CN115547927A - Preparation method of array substrate, array substrate and display panel - Google Patents
Preparation method of array substrate, array substrate and display panel Download PDFInfo
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Abstract
Description
技术领域technical field
本申请涉及显示面板技术领域,尤其涉及一种阵列基板的制备方法、阵列基板及显示面板。The present application relates to the technical field of display panels, in particular to a method for preparing an array substrate, an array substrate and a display panel.
背景技术Background technique
薄膜晶体管液晶显示器(TFT-LCD)是由阵列玻璃基板(Array)和彩膜玻璃基板(CF)以及两者成盒(cell)而成。传动的阵列基板包含,基板上形成的栅极信号线(GE)或第一金属层(M1)(GE or M1)、栅极绝缘层(GI)、非晶硅半导体层(a-Si)、源漏极或第二金属层(SD or M2)、钝化层(PV)和透明电极(ITO),制备阵列基板常采用4mask工艺,将非晶硅半导体层(a-Si层)和源漏极层(SD层)合并成一层,在传统的阵列基板的制备过程中常采用刻蚀的方式形成所需图案化膜层,且除栅极绝缘层(GI)无需形成图案化处理外,其他各层均需要使用掩模板(Mask)经过黄光制程形成图案化的膜层,由于需要多次刻蚀,容易导致面板特性的均匀性较差,尤其是现在越来越多大尺寸产品,更容易出现面板品质异常的问题。A thin film transistor liquid crystal display (TFT-LCD) is composed of an array glass substrate (Array), a color filter glass substrate (CF) and a cell of the two. The transmission array substrate includes the gate signal line (GE) or the first metal layer (M1) (GE or M1) formed on the substrate, the gate insulating layer (GI), the amorphous silicon semiconductor layer (a-Si), The source and drain or the second metal layer (SD or M2), passivation layer (PV) and transparent electrode (ITO), the preparation of the array substrate often adopts the 4mask process, and the amorphous silicon semiconductor layer (a-Si layer) and the source and drain The electrode layer (SD layer) is combined into one layer. In the preparation process of the traditional array substrate, etching is often used to form the required patterned film layer, and except for the gate insulating layer (GI), which does not need to be patterned, other various All layers need to use a mask (Mask) to form a patterned film layer through a yellow light process. Due to the need for multiple etchings, it is easy to cause poor uniformity of panel characteristics, especially now that more and more large-size products are more likely to appear. The problem of abnormal panel quality.
发明内容Contents of the invention
为了解决阵列基板刻蚀次数多、控制难度大的技术问题,本申请的主要目的在于,提供一种能够减小刻蚀次数、简化工艺的一种阵列基板的制备方法、阵列基板及显示面板。In order to solve the technical problem of many etching times and difficult control of the array substrate, the main purpose of the present application is to provide a method for preparing an array substrate, an array substrate and a display panel that can reduce the number of etching times and simplify the process.
为实现上述发明目的,本申请采用如下技术方案:In order to realize the above-mentioned purpose of the invention, the application adopts the following technical solutions:
根据本申请的一个方面,提供一种阵列基板的制备方法,包括在基板上依次形成栅极金属层、栅极绝缘层及第一半导体层;所述制备方法还包括步骤:According to one aspect of the present application, a method for preparing an array substrate is provided, including sequentially forming a gate metal layer, a gate insulating layer, and a first semiconductor layer on the substrate; the preparation method further includes the steps of:
在所述第一半导体层上形成光刻胶层;forming a photoresist layer on the first semiconductor layer;
通过掩模板对所述光刻胶层进行曝光、显影,在所述第一半导体层上形成第一胶层模块及第二胶层模块,所述第一胶层模块与第二胶层模块之间具有与所述第一半导体层接触的开孔,所述第二胶层模块的厚度大于所述第一胶层模块的厚度;Exposing and developing the photoresist layer through a mask, forming a first subbing layer module and a second subbing layer module on the first semiconductor layer, and the connection between the first subbing layer module and the second subbing layer module There is an opening in contact with the first semiconductor layer, and the thickness of the second glue layer module is greater than the thickness of the first glue layer module;
依次形成第二半导体层及第二金属层;sequentially forming a second semiconductor layer and a second metal layer;
完全清除第一胶层模块,暴露所述第一胶层模块对应的所述第一半导体层,并保留部分厚度的所述第二胶层模块作为缓冲模块,以图案化所述第二半导体层及所述第二金属层;completely removing the first glue layer module, exposing the first semiconductor layer corresponding to the first glue layer module, and retaining a part of the thickness of the second glue layer module as a buffer module to pattern the second semiconductor layer and the second metal layer;
刻蚀图案化所述第一半导体层,形成与所述栅极绝缘层接触的第一沟道,同时清除所述缓冲模块,在相邻所述开孔对应的所述第二金属层、所述第二半导体层之间形成与所述第一半导体层接触的第二沟道。Etching and patterning the first semiconductor layer to form a first channel in contact with the gate insulating layer, and cleaning the buffer module at the same time, the second metal layer corresponding to the adjacent opening, the A second channel in contact with the first semiconductor layer is formed between the second semiconductor layers.
根据本申请的一实施方式,其中通过掩模板对所述光刻胶层进行曝光、显影后,还包括步骤:According to an embodiment of the present application, after exposing and developing the photoresist layer through a mask, the steps further include:
等离子体轰击,以使所述第一半导体层向外溅射无机粒子,在所述第一胶层模块及所述第二胶层模块的表面并形成不连续的掩体层;Plasma bombardment, so that the first semiconductor layer sputters inorganic particles outward, forming a discontinuous masking layer on the surface of the first glue layer module and the second glue layer module;
刻蚀所述掩体层以对所述掩体层进行制绒处理,形成与所述第一胶层模块及所述第二胶层模块接触的剥离腔;Etching the masking layer to perform texturing on the masking layer to form a peeling cavity in contact with the first adhesive layer module and the second adhesive layer module;
依次形成第二半导体层及第二金属层;sequentially forming a second semiconductor layer and a second metal layer;
使采用剥离液浸入所述剥离腔内与所述第一胶层模块及所述第二胶层模块接触,以完全清除所述第一胶层模块,并保留部分厚度的所述第二胶层模块作为所述缓冲模块,以图案化所述第二半导体层及所述第二金属层。immersing the stripping liquid into the stripping chamber to contact the first glue line module and the second glue line module, so as to completely remove the first glue line module and retain part of the thickness of the second glue line The module serves as the buffer module to pattern the second semiconductor layer and the second metal layer.
根据本申请的一实施方式,其中刻蚀所述掩体层以对所述掩体层进行制绒,其中,对所述掩体层进行刻蚀后,在所述第一胶层模块表面及所述第二胶层模块表面形成多个支撑柱,相邻所述支撑柱之间具有所述剥离腔。According to an embodiment of the present application, the masking layer is etched to texture the masking layer, wherein, after etching the masking layer, the surface of the first adhesive layer module and the second A plurality of support columns are formed on the surface of the second glue layer module, and the stripping cavity is formed between adjacent support columns.
根据本申请的一实施方式,其中所述掩体层的厚度为所述支撑柱的高度为所述支撑柱的最大外径的范围为 According to an embodiment of the present application, wherein the thickness of the mask layer is The height of the support column is The range of the maximum outer diameter of the support column is
根据本申请的一实施方式,其中所述剥离液为包括胺类碱性有机物和极性有机溶剂的混合溶液,采用所述剥离液进行剥离的处理时间为1S-1200S。According to an embodiment of the present application, wherein the stripping solution is a mixed solution including amine basic organic substances and polar organic solvents, and the treatment time for stripping with the stripping solution is 1S-1200S.
根据本申请的一实施方式,其中通过掩模板对所述光刻胶层进行曝光、显影,其中,所述掩模板为半透过光罩,在垂直于所述基板的投影面内,所述第一胶层模块与所述掩模板的次透光区一一对应,所述第二胶层模块与所述掩模板的全遮挡区一一对应,所述开孔与所述掩模板的全透光区一一对应。According to an embodiment of the present application, the photoresist layer is exposed and developed through a mask, wherein the mask is a semi-transmissive mask, and in a projection plane perpendicular to the substrate, the The first adhesive layer module corresponds to the sub-light transmission area of the mask plate one by one, the second adhesive layer module corresponds to the full shielding area of the mask plate one by one, and the openings correspond to the full shielding area of the mask plate The light-transmitting regions correspond one-to-one.
根据本申请的一实施方式,其中所述第一胶层模块的厚度为D1,所述第二胶层模块的厚度为D2,其中,且 According to an embodiment of the present application, wherein the thickness of the first glue layer module is D1, and the thickness of the second glue layer module is D2, wherein, and
根据本申请的一实施方式,其中所述缓冲模块的厚度为D3,且 According to an embodiment of the present application, wherein the thickness of the buffer module is D3, and
根据本申请的另一方面,提供一种阵列基板,包括:According to another aspect of the present application, an array substrate is provided, comprising:
通过所述阵列基板的制备方法制备得到的器件结构;The device structure prepared by the preparation method of the array substrate;
依次形成于所述器件结构上的钝化层及像素电极层。A passivation layer and a pixel electrode layer are sequentially formed on the device structure.
根据本申请的另一方面,提供一种显示面板,包括:According to another aspect of the present application, a display panel is provided, including:
上述的阵列基板;The above-mentioned array substrate;
彩膜基板,与所述阵列基板对盒设置;The color filter substrate is arranged in a box with the array substrate;
液晶层,设置于所述的阵列基板与所述彩膜基板之间。The liquid crystal layer is arranged between the array substrate and the color filter substrate.
由上述技术方案可知,本申请的一种阵列基板的制备方法、阵列基板及显示面板的优点和积极效果在于:From the above technical solutions, it can be seen that the advantages and positive effects of the method for preparing an array substrate, the array substrate and the display panel of the present application are as follows:
通过在第一半导体上形成光刻胶层厚,通过对光刻胶层进行曝光、显影后,保留第一叫层面模块及第二胶层模块,并形成与第一半导体层接触的开孔,在依次形成第二半导体层及第二金属层厚,在开孔位置的第二半导体层与第一半导体层接触,在完全清除第一胶层模块后,暴露第一胶层模块对应的第一半导体层,并保留部分厚度的第二胶层模块作为缓冲模块,实现图案化所述第二半导体层及所述第二金属层,之后经过刻蚀处理图案化所述第一半导体层,在没有缓冲模块覆盖的位置,形成与栅极绝缘层结合接触的第一沟道,刻蚀清除缓冲模块后,在相邻开孔对应的所述第二金属层、所述第二半导体层之间形成对与第一半导体层接触的第二沟道,进而,通过本申请的制备方法,相比现有技术,图案化第二金属层及第二半导体层时无需进行刻蚀工艺处理,减少刻蚀次数、简化处理工艺,提高显示面板特性的均匀性,有效提高显示面板的品质。By forming a thick photoresist layer on the first semiconductor, after exposing and developing the photoresist layer, retaining the first layer module and the second layer module, and forming an opening in contact with the first semiconductor layer, After forming the second semiconductor layer and the thickness of the second metal layer in sequence, the second semiconductor layer at the opening position is in contact with the first semiconductor layer. After the first glue layer module is completely removed, the corresponding first glue layer module is exposed. semiconductor layer, and retain a part of the thickness of the second adhesive layer module as a buffer module to realize the patterning of the second semiconductor layer and the second metal layer, and then pattern the first semiconductor layer after etching, without The position covered by the buffer module forms a first channel in joint contact with the gate insulating layer. After the buffer module is etched and removed, a channel is formed between the second metal layer and the second semiconductor layer corresponding to the adjacent opening. For the second channel that is in contact with the first semiconductor layer, furthermore, through the preparation method of the present application, compared with the prior art, no etching process is required when patterning the second metal layer and the second semiconductor layer, reducing the etching process. The number of times, the simplification of the processing process, the uniformity of the characteristics of the display panel are improved, and the quality of the display panel is effectively improved.
附图说明Description of drawings
此处的附图被并入说明书中并构成本说明书的一部分,示出了符合本申请的实施例,并与说明书一起用于解释本申请的原理。The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments consistent with the application and together with the description serve to explain the principles of the application.
为了更清楚地说明本申请实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,对于本领域普通技术人员而言,在不付出创造性劳动性的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present application or the prior art, the following will briefly introduce the drawings that need to be used in the description of the embodiments or the prior art. Obviously, for those of ordinary skill in the art, In other words, other drawings can also be obtained from these drawings without paying creative labor.
图1为本申请实施例提供的一个实施例的一种阵列基板的制备方法的流程示意图;FIG. 1 is a schematic flowchart of a method for preparing an array substrate according to an embodiment of the present application;
图2为本申请实施例提供的另一实施例的一种阵列基板的制备方法的流程示意图;FIG. 2 is a schematic flowchart of a method for preparing an array substrate according to another embodiment provided by the embodiment of the present application;
图3为本申请实施例提供的一种阵列基板的制备方法的中形成第一半导体层的阵列基板的剖面结构示意图;3 is a schematic cross-sectional structure diagram of an array substrate on which a first semiconductor layer is formed in a method for preparing an array substrate provided in an embodiment of the present application;
图4为本申请实施例提供的一种阵列基板的制备方法的中形成对光刻胶层的阵列基板的剖面结构示意图;4 is a schematic cross-sectional structure diagram of an array substrate with a photoresist layer formed in a method for preparing an array substrate provided in an embodiment of the present application;
图5为本申请实施例提供的一种阵列基板的制备方法的中对光刻胶层进行曝光时阵列基板的剖面结构示意图;5 is a schematic cross-sectional structure diagram of an array substrate when exposing a photoresist layer in a method for preparing an array substrate provided in an embodiment of the present application;
图6为本申请实施例提供的一种阵列基板的制备方法的中对光刻胶层进行显影时阵列基板的剖面结构示意图;6 is a schematic cross-sectional structure diagram of an array substrate when developing a photoresist layer in a method for preparing an array substrate provided in an embodiment of the present application;
图7为本申请实施例提供的一种阵列基板的制备方法的中制绒处理后阵列基板的剖面结构示意图;FIG. 7 is a schematic cross-sectional structure diagram of an array substrate after texturing in a method for preparing an array substrate provided in an embodiment of the present application;
图8为本申请实施例提供的一种阵列基板的制备方法的中制绒处理后第一胶层模块(第二胶层模块)的剖面结构示意图;Fig. 8 is a schematic cross-sectional structure diagram of the first adhesive layer module (second adhesive layer module) after texturing in the method for preparing an array substrate provided by the embodiment of the present application;
图9为本申请实施例提供的一种阵列基板的制备方法的中形成第二半导体层后阵列基板的剖面结构示意图;9 is a schematic cross-sectional structure diagram of an array substrate after forming a second semiconductor layer in a method for manufacturing an array substrate provided by an embodiment of the present application;
图10为本申请实施例提供的一种阵列基板的制备方法的中形成第二金属层后阵列基板的剖面结构示意图;10 is a schematic cross-sectional structure diagram of an array substrate after forming a second metal layer in a method for manufacturing an array substrate provided in an embodiment of the present application;
图11为本申请实施例提供的一种阵列基板的制备方法的中完全清除第一胶层模块并形成缓冲模块时阵列基板的剖面结构示意图;11 is a schematic cross-sectional structure diagram of the array substrate when the first adhesive layer module is completely removed and a buffer module is formed in a method for preparing an array substrate provided by the embodiment of the present application;
图12为本申请实施例提供的一种阵列基板的制备方法的中刻蚀图案化第一半导体层后阵列基板的剖面结构示意图;FIG. 12 is a schematic cross-sectional structure diagram of the array substrate after etching and patterning the first semiconductor layer in a method for preparing an array substrate provided by an embodiment of the present application;
图13为本申请实施例提供的另一个实施例的一种阵列基板的制备方法的流程示意图。FIG. 13 is a schematic flowchart of a method for manufacturing an array substrate according to another embodiment provided by the embodiments of the present application.
其中:in:
10、基板;20、栅极金属层;30、栅极绝缘层;40、第一半导体层;10. Substrate; 20. Gate metal layer; 30. Gate insulating layer; 40. First semiconductor layer;
50、光刻胶层;51、第一胶层模块;52、第二胶层模块;53、开孔;54、缓冲模块;50. Photoresist layer; 51. First glue layer module; 52. Second glue layer module; 53. Opening hole; 54. Buffer module;
60、第二半导体层;70、第二金属层;80、第一沟道;90、第二沟道;100、掩模板;1、掩体层;2、剥离腔;3、支撑柱。60. The second semiconductor layer; 70. The second metal layer; 80. The first channel; 90. The second channel; 100. The mask plate; 1. The mask layer;
具体实施方式detailed description
为使本申请实施例的目的、技术方案和优点更加清楚,下面将结合本申请实施例中的附图,对本申请实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本申请的一部分实施例,而不是全部的实施例。基于本申请中的实施例,本领域普通技术人员在没有做出创造性劳动的前提下所获得的所有其他实施例,都属于本申请保护的范围。In order to make the purposes, technical solutions and advantages of the embodiments of the present application clearer, the technical solutions in the embodiments of the present application will be clearly and completely described below in conjunction with the drawings in the embodiments of the present application. Obviously, the described embodiments It is a part of the embodiments of this application, but not all of them. Based on the embodiments in the present application, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present application.
现有技术中在阵列基板的制备过程中会经过至少4次刻蚀,才可以对栅极信号线(GE)或第一金属层(M1)(GE or M1)、非晶硅半导体层(a-Si)、源漏极或第二金属层(SD orM2)、钝化层(PV)和透明电极(ITO)进行图案化,由于刻蚀工艺控制难度大,多次刻蚀后会导致形成的显示面板制程特性不均匀问题,为了解决阵列基板刻蚀次数多、控制刻蚀的均匀性难度大的技术问题,本申请的主要目的在于,提供一种能够减小刻蚀次数、提高刻蚀均匀性的一种阵列基板的制备方法及阵列基板。In the prior art, at least four times of etching are performed during the preparation of the array substrate before the gate signal line (GE) or the first metal layer (M1) (GE or M1 ), the amorphous silicon semiconductor layer (a -Si), source and drain or second metal layer (SD orM2), passivation layer (PV) and transparent electrode (ITO) for patterning, due to the difficulty in controlling the etching process, multiple etchings will lead to the formation of In order to solve the problem of uneven process characteristics of the display panel, in order to solve the technical problem that the number of etching times of the array substrate is high and the uniformity of etching is difficult to control, the main purpose of this application is to provide a method that can reduce the number of etching times and improve the uniformity of etching. A method for preparing an array substrate and the array substrate.
为实现上述发明目的,本申请采用如下技术方案:In order to realize the above-mentioned purpose of the invention, the application adopts the following technical solutions:
根据本申请的一个方面,提供一种阵列基板的制备方法,包括:According to one aspect of the present application, a method for preparing an array substrate is provided, including:
S10:在基板10上依次形成栅极金属层20、栅极绝缘层30及第一半导体层40;S10: sequentially forming a
在本申请中的一个实施例中,玻璃基板10上通过物理气相沉积(PVD)第一金属层,再通过第一道光衍膜板(mask)进行黄光制程(Photo)形成图案化正性光刻胶层50(PR),其中Photo制程包含涂布光刻胶、曝光和显影制程;In one embodiment of the present application, the first metal layer is formed by physical vapor deposition (PVD) on the
再通过湿刻蚀(Wet)制程将未被PR覆盖的金属去除,形成图案化栅极信号线(GE)及阵列公共电极(A_Com),最后通过剥离液将PR层剥离掉,当第一金属层完成后其厚度为 Then, the metal not covered by PR is removed by wet etching (Wet) process to form patterned gate signal line (GE) and array common electrode (A_Com), and finally the PR layer is peeled off by stripping solution. When the first metal After the layer is completed its thickness is
之后通过化学气相沉积(CVD)一层栅极绝缘层30(GI)和第一半导体层40(a-si),其中GI层厚度为其成分为氮化硅或者氧化硅或氮化硅与氧化硅组合层,第一半导体层40(a-si)层厚度为其成分为非晶硅。Then by chemical vapor deposition (CVD) a layer of gate insulating layer 30 (GI) and the first semiconductor layer 40 (a-si), wherein the thickness of the GI layer is Its composition is silicon nitride or silicon oxide or a combination layer of silicon nitride and silicon oxide, and the thickness of the first semiconductor layer 40 (a-si) is Its composition is amorphous silicon.
所述制备方法还包括步骤:The preparation method also includes the steps of:
S20:在所述第一半导体层40上形成光刻胶层50;S20: forming a
S30:通过掩模板100对所述光刻胶层50进行曝光、显影,在所述第一半导体层40上形成第一胶层模块51及第二胶层模块52,所述第一胶层模块51与第二胶层模块52之间具有与所述第一半导体层40接触的开孔53,所述第二胶层模块52的厚度大于所述第一胶层模块51的厚度;S30: Exposing and developing the
S40:依次形成第二半导体层60及第二金属层70;S40: sequentially forming the
S50:完全清除第一胶层模块51,暴露所述第一胶层模块51对应的所述第一半导体层40,并保留部分厚度的所述第二胶层模块52作为缓冲模块54,以图案化所述第二半导体层60及所述第二金属层70;S50: completely remove the first
S60:刻蚀图案化所述第一半导体层40,形成与所述栅极绝缘层30接触的第一沟道80,同时清除所述缓冲模块54,在相邻所述开孔53对应的所述第二金属层70、所述第二半导体层60之间形成与所述第一半导体层40接触的第二沟道90。S60: Etching and patterning the
参考图1-图6,通过在第一半导体上形成光刻胶层50厚,通过对光刻胶层50进行曝光、显影后,保留第一叫层面模块及第二胶层模块52,并形成与第一半导体层40接触的开孔53,在依次形成第二半导体层60及第二金属层70厚,在开孔53位置的第二半导体层60与第一半导体层40接触,可通过所述开孔53为形成第二半导体层60及第二金属层70预留容纳的位置,以使第二半导体层60与第一半导体层40级接触,并方便对第二半导体层60及第二金属层70进行图案化。Referring to Figures 1-6, by forming a
在S30步骤中,根据本申请的一实施方式,其中通过掩模板100对所述光刻胶层50进行曝光、显影,其中,所述掩模板100为半透过光罩,在垂直于所述基板10的投影面内,所述第一胶层模块51与所述掩模板100的次透光区一一对应,所述第二胶层模块52与所述掩模板100的全遮挡区一一对应,所述开孔53与所述掩模板100的全透光区一一对应。进而,可使第二胶层模块52的厚度大于第一胶层模块51的厚度。In step S30, according to an embodiment of the present application, the
在本申请的一个示例中,使用半透过光衍膜板(Half-Tone Mask:HTM)进行黄光制程(photo)制作图案化正性光刻胶层50(PR),其中后续第二金属层70(SD)需保留位置(相当于开孔53位置)的PR全部去除,后续SD层需去除位置(相当于第一胶层模块51及第二胶层模块52)的PR保留,进一步的薄膜晶体管(TFT)沟道(相当于第二胶层模块52)位置的PR使用HTM不透过部分制作而成,其他保留的PR(相当于第一胶层模块51)则使用HTM半透过部分制作而成,因此TFT沟道位置PR会较其他位置保留的PR厚度更厚一些。In an example of the present application, a patterned positive photoresist layer 50 (PR) is produced by using a half-tone mask (Half-Tone Mask: HTM) to produce a patterned positive photoresist layer 50 (PR), in which the second metal All the PRs in the positions to be reserved for the layer 70 (SD) (equivalent to the position of the opening 53) are all removed, and the PRs in the positions to be removed in the subsequent SD layer (equivalent to the first
在本申请中,其他位置保留PR(相当于第一胶层模块51)厚度为TFT沟道处PR厚度(相当于第二胶层模块52)通常较其他位置PR(相当于第一胶层模块51)厚 In this application, other positions reserve PR (equivalent to the first adhesive layer module 51) thickness is The thickness of PR at the TFT channel (equivalent to the second glue layer module 52) is usually thicker than other positions PR (equivalent to the first glue layer module 51)
也就是,所述第一胶层模块51的厚度为D1,所述第二胶层模块52的厚度为D2,其中, 且进而以预留足够厚度的缓冲模块54,为S60在步骤中,形成第二沟道90做基础。That is, the thickness of the first
参考图12,在对光刻胶层50进行显影后,去除开孔53位置处的光刻胶层50,并是第二胶层模块52的厚度大于第一胶层模块51的厚度,以便于在完全清除第一胶层模块51后,第二胶层模块52还具有剩余厚度,形成缓冲模块54,通过缓冲模块54可便于在刻蚀后形成在相邻两个开孔53对应的在相邻开孔53对应的所述第二金属层70、所述第二半导体层60之间形成对与第一半导体层40接触的第二沟道90。With reference to Fig. 12, after
且,经过S50步骤处理后,将暴露第一胶层模块51对应的第一半导体层40,并保留部分厚度的第二胶层模块52作为缓冲模块54,实现图案化所述第二半导体层60及所述第二金属层70,之后经过S60步骤经过刻蚀处理图案化所述第一半导体层40,在没有缓冲模块54覆盖的位置,形成与栅极绝缘层30结合接触的第一沟道80,刻蚀清除缓冲模块54后,进而,通过本申请的制备方法,相比现有技术,图案化第二金属层70及第二半导体层60时无需进行刻蚀工艺处理,减少刻蚀次数,进而简化处理工艺,提高多次刻蚀后面板特性的均匀性,有效提高产品品质。And, after the processing in step S50, the
相比现有的4mask工艺的TFT—LCD阵列基板较现有工艺减少2道Wet工艺,并简化一道Dry工艺,同时与现有5mask工艺相同可减少一张mask和减少一道黄光制程。因刻蚀工艺减少,因而可有效改善由于多道刻蚀工艺而导致的面板制程特性不均匀问题,进而改善由制程特性不均匀引起的产品品质问题,如GI制程膜厚不均匀导致的面板颜色不均问题,以及沟道长和半导体层拖尾长度不均导致的电性信赖性问题。Compared with the existing 4mask process, the TFT-LCD array substrate reduces 2 Wet processes and simplifies a Dry process. At the same time, it can reduce a mask and a yellow light process the same as the existing 5mask process. Due to the reduction of etching process, it can effectively improve the problem of uneven panel process characteristics caused by multi-channel etching process, and then improve the product quality problems caused by uneven process characteristics, such as panel color caused by uneven film thickness of GI process The problem of unevenness, and the electrical reliability problem caused by the uneven length of the channel length and the tail length of the semiconductor layer.
参考图2以及图7及图8所示,根据本申请的一实施方式,其中通过掩模板100对所述光刻胶层50进行曝光、显影后,也就是经过S30处理步骤后,还包括步骤:Referring to FIG. 2 and FIG. 7 and FIG. 8, according to an embodiment of the present application, after exposing and developing the
S100:等离子体轰击,以使所述第一半导体层40向外溅射无机粒子,在所述第一胶层模块51及所述第二胶层模块52的表面并形成不连续的掩体层1;S100: plasma bombardment, so that the
S200:刻蚀所述掩体层1以对所述掩体层1进行制绒处理,形成与所述第一胶层模块51及所述第二胶层模块52接触的剥离腔2;S200: Etching the
S300(S40):参考图9及图10所示,依次形成第二半导体层60及第二金属层70;作为示例,通过化学气相沉积法制作一层掺硼非晶硅层(N+a-Si层),其厚度为通过物理气相沉积法制作一层第二金属层70(SD层),其厚度为 S300 (S40): Referring to FIGS. 9 and 10, the
S400(S50):参考图11所示,使采用剥离液浸入所述剥离腔2内与所述第一胶层模块51及所述第二胶层模块52接触,以完全清除所述第一胶层模块51,并保留部分厚度的所述第二胶层模块52作为所述缓冲模块54,以图案化所述第二半导体层60及所述第二金属层70。S400 (S50): As shown in FIG. 11 , make the stripping solution immersed in the stripping
在经过S30步骤后,通过S100处理步骤,在第一胶层模块51及第二胶层模块52的表面形成不连续的无机粒子的掩体层1,其中无机粒子为对第一半导体层40等离子体轰击,以第一半导体层40的无机粒子溅射形成,其中不连续的无机粒子掩体层1。After the step S30, through the processing step S100, a
参考图在本申请一个实施例中,使用氩气惰性气体等离子体(Plasma)对未被光刻胶层50(PR)覆盖的第一半导体层40(a-Si层)进行轰击,将非晶硅(a-Si)溅射转移至PR表面,也就是第一胶层模块51及第二胶层模块52的表面,形成不连续无机非晶硅层的掩体,其无机a-Si层掩体层1的厚度为 Referring to the figure, in one embodiment of the present application, argon inert gas plasma (Plasma) is used to bombard the first semiconductor layer 40 (a-Si layer) not covered by the photoresist layer 50 (PR), and the amorphous Silicon (a-Si) is sputtered and transferred to the PR surface, that is, the surfaces of the first
在本申请的一个实施例中,通过S200步骤后形成剥离腔2,以便于后续S400中剥离液浸入所述剥离腔2内与所述第一胶层模块51及所述第二胶层模块52接触,参考图11所示,完全清除所述第一胶层模块51,并保留部分厚度的所述第二胶层模块52作为所述缓冲模块54,以图案化所述第二半导体层60及所述第二金属层70,进而,在形成图案化所述第二半导体层60及所述第二金属层70后,进行S60的步骤,参考图12所示,刻蚀图案化所述第一半导体层40,形成与所述栅极绝缘层30接触的第一沟道80,同时清除所述缓冲模块54,在相邻所述开孔53对应的所述第二金属层70、所述第二半导体层60之间形成与所述第一半导体层40接触的第二沟道90。In one embodiment of the present application, the stripping
进而,通过此步骤,无需通过刻蚀即可完成对第二金属层70及第二半导体层60的图案化处理,相比现有的4mask工艺,减少了两次刻蚀工艺,简化制备工艺的基础上,避免由于刻蚀控制难度大导致的显示面板的特性不均匀的问题。Furthermore, through this step, the patterning treatment of the
根据本申请的一实施方式,其中刻蚀所述掩体层1以对所述掩体层1进行制绒,其中,对所述掩体层1进行刻蚀后,在所述第一胶层模块51表面及所述第二胶层模块52表面形成多个支撑柱3,相邻所述支撑柱3之间具有所述剥离腔2。参考图8所示,通过支撑柱3提高剥离腔2的体积,以避免形成第二半导体层60及第二金属层70时遮蔽剥离腔2,提高剥离液与第一胶层模块51及第二胶层模块52的接触面积,提高S400步骤的剥离效率,提高第一胶层模块51及第二胶层模块52的剥离精确度。According to an embodiment of the present application, the
根据本申请的一实施方式,其中所述掩体层1的厚度为所述支撑柱3的高度为所述支撑柱3的最大外径的范围为以进一步的提高剥离腔2的体积,以提高剥离液与第一胶层模块51及第二胶层模块52的接触面积,提高S400步骤的剥离效率,提高第一胶层模块51及第二胶层模块52的剥离精确度。According to an embodiment of the present application, wherein the thickness of the
根据本申请的一实施方式,其中所述剥离液为包括胺类碱性有机物和极性有机溶剂的混合溶液,采用所述剥离液进行剥离的处理时间为1S-1200S。According to an embodiment of the present application, wherein the stripping solution is a mixed solution including amine basic organic substances and polar organic solvents, and the treatment time for stripping with the stripping solution is 1S-1200S.
其中S400步骤中,使用剥离液对第一胶层模块51及第二胶层模块52进行剥离(strip),所述剥离液主要成分为胺类碱性有机物和极性有机溶剂。其中胺类碱性有机物如酰胺类或醇胺类等,其含量占比30%-90%;其中极性有机溶剂如二甲基亚砜或二乙二醇丁醚等,其含量占比10%-70%。剥离工艺时间为1S-1200S。In the step S400, the first
对应在所述第二沟道90(TFT沟道)内的第二胶层模块52由于较第一沟道80对应的第一胶层模块51位置保留的光刻胶更厚,剥离工艺后第一胶层模块51被完全剥离,第二沟道90内第二胶层模块52仍有残留,形成缓冲模块54,缓冲模块54的厚度为 Corresponding to the second
在经过S400步骤后,进行S60的步骤,通过干刻蚀制程将未被金属覆盖位置(对应第一沟道80位置处的)的第一半导体层40(a-Si层)去除,同时去除第二沟道90(TFT沟道)内残留PR(相当于缓冲模块54)和少部分第二沟道90(TFT沟道)内第一半导体层40(a-Si层),进而通过以上工艺完成第二道mask工艺图案化第一半导体层40(a-Si层)和第二金属层70高(SD层)。After step S400, step S60 is performed to remove the first semiconductor layer 40 (a-Si layer) at the position not covered by metal (corresponding to the position of the first channel 80) through a dry etching process, and remove the
参考图13所示,根据本申请的一实施方式,其中刻蚀图案化所述第一半导体层40之后,还包括步骤:Referring to FIG. 13 , according to an embodiment of the present application, after etching and patterning the
形成钝化基层,通过掩模板100对所述钝化基层进行图案化处理,形成钝化层;forming a passivation base layer, and patterning the passivation base layer through a
形成像素电极基层,通过掩模板100对所述像素电极基层进行图案化处理,形成像素电极层。A pixel electrode base layer is formed, and the pixel electrode base layer is patterned through a
在本申请的一个实施例中,通过化学气相沉积法进行钝化层(Passivation:PV)镀膜,使用第3道mask进行黄光制程形成图案化正性光刻胶层50(PR),其中Photo制程包含涂布光刻胶、曝光和显影制程;再通过干刻蚀(Dry)制程将未被PR覆盖的钝化层去除,形成图案化钝化层,可对第二金属层70及薄膜晶体管形成保护作用。最后通过剥离液将PR层剥离掉。钝化层成分为氮化硅或氧化硅或氮化硅与氧化硅组合层,其厚度为 In one embodiment of the present application, the passivation layer (Passivation: PV) coating is carried out by chemical vapor deposition, and the third mask is used to perform a yellow light process to form a patterned positive photoresist layer 50 (PR), wherein Photo The process includes coating photoresist, exposure and development processes; and then removes the passivation layer not covered by PR through a dry etching (Dry) process to form a patterned passivation layer, which can be used for the
通过物理气相沉积法进行像素电极层镀膜,使用第4道mask进行黄光制程形成图案化正性光刻胶层50(PR),其中Photo制程包含涂布光刻胶、曝光和显影制程;再通过湿刻蚀(Wet)制程将未被PR覆盖的像素电极层去除,形成图案化像素电极层,最后通过剥离液将PR层剥离掉。像素电极层成分目前业界使用为氧化铟锡,亦可替换为其他透明导电材料,如PEDOT:PSS或银纳米线等,均在本发明范围内。像素电极层其厚度为 The pixel electrode layer is coated by physical vapor deposition, and the fourth mask is used to perform a yellow light process to form a patterned positive photoresist layer 50 (PR), wherein the Photo process includes coating photoresist, exposure and development processes; and then The pixel electrode layer not covered by PR is removed by a wet etching (Wet) process to form a patterned pixel electrode layer, and finally the PR layer is peeled off by a stripping solution. The composition of the pixel electrode layer is currently used in the industry as indium tin oxide, and it can also be replaced by other transparent conductive materials, such as PEDOT:PSS or silver nanowires, etc., all within the scope of the present invention. The thickness of the pixel electrode layer is
参考图1-图12所示,本申请提出一种阵列基板制备方法与现有4mask工艺相同是将a-Si层和SD层合并为一张mask制作,在a-Si镀膜完成后,使用HTM制作所需图形,将后续SD层金属需保留位置的有机光刻胶层50(PR)层预先在黄光制程中去除,后续需要去除SD金属层的位置保留PR并使用HTM的半透过部分制作,但其中TFT沟道位置使用HTM不透部分保留PR,此部分PR厚度较其他位置更厚。Referring to Figure 1-Figure 12, this application proposes an array substrate preparation method that is the same as the existing 4mask process, which is to combine the a-Si layer and the SD layer into one mask. After the a-Si coating is completed, use the HTM Make the required pattern, remove the organic photoresist layer 50 (PR) layer where the subsequent SD layer metal needs to be reserved in advance in the yellow light process, and then retain the PR at the position where the SD metal layer needs to be removed and use the semi-transparent part of the HTM Fabrication, but the TFT channel position uses the HTM opaque part to reserve the PR, and the PR thickness of this part is thicker than other positions.
经过S100及S200用等离子体轰击对保留的PR层进行制绒处理;After S100 and S200, the remaining PR layer is subjected to texturing treatment by plasma bombardment;
再进行步骤S300掺硼(P)a-Si层(N+a-Si)镀膜和第二金属层70(SD)镀膜;Then perform step S300 of boron-doped (P) a-Si layer (N+a-Si) coating and second metal layer 70 (SD) coating;
再进行S400中,采用剥离液对PR层进行剥离(strip),因保留PR的表面有一层绒状纳米柱状物PR层,在绒状PR上沉积的N+a-Si和SD层为非连续致密膜层(相当于掩体层1),因此剥离液能透过上层覆盖的膜层与PR接触,并将PR层和覆盖于PR上层的N+a-Si和SD层一起剥离。Then in S400, the PR layer is stripped using a stripping solution, because there is a layer of velvet nano-pillar PR layer on the surface of the PR, and the N+a-Si and SD layers deposited on the velvet PR are discontinuous The dense film layer (equivalent to the mask layer 1), so the stripping liquid can penetrate the upper covering film layer to contact PR, and peel off the PR layer together with the N+a-Si and SD layers covering the upper layer of PR.
由于通过HTM形成的TFT沟道(相当于第二沟道90)内的PR较厚(第二胶层模块52),通过剥离液剥离后,其他位置保留PR(第一胶层模块51)被剥离,而TFT沟道内仍会残留一定厚度PR(相当于缓冲模块54),最后通过干刻蚀制程将未被金属覆盖部分的a-Si层去除,同时可将沟道处残留的PR(相当于缓冲模块54)去除。Since the PR in the TFT channel (equivalent to the second channel 90) formed by the HTM is relatively thick (the second adhesive layer module 52), after stripping by the stripping liquid, the PR remaining in other positions (the first adhesive layer module 51) is removed. However, a certain thickness of PR (equivalent to the buffer module 54) will still remain in the channel of the TFT. Finally, the a-Si layer not covered by the metal will be removed through a dry etching process, and the remaining PR in the channel (equivalent to in the buffer module 54) to remove.
通过本发明所述制作方法的4mask工艺较现有工艺减少2道Wet工艺,并简化一道Dry工艺,同时与现有5mask工艺相同可减少一张mask和减少一道黄光制程。因刻蚀工艺减少,因而可有效改善由于多道刻蚀工艺而导致的面板制程特性不均匀问题,进而改善由制程特性不均匀引起的产品品质问题,如GI制程膜厚不均匀导致的面板颜色不均问题,以及沟道长和半导体层拖尾长度不均导致的电性信赖性问题。The 4mask process of the manufacturing method of the present invention reduces 2 Wet processes and simplifies a Dry process compared with the existing process, and at the same time reduces a mask and a yellow light process the same as the existing 5mask process. Due to the reduction of etching process, it can effectively improve the problem of uneven panel process characteristics caused by multi-channel etching process, and then improve the product quality problems caused by uneven process characteristics, such as panel color caused by uneven film thickness of GI process The problem of unevenness, and the electrical reliability problem caused by the uneven length of the channel length and the tail length of the semiconductor layer.
根据本申请的另一方面,提供一种阵列基板,包括:According to another aspect of the present application, an array substrate is provided, comprising:
通过所述阵列基板的制备方法制备得到的器件结构;The device structure prepared by the preparation method of the array substrate;
依次形成于所述器件结构上的钝化层及像素电极层。A passivation layer and a pixel electrode layer are sequentially formed on the device structure.
根据本申请的另一方面,提供一种显示面板,包括:According to another aspect of the present application, a display panel is provided, comprising:
所述的阵列基板;The array substrate;
彩膜基板,与所述阵列基板对盒设置;The color filter substrate is arranged in a box with the array substrate;
液晶层,设置于所述阵列基板及所述彩膜基板之间。The liquid crystal layer is arranged between the array substrate and the color filter substrate.
需要说明的是,在本文中,诸如“第一”和“第二”等之类的关系术语仅仅用来将一个实体或者操作与另一个实体或操作区分开来,而不一定要求或者暗示这些实体或操作之间存在任何这种实际的关系或者顺序。而且,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。在没有更多限制的情况下,由语句“包括一个……”限定的要素,并不排除在包括所述要素的过程、方法、物品或者设备中还存在另外的相同要素。It should be noted that in this article, relative terms such as "first" and "second" are only used to distinguish one entity or operation from another entity or operation, and do not necessarily require or imply these No such actual relationship or order exists between entities or operations. Furthermore, the term "comprises", "comprises" or any other variation thereof is intended to cover a non-exclusive inclusion such that a process, method, article, or apparatus comprising a set of elements includes not only those elements, but also includes elements not expressly listed. other elements of or also include elements inherent in such a process, method, article, or apparatus. Without further limitations, an element defined by the phrase "comprising a ..." does not exclude the presence of additional identical elements in the process, method, article or apparatus comprising said element.
以上所述仅是本申请的具体实施方式,使本领域技术人员能够理解或实现本申请。对这些实施例的多种修改对本领域的技术人员来说将是显而易见的,本文中所定义的一般原理可以在不脱离本申请的精神或范围的情况下,在其它实施例中实现。因此,本申请将不会被限制于本文所示的这些实施例,而是要符合与本文所申请的原理和新颖特点相一致的最宽的范围。The above descriptions are only specific implementation manners of the present application, so that those skilled in the art can understand or implement the present application. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the general principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the application. Therefore, the present application will not be limited to the embodiments shown herein, but is to be accorded the widest scope consistent with the principles and novel features claimed herein.
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