镁水泥基体粉料总质量1.25~4倍添加,粗集料选择粒径较小且差异性较小的碎石(可参照道路养护标准中的碎石粒径要求),粗集料的添加量过小会导致原有沥青路面与修补区域均一性的差异过大,且路面防滑性较差;而粗集料占比过大导致材料未能将粗集料包裹,集料间的凝结性能受到影响,经试验得到,粗集料在MPC质量的1.25~4倍之间时,性能较为出色。Fly ash: its average particle size distribution is about 8 to 20 μm, and its specific surface area is 300 to 600 m 2 /kg; further, coarse aggregate is added according to 1.25 to 4 times the total mass of magnesium phosphate cement matrix powder, and the coarse aggregate is selected For gravel with smaller particle size and less variability (refer to the gravel particle size requirements in road maintenance standards), too small an amount of coarse aggregate will lead to an excessive difference in uniformity between the original asphalt pavement and the repair area. , and the pavement has poor skid resistance; and the excessive proportion of coarse aggregate causes the material to fail to wrap the coarse aggregate, and the coagulation performance between the aggregates is affected. According to the test, the coarse aggregate is 1.25 to 4 times the mass of the MPC In between, the performance is excellent.

本发明第二方面,提供第一方面所述快硬早强材料的制备方法,包括如下步骤:A second aspect of the present invention provides a method for preparing the fast hardening and early strength material described in the first aspect, which includes the following steps:

将磷酸二氢铵、硼砂、重烧氧化镁、矿粉、硅灰、粉煤灰按一定配比混均配制成MPC干料;将乳化沥青及拌合水混合进行低速搅拌,缓慢加入MPC干料及抗分散剂,充分混匀形成MPC-EA胶结料;Mix ammonium dihydrogen phosphate, borax, dead-burned magnesium oxide, mineral powder, silica fume, and fly ash according to a certain ratio to prepare MPC dry material; mix emulsified asphalt and mixing water for low-speed stirring, and slowly add MPC dry material Material and anti-dispersion agent, mix thoroughly to form MPC-EA cementing material;

然后加入机制砂高速搅拌形成MPC-EA砂浆;最后加入粗集料,高速搅拌制备出MPC-EA混合料,将其摊铺在路面上形成所述稀浆封层。Then, machine-made sand is added and stirred at high speed to form MPC-EA mortar; finally, coarse aggregate is added and stirred at high speed to prepare the MPC-EA mixture, which is spread on the road surface to form the slurry seal layer.

优选的,所述低速搅拌的转速为140±5r/min,搅拌时间为0.1~1min.Preferably, the low-speed stirring speed is 140 ± 5 r/min, and the stirring time is 0.1 to 1 min.

优选的,上述MPC干料和抗分散剂应当采用缓慢均匀的速度加入,优选的方案中,在0.8~1.2min内加完,加完后持续搅拌2~4min得到MPC-EA胶结料。Preferably, the above-mentioned MPC dry material and anti-dispersion agent should be added at a slow and uniform speed. In the preferred solution, the addition is completed within 0.8 to 1.2 minutes. After the addition, the MPC-EA cementing material is continuously stirred for 2 to 4 minutes.

优选的,所述高速搅拌的速度为285±3r/min,搅拌时间为3~5min。Preferably, the speed of the high-speed stirring is 285 ± 3 r/min, and the stirring time is 3 to 5 minutes.

上述MPC-EA混合料摊铺在路面上,有必要的情况下,可以通过手工修复局部施工缺陷,自然养护1.5~2h,即可开放交通。The above-mentioned MPC-EA mixture is paved on the road. If necessary, local construction defects can be repaired manually and maintained naturally for 1.5 to 2 hours before it can be opened to traffic.

优选的,所述MPC-EA混合料摊铺压实速度应与拌合量保持一致,且厚度不超过3cm。Preferably, the paving and compaction speed of the MPC-EA mixture should be consistent with the mixing amount, and the thickness should not exceed 3cm.

为了使得本领域技术人员能够更加清楚地了解本发明的技术方案,以下将结合具体的实施例详细说明本发明的技术方案。In order to enable those skilled in the art to understand the technical solution of the present invention more clearly, the technical solution of the present invention will be described in detail below with reference to specific embodiments.

实施例1Example 1

一种应用于乳化沥青稀浆封层的快硬早强材料由重烧氧化镁、磷酸二氢铵和硼砂混合均匀,配置得到胶凝材料,再与乳化沥青和水混合得到MPC-乳化沥青复合体系。磷酸镁水泥基材料质量分数:重烧氧化镁15份和磷酸二氢铵5份,硼砂掺量为1份,粉煤灰5份,矿粉1份,硅灰1份。A fast-hardening early-strength material used in emulsified asphalt slurry seals is mixed evenly with dead-burned magnesium oxide, ammonium dihydrogen phosphate and borax, configured to obtain a cementitious material, and then mixed with emulsified asphalt and water to obtain MPC-emulsified asphalt composite system. The mass fraction of magnesium phosphate cement-based materials: 15 parts of dead-burned magnesium oxide and 5 parts of ammonium dihydrogen phosphate, 1 part of borax, 5 parts of fly ash, 1 part of mineral powder, and 1 part of silica fume.

所述的抗分散剂中,纤维素醚:纳米SiO2:超细粉煤灰=0.05:1:3。In the anti-dispersion agent, cellulose ether: nano-SiO 2 : ultrafine fly ash = 0.05:1:3.

乳化沥青掺量为12份;机制砂,13份;SMA-13粗集料,50份;拌合水为8份。The dosage of emulsified asphalt is 12 parts; machine-made sand, 13 parts; SMA-13 coarse aggregate, 50 parts; and mixing water, 8 parts.

将磷酸二氢铵、硼砂、重烧氧化镁、矿粉、硅灰、粉煤灰按配比混均配制成MPC干料;将乳化沥青及拌合水混合后低速搅拌1min,缓慢加入MPC干料及抗分散剂,在0.8~1.2min内加完,加完后持续搅拌2~4min,充分混匀形成MPC-EA胶结料;Mix ammonium dihydrogen phosphate, borax, dead-burned magnesium oxide, mineral powder, silica fume, and fly ash according to the proportions to prepare MPC dry material; mix emulsified asphalt and mixing water and stir at low speed for 1 minute, then slowly add MPC dry material and The anti-dispersion agent should be added within 0.8 to 1.2 minutes. After the addition, continue to stir for 2 to 4 minutes and mix thoroughly to form MPC-EA cement;

然后加入机制砂高速搅拌形成MPC-EA砂浆;最后加入粗集料,高速搅拌4min制备出MPC-EA混合料,将其摊铺在路面上形成所述稀浆封层;上述搅拌过程在行星式砂浆搅拌机中进行,采用仪器自转方式,其高速搅拌的转速为285±3r/min,低速搅拌的转速为140±5r/min。Then add machine-made sand and stir at high speed to form MPC-EA mortar; Finally, add coarse aggregate and stir at high speed for 4 minutes to prepare the MPC-EA mixture, which is spread on the road surface to form the slurry seal; the above mixing process is carried out in a planetary type It is carried out in a mortar mixer, using the instrument rotation mode. The high-speed mixing speed is 285±3r/min, and the low-speed mixing speed is 140±5r/min.

按上述拌合方法搅拌均匀后,测试其可工作时间在40min左右,在待养护路段摊铺均匀,压实。放置警示物,自然养护2h即可开放交通。After mixing evenly according to the above mixing method, the working time is tested to be about 40 minutes. Pave the road section to be maintained evenly and compact it. Place warning signs and allow for natural curing for 2 hours before opening to traffic.

实施例2Example 2

本实施具体方式与实施例1仅有下述材料的比例分数不同,操作步骤及材料组成基本一致,采用了重烧氧化镁、磷酸二氢铵和硼砂混合均匀,配制得到胶凝材料,再与乳化沥青和水混合得到MPC-乳化沥青复合体系。磷酸镁水泥基材料质量分数:重烧氧化镁20份和磷酸二氢铵7份,硼砂掺量为1.2份,粉煤灰10份,矿粉0份,硅灰2份。The specific mode of this implementation is different from Example 1 only in the proportions of the following materials. The operating steps and material composition are basically the same. Dead-burned magnesium oxide, ammonium dihydrogen phosphate and borax are mixed evenly to prepare a gelling material, which is then mixed with Emulsified asphalt and water are mixed to obtain an MPC-emulsified asphalt composite system. The mass fraction of magnesium phosphate cement-based materials: 20 parts of dead-burned magnesium oxide and 7 parts of ammonium dihydrogen phosphate, 1.2 parts of borax, 10 parts of fly ash, 0 parts of mineral powder, and 2 parts of silica fume.

所述的抗分散剂中,纤维素醚:纳米SiO2:超细粉煤灰=0.1:1:5。In the anti-dispersion agent, cellulose ether: nano-SiO 2 : ultrafine fly ash = 0.1:1:5.

乳化沥青掺量为20份;机制砂,10份;SMA-13集料,60份;拌合水为8份。The dosage of emulsified asphalt is 20 parts; machine-made sand, 10 parts; SMA-13 aggregate, 60 parts; and mixing water, 8 parts.

按实施例1中拌合方法搅拌均匀后,测试其可工作时间在23min左右,在待养护路段摊铺均匀,压实。放置警示物,自然养护1.5h即可开放交通。After mixing evenly according to the mixing method in Example 1, the working time is tested to be about 23 minutes, and the road section to be maintained is paved evenly and compacted. Place warning signs and it will be open to traffic after 1.5 hours of natural curing.

实施例3Example 3

本实施具体方式与实施例1仅有下述材料的比例分数不同,操作步骤及材料组成基本一致,采用了重烧氧化镁、磷酸二氢铵和硼砂混合均匀,配制得到胶凝材料,再与乳化沥青和水混合得到MPC-乳化沥青复合体系:磷酸镁水泥基材料质量分数:重烧氧化镁20份和磷酸二氢铵5份,硼砂掺量为1.6份,粉煤灰15份,矿粉2份,硅灰2份。The specific mode of this implementation is different from Example 1 only in the proportions of the following materials. The operating steps and material composition are basically the same. Dead-burned magnesium oxide, ammonium dihydrogen phosphate and borax are mixed evenly to prepare a gelling material, which is then mixed with Emulsified asphalt and water are mixed to obtain an MPC-emulsified asphalt composite system: magnesium phosphate cement-based material mass fraction: 20 parts of burned magnesium oxide and 5 parts of ammonium dihydrogen phosphate, borax content is 1.6 parts, fly ash 15 parts, mineral powder 2 parts, 2 parts silica fume.

所述的抗分散剂中,纤维素醚:纳米SiO2:超细粉煤灰=0.1:2:0。In the anti-dispersion agent, cellulose ether: nano-SiO 2 : ultrafine fly ash = 0.1:2:0.

乳化沥青掺量为25份;机制砂,15份;SMA-13集料,40份;拌合水为10份。The dosage of emulsified asphalt is 25 parts; machine-made sand, 15 parts; SMA-13 aggregate, 40 parts; and mixing water, 10 parts.

按实施例1中拌合方法搅拌均匀后,测试其可工作时间在20min左右,在待养护路段摊铺均匀,压实。放置警示物,自然养护1.5h即可开放交通。After mixing evenly according to the mixing method in Example 1, the working time is tested to be about 20 minutes, and the road section to be maintained is paved evenly and compacted. Place warning signs and it will be open to traffic after 1.5 hours of natural curing.

实施例4Example 4

本实施具体方式与实施例1仅有下述材料的比例分数不同,操作步骤及材料组成基本一致,采用了重烧氧化镁、磷酸二氢铵和硼砂混合均匀,配制得到胶凝材料,再与固含量60%的乳化沥青和水混合得到MPC-乳化沥青复合体系磷酸镁水泥基材料质量分数:重烧氧化镁15份和磷酸二氢铵5份,硼砂掺量为2份,粉煤灰20份,矿粉5份,硅灰5份。The specific mode of this implementation is different from Example 1 only in the proportions of the following materials. The operating steps and material composition are basically the same. Dead-burned magnesium oxide, ammonium dihydrogen phosphate and borax are mixed evenly to prepare a gelling material, which is then mixed with Emulsified asphalt with a solid content of 60% is mixed with water to obtain MPC-emulsified asphalt composite system magnesium phosphate cement-based material mass fraction: 15 parts of burned magnesium oxide and 5 parts of ammonium dihydrogen phosphate, 2 parts of borax, and 20 parts of fly ash parts, 5 parts of mineral powder, 5 parts of silica fume.

所述的抗分散剂中,纤维素醚:纳米SiO2:超细粉煤灰=0.15:3:10。In the anti-dispersion agent, cellulose ether: nano-SiO 2 : ultrafine fly ash = 0.15:3:10.

乳化沥青掺量为30份;机制砂,15份;SMA-13集料,45份;拌合水为10份。The dosage of emulsified asphalt is 30 parts; machine-made sand, 15 parts; SMA-13 aggregate, 45 parts; and mixing water, 10 parts.

按实施例1中拌合方法搅拌均匀后,测试其可工作时间在50min左右,在待养护路段摊铺均匀,压实。放置警示物,自然养护2h即可开放交通。After mixing evenly according to the mixing method in Example 1, the working time is tested to be about 50 minutes, and the road section to be maintained is paved evenly and compacted. Place warning signs and allow for natural curing for 2 hours before opening to traffic.

实施例5Example 5

本实施具体方式与实施例一仅有下述材料的比例分数不同,操作步骤及材料组成基本一致,采用了重烧氧化镁、磷酸二氢铵和硼砂混合均匀,配制得到胶凝材料磷酸镁水泥基材料质量分数:重烧氧化镁10份和磷酸二氢铵5份,硼砂掺量为1份,粉煤灰20份,矿粉7份,硅灰5份。The specific mode of this implementation is different from Example 1 only in the proportions of the following materials. The operating steps and material composition are basically the same. Dead-burned magnesium oxide, ammonium dihydrogen phosphate and borax are mixed evenly to prepare the cementing material magnesium phosphate cement. Base material mass fraction: 10 parts of dead burnt magnesium oxide and 5 parts of ammonium dihydrogen phosphate, 1 part of borax, 20 parts of fly ash, 7 parts of mineral powder, and 5 parts of silica fume.

所述的抗分散剂中,纤维素醚:纳米SiO2:超细粉煤灰=0.15:2:5。In the anti-dispersion agent, cellulose ether: nano-SiO 2 : ultrafine fly ash = 0.15:2:5.

乳化沥青掺量为25份;机制砂,15份;SMA-13集料,50份;拌合水为15份。The dosage of emulsified asphalt is 25 parts; machine-made sand, 15 parts; SMA-13 aggregate, 50 parts; and mixing water, 15 parts.

按实施例1中拌合方法搅拌均匀后,测试其可工作时间在60min左右,在待养护路段摊铺均匀,压实。放置警示物,自然养护2h即可开放交通。After mixing evenly according to the mixing method in Example 1, the working time is tested to be about 60 minutes, and the road section to be maintained is paved evenly and compacted. Place warning signs and allow for natural curing for 2 hours before opening to traffic.

关于MPC-乳化沥青复合体系的相关性能并没有明确的规范测试方法,本发明因材料的快硬特性,主要针对其可工作时间(即浆体失去流动性时间)、硬化时间、无侧限抗压强度,抗弯强度及与旧基体粘结强度等进行初步工作性能测试。There is no clear standard test method for the relevant performance of the MPC-emulsified asphalt composite system. Due to the rapid hardening characteristics of the material, the present invention mainly focuses on its working time (that is, the time when the slurry loses fluidity), hardening time, and unconfined resistance. Preliminary performance tests were conducted on compressive strength, flexural strength and bonding strength with the old matrix.

实施例1至实施例5具体性能参数测试值见表1:The specific performance parameter test values of Examples 1 to 5 are shown in Table 1:

表1材料性能测试结果Table 1 Material performance test results

由上述试验数据可知,本发明材料的凝结时间可通过调节配合比来实现,凝结时间可在30~70min内调节,混合料的强度明显高于同比例下砂浆的强度,复合材料能适应不同环境不同道路下的不同施工要求,养护条件简单,对交通影响较小,大大地减少了经济损失和安全隐患;并且MPC材料的快硬早强性能使得其1h内强度发展迅速,能够为乳化沥青稀浆封层材料领域提供一种新的选择。It can be seen from the above test data that the setting time of the material of the present invention can be achieved by adjusting the mix ratio. The setting time can be adjusted within 30 to 70 minutes. The strength of the mixture is significantly higher than that of mortar under the same proportion. The composite material can adapt to different environments. Different construction requirements on different roads, simple maintenance conditions, little impact on traffic, greatly reducing economic losses and safety hazards; and the rapid hardening and early strength properties of MPC materials enable its strength to develop rapidly within 1 hour, which can be used to thin emulsified asphalt. Slurry sealant materials provide a new choice.

以上所述仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modifications, equivalent substitutions, improvements, etc. made within the spirit and principles of the present invention shall be included in the protection scope of the present invention.

Claims (10)

1. The quick hardening early strength material applied to the emulsified asphalt slurry seal layer is characterized by comprising the following raw materials in parts by weight: 21-50 parts of magnesium phosphate cement matrix powder, 10-25 parts of emulsified asphalt, 5-15 parts of mixing water, 5-20 parts of machine-made sand, 40-60 parts of coarse aggregate and 0.5-1 part of anti-dispersant;
the magnesium phosphate cement powder is prepared from 10-20 parts of re-burned magnesium oxide, 1-4 parts of borax, 5-10 parts of monoammonium phosphate, 0-3 parts of mineral powder, 0-3 parts of silica fume and 5-10 parts of fly ash.
2. A rapid hardening early strength material for an emulsified asphalt slurry seal according to claim 1,
the emulsified asphalt is cationic polymer modified emulsified asphalt with the solid content of 55-60 percent, and accords with the BCR type regulation in micro-surfacing and slurry seal technical guidelines (JTG/T F40-02-2005);
the mixing water is tap water;
the grain diameter of the machine-made sand is 40-80 meshes;
the coarse aggregate is basalt, SMA-13 is selected for grading, and aggregate is screened according to JTG E42-2005 Highway engineering aggregate test procedure.
3. The rapid hardening early strength material applied to an emulsified asphalt slurry seal layer according to claim 1, wherein the anti-dispersant comprises the following components in parts by weight: cellulose ether 0.05-0.15 parts, nano SiO 2 1-3 parts of superfine fly ash and 0-5 parts of superfine fly ash.
4. The rapid hardening early strength material for an emulsified asphalt slurry seal layer according to claim 1, wherein the re-burned magnesia is obtained by calcining magnesite at high temperature, crushing and grinding, and has a light yellow appearance, purity of 90% or above, fineness of not more than 200 meshes and purity of 91%;
the borax adopts borax decahydrate as crystalline white powder with density of 1.72g/cm 3 The purity is more than 95 percent.
5. The rapid hardening early strength material for an emulsified asphalt slurry seal according to claim 1, wherein said monoammonium phosphate is technical grade, white powder particles, NH 4 H 2 PO 4 The content is 99%;
the fineness of the mineral powder is less than 1 mu m and accounts for more than 80%, and the average grain diameter is 0.1-0.3 mu m.
6. The rapid hardening early strength material for an emulsified asphalt slurry seal layer according to claim 1, wherein the silica fume has an average particle diameter of 0.1 to 0.15 μm;
the average particle size distribution of the fly ash is 8-20 mu m, and the specific surface area is 300-600 m 2 /kg。
7. The rapid hardening early-strength material applied to an emulsified asphalt slurry seal layer according to claim 1, wherein the coarse aggregate is added according to 1.25-4 times of the total mass of magnesium phosphate cement matrix powder, and the coarse aggregate selects broken stone with smaller particle size and smaller difference, and refers to the broken stone particle size requirement in a road maintenance standard.
8. The method for preparing the rapid hardening early strength material according to any one of claims 1 to 7, comprising the steps of: mixing monoammonium phosphate, borax, re-burned magnesia, mineral powder, silica fume and fly ash according to a certain proportion to prepare an MPC dry material; mixing emulsified asphalt and mixing water, stirring at a low speed, slowly adding MPC dry material and anti-dispersant, and fully and uniformly mixing to form MPC-EA cementing material;
then adding machine-made sand and stirring at high speed to form MPC-EA mortar; and finally adding coarse aggregate, stirring at a high speed to prepare an MPC-EA mixture, and paving the MPC-EA mixture on a pavement to form the slurry seal.
9. The method for preparing a rapid hardening early-strength material according to claim 8, wherein the rotation speed of the low-speed stirring is 140+ -5 r/min, the stirring time is 0.1-1 min, the rotation speed of the high-speed stirring is 285+ -3 r/min, and the stirring time is 3-5 min;
or, the MPC dry material and the anti-dispersant are added within 0.8-1.2 min, and stirring is continued for 2-4 min after the addition is finished, so as to obtain the MPC-EA cementing material.
10. The method for preparing the rapid hardening early-strength material according to claim 8, wherein the MPC-EA mixture is paved on a road surface, and natural curing is carried out for 1.5-2 hours, so that the traffic can be opened;
or, the paving compaction speed of the MPC-EA mixture is consistent with the mixing amount, and the thickness of the MPC-EA mixture is not more than 3cm.
CN202310726925.3A 2023-06-19 2023-06-19 Quick hardening early strength material applied to emulsified asphalt slurry seal layer and preparation method thereof Pending CN117125955A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310726925.3A CN117125955A (en) 2023-06-19 2023-06-19 Quick hardening early strength material applied to emulsified asphalt slurry seal layer and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310726925.3A CN117125955A (en) 2023-06-19 2023-06-19 Quick hardening early strength material applied to emulsified asphalt slurry seal layer and preparation method thereof

Publications (1)

Publication Number Publication Date
CN117125955A true CN117125955A (en) 2023-11-28

Family

ID=88859073

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202310726925.3A Pending CN117125955A (en) 2023-06-19 2023-06-19 Quick hardening early strength material applied to emulsified asphalt slurry seal layer and preparation method thereof

Country Status (1)

Country Link
CN (1) CN117125955A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN118479839A (en) * 2024-04-26 2024-08-13 石家庄同人路桥工程有限公司 Composite sealing layer material for road maintenance and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN118479839A (en) * 2024-04-26 2024-08-13 石家庄同人路桥工程有限公司 Composite sealing layer material for road maintenance and preparation method thereof

Similar Documents

Publication Publication Date Title
CN104312175B (en) A kind of asphalt modifier, modified emulsifying asphalt and modified asphalt mixture and each preparation method
CN102505601B (en) Fast repairing method for asphalt concrete pavement
CN103450692B (en) A kind of regeneration half-flexible pavement material and preparation method thereof
CN101187193A (en) A semi-flexible drainage anti-skid noise reduction pavement structure
CN103242002A (en) Cold-mix semi-flexible composite pavement material and preparation method thereof
CN103952958A (en) Method for rut maintaining and paving of municipal road
CN104762861A (en) Semi-flexible pavement based on cold-recycling base of bituminous pavement and construction method of semi-flexible pavement
CN106495585A (en) Geo-polymer based heavy-load paving material and preparation method thereof
CN107572981A (en) Self-compacting concrete for concrete repair and preparation method thereof
CN103204654B (en) Micro-surfacing mixing material doped with rock asphalt and preparation method thereof
CN1644800A (en) Bridge paving material with big span
CN106800400B (en) A kind of preparation method and applications of road repair mortar dry powder
CN112694304A (en) Cold recycling and old asphalt pavement cold joint adhesive for pavement reconstruction and extension
CN117125955A (en) Quick hardening early strength material applied to emulsified asphalt slurry seal layer and preparation method thereof
CN114276049B (en) Environment-friendly asphalt-cement composite material, preparation method and construction process
CN1558032A (en) Manufacturing method of high-porosity permeable concrete pavement containing active minerals
CN107555919A (en) Bridge grouting material and the method using its quick repair bridge expansion joint
CN110128070A (en) Graded crushed stone poured semi-flexible composite pavement mixture and pavement construction method
CN211645819U (en) Old cement road surface adds spreads semi-flexible material road surface structure
CN107721330A (en) Permanent seal cooling Identification Beneath Concrete Slabs injecting paste material and preparation method thereof
CN118439821A (en) High-performance steel slag cold-mixing cold-paving wearing layer material and preparation method thereof
CN107759166A (en) Half-flexible pavement material and can quick open to traffic half-flexible pavement paving method
CN111499240A (en) A kind of red mud fiber composite material, its preparation method and application in modified asphalt
CN114716180B (en) High-performance colored semi-flexible pavement material for urban heavy-duty roads
CN106758647B (en) A kind of method of asphalt pavement pit repairing

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination