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CN116002685A - A production and preparation system for powdered activated carbon - Google Patents

A production and preparation system for powdered activated carbon Download PDF

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Publication number
CN116002685A
CN116002685A CN202310158580.6A CN202310158580A CN116002685A CN 116002685 A CN116002685 A CN 116002685A CN 202310158580 A CN202310158580 A CN 202310158580A CN 116002685 A CN116002685 A CN 116002685A
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set temperature
activated carbon
coal
activation
gas
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CN116002685B (en
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刘嘉鹏
吴桂安
段家奇
刘志雨
何文婷
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Zhongke Hefei Coal Gasification Technology Co ltd
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Abstract

The invention discloses a production and preparation system of powdery activated carbon, and relates to the field of coal gasification ash combustion; activating working section equipment enables the production raw materials to undergo an activating reaction under the action of an activating agent to obtain an activated product with a first set temperature; the activated product with the first set temperature heats air in the waste heat recovery device to obtain heated air and an activated product with the second set temperature, and the waste heat recovery device exchanges heat with the activated product with the second set temperature and cools the activated product with the second set temperature to obtain a recovered product with the third set temperature; the heated air is used as an activating agent and is transmitted to activating section equipment; the dry type filtering and collecting equipment collects activated carbon powder carbon in the recovered product with the third set temperature, and separates the activated carbon powder carbon in the recovered product with the third set temperature from the gas mixture; the invention can realize the conversion of powdery active carbon and reduce the cost.

Description

一种粉状活性炭生产制备系统A production and preparation system for powdered activated carbon

技术领域technical field

本发明涉及煤气化灰渣燃烧领域,特别是涉及一种粉状活性炭生产制备系统。The invention relates to the field of coal gasification ash combustion, in particular to a production and preparation system for powdered activated carbon.

背景技术Background technique

为积极建设生态文明社会,对环保的要求越来越高。活性炭作为广泛的吸附材料在各种领域均得到广泛应用。目前活性炭主要生产工艺流程可以分为原煤破碎活性炭、成型活性炭(柱状、压块)和粉状活性炭3种。原煤破碎活性炭生产工艺适合具有较高物理强度和反应活性的原料煤,对原料要求高;成型活性炭生产工艺多为颗粒炭,蒸汽消耗量大。粉状活性炭多以优质木屑为原料,经特殊生产工艺精制而成。In order to actively build an ecologically civilized society, the requirements for environmental protection are getting higher and higher. Activated carbon has been widely used as a wide range of adsorption materials in various fields. At present, the main production process of activated carbon can be divided into three types: raw coal crushed activated carbon, shaped activated carbon (column, briquette) and powdered activated carbon. The raw coal crushing activated carbon production process is suitable for raw coal with high physical strength and reactivity, and has high requirements for raw materials; the shaped activated carbon production process is mostly granular carbon, and the steam consumption is large. Powdered activated carbon is mostly made of high-quality wood chips and refined through special production processes.

对比颗粒活性炭和粉状活性炭的应用,颗粒状活性炭可用于液相和气相的吸附,一般是用于处理需要连续通过活性炭的气体。颗粒状活性炭的特点是:适用于连续工艺与自动控制,因价格较高大量使用时应予再生,且较易再生;粉状活性炭用于液相吸附,价格较低,加入液体后经搅拌混合、过滤或沉降,而得所要的液体,同时粉状活性炭的特点是:适用于间歇工艺、易控制加入量、可利用现成过滤设备,与颗粒炭相比,有不同的市场需求。然而现有市场上大多数为颗粒炭,缺乏粉状活性炭。Comparing the application of granular activated carbon and powdered activated carbon, granular activated carbon can be used for liquid phase and gas phase adsorption, and is generally used to treat gases that need to pass through activated carbon continuously. The characteristics of granular activated carbon are: suitable for continuous process and automatic control, due to the high price, it should be regenerated when used in large quantities, and it is easy to regenerate; powdered activated carbon is used for liquid phase adsorption, the price is low, and it is mixed after adding liquid , Filtration or sedimentation to obtain the desired liquid. At the same time, the characteristics of powdered activated carbon are: suitable for batch processes, easy to control the amount added, and ready-made filtration equipment can be used. Compared with granular carbon, it has different market demands. However, most of them are granular carbons in the existing market and lack powdery activated carbons.

气化灰的含炭量较高,可作为粉末活性炭制备原料,仅作为固废直接处理是对炭资源的白白浪费,因此,将煤气化产生的气化灰加工成粉状活性炭产品,当地转化,能够达到资源整合利用的目的,满足市场对活性炭的不同需求,同时增加煤气化企业经济效益,实现变废为宝。那么,如何实现将气化灰转化成粉状活性炭至关重要。Gasification ash has a high carbon content and can be used as a raw material for powdered activated carbon. It is a waste of carbon resources to be directly treated as solid waste. Therefore, the gasification ash produced by coal gasification is processed into powdered activated carbon products and converted locally. , can achieve the purpose of resource integration and utilization, meet the different needs of the market for activated carbon, and at the same time increase the economic benefits of coal gasification enterprises, and realize the transformation of waste into wealth. Then, how to realize the conversion of gasification ash into powdered activated carbon is very important.

发明内容Contents of the invention

本发明的目的是提供一种粉状活性炭生产制备系统,可实现粉状活性炭的转化并降低成本。The purpose of the present invention is to provide a production and preparation system for powdered activated carbon, which can realize the transformation of powdered activated carbon and reduce the cost.

为实现上述目的,本发明提供了如下方案:To achieve the above object, the present invention provides the following scheme:

一种粉状活性炭生产制备系统,所述系统包括:活化工段设备、余热回收设备和干式过滤收集设备;A powdery activated carbon production and preparation system, the system includes: activation section equipment, waste heat recovery equipment and dry filtration collection equipment;

所述活化工段设备与所述干式过滤收集设备均与所述余热回收设备连接;Both the activation section equipment and the dry filter collection equipment are connected to the waste heat recovery equipment;

所述活化工段设备,用于:The activation section equipment is used for:

将生产原料在活化剂的作用下发生活化反应,得到第一设定温度的活化产物;所述生产原料包括:启炉原煤和气化灰;所述活化产物为粉气混合物;所述粉气混合物为活性炭粉炭和煤气的混合物;所述启炉原煤为粒径不大于设定粒径的煤;The production raw materials undergo an activation reaction under the action of an activator to obtain an activated product at a first set temperature; the production raw materials include: raw coal for starting the furnace and gasification ash; the activated product is a powder-gas mixture; the powder-gas mixture It is a mixture of activated carbon powder and coal gas; the raw coal for starting the furnace is coal whose particle size is not larger than the set particle size;

所述余热回收设备,用于:The waste heat recovery equipment is used for:

接收所述第一设定温度的活化产物,并利用第一设定温度的活化产物的热量对空气加热,得到加热后的空气和第二设定温度的活化产物;加热后的空气作为活化剂,传输至所述活化工段设备;所述第二设定温度小于所述第一设定温度;Receive the activated product at the first set temperature, and use the heat of the activated product at the first set temperature to heat the air to obtain heated air and the activated product at the second set temperature; the heated air is used as an activator , transmitted to the activation section equipment; the second set temperature is lower than the first set temperature;

对第二设定温度的活化产物进行换热降温处理,得到第三设定温度的回收产物;所述回收产物包括:活性炭粉炭和煤汽混合物;所述第三设定温度小于所述第二设定温度;所述煤汽混合物为煤气和蒸汽的混合物;The activated product at the second set temperature is subjected to heat exchange and cooling treatment to obtain the recovered product at the third set temperature; the recovered product includes: activated carbon powder and gas mixture; the third set temperature is lower than the second set temperature Set temperature; The gas mixture is a mixture of gas and steam;

所述干式过滤收集设备,用于:The dry filter collection equipment is used for:

收集第三设定温度的回收产物中的活性炭粉炭,并将第三设定温度的回收产物中的活性炭粉炭和煤汽混合物进行分离。The activated carbon powder in the recovered product at the third set temperature is collected, and the activated carbon powder and the gas mixture in the recovered product at the third set temperature are separated.

可选地,所述活化工段设备包括:活化炉、旋风分离器和返料器;Optionally, the equipment in the activation section includes: an activation furnace, a cyclone separator and a feeder;

所述旋风分离器分别与所述活化炉与所述余热回收设备连接;所述返料器分别与所述旋风分离器和所述活化炉连接;The cyclone separator is respectively connected with the activation furnace and the waste heat recovery equipment; the return device is respectively connected with the cyclone separator and the activation furnace;

所述活化炉,用于:The activation furnace is used for:

将所述生产原料在活化剂的作用下发生活化反应,得到活化混合物;所述活化混合物为第一设定温度的活化产物以及半焦颗粒煤的混合物;Activating the production raw materials under the action of an activator to obtain an activation mixture; the activation mixture is a mixture of an activation product at a first set temperature and semi-coke granular coal;

所述旋风分离器,用于:Said cyclone separator is used for:

对所述活化混合物进行分离,得到所述半焦颗粒煤和第一设定温度的活化产物;Separating the activation mixture to obtain the semi-coke granular coal and an activation product at a first set temperature;

所述返料器,用于:The feeder is used for:

将所述半焦颗粒煤输送至所述活化炉。The semi-coke granular coal is transported to the activation furnace.

可选地,所述余热回收设备包括:空气预热器和余热锅炉;Optionally, the waste heat recovery equipment includes: an air preheater and a waste heat boiler;

所述空气预热器分别与所述活化工段设备和所述余热锅炉连接;所述余热锅炉还与所述干式过滤收集设备连接;The air preheater is respectively connected with the activation section equipment and the waste heat boiler; the waste heat boiler is also connected with the dry filter collection equipment;

所述空气预热器,用于:The air preheater is used for:

对空气进行预热,得到预热后的空气;Preheat the air to obtain preheated air;

接收所述第一设定温度的活化产物,并利用第一设定温度的活化产物的热量对预热后的空气进行加热,得到加热后的空气和第二设定温度的活化产物;receiving the activated product at the first set temperature, and using the heat of the activated product at the first set temperature to heat the preheated air to obtain heated air and the activated product at the second set temperature;

将加热后的空气传输至所述活化工段设备,以补充活化剂同时为活化反应提供热量;Transport the heated air to the activation section equipment to supplement the activator and provide heat for the activation reaction;

所述余热锅炉,用于:The waste heat boiler is used for:

对第二设定温度的活化产物进行降温处理,得到第三设定温度的活化产物,同时产生饱和或过热蒸汽。The activated product at the second set temperature is cooled to obtain the activated product at the third set temperature, and saturated or superheated steam is generated at the same time.

可选地,所述干式过滤收集设备包括:旋风收集器、旋风收集器仓泵、布袋收集器和布袋收集器仓泵;Optionally, the dry filter collection equipment includes: a cyclone collector, a cyclone collector bin pump, a cloth bag collector and a cloth bag collector bin pump;

所述旋风收集器分别与所述余热回收设备和所述旋风收集器仓泵连接;所述布袋收集器分别与所述旋风收集器和所述布袋收集器仓泵连接;The cyclone collector is respectively connected to the waste heat recovery equipment and the cyclone collector bin pump; the bag collector is connected to the cyclone collector and the bag collector bin pump respectively;

所述旋风收集器用于收集第三设定温度的回收产物中的部分活性炭粉炭,并传输至所述旋风收集器仓泵;The cyclone collector is used to collect part of the activated carbon powder carbon in the recovery product of the third set temperature, and is transported to the cyclone collector bin pump;

所述旋风收集器仓泵用于将所述旋风收集器收集的活性炭粉炭传送至活性炭粉炭仓;The cyclone collector bin pump is used to transfer the activated carbon powder carbon collected by the cyclone collector to the activated carbon powder carbon bin;

所述布袋收集器用于收集第三设定温度的回收产物中的另一部分活性炭粉炭,并传输至所述布袋收集器仓泵;The bag collector is used to collect another part of activated carbon powder carbon in the recovery product of the third set temperature, and transfer to the bag collector warehouse pump;

所述布袋收集器仓泵用于将所述布袋收集器收集的活性炭粉炭,传输至活性炭粉炭仓。The bag collector bin pump is used to transfer the activated carbon powder collected by the bag collector to the activated carbon powder carbon bin.

可选地,所述系统还包括:输料装置;Optionally, the system also includes: a feeding device;

所述输料装置与所述活化工段设备连接;所述输料装置用于输送所述生产原料。The conveying device is connected with the equipment in the activation section; the conveying device is used for conveying the production raw materials.

可选地,所述系统还包括:煤气分离装置;Optionally, the system also includes: a gas separation device;

所述煤气分离装置与所述干式过滤收集设备连接;The gas separation device is connected to the dry filter collection equipment;

所述煤气分离装置用于对第三设定温度的回收产物中的煤汽混合物进行降温处理和分离处理,得到干煤气。The gas separation device is used for cooling and separating the gas mixture in the recovered product at the third set temperature to obtain dry gas.

可选地,所述煤气分离装置包括:煤气冷却罐和煤气分离罐;Optionally, the gas separation device includes: a gas cooling tank and a gas separation tank;

所述煤气冷却罐与所述干式过滤收集设备连接;所述煤气分离罐与所述煤气冷却罐连接;The gas cooling tank is connected to the dry filter collection equipment; the gas separation tank is connected to the gas cooling tank;

所述煤气冷却罐,用于:The gas cooling tank is used for:

对第三设定温度的回收产物中的煤汽混合物进行降温处理,得到第四温度的煤水混合物;所述煤水混合物为煤气和冷凝水的混合物;所述第四温度小于所述第三设定温度;The coal-gas mixture in the recovered product at the third set temperature is cooled to obtain a coal-water mixture at a fourth temperature; the coal-water mixture is a mixture of gas and condensed water; the fourth temperature is lower than the third set temperature;

所述煤气分离罐,用于:The gas separation tank is used for:

将第四温度的煤水混合物进行分离,得到第四温度的煤气和第四温度的冷凝水。The coal-water mixture at the fourth temperature is separated to obtain coal gas at the fourth temperature and condensed water at the fourth temperature.

可选地,所述启炉原煤包括:褐煤、长焰煤、不粘性烟煤、弱粘性烟煤和无烟煤。Optionally, the starting coal includes: lignite, long-flame coal, non-sticky bituminous coal, weakly sticky bituminous coal and anthracite.

根据本发明提供的具体实施例,本发明公开了以下技术效果:According to the specific embodiments provided by the invention, the invention discloses the following technical effects:

本发明提供了一种粉状活性炭生产制备系统,通过活化工段设备将生产原料在活化剂的作用下发生活化反应,得到第一设定温度的活化产物;余热回收设备接收第一设定温度的活化产物并进行降温,再经干式过滤收集设备收集第三设定温度的回收产物中的活性炭粉炭,将其从与煤气的混合物中进行分离;最终得到活性炭粉炭;本发明通过活化工段设备、余热回收设备和干式过滤收集设备,实现启炉原煤和气化灰向粉状活性炭的转化,并实现了工艺生产中的废弃气化灰的回收再利用,减少了资源的浪费,降低了生产成本;由此,本发明能够实现粉状活性炭的转化并降低成本。The invention provides a production and preparation system for powdered activated carbon. The production raw materials are activated under the action of an activator through the activation section equipment to obtain the activated product at the first set temperature; the waste heat recovery equipment receives the first set temperature The activation product is lowered in temperature, and then the activated carbon powder carbon in the recovered product at the third set temperature is collected through a dry filter collection device, and is separated from the mixture with the gas; finally, the activated carbon powder carbon is obtained; the present invention passes through the activation section Equipment, waste heat recovery equipment and dry filter collection equipment realize the transformation of raw coal and gasification ash into powdered activated carbon, and realize the recycling and reuse of waste gasification ash in process production, reducing the waste of resources and reducing the Production cost; thus, the present invention can realize the transformation of powdered activated carbon and reduce the cost.

附图说明Description of drawings

为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动性的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present invention or the prior art, the following will briefly introduce the accompanying drawings required in the embodiments. Obviously, the accompanying drawings in the following description are only some of the present invention. Embodiments, for those of ordinary skill in the art, other drawings can also be obtained according to these drawings without paying creative labor.

图1为本发明实施例提供的状活性炭生产制备系统的结构示意图。Fig. 1 is a schematic structural diagram of a production and preparation system for activated carbon provided in an embodiment of the present invention.

符号说明:Symbol Description:

活化工段设备-1、余热回收设备-2、干式过滤收集设备-3、活化炉-4、旋风分离器-5、返料器-6、空气预热器-7、余热锅炉-8、旋风收集器-9、旋风收集器仓泵-10、布袋收集器-11、布袋收集器仓泵-12、输料装置-13、煤气分离装置-14、煤气冷却罐-15、煤气分离罐-16、尾部余热回收设备-17、冷渣机-18、点火燃烧器-19、飞灰料仓-20、第一飞灰缓冲仓-21、第二飞灰缓冲仓-22、给煤仓-23、第一气体喷射器-24、第二气体喷射器-25。Activation section equipment-1, waste heat recovery equipment-2, dry filter collection equipment-3, activation furnace-4, cyclone separator-5, feeder-6, air preheater-7, waste heat boiler-8, Cyclone collector-9, cyclone collector bin pump-10, cloth bag collector-11, cloth bag collector bin pump-12, material conveying device-13, gas separation device-14, gas cooling tank-15, gas separation tank- 16. Tail waste heat recovery equipment-17, slag cooling machine-18, ignition burner-19, fly ash bin-20, first fly ash buffer bin-21, second fly ash buffer bin-22, coal feeding bin- 23. First gas injector-24, second gas injector-25.

具体实施方式Detailed ways

下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some, not all, embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.

本发明的目的是提供一种粉状活性炭生产制备系统,可实现粉状活性炭的转化并降低成本。The purpose of the present invention is to provide a production and preparation system for powdered activated carbon, which can realize the transformation of powdered activated carbon and reduce the cost.

为使本发明的上述目的、特征和优点能够更加明显易懂,下面结合附图和具体实施方式对本发明作进一步详细的说明。In order to make the above objects, features and advantages of the present invention more comprehensible, the present invention will be further described in detail below in conjunction with the accompanying drawings and specific embodiments.

如图1所示,本发明实施例提供的一种粉状活性炭生产制备系统,该系统包括:活化工段设备1、余热回收设备2和干式过滤收集设备3。As shown in FIG. 1 , a powdered activated carbon production and preparation system provided by an embodiment of the present invention includes: activation section equipment 1 , waste heat recovery equipment 2 and dry filter collection equipment 3 .

活化工段设备1与干式过滤收集设备3均与余热回收设备2连接。活化工段设备1用于将生产原料在活化剂的作用下发生活化反应,得到第一设定温度的活化产物;生产原料包括:启炉原煤和气化灰;第一设定温度的活化产物为粉气混合物;粉气混合物包括:活性炭粉炭和煤气;启炉原煤为粒径不大于设定粒径的煤。具体地,启炉原煤的粒径≤10mm。Both the activation section equipment 1 and the dry filter collection equipment 3 are connected to the waste heat recovery equipment 2 . Activation section equipment 1 is used to activate the production raw materials under the action of an activator to obtain an activated product at the first set temperature; the production raw materials include: raw coal for starting the furnace and gasification ash; the activated product at the first set temperature is Powder-gas mixture; powder-gas mixture includes: activated carbon powder and coal gas; the raw coal for starting furnace is coal whose particle size is not larger than the set particle size. Specifically, the particle size of the furnace-starting raw coal is ≤10 mm.

活化工段设备1中的活化炉4顶部出口接高效的旋风分离器5,旋风分离器5下端接返料器6,返料器6下部出口与活化炉4的炉膛下端相连,形成一个高倍率的外循环回路。具体地,高效的旋风分离器5将活化炉4出口煤气中的半焦与煤气高效分离,实现高效低阻的分离效果,确保活化炉4炉膛可以在微正压条件下运行;返料器6采用高通量U型自平衡返料装置,与活化炉4、旋风分离器5形成高倍率外循环回路。The top outlet of the activation furnace 4 in the activation section equipment 1 is connected to the high-efficiency cyclone separator 5, and the lower end of the cyclone separator 5 is connected to the feeder 6, and the lower outlet of the feeder 6 is connected to the lower end of the furnace of the activation furnace 4 to form a high-power external circulation loop. Specifically, the high-efficiency cyclone separator 5 efficiently separates the semi-coke from the gas at the outlet of the activation furnace 4 to achieve a high-efficiency and low-resistance separation effect, ensuring that the furnace of the activation furnace 4 can operate under slightly positive pressure conditions; the return device 6 A high-throughput U-shaped self-balancing feeding device is adopted to form a high-rate external circulation loop with the activation furnace 4 and the cyclone separator 5.

具体地,活化工段设备1包括:活化炉4、旋风分离器5和返料器6;旋风分离器5分别与活化炉4与余热回收设备2连接;返料器6分别与旋风分离器5和活化炉4连接。Specifically, the activation section equipment 1 includes: an activation furnace 4, a cyclone separator 5 and a feeder 6; the cyclone separator 5 is connected to the activation furnace 4 and the waste heat recovery device 2 respectively; the feeder 6 is connected to the cyclone separator 5 Connect with activation furnace 4.

活化炉4用于将生产原料在活化剂的作用下发生活化反应,得到初始活化产物;初始活化产物为活性炭粉炭、煤气以及半焦颗粒煤的混合物。The activation furnace 4 is used to activate the production raw materials under the action of an activator to obtain an initial activation product; the initial activation product is a mixture of activated carbon powder, gas and semi-coke granular coal.

旋风分离器5用于将初始活化产物中的活性炭粉炭、煤气以及半焦颗粒煤进行分离,得到半焦颗粒煤和第一设定温度的活化产物。返料器6用于将半焦颗粒煤输送至活化炉4。The cyclone separator 5 is used to separate the activated carbon powder, coal gas and semi-coke granular coal in the initial activation product to obtain the semi-coke granular coal and the activated product at the first set temperature. The feeder 6 is used to transport the semi-coke granular coal to the activation furnace 4 .

余热回收设备2用于接收第一设定温度的活化产物;第一设定温度的活化产物的热量对余热回收设备2内的空气加热,得到加热后的空气和第二设定温度的活化产物;加热后的空气的作为活化剂和热源,传输至活化工段设备1;第二设定温度小于第一设定温度。The waste heat recovery device 2 is used to receive the activated product at the first set temperature; the heat of the activated product at the first set temperature heats the air in the waste heat recovery device 2 to obtain the heated air and the activated product at the second set temperature ; The heated air is used as an activator and a heat source, and is transmitted to the activation section equipment 1; the second set temperature is lower than the first set temperature.

余热回收设备2还用于对第二设定温度的活化产物进行降温处理,得到第三设定温度的回收产物;回收产物包括:活性炭粉炭以及煤汽混合物;第三设定温度小于第二设定温度。煤汽混合物为煤气和蒸汽的混合物。The waste heat recovery equipment 2 is also used to cool down the activated product at the second set temperature to obtain the recovered product at the third set temperature; the recovered product includes: activated carbon powder and gas mixture; the third set temperature is lower than the second set temperature set temperature. A gas mixture is a mixture of gas and steam.

余热回收设备2可以由空气预热器7和蒸汽发生器或余热锅炉8等组成。余热回收设备2加热产生的空气和部分蒸汽回送活化炉4炉膛,空气温度为600~800℃,蒸汽温度120~540℃,压力1.2~5.4MPaG。The waste heat recovery equipment 2 may consist of an air preheater 7 and a steam generator or waste heat boiler 8 and the like. The air and part of the steam generated by the heating of the waste heat recovery equipment 2 are returned to the furnace of the activation furnace 4, the air temperature is 600-800°C, the steam temperature is 120-540°C, and the pressure is 1.2-5.4MPaG.

具体地,余热回收设备2包括:空气预热器7和余热锅炉8;空气预热器7分别与活化工段设备1和余热锅炉8连接;余热锅炉8还与干式过滤收集设备3连接。Specifically, the waste heat recovery equipment 2 includes: an air preheater 7 and a waste heat boiler 8; the air preheater 7 is connected to the activation section equipment 1 and the waste heat boiler 8; the waste heat boiler 8 is also connected to the dry filter collection equipment 3.

空气预热器7用于对空气进行预热,得到预热后的空气;空气预热器7还用于接收第一设定温度的活化产物;第一设定温度的活化产物的热量对进入空气预热器7的冷空气进行加热,得到加热后的空气和第二设定温度的活化产物。离开空气预热器7的加热后的空气传输至活化工段设备1。Air preheater 7 is used for preheating air, obtains the air after preheating; Air preheater 7 is also used for receiving the activated product of first set temperature; The heat of the activated product of first set temperature is to entering The cold air of the air preheater 7 is heated to obtain the heated air and the activated product at the second preset temperature. The heated air leaving the air preheater 7 is conveyed to the activation section equipment 1 .

余热锅炉8用于对第二设定温度的活化产物进行降温处理,得到第三设定温度的回收产物;回收产物包括:活性炭粉炭以及煤汽混合物;即余热锅炉8用于对第二设定温度的活化产物进行降温处理,得到第三设定温度的活化产物,同时产生饱和或过热蒸汽。The waste heat boiler 8 is used to lower the temperature of the activated product at the second set temperature to obtain the recovered product at the third set temperature; the recovered product includes: activated carbon powder and gas mixture; that is, the waste heat boiler 8 is used for the second set temperature The activated product of the first temperature is subjected to cooling treatment to obtain the activated product of the third set temperature, and at the same time, saturated or superheated steam is generated.

干式过滤收集设备3用于收集第三设定温度的回收产物中的活性炭粉炭,将第三设定温度的回收产物中的活性炭粉炭和煤气的混合物进行分离。The dry filter collection device 3 is used to collect the activated carbon powder in the recovered product at the third set temperature, and separate the activated carbon powder and the gas mixture in the recovered product at the third set temperature.

干式过滤收集装置捕集的活性炭粉炭,采用气力输送的方式;在旋风收集器9和布袋收集器11下部出口均设置仓泵,浓相输送,气体用氮气,送至中间储存仓。The activated carbon powder collected by the dry filter collection device is conveyed by pneumatic means; the outlet of the cyclone collector 9 and the lower part of the bag collector 11 are equipped with a warehouse pump for dense phase transportation, and the gas is sent to the intermediate storage warehouse with nitrogen.

具体地,干式过滤收集设备3包括:旋风收集器9、旋风收集器仓泵10、布袋收集器11和布袋收集器仓泵12;旋风收集器9分别与余热回收设备2和旋风收集器仓泵10连接;布袋收集器11分别与旋风收集器9和布袋收集器仓泵12连接。Specifically, the dry filter collection equipment 3 includes: a cyclone collector 9, a cyclone collector bin pump 10, a bag collector 11 and a bag collector bin pump 12; the cyclone collector 9 is connected with the waste heat recovery device 2 and the cyclone collector bin The pump 10 is connected; the bag collector 11 is connected with the cyclone collector 9 and the bag collector bin pump 12 respectively.

旋风收集器9用于收集部分第三设定温度的回收产物中的活性炭粉炭;旋风收集器仓泵10用于将旋风收集器9收集的部分活性炭粉炭传送至活性炭粉炭仓;布袋收集器11用于收集另一部分的第三设定温度的回收产物中的活性炭粉炭;布袋收集器仓泵12用于将布袋收集器11收集的另一部分活性炭粉炭传输至活性炭粉炭仓。The cyclone collector 9 is used to collect the active carbon powder carbon in the recovered product of the third preset temperature; the cyclone collector storehouse pump 10 is used to transfer the part activated carbon powder carbon collected by the cyclone collector 9 to the activated carbon powder carbon storehouse; the cloth bag collector 11 is used Collect another part of activated carbon powder charcoal in the recovery product of the third set temperature; the bag collector bin pump 12 is used to transfer another part of activated carbon powder carbon collected by the bag collector 11 to the activated carbon powder carbon bin.

作为一种可选地实施方式,该系统还包括:输料装置13;输料装置13与活化工段设备1连接;输料装置13用于输送生产原料。As an optional embodiment, the system further includes: a conveying device 13; the conveying device 13 is connected to the activation section equipment 1; the conveying device 13 is used for conveying production raw materials.

在一种实施例中,该系统还包括:煤气分离装置14;煤气分离装置14与干式过滤收集设备3连接;煤气分离装置14用于对第三设定温度的回收产物中的煤汽混合物进行降温处理和分离处理,得到干煤气。In one embodiment, the system also includes: gas separation device 14; gas separation device 14 is connected with dry filter collection equipment 3; Perform cooling treatment and separation treatment to obtain dry gas.

具体地,煤气分离装置14包括:煤气冷却罐15和煤气分离罐16;煤气冷却罐与干式过滤收集设备3连接;煤气分离罐16与煤气冷却罐15连接。Specifically, the gas separation device 14 includes: a gas cooling tank 15 and a gas separation tank 16; the gas cooling tank is connected to the dry filter collection device 3;

煤气冷却罐用于对第三设定温度的回收产物中的煤汽混合物进行降温处理,得到第四温度的煤水混合物;煤水混合物包括:煤气和冷凝水;第四温度小于第三设定温度。The gas cooling tank is used to lower the temperature of the gas-gas mixture in the recovered product at the third set temperature to obtain the coal-water mixture at the fourth temperature; the coal-water mixture includes: gas and condensed water; the fourth temperature is lower than the third setting temperature.

煤气分离罐16用于将第四温度的煤水混合物进行分离,得到第四温度的煤气和第四温度的冷凝水。The gas separation tank 16 is used to separate the coal-water mixture at the fourth temperature to obtain the gas at the fourth temperature and the condensed water at the fourth temperature.

在一种实施例中,启炉原煤包括:褐煤、长焰煤、不粘性烟煤、弱粘性烟煤和无烟煤。In one embodiment, the starting raw coal includes lignite, long-flame coal, non-sticky bituminous coal, weakly sticky bituminous coal and anthracite.

该系统还包括尾部余热回收设备17;尾部余热回收设备17回送尾部煤气至活化炉4的底部燃烧器,点燃生成的烟气进入活化炉4的炉膛。活化炉4炉膛底部有均匀布置的风帽。活化炉4的温度为900~1100℃,活化炉4顶的温度为800~1000℃,活化炉4出口高温煤气温度为900~1100℃。The system also includes a tail waste heat recovery device 17; the tail waste heat recovery device 17 returns the tail gas to the bottom burner of the activation furnace 4, and the flue gas generated by ignition enters the furnace of the activation furnace 4. There are evenly arranged wind caps at the bottom of the furnace chamber of the activation furnace 4 . The temperature of activation furnace 4 is 900~1100 ℃, the temperature of activation furnace 4 top is 800~1000 ℃, and the temperature of high temperature gas at the outlet of activation furnace 4 is 900~1100 ℃.

该系统的活化炉4飞灰处理量为0.5~50t/h,活性炭粉炭产量为100~15000kg/h,副产煤气(干煤气)产量为1000~80000Nm3/h(热值1000~2500kcal/Nm3),饱和蒸汽产量为1000~50000kg/h。The fly ash processing capacity of activation furnace 4 of this system is 0.5-50t/h, the output of activated carbon powder is 100-15000kg/h, and the output of by-product gas (dry gas) is 1000-80000Nm 3 /h (calorific value 1000-2500kcal/Nm 3 ), the saturated steam output is 1000~50000kg/h.

本发明提供的粉状活性炭生产制备系统主要包含以下几个部分:The powdered activated carbon production and preparation system provided by the invention mainly includes the following parts:

1.气化灰和启炉原煤的进料;2.活化炉内活化反应;3.煤气高效分离及返料回送;4.废渣冷却排出;5.煤气的余热回收处理;6.活性炭粉炭的干式过滤收集;7.副产煤气冷却;8.尾部煤气余热回收。1. Feeding of gasification ash and starting coal; 2. Activation reaction in the activation furnace; 3. High-efficiency separation of gas and return of materials; 4. Cooling and discharge of waste residue; 5. Waste heat recovery treatment of gas; 6. Activated carbon powder Dry filtration collection; 7. By-product gas cooling; 8. Tail gas waste heat recovery.

在实际应用中,该系统的具体操作过程可以如下:In practical applications, the specific operation process of the system can be as follows:

将启炉原煤(粒径≤10mm)和气化灰经过输料装置13送入到活化工段设备1。The raw coal (particle size ≤ 10 mm) and gasification ash are sent to the activation section equipment 1 through the feeding device 13 .

活化工段设备1的活化反应产生900~1100℃高温煤气,经过旋风分离器5高效分离和返料器6返料回送后,进入余热回收设备2。部分尾部煤气进入尾部余热回收设备17。The activation reaction of the equipment 1 in the activation section produces high-temperature gas at 900-1100°C, which enters the waste heat recovery equipment 2 after being efficiently separated by the cyclone separator 5 and returned by the feeder 6. Part of the tail gas enters the tail waste heat recovery equipment 17 .

余热回收设备2通过换热回收高温煤气热量,产生高温空气和蒸气,煤气降温至180℃左右送入干式过滤收集设备3。Waste heat recovery equipment 2 recovers the heat of high-temperature gas through heat exchange to generate high-temperature air and steam, and the gas is cooled to about 180°C and sent to dry filter collection equipment 3 .

干式过滤收集设备3捕集煤气中的活性炭粉炭,气力输送至中间储存仓,净化后煤气冷却至60℃左右作为副产品。The dry filter collection equipment 3 captures the activated carbon powder in the gas, and pneumatically transports it to the intermediate storage warehouse. After purification, the gas is cooled to about 60°C as a by-product.

尾部余热回收设备17将尾部煤气送至炉膛底部燃烧器,点燃送回活化工段设备1。The tail waste heat recovery equipment 17 sends the tail gas to the burner at the bottom of the furnace, ignites and sends it back to the activation section equipment 1.

活化工段设备1的原料与高温循环半焦混合,较粗的颗粒下沉到炉膛底部,与富氧空气和蒸汽组成的气化剂发生燃烧和气化反应;较细的半焦颗粒上升到炉膛上部,吸收来自底部的热量并与二氧化碳、蒸汽等发生活化反应生成夹带活性炭粉炭的煤气;煤气和半焦的混合物经过旋风分离器5气固分离后,半焦通过返料器6继续返回到炉膛参与反应,高温煤气送入后续余热回收系统。反应后得到的炉渣从气化炉底部经冷渣机18冷却后通过输渣螺旋机排出。The raw material of equipment 1 in the activation section is mixed with high-temperature circulating semi-coke, and the coarser particles sink to the bottom of the furnace, where they burn and gasify with the gasification agent composed of oxygen-enriched air and steam; the finer semi-coke particles rise to the furnace The upper part absorbs heat from the bottom and reacts with carbon dioxide, steam, etc. to generate gas entrained with activated carbon powder; after the mixture of gas and semi-coke passes through the cyclone separator 5 for gas-solid separation, the semi-coke continues to return to the furnace through the return device 6 Participating in the reaction, the high-temperature gas is sent to the subsequent waste heat recovery system. The slag obtained after the reaction is cooled by the slag cooler 18 from the bottom of the gasifier and discharged through the slag conveying screw.

活化工段设备1的启炉原煤适应性广,直接使用粉煤制备:可利用褐煤、长焰煤、不粘性烟煤、弱粘性烟煤、无烟煤等。The starting raw coal of equipment 1 in the activation section has wide adaptability and can be prepared directly from pulverized coal: lignite, long-flame coal, non-sticky bituminous coal, weakly sticky bituminous coal, anthracite, etc. can be used.

活化工段设备1的活化剂可以灵活选择:空气、空气+水蒸气、富氧空气/纯氧+蒸汽、CO2中一种,两种或者多种组合。循环流化床活化炉4内布置风帽,使活化温度均匀,可达1000℃左右。The activator of equipment 1 in the activation section can be flexibly selected: one, two or more combinations of air, air+water vapor, oxygen-enriched air/pure oxygen+steam, CO2 . A wind cap is arranged in the circulating fluidized bed activation furnace 4 to make the activation temperature uniform, which can reach about 1000°C.

余热回收设备2中空气预热器7接收来自旋风分离器5的高温煤气,加热产生650℃高温空气。降温到一定程度的煤气离开空气预热器7进入蒸汽发生器或余热锅炉8等,降温至200℃以下,产生3.8MPaG(380℃)过热蒸汽及0.3MPaG低压饱和蒸汽。低压蒸汽一部分供活化炉4作活化剂及除氧器自用,副产过热蒸汽送往界区外。The air preheater 7 in the waste heat recovery equipment 2 receives the high-temperature gas from the cyclone separator 5, and heats it to generate 650°C high-temperature air. The gas cooled to a certain degree leaves the air preheater 7 and enters the steam generator or waste heat boiler 8, etc., and cools down to below 200°C to produce 3.8MPaG (380°C) superheated steam and 0.3MPaG low-pressure saturated steam. Part of the low-pressure steam is used by the activation furnace 4 as an activator and a deaerator for self-use, and the by-product superheated steam is sent outside the boundary area.

干式过滤收集设备3将旋风收集器9和布袋收集器11依次连接,捕集离开余热回收设备2的煤气中的活性炭粉炭,旋风收集器9活性炭粉炭捕集效率20%~30%,布袋收集器11的捕集效率可以达到99%以上。The dry filter collection device 3 connects the cyclone collector 9 and the bag collector 11 in sequence to capture the activated carbon powder in the gas leaving the waste heat recovery device 2. The cyclone collector 9 has an activated carbon powder carbon collection efficiency of 20% to 30%. The collection efficiency of the device 11 can reach more than 99%.

干式过滤收集设备3捕集的活性炭粉炭(100~15000kg/h),采用气力输送,浓相输送,气体采用氮气,经旋风收集器仓泵10和布袋收集器仓泵12送至中间储存仓。Activated carbon powder carbon (100-15000kg/h) captured by the dry filter collection equipment 3 is transported by pneumatic, dense phase, and the gas is nitrogen, and sent to the intermediate storage warehouse through the cyclone collector chamber pump 10 and the bag collector chamber pump 12 .

干式过滤收集设备3结束后离开的煤气,为进一步冷却,进入煤气冷却器,喷淋水喷淋降温。煤气和喷淋水在塔中逆流换热,煤气降温至45℃后可作为副产品(热值1450~2500kcal/Nm3)送界区外。The coal gas that leaves after dry filter collection equipment 3 finishes, for further cooling, enters gas cooler, and spraying water sprays and cools down. Coal gas and spray water exchange heat countercurrently in the tower, and the gas can be sent out of the boundary area as a by-product (calorific value 1450-2500kcal/Nm 3 ) after cooling down to 45°C.

输料装置13包括飞灰料仓20、第一飞灰缓冲仓21、第二飞灰缓冲仓22、第一气体喷射器24、第二气体喷射器25和给煤仓23。飞灰料仓20下端出口与缓冲仓进口连通,缓冲仓出口通过气体喷射器与活化炉4连通,煤仓出口通过给料机与活化炉4连通。The conveying device 13 includes a fly ash silo 20 , a first fly ash buffer bin 21 , a second fly ash buffer bin 22 , a first gas injector 24 , a second gas injector 25 and a coal feeding bin 23 . The outlet at the lower end of the fly ash bin 20 is connected to the inlet of the buffer bin, the outlet of the buffer bin is connected to the activation furnace 4 through the gas injector, and the outlet of the coal bunker is connected to the activation furnace 4 through the feeder.

活化工段设备1的活化炉4顶部出口接高效旋风分离器5,旋风分离器5下端接返料器6,返料器6下部出口与活化炉4炉膛下端相连,形成一个高倍率的外循环回路。The top outlet of the activation furnace 4 of the equipment 1 in the activation section is connected to the high-efficiency cyclone separator 5, the lower end of the cyclone separator 5 is connected to the feeder 6, and the lower outlet of the feeder 6 is connected to the lower end of the furnace of the activation furnace 4 to form a high-rate external circulation circuit.

余热回收设备2由空气预热器7和蒸汽发生器或余热锅炉8等组成,空气预热器7入口接旋风分离器5出口。The waste heat recovery equipment 2 is composed of an air preheater 7 and a steam generator or a waste heat boiler 8. The inlet of the air preheater 7 is connected to the outlet of the cyclone separator 5.

干式过滤收集设备3由旋风收集器9、布袋收集器11和煤气冷却器依次连接组成,旋风收集器9接在余热回收工段蒸汽发生器或余热锅炉8后。尾部余热回收工段为点火燃烧器19,安装在活化炉4炉膛底部。The dry filter collection equipment 3 is composed of a cyclone collector 9, a bag collector 11 and a gas cooler connected in sequence. The cyclone collector 9 is connected behind the steam generator or the waste heat boiler 8 in the waste heat recovery section. The tail waste heat recovery section is an ignition burner 19 installed at the bottom of the furnace of the activation furnace 4 .

活化工段设备1中的高效的旋风分离器5将活化炉4出口煤气中的半焦与煤气高效分离,实现高效低阻的分离效果,确保活化炉4炉膛可以在微正压条件下运行;其中,返料器6采用高通量U型自平衡返料装置,与活化炉4、旋风分离器5形成高倍率外循环回路,有效降低废渣含炭量。The high-efficiency cyclone separator 5 in the equipment 1 of the activation section efficiently separates the semi-coke in the gas at the outlet of the activation furnace 4 from the gas to achieve a high-efficiency and low-resistance separation effect and ensure that the furnace of the activation furnace 4 can operate under slightly positive pressure conditions; Among them, the feeder 6 adopts a high-throughput U-shaped self-balanced feeder device, which forms a high-rate external circulation loop with the activation furnace 4 and the cyclone separator 5, effectively reducing the carbon content of the waste residue.

余热回收设备2加热产生的空气和部分蒸汽回送活化炉4炉膛提供热量并作为活化剂,部分蒸汽送界区外,空气温度为600~800℃,蒸汽温度120~540℃,压力1.2~5.4MPaG;尾部余热回收设备17回送尾部煤气至活化炉4底部燃烧器,点燃生成的烟气进入活化炉4炉膛,提供热量同时提供CO2和H2O。The air and part of the steam generated by the heating of the waste heat recovery equipment 2 are returned to the furnace of the activation furnace 4 to provide heat and act as an activator, and part of the steam is sent to the outside of the boundary area. ; Tail waste heat recovery equipment 17 returns the tail gas to the bottom burner of the activation furnace 4, and the flue gas generated by ignition enters the furnace of the activation furnace 4 to provide heat and CO 2 and H 2 O at the same time.

活化炉4炉膛底部有均匀布置的风帽,可以将底部进入炉膛的烟气、空气、蒸汽均匀分布在活化炉4炉膛中,保证活化炉4温度和活化反应的反应效率。活化炉4的温度为900~1100℃,活化炉4顶的温度为800~1000℃,活化炉4出口高温煤气温度为900~1100℃。The bottom of the furnace of the activation furnace 4 has uniformly arranged hoods, which can evenly distribute the flue gas, air, and steam entering the furnace from the bottom into the furnace of the activation furnace 4 to ensure the temperature of the activation furnace 4 and the reaction efficiency of the activation reaction. The temperature of activation furnace 4 is 900~1100 ℃, the temperature of activation furnace 4 top is 800~1000 ℃, and the temperature of high temperature gas at the outlet of activation furnace 4 is 900~1100 ℃.

干式过滤收集设备3的旋风收集器9由本体、活性炭排放系统、钢架、保温材料等组成,设备布置在余热锅炉8之后布袋收集器11之前,作用是对煤气中活性炭进行预分离,采用入口高速、出口低速的设计原则。旋风收集器9分离降低了布袋收集器11入口的煤气含炭浓度,延长了布袋收集器11的使用寿命。布袋收集器11包括收集器筒体、滤袋、袋笼、清粉系统,锥形料斗、氮气炮清堵装置、电控等。The cyclone collector 9 of the dry filter collection equipment 3 is composed of a body, an activated carbon discharge system, a steel frame, and insulation materials. The equipment is arranged behind the waste heat boiler 8 and before the bag collector 11. The design principle of high speed at the entrance and low speed at the exit. The separation of the cyclone collector 9 reduces the concentration of charcoal in the gas at the inlet of the bag collector 11 and prolongs the service life of the bag collector 11 . The bag collector 11 includes collector cylinder, filter bag, bag cage, powder cleaning system, conical hopper, nitrogen cannon cleaning device, electric control, etc.

本发明实施例具有如下优点:Embodiments of the present invention have the following advantages:

1.本发明通过活化炉装置处理飞灰量0.5~50t/h,活性炭粉炭产量100~15000kg/h,副产煤气1000~80000Nm3/h(热值1000~2500kcal/Nm3),饱和蒸汽产量1000~50000kg/h。本发明的生产工艺在产量上对比其他活性炭生产工艺有明显提升,同时活性炭产品为粉炭,满足了不同市场需求。1. In the present invention, the amount of fly ash treated by the activation furnace device is 0.5-50t/h, the output of activated carbon powder is 100-15000kg/h, the by-product gas is 1000-80000Nm 3 /h (calorific value 1000-2500kcal/Nm 3 ), and the output of saturated steam 1000~50000kg/h. Compared with other activated carbon production processes, the production process of the present invention has obvious improvement in output, and the activated carbon product is powdered carbon, which satisfies different market demands.

2.本发明设置余热回收设备,充分吸收高温煤气中的热量,避免热量浪费。同时加热空气和产生蒸汽,作为活化剂进入活化炉,可以有效减少活性炭生产工艺中蒸汽的消耗量。2. The present invention is equipped with waste heat recovery equipment to fully absorb the heat in the high-temperature gas and avoid waste of heat. At the same time, air is heated and steam is generated, which enters the activation furnace as an activator, which can effectively reduce the consumption of steam in the activated carbon production process.

3.本发明设置旋风收集器和布袋收集器,有效收集煤气中夹带的活性炭粉炭,同时净化煤气生成副产品,减少资源浪费,增加经济效益。3. The present invention is equipped with a cyclone collector and a bag collector to effectively collect the activated carbon powder entrained in the gas, and at the same time purify the gas to generate by-products, reduce waste of resources, and increase economic benefits.

4.本发明设置尾部余热回收设备,将尾部煤气回送活化炉底部燃烧器,点燃后生成烟气送活化炉炉膛。提供热量的同时也提供活化反应需要的CO2和H2O。进一步减少了活性炭生产工艺中的蒸汽消耗。4. The present invention is equipped with waste heat recovery equipment at the tail to return the tail gas to the burner at the bottom of the activation furnace, and after being ignited, the generated flue gas is sent to the hearth of the activation furnace. While providing heat, CO 2 and H 2 O required for the activation reaction are also provided. The steam consumption in the activated carbon production process is further reduced.

本说明书中各个实施例采用递进的方式描述,每个实施例重点说明的都是与其他实施例的不同之处,各个实施例之间相同相似部分互相参见即可。Each embodiment in this specification is described in a progressive manner, each embodiment focuses on the difference from other embodiments, and the same and similar parts of each embodiment can be referred to each other.

本文中应用了具体个例对本发明的原理及实施方式进行了阐述,以上实施例的说明只是用于帮助理解本发明的方法及其核心思想;同时,对于本领域的一般技术人员,依据本发明的思想,在具体实施方式及应用范围上均会有改变之处。综上所述,本说明书内容不应理解为对本发明的限制。In this paper, specific examples have been used to illustrate the principle and implementation of the present invention. The description of the above embodiments is only used to help understand the method of the present invention and its core idea; meanwhile, for those of ordinary skill in the art, according to the present invention Thoughts, there will be changes in specific implementation methods and application ranges. In summary, the contents of this specification should not be construed as limiting the present invention.

Claims (8)

1. A powdered activated carbon production and production system, the system comprising: the device comprises an activation working section device, a waste heat recovery device and a dry type filtering and collecting device;
the activation working section equipment and the dry type filtering and collecting equipment are connected with the waste heat recovery equipment;
the activation section device is used for:
activating the production raw materials under the action of an activating agent to obtain an activated product with a first set temperature; the production raw materials comprise: starting raw coal and gasified ash; the activation product is a powder-gas mixture; the powder-gas mixture is a mixture of activated carbon powder carbon and gas; the raw coal for starting the furnace is coal with the grain diameter not larger than a set grain diameter;
the waste heat recovery device is used for:
receiving the activation product with the first set temperature, and heating the air by utilizing the heat of the activation product with the first set temperature to obtain heated air and an activation product with the second set temperature; the heated air is used as an activating agent and is transmitted to the activating section equipment; the second set temperature is less than the first set temperature;
performing heat exchange and cooling treatment on the activated product at the second set temperature to obtain a recovered product at a third set temperature; the recovered product comprises: activated carbon powder carbon and coal gas mixture; the third set temperature is less than the second set temperature; the coal gas mixture is a mixture of coal gas and steam;
the dry filtration collection device is used for:
and collecting activated carbon powder carbon in the recovered product at the third set temperature, and separating the activated carbon powder carbon and the coal gas mixture in the recovered product at the third set temperature.
2. The powdered activated carbon production and preparation system of claim 1, wherein the activation section equipment comprises: an activation furnace, a cyclone separator and a material returning device;
the cyclone separator is respectively connected with the activation furnace and the waste heat recovery equipment; the material returning device is respectively connected with the cyclone separator and the activation furnace;
the activation furnace is used for:
activating the production raw materials under the action of an activating agent to obtain an activated mixture; the activated mixture is a mixture of activated products at a first set temperature and semicoke granular coal;
the cyclone separator is used for:
separating the activated mixture to obtain the semicoke granular coal and an activated product with a first set temperature;
the material returning device is used for:
and conveying the semicoke granular coal to the activation furnace.
3. The powdered activated carbon production and preparation system of claim 1, wherein the waste heat recovery device comprises: an air preheater and a waste heat boiler;
the air preheater is respectively connected with the activation working section equipment and the waste heat boiler; the waste heat boiler is also connected with the dry type filtering and collecting equipment;
the air preheater is used for:
preheating air to obtain preheated air;
receiving the activation product with the first set temperature, and heating the preheated air by utilizing the heat of the activation product with the first set temperature to obtain heated air and an activation product with the second set temperature;
the heated air is transmitted to the activation working section equipment to supplement the activating agent and simultaneously provide heat for the activation reaction;
the waste heat boiler is used for:
and cooling the activated product at the second set temperature to obtain the activated product at the third set temperature, and generating saturated or superheated steam.
4. The powdered activated carbon production and preparation system of claim 1, wherein the dry filtration collection device comprises: cyclone collector, cyclone collector bin pump, cloth bag collector and cloth bag collector bin pump;
the cyclone collector is respectively connected with the waste heat recovery equipment and the cyclone collector bin pump; the cloth bag collector is respectively connected with the cyclone collector and the cloth bag collector bin pump;
the cyclone collector is used for collecting part of activated carbon powder carbon in the recovered product with the third set temperature and transmitting the part of activated carbon powder carbon to the cyclone collector bin pump;
the cyclone collector bin pump is used for conveying the activated carbon powder and carbon collected by the cyclone collector to the activated carbon powder and carbon bin;
the cloth bag collector is used for collecting the other part of activated carbon powder carbon in the recovered product with the third set temperature and transmitting the activated carbon powder carbon to the cloth bag collector bin pump;
the cloth bag collector bin pump is used for conveying the activated carbon powder carbon collected by the cloth bag collector to the activated carbon powder carbon bin.
5. The powdered activated carbon production and preparation system of claim 1, further comprising: a material conveying device;
the material conveying device is connected with the activation working section equipment; the conveying device is used for conveying the production raw materials.
6. The powdered activated carbon production and preparation system of claim 1, further comprising: a gas separation device;
the gas separation device is connected with the dry type filtering and collecting equipment;
the gas separation device is used for carrying out cooling treatment and separation treatment on the gas mixture in the recovered product with the third set temperature to obtain dry gas.
7. The powdered activated carbon production and preparation system of claim 6, wherein the gas separation device comprises: a gas cooling tank and a gas separation tank;
the gas cooling tank is connected with the dry type filtering and collecting equipment; the gas separation tank is connected with the gas cooling tank;
the gas cooling tank is used for:
cooling the coal-gas mixture in the recovered product with the third set temperature to obtain a coal-water mixture with a fourth temperature; the coal-water mixture is a mixture of coal gas and condensed water; the fourth temperature is less than the third set temperature;
the gas separation tank is used for:
and separating the coal-water mixture at the fourth temperature to obtain coal gas at the fourth temperature and condensed water at the fourth temperature.
8. The powdered activated carbon production and production system of claim 1, wherein the raw coal for start-up comprises: lignite, long flame coal, non-sticky bituminous coal, weak sticky bituminous coal and anthracite coal.
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CN112029518A (en) * 2020-09-15 2020-12-04 浙江大学 System and method for preparing activated carbon by integrating coal/biomass carbonization and activation

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATA205298A (en) * 1998-12-07 2000-01-15 Luetke Joachim ANGLE OR SLOPE DRILLING DEVICE
CN102481516A (en) * 2009-09-11 2012-05-30 西门子Vai金属科技有限责任公司 Method for removing carbon dioxide from waste gas such as waste gas from pig iron production plant or waste gas from synthesis gas plant
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