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CN115576041B - Crystal alignment method - Google Patents

Crystal alignment method Download PDF

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CN115576041B
CN115576041B CN202211207903.8A CN202211207903A CN115576041B CN 115576041 B CN115576041 B CN 115576041B CN 202211207903 A CN202211207903 A CN 202211207903A CN 115576041 B CN115576041 B CN 115576041B
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precision turntable
grating
alignment
turntable
interference
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CN115576041A (en
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巴音贺希格
姜岩秀
陈星硕
姜珊
郑钟铭
王瑞鹏
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Changchun Institute of Optics Fine Mechanics and Physics of CAS
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/18Diffraction gratings
    • G02B5/1847Manufacturing methods
    • G02B5/1857Manufacturing methods using exposure or etching means, e.g. holography, photolithography, exposure to electron or ion beams
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/18Diffraction gratings
    • G02B5/1838Diffraction gratings for use with ultraviolet radiation or X-rays

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Abstract

The method for precisely aligning the crystal orientation provided by the application is used for positioning the crystal orientation of the silicon wafer; acquiring a reference grating parallel to the crystal direction of a silicon wafer; placing a grating substrate to be exposed with a reference grating on a precise turntable; moving the precise turntable to enable the left and right exposure beams positioned on the precise turntable to generate diffraction light in the normal direction of the grating substrate; rotating the precise turntable to enable the two beams of diffracted light to coincide and obtain an interference pattern; the precise turntable is adjusted to make the interference fringe period of the interference pattern reach the maximum value, and the static alignment is completed, the method for precisely aligning the crystal orientation provided by the application introduces a reference grating with a grating period matched with the interference field period of the SBIL system as an intermediate process, the method avoids introducing extra elements into the SBIL system, transfers a long-time-consuming process into ultraviolet lithography equipment, and improves the use efficiency of the SBIL system.

Description

一种晶向对准的方法A method for crystal alignment

技术领域Technical Field

本申请涉及微纳结构加工技术领域,特别涉及一种晶向对准的方法。The present application relates to the technical field of micro-nano structure processing, and in particular to a method for crystal orientation alignment.

背景技术Background Art

高深宽比硅光栅(HARSG)是一种重要的短波光学器件,在X射线成像和光谱探测系统中有着广泛的应用。其中,高线密度(大于3000gr/mm)的高深宽比硅光栅是软X射线波段能谱探测系统的关键器件。目前,高深宽比硅光栅的制作技术可以分为三种:单晶硅在碱性溶液中的各向异性湿法刻蚀、基于刻蚀-钝化工艺(Bosch工艺)的深反应离子刻蚀、金属辅助化学刻蚀。在前两种技术路线中,由于深宽比与侧壁粗糙度的要求,令硅基底的<111>晶向与光栅刻线方向保持精确平行是一项必要的技术。金属辅助化学刻蚀可以摆脱晶向的限制,但现有的工艺还难以制作同时拥有高刻线密度与大面积(大于cm量级)的高深宽比硅光栅。因此,高线密度光栅刻线方向与硅晶圆<111>晶向的精确对准是一项重要的技术难点。High aspect ratio silicon grating (HARSG) is an important short-wave optical device with wide applications in X-ray imaging and spectral detection systems. Among them, high aspect ratio silicon gratings with high line density (greater than 3000gr/mm) are key components of soft X-ray band energy spectrum detection systems. At present, the production technology of high aspect ratio silicon grating can be divided into three types: anisotropic wet etching of single crystal silicon in alkaline solution, deep reactive ion etching based on etching-passivation process (Bosch process), and metal-assisted chemical etching. In the first two technical routes, due to the requirements of aspect ratio and sidewall roughness, it is a necessary technology to keep the <111> crystal direction of the silicon substrate precisely parallel to the grating line direction. Metal-assisted chemical etching can get rid of the limitation of crystal direction, but the existing process is still difficult to produce high aspect ratio silicon gratings with high line density and large area (greater than cm level). Therefore, the precise alignment of the high line density grating line direction with the <111> crystal direction of the silicon wafer is an important technical difficulty.

高刻线密度光栅掩模可以通过扫描干涉场曝光(Scanning beam interferencelithography,SBIL)技术进行制备。在此过程中,需要将SBIL系统内干涉场的条纹方向与基底的<111>晶向进行对准。现有的技术方案为M.Ahn提出的一种将显微成像系统植入SBIL系统的方法:首先通过扇形掩模预刻蚀技术,通过一根特定的狭长矩形硅结构表征晶圆的<111>晶向;之后将晶圆放置在SBIL系统的工作台上,令工作台在扫描方向运动,通过狭长矩形与显微镜准心的相对移动,可以逐渐调整晶圆的方向,直至显微镜准心在运动过程中始终保持在矩形内部,最后进行曝光,此时<111>晶向与光刻后得到的光栅条纹方向一致,对准误差在0.05°以内。High-line density grating masks can be prepared by scanning beam interference lithography (SBIL) technology. In this process, the stripe direction of the interference field in the SBIL system needs to be aligned with the <111> crystal direction of the substrate. The existing technical solution is a method proposed by M.Ahn to implant a microscopic imaging system into the SBIL system: first, through the fan-shaped mask pre-etching technology, a specific narrow rectangular silicon structure is used to characterize the <111> crystal direction of the wafer; then the wafer is placed on the workbench of the SBIL system, and the workbench is moved in the scanning direction. Through the relative movement of the narrow rectangle and the microscope collimator, the direction of the wafer can be gradually adjusted until the microscope collimator remains inside the rectangle during the movement. Finally, exposure is performed. At this time, the <111> crystal direction is consistent with the grating stripe direction obtained after photolithography, and the alignment error is within 0.05°.

上述M.Ahn的方法可以令SBIL系统制作的光栅掩模方向与硅晶圆的<111>晶向一致,但是,这需要将显微成像系统的光学元件加入到本就结构复杂的SBIL系统中,会增加系统的复杂性,导致光路设计难度与装调难度上升。并且,表征<111>晶向的狭长矩形硅结构与显微镜准心之间的对准较为困难,由于对准期间需要反复多次进行调整,且运动过程中也需要持续观察,因此对准流程需要较长的时间,会降低SBIL系统的使用效率。The above-mentioned M.Ahn method can make the grating mask produced by the SBIL system consistent with the <111> crystal orientation of the silicon wafer. However, this requires adding the optical elements of the microscopic imaging system to the already complex SBIL system, which will increase the complexity of the system and increase the difficulty of optical path design and adjustment. In addition, it is difficult to align the narrow rectangular silicon structure representing the <111> crystal orientation with the microscope collimator. Since adjustments need to be made repeatedly during alignment and continuous observation is required during the movement, the alignment process takes a long time, which will reduce the efficiency of the SBIL system.

发明内容Summary of the invention

鉴于此,有必要针对现有技术中存在的缺陷提供一种在实现高精度对准的同时提高对准效率,同时避免在SBIL系统中引入其它元件的晶向精确对准的方法。In view of this, it is necessary to provide a method for achieving high-precision alignment while improving alignment efficiency and avoiding the introduction of crystal orientation precise alignment of other components in the SBIL system in view of the defects existing in the prior art.

为解决上述问题,本申请采用下述技术方案:To solve the above problems, this application adopts the following technical solutions:

本申请目的之一提供了一种晶向精确对准的方法,包括下述步骤:One of the purposes of the present application is to provide a method for precise crystal alignment, comprising the following steps:

对硅晶圆进行晶向定位;Perform crystal orientation positioning on silicon wafers;

获取与所述硅晶圆的晶向平行的参考光栅;Acquiring a reference grating parallel to the crystal direction of the silicon wafer;

将带有所述参考光栅的欲曝光的光栅基底置于精密转台上;Placing the grating substrate to be exposed and carrying the reference grating on a precision turntable;

移动所述精密转台,使位于所述精密转台左右两束曝光光束均在所述光栅基底的法线方向产生衍射光;Moving the precision turntable so that the two exposure light beams on the left and right of the precision turntable both generate diffracted light in the normal direction of the grating substrate;

旋转所述精密转台使两束衍射光重合并获取干涉图样;Rotating the precision turntable to make the two diffracted light beams overlap and obtain an interference pattern;

调整所述精密转台,使所述干涉图样出现的干涉条纹周期达到最大值,静态对准完成。The precision turntable is adjusted so that the interference fringe period of the interference pattern reaches a maximum value, and the static alignment is completed.

在其中一些实施例中,在对硅晶圆进行晶向定位的步骤中,具体包括下述步骤:通过扇形掩模预刻蚀技术对硅晶圆进行<111>晶向定位。In some of the embodiments, the step of performing crystal orientation positioning on the silicon wafer specifically includes the following step: performing <111> crystal orientation positioning on the silicon wafer by using a fan-shaped mask pre-etching technology.

在其中一些实施例中,在获取与所述硅晶圆的晶向平行的参考光栅的步骤中,具体包括下述步骤:通过紫外接触式光刻设备制作与晶向平行的参考光栅。In some of the embodiments, the step of obtaining a reference grating parallel to the crystal direction of the silicon wafer specifically includes the following steps: making a reference grating parallel to the crystal direction by ultraviolet contact lithography equipment.

在其中一些实施例中,在将带有所述参考光栅与光致抗蚀剂的欲曝光硅晶圆置于精密转台上的步骤中,所述精密转台为二维运动工作台。In some of the embodiments, in the step of placing the silicon wafer to be exposed with the reference grating and the photoresist on a precision turntable, the precision turntable is a two-dimensional motion worktable.

在其中一些实施例中,所述二维运动工作台由直线电机牵引并分别沿扫描方向和步进方向运动,且扫描方向和步进方向相垂直。In some of the embodiments, the two-dimensional motion workbench is pulled by a linear motor and moves along a scanning direction and a stepping direction respectively, and the scanning direction and the stepping direction are perpendicular to each other.

在其中一些实施例中,所述参考光栅的刻线方向与扫描方向平行。In some embodiments, the ruling direction of the reference grating is parallel to the scanning direction.

在其中一些实施例中,在移动所述精密转台,位于所述精密转台左右两束曝光光束均会在法线方向产生衍射光;的步骤中,具体包括下述步骤:In some embodiments, in the step of moving the precision turntable, both the left and right exposure light beams on the precision turntable will generate diffracted light in the normal direction; specifically including the following steps:

移动所述精密转台,使干涉场位于所述参考光栅上,位于所述精密转台的左右两束曝光光束在所述参考光栅的表面重合,左右两束曝光光束均在所述光栅基底法线方向产生衍射光。The precision turntable is moved so that the interference field is located on the reference grating, and the left and right exposure beams located on the precision turntable overlap on the surface of the reference grating, and both the left and right exposure beams generate diffraction light in the normal direction of the grating base.

在其中一些实施例中,在旋转所述精密转台使两束衍射光重合并获取干涉图样的步骤中,具体包括下述步骤:In some embodiments, the step of rotating the precision turntable to make the two diffracted light beams overlap and obtain the interference pattern specifically includes the following steps:

在所述光栅基底的法线方向产生的两束衍射光经过上方的平面镜入射至一侧的CCD上,再通过计算机获取CCD上的实时光强分布图像。Two beams of diffracted light generated in the normal direction of the grating substrate are incident on the CCD on one side through the upper plane mirror, and then a real-time light intensity distribution image on the CCD is obtained by a computer.

在其中一些实施例中,在调整所述精密转台,使所述干涉图样出现的干涉条纹周期达到最大值,静态对准完成的步骤中,具体包括下述步骤:In some embodiments, the step of adjusting the precision turntable so that the interference fringe period of the interference pattern reaches a maximum value and the static alignment is completed specifically includes the following steps:

通过调整所述精密转台,使光斑图像出现干涉条纹,之后缓慢调整所述精密转台使干涉条纹的周期达到最大值,此时静态对准完成,所述周期达到最大值即周期大于光斑的直径,光斑范围内无法观测到完整的周期性条纹。By adjusting the precision turntable, interference fringes appear in the spot image, and then slowly adjusting the precision turntable to make the period of the interference fringes reach a maximum value, the static alignment is completed at this time, the period reaches the maximum value, that is, the period is greater than the diameter of the spot, and no complete periodic fringes can be observed within the spot range.

在其中一些实施例中,在调整所述精密转台,使所述干涉图样出现的干涉条纹周期达到最大值,静态对准完成的步骤,具体还包括下述步骤:In some embodiments, the step of adjusting the precision turntable so that the interference fringe period of the interference pattern reaches a maximum value and the static alignment is completed specifically includes the following steps:

调整所述精密转台在扫描方向匀速移动,所述参考光栅与所述左右两束曝光光束产生的相对移动并使得两个衍射光束之间产生一个随移动距离线性变化的相位差,从而在所述干涉图样的光斑上每一点的光强产生明暗的周期性变化,其变化周期与对准角度误差成反比。The precision turntable is adjusted to move at a uniform speed in the scanning direction. The reference grating and the left and right exposure beams produce relative movement, and a phase difference is generated between the two diffracted beams that changes linearly with the moving distance, thereby producing a periodic change in light intensity at each point on the light spot of the interference pattern, and the change period is inversely proportional to the alignment angle error.

在其中一些实施例中,在在调整所述精密转台,使所述干涉图样出现的干涉条纹周期达到最大值,静态对准完成的步骤中的步骤中,还包括下述步骤:In some embodiments, in the step of adjusting the precision turntable so that the interference fringe period of the interference pattern reaches a maximum value and the static alignment is completed, the following steps are also included:

所述精密转台每次移动完成后,调节所述精密转台角度,再调节所述精密转台反向移动,重复上述过程,直至找到变化周期最大的转台位置,此时保持所述精密转台位置不变,完成动态对准过程。After each movement of the precision turntable is completed, the angle of the precision turntable is adjusted, and then the precision turntable is adjusted to move in the opposite direction, and the above process is repeated until the turntable position with the largest change cycle is found. At this time, the position of the precision turntable is kept unchanged to complete the dynamic alignment process.

在完成动态对准过程后还包括下述步骤:通过所述精密转台的移动对光栅基底的剩余区域进行曝光流程,在显影完成后即可获得与硅晶圆方向精确平行的高刻线密度光栅掩模。After the dynamic alignment process is completed, the following steps are also included: the remaining area of the grating substrate is exposed by moving the precision turntable, and after the development is completed, a high-line density grating mask that is precisely parallel to the direction of the silicon wafer can be obtained.

本申请采用上述技术方案,其有益效果如下:This application adopts the above technical solution, and its beneficial effects are as follows:

本申请提供的晶向精确对准的方法,对硅晶圆进行晶向定位;获取与所述硅晶圆的晶向平行的参考光栅;将带有所述参考光栅的欲曝光的光栅基底置于精密转台上;移动所述精密转台,使位于所述精密转台左右两束曝光光束均在所述光栅基底的法线方向产生衍射光;旋转所述精密转台使两束衍射光重合并获取干涉图样;调整所述精密转台,使所述干涉图样出现的干涉条纹周期达到最大值,静态对准完成,本申请提供的晶向精确对准的方法,通过引入一个光栅周期与SBIL系统干涉场周期相匹配的参考光栅作为中间过程,避免了在SBIL系统中引入额外元件,并且把耗时较长的过程转移到紫外光刻设备中,提高了SBIL系统的使用效率,能够使SBIL系统的干涉条纹在(110)硅片表面上精确对准<111>晶体取向,从而在湿法蚀刻工艺中获得超高的蚀刻速率比,制备出高质量的高线密度高深宽比单晶硅光栅。The present application provides a method for precise crystal alignment, which includes positioning the crystal orientation of a silicon wafer; obtaining a reference grating parallel to the crystal orientation of the silicon wafer; placing a grating substrate to be exposed with the reference grating on a precision turntable; moving the precision turntable so that the two exposure light beams on the left and right of the precision turntable both generate diffracted light in the normal direction of the grating substrate; rotating the precision turntable so that the two diffracted light beams overlap and obtain an interference pattern; adjusting the precision turntable so that the interference fringe period of the interference pattern reaches a maximum value, and static alignment is completed. The present application provides a method for precise crystal alignment, which introduces a reference grating whose grating period matches the interference field period of the SBIL system as an intermediate process, thereby avoiding the introduction of additional components in the SBIL system, and transferring the time-consuming process to the ultraviolet lithography equipment, thereby improving the use efficiency of the SBIL system, and enabling the interference fringes of the SBIL system to be precisely aligned with the <111> crystal orientation on the (110) silicon wafer surface, thereby obtaining an ultra-high etching rate ratio in the wet etching process, and preparing high-quality, high-line-density, high-aspect-ratio single-crystal silicon gratings.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

为了更清楚地说明本申请实施例的技术方案,下面将对本申请实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面所描述的附图仅仅是本申请的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions of the embodiments of the present application, the drawings required for use in the embodiments of the present application or the description of the prior art will be briefly introduced below. Obviously, the drawings described below are only some embodiments of the present application. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying any creative work.

图1为本申请提供的晶向精确对准的方法的步骤流程图。FIG. 1 is a flow chart of the steps of the method for precise crystal alignment provided in the present application.

图2为本申请采用的参考光栅与扫描干涉场曝光系统干涉条纹对准示意图;FIG2 is a schematic diagram of the interference fringe alignment between the reference grating and the scanning interference field exposure system used in the present application;

图3为本申请采用的基于参考光栅和SBIL系统的对准方法原理图;FIG3 is a schematic diagram of the alignment method based on the reference grating and the SBIL system used in the present application;

图4为申请提供的参考光栅与曝光场之间x方向相对运动的动态对准过程示意图。FIG. 4 is a schematic diagram of the dynamic alignment process of the relative movement between the reference grating and the exposure field in the x direction provided by the application.

具体实施方式DETAILED DESCRIPTION

下面详细描述本申请的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,旨在用于解释本申请,而不能理解为对本申请的限制。Embodiments of the present application are described in detail below, and examples of the embodiments are shown in the accompanying drawings, wherein the same or similar reference numerals throughout represent the same or similar elements or elements having the same or similar functions. The embodiments described below with reference to the accompanying drawings are exemplary and are intended to be used to explain the present application, and should not be construed as limiting the present application.

在本申请的描述中,需要理解的是,术语“上”、“下”、“水平”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本申请和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请的限制。In the description of the present application, it should be understood that the terms "upper", "lower", "horizontal", "inside", "outside", etc., indicating orientations or positional relationships, are based on the orientations or positional relationships shown in the accompanying drawings, and are only for the convenience of describing the present application and simplifying the description, rather than indicating or implying that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore should not be understood as a limitation on the present application.

此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个该特征。在本申请的描述中,“多个”的含义是两个或两个以上,除非另有明确具体的限定。In addition, the terms "first" and "second" are used for descriptive purposes only and should not be understood as indicating or implying relative importance or implicitly indicating the number of the indicated technical features. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of the features. In the description of this application, the meaning of "plurality" is two or more, unless otherwise clearly and specifically defined.

为了使本申请的目的、技术方案及优点更加清楚明白,以下结合附图及实施例,对本申请进行进一步详细说明。In order to make the objectives, technical solutions and advantages of the present application more clearly understood, the present application is further described in detail below in conjunction with the accompanying drawings and embodiments.

请参阅图1,为本实施例1提供的一种晶向精确对准的方法的步骤流程图,包括下述步骤S110至步骤S160,以下详细说明各个步骤的实现方式。Please refer to FIG. 1 , which is a flow chart of the steps of a method for precise crystal alignment provided in the present embodiment 1, including the following steps S110 to S160 . The implementation method of each step is described in detail below.

步骤S110:对硅晶圆进行晶向定位。Step S110: performing crystal orientation positioning on the silicon wafer.

在其中一些实施例中,在对硅晶圆进行晶向定位的步骤中,具体包括下述步骤:通过扇形掩模预刻蚀技术对硅晶圆进行<111>晶向定位。In some of the embodiments, the step of performing crystal orientation positioning on the silicon wafer specifically includes the following step: performing <111> crystal orientation positioning on the silicon wafer by using a fan-shaped mask pre-etching technology.

可以理解,在对硅晶圆进行晶向定位的步骤中,采用与现有技术的方式相同,所用基底为(110)单晶硅晶圆,表面覆盖40nm厚的氮化硅层。通过紫外接触式光刻在<111>晶向附近制作扇形辐条式的光刻胶掩模,辐条间的角度间隔为0.03°,之后通过反应离子刻蚀将掩模转移至氮化硅层。晶圆在氢氧化钾中进行刻蚀,每个辐条的侧向刻蚀宽度与其和<111>晶向的夹角呈正相关。在显微镜下测量各辐条的侧向刻蚀宽度,侧向刻蚀最短的辐条认为与<111>晶向平行,其最大误差为角度间隔的一半,即0.015°。It can be understood that in the step of crystal orientation positioning of the silicon wafer, the same method as the prior art is adopted, and the substrate used is a (110) single crystal silicon wafer, and the surface is covered with a 40nm thick silicon nitride layer. A fan-shaped spoke-type photoresist mask is made near the <111> crystal orientation by ultraviolet contact lithography, and the angle interval between the spokes is 0.03°, and then the mask is transferred to the silicon nitride layer by reactive ion etching. The wafer is etched in potassium hydroxide, and the lateral etching width of each spoke is positively correlated with the angle between it and the <111> crystal orientation. The lateral etching width of each spoke is measured under a microscope, and the spoke with the shortest lateral etching is considered to be parallel to the <111> crystal orientation, and its maximum error is half of the angle interval, that is, 0.015°.

步骤S120:获取与所述硅晶圆的晶向平行的参考光栅。Step S120: Acquire a reference grating parallel to the crystal direction of the silicon wafer.

在本实施例中,在获取与所述硅晶圆的晶向平行的参考光栅的步骤中,具体包括下述步骤:通过紫外接触式光刻设备制作与晶向平行的参考光栅。In this embodiment, the step of obtaining a reference grating parallel to the crystal direction of the silicon wafer specifically includes the following steps: manufacturing a reference grating parallel to the crystal direction by using ultraviolet contact lithography equipment.

具体地,参考光栅采用紫外接触式光刻设备进行制作,所使用的掩模版上的图形包括参考光栅图形以及与参考光栅平行的狭缝。首先在晶圆表面旋转涂敷Shipley1805型光致抗蚀剂,通过带有显微镜的接触式光刻系统将掩模版上的狭缝与步骤一中选定的辐条对准,对基底边缘附近区域进行曝光,在氢氧化钠溶液中进行显影,获得参考光栅掩模。掩模版上光栅图形的周期应为扫描干涉场曝光系统中干涉场条纹周期的偶数倍,以实现法线方向的衍射。显影完成后,通过干法刻蚀设备将参考光栅图形转移到基底上。清洗完成后,再次旋转涂敷Shipley1805型光致抗蚀剂,并进行前烘,预备进行对准与曝光。Specifically, the reference grating is made by ultraviolet contact lithography equipment, and the pattern on the mask used includes a reference grating pattern and a slit parallel to the reference grating. First, Shipley 1805 photoresist is spin-coated on the surface of the wafer, and the slits on the mask are aligned with the spokes selected in step one through a contact lithography system with a microscope, and the area near the edge of the substrate is exposed, and developed in a sodium hydroxide solution to obtain a reference grating mask. The period of the grating pattern on the mask should be an even multiple of the period of the interference field fringes in the scanning interference field exposure system to achieve diffraction in the normal direction. After the development is completed, the reference grating pattern is transferred to the substrate by a dry etching device. After cleaning, Shipley 1805 photoresist is spin-coated again, and pre-baked to prepare for alignment and exposure.

步骤S130:将带有所述参考光栅的欲曝光的光栅基底置于精密转台上。Step S130: placing the grating substrate to be exposed with the reference grating on a precision turntable.

在其中一些实施例中,所述精密转台为二维运动工作台。二维运动工作台的扫描运动方向双导轨与步进运动方向双导轨相垂直。工作台由直线电机牵引可以分别沿扫描方向和步进方向运动,同时扫描方向与干涉场条纹方向严格平行。在放置欲曝光基底时,应使参考光栅的刻线方向大致与扫描方向平行。In some embodiments, the precision turntable is a two-dimensional motion worktable. The double guide rails in the scanning motion direction of the two-dimensional motion worktable are perpendicular to the double guide rails in the stepping motion direction. The worktable is pulled by a linear motor and can move in the scanning direction and the stepping direction respectively, and the scanning direction is strictly parallel to the direction of the interference field stripes. When placing the substrate to be exposed, the direction of the lines of the reference grating should be roughly parallel to the scanning direction.

步骤S140:移动所述精密转台,使位于所述精密转台左右两束曝光光束均在所述光栅基底的法线方向产生衍射光。Step S140: moving the precision turntable so that the two exposure light beams on the left and right of the precision turntable both generate diffraction light in the normal direction of the grating substrate.

请参阅图2,为本实施例提供的参考光栅与扫描干涉场曝光系统干涉条纹对准示意图,其中,左侧曝光光束1、右侧曝光光束2、反射镜4,5,6,7,8,9、带有参考光栅的基底10、精密转台11、二维工作台12、参考光栅的衍射光束13,14、CCD 15。Please refer to Figure 2, which is a schematic diagram of the interference fringe alignment between the reference grating and the scanning interference field exposure system provided in this embodiment, wherein there are a left exposure beam 1, a right exposure beam 2, mirrors 4, 5, 6, 7, 8, 9, a substrate 10 with a reference grating, a precision turntable 11, a two-dimensional workbench 12, diffraction beams 13, 14 of the reference grating, and a CCD 15.

可以理解,移动所述精密转台11,使干涉场位于所述参考光栅上,左右两束曝光光束1,2通过反射镜3,4,5,6,7,8,在带有参考光栅的基底10,上重合形成曝光场,由于参考周期为干涉场条纹周期的偶数倍,因此左右两路光束曝光光束1,2均会在法线方向产生衍射光。It can be understood that the precision turntable 11 is moved so that the interference field is located on the reference grating, and the left and right exposure light beams 1, 2 pass through the reflecting mirrors 3, 4, 5, 6, 7, 8 and overlap on the substrate 10 with the reference grating to form an exposure field. Since the reference period is an even multiple of the interference field fringe period, the left and right exposure light beams 1, 2 will both generate diffraction light in the normal direction.

步骤S150:旋转所述精密转台使两束衍射光重合并获取干涉图样。Step S150: Rotate the precision turntable to make the two diffracted light beams overlap and obtain an interference pattern.

在其中一些实施例中,在旋转所述精密转台使两束衍射光重合并获取干涉图样的步骤中,具体包括下述步骤:在所述光栅基底的法线方向产生的两束衍射光经过上方的平面镜入射至一侧的CCD上,再通过计算机获取CCD上的实时光强分布图像。In some of the embodiments, the step of rotating the precision turntable to make the two diffracted light beams overlap and obtain the interference pattern specifically includes the following steps: the two diffracted light beams generated in the normal direction of the grating substrate are incident on the CCD on one side through the upper plane mirror, and then the real-time light intensity distribution image on the CCD is obtained by a computer.

需要指出,平面镜7并非为实现本发明所引入的额外元件,其在SBIL系统中原本的功能是在系统搭建与调试时令工作台扫描方向与干涉条纹方向严格平行。It should be pointed out that the plane mirror 7 is not an additional element introduced to realize the present invention. Its original function in the SBIL system is to make the scanning direction of the workbench strictly parallel to the direction of the interference fringes during system construction and debugging.

请参阅图3,为本实施例提供的基于参考光栅和SBIL系统的对准方法原理图,其中:干涉场曝光光束1,2;待曝光光栅区域3;参考光栅区域4;法线方向衍射光形成的干涉光场5;非法线方向其它级次衍射光形成的干涉光场6,7。Please refer to Figure 3, which is a schematic diagram of the alignment method based on the reference grating and the SBIL system provided in this embodiment, wherein: interference field exposure beams 1, 2; grating area 3 to be exposed; reference grating area 4; interference light field 5 formed by diffracted light in the normal direction; interference light fields 6, 7 formed by other orders of diffracted light in non-normal directions.

在SBIL系统中,曝光光场两束光1和2入射到晶圆的参考光栅区域4,两束曝光光束的衍射光8通过晶圆上方的镜面反射被CCD探测器接收。由于不同阶衍射效率的差异,±m阶衍射光产生的干涉条纹5对比度最好。将参考光栅4的周期设置为干涉场周期的偶数倍,当曝光系统的两束相干光束都位于光栅的主平面时,理想情况下会在参考光栅表面法线方向4产生两束重合的衍射光束。如果当参考光栅4栅线方向与干涉场条纹方向存在偏差时,左右光束1、2在参考光栅上发生锥面衍射使两束衍射光束1、2偏离法线8方向,从而产生干涉,探测器上衍射光束相干区中的条纹。In the SBIL system, the two beams 1 and 2 of the exposure light field are incident on the reference grating area 4 of the wafer, and the diffracted light 8 of the two exposure beams is received by the CCD detector through the mirror reflection above the wafer. Due to the difference in diffraction efficiency of different orders, the interference fringes 5 produced by the ±m-order diffracted light have the best contrast. The period of the reference grating 4 is set to an even multiple of the interference field period. When the two coherent light beams of the exposure system are located in the main plane of the grating, ideally two overlapping diffracted light beams will be generated in the normal direction 4 of the reference grating surface. If there is a deviation between the grating line direction of the reference grating 4 and the direction of the interference field fringes, the left and right light beams 1 and 2 will undergo conical diffraction on the reference grating, causing the two diffracted light beams 1 and 2 to deviate from the normal 8 direction, thereby generating interference and fringes in the coherent area of the diffracted light beams on the detector.

步骤S160:调整所述精密转台,使所述干涉图样出现的干涉条纹周期达到最大值,静态对准完成。Step S160: adjusting the precision turntable so that the interference fringe period of the interference pattern reaches a maximum value, and the static alignment is completed.

可以理解,由于衍射光产生的干涉条纹的周期与偏转角成反比,使用了一个精密转台在SBIL系统中精细地调整晶圆的方向,以最大限度地增加干涉条纹周期。将干涉场移动到参考光栅区域4后,通过调整转台进行准直操作,当观察到干涉条纹周期最大时,通过干涉场与晶圆之间的相对运动直接进行曝光过程。在其中一些实施例中,在调整所述精密转台,使所述干涉图样出现的干涉条纹周期达到最大值,静态对准完成的步骤中,具体包括下述步骤:It can be understood that since the period of the interference fringes generated by the diffracted light is inversely proportional to the deflection angle, a precision turntable is used to finely adjust the direction of the wafer in the SBIL system to maximize the period of the interference fringes. After the interference field is moved to the reference grating area 4, the alignment operation is performed by adjusting the turntable. When the maximum period of the interference fringes is observed, the exposure process is directly performed through the relative movement between the interference field and the wafer. In some embodiments, the step of adjusting the precision turntable so that the period of the interference fringes appearing in the interference pattern reaches the maximum value and the static alignment is completed specifically includes the following steps:

通过调整所述精密转台,使光斑图像出现干涉条纹,之后缓慢调整所述精密转台使干涉条纹的周期达到最大值,此时静态对准完成,所述周期达到最大值即周期大于光斑的直径,光斑范围内无法观测到完整的周期性条纹。By adjusting the precision turntable, interference fringes appear in the spot image, and then slowly adjusting the precision turntable to make the period of the interference fringes reach a maximum value, the static alignment is completed at this time, the period reaches the maximum value, that is, the period is greater than the diameter of the spot, and no complete periodic fringes can be observed within the spot range.

请参阅图4,为本实施例提供的参考光栅与曝光场之间x方向相对运动的动态对准过程示意图,其中:运动前干涉场曝光光束1,2;运动后干涉场曝光光束3,4;运动前干涉图样5;运动后干涉图样6。Please refer to Figure 4, which is a schematic diagram of the dynamic alignment process of the relative movement between the reference grating and the exposure field in the x-direction provided in this embodiment, wherein: interference field exposure beams 1, 2 before movement; interference field exposure beams 3, 4 after movement; interference pattern 5 before movement; interference pattern 6 after movement.

可以理解,当条纹周期大于接收平面光斑尺寸时,通过参考光栅在SBIL系统中运动产生的额外相变,可以进一步提高对准过程的精度。当晶圆沿扫描方向X移动时,由于光栅线和曝光场条纹之间存在角度偏差α,曝光场垂直于光栅线Y方向的运动将导致两束衍射光束之间的相位差,导致光强在接收面5、6上周期性变化,因此可以通过动态准直过程实现参考光栅与干涉条纹之间的超高对准精度。It can be understood that when the fringe period is larger than the spot size of the receiving plane, the accuracy of the alignment process can be further improved by the additional phase change caused by the movement of the reference grating in the SBIL system. When the wafer moves along the scanning direction X, due to the angle deviation α between the grating lines and the exposure field fringes, the movement of the exposure field perpendicular to the grating lines in the Y direction will cause a phase difference between the two diffracted beams, resulting in periodic changes in the light intensity on the receiving surfaces 5 and 6. Therefore, ultra-high alignment accuracy between the reference grating and the interference fringes can be achieved through the dynamic alignment process.

在其中一些实施例中,在调整所述精密转台,使所述干涉图样出现的干涉条纹周期达到最大值,静态对准完成的步骤,具体包括下述步骤:In some embodiments, the step of adjusting the precision turntable so that the interference fringe period of the interference pattern reaches a maximum value and the static alignment is completed specifically includes the following steps:

调整所述精密转台在扫描方向匀速移动,所述参考光栅与所述左右两束曝光光束产生的相对移动并使得两个衍射光束之间产生一个随移动距离线性变化的相位差,从而在所述干涉图样的光斑上每一点的光强产生明暗的周期性变化,其变化周期与对准角度误差成反比。The precision turntable is adjusted to move at a uniform speed in the scanning direction. The reference grating and the left and right exposure beams produce relative movement, and a phase difference is generated between the two diffracted beams that changes linearly with the moving distance, thereby producing a periodic change in light intensity at each point on the light spot of the interference pattern, and the change period is inversely proportional to the alignment angle error.

步骤S160:在在调整所述精密转台,使所述干涉图样出现的干涉条纹周期达到最大值,静态对准完成的步骤后,还包括下述步骤:Step S160: After the step of adjusting the precision turntable so that the interference fringe period of the interference pattern reaches a maximum value and the static alignment is completed, the following steps are also included:

所述精密转台每次移动完成后,调节所述精密转台角度,再调节所述精密转台反向移动,重复上述过程,直至找到变化周期最大的转台位置,此时保持所述精密转台位置不变,完成动态对准过程完成。After each movement of the precision turntable is completed, the angle of the precision turntable is adjusted, and then the precision turntable is adjusted to move in the opposite direction, and the above process is repeated until the turntable position with the largest change cycle is found. At this time, the position of the precision turntable is kept unchanged, and the dynamic alignment process is completed.

具体地,令工作台以0.5mm/s的速度在工作台的扫描方向移动10mm,此时CCD观察到的干涉图样发生周期性的明暗变化,说明参考光栅沿垂直于刻线方向产生位移,即参考光栅的刻线方向与扫描方向之间存在角度误差。进一步调节转台,直至移动过程中干涉图样不产生明显明暗变化,此时说明参考光栅与扫描方向保持一致,也即参考光栅刻线方向与干涉条纹方向一致。该过程的对准精度受到参考光栅尺寸与移动距离的限制,对于10mm的移动距离,其角度对准误差可以控制到0.001°。Specifically, the workbench is moved 10 mm in the scanning direction of the workbench at a speed of 0.5 mm/s. At this time, the interference pattern observed by the CCD undergoes periodic changes in brightness, indicating that the reference grating is displaced in a direction perpendicular to the grating lines, that is, there is an angular error between the grating line direction and the scanning direction of the reference grating. The turntable is further adjusted until the interference pattern does not produce obvious changes in brightness during the movement. At this time, it indicates that the reference grating is consistent with the scanning direction, that is, the grating line direction of the reference grating is consistent with the interference fringe direction. The alignment accuracy of this process is limited by the size of the reference grating and the moving distance. For a moving distance of 10 mm, the angular alignment error can be controlled to 0.001°.

步骤S180:在完成动态对准过程后还包括下述步骤:Step S180: After the dynamic alignment process is completed, the following steps are also included:

通过所述精密转台的移动对光栅基底的剩余区域进行曝光流程,在显影完成后即可获得与硅晶圆方向精确平行的高刻线密度光栅掩模。The remaining area of the grating substrate is exposed by moving the precision turntable, and after development is completed, a high-line density grating mask that is precisely parallel to the direction of the silicon wafer can be obtained.

可以理解,调节完成后,保持精密转台角度不变,控制工作台移动使曝光光束形成的干涉场光斑移出参考光栅区域,回到初始位置。控制工作台运动进行曝光流程。曝光与显影完成后,即可获得与晶圆<111>晶向平行的高刻线密度光栅掩模。It can be understood that after the adjustment is completed, the angle of the precision turntable is kept unchanged, and the worktable is controlled to move so that the interference field spot formed by the exposure beam moves out of the reference grating area and returns to the initial position. The worktable movement is controlled to perform the exposure process. After the exposure and development are completed, a high-line density grating mask parallel to the <111> crystal direction of the wafer can be obtained.

本申请提供的晶向精确对准的方法,通过引入一个光栅周期与SBIL系统干涉场周期相匹配的参考光栅作为中间过程,避免了在SBIL系统中引入额外元件,并且把耗时较长的过程转移到紫外光刻设备中,提高了SBIL系统的使用效率,能够使SBIL系统的干涉条纹在(110)硅片表面上精确对准<111>晶体取向,从而在湿法蚀刻工艺中获得超高的蚀刻速率比,制备出高质量的高线密度高深宽比单晶硅光栅。The method for precise crystal orientation alignment provided by the present application avoids the introduction of additional components into the SBIL system by introducing a reference grating whose grating period matches the interference field period of the SBIL system as an intermediate process, and transfers the time-consuming process to the ultraviolet lithography equipment, thereby improving the utilization efficiency of the SBIL system, and enabling the interference fringes of the SBIL system to be precisely aligned with the <111> crystal orientation on the (110) silicon wafer surface, thereby obtaining an ultra-high etching rate ratio in the wet etching process, and preparing high-quality, high-line-density, high-aspect-ratio single-crystal silicon gratings.

可以理解,以上所述实施例的各技术特征可以进行任意的组合,为使描述简洁,未对上述实施例中的各个技术特征所有可能的组合都进行描述,然而,只要这些技术特征的组合不存在矛盾,都应当认为是本说明书记载的范围。It can be understood that the technical features of the above-described embodiments can be arbitrarily combined. In order to make the description concise, not all possible combinations of the technical features in the above-described embodiments are described. However, as long as there is no contradiction in the combination of these technical features, they should be considered to be within the scope of this specification.

以上仅为本申请的较佳实施例而已,仅具体描述了本申请的技术原理,这些描述只是为了解释本申请的原理,不能以任何方式解释为对本申请保护范围的限制。基于此处解释,凡在本申请的精神和原则之内所作的任何修改、等同替换和改进,及本领域的技术人员不需要付出创造性的劳动即可联想到本申请的其他具体实施方式,均应包含在本申请的保护范围之内。The above are only preferred embodiments of the present application, and only specifically describe the technical principles of the present application. These descriptions are only for explaining the principles of the present application and cannot be interpreted in any way as limiting the scope of protection of the present application. Based on the explanation here, any modifications, equivalent substitutions and improvements made within the spirit and principles of the present application, and other specific implementation methods of the present application that can be associated with by technicians in this field without creative work, should be included in the scope of protection of the present application.

Claims (12)

1.一种晶向对准的方法,其特征在于,包括下述步骤:1. A method for crystal alignment, comprising the following steps: 对硅晶圆进行晶向定位;Perform crystal orientation positioning on silicon wafers; 获取与所述硅晶圆的晶向平行的参考光栅;Acquiring a reference grating parallel to the crystal direction of the silicon wafer; 将带有所述参考光栅的欲曝光的光栅基底置于精密转台上;Placing the grating substrate to be exposed and carrying the reference grating on a precision turntable; 移动所述精密转台,使位于所述精密转台左右两束曝光光束均在所述光栅基底的法线方向产生衍射光;Moving the precision turntable so that the two exposure light beams on the left and right of the precision turntable both generate diffracted light in the normal direction of the grating substrate; 旋转所述精密转台使两束衍射光重合并获取干涉图样;Rotating the precision turntable to make the two diffracted light beams overlap and obtain an interference pattern; 调整所述精密转台,使所述干涉图样出现的干涉条纹周期达到最大值,静态对准完成。The precision turntable is adjusted so that the interference fringe period of the interference pattern reaches a maximum value, and the static alignment is completed. 2.如权利要求1所述的晶向对准的方法,其特征在于,在对硅晶圆进行晶向定位的步骤中,具体包括下述步骤:通过扇形掩模预刻蚀技术对硅晶圆进行<111>晶向定位。2. The method for crystal orientation alignment as claimed in claim 1, characterized in that, in the step of performing crystal orientation positioning on the silicon wafer, the following step is specifically included: performing <111> crystal orientation positioning on the silicon wafer by using a fan-shaped mask pre-etching technology. 3.如权利要求1所述的晶向对准的方法,其特征在于,在获取与所述硅晶圆的晶向平行的参考光栅的步骤中,具体包括下述步骤:通过紫外接触式光刻设备制作与晶向平行的参考光栅。3. The method for crystal orientation alignment as described in claim 1 is characterized in that, in the step of obtaining a reference grating parallel to the crystal orientation of the silicon wafer, the following step is specifically included: making a reference grating parallel to the crystal orientation by ultraviolet contact lithography equipment. 4.如权利要求1所述的晶向对准的方法,其特征在于,在将带有所述参考光栅与光致抗蚀剂的欲曝光硅晶圆置于精密转台上的步骤中,所述精密转台为二维运动工作台。4. The method for crystal alignment as described in claim 1 is characterized in that in the step of placing the silicon wafer to be exposed with the reference grating and the photoresist on a precision turntable, the precision turntable is a two-dimensional motion worktable. 5.如权利要求4所述的晶向对准的方法,其特征在于,所述二维运动工作台由直线电机牵引并分别沿扫描方向和步进方向运动,且扫描方向和步进方向相垂直。5. The method for crystal alignment as described in claim 4 is characterized in that the two-dimensional motion workbench is pulled by a linear motor and moves along a scanning direction and a stepping direction respectively, and the scanning direction and the stepping direction are perpendicular to each other. 6.如权利要求5所述的晶向对准的方法,其特征在于,所述参考光栅的刻线方向与扫描方向平行。6 . The method for crystal alignment as claimed in claim 5 , wherein the direction of the lines of the reference grating is parallel to the scanning direction. 7.如权利要求1所述的晶向对准的方法,其特征在于,在移动所述精密转台,位于所述精密转台左右两束曝光光束均会在法线方向产生衍射光的步骤中,具体包括下述步骤:7. The method for crystal alignment according to claim 1, characterized in that, in the step of moving the precision turntable so that the two exposure light beams on the left and right of the precision turntable both generate diffracted light in the normal direction, the method specifically comprises the following steps: 移动所述精密转台,使干涉场位于所述参考光栅上,位于所述精密转台的左右两束曝光光束在所述参考光栅的表面重合,左右两束曝光光束均在所述光栅基底法线方向产生衍射光。The precision turntable is moved so that the interference field is located on the reference grating, and the left and right exposure beams located on the precision turntable overlap on the surface of the reference grating, and both the left and right exposure beams generate diffraction light in the normal direction of the grating base. 8.如权利要求1所述的晶向对准的方法,其特征在于,在旋转所述精密转台使两束衍射光重合并获取干涉图样的步骤中,具体包括下述步骤:8. The method for crystal alignment according to claim 1, characterized in that the step of rotating the precision turntable to make the two diffracted light beams overlap and obtain the interference pattern specifically comprises the following steps: 在所述光栅基底的法线方向产生的两束衍射光经过上方的平面镜入射至一侧的CCD上,再通过计算机获取CCD上的实时光强分布图像。Two beams of diffracted light generated in the normal direction of the grating substrate are incident on the CCD on one side through the upper plane mirror, and then a real-time light intensity distribution image on the CCD is obtained by a computer. 9.如权利要求1所述的晶向对准的方法,其特征在于,在调整所述精密转台,使所述干涉图样出现的干涉条纹周期达到最大值,静态对准完成的步骤中,具体包括下述步骤:9. The method for crystal alignment according to claim 1, characterized in that, in the step of adjusting the precision turntable so that the interference fringe period of the interference pattern reaches a maximum value and static alignment is completed, the following steps are specifically included: 通过调整所述精密转台,使光斑图像出现干涉条纹,之后缓慢调整所述精密转台使干涉条纹的周期达到最大值,此时静态对准完成,所述周期达到最大值即周期大于光斑的直径,光斑范围内无法观测到完整的周期性条纹。By adjusting the precision turntable, interference fringes appear in the spot image, and then slowly adjusting the precision turntable to make the period of the interference fringes reach a maximum value, the static alignment is completed at this time, the period reaches the maximum value, that is, the period is greater than the diameter of the spot, and no complete periodic fringes can be observed within the spot range. 10.如权利要求9所述的晶向对准的方法,其特征在于,在调整所述精密转台,使所述干涉图样出现的干涉条纹周期达到最大值,静态对准完成的步骤,具体包括下述步骤:10. The method for crystal alignment according to claim 9, characterized in that the step of adjusting the precision turntable so that the interference fringe period of the interference pattern reaches a maximum value and the static alignment is completed specifically comprises the following steps: 调整所述精密转台在扫描方向匀速移动,所述参考光栅与所述左右两束曝光光束产生的相对移动并使得两个衍射光束之间产生一个随移动距离线性变化的相位差,从而在所述干涉图样的光斑上每一点的光强产生明暗的周期性变化,其变化周期与对准角度误差成反比。The precision turntable is adjusted to move at a uniform speed in the scanning direction. The reference grating and the left and right exposure beams produce relative movement, and a phase difference is generated between the two diffracted beams that changes linearly with the moving distance, thereby producing a periodic change in light intensity at each point on the light spot of the interference pattern, and the change period is inversely proportional to the alignment angle error. 11.如权利要求10所述的晶向对准的方法,其特征在于,在在调整所述精密转台,使所述干涉图样出现的干涉条纹周期达到最大值,静态对准完成的步骤中的步骤中,还包括下述步骤:11. The method for crystal alignment according to claim 10, characterized in that, in the step of adjusting the precision turntable so that the interference fringe period of the interference pattern reaches a maximum value and the static alignment is completed, the following step is also included: 所述精密转台每次移动完成后,调节所述精密转台角度,再调节所述精密转台反向移动,重复上述过程,直至找到变化周期最大的转台位置,此时保持所述精密转台位置不变完成动态对准过程完成。After each movement of the precision turntable is completed, the angle of the precision turntable is adjusted, and then the precision turntable is adjusted to move in the opposite direction, and the above process is repeated until the turntable position with the largest change cycle is found. At this time, the position of the precision turntable is kept unchanged to complete the dynamic alignment process. 12.如权利要求11所述的晶向对准的方法,其特征在于,在完成动态对准过程后还包括下述步骤:12. The method for crystal alignment according to claim 11, characterized in that it further comprises the following steps after completing the dynamic alignment process: 通过所述精密转台的移动对光栅基底的剩余区域进行曝光流程,在显影完成后即可获得与硅晶圆方向精确平行的高刻线密度光栅掩模。The remaining area of the grating substrate is exposed by moving the precision turntable, and after development is completed, a high-line density grating mask that is precisely parallel to the direction of the silicon wafer can be obtained.
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