CN115483120B - Micro-connection process based on laser ultrasonic coupling - Google Patents
Micro-connection process based on laser ultrasonic coupling Download PDFInfo
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- CN115483120B CN115483120B CN202210933557.5A CN202210933557A CN115483120B CN 115483120 B CN115483120 B CN 115483120B CN 202210933557 A CN202210933557 A CN 202210933557A CN 115483120 B CN115483120 B CN 115483120B
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
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- H01L24/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L24/26—Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
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- H01L21/60—Attaching or detaching leads or other conductive members, to be used for carrying current to or from the device in operation
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Abstract
本发明涉及电子元器件封装技术领域,提供一种基于激光超声耦合的微连接工艺,包括在管壳的敞口的端面上依次附着第一粘附层、种子层、第一键合层、第二键合层及抗氧化层,在半导体晶圆盖板的盖合面上依次附着第二粘附层与第三键合层;将电子元器件放入管壳内,将半导体晶圆盖板的盖合面盖设于敞口的端面上;由敞口确定激光键合路径,开启超声波发生装置以带动管壳及半导体晶圆盖板振动;控制激光发生器发射的激光在半导体晶圆盖板上沿激光键合路径移动;第一键合层与第三键合层的材质相同,第一键合层的熔点高于第二键合层的熔点;本发明通过将激光作为瞬态液相键合的热源,并将超声波介入瞬态液相键合的反应过程,保证了封装的瞬时性与可靠性。
The invention relates to the technical field of electronic component packaging, and provides a micro-connection process based on laser ultrasonic coupling, comprising: sequentially attaching a first adhesion layer, a seed layer, a first bonding layer, a second bonding layer and an anti-oxidation layer on the open end face of a tube shell, and sequentially attaching a second adhesion layer and a third bonding layer on the cover surface of a semiconductor wafer cover; placing the electronic component into the tube shell, and covering the cover surface of the semiconductor wafer cover plate on the open end face; determining a laser bonding path by the open end, turning on an ultrasonic generator to drive the tube shell and the semiconductor wafer cover plate to vibrate; controlling the laser emitted by the laser generator to move along the laser bonding path on the semiconductor wafer cover plate; the first bonding layer and the third bonding layer are made of the same material, and the melting point of the first bonding layer is higher than the melting point of the second bonding layer; the invention ensures the instantaneousness and reliability of packaging by using laser as a heat source for transient liquid phase bonding and intervening ultrasonic waves in the reaction process of transient liquid phase bonding.
Description
技术领域Technical Field
本发明涉及电子元器件封装技术领域,尤其涉及一种基于激光超声耦合的微连接工艺。The invention relates to the technical field of electronic component packaging, and in particular to a micro-connection process based on laser ultrasonic coupling.
背景技术Background technique
随着集成电路领域的发展,电子元器件呈现出小型化及高度集成化的特点;为了确保电子元器件工作的稳定性与可靠性,需要对电子元器件进行良好的封装,一方面,可以减少电子元器件的机械振动损伤,另一方面,可以保证良好的真空性与气密性。With the development of the integrated circuit field, electronic components are becoming miniaturized and highly integrated. In order to ensure the stability and reliability of the electronic components, they need to be well packaged. On the one hand, it can reduce the mechanical vibration damage of the electronic components, and on the other hand, it can ensure good vacuum and airtightness.
现有的封装方法包括热压键合与表面活化键合,热压键合是通过对键合界面加热、施压,使得原子间发生相互扩散、重结晶实现连接;然而热压键合工艺温度通常达到300℃以上,高温会使得键合接头中热应力提高,降低连接强度,且容易对热敏元件造成损伤;表面活化键合是通过高能粒子束轰击键合界面,去除表面的氧化层及污染物从而获得高活性的材料表面,施加压力即可在室温下实现牢固的键合,然而表面活化键合的工艺复杂,对设备要求较高。Existing packaging methods include thermocompression bonding and surface activated bonding. Thermocompression bonding is achieved by heating and applying pressure to the bonding interface to allow atoms to diffuse and recrystallize to achieve connection. However, the process temperature of thermocompression bonding usually reaches above 300°C. High temperature will increase the thermal stress in the bonding joint, reduce the connection strength, and easily damage the thermosensitive components. Surface activated bonding is achieved by bombarding the bonding interface with a high-energy particle beam to remove the surface oxide layer and contaminants to obtain a highly active material surface. Applying pressure can achieve a strong bond at room temperature. However, the process of surface activated bonding is complicated and has high requirements for equipment.
发明内容Summary of the invention
本发明提供一种基于激光超声耦合的微连接工艺,用以解决或改善现有电子元器件在封装过程中存在封装工艺复杂、可靠性较低的问题。The present invention provides a micro-connection process based on laser ultrasonic coupling, which is used to solve or improve the problems of complex packaging process and low reliability in the packaging process of existing electronic components.
本发明提供一种基于激光超声耦合的微连接工艺,包括:在管壳的敞口的端面上依次附着第一粘附层、种子层、第一键合层、第二键合层及抗氧化层,在半导体晶圆盖板的盖合面上依次附着第二粘附层与第三键合层;The present invention provides a micro-connection process based on laser ultrasonic coupling, comprising: sequentially attaching a first adhesion layer, a seed layer, a first bonding layer, a second bonding layer and an anti-oxidation layer on an open end surface of a tube shell, and sequentially attaching a second adhesion layer and a third bonding layer on a cover surface of a semiconductor wafer cover plate;
将电子元器件放入所述管壳内,将所述半导体晶圆盖板的盖合面盖设于所述敞口的端面上,以使得所述抗氧化层与所述第三键合层接触;Putting electronic components into the tube shell, and placing the covering surface of the semiconductor wafer cover plate on the open end surface so that the anti-oxidation layer contacts the third bonding layer;
根据所述敞口确定激光键合路径,开启超声波发生装置以带动所述管壳及所述半导体晶圆盖板振动;控制激光发生器发射的激光在所述半导体晶圆盖板上沿所述激光键合路径移动;Determine a laser bonding path according to the opening, turn on an ultrasonic generator to drive the tube shell and the semiconductor wafer cover to vibrate; control the laser emitted by the laser generator to move along the laser bonding path on the semiconductor wafer cover;
其中,所述第一键合层与所述第三键合层的材质相同,所述第一键合层的熔点高于所述第二键合层的熔点。The first bonding layer and the third bonding layer are made of the same material, and the melting point of the first bonding layer is higher than the melting point of the second bonding layer.
根据本发明提供的一种基于激光超声耦合的微连接工艺,所述将所述半导体晶圆盖板的盖合面盖设于所述敞口的端面上,包括:According to a micro-connection process based on laser ultrasonic coupling provided by the present invention, the covering surface of the semiconductor wafer cover plate is placed on the open end surface, comprising:
将所述管壳置于封装平台的凹槽内,将所述半导体晶圆盖板的盖合面盖设于所述敞口的端面上,所述半导体晶圆盖板在所述封装平台上的透明压板的作用下与所述敞口的端面抵接;The tube shell is placed in the groove of the packaging platform, and the covering surface of the semiconductor wafer cover plate is placed on the end surface of the opening, and the semiconductor wafer cover plate abuts against the end surface of the opening under the action of the transparent pressing plate on the packaging platform;
其中,所述超声波发生装置设于所述封装平台上。Wherein, the ultrasonic generating device is arranged on the packaging platform.
根据本发明提供的一种基于激光超声耦合的微连接工艺,所述在管壳的敞口的端面上依次附着第一粘附层、种子层、第一键合层、第二键合层及抗氧化层,包括:According to a micro-connection process based on laser ultrasonic coupling provided by the present invention, the first adhesion layer, the seed layer, the first bonding layer, the second bonding layer and the anti-oxidation layer are sequentially attached to the open end surface of the tube shell, comprising:
通过电子束蒸发工艺在所述端面上沉积厚度范围为1.9微米至2.1微米的所述第一粘附层;Depositing the first adhesion layer having a thickness ranging from 1.9 micrometers to 2.1 micrometers on the end surface by an electron beam evaporation process;
其中,所述第一粘附层为镍粘附层。Wherein, the first adhesion layer is a nickel adhesion layer.
根据本发明提供的一种基于激光超声耦合的微连接工艺,所述在管壳的敞口的端面上依次附着第一粘附层、种子层、第一键合层、第二键合层及抗氧化层,还包括:According to a micro-connection process based on laser ultrasonic coupling provided by the present invention, the first adhesion layer, the seed layer, the first bonding layer, the second bonding layer and the anti-oxidation layer are sequentially attached to the open end surface of the tube shell, and further includes:
在所述第一粘附层上电镀厚度范围为2.85微米至3.15微米的所述种子层;electroplating the seed layer having a thickness ranging from 2.85 micrometers to 3.15 micrometers on the first adhesion layer;
其中,所述种子层为金种子层。Wherein, the seed layer is a gold seed layer.
根据本发明提供的一种基于激光超声耦合的微连接工艺,所述在管壳的敞口的端面上依次附着第一粘附层、种子层、第一键合层、第二键合层及抗氧化层,还包括:According to a micro-connection process based on laser ultrasonic coupling provided by the present invention, the first adhesion layer, the seed layer, the first bonding layer, the second bonding layer and the anti-oxidation layer are sequentially attached to the open end surface of the tube shell, and further includes:
在所述种子层上电镀厚度范围为2.85微米至3.15微米的所述第一键合层。The first bonding layer is electroplated on the seed layer with a thickness ranging from 2.85 microns to 3.15 microns.
根据本发明提供的一种基于激光超声耦合的微连接工艺,所述在管壳的敞口的端面上依次附着第一粘附层、种子层、第一键合层、第二键合层及抗氧化层,还包括:According to a micro-connection process based on laser ultrasonic coupling provided by the present invention, the first adhesion layer, the seed layer, the first bonding layer, the second bonding layer and the anti-oxidation layer are sequentially attached to the open end surface of the tube shell, and further includes:
在所述第一键合层上电镀厚度范围为1.9微米至2.1微米的所述第二键合层。The second bonding layer having a thickness ranging from 1.9 micrometers to 2.1 micrometers is electroplated on the first bonding layer.
根据本发明提供的一种基于激光超声耦合的微连接工艺,所述在管壳的敞口的端面上依次附着第一粘附层、种子层、第一键合层、第二键合层及抗氧化层,还包括:According to a micro-connection process based on laser ultrasonic coupling provided by the present invention, the first adhesion layer, the seed layer, the first bonding layer, the second bonding layer and the anti-oxidation layer are sequentially attached to the open end surface of the tube shell, and further includes:
在所述第二键合层上电镀厚度范围为0.027微米至0.033微米的所述抗氧化层;Electroplating the anti-oxidation layer with a thickness ranging from 0.027 micrometers to 0.033 micrometers on the second bonding layer;
其中,所述抗氧化层的材质与所述第一键合层的材质相同。Wherein, the material of the anti-oxidation layer is the same as that of the first bonding layer.
根据本发明提供的一种基于激光超声耦合的微连接工艺,所述在半导体晶圆盖板的盖合面上依次附着第二粘附层与第三键合层,包括:According to a micro-connection process based on laser ultrasonic coupling provided by the present invention, the second adhesive layer and the third bonding layer are sequentially attached to the covering surface of the semiconductor wafer cover plate, comprising:
通过电子束蒸发工艺在所述盖合面上沉积厚度范围为0.045微米至0.055微米的所述第二粘附层;Depositing the second adhesion layer having a thickness ranging from 0.045 micrometers to 0.055 micrometers on the covering surface by an electron beam evaporation process;
其中,所述第二粘附层为钛粘附层。Wherein, the second adhesion layer is a titanium adhesion layer.
根据本发明提供的一种基于激光超声耦合的微连接工艺,所述在半导体晶圆盖板的盖合面上依次附着第二粘附层与第三键合层,还包括:According to a micro-connection process based on laser ultrasonic coupling provided by the present invention, the second adhesive layer and the third bonding layer are sequentially attached to the covering surface of the semiconductor wafer cover plate, and further comprises:
在所述第二粘附层上电镀厚度范围为2.85微米至3.15微米的所述第三键合层。The third bonding layer having a thickness ranging from 2.85 micrometers to 3.15 micrometers is electroplated on the second adhesion layer.
根据本发明提供的一种基于激光超声耦合的微连接工艺,所述第一键合层与所述第三键合层均为银键合层,所述第二键合层为铟键合层;According to a micro-connection process based on laser ultrasonic coupling provided by the present invention, the first bonding layer and the third bonding layer are both silver bonding layers, and the second bonding layer is an indium bonding layer;
或者,所述第一键合层与所述第三键合层均为金键合层,所述第二键合层为锡键合层;Alternatively, the first bonding layer and the third bonding layer are both gold bonding layers, and the second bonding layer is a tin bonding layer;
或者,所述第一键合层与所述第三键合层均为铜键合层,所述第二键合层为锡键合层。Alternatively, the first bonding layer and the third bonding layer are both copper bonding layers, and the second bonding layer is a tin bonding layer.
本发明提供的基于激光超声耦合的微连接工艺,通过将激光作为瞬态液相键合的热源,并将超声波介入瞬态液相键合的反应过程,在保证电子元器件性能的同时,缩小了键合热影响区,加快了瞬态液相键合的反应进程,提升了电子元器件封装的稳定性、可靠性及效率,且该基于激光超声耦合的微连接工艺具有良好的适应性,尤其适用于热敏元器件、红外探测器及晶圆级气密性封装领域的应用。The micro-connection process based on laser ultrasonic coupling provided by the present invention uses laser as the heat source of transient liquid phase bonding and introduces ultrasound into the reaction process of transient liquid phase bonding. While ensuring the performance of electronic components, it reduces the bonding heat affected zone, accelerates the reaction process of transient liquid phase bonding, and improves the stability, reliability and efficiency of electronic component packaging. The micro-connection process based on laser ultrasonic coupling has good adaptability and is particularly suitable for applications in the fields of thermosensitive components, infrared detectors and wafer-level airtight packaging.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
为了更清楚地说明本发明或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作一简单地介绍,显而易见地,下面描述中的附图是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the present invention or the prior art, the following briefly introduces the drawings required for use in the embodiments or the description of the prior art. Obviously, the drawings described below are some embodiments of the present invention. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying creative work.
图1是本发明提供的基于激光超声耦合的微连接工艺的流程示意图;FIG1 is a schematic diagram of a process flow of a micro-connection process based on laser ultrasonic coupling provided by the present invention;
图2是本发明提供的管壳与半导体晶圆盖板的整体结构示意图;FIG2 is a schematic diagram of the overall structure of the tube shell and the semiconductor wafer cover provided by the present invention;
图3是本发明提供的半导体晶圆盖板上的第二金属化层的结构示意图;3 is a schematic structural diagram of a second metallization layer on a semiconductor wafer cover provided by the present invention;
图4是本发明提供的管壳上的第一金属化层的结构示意图;FIG4 is a schematic diagram of the structure of the first metallization layer on the tube shell provided by the present invention;
图5是本发明提供的封装平台的结构示意图;FIG5 is a schematic diagram of the structure of a packaging platform provided by the present invention;
图6是本发明提供的超声波发生装置的结构示意图;FIG6 is a schematic structural diagram of an ultrasonic generating device provided by the present invention;
图7是本发明提供的管壳与半导体晶圆盖板键合后的结构示意图;7 is a schematic diagram of the structure of the tube shell and the semiconductor wafer cover plate after bonding provided by the present invention;
附图标记:Reference numerals:
1:管壳;11:粘附层;12:种子层;13:第一键合层;14:第二键合层;15:抗氧化层;2:半导体晶圆盖板;21:第二粘附层;22:第三键合层;3:封装平台;31:样品台;32:弹簧夹具;33:三轴位移平台;331:第一手柄;332:第二手柄;333:第三手柄;34:底座;35:透明压板;4:超声波发生装置;5:激光发生器;6:Ag2In层。1: tube shell; 11: adhesion layer; 12: seed layer; 13: first bonding layer; 14: second bonding layer; 15: anti-oxidation layer; 2: semiconductor wafer cover; 21: second adhesion layer; 22: third bonding layer; 3: packaging platform; 31: sample stage; 32: spring clamp; 33: three-axis displacement platform; 331: first handle; 332: second handle; 333: third handle; 34: base; 35: transparent pressing plate; 4: ultrasonic generator; 5: laser generator; 6: Ag 2 In layer.
具体实施方式Detailed ways
为使本发明的目的、技术方案和优点更加清楚,下面将结合本发明中的附图,对本发明中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。In order to make the purpose, technical solution and advantages of the present invention clearer, the technical solution of the present invention will be clearly and completely described below in conjunction with the drawings of the present invention. Obviously, the described embodiments are part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
在本发明实施例的描述中,需要说明的是,术语“中心”、“纵向”、“横向”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明实施例和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明实施例的限制。此外,术语“第一”、“第二”、“第三”仅用于描述目的,而不能理解为指示或暗示相对重要性。In the description of the embodiments of the present invention, it should be noted that the terms "center", "longitudinal", "lateral", "up", "down", "front", "back", "left", "right", "vertical", "horizontal", "top", "bottom", "inside", "outside" and the like indicate positions or positional relationships based on the positions or positional relationships shown in the accompanying drawings, and are only for the convenience of describing the embodiments of the present invention and simplifying the description, and do not indicate or imply that the devices or elements referred to must have a specific orientation, be constructed and operate in a specific orientation, and therefore cannot be understood as limitations on the embodiments of the present invention. In addition, the terms "first", "second", and "third" are used for descriptive purposes only and cannot be understood as indicating or implying relative importance.
在本发明实施例的描述中,需要说明的是,除非另有明确的规定和限定,术语“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本发明实施例中的具体含义。In the description of the embodiments of the present invention, it should be noted that, unless otherwise clearly specified and limited, the terms "connected" and "connection" should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediate medium. For ordinary technicians in this field, the specific meanings of the above terms in the embodiments of the present invention can be understood according to specific circumstances.
下面结合图1至图7描述本发明提供的一种基于激光超声耦合的微连接工艺。A micro-connection process based on laser ultrasonic coupling provided by the present invention is described below in conjunction with FIGS. 1 to 7 .
如图1所示,本实施例所示的基于激光超声耦合的微连接工艺包括:步骤110,步骤120及步骤130。As shown in FIG. 1 , the micro-connection process based on laser ultrasonic coupling shown in this embodiment includes: step 110 , step 120 and step 130 .
步骤110,在管壳的敞口的端面上依次附着第一粘附层、种子层、第一键合层、第二键合层及抗氧化层,在半导体晶圆盖板的盖合面上依次附着第二粘附层与第三键合层。Step 110, sequentially attaching a first adhesive layer, a seed layer, a first bonding layer, a second bonding layer and an anti-oxidation layer on the open end surface of the tube shell, and sequentially attaching a second adhesive layer and a third bonding layer on the covering surface of the semiconductor wafer cover.
如图2所示,管壳1的材质为氧化铝,管壳1的制作方法如下,以长宽高分别为7mm、7mm、0.8mm的长方体块状氧化铝为例进行说明,在长方体的正方形面的中心凹设长6.1mm、宽6.1mm、深0.5mm的长方体安装槽,从而形成一个具有一端开口的管壳1,安装槽的槽口即为管壳1的敞口,安装槽内用于布置待封装的电子元器件。As shown in FIG2 , the material of the tube shell 1 is alumina. The manufacturing method of the tube shell 1 is as follows, taking a rectangular block of alumina with a length, width and height of 7 mm, 7 mm and 0.8 mm as an example for explanation, a rectangular mounting groove with a length of 6.1 mm, a width of 6.1 mm and a depth of 0.5 mm is provided in the center of the square face of the rectangular block, thereby forming a tube shell 1 with an opening at one end, the notch of the mounting groove is the opening of the tube shell 1, and the mounting groove is used to arrange the electronic components to be packaged.
其中,管壳1上预先制作有金属焊盘,从而可通过引线键合的方式实现管壳1内电子元器件与管壳1外元件的电连接。Among them, a metal pad is pre-made on the tube shell 1, so that the electronic components in the tube shell 1 can be electrically connected with the components outside the tube shell 1 by wire bonding.
半导体晶圆盖板2的材质为硅,半导体晶圆盖板2由半导体划片机在晶圆上切割而成,晶圆由前道工艺制得;半导体晶圆盖板2的长宽高分别为6.8mm、6.8mm、0.5mm,从而该尺寸的半导体晶圆盖板2能够与上述尺寸的管壳1相适配,半导体晶圆盖板2能够盖设于管壳1的敞口,从而形成封闭的结构。The material of the semiconductor wafer cover plate 2 is silicon, and the semiconductor wafer cover plate 2 is cut on the wafer by a semiconductor dicing machine, and the wafer is made by the front-end process; the length, width and height of the semiconductor wafer cover plate 2 are 6.8mm, 6.8mm, and 0.5mm respectively, so that the semiconductor wafer cover plate 2 of this size can be adapted to the tube shell 1 of the above size, and the semiconductor wafer cover plate 2 can be covered on the opening of the tube shell 1 to form a closed structure.
如图3和图4所示,在管壳1与半导体晶圆盖板2制作完毕后,在管壳1的敞口的端面上依次附着第一粘附层11、种子层12、第一键合层13、第二键合层14及抗氧化层15,第一粘附层11、种子层12、第一键合层13、第二键合层14及抗氧化层15形成第一金属化层;在半导体晶圆盖板2的盖合面上依次附着第二粘附层21与第三键合层22,第二粘附层21与第三键合层22形成第二金属化层,从而为管壳1与半导体晶圆盖板2的键合封装作准备。As shown in FIGS. 3 and 4 , after the tube shell 1 and the semiconductor wafer cover plate 2 are manufactured, the first adhesion layer 11, the seed layer 12, the first bonding layer 13, the second bonding layer 14 and the anti-oxidation layer 15 are sequentially attached to the open end surface of the tube shell 1, and the first adhesion layer 11, the seed layer 12, the first bonding layer 13, the second bonding layer 14 and the anti-oxidation layer 15 form a first metallization layer; the second adhesion layer 21 and the third bonding layer 22 are sequentially attached to the covering surface of the semiconductor wafer cover plate 2, and the second adhesion layer 21 and the third bonding layer 22 form a second metallization layer, thereby preparing for the bonding package of the tube shell 1 and the semiconductor wafer cover plate 2.
第一粘附层11、种子层12、第一键合层13、第二键合层14及抗氧化层15的附着方法,以及第二粘附层21与第三键合层22的附着方法将在后文描述。The attachment method of the first adhesion layer 11 , the seed layer 12 , the first bonding layer 13 , the second bonding layer 14 and the anti-oxidation layer 15 , and the attachment method of the second adhesion layer 21 and the third bonding layer 22 will be described later.
其中,第一键合层13与第三键合层22的材质相同,第一键合层13的熔点高于第二键合层14的熔点。The first bonding layer 13 and the third bonding layer 22 are made of the same material, and the melting point of the first bonding layer 13 is higher than the melting point of the second bonding layer 14 .
在第一键合层13与第三键合层22的材质均为银的情况下,第二键合层14的材质为铟,即第一键合层13与第三键合层22均为银键合层,第二键合层14为铟键合层。When the first bonding layer 13 and the third bonding layer 22 are both made of silver, the second bonding layer 14 is made of indium, that is, the first bonding layer 13 and the third bonding layer 22 are both silver bonding layers, and the second bonding layer 14 is an indium bonding layer.
在第一键合层13与第三键合层22的材质均为金的情况下,第二键合层14的材质为锡,即第一键合层13与第三键合层22均为金键合层,第二键合层14为锡键合层。When the first bonding layer 13 and the third bonding layer 22 are both made of gold, the second bonding layer 14 is made of tin, that is, the first bonding layer 13 and the third bonding layer 22 are both gold bonding layers, and the second bonding layer 14 is a tin bonding layer.
在第一键合层13与第三键合层22的材质均为铜的情况下,第二键合层14的材质为锡,即第一键合层13与第三键合层22均为铜键合层,第二键合层14为锡键合层。When the first bonding layer 13 and the third bonding layer 22 are both made of copper, the second bonding layer 14 is made of tin, that is, the first bonding layer 13 and the third bonding layer 22 are both copper bonding layers, and the second bonding layer 14 is a tin bonding layer.
即总共包括但不限于三种键合材料体系,三种键合材料体系分别为:银和铟,金和锡,以及铜和锡。That is, a total of three bonding material systems are included but not limited to, and the three bonding material systems are: silver and indium, gold and tin, and copper and tin.
需要说明的是,为便于描述,后文均以银和铟的键合材料体系为例进行说明,即第一键合层13与第三键合层22的材质均为银,第二键合层14的材质为铟。It should be noted that, for ease of description, the following text uses a bonding material system of silver and indium as an example, that is, the first bonding layer 13 and the third bonding layer 22 are both made of silver, and the second bonding layer 14 is made of indium.
步骤120,将电子元器件放入管壳内,将半导体晶圆盖板的盖合面盖设于敞口的端面上,以使得抗氧化层与第三键合层接触。Step 120, placing the electronic components into the tube shell, and placing the covering surface of the semiconductor wafer cover plate on the open end surface so that the anti-oxidation layer contacts the third bonding layer.
在将管壳1与半导体晶圆盖板2键合封装的过程中,需要借助封装平台3对管壳1与半导体晶圆盖板2进行固定,以保证封装的精度。In the process of bonding and packaging the tube shell 1 and the semiconductor wafer cover plate 2, the tube shell 1 and the semiconductor wafer cover plate 2 need to be fixed by means of the packaging platform 3 to ensure the packaging accuracy.
如图5所示,封装平台3包括:样品台31、弹簧夹具32、三轴位移平台33及底座34;样品台31通过三轴位移平台33与底座34连接,样品台31上设有凹槽,凹槽与管壳1相适配。As shown in FIG5 , the packaging platform 3 includes: a sample stage 31 , a spring clamp 32 , a three-axis displacement platform 33 and a base 34 ; the sample stage 31 is connected to the base 34 via the three-axis displacement platform 33 , and a groove is provided on the sample stage 31 , which is adapted to the tube shell 1 .
将管壳1放入凹槽内,以实现管壳1的固定;将半导体晶圆盖板2的盖合面盖设于管壳1的敞口的端面上,弹簧夹具32上的透明压板35将半导体晶圆盖板2压紧在管壳1的敞口,使得半导体晶圆盖板2抵接在管壳1的敞口,以避免半导体晶圆盖板2与管壳1之间产生相对运动。Place the tube shell 1 into the groove to fix the tube shell 1; cover the covering surface of the semiconductor wafer cover plate 2 on the open end surface of the tube shell 1, and the transparent pressing plate 35 on the spring clamp 32 presses the semiconductor wafer cover plate 2 against the opening of the tube shell 1, so that the semiconductor wafer cover plate 2 abuts against the opening of the tube shell 1 to avoid relative movement between the semiconductor wafer cover plate 2 and the tube shell 1.
在后续的封装过程中,由于激光需要透射透明压板35并照射在半导体晶圆盖板2上,因此,透明压板35需具有较高的透射率,透明压板35的材质可选择氧化铝;申请人在研发过程中发现,氧化铝材料对于波长为980nm的激光,透射率可达到80%以上。In the subsequent packaging process, since the laser needs to transmit the transparent pressure plate 35 and irradiate the semiconductor wafer cover 2, the transparent pressure plate 35 needs to have a high transmittance, and the material of the transparent pressure plate 35 can be selected as alumina; the applicant discovered during the research and development process that the transmittance of the alumina material for the laser with a wavelength of 980nm can reach more than 80%.
步骤130,根据管壳的敞口确定激光键合路径,开启超声波发生装置以带动管壳及半导体晶圆盖板振动;控制激光发生器发射的激光在半导体晶圆盖板上沿激光键合路径移动。Step 130, determine the laser bonding path according to the opening of the tube shell, turn on the ultrasonic generator to drive the tube shell and the semiconductor wafer cover to vibrate; control the laser emitted by the laser generator to move along the laser bonding path on the semiconductor wafer cover.
如图6所示,在底座34背离样品台31的一侧设置超声波发生装置4,超声波发生装置4包括发生器、换能器与模具,发生器用于将220V市电转化为高频交流电信号以驱动换能器工作,换能器用于将高频交流电信号转化为机械振动即超声波并传递至模具,模具将超声波传递至底座34,从而带动整个封装平台3、管壳1及半导体晶圆盖板2同步振动。As shown in FIG6 , an ultrasonic generating device 4 is arranged on the side of the base 34 away from the sample stage 31. The ultrasonic generating device 4 includes a generator, a transducer and a mold. The generator is used to convert 220V AC power into a high-frequency AC signal to drive the transducer to work. The transducer is used to convert the high-frequency AC signal into mechanical vibration, i.e., ultrasonic wave and transmit it to the mold. The mold transmits the ultrasonic wave to the base 34, thereby driving the entire packaging platform 3, the tube shell 1 and the semiconductor wafer cover plate 2 to vibrate synchronously.
在封装的过程中,激光需垂直照射在管壳1的敞口上,并沿着管壳1的敞口环绕移动一周,若管壳1的敞口的形状为正方形,激光移动的路径也呈正方形,即管壳1的敞口的形状可以表征激光移动的路径,从而通过敞口确定激光键合路径。During the packaging process, the laser needs to be irradiated vertically on the opening of the tube shell 1 and move around the opening of the tube shell 1. If the shape of the opening of the tube shell 1 is a square, the path of the laser movement is also a square, that is, the shape of the opening of the tube shell 1 can represent the path of the laser movement, thereby determining the laser bonding path through the opening.
如图7所示,管壳1与半导体晶圆盖板2通过超声波实现高频振动的同时,激光沿着激光键合路径移动,激光的热量使得熔点较低的铟键合层熔化,并与熔点较高的银键合层生成金属间化合物(Intermetallic Compound,缩写为IMC)Ag2In,Ag2In形成Ag2In层6,从而形成Ag-Ag2In-Ag的界面结构,以实现瞬态液相键合,进而实现管壳1与半导体晶圆盖板2的气密性封装;Ag2In的熔点高于700摄氏度,由此,由Ag2In层6形成的键合接头具有良好的耐高温性。As shown in FIG7 , while the tube shell 1 and the semiconductor wafer cover plate 2 are vibrated at high frequency by ultrasound, the laser moves along the laser bonding path. The heat of the laser melts the indium bonding layer with a lower melting point, and generates an intermetallic compound (IMC) Ag 2 In with the silver bonding layer with a higher melting point. Ag 2 In forms an Ag 2 In layer 6, thereby forming an Ag-Ag 2 In-Ag interface structure to achieve transient liquid phase bonding, thereby achieving airtight packaging of the tube shell 1 and the semiconductor wafer cover plate 2. The melting point of Ag 2 In is higher than 700 degrees Celsius, so that the bonding joint formed by the Ag 2 In layer 6 has good high temperature resistance.
其中,采用激光作为瞬态液相键合的热源,益处在于,激光的能量高度集中化,在激光沿激光键合路径移动的过程中,可在局部互连区域进行选择性加热,以在几秒钟的时间内将键合区域的温度升高至材料的熔点以上,而除了互连区域的其他部分的温度基本维持在初始温度,在保证材料之间键合连接的同时,能够防止热量的传递,从而避免键合过程中高温对管壳1内的热敏元件造成损伤,且利用激光键合的另一特点是在键合材料与管壳的基底材料之间形成垂直方向的热梯度,减小了键合过程中电子元器件由于热应力造成的热致翘曲,提升了封装的稳定性与可靠性。Among them, the use of laser as a heat source for transient liquid phase bonding has the advantage that the energy of the laser is highly concentrated. When the laser moves along the laser bonding path, it can selectively heat the local interconnection area to increase the temperature of the bonding area to above the melting point of the material within a few seconds, while the temperature of other parts except the interconnection area is basically maintained at the initial temperature. While ensuring the bonding connection between the materials, it can prevent heat transfer, thereby avoiding damage to the thermosensitive elements in the tube shell 1 caused by high temperature during the bonding process. Another feature of laser bonding is that a vertical thermal gradient is formed between the bonding material and the base material of the tube shell, which reduces the thermal warping of electronic components due to thermal stress during the bonding process and improves the stability and reliability of the package.
申请人在研发过程中发现,利用激光作为热源加热玻璃熔块的中间层材料,可实现陶瓷与可伐合金异质材料对的气密性封装;同样地,利用激光加热金属焊料可实现晶圆级封装,由此,引入激光作为键合热源的方案是可行的。During the research and development process, the applicant discovered that using laser as a heat source to heat the intermediate layer material of the glass frit can achieve airtight packaging of ceramic and kovar alloy heterogeneous materials; similarly, using laser to heat metal solder can achieve wafer-level packaging. Therefore, the solution of introducing laser as a bonding heat source is feasible.
在通过激光加热的过程中,通过将超声波介入瞬态液相键合的反应过程,加快了反应进程,缩短了反应时间,提升了封装的效率。During the laser heating process, ultrasound is introduced into the transient liquid phase bonding reaction process, which accelerates the reaction process, shortens the reaction time, and improves the packaging efficiency.
瞬态液相键合工艺通过低熔点材料熔化与高熔点材料形成金属间化合物从而实现材料间的有效连接;各相金属间化合物的形成及演变是影响键合接头的强度及性能的决定性因素,然而,由于激光热源的瞬时性与高度集中性,传统激光键合工艺中键合接头在停止加热后的几秒钟内便会冷却凝固,这极大的限制了接头中的冶金过程,元素扩散及再结晶被迫中断,不利于形成均质、细晶及力学强度等综合性能较好的金属间化合物组元;因此,为了保证以激光为热源的瞬态液相工艺接头中的冶金反应进程可以在秒级尺度内完成,本申请在利用激光加热的情况下引入超声工艺以加快元素扩散速率,保证键合接头的强度与致密性以获得气密性封装。The transient liquid phase bonding process achieves effective connection between materials by melting low-melting point materials and forming intermetallic compounds with high-melting point materials; the formation and evolution of intermetallic compounds of each phase are the decisive factors affecting the strength and performance of the bonded joint. However, due to the instantaneous and highly concentrated nature of the laser heat source, the bonded joint in the traditional laser bonding process will cool and solidify within a few seconds after the heating is stopped, which greatly limits the metallurgical process in the joint, and the element diffusion and recrystallization are forced to be interrupted, which is not conducive to the formation of intermetallic compound components with good comprehensive properties such as homogeneity, fine grains and mechanical strength; therefore, in order to ensure that the metallurgical reaction process in the transient liquid phase process joint with laser as the heat source can be completed within seconds, the present application introduces an ultrasonic process to accelerate the element diffusion rate while utilizing laser heating, thereby ensuring the strength and density of the bonded joint to obtain an airtight package.
其中,超声波加快反应进程的原理为,当超声波作用于固-液界面时,液体内部会产生极高的拉应力,拉应力的数值超过液体表面张力时,液体就会破裂形成一个个微小的气泡,气泡会在极短的时间内形核、长大并爆破,内部形成几千个大气压强的负压,使得周围液体以极快的速度涌入破裂的气泡,形成微射流,由于气泡大多形成于固-液界面处,且微泡塌陷的方向垂直固-液界面,因此微射流的方向同样垂直于固-液界面,微射流的运动对固-液界面形成强大的冲击力,能够击碎固体材料表面的氧化膜,甚至击碎材料自身,使得更多的物质参与反应;此外,气泡中心的温度可达到几千K,微射流的冲击及高温使得固体材料界面被“刻蚀”,这种由于超声波引起的材料界面刻蚀现象称为“声蚀”,声蚀效应极大地加速了反应进程。Among them, the principle of ultrasound accelerating the reaction process is that when ultrasound acts on the solid-liquid interface, extremely high tensile stress will be generated inside the liquid. When the value of the tensile stress exceeds the surface tension of the liquid, the liquid will rupture to form tiny bubbles. The bubbles will nucleate, grow and explode in a very short time, forming a negative pressure of several thousand atmospheres inside, causing the surrounding liquid to rush into the ruptured bubbles at a very fast speed to form microjets. Since most bubbles are formed at the solid-liquid interface and the direction of microbubble collapse is perpendicular to the solid-liquid interface, the direction of the microjets is also perpendicular to the solid-liquid interface. The movement of the microjets forms a strong impact force on the solid-liquid interface, which can break the oxide film on the surface of the solid material and even break the material itself, allowing more substances to participate in the reaction. In addition, the temperature at the center of the bubble can reach several thousand K. The impact and high temperature of the microjets cause the interface of the solid material to be "etched". This material interface etching phenomenon caused by ultrasound is called "acoustic erosion". The acoustic erosion effect greatly accelerates the reaction process.
针对银-铟瞬态液相材料而言,申请人在研发过程中发现,一种调幅分解Ag3In-Ag2In IMC spinodal结构,相较其他IMC组元,该调幅分解结构内部几乎无孔洞,保证了键合接头的气密性;然而,该键合接头的形成需满足秒级尺度下的元素扩散凝固过程;因此,为实现热敏元件的气密性封装,将超声波与激光键合工艺同时引入瞬态液相互连工艺中,能够生成性能更好的Ag3In-Ag2In IMC spinodal结构,进一步保证了键合接头的可靠性。With respect to silver-indium transient liquid phase materials, the applicant discovered during the research and development process that a spinodal decomposition Ag 3 In-Ag 2 In IMC spinodal structure has almost no holes inside compared to other IMC components, thereby ensuring the airtightness of the bonding joint; however, the formation of the bonding joint requires the element diffusion and solidification process at a second scale; therefore, in order to achieve airtight packaging of the thermosensitive element, the ultrasonic and laser bonding processes are simultaneously introduced into the transient liquid bonding process, which can generate a Ag 3 In-Ag 2 In IMC spinodal structure with better performance, further ensuring the reliability of the bonding joint.
本实施例所示的微连接工艺,通过将激光作为瞬态液相键合的热源,并将超声波介入瞬态液相键合的反应过程,在保证电子元器件性能的同时,加快了瞬态液相键合的反应进程,提升了电子元器件封装的稳定性、可靠性及效率,且该基于激光超声耦合的微连接工艺具有良好的适应性,尤其适用于热敏元器件、红外探测器及晶圆级气密性封装领域的应用。The micro-connection process shown in this embodiment uses laser as the heat source of transient liquid phase bonding and introduces ultrasound into the reaction process of transient liquid phase bonding. While ensuring the performance of electronic components, it accelerates the reaction process of transient liquid phase bonding and improves the stability, reliability and efficiency of electronic component packaging. The micro-connection process based on laser ultrasonic coupling has good adaptability and is particularly suitable for applications in the fields of thermosensitive components, infrared detectors and wafer-level airtight packaging.
需要说明的是,封装平台3在超声波的作用下的振动幅度较小,由此,可认为管壳1与半导体晶圆盖板2在振动过程中不会对激光键合路径造成较大的偏移,即激光在移动过程中,激光始终位于激光键合路径上。It should be noted that the vibration amplitude of the packaging platform 3 under the action of ultrasound is small. Therefore, it can be considered that the tube shell 1 and the semiconductor wafer cover plate 2 will not cause a large deviation to the laser bonding path during the vibration process, that is, the laser is always located on the laser bonding path during the movement.
进一步地,可将振动方向与激光的移动方向保持一致,从而可避免激光键合路径由于振动而造成的偏移;以激光键合路径为正方形为例进行说明,当激光沿着正方形X轴方向的边移动时,可控制封装平台3沿X轴方向振动,以避免激光键合路径在Y轴方向出现偏移;当激光沿着正方形Y轴方向的边移动时,可控制封装平台3沿Y轴方向振动,以避免激光键合路径在X轴方向出现偏移。Furthermore, the vibration direction can be kept consistent with the moving direction of the laser, thereby avoiding the deviation of the laser bonding path due to vibration; taking the laser bonding path as a square as an example, when the laser moves along the edge of the square in the X-axis direction, the packaging platform 3 can be controlled to vibrate along the X-axis direction to avoid the deviation of the laser bonding path in the Y-axis direction; when the laser moves along the edge of the square in the Y-axis direction, the packaging platform 3 can be controlled to vibrate along the Y-axis direction to avoid the deviation of the laser bonding path in the X-axis direction.
在利用激光加热前,需要校准样品台31与激光发生器5之间的相对位置,可在激光发生器5上设置CCD工业相机,CCD工业相机可发射多组十字对准线,在液晶显示屏的辅助下,操作人员通过三轴位移平台33调节样品台31的位置。Before using laser heating, it is necessary to calibrate the relative position between the sample stage 31 and the laser generator 5. A CCD industrial camera can be set on the laser generator 5. The CCD industrial camera can emit multiple sets of cross alignment lines. With the assistance of the LCD screen, the operator adjusts the position of the sample stage 31 through the three-axis displacement platform 33.
三轴位移平台33包括第一手柄331、第二手柄332及第三手柄333,第一手柄331用于驱动样品台31在X轴方向移动,第二手柄332用于驱动样品台31在Y轴方向移动,第三手柄333用于驱动样品台31绕Z轴转动;第一手柄331、第二手柄332及第三手柄333驱动样品台31移动或转动的方式为丝杠传动。The three-axis displacement platform 33 includes a first handle 331, a second handle 332 and a third handle 333. The first handle 331 is used to drive the sample stage 31 to move in the X-axis direction, the second handle 332 is used to drive the sample stage 31 to move in the Y-axis direction, and the third handle 333 is used to drive the sample stage 31 to rotate around the Z-axis. The first handle 331, the second handle 332 and the third handle 333 drive the sample stage 31 to move or rotate by a screw drive.
由公知常识可知,激光光斑的中心位置的能量最高,且能量随着与中心距离的增大而减小。It is known from common knowledge that the energy of the laser spot is the highest at the center, and the energy decreases as the distance from the center increases.
由此,申请人在研发过程中对影响激光能量的各个参数进行了量化分析。Therefore, the applicant conducted a quantitative analysis of various parameters affecting laser energy during the research and development process.
激光热通量F的计算公式如下:The calculation formula of laser heat flux F is as follows:
其中,PL为激光功率,RL为激光半径,RF为激光光斑中任一点与光斑中心之间的距离,Ab为吸收率因子。Where PL is the laser power, RL is the laser radius, RF is the distance between any point in the laser spot and the center of the spot, and Ab is the absorptivity factor.
考虑到激光的散射现象会损失一部分激光能量,因此在上述公式中引入吸收率因子Ab,在本实施例中,Ab=0.6。Considering that the scattering phenomenon of laser light will cause a part of laser energy to be lost, an absorption factor A b is introduced into the above formula. In this embodiment, A b = 0.6.
RF的计算公式如下:The formula for calculating RF is as follows:
其中,x为激光光斑中待计算点的横坐标,y为激光光斑中待计算点的纵坐标,xC为激光光斑的光斑中心的横坐标,yC为激光光斑的光斑中心的纵坐标。Wherein, x is the abscissa of the point to be calculated in the laser spot, y is the ordinate of the point to be calculated in the laser spot, xC is the abscissa of the center of the laser spot, and yC is the ordinate of the center of the laser spot.
由激光热通量F的计算公式可以看出,激光半径RL与激光功率PL是影响激光能量的两大因素;同时,在将激光作为瞬态液相的键合热源时,激光沿激光键合路径的移动速度也会影响键合过程中激光输入的总能量,由此,在利用激光进行瞬态液相键合的过程中,通过控制激光半径、激光功率以及激光的移动速度,来调节激光参数,从而在满足熔点较低的第二键合层能够熔化的条件下,尽可能地减小激光输入的总能量,从而控制热量的传递,以减少管壳1内热敏元件的损伤。It can be seen from the calculation formula of the laser heat flux F that the laser radius RL and the laser power PL are the two major factors that affect the laser energy; at the same time, when the laser is used as the bonding heat source of the transient liquid phase, the moving speed of the laser along the laser bonding path will also affect the total energy of the laser input during the bonding process. Therefore, in the process of transient liquid phase bonding using the laser, the laser parameters are adjusted by controlling the laser radius, the laser power and the moving speed of the laser, so as to reduce the total energy of the laser input as much as possible under the condition that the second bonding layer with a lower melting point can be melted, thereby controlling the heat transfer and reducing the damage to the thermal sensitive element in the tube shell 1.
下面结合图3和图4对管壳1上的第一金属化层及半导体晶圆盖板2上的第二金属化层的制作方法进行说明。The following describes a method for manufacturing the first metallization layer on the tube shell 1 and the second metallization layer on the semiconductor wafer cover plate 2 in conjunction with FIG. 3 and FIG. 4 .
通过电子束蒸发工艺在管壳1的敞口的端面上沉积厚度范围为1.9微米至2.1微米的第一粘附层11;第一粘附层11的具体厚度可以为1.9微米、1.95微米、2微米、2.05微米或2.1微米,优选2微米;其中,第一粘附层11为镍粘附层,即第一粘附层11的材质为镍。A first adhesion layer 11 with a thickness ranging from 1.9 microns to 2.1 microns is deposited on the open end surface of the tube shell 1 by electron beam evaporation process; the specific thickness of the first adhesion layer 11 can be 1.9 microns, 1.95 microns, 2 microns, 2.05 microns or 2.1 microns, preferably 2 microns; wherein the first adhesion layer 11 is a nickel adhesion layer, that is, the material of the first adhesion layer 11 is nickel.
具体地,在敞口的端面上沉积第一粘附层11有利于后续种子层12的电镀沉积,同时,第一粘附层11还能够抑制种子层12的材料向管壳1扩散,即第一粘附层11既具有粘附的作用,还具有阻挡扩散的作用。Specifically, depositing the first adhesion layer 11 on the open end surface is beneficial to the subsequent electroplating deposition of the seed layer 12. At the same time, the first adhesion layer 11 can also inhibit the material of the seed layer 12 from diffusing into the tube shell 1, that is, the first adhesion layer 11 has both adhesion and diffusion blocking effects.
在第一粘附层11制作完毕后,在第一粘附层12上电镀厚度范围为2.85微米至3.15微米的种子层12;种子层12的具体厚度可以为2.85微米、2.9微米、3微米、3.1微米或3.15微米,优选3微米;其中,种子层12为金种子层,即种子层12的材质为金。After the first adhesion layer 11 is produced, a seed layer 12 with a thickness ranging from 2.85 microns to 3.15 microns is electroplated on the first adhesion layer 12; the specific thickness of the seed layer 12 can be 2.85 microns, 2.9 microns, 3 microns, 3.1 microns or 3.15 microns, preferably 3 microns; wherein the seed layer 12 is a gold seed layer, that is, the material of the seed layer 12 is gold.
具体地,通过在第一粘附层11上电镀种子层12,从而可以提升键合后键合接头的力学强度,并减少裂纹与孔隙率,保证了封装的可靠性。Specifically, by electroplating the seed layer 12 on the first adhesion layer 11 , the mechanical strength of the bonding joint after bonding can be improved, and cracks and porosity can be reduced, thereby ensuring the reliability of the package.
在种子层12制作完毕后,在种子层12上电镀厚度范围为2.85微米至3.15微米的第一键合层13;第一键合层13的具体厚度可以为2.85微米、2.9微米、3微米、3.1微米或3.15微米,优选3微米。After the seed layer 12 is produced, a first bonding layer 13 with a thickness ranging from 2.85 microns to 3.15 microns is electroplated on the seed layer 12; the specific thickness of the first bonding layer 13 can be 2.85 microns, 2.9 microns, 3 microns, 3.1 microns or 3.15 microns, preferably 3 microns.
在第一键合层13制作完毕后,在第一键合层13上电镀厚度范围为1.9微米至2.1微米的第二键合层14;第二键合层14的具体厚度可以为1.9微米、1.95微米、2微米、2.05微米或2.1微米,优选2微米。After the first bonding layer 13 is manufactured, a second bonding layer 14 with a thickness ranging from 1.9 microns to 2.1 microns is electroplated on the first bonding layer 13; the specific thickness of the second bonding layer 14 can be 1.9 microns, 1.95 microns, 2 microns, 2.05 microns or 2.1 microns, preferably 2 microns.
对于银和铟的键合材料体系而言,申请人通过试验验证,温度只要达到180摄氏度以上即可实现有效键合,相较于现有工艺温度为300摄氏度以上的热压键合,本实施例可在相对较低的温度下实现键合,从而减小了管壳1内热敏元件的损伤。For the bonding material system of silver and indium, the applicant has verified through experiments that effective bonding can be achieved as long as the temperature reaches above 180 degrees Celsius. Compared with the existing hot pressing bonding with a process temperature of more than 300 degrees Celsius, this embodiment can achieve bonding at a relatively low temperature, thereby reducing damage to the thermal sensitive components in the tube shell 1.
在第二键合层14制作完毕后,在第二键合层14上电镀厚度范围为0.027微米至0.033微米的抗氧化层15;抗氧化层15的具体厚度可以为0.027微米、0.028微米、0.03微米、0.032微米或0.033微米,优选0.03微米;其中,抗氧化层15的材质与第一键合层13的材质相同,对于银和铟的键合材料体系而言,抗氧化层的材质为银。After the second bonding layer 14 is completed, an anti-oxidation layer 15 with a thickness ranging from 0.027 microns to 0.033 microns is electroplated on the second bonding layer 14; the specific thickness of the anti-oxidation layer 15 can be 0.027 microns, 0.028 microns, 0.03 microns, 0.032 microns or 0.033 microns, preferably 0.03 microns; wherein the material of the anti-oxidation layer 15 is the same as the material of the first bonding layer 13, and for the bonding material system of silver and indium, the material of the anti-oxidation layer is silver.
具体地,由于裸露的铟在室温下容易被空气氧化形成氧化铟层,氧化铟具有高度热稳定性及化学稳定性,则氧化铟层不利于银和铟的键合,相应地,会降低键合接头的力学强度,不利于形成密封性封装,封装的可靠性较低,因此,在第二键合层14上附着一层银,以形成抗氧化层15。Specifically, since exposed indium is easily oxidized by air at room temperature to form an indium oxide layer, and indium oxide has high thermal and chemical stability, the indium oxide layer is not conducive to the bonding of silver and indium. Accordingly, it will reduce the mechanical strength of the bonding joint, which is not conducive to the formation of a sealed package, and the reliability of the package is low. Therefore, a layer of silver is attached to the second bonding layer 14 to form an anti-oxidation layer 15.
在晶圆上切割半导体晶圆盖板前,需对整片晶圆进行双面抛光处理,以降低表面粗糙度,从而有利于后续第二金属化层的沉积;其中,晶圆为硅晶圆。Before cutting the semiconductor wafer cover on the wafer, the entire wafer needs to be double-sided polished to reduce the surface roughness, thereby facilitating the subsequent deposition of the second metallization layer; wherein the wafer is a silicon wafer.
通过电子束蒸发工艺在盖合面上沉积厚度范围为0.045微米至0.055微米的第二粘附层21;第二粘附层21的厚度具体可以为0.045微米、0.048微米、0.05微米、0.052微米或0.055微米,优选0.05微米;其中第二粘附层21为钛粘附层,即第二粘附层21的材质为钛。A second adhesion layer 21 with a thickness ranging from 0.045 microns to 0.055 microns is deposited on the covering surface by an electron beam evaporation process; the thickness of the second adhesion layer 21 can specifically be 0.045 microns, 0.048 microns, 0.05 microns, 0.052 microns or 0.055 microns, preferably 0.05 microns; wherein the second adhesion layer 21 is a titanium adhesion layer, that is, the material of the second adhesion layer 21 is titanium.
具体地,在半导体晶圆盖板2上沉积第二粘附层21,既有利于后续第三键合层22的电镀沉积,还能够抑制第三键合层22的材料向半导体晶圆盖板2扩散。Specifically, depositing the second adhesion layer 21 on the semiconductor wafer cover plate 2 is beneficial to the subsequent electroplating deposition of the third bonding layer 22 and can also inhibit the diffusion of the material of the third bonding layer 22 into the semiconductor wafer cover plate 2 .
在第二粘附层21制作完毕后,在第二粘附层21上电镀厚度范围为2.85微米至3.15微米的第三键合层22;第三键合层22的具体厚度可以为2.85微米、2.9微米、3微米、3.1微米或3.15微米,优选3微米;其中,第三键合层22的材质与第一键合层13的材质相同。After the second adhesion layer 21 is produced, a third bonding layer 22 with a thickness ranging from 2.85 microns to 3.15 microns is electroplated on the second adhesion layer 21; the specific thickness of the third bonding layer 22 can be 2.85 microns, 2.9 microns, 3 microns, 3.1 microns or 3.15 microns, preferably 3 microns; wherein the material of the third bonding layer 22 is the same as the material of the first bonding layer 13.
在管壳1上的第一金属化层与半导体晶圆盖板2上的第二金属化层制作完毕后,即可在激光与超声波的共同作用下进行瞬态液相键合,以完成电子元器件的封装。After the first metallization layer on the tube shell 1 and the second metallization layer on the semiconductor wafer cover plate 2 are manufactured, transient liquid phase bonding can be performed under the combined action of laser and ultrasonic waves to complete the packaging of electronic components.
最后应说明的是:以上实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的精神和范围。Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, rather than to limit it. Although the present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that they can still modify the technical solutions described in the aforementioned embodiments, or make equivalent replacements for some of the technical features therein. However, these modifications or replacements do not deviate the essence of the corresponding technical solutions from the spirit and scope of the technical solutions of the embodiments of the present invention.
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US5948286A (en) * | 1997-02-06 | 1999-09-07 | International Business Machines Corporation | Diffusion bonding of lead interconnections using precise laser-thermosonic energy |
CN1480724A (en) * | 2003-07-18 | 2004-03-10 | 华中科技大学 | Bonding and packaging method and device for plastic biochip |
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US20040240804A1 (en) * | 2003-06-02 | 2004-12-02 | Amaresh Mahapatra | Liquid crystal polymer clad optical fiber and its use in hermetic packaging |
WO2020226626A1 (en) * | 2019-05-07 | 2020-11-12 | Light-Med (Usa), Inc. | Silver-indium transient liquid phase method of bonding semiconductor device and heat-spreading mount and semiconductor structure having silver-indium transient liquid phase bonding joint |
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US5948286A (en) * | 1997-02-06 | 1999-09-07 | International Business Machines Corporation | Diffusion bonding of lead interconnections using precise laser-thermosonic energy |
CN1480724A (en) * | 2003-07-18 | 2004-03-10 | 华中科技大学 | Bonding and packaging method and device for plastic biochip |
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